WO2013118734A1 - Aluminum alloy sheet for connecting components and manufacturing process therefor - Google Patents
Aluminum alloy sheet for connecting components and manufacturing process therefor Download PDFInfo
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- WO2013118734A1 WO2013118734A1 PCT/JP2013/052630 JP2013052630W WO2013118734A1 WO 2013118734 A1 WO2013118734 A1 WO 2013118734A1 JP 2013052630 W JP2013052630 W JP 2013052630W WO 2013118734 A1 WO2013118734 A1 WO 2013118734A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/05—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
- H01B1/023—Alloys based on aluminium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
Definitions
- the present invention electrically connects between electric devices (batteries, inverters, motors, etc.) mounted on various electric transportation devices using electricity as a power source such as an electric vehicle or between components inside the electric device.
- the present invention relates to an aluminum alloy plate for connecting parts used for connecting parts to be connected and a method for manufacturing the same.
- Various electric devices such as a battery group, an inverter, and a motor are mounted on various electric transport devices (hybrid vehicle, fuel cell vehicle, electric locomotive, etc.) that use electricity as a power source including an electric vehicle.
- a connecting component called a bus-bar is used.
- connection component Since this connection component must conduct electricity, it is naturally necessary to have excellent conductivity. Further, when the connecting part is connected by a connecting tool such as a bolt, deformation (creep deformation) of the connecting part 1a (see FIG. 1) of the connecting part 1 occurs due to heat generation when energized, so that the tightening torque of the connecting tool is increased.
- the connecting parts must have a high creep resistance so that they do not drop and the couplings come loose or come off.
- the connecting component is often designed in a shape having a curved portion with a small bending radius (R). Therefore, the connection component needs to be excellent in bending workability.
- Patent Document 1 discloses an aluminum alloy for connection parts in which the component composition is specified and the conditions of conductivity and tempering are specified. Patent Document 1 describes that the aluminum alloy has excellent conductivity and excellent creep resistance.
- Patent Document 2 discloses a method for producing an aluminum alloy sheet in which a homogenized heat treatment, hot rolling, cold rolling, and final annealing under predetermined conditions are performed on an ingot with a specified component composition. And in patent document 2, it describes that the aluminum alloy plate manufactured with the said manufacturing method has the bending workability requested
- Patent Documents 3 and 4 disclose a technique related to an aluminum alloy plate for an automobile panel, not for a connection part, in order to improve the bending workability of an Al—Mg—Si based alloy (JIS6000 based Al alloy).
- a technique in which the texture is controlled to set the Cube orientation distribution density to a predetermined value (Patent Document 3) or a crystal grain having an orientation difference of 20 ° or less with respect to the total grain boundary length between all crystal grains.
- Patent Document 4 is disclosed.
- Patent Document 1 is a technique that focuses on the improvement of creep resistance, it is a technique that does not consider bending workability at all (see paragraph 0010 of Patent Document 1). Naturally, the bending workability required for the connecting parts could not be satisfied. Therefore, when the technique disclosed in Patent Document 1 is applied to a connection part, a bending crack may occur on the surface during molding.
- Patent Document 2 is a technique that focuses on the improvement of bending workability, it is a technique that does not consider creep resistance at all (see paragraph 0001 and the like in Patent Document 2). Of course, the creep resistance required for the connecting parts could not be satisfied. Therefore, when the technique disclosed in Patent Document 2 is applied to a connection component, a connecting portion 1a (see FIG. 1) of the connection component 1 is deformed by heat generated during energization, so that a bolt or the like for connecting the connection component can be obtained. There is a possibility that the connector will loosen or come off.
- Patent Documents 3 and 4 consider bending workability as well as Patent Document 2, but do not consider creep resistance at all, and are not for connecting parts. It is a technology for automobile panels. Therefore, the techniques disclosed in Patent Documents 3 and 4 do not satisfy the creep resistance required for connecting parts. Furthermore, even if it has the bending workability required for an automobile panel having a plate thickness of about 1 mm, the connecting part usually has a plate thickness of about 2 mm, so that it has a high bending workability as required for the connecting part. Hard to think.
- the aluminum alloy plate has both the creep resistance and the bending workability required for the connecting part while maintaining the conductivity that is an essential characteristic for the connecting part. No technology seems to exist. In addition, this situation is technical common sense (in order to improve the creep resistance of a plate made of metal, it is necessary to improve the strength, but if the strength is improved, the bending workability of the plate will be reduced, that is, The creep resistance and the bending workability are in a trade-off relationship) and have been considered as a matter of course.
- an object of the present invention is to provide an aluminum alloy plate for connection parts that is excellent in creep resistance and bending workability while maintaining conductivity, and a method for manufacturing the same.
- the inventors of the present invention show that the Cube orientation distribution density and the component composition on the surface of the aluminum alloy plate for connecting parts have a great influence on the creep resistance and bending workability. And found the present invention.
- the aluminum alloy plate for connecting parts according to the present invention contains Si: 0.3 to 1.5 mass%, Mg: 0.3 to 1.0 mass%, and the balance is made of Al and inevitable impurities. It is made of an aluminum alloy, has an electric conductivity of 45.0% IACS or more, and a Cube orientation distribution density on the plate surface by a crystal orientation distribution function analysis of 15 or more.
- the creep resistance can be improved and the bending workability can be improved. That is, according to the aluminum alloy plate for connecting parts, both creep resistance and bending workability required for the connecting parts can be achieved. Moreover, according to this aluminum alloy plate for connection parts, since the content of Si and Mg is specified within a predetermined range, the effect of improving creep resistance can be ensured. Furthermore, according to this aluminum alloy plate for connection parts, since the electrical conductivity is specified to be 45.0% IACS or more, the electrical conductivity required for the connection parts can be ensured.
- the aluminum alloy plate for connection parts according to the present invention preferably includes Fe: less than 0.5 mass% and Zn: less than 0.5 mass% among the inevitable impurities.
- the content of Fe and Zn among inevitable impurities is specified to be less than a predetermined value, so that the effect of improving the bending workability can be ensured. it can.
- the aluminum alloy plate for connecting parts contains Cu: less than 1.0% by mass, Mn: less than 1.0% by mass, Cr: less than 0.5% by mass, Zr: 0.0. It is preferable to further contain one or more selected from less than 3% by mass and Ti: less than 0.1% by mass.
- this aluminum alloy plate for connecting parts since it further contains one or more selected from Cu, Mn, Cr, Zr, Ti less than a predetermined value, while ensuring the effect of improving the bending workability, The effect of improving the creep resistance can be further ensured.
- the method for producing an aluminum alloy plate for connecting parts comprises a homogenization heat treatment step of subjecting an ingot made of the aluminum alloy to a homogenization heat treatment at 500 to 570 ° C. for 1 to 24 hours, and the homogenization heat treatment.
- a solution heat treatment step of applying an artificial aging treatment to the hot-rolled sheet subjected to the solution heat treatment.
- the component composition of the aluminum alloy to be used is specified, the conditions for the homogenization heat treatment and the solution heat treatment are specified, and the cold rolling is not performed.
- the electrical conductivity, the Cube orientation distribution density on the surface of the plate, and the proof stress of the aluminum alloy plate for connection parts manufactured by the method can be set to a predetermined value or more.
- the Cube orientation distribution density on the plate surface by the crystal orientation distribution function analysis is 20 or more, and the average crystal grain size in the rolling direction on the plate surface is 150 ⁇ m or less. Bending surface quality can be improved by reducing the crystal grain size.
- the method for producing an aluminum alloy plate for connecting parts comprises a homogeneous heat treatment step of subjecting an ingot made of the aluminum alloy to a homogenization heat treatment at 500 to 570 ° C. for 1 to 24 hours, and the homogenization heat treatment.
- the component composition of the aluminum alloy to be used is specified, the conditions for the homogenization heat treatment, hot rolling and solution heat treatment are specified, and cold rolling is not performed.
- the electrical conductivity, the Cube orientation distribution density and the proof stress of the aluminum alloy plate for connecting parts manufactured by the manufacturing method can be set to a predetermined value or more and the crystal grain size can be set to a predetermined value or less.
- the conductivity, the Cube orientation distribution density of the plate surface is specified as a predetermined value or more, and the contents of Si and Mg are specified in a predetermined range. Since it retains conductivity and is excellent in creep resistance and bending workability, it can be suitably used as a connection part.
- the composition of the aluminum alloy to be used is specified, the conditions for the homogenization heat treatment and the solution heat treatment are specified, and cold rolling is not performed. As a result, it is possible to produce an aluminum alloy plate for connecting parts that is excellent in creep resistance and bending workability while maintaining conductivity.
- connection component bus bar
- connection component bus bar
- FIG. 1 It is a perspective view of the connection component (bus bar) concerning the embodiment of the present invention. It is a flowchart of the manufacturing method of the aluminum alloy plate for connection components which concerns on this invention. It is a schematic diagram explaining the method of the bending test in the Example of this invention.
- An aluminum alloy plate for connecting parts according to the present invention contains a predetermined amount of Si and Mg, and the balance is made of an aluminum alloy composed of Al and inevitable impurities, and has a conductivity, And the Cube orientation distribution density on the plate surface is a predetermined value or more.
- the aluminum alloy plate for connecting parts according to the present invention preferably has Fe and Zn of unavoidable impurities less than a predetermined value, and is selected from Cu, Mn, Cr, Zr, and Ti that are less than a predetermined value. More preferably, it contains seeds or more.
- Si forms aging precipitates together with Mg during the artificial aging treatment after solution heat treatment. Since Si inhibits the movement of dislocations in a high temperature environment and improves creep resistance, Si is an essential element for the aluminum alloy plate for connecting parts according to the present invention. If the Si content is less than 0.3% by mass, desired creep resistance cannot be obtained. On the other hand, when the Si content exceeds 1.5% by mass, coarse crystallized substances and precipitates are formed, and particularly bending workability is deteriorated. Therefore, the Si content is 0.3 to 1.5% by mass. In order to ensure the effect of improving the bending workability and creep resistance, the Si content is preferably 0.4 to 1.5% by mass, preferably 0.5 to 1.3% by mass. % Is more preferable.
- Mg forms an aging precipitate during the artificial aging treatment after solution heat treatment with Si. Since Mg inhibits the movement of dislocations under a high temperature environment and improves creep resistance, Mg is an essential element for the aluminum alloy plate for connecting parts according to the present invention. If the Mg content is less than 0.3% by mass, desired creep resistance cannot be obtained. On the other hand, when the Mg content exceeds 1.0% by mass, coarse crystallized substances and precipitates are formed, and bending workability is particularly deteriorated. Therefore, the Mg content is 0.3 to 1.0 mass%. The Mg content is preferably 0.5 to 0.8% by mass in order to ensure the effect of improving bending workability and creep resistance.
- Fe, Zn, or the like may be contained within a range that does not hinder the effects of the present invention.
- Fe and Zn are each preferably less than 0.50% by mass (restricted to less than 0.50% by mass). This is because if the Fe content or Zn content is 0.50% by mass or more, the bending workability or the corrosion resistance is lowered.
- Fe and Zn are contained to some extent in scrap and recycled metal (for example, scraps of aluminum alloy materials for clad materials such as brazing sheets). The recycled metal can be blended so that the content of Fe and Zn in the aluminum alloy plate is less than the above range, and the raw material cost can be reduced.
- elements other than Fe and Zn may be contained as unavoidable impurities to the extent that the effects of the present invention are not hindered.
- Cu less than 1.00% by mass
- Cu accelerates aging precipitate formation in the artificial aging treatment after the solution heat treatment. By inhibiting the movement of dislocations in a high temperature environment, Cu improves creep resistance. In order to acquire the said effect, it is preferable to contain Cu 0.05 mass% or more. On the other hand, if the Cu content is 1.00% by mass or more, the stress corrosion cracking resistance, weldability, and bending workability are remarkably deteriorated. Therefore, when Cu is contained in the aluminum alloy plate, the Cu content is less than 1.00% by mass.
- Mn (Mn: less than 1.00% by mass) Mn generates dispersed particles (dispersed phase) during the homogenization heat treatment, and these dispersed particles hinder grain boundary movement after recrystallization. Therefore, Mn is an element that has an effect of refining crystal grains.
- the bending workability of the aluminum alloy plate for connection parts according to the present invention improves as the crystal grains of the aluminum alloy structure become finer. In order to acquire the said effect, it is preferable to contain 0.01 mass% or more of Mn.
