WO2013029980A1 - Verfahren zum herstellen von feuerfestkeramiken für gasturbinenanlagen - Google Patents
Verfahren zum herstellen von feuerfestkeramiken für gasturbinenanlagen Download PDFInfo
- Publication number
- WO2013029980A1 WO2013029980A1 PCT/EP2012/065846 EP2012065846W WO2013029980A1 WO 2013029980 A1 WO2013029980 A1 WO 2013029980A1 EP 2012065846 W EP2012065846 W EP 2012065846W WO 2013029980 A1 WO2013029980 A1 WO 2013029980A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- refractory
- gas turbine
- casting
- heat shield
- ceramic
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/08—Producing shaped prefabricated articles from the material by vibrating or jolting
- B28B1/087—Producing shaped prefabricated articles from the material by vibrating or jolting by means acting on the mould ; Fixation thereof to the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/14—Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
- B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
- B28B3/02—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
- B28B3/022—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form combined with vibrating or jolting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B11/00—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
- B30B11/02—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses using a ram exerting pressure on the material in a moulding space
- B30B11/022—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses using a ram exerting pressure on the material in a moulding space whereby the material is subjected to vibrations
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/002—Wall structures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/007—Continuous combustion chambers using liquid or gaseous fuel constructed mainly of ceramic components
Definitions
- the invention relates to a process for the production of refractory ceramics for use as a heat shield in the hot gas path of gas turbine plants according to the preamble of claim 1.
- Gas turbine plants essentially consist of a compressor, a burner and an expansion turbine.
- In the compressor intake air is compressed before it is mixed in the nachge ⁇ off and disposed in the compressor plenum burner in a combustion chamber with fuel and burned this mixture.
- the downstream of the combustion chamber for drinks ⁇ cycle turbine then withdraws the resulting Verbrennungsabga ⁇ sen thermal energy and converts it into mechanical energy ⁇ Ener.
- a generator connected to the expansion turbine converts this mechanical energy for generating electricity into electrical energy.
- Such heat shields can be carried out both metallic and ceramic.
- ceramic materials vorzugt loading that are provided ⁇ for example by a casting process ago.
- air pockets can form in the casting compound, which lead to defects (blowholes) in the green body or in the finished component can. These defects are present both in volume and on the surface of the refractory ceramics.
- surface defects are the main criterion for quality control in the context of quality control, as these particularly affect the mechanical properties. Due to the voids, it can lead to a weakening of the mechanical structures and thus to increased cracking in the refractory ceramic.
- the object of the invention is to provide a method to stel ⁇ len, which avoids this disadvantage.
- a heat shield consisting of at least one refractory ceramic manufactured by the method according to the invention is particularly robust and a gas turbine plant equipped with such a heat shield can be safely operated.
- the invention will now be explained by way of example with reference to the refractory ceramic K shown in the figure.
- a non-nä ⁇ forth shown mold cover is used, which dips when placed on the mold shell in the molding compound therein and the casting compound when closing the lid zuneh ⁇ ing up to the mold closure with a previously defined static Pressure applied.
- the filling level of the casting compound represents the essential process parameter, which determines the mass displacement degree and thus the resulting static pressure.
- the placing of the mold cover can already be carried out with vibration.
- For secure mold closure is the
- a clamping device with the high clamping forces can be generated.
- a clamping ⁇ device represent, for example, toggle clamps.
- the geometry of the mold closure already corresponds to the actual geometry of the produced refractory ceramic K, so that a reworking of the component surfaces can be completely eliminated and also the grinding of any existing sprue webs can be significantly reduced.
- the sealed, static pressure mold is then vibrated directionally. With the vibration ⁇ or force introduction direction V, which is determined by the position of the mold relative to the vibration direction, the distribution of surface and volume errors (voids) in the component K can be controlled.
- the force direction V is to be chosen such that it toward the Oberflä ⁇ normals N of the quality-critical component area - acts - here the hot gas side HS of refractory ceramics.
