WO2013120917A1 - Verfahren und vorrichtung zur festbettdruckvergasung fester brennstoffe - Google Patents

Verfahren und vorrichtung zur festbettdruckvergasung fester brennstoffe Download PDF

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Publication number
WO2013120917A1
WO2013120917A1 PCT/EP2013/052910 EP2013052910W WO2013120917A1 WO 2013120917 A1 WO2013120917 A1 WO 2013120917A1 EP 2013052910 W EP2013052910 W EP 2013052910W WO 2013120917 A1 WO2013120917 A1 WO 2013120917A1
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WO
WIPO (PCT)
Prior art keywords
gasification
fixed
bed
bed pressure
fixed bed
Prior art date
Application number
PCT/EP2013/052910
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German (de)
English (en)
French (fr)
Inventor
Bernd Meyer
Martin Gräbner
Original Assignee
Technische Universität Bergakademie Freiberg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Technische Universität Bergakademie Freiberg filed Critical Technische Universität Bergakademie Freiberg
Priority to CN201390000256.1U priority Critical patent/CN204111704U/zh
Priority to UAA201409958A priority patent/UA112216C2/uk
Priority to AU2013220406A priority patent/AU2013220406B2/en
Priority to KR1020147025609A priority patent/KR102054353B1/ko
Priority to IN6625DEN2014 priority patent/IN2014DN06625A/en
Priority to AP2014007913A priority patent/AP2014007913A0/xx
Priority to RU2014137020A priority patent/RU2607662C2/ru
Publication of WO2013120917A1 publication Critical patent/WO2013120917A1/de
Priority to ZA2014/06700A priority patent/ZA201406700B/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/34Grates; Mechanical ash-removing devices
    • C10J3/40Movable grates
    • C10J3/42Rotary grates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/15Details of feeding means
    • C10J2200/152Nozzles or lances for introducing gas, liquids or suspensions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/15Details of feeding means
    • C10J2200/154Pushing devices, e.g. pistons

Definitions

  • the invention relates to a method and a device for fixed bed pressure gasification of solid fuels with increased performance and broader range of solid fuels.
  • Inventive method and apparatus allow the gasification of coals with higher fines and / or additional fine-grained and dust-like fuels to gasify.
  • the gasification of coarse solid fuels is preferably carried out in a fixed bed by the method of fixed bed pressure gasification FDV, also known as fixed bed dry bottom gasification.
  • FDV fixed bed pressure gasification
  • the fuels are introduced by means of pressure locks overhead in the fixed bed pressure carburetor.
  • the fixed bed actually moving bed
  • the following zones form ideally from top to bottom: drying zone, pyrolysis zone, gasification zone, oxidation zone and ash zone.
  • the ashes are discharged at the bottom of the carburetor through a rotary grate, which also serves to supply the gasification agent.
  • the raw gas exhaust is located at the top of the fixed bed pressure carburetor.
  • the gasification agents consist essentially of technical oxygen and water vapor.
  • the latter is added in excess to limit the maximum temperatures in the oxidation zone to levels below or near the ash melt temperatures relevant to fixed bed pressure gasification, thus avoiding the formation of massive, malfunctioning ash agglomerates or slagging (non-slagging gasification).
  • the quantitative ratio of water vapor and oxygen in the gasification agent is one of the most important variables for controlling the process. It is frequently used as steam-oxygen ratio (DSV), preferably in the units kg steam / m 3 (iN) oxygen (100 vol. ).
  • DSV steam-oxygen ratio
  • iN units kg steam / m 3 oxygen
  • a thereby caused with, general disadvantage of fixed-bed pressure gasification is that the solid fuel to be gasified may contain only small proportions of fine-grained fuels with particle sizes less than about 5 mm and in particular dusty fuels with particle sizes less than about 1 mm. Otherwise, there are local accumulations of fine-grained material in a fixed bed with the result of non-regular, channel-like flows through the fixed bed, and high dust emissions, incomplete carbon sales in the ashes or slagging. These negative effects increase when using baking coal or briquetted lignite in different ways.
  • the extracted raw coal In order to comply with the required particle size spectrum of the coarse-grained fuels to be gasified, the extracted raw coal must be treated. In particular, coal is screened and / or scrubbed prior to gasification to separate the fine fines (coal fines), reduce ash levels and increase the quality of the solid fuels to be gasified. Often, the fines are less than 5 mm up to 50% of the unspiked, extracted coal. Since the separated coal fines can not readily be used to generate synthesis gases in fixed-bed pressure gasification, appropriate solutions have been sought.