- the Mn content is 1.00% by mass or more, a coarse Al—Fe—Si—Mn-based crystallized product is likely to be formed during melting and casting, which causes a decrease in bending workability. Therefore, when Mn is contained in the aluminum alloy plate, the Mn content is less than 1.00% by mass.
- Cr is an element that has an effect of refining crystal grains. In order to acquire the said effect, it is preferable to contain 0.01 mass% or more of Cr. On the other hand, if the Cr content is 0.50% by mass or more, a coarse intermetallic compound is likely to be produced during melting and casting, and the bending workability is deteriorated. Therefore, when Cr is contained in the aluminum alloy plate, the Cr content is less than 0.50% by mass.
- Zr is an element that has an effect of refining crystal grains. In order to acquire the said effect, it is preferable to contain Zr 0.01 mass% or more. On the other hand, when the Zr content is 0.30 mass% or more, a coarse intermetallic compound is likely to be produced during melting and casting, and bending workability is deteriorated. Therefore, when Zr is contained in the aluminum alloy plate, the content of Zr is less than 0.30% by mass.
- Ti is an element having the effect of making the crystal grains of the ingot finer and improving the bending workability by containing a small amount of Ti. In order to acquire the said effect, it is preferable to contain Ti 0.01 mass% or more. On the other hand, if the Ti content is 0.10% by mass or more, a coarse compound is formed and bending workability is deteriorated. Therefore, when Ti is contained in the aluminum alloy plate, the Ti content is less than 0.10% by mass.
- the electrical conductivity of the aluminum alloy plate for connecting parts according to the present invention is 45.0% IACS or more.
- the electrical conductivity is 45.0% IACS or more, electrical conductivity as a connected device can be ensured.
- the electrical resistance is high, that is, the conductivity is less than 45.0% IACS, it is necessary to increase the cross-sectional area of the connecting component in order to flow a desired current, leading to an increase in the component weight.
- the conductivity is preferably as high as possible, preferably 47.0% IACS or more, and more preferably 50.0% IACS or more.
- the adjustment of conductivity is achieved by controlling the Si content, Mg content, homogenization heat treatment conditions, solution heat treatment conditions, and artificial aging conditions in the aluminum alloy sheet manufacturing process.
- the conductivity is preferably 60% IACS or less.
- the Cube orientation distribution density on the surface of the aluminum alloy plate for connection parts according to the present invention is 15 or more.
- the Cube orientation distribution density on the plate surface is 15 or more, both creep resistance and bending workability required for the connecting parts can be achieved.
- the Cube orientation distribution density on the surface of the plate is less than 15, bending workability is deteriorated.
- the Cube orientation distribution density is preferably 20 or more, more preferably 30 or more, in order to ensure the effect of improving creep resistance and bending workability.
- the Cube orientation distribution density is less than 15, which indicates that the crystal orientation of the plate surface is relatively random.
- the Cube orientation distribution density is 15 or more, that is, when the Cube orientation is accumulated more than a certain amount, the ratio of small-angle grain boundaries having a small orientation difference between adjacent crystal grains increases. Reduce or eliminate grain boundary step during deformation.
- the Cube orientation since a uniform slip deformation is possible compared to other orientations, formation of a shear band is suppressed.
- the bending workability is improved by setting the Cube orientation distribution density to 15 or more. Can improve (improve). If the Cube orientation distribution density is excessively increased, the manufacturing conditions become severe and the productivity is lowered. Therefore, the Cube orientation distribution density is preferably 100 or less.
- the Cube orientation distribution density is defined by the Cube orientation distribution density by crystal orientation distribution function analysis (hereinafter, referred to as ODF analysis as appropriate) with more accurate crystal texture measurement accuracy.
- ODF analysis crystal orientation distribution function analysis
- the Cube orientation distribution density by ODF analysis can express a wide range quantitatively because the Cube orientation is represented by a ratio (dimensionalless) from a random orientation (non-oriented Al powder sample of a standard sample).
- the in-plane (100 plane) rotational orientation cannot be separated, only a pure Cube orientation cannot be extracted.
- Cube orientation distribution density on the surface of the aluminum alloy plate by ODF analysis is measured using, for example, an X-ray diffractometer [model “Rigaku RAD-rX” (Ru-200B)] manufactured by Rigaku Corporation. This is done by measuring the plate surface.
- the X-ray diffractometer can perform ODF analysis with an incomplete pole figure. That is, incomplete pole figures of ⁇ 100 ⁇ plane and ⁇ 111 ⁇ plane are created by schluz reflection method, ODF analysis is performed by applying Bunge's iterative series expansion method (positivity method), and Cube orientation distribution density Can be requested.
- the relationship between the bending direction and the Cube orientation (orientation direction) when bending the aluminum alloy plate is set so that the Cube orientation of the plate is parallel to the bending direction of the plate (the bending direction of the plate is the material plate).
- the Cube orientation during deformation becomes stable, and good bending workability is obtained. Since the Cube orientation of the plate has the same structure even when rotated 90 degrees, there is no distinction between 0 degrees and 90 degrees. For this reason, even if the bending direction of the plate is parallel or perpendicular to the rolling direction of the material plate, the Cube orientation has the same structure, and good bending workability can be obtained.
- the Cube orientation (distribution direction) of the plate, such as the rolling direction of the plate being 45 degrees with the bending direction of the plate, the Cube orientation is being deformed. Since the crystal orientation is randomized and the bending workability may be inferior, it is preferable that the bending direction of the plate when bending is the above two directions.
- the adjustment of the Cube orientation distribution density on the surface of the plate is achieved by the Si content, the Mg content, the hot rolling conditions in the manufacturing process of the aluminum alloy plate, and the absence of cold rolling. .
- the proof stress (0.2% proof stress) of the aluminum alloy plate for connecting parts according to the present invention is preferably 180 MPa or more.
- the yield strength is preferably 190 MPa or more, and more preferably 195 MPa or more.
- the adjustment of the proof stress is achieved by the Si content, the Mg content, the homogenization heat treatment condition, the solution treatment condition and the artificial aging treatment condition in the production process of the aluminum alloy sheet.
- connection component is a component that electrically connects a plurality of members. Specifically, it is a bus bar that is electrically connected to various electric devices such as battery groups, inverters, motors, etc. is there. And although a bus bar is not specifically limited about a shape, while it has predetermined thickness, it is a component which exhibits plate shape or a square material shape. For example, the bus bar is a component having a shape as shown in FIG.
- the bus bar made of aluminum alloy has to have a larger cross-sectional area than the bus bar made of copper in order to ensure the conductive performance.
- the bus bar made of aluminum alloy has to have a larger cross-sectional area than the bus bar made of copper in order to ensure the conductive performance.
- the aluminum alloy plate for connection parts according to the present invention is preferably applied to a bus bar having a thickness of 1.5 mm or more, particularly 1.8 to 5.0 mm, among the connection parts, and has a remarkable effect ( Effect of achieving both creep resistance and bending workability).
- the method for producing an aluminum alloy plate for connecting parts includes a homogenization heat treatment step S2, a hot rolling step S3, a solution heat treatment step S4, and an artificial aging treatment step S5. .
- a homogenization heat treatment step S2 a hot rolling step S3, a solution heat treatment step S4, and an artificial aging treatment step S5. .
- the respective steps will be mainly described.
- the aluminum alloy having the above component composition is melted, cast by a known casting method such as a DC forging method, and cooled to below the solidus temperature of the aluminum alloy, and cast to a thickness of about 400 to 600 mm. Make a lump and chamfer as necessary.
- homogenization heat treatment process In the homogenization heat treatment step S2, homogenization heat treatment (soaking) is performed at a predetermined temperature before rolling the ingot cast in the casting step S1. By subjecting the ingot to homogenization heat treatment, internal stress is removed, solute elements segregated at the time of casting are homogenized, and intermetallic compounds precipitated at the time of casting cooling and thereafter grow. Further, the homogenization heat treatment also serves as preheating for the subsequent hot rolling step S3.
- the heat treatment temperature (ingot temperature) in the homogenization heat treatment step S2 is 500 to 570 ° C.
- the heat treatment time (holding time) in the homogenization heat treatment step S2 may be 1 hour or longer in order to complete the homogenization, and may be within 24 hours from the viewpoint of production efficiency.
- the homogenized ingot is hot-rolled continuously from the homogenizing heat treatment step S2.
- the temperature at the time of completion of the heat treatment in the homogenization heat treatment step S2 is maintained, the ingot is roughly rolled, and further, hot rolled plate (hot coil) having a desired thickness is obtained by finish rolling.
- the thickness of the hot rolled sheet may be set by calculating back from the final thickness of the aluminum alloy sheet.
- the Cube orientation distribution density can be controlled by the hot rolling end temperature.
- the hot rolling end temperature should be 360 ° C. or less, and recrystallization is suppressed even at the end of hot rolling, and the processed structure remains.
- the temperature is 330 ° C. or lower.
- the hot rolled plate manufactured in the hot rolling step S3 is solution heat treated.
- the heat treatment temperature (ingot temperature) in the solution heat treatment step S4 is 500 to 570 ° C.
- the heat treatment temperature is less than 500 ° C., undissolved Si or Mg remains, so that an appropriate precipitate distribution cannot be obtained after solution heat treatment and artificial aging treatment, and desired proof stress and creep resistance can be obtained. I can't.
- it exceeds 570 ° C. local melting (burning) occurs on the plate surface. More preferably, it is 520 to 550 ° C.
- the holding time at the heat treatment temperature in the solution heat treatment step S4 is within 60 seconds (may be 0 seconds).
- the rate of temperature increase from 200 ° C. to the heat treatment temperature is preferably 5 ° C./s or more, and the rate of temperature decrease from the heat treatment temperature to 200 ° C. is 10 ° C./s or more. preferable.
- the artificial aging treatment is performed at a predetermined temperature and a predetermined time on the hot-rolled sheet subjected to the solution heat treatment in the solution heat treatment step S4.
- the heat treatment temperature in the artificial aging treatment step S5 is not particularly limited, but is preferably 150 to 250 ° C. When the temperature is lower than 150 ° C., desired proof stress and creep resistance cannot be obtained, and when the temperature exceeds 250 ° C., precipitates are coarsened and the proof strength and creep resistance are lowered.
- the heat treatment time is not particularly limited, but is preferably 1 to 30 hours. If the time is less than 1 hour, particularly when mass production is assumed, a non-uniform temperature distribution occurs in the coil or the sheet, and the material characteristics tend to become unstable. In consideration of productivity, the upper limit is 30 hours.
- the manufacturing method of the aluminum alloy plate for connecting parts according to the present invention is as described above. However, in carrying out the present invention, other processes may be performed between or before and after the respective steps within a range that does not adversely affect the respective steps. These steps may be included. For example, after the artificial aging treatment step S5, a cutting step for cutting into a predetermined size or a processing step for processing into a predetermined shape (bending, punching, etc.) as shown in FIG. 1 may be included. In addition, as for conditions that are not clearly shown in the respective steps, it is sufficient to use conventionally known conditions, and it is needless to say that the conditions can be appropriately changed as long as the effects obtained by the processing in the respective steps are exhibited.
- An aluminum alloy plate for connecting parts according to the present invention contains a predetermined amount of Si and Mg, and the balance is made of an aluminum alloy composed of Al and inevitable impurities, and has a conductivity, And the Cube orientation distribution density of the plate surface is not less than a predetermined value and the crystal grain size is not more than a predetermined value.
- the aluminum alloy plate for connecting parts according to the present invention preferably has Fe and Zn of unavoidable impurities less than a predetermined value, and is selected from Cu, Mn, Cr, Zr, and Ti that are less than a predetermined value. More preferably, it contains seeds or more.
- the Cube orientation distribution density on the plate surface of the aluminum alloy plate for connection parts according to the present invention is 20 or more.
- the Cube orientation distribution density on the plate surface of the aluminum alloy plate for connection parts according to the present invention is 20 or more.
- both creep resistance and bending workability required for connecting parts can be achieved.
- the Cube orientation distribution density on the surface of the plate is less than 20, bending workability is deteriorated.
- the Cube orientation distribution density is preferably 30 or more, and more preferably 50 or more, in order to ensure the effect of improving creep resistance and bending workability.
- the Cube orientation distribution density is less than 20, which indicates that the crystal orientation of the plate surface is relatively random.