- a virtually void-free surface of the hot gas side HS of the refractory ceramic for gas turbine plants can be achieved.
- the side surfaces SF - similar quality requirements as the hot gas side described above are subjected to HS, the directed Vib ⁇ ration for these areas is to be repeated in the same manner.
- the casting mold is then vibrated one after the other in a direction normal to the quality-critical component surfaces.
- the essential process parameters for the directed vibration make the vibration direction, time, frequency and - amplitude and the stati ⁇ specific pressure generated by the mold closure is Overall, there are therefore by the inventions dung process according to the following advantages:.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/240,179 US20140165573A1 (en) | 2011-08-31 | 2012-08-14 | Process for producing refractory ceramics for gas turbine plants |
EP12748202.4A EP2750844A1 (de) | 2011-08-31 | 2012-08-14 | Verfahren zum herstellen von feuerfestkeramiken für gasturbinenanlagen |
RU2014112056/06A RU2014112056A (ru) | 2011-08-31 | 2012-08-14 | Способ изготовления огнеупорной керамики для газотурбинных установок |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011081847A DE102011081847A1 (de) | 2011-08-31 | 2011-08-31 | Verfahren zum Herstellen von Feuerfestkeramiken für Gasturbinenanlagen |
DE102011081847.2 | 2011-08-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013029980A1 true WO2013029980A1 (de) | 2013-03-07 |
Family
ID=46690500
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2012/065846 WO2013029980A1 (de) | 2011-08-31 | 2012-08-14 | Verfahren zum herstellen von feuerfestkeramiken für gasturbinenanlagen |
Country Status (5)
Country | Link |
---|---|
US (1) | US20140165573A1 (de) |
EP (2) | EP2750844A1 (de) |
DE (1) | DE102011081847A1 (de) |
RU (1) | RU2014112056A (de) |
WO (1) | WO2013029980A1 (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105128139A (zh) * | 2015-09-30 | 2015-12-09 | 佛山市新鹏工业服务有限公司 | 一种压制陶瓷砖用的振动模具 |
CN114484506B (zh) * | 2022-01-27 | 2023-04-18 | 西安鑫垚陶瓷复合材料有限公司 | 用于陶瓷基复合材料单头部火焰筒的定型模具及制备方法 |
Citations (6)
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---|---|---|---|---|
GB380432A (en) * | 1930-04-16 | 1932-09-13 | Elisabeth Lux | Improvements in or relating to moulding for the manufacture of refractory masses |
US1944989A (en) * | 1930-08-11 | 1934-01-30 | Koppers Co Delaware | Method and apparatus for making ceramic shapes |
US3712785A (en) * | 1968-09-04 | 1973-01-23 | Vaw Ver Aluminium Werke Ag | Molding machine |
US4069057A (en) * | 1975-02-15 | 1978-01-17 | Nippon Crucible Co., Ltd. | Monolithic refractory materials |
EP0155086A1 (de) * | 1984-02-15 | 1985-09-18 | Shinagawa Shirorenga Kabushiki Kaisha | Verfahren und Vorrichtung zum Pressen von feuerfesten Steinen |
EP1741531A1 (de) * | 2005-07-07 | 2007-01-10 | Siemens Aktiengesellschaft | Form zur Herstellung eines keramischen Hitzeschildelementes |
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DE563358C (de) * | 1930-01-28 | 1932-11-04 | Heinrich Koppers Akt Ges | Ruettelformmaschine zum Herstellen von Formlingen fuer die Fabrikation feuerfester Steine |
US2959900A (en) * | 1956-10-12 | 1960-11-15 | S G Leoffler | Packaging finely divided materials |
