WO2013018993A3 - 화학수소화물 수소발생용 금속폼 촉매 및 그 제조방법 - Google Patents

화학수소화물 수소발생용 금속폼 촉매 및 그 제조방법 Download PDF

Info

Publication number
WO2013018993A3
WO2013018993A3 PCT/KR2012/005267 KR2012005267W WO2013018993A3 WO 2013018993 A3 WO2013018993 A3 WO 2013018993A3 KR 2012005267 W KR2012005267 W KR 2012005267W WO 2013018993 A3 WO2013018993 A3 WO 2013018993A3
Authority
WO
WIPO (PCT)
Prior art keywords
foam
metal
catalyst
nickel
shapes
Prior art date
Application number
PCT/KR2012/005267
Other languages
English (en)
French (fr)
Other versions
WO2013018993A4 (ko
WO2013018993A2 (ko
Inventor
강신왕
김태규
Original Assignee
휴그린파워(주)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 휴그린파워(주) filed Critical 휴그린파워(주)
Publication of WO2013018993A2 publication Critical patent/WO2013018993A2/ko
Publication of WO2013018993A3 publication Critical patent/WO2013018993A3/ko
Publication of WO2013018993A4 publication Critical patent/WO2013018993A4/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 화학수소화물 수소발생용 금속폼 촉매 제조방법에 관한 것으로서, 더욱 상세하게는 금속폼 촉매를 제조하는데 있어서 특정물질을 만들어내기 이전에 선행하는 물질인 촉매 전구체를 별도로 사용하지 않고 니켈 금속폼의 니켈(Ni) 성분을 촉매 전구체로 사용함으로써, 금속폼 촉매 제조과정을 단순화한 화학수소화물 수소발생용 금속폼 촉매 및 그 제조방법에 관한 것이다. 본 발명은 니켈 금속폼을 지지체로 사용하기 위해 니켈 금속폼을 산성 용액에 담가 니켈 금속폼의 표면에 전구체 역할을 하는 니켈을 형성하는 단계, 니켈 금속폼을 알칼리성 붕소수소화물 용액에 담가 니켈 금속폼의 표면에 형성된 니켈을 환원시키는 단계, 니켈 금속폼을 증류수로 세척하여 니켈과 상기 붕소수소화물의 붕소를 결합한 화합물인 니켈-붕소(Ni-B) 금속폼 촉매를 얻는 단계와 니켈-붕소(Ni-B) 금속폼 촉매를 건조 및 하소하는 단계를 포함한다. 또한, 본 발명은 금속폼의 구조가 다수개의 홀들, 개구된 타원 형상, 초승달 형상, 나뭇가지 형상, 아령 형상, 십자형상 또는 아치 형상 중 어느 하나 이상으로 이루어진 세공 구조로 이루어져 촉매와의 접합 면적이 넓고, 촉매가 균일하게 형성되는 것을 특징으로 한다. 나아가, 본 발명은 금속폼 촉매가 위에서 설명한 형상들 중 어느 하나 이상으로 이음 연결되는 것을 특징으로 한다. 따라서 본 발명은 촉매 전구체를 별도로 사용하지 않아 제조 과정이 단순하고 대량 생산이 용이하기 때문에 제조 가격 단가를 낮출 수 있다. 또한, 금속폼 지지체가 넓은 세공구조를 가지기 때문에 촉매를 균일하고 견고하게 담지할 수 있어 반응물이 촉매 표면까지 원활히 이동하고, 가수분해 반응이 진행되는 동안 촉매의 유실이 최소화되는 장점을 가진다.
PCT/KR2012/005267 2011-07-29 2012-07-03 화학수소화물 수소발생용 금속폼 촉매 및 그 제조방법 WO2013018993A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2011-0075707 2011-07-29
KR1020110075707A KR101099875B1 (ko) 2011-07-29 2011-07-29 화학수소화물 수소발생용 금속폼 촉매 및 그 제조방법

Publications (3)

Publication Number Publication Date
WO2013018993A2 WO2013018993A2 (ko) 2013-02-07
WO2013018993A3 true WO2013018993A3 (ko) 2013-04-04
WO2013018993A4 WO2013018993A4 (ko) 2013-06-20

Family

ID=45507118

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2012/005267 WO2013018993A2 (ko) 2011-07-29 2012-07-03 화학수소화물 수소발생용 금속폼 촉매 및 그 제조방법

Country Status (2)