- the Cube orientation distribution density is 20 or more, that is, when the Cube orientation is accumulated more than a certain amount, the proportion of small-angle grain boundaries having a small orientation difference between adjacent crystal grains increases. Reduce or eliminate grain boundary step during deformation.
- the Cube orientation since a uniform slip deformation is possible compared to other orientations, formation of a shear band is suppressed.
- the bending workability can be improved by setting the Cube orientation distribution density to 20 or more. Can improve (improve). If the Cube orientation distribution density is excessively increased, the manufacturing conditions become severe and the productivity is lowered. Therefore, the Cube orientation distribution density is preferably 100 or less.
- the Cube orientation distribution density is set to 20 or more, even when compared with the same level of proof stress, the creep resistance required for the connecting parts can be improved.
- the reason for this is not necessarily clear, it is known that the Cube orientation has a small Taylor factor and a small momentum of dislocation (Sai ⁇ ⁇ Ki et al .: Light Metal, 49 (1999), P. 583), which is presumed to be due to suppression of recovery during high temperature holding.
- the aluminum alloy plate for connecting parts according to the present invention has an average crystal grain size in the rolling direction on the plate surface of 150 ⁇ m or less.
- the average grain size in the rolling direction is 150 ⁇ m or less, the surface quality during bending can be improved.
- the average crystal grain size in the rolling direction exceeds 150 ⁇ m, the possibility of rough skin and cracks on the surface during bending increases.
- the average crystal grain size in the rolling direction is preferably 100 ⁇ m or less, and more preferably 50 ⁇ m or less, in order to ensure the effect of improving the surface quality during bending.
- the average crystal grain size in the rolling direction is preferably 10 ⁇ m or more because manufacturing conditions become stricter and productivity is lowered when trying to make it excessively small.
- the average particle size in the rolling direction can be measured by cutting a measurement piece from an aluminum alloy plate, polishing the plate surface, etching it with an electrolytic solution, and observing it at about 100 times with an optical microscope.
- the average grain size in the rolling direction is achieved by controlling the hot rolling start temperature and rolling end temperature in the aluminum alloy sheet manufacturing process.
- the method for producing an aluminum alloy plate for connecting parts includes a homogenization heat treatment step S2, a hot rolling step S3, a solution heat treatment step S4, and an artificial aging treatment step S5. .
- a homogenization heat treatment step S2 a hot rolling step S3, a solution heat treatment step S4, and an artificial aging treatment step S5. .
- steps different from those of the first embodiment will be described. Since others are the same as that of 1st Embodiment, description is abbreviate
- the homogenized ingot is hot rolled.
- the rolling start temperature at this time is set to 350 to 450 ° C.
- a hot rolled plate (hot coil) having a desired thickness is obtained.
- the aspect of cooling to a temperature range of 350 to 450 ° C. where the hot rolling is started may be directly cooled to this temperature range and the hot rolling may be started within this temperature range. (Hereinafter also referred to as two-stage soaking).
- the temperature may be cooled to a temperature range of 350 ° C. or lower, and then reheated to a temperature range of 350 to 450 ° C. where hot rolling is started, and hot rolling may be started in this temperature range (hereinafter, Also called twice soaking).
- the hot rolling start temperature exceeds 450 ° C, it causes rough skin during bending. Moreover, if the hot rolling start temperature is less than 350 ° C., the hot rolling itself becomes difficult.
- the present invention is characterized in that the cold rolling process is not performed after hot rolling, and thus the structure control of the hot rolled sheet is very important.
- the present inventors have found that recrystallized grains generated during hot rolling tend to be coarse and this structure is maintained even after solution heat treatment, which causes rough skin during bending.
- the hot rolling start temperature 450 ° C. or less, recrystallization during hot rolling can be suppressed, and the crystal grain size after the subsequent solution heat treatment can be set to a predetermined value or less.
- an Mg 2 Si compound is formed in the ingot, and this Mg 2 Si compound is a nucleation site of recrystallized grains during the solution heat treatment Therefore, the crystal grain size can be reduced.
- the cooling rate to the hot rolling start temperature range after the homogenization heat treatment is not particularly specified, it is preferably in the range of 20 to 200 ° C./h.
- the cooling rate is 20 ° C./h or less, the Mg 2 Si compound becomes coarse. Therefore, if it is attempted to re-solidify the Mg 2 Si compound in order to obtain a desired strength, a solution heat treatment is required for a long time, and productivity is increased. descend.
- the cooling rate is too high at 200 ° C./h, the temperature distribution in the ingot becomes non-uniform, and there is a possibility that a new problem in which an abnormality such as deformation or warping due to heat shrinkage occurs.
- Cooling means after homogenization heat treatment there are, for example, forced fan air cooling in the soaking furnace or outside the furnace, contact cooling, and cooling by mist or spray.
- the hot rolling finish temperature is not specified. However, by lowering the hot rolling end temperature to 300 ° C. or less in particular, the accumulated strain during hot rolling can be increased and the recrystallization driving force in the subsequent solution heat treatment can be increased. The recrystallized grain size can be further refined while increasing the Cube orientation distribution density.
- the holding time at the heat treatment temperature in the solution heat treatment step S4 is within 100 seconds (may be 0 seconds). This is because when the time exceeds 100 seconds, the effect is saturated and the productivity is lowered. Since others are the same as that of 1st Embodiment, description is abbreviate
- the rate of temperature increase from 200 ° C. to the heat treatment temperature is preferably 5 ° C./s or more, and the rate of temperature decrease from the heat treatment temperature to 200 ° C. is 10 ° C./s or more. preferable.
- Example 1 Example of the first embodiment
- Aluminum alloys (alloys 1 to 17) having the compositions shown in Table 1 were melted, ingots were produced by semi-continuous casting, and face machining was performed. The ingot was subjected to homogenization heat treatment under the conditions shown in Table 2, and then subjected to hot rolling at a rolling rate of 99% continuously without cooling (hot rolling end temperature is Table 2). A rolled sheet was used. Thereafter, cold rolling was not performed (the test materials 20 and 21 were cold rolled), and solution heat treatment was performed under the conditions shown in Table 2. Then, after the solution heat treatment, a sample material (thickness 2 mm) was produced by performing an artificial aging treatment (not performed on the sample material 20) that is held at 200 ° C. for 2 hours.
- Test test A test piece of JIS No. 5 was cut out from the specimen so that the tensile direction was parallel to the rolling direction. Using this test piece, a tensile test was performed in accordance with JIS Z 2241, and tensile strength, yield strength (0.2% yield strength), and elongation were measured. The crosshead speed was 5 mm / min, and the test was performed at a constant speed until the test piece broke.
- Cube orientation distribution density was determined by measuring the surface of the prepared specimen using an X-ray diffractometer manufactured by Rigaku Corporation [model “Rigaku RAD-rX” (Ru-200B)]. ODF analysis was performed using an incomplete pole figure using the X-ray diffractometer. In detail, the incomplete pole figure of ⁇ 100 ⁇ plane and ⁇ 111 ⁇ plane is created by schluz reflection method, ODF analysis is performed by applying Bunge's iterative series expansion method (positivity method), and Cube orientation The distribution density was determined.
- the conductivity was measured by an eddy current conductivity measuring device [model “Sigma Test D2.068”] manufactured by FOERSTER JAPAN Limited. In addition, the measurement of the conductivity was performed at any five locations on the surface of the test material with a space of 100 mm or more between each other.
- the electrical conductivity in the present invention is obtained by averaging the measured electrical conductivities.
- a test piece of JIS No. 3 (JIS Z 2204) was cut out from the specimen so that the longitudinal direction of the test piece coincided with the rolling direction.
- the test piece was subjected to a bending test by the V-block method according to JIS Z 2248 (see FIG. 3), and the bending workability was evaluated.
- the bending test was performed under the conditions of ⁇ (bending angle): 90 °, r (inner bending radius): 0 mm, and t (test material plate thickness): 2 mm.
- residual stress ratio value 75% or more, it has the ability to withstand the phenomenon (creep) that is deformed by continuous stress at high temperature, that is, it has the creep resistance required for connecting parts. evaluated.
- Table 1 or 2 shows the detailed components of the aluminum alloy, the production conditions of the test material, and the material characteristics (test results). In Tables 1 and 2, numerical values that do not satisfy the configuration of the present invention are underlined.
- the specimen 10 (alloy 9) had a Si content that was less than the lower limit of the numerical range defined in the present invention, and the Mg content exceeded the upper limit of the numerical range defined in the present invention.
- the proof stress did not exceed a predetermined value, and as a result, the evaluation was that the bending workability and creep resistance were not excellent.
- the Si content exceeded the upper limit of the numerical range defined in the present invention, and the Mg content was less than the lower limit of the numerical range defined in the present invention.
- the bending workability and creep resistance were not excellent.
- test materials 12 to 18 (alloys 11 to 17) had a value greater than the value specified in the present invention, any one of Fe, Zn, Cu, Mn, Cr, Zr, and Ti had bending workability.
- the evaluation was bad ( ⁇ ).
- the Cube orientation distribution density was less than a predetermined value, resulting in poor bending workability (x). Furthermore, since the sample material 20 was subjected to batch furnace annealing (240 ° C. ⁇ 5 hours (temperature increase rate: 50 ° C./hour, temperature decrease rate: 50 ° C./hour)) as a solution heat treatment, the creep resistance was improved. The evaluation was not good.
- the test material 22 was burned, and the subsequent manufacturing and testing could not be performed.
- sample material 20 assumes the aluminum alloy plate described in Patent Document 2
- sample material 21 assumes the aluminum alloy plate described in Patent Document 1.
- Aluminum alloys (alloys 1 to 17) having the compositions shown in Table 1 were melted, ingots were produced by semi-continuous casting, and face machining was performed. This ingot was subjected to homogenization heat treatment under the conditions shown in Table 3, and then subjected to hot rolling at a rolling rate of 99% continuously without cooling (hot rolling end temperature is Table 3). A rolled sheet was used.
- test material thickness 2 mm
- solution heat treatment was performed under the conditions shown in Table 3.
- a test material thickness 2 mm
- hot rolling was performed by two-stage soaking, and for the test materials 5 to 18, 20, and 23, hot rolling was performed twice by soaking.
- Table 1 or Table 3 shows detailed aluminum alloy components, production conditions of the test materials, and material characteristics (test results). In Tables 1 and 3, numerical values that do not satisfy the configuration of the present invention are underlined.
- the test material 20 was burned, and the subsequent manufacturing and testing could not be performed.
- the Cube orientation distribution density was less than a predetermined value, resulting in poor bending workability. Furthermore, since the sample material 24 was subjected to batch furnace annealing (240 ° C. ⁇ 5 hours (temperature increase rate: 50 ° C./hour, temperature decrease rate: 50 ° C./hour)) as a solution heat treatment, the creep resistance was improved. The evaluation was not good.
- sample material 24 assumes the aluminum alloy plate described in Patent Document 2
- sample material 25 assumes the aluminum alloy plate described in Patent Document 1.
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Abstract
Description
また、当該接続部品をボルト等の連結具により連結する場合、通電時の発熱により接続部品1の連結部1a(図1参照)の変形(クリープ変形)が生じることにより、連結具の締め付けトルクが低下して、連結具が緩んだり外れたりすることがないように、接続部品は高い耐クリープ性を備える必要がある。
さらに、電気機器の省スペース化(小型化)の要望を満たすため、接続部品は、曲げ半径(R)が小さな湾曲部分を有する形状に設計される場合が多い。したがって、接続部品は、曲げ加工性にも優れる必要がある。 Since this connection component must conduct electricity, it is naturally necessary to have excellent conductivity.
Further, when the connecting part is connected by a connecting tool such as a bolt, deformation (creep deformation) of the connecting
Furthermore, in order to satisfy the demand for space saving (miniaturization) of electrical equipment, the connecting component is often designed in a shape having a curved portion with a small bending radius (R). Therefore, the connection component needs to be excellent in bending workability.
しかしながら、近年、自動車の燃費を低減するために、自動車の軽量化、ひいては、自動車に搭載される電気機器の軽量化が求められている。
上記の事情を勘案し、銅よりも軽量であるアルミニウム合金からなる接続部品が提案されている。 Up to now, copper-based materials have been studied for connecting parts that satisfy the above conditions.
However, in recent years, in order to reduce the fuel consumption of automobiles, it has been required to reduce the weight of automobiles and, in turn, to reduce the weight of electrical devices mounted on automobiles.
In view of the above circumstances, connecting parts made of an aluminum alloy that is lighter than copper have been proposed.