  • pellets are formed from the fine-grained fuels, which are surrounded by a non-baking coating layer.
  • GB1435089A describes the preparation of a fine coal / ash / pitch mixture which is extruded into an extruder and forced out of the extruder directly into the gas space of the atmospheric fixed bed pressure carburetor.
  • Bentonite proposed (US 4,773,919 B1).
  • US Pat. No. 4,146,369 B1 proposes to expand the fixed-bed pressure carburetor upwards by a fluidized-bed gasifier and above it by an entrained-flow gasifier in which fine-grained and pulverulent fuels are to be usable.
  • DD 219 597 A1 discloses a process for the non-slagging gasification of coals in which the gasification agent feed is subdivided into a primary and a secondary feed.
  • the main part of the gasification agent is separated from the grate to the primary gasification and the gasification fraction provided for the secondary gasification in a freely selectable, matched to the gasification material supplied in a known manner via the grate, the DSV should be down to the exclusive steam feed down.
  • this is a non-slagging method of gasification with formation of fine-grained ash.
  • the gasifier must be operated with high DSV, so as not to exceed the ash melting point. The reason for this is the avoidance of slagging of the carburettor.
  • the fine ash constituents should be transported quickly into the area below the Vergasungsffenaustrittes to avoid an ash transport in the upper reactor sections and the ash discharge with the production gas.
  • the proposal does not take into account the fundamental requirements of environmental protection, efficiency and operational safety.
  • the predominant to complete supply of the gasification agent with Vietnameseverschlackendem driving the carburetor in the higher areas of the bed inevitably leads to burning through the bed (channel breakthrough) and the mixing of incompletely reacted oxygen with the raw gas, so that deflagrations or explosions can occur with catastrophic consequences.
  • Other reasons for the impracticability of the proposal are the incompleteness of the carbon turnover, i. the high carbon content of the ashes removed from the rotary grate, as well as the prevention of the landfill capacity of the ash.
  • a further procedural limitation of the non-slagging fixed-bed gasification according to the prior art relates to the fuel spectrum with regard to the bakeability of the coals. Although hard coal with stronger baking properties can be gasified, but require a mechanical stirrer in the top of the fixed bed pressure carburetor, making the process more complicated, prone to failure and more expensive.
  • the object is achieved by a method for fixed bed pressure gasification of coarse solid fuels with oxygen and water vapor-containing gasification means of a Festbettdruckvergasers with a supply of coarse-grained solid fuels and with a gas outlet, both at the head of Festbetttikvergasers, with a rotary grate and an ash discharge at the bottom of the fixed bed pressure carburetor, with an adjustable first gasification agent supply for non-gassing by means of the fixed bed pressure carburettor rotary grate, whereby critical minimum steam-oxygen ratio can be set, with a bed of fixed bed above the rotary grate;
  • second gasification means for a gassing are injected via at least one gasification agent nozzle extending into the upper region of the fixed bed,
  • second gasification agents for the gassing are fed to the fixed-bed pressure carburetor additionally and independently of the first gasification means supplied via the rotary grate for the non-gasifying gasification, wherein the second gasification agent is injected into the upper region of the bed of the fixed bed by means of gasification nozzles extending into the upper region of the fixed bed become.
  • the first gasification agents the first non-slagging gasification with the ideal zone formation over the entire bed of the fixed bed (first drying zone, first pyrolysis zone, first gasification zone, first oxidation zone, first ash zone) and the second gasification means is the second slagging gasification with local vortex zones (Raceway ) Formation.
  • the critical minimum values for the steam-oxygen ratios (in units of kg of steam / m 3 (iN) oxygen (100 vol.%), Stated) of the first gasification agents for the "hot" mode of operation at the "slag limit” are the ash melting behavior of the adapted solid fuels adjusted.
  • the adaptation is simplified in such a way that as defined as ash granulation takes place (softening and sintering of the ashes), without causing slagging and the formation of large slags that block the discharge, cf. / J. Schmalfeld: The refinement and conversion of coal, DGMK (2008), p. 31 1 /.