DE1252835B (de) * | 1964-05-21 | 1967-10-26 | Farbwerke Hoechst Aktiengesellschaft vormals Meister Lucius &. Brüning, Frankfurt/M | Verwendung von kondensierten Aluminiumphosphaten zum Härten von Wasserglaskitten |
US3650783A (en) * | 1969-05-13 | 1972-03-21 | Du Pont | Trivalent metal phosphate coated colloidal silica molding powders |
US3547670A (en) * | 1969-05-28 | 1970-12-15 | Fmc Corp | Metal oxide-phosphoric acid coatings |
US3634286A (en) * | 1969-07-09 | 1972-01-11 | Du Pont | Stable homogeneous suspension of silicaphosphate composition and method of preparation |
JPS4927515Y1 (de) * | 1970-03-31 | 1974-07-25 | ||
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JPS5338283B2 (de) * | 1972-05-19 | 1978-10-14 | ||
US3944193A (en) * | 1972-08-26 | 1976-03-16 | Nippon Steel Corporation | Method and apparatus for forming by vibration a refractory lining of a container for a molten metal |
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US4150999A (en) * | 1974-08-12 | 1979-04-24 | Denki Kagaku Kogyo Kabushiki Kaisha | Method for manufacture of ferrosilicon nitride |
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JPS5844052B2 (ja) * | 1979-04-13 | 1983-09-30 | 新日本製鐵株式会社 | 耐火ブロツクの製造方法 |
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EP2168935A1 (de) * | 2008-09-29 | 2010-03-31 | Siemens Aktiengesellschaft | Materialzusammensetzung zur Herstellung eines Feuerfestwerkstoffes sowie ihre Verwendung und Feuerfestformkörper sowie Verfahren zu seiner Herstellung |
US9315426B2 (en) * | 2010-05-20 | 2016-04-19 | Comanche Tecnologies, LLC | Coatings for refractory substrates |
KR101321944B1 (ko) * | 2012-03-30 | 2013-11-04 | 한국과학기술연구원 | 무시멘트 고강도 부정형 내화물 |
-
2011
- 2011-08-31 DE DE102011081847A patent/DE102011081847A1/de not_active Withdrawn
-
2012
- 2012-08-14 RU RU2014112056/06A patent/RU2014112056A/ru not_active Application Discontinuation
- 2012-08-14 US US14/240,179 patent/US20140165573A1/en not_active Abandoned
- 2012-08-14 WO PCT/EP2012/065846 patent/WO2013029980A1/de active Application Filing
- 2012-08-14 EP EP12748202.4A patent/EP2750844A1/de not_active Withdrawn
- 2012-08-14 EP EP16001473.4A patent/EP3120982A3/de not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB380432A (en) * | 1930-04-16 | 1932-09-13 | Elisabeth Lux | Improvements in or relating to moulding for the manufacture of refractory masses |
US1944989A (en) * | 1930-08-11 | 1934-01-30 | Koppers Co Delaware | Method and apparatus for making ceramic shapes |
US3712785A (en) * | 1968-09-04 | 1973-01-23 | Vaw Ver Aluminium Werke Ag | Molding machine |
US4069057A (en) * | 1975-02-15 | 1978-01-17 | Nippon Crucible Co., Ltd. | Monolithic refractory materials |
EP0155086A1 (de) * | 1984-02-15 | 1985-09-18 | Shinagawa Shirorenga Kabushiki Kaisha | Verfahren und Vorrichtung zum Pressen von feuerfesten Steinen |
EP1741531A1 (de) * | 2005-07-07 | 2007-01-10 | Siemens Aktiengesellschaft | Form zur Herstellung eines keramischen Hitzeschildelementes |
Also Published As
Publication number | Publication date |
---|---|
US20140165573A1 (en) | 2014-06-19 |
EP3120982A3 (de) | 2017-03-08 |
EP2750844A1 (de) | 2014-07-09 |
RU2014112056A (ru) | 2015-10-10 |
DE102011081847A1 (de) | 2013-02-28 |
EP3120982A2 (de) | 2017-01-25 |
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