なお、この実情は、技術常識(金属から構成される板材の耐クリープ性を向上させるには強度を向上させる必要があるが、強度を向上させると板材の曲げ加工性が低下してしまう、つまり、耐クリープ性と曲げ加工性とはトレードオフの関係にある)に合致するものであり、当然のことであると考えられてきた。 As can be seen from the descriptions in
In addition, this situation is technical common sense (in order to improve the creep resistance of a plate made of metal, it is necessary to improve the strength, but if the strength is improved, the bending workability of the plate will be reduced, that is, The creep resistance and the bending workability are in a trade-off relationship) and have been considered as a matter of course.
また、この接続部品用アルミニウム合金板によれば、SiおよびMgの含有量を所定範囲に特定していることから、耐クリープ性の向上という効果を確実なものとすることができる。
さらに、この接続部品用アルミニウム合金板によれば、導電率を45.0%IACS以上に特定していることから、接続部品に要求される導電率を確保することができる。 According to the aluminum alloy plate for connecting parts, since the Cube orientation distribution density on the surface of the plate is specified more than a predetermined value, the creep resistance can be improved and the bending workability can be improved. That is, according to the aluminum alloy plate for connecting parts, both creep resistance and bending workability required for the connecting parts can be achieved.
Moreover, according to this aluminum alloy plate for connection parts, since the content of Si and Mg is specified within a predetermined range, the effect of improving creep resistance can be ensured.
Furthermore, according to this aluminum alloy plate for connection parts, since the electrical conductivity is specified to be 45.0% IACS or more, the electrical conductivity required for the connection parts can be ensured.
結晶粒径を微細化することで、曲げ表面品質を向上させることができる。 It is preferable that the Cube orientation distribution density on the plate surface by the crystal orientation distribution function analysis is 20 or more, and the average crystal grain size in the rolling direction on the plate surface is 150 μm or less.
Bending surface quality can be improved by reducing the crystal grain size.
本発明に係る接続部品用アルミニウム合金板(以下、適宜、アルミニウム合金板という)は、所定量のSiおよびMgを含有し、残部がAlおよび不可避的不純物からなるアルミニウム合金で構成され、導電率、および板表面のCube方位分布密度が所定値以上であることを特徴とする。
また、本発明に係る接続部品用アルミニウム合金板は、不可避的不純物のうちFe、Znが所定値未満であることが好ましく、所定値未満のCu、Mn、Cr、Zr、Tiから選択される1種以上を含有することがさらに好ましい。
以下、本発明に係る接続部品用アルミニウム合金板の各合金成分、導電率、および板表面のCube方位分布密度について数値限定した理由を説明する。 [Aluminum alloy plate for connecting parts]
An aluminum alloy plate for connecting parts according to the present invention (hereinafter, appropriately referred to as an aluminum alloy plate) contains a predetermined amount of Si and Mg, and the balance is made of an aluminum alloy composed of Al and inevitable impurities, and has a conductivity, And the Cube orientation distribution density on the plate surface is a predetermined value or more.
Further, the aluminum alloy plate for connecting parts according to the present invention preferably has Fe and Zn of unavoidable impurities less than a predetermined value, and is selected from Cu, Mn, Cr, Zr, and Ti that are less than a predetermined value. More preferably, it contains seeds or more.
Hereinafter, the reason why the alloy components, the electrical conductivity, and the Cube orientation distribution density on the surface of the aluminum alloy plate for connecting parts according to the present invention are numerically limited will be described.
Siは、Mgとともに溶体化熱処理後の人工時効処理時に時効析出物を形成する。Siが高温環境下での転位の移動を阻害することで、耐クリープ性を向上させるため、Siは、本発明に係る接続部品用アルミニウム合金板に必須の元素である。
Siの含有量が0.3質量%未満では、所望の耐クリープ性を得られない。一方、Siの含有量が1.5質量%を超えると粗大な晶出物、析出物が形成されて、特に曲げ加工性を劣化させる。
したがって、Siの含有量は0.3~1.5質量%である。
なお、曲げ加工性と耐クリープ性の向上という効果をより確実なものとするため、Siの含有量は0.4~1.5質量%であることが好ましく、0.5~1.3質量%であることがさらに好ましい。 (Si: 0.3-1.5% by mass)
Si forms aging precipitates together with Mg during the artificial aging treatment after solution heat treatment. Since Si inhibits the movement of dislocations in a high temperature environment and improves creep resistance, Si is an essential element for the aluminum alloy plate for connecting parts according to the present invention.
If the Si content is less than 0.3% by mass, desired creep resistance cannot be obtained. On the other hand, when the Si content exceeds 1.5% by mass, coarse crystallized substances and precipitates are formed, and particularly bending workability is deteriorated.
Therefore, the Si content is 0.3 to 1.5% by mass.
In order to ensure the effect of improving the bending workability and creep resistance, the Si content is preferably 0.4 to 1.5% by mass, preferably 0.5 to 1.3% by mass. % Is more preferable.
Mgは、Siとともに溶体化熱処理後の人工時効処理時に時効析出物を形成する。Mgが高温環境下での転位の移動を阻害することで、耐クリープ性を向上させるため、Mgは、本発明に係る接続部品用アルミニウム合金板に必須の元素である。
Mgの含有量が0.3質量%未満では、所望の耐クリープ性を得られない。一方、Mgの含有量が1.0質量%を超えると粗大な晶出物、析出物が形成されて、特に曲げ加工性を劣化させる。
したがって、Mgの含有量は0.3~1.0質量%である。
なお、曲げ加工性と耐クリープ性の向上という効果をより確実なものとするため、Mgの含有量は0.5~0.8質量%であることが好ましい。 (Mg: 0.3-1.0% by mass)
Mg forms an aging precipitate during the artificial aging treatment after solution heat treatment with Si. Since Mg inhibits the movement of dislocations under a high temperature environment and improves creep resistance, Mg is an essential element for the aluminum alloy plate for connecting parts according to the present invention.
If the Mg content is less than 0.3% by mass, desired creep resistance cannot be obtained. On the other hand, when the Mg content exceeds 1.0% by mass, coarse crystallized substances and precipitates are formed, and bending workability is particularly deteriorated.
Therefore, the Mg content is 0.3 to 1.0 mass%.
The Mg content is preferably 0.5 to 0.8% by mass in order to ensure the effect of improving bending workability and creep resistance.
不可避的不純物として、Fe、Zn等が本発明の効果を妨げない範囲で含有されていてもよい。詳細には、FeとZnは、それぞれ、0.50質量%未満であること(0.50質量%未満に制限されていること)が好ましい。Feの含有量またはZnの含有量が0.50質量%以上となると曲げ加工性または耐蝕性が低下してしまうからである。
なお、Fe、Znは、スクラップや再生地金(例えば、ブレージングシート(brazing sheet)等のクラッド材用のアルミニウム合金材の屑等)にある程度含有していることから、製造(溶解)時にスクラップや再生地金を、アルミニウム合金板におけるFe、Znの含有量が前記範囲未満となる程度で配合することができ、原料コストを低減することができる。
また、不可避的不純物として、本発明の効果を妨げない程度に、Fe、Zn以外の元素が含まれていてもよい。 (Inevitable impurities)
As an unavoidable impurity, Fe, Zn, or the like may be contained within a range that does not hinder the effects of the present invention. Specifically, Fe and Zn are each preferably less than 0.50% by mass (restricted to less than 0.50% by mass). This is because if the Fe content or Zn content is 0.50% by mass or more, the bending workability or the corrosion resistance is lowered.
Fe and Zn are contained to some extent in scrap and recycled metal (for example, scraps of aluminum alloy materials for clad materials such as brazing sheets). The recycled metal can be blended so that the content of Fe and Zn in the aluminum alloy plate is less than the above range, and the raw material cost can be reduced.
Moreover, elements other than Fe and Zn may be contained as unavoidable impurities to the extent that the effects of the present invention are not hindered.
Cuは、溶体化熱処理後の人工時効処理における時効析出物形成を促進する。Cuが高温環境下での転位の移動を阻害することで、耐クリープ性を向上させる。
当該効果を得るためには、Cuを0.05質量%以上含有させるのが好ましい。
一方、Cuの含有量が1.00質量%以上であると耐応力腐食割れ性や溶接性、曲げ加工性を著しく劣化させる。
したがって、Cuをアルミニウム合金板に含有させる場合、Cuの含有量は、1.00質量%未満である。 (Cu: less than 1.00% by mass)
Cu accelerates aging precipitate formation in the artificial aging treatment after the solution heat treatment. By inhibiting the movement of dislocations in a high temperature environment, Cu improves creep resistance.
In order to acquire the said effect, it is preferable to contain Cu 0.05 mass% or more.
On the other hand, if the Cu content is 1.00% by mass or more, the stress corrosion cracking resistance, weldability, and bending workability are remarkably deteriorated.
Therefore, when Cu is contained in the aluminum alloy plate, the Cu content is less than 1.00% by mass.
Mnは、均質化熱処理時に分散粒子(分散相)を生成し、これらの分散粒子は再結晶後の粒界移動を妨げる。よって、Mnは、結晶粒を微細化させる効果がある元素である。なお、本発明に係る接続部品用アルミニウム合金板の曲げ加工性は、アルミニウム合金組織の結晶粒が微細なほど向上する。
当該効果を得るためには、Mnを0.01質量%以上含有させるのが好ましい。
一方、Mnの含有量が1.00質量%以上であると溶解、鋳造時に粗大なAl-Fe-Si-Mn系の晶出物を生成しやすく、かえって曲げ加工性を低下させる原因となる。
したがって、Mnをアルミニウム合金板に含有させる場合、Mnの含有量は、1.00質量%未満である。 (Mn: less than 1.00% by mass)
Mn generates dispersed particles (dispersed phase) during the homogenization heat treatment, and these dispersed particles hinder grain boundary movement after recrystallization. Therefore, Mn is an element that has an effect of refining crystal grains. In addition, the bending workability of the aluminum alloy plate for connection parts according to the present invention improves as the crystal grains of the aluminum alloy structure become finer.
In order to acquire the said effect, it is preferable to contain 0.01 mass% or more of Mn.
On the other hand, if the Mn content is 1.00% by mass or more, a coarse Al—Fe—Si—Mn-based crystallized product is likely to be formed during melting and casting, which causes a decrease in bending workability.
Therefore, when Mn is contained in the aluminum alloy plate, the Mn content is less than 1.00% by mass.
Crは、Mnと同様に均質化熱処理時に分散粒子(分散相)を生成し、これらの分散粒子は再結晶後の粒界移動を妨げる。よって、Crは、結晶粒を微細化させる効果がある元素である。
当該効果を得るためには、Crを0.01質量%以上含有させるのが好ましい。
一方、Crの含有量が0.50質量%以上であると溶解、鋳造時に粗大な金属間化合物を生成しやすく、かえって曲げ加工性を劣化させる。
したがって、Crをアルミニウム合金板に含有させる場合、Crの含有量は、0.50質量%未満である。 (Cr: less than 0.50% by mass)
Cr, like Mn, produces dispersed particles (dispersed phase) during the homogenization heat treatment, and these dispersed particles hinder grain boundary movement after recrystallization. Therefore, Cr is an element that has an effect of refining crystal grains.
In order to acquire the said effect, it is preferable to contain 0.01 mass% or more of Cr.
On the other hand, if the Cr content is 0.50% by mass or more, a coarse intermetallic compound is likely to be produced during melting and casting, and the bending workability is deteriorated.
Therefore, when Cr is contained in the aluminum alloy plate, the Cr content is less than 0.50% by mass.
Zrは、Mnと同様に均質化熱処理時に分散粒子(分散相)を生成し、これらの分散粒子は再結晶後の粒界移動を妨げる。よって、Zrは、結晶粒を微細化させる効果がある元素である。
当該効果を得るためには、Zrを0.01質量%以上含有させるのが好ましい。
一方、Zrの含有量が0.30質量%以上であると溶解、鋳造時に粗大な金属間化合物を生成しやすく、かえって曲げ加工性を劣化させる。
したがって、Zrをアルミニウム合金板に含有させる場合、Zrの含有量は、0.30質量%未満である。 (Zr: less than 0.30% by mass)
Zr, like Mn, generates dispersed particles (dispersed phase) during the homogenization heat treatment, and these dispersed particles hinder grain boundary movement after recrystallization. Therefore, Zr is an element that has an effect of refining crystal grains.