  • the second gasification agents are introduced into the upper half of the first gasification zone forming during the gasification, d. H. injected below the first pyrolysis zone forming during the gasification.
  • the injection of the second gasification agent in a vertical zone which comprises a vertical extent of ⁇ 1 m in the upper half of the first gasification zone below the pyrolysis zone.
  • the second gasification agents are injected in a vertical zone of the fixed-bed pressure gasifier which reaches at most 1 m above the tip of the rotary grate to 0.5 m below the surface of the bed of the fixed bed, preferably from 2 m above the top of the rotary grate to 1 m below the surface of the bed of the fixed bed.
  • the amount of injected oxygen of the second gasification agent is 0 to 50% of the total amount of oxygen supplied.
  • the injection of the second gasification agent with gas exit velocities of 20 to 120 m / s causes the formation of turbulent vortex zones in the form of voids in the fixed bed in front of the outlet openings of the gasification agent nozzles, in which carbon burns with oxygen (second combustion zones).
  • the vortex zones in front of the nozzles are enveloped by a bed of coke, with which the excess water vapor of the first non-slagging and, if appropriate, the water vapor of the second slagging gasification reacts with a decrease in temperature (second gasification zones).
  • the second gasification agent with steam-oxygen ratios with values of 0.5 kg / m 3 (iN) to 4 kg / m 3 , preferably from 0.5 to 3 kg / m 3 are injected, it is achieved that the before the at least one ash released into the upper region of the packed bed immediately melts or sinters and accumulates in the coke bed at the edge of the fluidized zones (second slag zones).
  • the molten or sintered ashes cool rapidly in the surrounding, colder coke bed and solidify and release their heat to the environment to enhance the endothermic second gasification processes.
  • the formation of classical stratified zones does not take place during gasification with the second gasification agents.
  • the second gasification agents having steam-oxygen ratios of 0.5
  • average maximum temperatures of about 2,000 ° C. are reached in front of the gasification agent nozzles reaching into the packed bed, which results in the gasification of coals with ash melting points of 1,500-1,700 ° C.
  • the vapor / oxygen ratio of the second gasification agent is 3.0
  • average maximum temperatures of about 1,800 ° C. are reached before the gasification agent nozzles reaching into the packed bed. This is advantageous for the gasification of coals with ash melting points of 1,300-1,500 ° C.
  • the gasification with the second gasification agents is carried out below the first pyrolysis zone. This ensures that degassed coke is available (higher cold gas efficiency compared to coal) and that the forming slag or sinter solidifies quickly in the surrounding, colder coke bed.
  • the ambient temperatures in the vicinity of the gasification agent nozzles reaching into the packed beds are approximately 800-1.100 ° C. so high that the solidified slags do not yet attain high strength. Slags adhering to the gasifying agent nozzles are detached from the bed moving downwards and transported further.
  • the temperatures of the coke bed in the first gasification zone oscillate, due to the endothermic gasification reactions (initially without consideration of the second gasification processes) at approximately constant values of the so-called kinetic reaction end temperatures. These values are independent, mainly dependent on the reactivity of the cokes to water vapor.
  • the range of reaction end temperatures ranges from about 800 ° C for highly reactive fuels (eg soft lignite) to 1,100 ° C for low-reactive fuels (eg low-volatile fuels) bituminous coal). It is therefore below the temperature range for the ash melting points of most fuels (about 1 .200 - 1 .500 ° C).
  • the ashes liberated in the second gassing process immediately melt and suppress any channeling, since channel-like "burning through" of oxygen by the bed due to immediate slag formation is prevented are also quickly “closed” under slag formation.
  • the vortex zones can not, or only slightly, move away from the gasification agent nozzles, but meander at a roughly constant height in front of and above the gasification agent nozzles.
  • the second gasification is thus locally limited and defined in height according to the arrangement of the outlet openings of the gasification agent nozzles.
  • the meandering gas flow and the forming slag stabilize the fixed bed in the environment and above the gasification agent nozzles, so that, despite higher flow rates, the regular flow through the fixed bed is maintained.
  • the second slagging gasification leads to a homogenization of the flow through the entire fixed bed.
  • the fine grain fractions of the coarse-grained fuels used can be increased without increasing the discharge of dust with the raw gases.
  • the lower particle sizes of the coarse-grained solid fuels fed to the fixed-bed pressure carburetor on the top side can be reduced from approx. 5 mm to approx. 2 mm.