Country Link
KR (1) KR101099875B1 (ko)
WO (1) WO2013018993A2 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101398296B1 (ko) 2013-01-16 2014-05-27 주식회사 알란텀 니켈 메탈폼 플레이트의 제조방법
CN112044459B (zh) * 2020-09-10 2022-02-18 中山大学 类石榴状多孔镍基磷化物纳米结构材料及其制备方法与应用
CN112827492B (zh) * 2021-01-07 2023-11-10 苏州大学 一种用于催化氨硼烷水解的催化剂的制备方法
CN113171776A (zh) * 2021-04-29 2021-07-27 苏州西热节能环保技术有限公司 用于硼氢化钠溶液水解制氢的负载型催化剂、制备方法及应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060095407A (ko) * 2005-02-28 2006-08-31 (주)덕양에너젠 알칼리붕소 수소화물의 수소발생을 위한 페이스트 형태의촉매극 개발
US20090196821A1 (en) * 2008-02-06 2009-08-06 University Of Delaware Plated cobalt-boron catalyst on high surface area templates for hydrogen generation from sodium borohydride

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060095407A (ko) * 2005-02-28 2006-08-31 (주)덕양에너젠 알칼리붕소 수소화물의 수소발생을 위한 페이스트 형태의촉매극 개발
US20090196821A1 (en) * 2008-02-06 2009-08-06 University Of Delaware Plated cobalt-boron catalyst on high surface area templates for hydrogen generation from sodium borohydride

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DAI IL, PARK ET AL.: "Hydrogen Generation from NaBH4 Hydrolysis on Co-Ni-P-B/Ni Foam Catalyst", JOURNAL OF KOREA HYDROGEN AND NEW ENERGY SOCIETY, vol. 21, no. 5, October 2010 (2010-10-01), pages 383 - 389 *

Also Published As

Publication number Publication date
KR101099875B1 (ko) 2011-12-28
WO2013018993A4 (ko) 2013-06-20
WO2013018993A2 (ko) 2013-02-07

Similar Documents

Publication Publication Date Title
Mohsenzadeh et al. DFT study of the adsorption and dissociation of water on Ni (111), Ni (110) and Ni (100) surfaces
WO2013018993A3 (ko) 화학수소화물 수소발생용 금속폼 촉매 및 그 제조방법
JP2019505361A5 (ko)
RU2011130904A (ru) Способы получения 1,1-дихлор-2,3,3,3-тетрафторпропена и 2,3,3,3-тетрафторпропена
EA201270641A1 (ru) Катализатор и способ получения амина
MX2009008662A (es) Metodo para la produccion de 2,3,3,3-tetrafluoropropeno.
Wang et al. Edge-activating CO2-mediated ethylbenzene dehydrogenation by a hierarchical porous BN catalyst
AR051606A1 (es) Metodo mejoradopara alcoxilar los compuestos que contienen hidrogeno activo y los compuestos alcoxilados realizados de los mismos
WO2010097754A3 (en) Process for the preparation of fischer - tropsch catalysts and their use
WO2011062773A3 (en) Zeolite supported cobalt hybrid fischer-tropsch catalyst
WO2010075516A3 (en) Zeolite supported cobalt hybrid fischer-tropsch catalyst
RU2011152487A (ru) Катализаторы для парового реформинга метанола
WO2011002912A3 (en) Process and reactor systems for converting sugars and sugar alcohols
BR112012028770A2 (pt) catalisador de aromatização de metano, e, processos para preparar um catalisador de aromatização de metano e para produzir hidrocarbonetos aromáticos
JP2013111496A5 (ko)
MY181657A (en) Catalyst for hydrogenolysis of polyhydric alcohol and method for producing 1,3-propanediol using catalyst for hydrogenolysis of polyhydric alcohol
WO2009138204A3 (de) Verfahren zur herstellung einer platinkatalysator-vorstufe
WO2009115322A3 (en) Hydrogen production from polyols
CN106423171B (zh) 一种用于催化甲醇合成反应的Ni/Cu/M催化剂及其制备方法
EP2468680A3 (en) Process for the production of hydrogen by catalyzed hydrolysis of a complex hydride over a cobalt boride catalyst, and facility with semi continuous reactor for carrying out the method
MY151103A (en) Process for the preparation of optically active compounds using transfer hydrogenation
RU2016142448A (ru) Усовершенствованный способ изготовления биопроизводного пропиленгликоля
Zhang et al. Selective hydrogenation of nitrobenzene to para-aminophenol on a zirconium-phosphate-supported platinum catalyst
WO2008148988A3 (fr) Procédé pour la fourniture du dihydrogène à partir de silicium hydrogéné
CN104862023B (zh) 一种化学催化法生产生物质燃气的方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12820478

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12820478

Country of ref document: EP

Kind code of ref document: A2