In order to acquire the said effect, it is preferable to contain Zr 0.01 mass% or more.
On the other hand, when the Zr content is 0.30 mass% or more, a coarse intermetallic compound is likely to be produced during melting and casting, and bending workability is deteriorated.
Therefore, when Zr is contained in the aluminum alloy plate, the content of Zr is less than 0.30% by mass.
Tiは、微量含有させることで、鋳塊の結晶粒を微細化し、曲げ加工性を向上させる効果がある元素である。
当該効果を得るためには、Tiを0.01質量%以上含有させるのが好ましい。
一方、Tiの含有量が0.10質量%以上であると粗大な化合物を形成して曲げ加工性を劣化させる。
したがって、Tiをアルミニウム合金板に含有させる場合、Tiの含有量は、0.10質量%未満である。 (Ti: less than 0.10% by mass)
Ti is an element having the effect of making the crystal grains of the ingot finer and improving the bending workability by containing a small amount of Ti.
In order to acquire the said effect, it is preferable to contain Ti 0.01 mass% or more.
On the other hand, if the Ti content is 0.10% by mass or more, a coarse compound is formed and bending workability is deteriorated.
Therefore, when Ti is contained in the aluminum alloy plate, the Ti content is less than 0.10% by mass.
本発明に係る接続部品用アルミニウム合金板の導電率は、45.0%IACS以上とする。
導電率が45.0%IACS以上であると、接続機器としての導電性能を確保することができる。一方、電気抵抗が高い、すなわち導電率が45.0%IACS未満であると、所望の電流を流すために接続部品の断面積を増加させる必要が生じ、部品重量の増加に繋がってしまう。
なお、導電率については、高ければ高いほどよく、好ましくは47.0%IACS以上、さらに好ましくは50.0%IACS以上である。 (Conductivity: 45.0% IACS or higher)
The electrical conductivity of the aluminum alloy plate for connecting parts according to the present invention is 45.0% IACS or more.
When the electrical conductivity is 45.0% IACS or more, electrical conductivity as a connected device can be ensured. On the other hand, if the electrical resistance is high, that is, the conductivity is less than 45.0% IACS, it is necessary to increase the cross-sectional area of the connecting component in order to flow a desired current, leading to an increase in the component weight.
The conductivity is preferably as high as possible, preferably 47.0% IACS or more, and more preferably 50.0% IACS or more.
なお、導電率を高くしすぎると、すなわち過度な固溶量減少および析出物粗大化が生じることにより耐クリープ性が低下する傾向にあるため、導電率は60%IACS以下であるのが好ましい。 The adjustment of conductivity is achieved by controlling the Si content, Mg content, homogenization heat treatment conditions, solution heat treatment conditions, and artificial aging conditions in the aluminum alloy sheet manufacturing process. The
If the conductivity is too high, that is, the creep resistance tends to decrease due to excessive decrease in the amount of solid solution and coarsening of precipitates, the conductivity is preferably 60% IACS or less.
本発明に係る接続部品用アルミニウム合金板の板表面におけるCube方位分布密度は15以上とする。
板表面におけるCube方位分布密度が15以上であることにより、接続部品に要求される耐クリープ性と曲げ加工性とを両立させることができる。一方、板表面におけるCube方位分布密度が15未満であると、曲げ加工性が低下してしまう。
なお、耐クリープ性および曲げ加工性の向上という効果をより確実なものとするため、Cube方位分布密度は、好ましくは20以上、さらに好ましくは30以上である。 (Cube orientation distribution density: 15 or more)
The Cube orientation distribution density on the surface of the aluminum alloy plate for connection parts according to the present invention is 15 or more.
When the Cube orientation distribution density on the plate surface is 15 or more, both creep resistance and bending workability required for the connecting parts can be achieved. On the other hand, if the Cube orientation distribution density on the surface of the plate is less than 15, bending workability is deteriorated.
The Cube orientation distribution density is preferably 20 or more, more preferably 30 or more, in order to ensure the effect of improving creep resistance and bending workability.
一方、本発明が規定するように、Cube方位分布密度を15以上とすると、つまり、Cube方位が一定量以上集積すると、隣り合う結晶粒との方位差の小さい小角粒界の割合が大きくなり、変形時の粒界段差を小さく、あるいは生じなくさせる。
また、Cube方位においては、他の方位と比較して均一なすべり変形が可能になることからせん断帯の形成が抑制される。
この結果、曲げ加工の際に割れの起点あるいは伝播経路となる粒界段差や結晶粒内でのせん断帯形成が抑制されるため、Cube方位分布密度を15以上とすることにより、曲げ加工性を改善(向上)できる。
なお、過度にCube方位分布密度を高めようとすると、製造条件が厳しくなり生産性の低下を招くため、Cube方位分布密度は100以下であるのが好ましい。 According to a general manufacturing method, the Cube orientation distribution density is less than 15, which indicates that the crystal orientation of the plate surface is relatively random.
On the other hand, as specified by the present invention, when the Cube orientation distribution density is 15 or more, that is, when the Cube orientation is accumulated more than a certain amount, the ratio of small-angle grain boundaries having a small orientation difference between adjacent crystal grains increases. Reduce or eliminate grain boundary step during deformation.
In addition, in the Cube orientation, since a uniform slip deformation is possible compared to other orientations, formation of a shear band is suppressed.
As a result, since the formation of a shear boundary in the grain boundary step and the crystal grain that becomes the starting point or propagation path of the crack in bending is suppressed, the bending workability is improved by setting the Cube orientation distribution density to 15 or more. Can improve (improve).
If the Cube orientation distribution density is excessively increased, the manufacturing conditions become severe and the productivity is lowered. Therefore, the Cube orientation distribution density is preferably 100 or less.
ただし、板の圧延方向が板の曲げ方向と45度の方向になるなど、上記二つの方向以外の板の曲げ方向と板のCube方位(配行方向)との関係では、Cube方位は変形中に回転し、結晶方位がランダム化して、曲げ加工性が劣る可能性があるため、曲げ加工を施す際における板の曲げ方向は、上記二つの方向とすることが好ましい。 The relationship between the bending direction and the Cube orientation (orientation direction) when bending the aluminum alloy plate is set so that the Cube orientation of the plate is parallel to the bending direction of the plate (the bending direction of the plate is the material plate). When the material is bent (parallel or perpendicular to the rolling direction), the Cube orientation during deformation becomes stable, and good bending workability is obtained. Since the Cube orientation of the plate has the same structure even when rotated 90 degrees, there is no distinction between 0 degrees and 90 degrees. For this reason, even if the bending direction of the plate is parallel or perpendicular to the rolling direction of the material plate, the Cube orientation has the same structure, and good bending workability can be obtained.
However, in the relationship between the bending direction of the plate other than the above two directions and the Cube orientation (distribution direction) of the plate, such as the rolling direction of the plate being 45 degrees with the bending direction of the plate, the Cube orientation is being deformed. Since the crystal orientation is randomized and the bending workability may be inferior, it is preferable that the bending direction of the plate when bending is the above two directions.
本発明に係る接続部品用アルミニウム合金板の耐力(0.2%耐力)は、180MPa以上であることが好ましい。
耐力が180MPa以上であると、接続部品に要求される耐クリープ性を確保することができる。一方、耐力が180MPa未満であると、耐クリープ性が低下してしまう。
なお、耐クリープ性の確保という効果をより確実なものとするため、耐力は、好ましくは190MPa以上、さらに好ましくは195MPa以上である。 (Yield strength: 180 MPa or more)
The proof stress (0.2% proof stress) of the aluminum alloy plate for connecting parts according to the present invention is preferably 180 MPa or more.
When the proof stress is 180 MPa or more, the creep resistance required for the connecting parts can be ensured. On the other hand, when the yield strength is less than 180 MPa, the creep resistance is lowered.
In order to secure the effect of ensuring creep resistance, the yield strength is preferably 190 MPa or more, and more preferably 195 MPa or more.
接続部品とは、複数の部材を電気的に接続する部品である。具体的には、電気を動力源とした各種電動輸送機器等に搭載されている、電池群、インバータ、モータ等の各種の電気機器間または電気機器内部の部品間を電気的に接続するバスバーである。
そして、バスバーは、形状について特に限定されないが、所定の厚さを有するとともに、板状や角材状を呈する部品である。例えば、バスバーは、図1に示すような形状を呈する部品である。 (Connecting parts)
The connection component is a component that electrically connects a plurality of members. Specifically, it is a bus bar that is electrically connected to various electric devices such as battery groups, inverters, motors, etc. is there.
And although a bus bar is not specifically limited about a shape, while it has predetermined thickness, it is a component which exhibits plate shape or a square material shape. For example, the bus bar is a component having a shape as shown in FIG.
言い換えると、本発明に係る接続部品用アルミニウム合金板は、接続部品の中でも、厚さが1.5mm以上、特に、1.8~5.0mmのバスバーに適用するのが好ましく、顕著な効果(耐クリープ性および曲げ加工性の両立という効果)を発揮することとなる。 Here, since aluminum has a lower conductivity than copper, the bus bar made of aluminum alloy has to have a larger cross-sectional area than the bus bar made of copper in order to ensure the conductive performance. When considering the installation area of the component, it is often difficult to increase the width of the component, and the plate thickness increases. In general, when the plate thickness increases, the amount of deformation on the bending surface increases, so the bus bar made of an aluminum alloy has a problem of occurrence of bending cracks during bending processing. The problem that workability must be improved will clearly appear.
In other words, the aluminum alloy plate for connection parts according to the present invention is preferably applied to a bus bar having a thickness of 1.5 mm or more, particularly 1.8 to 5.0 mm, among the connection parts, and has a remarkable effect ( Effect of achieving both creep resistance and bending workability).
[接続部品用アルミニウム合金板の製造方法]
本発明に係る接続部品用アルミニウム合金板の製造方法は、均質化熱処理工程S2と、熱間圧延工程S3と、溶体化熱処理工程S4と、人工時効処理工程S5と、を含むことを特徴とする。
以下、前記各工程を中心に説明する。 Next, the manufacturing method of the aluminum alloy plate for connection parts which concerns on 1st Embodiment is demonstrated, referring FIG.
[Method of manufacturing aluminum alloy plate for connecting parts]
The method for producing an aluminum alloy plate for connecting parts according to the present invention includes a homogenization heat treatment step S2, a hot rolling step S3, a solution heat treatment step S4, and an artificial aging treatment step S5. .
Hereinafter, the respective steps will be mainly described.
鋳造工程S1では、前記の成分組成であるアルミニウム合金を溶解し、DC鍛造法等の公知の鋳造法により鋳造し、アルミニウム合金の固相線温度未満まで冷却して厚さ400~600mm程度の鋳塊とし、必要に応じて面削を行う。 (Casting process)
In the casting step S1, the aluminum alloy having the above component composition is melted, cast by a known casting method such as a DC forging method, and cooled to below the solidus temperature of the aluminum alloy, and cast to a thickness of about 400 to 600 mm. Make a lump and chamfer as necessary.
均質化熱処理工程S2では、鋳造工程S1で鋳造した鋳塊を圧延する前に、所定温度で均質化熱処理(均熱処理)を施す。鋳塊に均質化熱処理を施すことによって、内部応力が除去され、鋳造時に偏析した溶質元素が均質化され、また、鋳造冷却時やそれ以降に析出した金属間化合物が成長する。さらにこの均質化熱処理は、後続の熱間圧延工程S3のための予備加熱を兼ねるものである。
均質化熱処理工程S2における熱処理温度(鋳塊温度)は500~570℃である。熱処理温度が500℃未満では、鋳造時に晶出したSiあるいはMgが未固溶のまま残存し、溶体化熱処理および人工時効処理後に適度な析出物分布を得ることができず、耐力および耐クリープ性が低下する。一方、570℃を超えると、鋳塊の表面で局部的な溶融(バーニング)が生じてしまう。さらに好ましくは、560℃以下である。
均質化熱処理工程S2における熱処理時間(保持時間)は、均質化を完了させるためには1時間以上であればよく、製造効率の点から24時間以内であればよい。 (Homogenization heat treatment process)
In the homogenization heat treatment step S2, homogenization heat treatment (soaking) is performed at a predetermined temperature before rolling the ingot cast in the casting step S1. By subjecting the ingot to homogenization heat treatment, internal stress is removed, solute elements segregated at the time of casting are homogenized, and intermetallic compounds precipitated at the time of casting cooling and thereafter grow. Further, the homogenization heat treatment also serves as preheating for the subsequent hot rolling step S3.