  • fine fuels Due to the gasification with the second gasifying agents for slagging gasification, in addition to the coarse-grained fuels fine-grained and / or dust-like fuels (fine fuels) can be utilized in larger quantities, which would otherwise be fed to another use or landfill.
  • the fine fuels are introduced in a concentrated form in the fluidized zones, the amounts of added fine fuels are at most so large that stoichiometric ensures a high degree of gasification in the fluidized zones.
  • Another essential advantage of the second gassing is that, in particular, the fine-grained and dust-like fractions of the fuels in the fluidized zones are gasified with coarsening of the ash / slag particles.
  • the cooled, solidified slags contribute to the coarsening of the granulation in the entire fixed bed, especially in the first ash zone, and further to the "interlocking" stabilization of the fixed bed over the entire height are one of the main causes of high dust emissions, are suppressed or pushed back.
  • the second gasification thus leads to a homogenization of the flow through the entire fixed bed.
  • the fines of the fuels used can be increased without increasing the discharge of dust with the raw gases.
  • Dry to moist free-flowing fine fuels are advantageously given up by gravity from above into the bed of the fixed bed, approximately perpendicularly over the vortex zones forming before the gasification agent nozzles.
  • gravity enters the fuel slip due to its own weight, from a arranged over the fixed bed pressure carburetor pressure lock via a metering in the carburetor. It is also possible, however, a gravity entry or a pressure entry from the side directly into the fixed bed above the vortex zones.
  • Dry, pneumatically eligible fine fuels are also blown by means of pneumatic conveying via the gasification agent nozzles or from the side directly into the vortex zones.
  • fine fuels are pumped in the form of slurries, either via the gasification agent nozzles or approximately perpendicularly over the fluidizing zones from above onto or into the bed of the fixed bed.
  • a stuffing insert which takes place at the upper edge of the fixed bed, preferably within the first drying zone.
  • a briquetting press preferably a stamping press
  • fine-grained and / or dust-like fuels fine fuels
  • a mold channel partially agglomerated or compacted and pressed directly into the bed.
  • the compacted fine fuels do not fall from above onto the fixed bed, whereby a disintegration of the compacted fine fuels followed by increased dust discharge in the raw gas is avoided.
  • This form of fine fuel input is independent of the operation of the second gasification and can also be used in non-operated or shut down second gasification agent nozzles.
  • the second slagging gasification not only improves the fuel tolerance for increased fine grain and dust levels of the fuels, or allows additional input of fine fuels, but also increases the fuel tolerance to baking coals that would not be gasifiable without the use of a stirrer.
  • the second combustion zones with their rapid temperature increases and high temperatures reduce the baking tendency of the coals and break up already formed coke networks. Due to the second gassing process, the use of the stirrer can be dispensed with in many cases.
  • the second slagging gasification in the first pyrolysis zone or in the region of the transition from the first pyrolysis zone to the first non-slagging gasification zone.
  • the ratio of the combustion and gasification reactions shifts more towards combustion reactions in the second slagging combustion zones.
  • the raw gas outlet temperatures rise and the higher hydrocarbons, phenols and tar oils, which leave the fixed bed up, are split more thermally.
  • the zone-related adjustment of the second slagging gasification is achieved by setting defined bed heights of the fixed bed. In this way, the raw gas outlet temperatures and the quality of the raw gas (methane content, unwanted secondary components, etc.) can be adjusted.
  • the gasification agent nozzles are designed as water-cooled gasification agent mixture nozzles (in the case of oxygen and water vapor as second gasification agents) or as water-cooled multi-component nozzles (in the case of the combined fine fuel feed). They can be both non-cranked (pipe nozzles), as well as cranked (crops), with the crop nozzles on the tubular nozzle shaft of the cranked nozzle head sits.
  • the gasification agent nozzles are guided through the cylindrical outer jacket or double jacket of the fixed bed pressure gasifier.
  • the non-cranked gasification nozzles are aligned radially and horizontally or deviating from the radial and horizontal alignment with angles of attack of ⁇ 45 ° in all directions adjustable.
  • the nozzles are radially and 10 to 20 ° aligned against the horizontal inclined downwards. This proves to be advantageous in avoiding the penetration of solids into the interior of the nozzles and in the formation of the vortex zones.
  • the Nozzle shanks approximately horizontally aligned and the nozzle heads analogous to the above-mentioned angle of the pipe nozzles.
  • the second gassing is carried out in a limited altitude zone in the upper part of the bed of the fixed-bed pressure gasifier.
  • the lower limit is given by ensuring a sufficiently large, vertical minimum distance to the underlying oxidation zone. This distance is> 0.5 m, preferably> 1 m.
  • the vertical minimum distance to the top of the rotary grate is thus> 1 m, preferably> 2 m. It is necessary for the slag or sinter formed in the fluidized zone to solidify before entering the oxidation zone or the surface of the rotary grate. On the other hand, the gasification nozzles in the gasification zone are not exposed to high temperatures ( ⁇ 1 .100 ° C).
  • the upper limit of the altitude zone results from the fact that a sufficiently high coverage of the gasification agent nozzles of> 0.5 m, preferably> 1 m, is ensured by the fuel bed of the fixed bed.
  • the vertical extent of the altitude zone for the second gasification can be a maximum of 3.5 m, preferably a maximum of 2 m.
  • the gasification agent nozzles may be distributed over this height and over the cross section of the fixed bed pressure gasifier.
  • a further advantageous embodiment consists in selecting as short a height zone with a vertical extent of ⁇ 1 m in the upper half of the first gasification zone, below the pyrolysis zone, as possible for the second gassing zone, so that the first non-gassing zone is uniform over the cross section is extended to the top.
  • the two height zones of Festbetttikvergasers are equipped with gasification nozzles, the lower altitude zone for the minimum level and the upper altitude zone for the maximum level of the fixed bed.
  • the vertical minimum distance between the two altitude zones is more than 1 m.
  • the two height zones are then optionally applied to the second gasification agents.
  • the second gasification agents are injected in an altitude zone either in a planar, horizontal plane, in a vertically stepped arrangement in the altitude zone, or in a conical altitude zone, which simulates the mushroom-shaped contour of the rotary grate or the contour of the bed surface.
  • the nozzle orifices of the gasification agent nozzles lie in a height zone either in a planar, horizontal plane, in a vertically stepped arrangement in the altitude zone, or in a conical height zone, which simulates approximately the mushroom-shaped contour of the rotary grate or the contour of the bed surface.
  • the gasification nozzles protrude with at least 10 cm free length (free nozzle lengths) into the gasification chamber of the fixed bed pressure gasifier.
  • the near-wall gasification agent nozzles preferably protrude approximately 20 cm to 1 m deep into the gasification space of the fixed bed pressure gasifier. For larger, free nozzle lengths up to about 3 m, the gasification nozzles are held with tie rods from above.
  • the lateral, horizontal distance between the outlet openings of the gasification agent nozzles should not be less than 50 cm.
  • the lateral, horizontal spacing of the outlet openings is 1 to 2 m.
  • the vertical distance of superimposed outlet openings should be at least 1 m, but preferably greater than 2 m.
  • the second gasification agents are injected with steam-oxygen ratios between 0.5 and 4 kg / m 3 , preferably between 0.5 and 3 kg / m 3 .
  • steam-oxygen ratios between 0.5 and 4 kg / m 3 , preferably between 0.5 and 3 kg / m 3 .
  • the proportions of second to first oxygen can be varied within wide limits. In the case of a single gasifying agent nozzle 5 to 20 wt .-% of the total oxygen supplied as second oxygen are injected. The upper value can also be exceeded if larger quantities of fine fuels are to be utilized with a gasification agent nozzle. In the case of the formation of a second gasification zone over the entire cross section of the fixed-bed pressure gasifier and the additional gasification of fine fuels, up to 50% by weight of the total oxygen fed in can be injected as second oxygen. The lower the ash contents of the fuel input, the higher the proportion of second oxygen can be achieved.
  • the size of the slag or sintered pieces forming in the vortex zones in front of the individual gasification agent nozzles is limited by the fact that the oxygen loadings of the individual gasification agent nozzles are varied between the minimum and maximum load.
  • the total amount of oxygen of the second gasification medium can be kept constant can be changed by changing the load distribution between the individual nozzles, or it can be varied over time, the total amount of oxygen.