The heat treatment temperature (ingot temperature) in the homogenization heat treatment step S2 is 500 to 570 ° C. When the heat treatment temperature is less than 500 ° C., Si or Mg crystallized at the time of casting remains undissolved, and an appropriate precipitate distribution cannot be obtained after solution heat treatment and artificial aging treatment, yield strength and creep resistance. Decreases. On the other hand, when it exceeds 570 ° C., local melting (burning) occurs on the surface of the ingot. More preferably, it is 560 degrees C or less.
The heat treatment time (holding time) in the homogenization heat treatment step S2 may be 1 hour or longer in order to complete the homogenization, and may be within 24 hours from the viewpoint of production efficiency.
熱間圧延工程S3では、均質化熱処理工程S2から連続して、均質化された鋳塊を熱間圧延する。まず、均質化熱処理工程S2の熱処理完了時の温度を保持して鋳塊を粗圧延して、さらに仕上げ圧延により、所望の板厚の熱間圧延板(ホットコイル)とする。熱間圧延板の板厚は、アルミニウム合金板の最終板厚から逆算して設定すればよい。また、熱間圧延終了温度によりCube方位分布密度を制御することができる。Cube方位分布密度を特に向上させて優れた曲げ加工性を得るためには、熱間圧延終了温度を360℃以下とし、熱間圧延終了時にも再結晶を抑制し、加工組織を残留させることが好ましく、330℃以下とするのが、さらに好ましい。 (Hot rolling process)
In the hot rolling step S3, the homogenized ingot is hot-rolled continuously from the homogenizing heat treatment step S2. First, the temperature at the time of completion of the heat treatment in the homogenization heat treatment step S2 is maintained, the ingot is roughly rolled, and further, hot rolled plate (hot coil) having a desired thickness is obtained by finish rolling. The thickness of the hot rolled sheet may be set by calculating back from the final thickness of the aluminum alloy sheet. Further, the Cube orientation distribution density can be controlled by the hot rolling end temperature. In order to improve the Cube orientation distribution density in particular and obtain excellent bending workability, the hot rolling end temperature should be 360 ° C. or less, and recrystallization is suppressed even at the end of hot rolling, and the processed structure remains. Preferably, the temperature is 330 ° C. or lower.
溶体化熱処理工程S4では、熱間圧延工程S3で製造した熱間圧延板を溶体化熱処理する。ここで、溶体化熱処理工程S4における熱処理温度(鋳塊温度)は500~570℃である。熱処理温度が500℃未満では、未固溶のSiあるいはMgが残存するため、溶体化熱処理および人工時効処理後に適度な析出物分布を得ることができず、所望の耐力および耐クリープ性を得ることができない。一方、570℃を超えると、板表面で局部的な溶融(バーニング)が生じてしまう。さらに好ましくは、520~550℃である。
溶体化熱処理工程S4における前記熱処理温度での保持時間については、60秒以内(0秒でもよい)である。60秒を超えると、その効果が飽和するとともに生産性が低下してしまうからである。
なお、熱間圧延工程S3の後に冷間圧延を施さないとともに、溶体化熱処理工程S4における熱処理温度を上記範囲とすることにより、Cube方位が適切に発達することとなり、板表面におけるCube方位分布密度が所定値以上となる。 (Solution heat treatment process)
In the solution heat treatment step S4, the hot rolled plate manufactured in the hot rolling step S3 is solution heat treated. Here, the heat treatment temperature (ingot temperature) in the solution heat treatment step S4 is 500 to 570 ° C. When the heat treatment temperature is less than 500 ° C., undissolved Si or Mg remains, so that an appropriate precipitate distribution cannot be obtained after solution heat treatment and artificial aging treatment, and desired proof stress and creep resistance can be obtained. I can't. On the other hand, when it exceeds 570 ° C., local melting (burning) occurs on the plate surface. More preferably, it is 520 to 550 ° C.
The holding time at the heat treatment temperature in the solution heat treatment step S4 is within 60 seconds (may be 0 seconds). This is because if the time exceeds 60 seconds, the effect is saturated and the productivity is lowered.
In addition, by not performing cold rolling after the hot rolling step S3 and setting the heat treatment temperature in the solution heat treatment step S4 within the above range, the Cube orientation is appropriately developed, and the Cube orientation distribution density on the plate surface is increased. Becomes a predetermined value or more.
昇温速度および降温速度を前記速度以上とすることにより、Cube方位が適切に発達するのをより確実なものとすることができる。 In the solution heat treatment step S4, the rate of temperature increase from 200 ° C. to the heat treatment temperature is preferably 5 ° C./s or more, and the rate of temperature decrease from the heat treatment temperature to 200 ° C. is 10 ° C./s or more. preferable.
By setting the rate of temperature rise and the rate of temperature fall to the above rate or more, it is possible to ensure that the Cube orientation is properly developed.
人工時効処理工程S5では、溶体化熱処理工程S4で溶体化熱処理を施した熱間圧延板に、所定温度・所定時間で人工時効処理を施す。
人工時効処理工程S5における熱処理温度については、特に限定されないが150~250℃であることが好ましい。150℃未満であると所望の耐力、耐クリープ性を得ることができず、250℃を超えると析出物が粗大化して耐力、耐クリープ性が低下するからである。また、熱処理時間についても、特に限定されないが1~30時間であることが好ましい。1時間未満であると特に量産時を想定した場合にはコイルあるいはシート内での不均一な温度分布を生じ、材料特性が不安定となりやすい。生産性を考慮して30時間を上限とする。 (Artificial aging treatment process)
In the artificial aging treatment step S5, the artificial aging treatment is performed at a predetermined temperature and a predetermined time on the hot-rolled sheet subjected to the solution heat treatment in the solution heat treatment step S4.
The heat treatment temperature in the artificial aging treatment step S5 is not particularly limited, but is preferably 150 to 250 ° C. When the temperature is lower than 150 ° C., desired proof stress and creep resistance cannot be obtained, and when the temperature exceeds 250 ° C., precipitates are coarsened and the proof strength and creep resistance are lowered. Further, the heat treatment time is not particularly limited, but is preferably 1 to 30 hours. If the time is less than 1 hour, particularly when mass production is assumed, a non-uniform temperature distribution occurs in the coil or the sheet, and the material characteristics tend to become unstable. In consideration of productivity, the upper limit is 30 hours.
また、前記各工程において、明示していない条件については、従来公知の条件を用いればよく、前記各工程での処理によって得られる効果を奏する限りにおいて、その条件を適宜変更できることは言うまでもない。 The manufacturing method of the aluminum alloy plate for connecting parts according to the present invention is as described above. However, in carrying out the present invention, other processes may be performed between or before and after the respective steps within a range that does not adversely affect the respective steps. These steps may be included. For example, after the artificial aging treatment step S5, a cutting step for cutting into a predetermined size or a processing step for processing into a predetermined shape (bending, punching, etc.) as shown in FIG. 1 may be included.
In addition, as for conditions that are not clearly shown in the respective steps, it is sufficient to use conventionally known conditions, and it is needless to say that the conditions can be appropriately changed as long as the effects obtained by the processing in the respective steps are exhibited.
本発明に係る接続部品用アルミニウム合金板(以下、適宜、アルミニウム合金板という)は、所定量のSiおよびMgを含有し、残部がAlおよび不可避的不純物からなるアルミニウム合金で構成され、導電率、および板表面のCube方位分布密度が所定値以上、結晶粒径が所定値以下であることを特徴とする。
また、本発明に係る接続部品用アルミニウム合金板は、不可避的不純物のうちFe、Znが所定値未満であることが好ましく、所定値未満のCu、Mn、Cr、Zr、Tiから選択される1種以上を含有することがさらに好ましい。
以下、本発明に係る接続部品用アルミニウム合金板の板表面のCube方位分布密度、および結晶粒径について数値限定した理由を説明する。なお、接続部品用アルミニウム合金板の各合金成分、および導電率は、第1実施形態と同様であるので説明を省略する。 [Aluminum alloy plate for connecting parts]
An aluminum alloy plate for connecting parts according to the present invention (hereinafter, appropriately referred to as an aluminum alloy plate) contains a predetermined amount of Si and Mg, and the balance is made of an aluminum alloy composed of Al and inevitable impurities, and has a conductivity, And the Cube orientation distribution density of the plate surface is not less than a predetermined value and the crystal grain size is not more than a predetermined value.
Further, the aluminum alloy plate for connecting parts according to the present invention preferably has Fe and Zn of unavoidable impurities less than a predetermined value, and is selected from Cu, Mn, Cr, Zr, and Ti that are less than a predetermined value. More preferably, it contains seeds or more.
The reason why the Cube orientation distribution density on the surface of the aluminum alloy plate for connecting parts according to the present invention and the crystal grain size are limited numerically will be described below. In addition, since each alloy component and electrical conductivity of the aluminum alloy plate for connection parts are the same as that of 1st Embodiment, description is abbreviate | omitted.
本発明に係る接続部品用アルミニウム合金板の板表面におけるCube方位分布密度は20以上とする。
板表面におけるCube方位分布密度が20以上であることにより、接続部品に要求される耐クリープ性と曲げ加工性とを両立させることができる。一方、板表面におけるCube方位分布密度が20未満であると、曲げ加工性が低下してしまう。
なお、耐クリープ性および曲げ加工性の向上という効果をより確実なものとするため、Cube方位分布密度は、好ましくは30以上、さらに好ましくは50以上である。 (Cube orientation distribution density: 20 or more)
The Cube orientation distribution density on the plate surface of the aluminum alloy plate for connection parts according to the present invention is 20 or more.
When the Cube orientation distribution density on the surface of the plate is 20 or more, both creep resistance and bending workability required for connecting parts can be achieved. On the other hand, if the Cube orientation distribution density on the surface of the plate is less than 20, bending workability is deteriorated.
The Cube orientation distribution density is preferably 30 or more, and more preferably 50 or more, in order to ensure the effect of improving creep resistance and bending workability.
一方、本発明が規定するように、Cube方位分布密度を20以上とすると、つまり、Cube方位が一定量以上集積すると、隣り合う結晶粒との方位差の小さい小角粒界の割合が大きくなり、変形時の粒界段差を小さく、あるいは生じなくさせる。
また、Cube方位においては、他の方位と比較して均一なすべり変形が可能になることからせん断帯の形成が抑制される。
この結果、曲げ加工の際に割れの起点あるいは伝播経路となる粒界段差や結晶粒内でのせん断帯形成が抑制されるため、Cube方位分布密度を20以上とすることにより、曲げ加工性を改善(向上)できる。
なお、過度にCube方位分布密度を高めようとすると、製造条件が厳しくなり生産性の低下を招くため、Cube方位分布密度は100以下であるのが好ましい。 According to a general manufacturing method, the Cube orientation distribution density is less than 20, which indicates that the crystal orientation of the plate surface is relatively random.
On the other hand, as specified by the present invention, when the Cube orientation distribution density is 20 or more, that is, when the Cube orientation is accumulated more than a certain amount, the proportion of small-angle grain boundaries having a small orientation difference between adjacent crystal grains increases. Reduce or eliminate grain boundary step during deformation.
In addition, in the Cube orientation, since a uniform slip deformation is possible compared to other orientations, formation of a shear band is suppressed.
As a result, since the formation of a shear boundary in the grain boundary step and the crystal grain which becomes the starting point or propagation path of the crack during bending is suppressed, the bending workability can be improved by setting the Cube orientation distribution density to 20 or more. Can improve (improve).
If the Cube orientation distribution density is excessively increased, the manufacturing conditions become severe and the productivity is lowered. Therefore, the Cube orientation distribution density is preferably 100 or less.
本発明に係る接続部品用アルミニウム合金板は、板表面における圧延方向の平均結晶粒径が、150μm以下とする。
圧延方向の平均結晶粒径が150μm以下であると、曲げ加工時における表面の品質を向上させることができる。一方、圧延方向の平均結晶粒径が150μmを超えると曲げ加工時における表面に肌荒れや亀裂が発生する可能性が高くなる。
なお、圧延方向の平均結晶粒径については、曲げ加工時の表面品質の向上という効果をより確実なものとするため、好ましくは100μm以下、さらに好ましくは50μm以下である。また、圧延方向の平均結晶粒径については、過度に小さくしようとすると、製造条件が厳しくなり生産性の低下を招くため、10μm以上が好ましい。 (Average grain size in rolling direction: 150 μm or less)
The aluminum alloy plate for connecting parts according to the present invention has an average crystal grain size in the rolling direction on the plate surface of 150 μm or less.