  • the thermal performances of the fixed bed pressure gasifier are increased approximately proportionally. It is of secondary importance, whether the fuel flow rate increased or whether additional fine fuels are registered. Together with the coarse-grained fuels or in addition to the coarse-grained fuels larger amounts of fine-grained and fine fuels can be gasified. Also, the fuel spectrum can be extended towards stronger baking coal without the use of a stirrer would be required. At the same time the specific steam input is lowered and the performance limit of the thermal carburetor performance is increased due to the improved flow conditions of the bed of the fixed bed.
  • the object is achieved by a fixed-bed pressure carburetor for the gasification of coarse-grained, solid fuels with oxygen and water vapor-containing gasification agents with a supply of coarse-grained, solid fuels and with a Rohgasabzug, both at the head of Festbetttigvergasers, with a rotary grate and with a ash discharge at the bottom of the fixed bed pressure carburetor, with an adjustable feed for first gasification means for non-gassing by means of the rotary grate of the fixed bed pressure carburetor, wherein critical minimum values for the steam-oxygen ratio are adjustable, with a bed of fixed bed above the rotary grate, the fixed bed pressure carburetor being at the level of at least one, in the upper region projecting gasification agent for a comparison with the first gasification means additional and independent supply of second gasification agent for a non-closing having gasification ackende, wherein the at least one gasification agent nozzle is designed so that it allows the injection of second gasification agent
  • the at least one gasification agent nozzle is designed such that the amount of injected oxygen of the second gasification agent is 0 to 50% of the total amount of oxygen supplied.
  • the fixed-bed pressure gasifier has a plurality of gasification agent nozzles arranged in one or two planes for the second gasification means.
  • the fixed bed pressure carburetor has at least one entry for fine-grained and / or dust-like fuels (fine fuel input).
  • the fine fuel entry is designed as a gravitational force or as a stuffing entry for compacted by briquetting fine fuels.
  • the gasification agent nozzles are designed as water-cooled gasification agent mixture nozzles (in the case of oxygen and water vapor as second gasification agents) or as water-cooled multicomponent nozzles (in the case of the combined fine fuel feed).
  • the gasification agent nozzles preferably protrude into the gasification space of the fixed bed pressure gasifier with at least 10 cm free length (free nozzle lengths).
  • the nozzle mouths of the gasifying agent nozzles are arranged according to an advantageous embodiment of the invention in a vertical zone either in a planar, horizontal plane, in a vertically stepped arrangement in the altitude zone, or in a conical altitude zone, which is approximately the mushroom-shaped contour of the rotary grate or the contour of the bed surface replicates.
  • the plant engineering design of the second slagging gasification is simple, robust and requires only small equipment technical adjustments of the known and proven Festbetttikvergasers. These relate to the bushings for the gasification nozzles, and if necessary, the supply nozzles for the fine fuels. It proves to be of particular advantage that the second slagging gasification in existing fixed bed pressure gasification plants is set up, retrofitted and operated in stages (starting with a gasification agent jet) completely (with a complete set of gasification jet nozzles) or partially operated or decommissioned or retrofitted according to the requirements can be.
  • FIG. 1 Schematic representation of a fixed bed pressure carburetor
  • FIG. 2 top view section A-A
  • Fig. 1 shows a Festbettdruckvergaser (1) and Fig. 2 is a sectional view of the plane A-A with a plan view.
  • a rotary grate (5) for supplying first gasification means (6) for the non-gasifying gasification and an ash discharge (31) is arranged.
  • the fuel entry (2) opens in the upper part of the fixed bed pressure carburetor in a Ein theoryschacht (28).
  • an entry (21) for fine fuels is arranged at the top of the fixed bed pressure gasifier (1).
  • the fine fuel entry (21) opens into a drop tube (22) supported inside the attachment shaft (28), wherein the drop tube (22) is longer than the attachment shaft (28) and ends with a baffle (24) in the reaction space of the fixed-bed pressure gasifier (1).
  • the fine fuel entry is inertizable with nitrogen (27).
  • the clear inside diameter of the fixed bed pressure carburetor (1) is 4 m and the height of the bed of the fixed bed (3), calculated from the top (4) of the rotary grate (5), an average of 6 m. It is limited by the connection shaft (28) for fuel distribution.
  • the bed of the fixed bed (3) is ideally divided into the five layers from bottom to top: first ash zone (14), first oxidation zone (15), first gasification zone (16), first pyrolysis zone (17) and first drying zone (18).
  • the container casing has feed nozzles (7).
  • the feed ports (7) in the upper level of the first non-slagging gasification zone (16) are equipped with gasifying agent nozzles (12) sufficient for supplying second gasifying means (8) for slagging gasification sufficient to enter the gasification zone.
  • the sockets (7) are numbered in the section A-A clockwise with IM to / 10 /. They are guided through the outer, pressure-bearing container wall (10) and the inner steel shell (1 1). A total of six of the ten nozzles (7) are equipped with gasification nozzles (12).
  • the gasification agent nozzles (12) are designed as tube nozzles, radially aligned and inclined 15 ° downwards towards the horizontal. They protrude 50 cm into the bed of the fixed bed (3).
  • the mouths (13) of the gasification agent nozzles (12) terminate in the upper region of the first non-slagging gasification zone (16).
  • the nozzle (7) directed into the first drying zone (18) is arranged with a briquetting press (32) for the supply of compacted or briquetted fine fuels (21).
  • the fixed bed pressure carburetor thus constructed is operated as follows:
  • the amount of second oxygen of the second gasification agent (8) is a total of 3,200 Nm 3 / h (based on pure oxygen), the steam-oxygen ratio 0.8 kg / Nm 3 .
  • the gasification nozzles (12) of the numbers / 3 /, / 4 /, / 8 / and / 9 / are each with 600 m 3 / h (iN) oxygen and the gasification nozzles (12) of the numbers IM and 161 with 400 m 3 / h (iN) oxygen is applied.
  • vortex zones (19) Before the mouths (13) vortex zones (19) form.
  • numbers 181 and 141 as well as numbers 181 and / 9 / two larger, contiguous regions (20) of the vortex zones (19) are formed.
  • baffles At the lower outlet opening (23) of the downpipe (22) are baffles (24), under which cavities (25) in the bed of the fixed bed (3) form, in which the fine fuels (21) can flow freely.
  • the drop tube (22) is supported on the attachment slot (28) with holders (26).
  • the vertical distance of the outlet openings (23) to the gasification agent nozzles (12) is 2 m.
  • the drop tube (22) is rendered inert with a small amount of nitrogen (27).
  • the fine fuels (21) come from the same hard coal (2).
  • the grain size of the fine fuels (21) is 0-2 mm, the ash content is 40 mass% (tr.), The water content is 5 mass% (tr.).
  • Both downpipes (22) are each 5.5 t / h fine fuels (21) supplied.
  • the thermal performance of the fixed-bed pressure gasifier (1) is increased in the present example by applying the solution according to the invention by about 25%.
  • the co-gasification of fine fuel is made possible for the first time to a considerable extent.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Processing Of Solid Wastes (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
PCT/EP2013/052910 2012-02-13 2013-02-13 Verfahren und vorrichtung zur festbettdruckvergasung fester brennstoffe WO2013120917A1 (de)

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CN201390000256.1U CN204111704U (zh) 2012-02-13 2013-02-13 用于固体燃料的固定床压力气化的装置
UAA201409958A UA112216C2 (uk) 2012-02-13 2013-02-13 Спосіб газифікації твердих горючих матеріалів під тиском у стаціонарному шарі
AU2013220406A AU2013220406B2 (en) 2012-02-13 2013-02-13 Process and device for fixed-bed pressure gasification of solid fuels
KR1020147025609A KR102054353B1 (ko) 2012-02-13 2013-02-13 고체 연료의 고정-베드 압력 가스화를 위한 프로세스 및 장치
IN6625DEN2014 IN2014DN06625A (xx) 2012-02-13 2013-02-13
AP2014007913A AP2014007913A0 (en) 2012-02-13 2013-02-13 Process and device for fixed-bed pressure gasification of solid fuels
RU2014137020A RU2607662C2 (ru) 2012-02-13 2013-02-13 Способ и устройство для газификации твердых горючих материалов под давлением в стационарном слое
ZA2014/06700A ZA201406700B (en) 2012-02-13 2014-09-12 Process and apparatus for the fixed-bed pressure gasification of solid fuels

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019226074A1 (ru) * 2018-05-24 2019-11-28 Общество с ограниченной ответственностью "Новые физические принципы" Устройство и способ газификации угля