When the average grain size in the rolling direction is 150 μm or less, the surface quality during bending can be improved. On the other hand, if the average crystal grain size in the rolling direction exceeds 150 μm, the possibility of rough skin and cracks on the surface during bending increases.
The average crystal grain size in the rolling direction is preferably 100 μm or less, and more preferably 50 μm or less, in order to ensure the effect of improving the surface quality during bending. Further, the average crystal grain size in the rolling direction is preferably 10 μm or more because manufacturing conditions become stricter and productivity is lowered when trying to make it excessively small.
[接続部品用アルミニウム合金板の製造方法]
本発明に係る接続部品用アルミニウム合金板の製造方法は、均質化熱処理工程S2と、熱間圧延工程S3と、溶体化熱処理工程S4と、人工時効処理工程S5と、を含むことを特徴とする。
以下、第1実施形態と異なる工程について説明する。他は、第1実施形態と同様であるので説明を省略する。 Next, the manufacturing method of the aluminum alloy plate for connection parts which concerns on 2nd Embodiment is demonstrated, referring FIG.
[Method of manufacturing aluminum alloy plate for connecting parts]
The method for producing an aluminum alloy plate for connecting parts according to the present invention includes a homogenization heat treatment step S2, a hot rolling step S3, a solution heat treatment step S4, and an artificial aging treatment step S5. .
Hereinafter, steps different from those of the first embodiment will be described. Since others are the same as that of 1st Embodiment, description is abbreviate | omitted.
熱間圧延工程S3では、均質化された鋳塊を熱間圧延する。このときの圧延開始温度を350~450℃とする。複数のパスからなる熱間圧延を施すことで、所望の板厚の熱間圧延板(ホットコイル)とする。 (Hot rolling process)
In the hot rolling step S3, the homogenized ingot is hot rolled. The rolling start temperature at this time is set to 350 to 450 ° C. By performing hot rolling consisting of a plurality of passes, a hot rolled plate (hot coil) having a desired thickness is obtained.
ここで、均質化熱処理後に、熱間圧延を開始する350~450℃の温度範囲まで冷却する際の態様は、この温度範囲まで直接冷却し、この温度範囲で熱間圧延を開始しても良い(以下、2段均熱とも言う)。また、350℃以下の温度範囲まで冷却し、その後更に、熱間圧延を開始する350~450℃の温度範囲まで再加熱して、この温度範囲で熱間圧延を開始しても良い(以下、2回均熱とも言う)。 (Mode of cooling after homogenization heat treatment)
Here, after the homogenization heat treatment, the aspect of cooling to a temperature range of 350 to 450 ° C. where the hot rolling is started may be directly cooled to this temperature range and the hot rolling may be started within this temperature range. (Hereinafter also referred to as two-stage soaking). Alternatively, the temperature may be cooled to a temperature range of 350 ° C. or lower, and then reheated to a temperature range of 350 to 450 ° C. where hot rolling is started, and hot rolling may be started in this temperature range (hereinafter, Also called twice soaking).
一方、冷却速度が200℃/hと速くなりすぎると、鋳塊内での温度分布が不均一となり、熱収縮による変形やソリなどの異常が生じる新たな問題が発生する可能性もある。 Although the cooling rate to the hot rolling start temperature range after the homogenization heat treatment is not particularly specified, it is preferably in the range of 20 to 200 ° C./h. When the cooling rate is 20 ° C./h or less, the Mg 2 Si compound becomes coarse. Therefore, if it is attempted to re-solidify the Mg 2 Si compound in order to obtain a desired strength, a solution heat treatment is required for a long time, and productivity is increased. descend.
On the other hand, if the cooling rate is too high at 200 ° C./h, the temperature distribution in the ingot becomes non-uniform, and there is a possibility that a new problem in which an abnormality such as deformation or warping due to heat shrinkage occurs.
鋳塊を冷却する方法としては、例えば均熱炉内または炉外での強制ファン空冷、接触冷却、ミストやスプレーによる冷却がある。 (Cooling means after homogenization heat treatment)
As a method for cooling the ingot, there are, for example, forced fan air cooling in the soaking furnace or outside the furnace, contact cooling, and cooling by mist or spray.
溶体化熱処理工程S4における前記熱処理温度での保持時間については、100秒以内(0秒でもよい)である。100秒を超えると、その効果が飽和するとともに生産性が低下してしまうからである。他は、第1実施形態と同様であるので説明を省略する。 (Solution heat treatment process)
The holding time at the heat treatment temperature in the solution heat treatment step S4 is within 100 seconds (may be 0 seconds). This is because when the time exceeds 100 seconds, the effect is saturated and the productivity is lowered. Since others are the same as that of 1st Embodiment, description is abbreviate | omitted.
昇温速度を前記速度以上とすることにより、Cube方位が適切に発達するのをより確実なものとすることができる。また降温速度を前記速度以上とすることにより、所望の強度を確実に得ることができる。 In the solution heat treatment step S4, the rate of temperature increase from 200 ° C. to the heat treatment temperature is preferably 5 ° C./s or more, and the rate of temperature decrease from the heat treatment temperature to 200 ° C. is 10 ° C./s or more. preferable.
By setting the temperature rising rate to be equal to or higher than the above rate, it is possible to ensure that the Cube orientation is appropriately developed. Moreover, desired intensity | strength can be acquired reliably by making temperature-fall rate more than the said speed | rate.
[供試材の作製]
表1に示す組成のアルミニウム合金(合金1~17)を、溶解し、半連続鋳造にて鋳塊を作製し、面削処理をした。この鋳塊に、表2に示す条件で均質化熱処理を行ったのち、冷却することなく連続して、圧延率99%の熱間圧延を施して(熱間圧延終了温度は表2)、熱間圧延板とした。その後、冷間圧延を施さず(供試材20、21は冷間圧延を施し)、表2に示す条件で溶体化熱処理を行った。そして、溶体化熱処理後、200℃、2時間保持する人工時効処理を施す(供試材20は施さない)ことで、供試材(厚さ2mm)を作製した。 Next, the aluminum alloy plate for connecting parts and the manufacturing method thereof according to the present invention will be specifically described by comparing an example satisfying the requirements of the present invention with a comparative example not satisfying the requirements of the present invention.
[Production of test materials]
Aluminum alloys (
(引張試験)
供試材から引張方向が圧延方向と平行になるようにJIS5号の試験片を切り出した。この試験片を用いて、JIS Z 2241に準拠して引張試験を実施し、引張強さ、耐力(0.2%耐力)、および伸びを測定した。
なお、クロスヘッド速度は5mm/分で、試験片が破断するまで一定の速度で行った。 [Evaluation]
(Tensile test)
A test piece of JIS No. 5 was cut out from the specimen so that the tensile direction was parallel to the rolling direction. Using this test piece, a tensile test was performed in accordance with JIS Z 2241, and tensile strength, yield strength (0.2% yield strength), and elongation were measured.
The crosshead speed was 5 mm / min, and the test was performed at a constant speed until the test piece broke.
作製した供試材の表面を、株式会社リガク製のX線回折装置[型式「リガクRAD-rX」(Ru-200B)]を用いて計測することで、Cube方位分布密度を求めた。当該X線回折装置を用いて不完全極点図によるODF解析を行った。詳細には、schluzの反射法により、{100}面、{111}面の不完全極点図を作成し、Bungeの反復級数展開法(positivity法)を適用してODF解析を実施し、Cube方位分布密度を求めた。 (Cube orientation distribution density)
Cube orientation distribution density was determined by measuring the surface of the prepared specimen using an X-ray diffractometer manufactured by Rigaku Corporation [model “Rigaku RAD-rX” (Ru-200B)]. ODF analysis was performed using an incomplete pole figure using the X-ray diffractometer. In detail, the incomplete pole figure of {100} plane and {111} plane is created by schluz reflection method, ODF analysis is performed by applying Bunge's iterative series expansion method (positivity method), and Cube orientation The distribution density was determined.
導電率の測定は、日本フェルスター株式会社(FOERSTER JAPAN Limited)製の渦流導電率測定装置[型式「シグマテストD2.068」]によって測定した。また、導電率の測定は、供試材表面の互いに間隔を100mm以上開けた任意の5箇所で行った。そして、本発明における導電率は、測定された各導電率を平均化したものとした。 (conductivity)
The conductivity was measured by an eddy current conductivity measuring device [model “Sigma Test D2.068”] manufactured by FOERSTER JAPAN Limited. In addition, the measurement of the conductivity was performed at any five locations on the surface of the test material with a space of 100 mm or more between each other. The electrical conductivity in the present invention is obtained by averaging the measured electrical conductivities.
供試材から試験片長手方向が圧延方向と一致するようにJIS3号(JIS Z 2204)の試験片を切り出した。この試験片を、JIS Z 2248に準拠してVブロック法により曲げ試験を実施し(図3参照)、曲げ加工性を評価した。なお、曲げ試験は、θ(曲げ角度):90°、r(内側曲げ半径):0mm、t(供試材板厚):2mm、という条件で実施した。
曲げ試験後の曲げ部(湾曲部、幅:30mm)の割れの発生状況を観察し、5枚の試験片のうち、全ての試験片において亀裂長さ2mm以上の曲げ割れが確認できなかったものを極めて良好(○)、いずれか1枚以上に割れが生じた場合を良好(△)、全ての試験片に割れが生じてしまった場合を不良(×)と評価した。 (Bending workability)
A test piece of JIS No. 3 (JIS Z 2204) was cut out from the specimen so that the longitudinal direction of the test piece coincided with the rolling direction. The test piece was subjected to a bending test by the V-block method according to JIS Z 2248 (see FIG. 3), and the bending workability was evaluated. The bending test was performed under the conditions of θ (bending angle): 90 °, r (inner bending radius): 0 mm, and t (test material plate thickness): 2 mm.
Observation of the occurrence of cracks in the bent part (curved part, width: 30 mm) after the bending test, and bending cracks with a crack length of 2 mm or more could not be confirmed in all of the five test pieces Was extremely good (◯), the case where any one or more cracks occurred was evaluated as good (Δ), and the case where all the test pieces were cracked was evaluated as defective (×).
残留応力比は、日本電子材料工業会(Japan Electronics and Information Technology Industries Association)標準規格EMAS-3003に記載の片持ち梁方式により測定した。
詳細には、試験片長手方向が圧延方向に対して直角となるように幅10mm、長さ250mmの短冊状の試験片(供試材板厚:2mm)を切り出した。その試験片の一端を剛体試験台に固定した。試験片に、スパン150mm、初期変形量(δ0=10mm)を付与し、その状態のまま120℃で100時間保持した後、応力を除去して試験片の変形量(ε)を測定した。残留応力比は、「残留応力比=(δ0-ε)÷δ0×100」で求めた。この残留応力比の値が75%以上のものを、高温時の持続的な応力により変形する現象(クリープ)に対して耐える性能を有する、つまり、接続部品に要求される耐クリープ性を有すると評価した。 (Residual stress ratio)
The residual stress ratio was measured by the cantilever method described in the Japan Electronics and Information Technology Industries Association standard EMAS-3003.
Specifically, a strip-shaped test piece (sample thickness: 2 mm) having a width of 10 mm and a length of 250 mm was cut out so that the longitudinal direction of the test piece was perpendicular to the rolling direction. One end of the test piece was fixed to a rigid test table. The test piece was given a span of 150 mm and an initial deformation amount (δ0 = 10 mm), held in that state at 120 ° C. for 100 hours, and then the stress was removed to measure the deformation amount (ε) of the test piece. The residual stress ratio was determined by “residual stress ratio = (δ0−ε) ÷ δ0 × 100”. When the residual stress ratio value is 75% or more, it has the ability to withstand the phenomenon (creep) that is deformed by continuous stress at high temperature, that is, it has the creep resistance required for connecting parts. evaluated.
供試材1~9については、本発明の規定する要件を全て満たしていることから、内曲げR=0mmと非常に厳しい曲げ加工条件とした場合にも、曲げ加工性が極めて良好(○)または良好(△)という評価となるとともに、接続部品に要求される耐クリープ性を有するという評価となった。 [Examination of results]
Since the
[供試材の作製]
表1に示す組成のアルミニウム合金(合金1~17)を、溶解し、半連続鋳造にて鋳塊を作製し、面削処理をした。この鋳塊に、表3に示す条件で均質化熱処理を行ったのち、冷却することなく連続して、圧延率99%の熱間圧延を施して(熱間圧延終了温度は表3)、熱間圧延板とした。その後、冷間圧延を施さず(供試材24、25は冷間圧延を施し)、表3に示す条件で溶体化熱処理を行った。そして、溶体化熱処理後、200℃、2時間保持する人工時効処理を施す(供試材24は施さない)ことで、供試材(厚さ2mm)を作製した。
なお、供試材1~4については、熱間圧延を2段均熱で行い、供試材5~18、20、23については、熱間圧延を2回均熱で行った。 Next, the aluminum alloy plate for connecting parts and the manufacturing method thereof according to the present invention will be specifically described by comparing an example satisfying the requirements of the present invention with a comparative example not satisfying the requirements of the present invention. The differences from the first embodiment will be described, and the other points are the same as those of the first embodiment, and the description thereof will be omitted.
[Production of test materials]
Aluminum alloys (
For the
供試材表面を研磨し、この研磨した面を電解液にてエッチングして、光学顕微鏡にて100倍で写真撮影した。この顕微鏡写真で、切片法により圧延方向の結晶粒径を測定した。結晶粒径は5箇所で測定し、平均値を表3に示す。 (Measurement of average crystal grain size)
The surface of the test material was polished, the polished surface was etched with an electrolytic solution, and photographed with an optical microscope at a magnification of 100. With this micrograph, the crystal grain size in the rolling direction was measured by the section method. The crystal grain size was measured at five locations, and the average value is shown in Table 3.
曲げ試験後の曲げ部(湾曲部、幅:30mm)の割れの発生状況を観察し、5枚の試験片のうち、全ての試験片において肌荒れおよび割れとも発生しなかったものを極めて良好(○)、いずれか1枚以上に許容レベルのわずかな肌荒れが生じたものを良好(△)、顕著な肌荒れが発生したもの(×)、または亀裂長さ2mm以上の割れが生じたものを不良(××)と評価した。他は、第1実施形態と同様であるので説明を省略する。 (Bending workability)
Observe the occurrence of cracks in the bent part (curved part, width: 30 mm) after the bending test, and among the five test pieces, all of the test pieces that did not generate rough skin or cracks were very good (○ ), One with at least one acceptable level of rough skin is good (△), marked with rough skin (×), or cracked with a crack length of 2 mm or more is defective ( Xx). Since others are the same as that of 1st Embodiment, description is abbreviate | omitted.
試供材1から19については、第1実施形態と同様であるので説明を省略する。ただし、供試材12~18(合金11~17)は、Fe、Zn、Cu、Mn、Cr、Zr、Tiのうち、いずれか一つが本発明で規定する数値以上となっていたため、曲げ加工性が不良(××)という評価となった。 [Examination of results]
Since the
1a 連結部 1 Connecting parts (bus bar)
1a connecting part
Claims (10)
- Si:0.3~1.5質量%、Mg:0.3~1.0質量%を含有し、残部がAlおよび不可避的不純物からなるアルミニウム合金で構成され、
導電率が45.0%IACS以上であり、結晶方位分布関数解析による板表面のCube方位分布密度が15以上であることを特徴とする接続部品用アルミニウム合金板。 Si: 0.3 to 1.5% by mass, Mg: 0.3 to 1.0% by mass, with the balance being made of an aluminum alloy consisting of Al and inevitable impurities,
An aluminum alloy plate for connecting parts, wherein the conductivity is 45.0% IACS or more, and the Cube orientation distribution density on the plate surface by a crystal orientation distribution function analysis is 15 or more. - 前記不可避的不純物のうち、Fe:0.5質量%未満、Zn:0.5質量%未満であることを特徴とする請求項1に記載の接続部品用アルミニウム合金板。 The aluminum alloy plate for connecting parts according to claim 1, wherein among the inevitable impurities, Fe: less than 0.5 mass%, Zn: less than 0.5 mass%.
- 前記アルミニウム合金が、Cu:1.0質量%未満、Mn:1.0質量%未満、Cr:0.5質量%未満、Zr:0.3質量%未満、Ti:0.1質量%未満、から選択される1種以上をさらに含有することを特徴とする請求項1に記載の接続部品用アルミニウム合金板。 The aluminum alloy is Cu: less than 1.0 mass%, Mn: less than 1.0 mass%, Cr: less than 0.5 mass%, Zr: less than 0.3 mass%, Ti: less than 0.1 mass%, The aluminum alloy plate for connection parts according to claim 1, further comprising at least one selected from the group consisting of:
- 前記アルミニウム合金が、Cu:1.0質量%未満、Mn:1.0質量%未満、Cr:0.5質量%未満、Zr:0.3質量%未満、Ti:0.1質量%未満、から選択される1種以上をさらに含有することを特徴とする請求項2に記載の接続部品用アルミニウム合金板。 The aluminum alloy is Cu: less than 1.0 mass%, Mn: less than 1.0 mass%, Cr: less than 0.5 mass%, Zr: less than 0.3 mass%, Ti: less than 0.1 mass%, The aluminum alloy plate for connection parts according to claim 2, further comprising at least one selected from the group consisting of:
- 前記結晶方位分布関数解析による板表面のCube方位分布密度が20以上、板表面における圧延方向の平均結晶粒径が150μm以下であることを特徴とする請求項1に記載の接続部品用アルミニウム合金板。 The aluminum alloy plate for connecting parts according to claim 1, wherein the Cube orientation distribution density on the plate surface by the crystal orientation distribution function analysis is 20 or more and the average crystal grain size in the rolling direction on the plate surface is 150 µm or less. .
- 前記不可避的不純物のうち、Fe:0.5質量%未満、Zn:0.5質量%未満であることを特徴とする請求項5に記載の接続部品用アルミニウム合金板。 6. The aluminum alloy plate for connecting parts according to claim 5, wherein among the inevitable impurities, Fe: less than 0.5 mass% and Zn: less than 0.5 mass%.
- 前記アルミニウム合金が、Cu:1.0質量%未満、Mn:1.0質量%未満、Cr:0.5質量%未満、Zr:0.3質量%未満、Ti:0.1質量%未満、から選択される1種以上をさらに含有することを特徴とする請求項5に記載の接続部品用アルミニウム合金板。 The aluminum alloy is Cu: less than 1.0 mass%, Mn: less than 1.0 mass%, Cr: less than 0.5 mass%, Zr: less than 0.3 mass%, Ti: less than 0.1 mass%, The aluminum alloy plate for connection parts according to claim 5, further comprising at least one selected from the group consisting of:
- 前記アルミニウム合金が、Cu:1.0質量%未満、Mn:1.0質量%未満、Cr:0.5質量%未満、Zr:0.3質量%未満、Ti:0.1質量%未満、から選択される1種以上をさらに含有することを特徴とする請求項6に記載の接続部品用アルミニウム合金板。 The aluminum alloy is Cu: less than 1.0 mass%, Mn: less than 1.0 mass%, Cr: less than 0.5 mass%, Zr: less than 0.3 mass%, Ti: less than 0.1 mass%, The aluminum alloy plate for connection parts according to claim 6, further comprising at least one selected from the group consisting of:
- 請求項1乃至請求項4のいずれか1項に記載の前記アルミニウム合金からなる鋳塊に500~570℃、1~24時間の均質化熱処理を施す均質化熱処理工程と、
前記均質化熱処理を施した鋳塊に熱間圧延を施して熱間圧延板を製造する熱間圧延工程と、
前記熱間圧延板に冷間圧延を施さずに、500~570℃、60秒以下保持する溶体化熱処理を施す溶体化熱処理工程と、
前記溶体化熱処理を施した熱間圧延板に人工時効処理を施す人工時効処理工程と、
を含むことを特徴とする接続部品用アルミニウム合金板の製造方法。 A homogenization heat treatment step of subjecting the ingot made of the aluminum alloy according to any one of claims 1 to 4 to a homogenization heat treatment at 500 to 570 ° C for 1 to 24 hours,
A hot rolling step of producing a hot rolled sheet by subjecting the ingot subjected to the homogenizing heat treatment to hot rolling;
A solution heat treatment step of subjecting the hot-rolled sheet to a solution heat treatment that is held at 500 to 570 ° C. for 60 seconds or less without cold rolling;
An artificial aging treatment step of performing an artificial aging treatment on the hot-rolled sheet subjected to the solution heat treatment;
The manufacturing method of the aluminum alloy plate for connection components characterized by including this. - 請求項5乃至請求項8のいずれか1項に記載の前記アルミニウム合金からなる鋳塊に500~570℃、1~24時間の均質化熱処理を施す均質化熱処理工程と、
前記均質化熱処理を施した鋳塊に圧延開始温度を350~450℃とした複数のパスからなる圧延を施して熱間圧延板を製造する熱間圧延工程と、
前記熱間圧延板に冷間圧延を施さずに、500~570℃、100秒以下保持する溶体化熱処理を施す溶体化熱処理工程と、
前記溶体化熱処理を施した熱間圧延板に人工時効処理を施す人工時効処理工程と、
を含むことを特徴とする接続部品用アルミニウム合金板の製造方法。 A homogenization heat treatment step of subjecting the ingot made of the aluminum alloy according to any one of claims 5 to 8 to a homogenization heat treatment at 500 to 570 ° C for 1 to 24 hours,
A hot rolling step of producing a hot-rolled sheet by subjecting the ingot subjected to the homogenization heat treatment to rolling comprising a plurality of passes at a rolling start temperature of 350 to 450 ° C .;
A solution heat treatment step of subjecting the hot rolled sheet to a solution heat treatment that is maintained at 500 to 570 ° C. for 100 seconds or less without performing cold rolling;
An artificial aging treatment step of performing an artificial aging treatment on the hot-rolled sheet subjected to the solution heat treatment;
The manufacturing method of the aluminum alloy plate for connection components characterized by including this.
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KR1020147022028A KR101600224B1 (en) | 2012-02-10 | 2013-02-05 | Aluminum alloy sheet for connecting components and manufacturing process therefor |
CN201380008239.7A CN104093868B (en) | 2012-02-10 | 2013-02-05 | Connection member aluminium alloy plate and manufacture method thereof |
EP13746696.7A EP2813592B1 (en) | 2012-02-10 | 2013-02-05 | Aluminum alloy sheet for connecting components and manufacturing process therefor |
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JP2012-277037 | 2012-12-19 | ||
JP2012277036A JP5647665B2 (en) | 2012-02-10 | 2012-12-19 | Aluminum alloy plate for busbar |
JP2012-277036 | 2012-12-19 | ||
JP2012277037A JP5330590B1 (en) | 2012-12-19 | 2012-12-19 | Aluminum alloy plate for bus bar and manufacturing method thereof |
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WO2015156319A1 (en) * | 2014-04-10 | 2015-10-15 | 株式会社Uacj | Bus bar aluminum alloy plate and method for producing same |
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US10538834B2 (en) | 2015-12-18 | 2020-01-21 | Novelis Inc. | High-strength 6XXX aluminum alloys and methods of making the same |
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JP2015203117A (en) * | 2014-04-10 | 2015-11-16 | 株式会社Uacj | Aluminum alloy sheet for bus bar and method for producing the same |
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US10513766B2 (en) | 2015-12-18 | 2019-12-24 | Novelis Inc. | High strength 6XXX aluminum alloys and methods of making the same |
US10538834B2 (en) | 2015-12-18 | 2020-01-21 | Novelis Inc. | High-strength 6XXX aluminum alloys and methods of making the same |
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US12043887B2 (en) | 2015-12-18 | 2024-07-23 | Novelis Inc. | High strength 6xxx aluminum alloys and methods of making the same |
US11932928B2 (en) | 2018-05-15 | 2024-03-19 | Novelis Inc. | High strength 6xxx and 7xxx aluminum alloys and methods of making the same |
CN112267036A (en) * | 2020-09-09 | 2021-01-26 | 宁波悦威液压科技有限公司 | Hydraulic cylinder cover and preparation method thereof |
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Also Published As
Publication number | Publication date |
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CN104093868A (en) | 2014-10-08 |
EP2813592A4 (en) | 2015-10-14 |
EP2813592A1 (en) | 2014-12-17 |
EP2813592B1 (en) | 2016-09-21 |
KR101600224B1 (en) | 2016-03-04 |
KR20140111022A (en) | 2014-09-17 |
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