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013112995B4 (de) * 2013-11-25 2019-10-31 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren zum Aufheizen eines Brennstoffbettes in einem Festbettdruckvergasungsreaktor
DE102013113769B4 (de) 2013-12-10 2020-07-16 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren zur Festbettdruckvergasung kohlenstoffhaltiger Brennstoffe
CN106574194B (zh) * 2014-07-29 2021-03-09 伯恩特·迈耶 用于均匀化流动的固定床气化的方法和设备
PL3887485T3 (pl) * 2018-11-28 2023-03-13 African Rainbow Minerals Limited Reaktor i proces zgazowania i/lub topienia materiałów wsadowych
EP3726202B1 (de) * 2019-04-15 2022-12-21 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Verfahren zur online-steuerung eines schlacke bildenden vergasungsprozesses und anlage für einen vergasungsprozess
RU2764686C1 (ru) * 2021-03-25 2022-01-19 Валентин Федорович Надеев Устройство для получения водорода, монооксида углерода, диоксида углерода и азота
DE102022106172A1 (de) 2022-03-16 2023-09-21 MHR Holding Pte. Ltd. Festbettvergaser mit Temperaturhomogenisierungsschicht

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0117765A2 (en) * 1983-03-01 1984-09-05 Heuristic Engineering Inc. Incinerators, and gasifiers and burners forming part of same
DE19509570A1 (de) * 1995-03-16 1996-09-19 Schwarze Pumpe Energiewerke Ag Verfahren zur Pyrolyse und Festbettdruckvergasung von kohlenstoffhaltigen Stoffen
DE102007017859A1 (de) * 2007-04-13 2008-10-23 Mallon, Joachim, Dipl.-Phys. Vergaser

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU106090A1 (ru) * 1956-06-04 1956-11-30 В.И. Бабий Газогенератор дл газификации кускового и пылевидного топлива с получением гор чего газа и непрерывным жидким шлакоудалением
GB1435089A (en) 1972-11-09 1976-05-12 Gen Electric Fixed bed coal gasification
DE2640180B2 (de) 1976-09-07 1980-10-23 Projektierung Chemische Verfahrenstechnik Gmbh, 4030 Ratingen Verfahren und Vorrichtung zum Vergasen fester Brennstoffe
US4199327A (en) 1978-10-30 1980-04-22 Kaiser Engineers, Inc. Process for gasification of coal to maximize coal utilization and minimize quantity and ecological impact of waste products
DE2847416A1 (de) 1978-11-02 1980-05-14 Metallgesellschaft Ag Verfahren zum vergasen feinkoerniger brennstoffe
DD219597A1 (de) 1983-11-29 1985-03-06 Typoart Schwenkbare anlageplatte fuer sensibilisiertes aufzeichnungsmaterial in belichtungseinrichtungen
DE3441757A1 (de) 1984-11-15 1986-05-15 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zum herstellen kohlehaltiger pellets fuer die vergasung
RU2044954C1 (ru) * 1993-12-21 1995-09-27 Владимир Геннадьевич Ионов Способ сжигания твердого топлива
RU2333929C1 (ru) * 2007-02-26 2008-09-20 Институт химии и химической технологии СО РАН (ИХХТ СО РАН) Способ и установка для газификации твердого топлива

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0117765A2 (en) * 1983-03-01 1984-09-05 Heuristic Engineering Inc. Incinerators, and gasifiers and burners forming part of same
DE19509570A1 (de) * 1995-03-16 1996-09-19 Schwarze Pumpe Energiewerke Ag Verfahren zur Pyrolyse und Festbettdruckvergasung von kohlenstoffhaltigen Stoffen
DE102007017859A1 (de) * 2007-04-13 2008-10-23 Mallon, Joachim, Dipl.-Phys. Vergaser

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019226074A1 (ru) * 2018-05-24 2019-11-28 Общество с ограниченной ответственностью "Новые физические принципы" Устройство и способ газификации угля

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RU2014137020A (ru) 2016-04-10
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AU2013220406A1 (en) 2014-09-04
CN204111704U (zh) 2015-01-21
KR102054353B1 (ko) 2019-12-10
AU2013220406B2 (en) 2015-12-24
DE102013202356A1 (de) 2013-08-14
UA112216C2 (uk) 2016-08-10
KR20140131358A (ko) 2014-11-12
RU2607662C2 (ru) 2017-01-10
AP2014007913A0 (en) 2014-09-30

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