WO2012174949A1 - Dispositif semi-conducteur d'émission de lumière en ultraviolet profond - Google Patents
Dispositif semi-conducteur d'émission de lumière en ultraviolet profond Download PDFInfo
- Publication number
- WO2012174949A1 WO2012174949A1 PCT/CN2012/075070 CN2012075070W WO2012174949A1 WO 2012174949 A1 WO2012174949 A1 WO 2012174949A1 CN 2012075070 W CN2012075070 W CN 2012075070W WO 2012174949 A1 WO2012174949 A1 WO 2012174949A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- light
- light emitting
- semiconductor
- emitting device
- Prior art date
Links
- 239000004065 semiconductor Substances 0.000 title claims abstract description 62
- 239000000758 substrate Substances 0.000 claims abstract description 29
- 230000017525 heat dissipation Effects 0.000 claims abstract description 9
- 230000003287 optical effect Effects 0.000 claims abstract 2
- 239000002184 metal Substances 0.000 claims description 29
- 229910052751 metal Inorganic materials 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 15
- 229910052737 gold Inorganic materials 0.000 claims description 10
- 239000004020 conductor Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 238000005253 cladding Methods 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 93
- 238000000034 method Methods 0.000 description 11
- 239000010931 gold Substances 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 5
- 238000000605 extraction Methods 0.000 description 4
- 239000010944 silver (metal) Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 3
- 239000006023 eutectic alloy Substances 0.000 description 3
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000001312 dry etching Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910017750 AgSn Inorganic materials 0.000 description 1
- 229910001020 Au alloy Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000007771 core particle Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000001126 phototherapy Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910001258 titanium gold Inorganic materials 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/36—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
- H01L33/40—Materials therefor
- H01L33/405—Reflective materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/64—Heat extraction or cooling elements
- H01L33/641—Heat extraction or cooling elements characterized by the materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/005—Processes
- H01L33/0093—Wafer bonding; Removal of the growth substrate
Definitions
- ultraviolet light emitting diodes have multiple layers of different material structures. The choice of material and thickness affects the wavelength of the LED. In order to improve the light extraction efficiency, these multilayer structures are selected with different chemical composition to promote the independent entry of photocarriers into the composite region (generally a quantum well).
- the quantum well is doped with a donor atom to increase the concentration of electrons (N-type layer), and the other side is doped with a acceptor atom to increase the concentration of the void (P-type layer:).
- the ultraviolet light emitting diode includes an electronic contact structure, and different electrode structures can be connected to the power source according to the properties of different devices, and the power source can supply current to the device through the contact structure.
- the present invention provides a deep ultraviolet semiconductor light emitting device.
- the light-emitting layer of the present invention produces light having a wavelength of from 100 nm to 315 nm.
- the metal structure comprises: an ohmic metal contact layer and a bonding layer.
- FIG. 3 is a schematic view showing the path of the light emitting direction of the semiconductor light emitting device of the present invention.
- 4 to 9 are schematic cross-sectional views showing the manufacturing process of the semiconductor light-emitting device of the invention.
- the metal structure 110 is composed of an ohmic metal contact layer 112 and a bonding layer 113.
- the towel bonding layer 113 is composed of a conductive material having a resistivity of 1.0 X 10 -8 to 1.0 X 1 ( ⁇ 4 ⁇ , a melting point of 200 ° C or more;
- the contact layer 112 is composed of a conductive material, the material The resistivity is between 1.0 X 10- 8 and 1.0 X 10" 4 ⁇ . ⁇ , and the material can be selected from Au, Ag, Cu, Al, Pt.
- the light emitting device turns on an external current through the conductive path 202 of the substrate 200, and the light emitting layer 102 emits light under the excitation of current.
- the direct light directly passes through the n-layer type 101, and is directly emitted through the surface light-increasing structure.
- the reflected light passes through the micro-light channel 105 of the p-type semiconductor layer cover layer 104, and is reflected by the metal reflective layer 111 to be emitted to the light-emitting direction.
- the absorption of ultraviolet light by the p-type semiconductor layer cap layer 104 is effectively reduced, and the light extraction efficiency is improved.
- the microchannel 105 is prepared by a dry etching method, and the depth of the microchannel is between 10 and 500 nm; the reflective metal layer 111 is formed on the top surface of the p-type semiconductor cladding layer 104, and the metal is reflective.
- NiAu is preferred as the layer material, and the thickness is between 50 and 1000 nm. It may also be made of an alloy including Al, Ag, Ni, Au, Cu, Pd and Rh, and the ohmic contact is achieved by high temperature annealing in a N 2 atmosphere.
- the A1N single crystal substrate 120 for growing the epitaxial structure is subjected to chemical polishing removal treatment, and the n-type semiconductor contact layer 101 is exposed by chemical polishing thickness control, in the n-type semiconductor
- An n-type ohmic contact metal layer is prepared on the surface of the body contact layer 101, and the material is preferably made of any alloy of Ti, Al, Au, or any alloy such as Ti, Al, Au, Ag, Rh, Co.
- An ultraviolet antireflection layer is prepared on the exposed N-type semiconductor layer; an n-electrode pad is prepared on the n-type ohmic contact metal layer, and the material is preferably TiAu, and the thickness is between 1 and 20 ⁇ m.
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Led Devices (AREA)
Abstract
L'invention concerne un dispositif semi-conducteur d'émission de lumière en ultraviolet profond, comprenant un substrat à dissipation de chaleur ayant un canal électroconducteur; une structure épitaxiale d'émission de lumière, formée d'une couche semi-conductrice de type n, une couche d'émission de lumière, d'une couche semi-conductrice de type n, en séquence, et ayant deux surfaces principales, qui sont une surface de sortie de lumière d'un côté et une surface non sortie de lumière de l'autre côté; une couche de recouvrement semi-conductrice ayant un canal de lumière faible et formée au côté surface non sortie de lumière de la structure épitaxiale d'émission de lumière. Une couche réfléchissante est formée sur la couche de recouvrement semi-conductrice. Le substrat est relié à la couche réfléchissante. Selon la présente invention, la structure épitaxiale d'émission de lumière est reliée au substrat à dissipation de chaleur ayant le canal électroconducteur, résolvant ainsi de façon efficace le problème de dissipation de chaleur de celui-ci. La couche de recouvrement, éloignée du côté surface de sortie de lumière, de la structure épitaxiale d'émission de lumière qui a le canal de faible lumière et, conjointement avec la couche réfléchissante, la plupart de la lumière produite par l'émetteur de lumière est délivrée en sortie par le côté structure support mécanique optique, de façon à empêcher le p-GaN de la couche de recouvremant d'absorber la lumière ultraviolette, augmentant ainsi l'efficacité de sortie de lumière.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/624,937 US8860059B2 (en) | 2011-06-20 | 2012-09-23 | Light emitting devices, systems, and methods of manufacturing |
US14/481,928 US9318657B2 (en) | 2011-06-20 | 2014-09-10 | Light emitting devices, systems, and methods of manufacturing |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110165297.3 | 2011-06-20 | ||
CN2011101652973A CN102222760B (zh) | 2011-06-20 | 2011-06-20 | 一种深紫外半导体发光器件 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2012/075071 Continuation WO2012174950A1 (fr) | 2011-06-20 | 2012-05-04 | Dispositif semi-conducteur électroluminescent émettant dans l'ultraviolet profond et son procédé de fabrication |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/624,937 Continuation US8860059B2 (en) | 2011-06-20 | 2012-09-23 | Light emitting devices, systems, and methods of manufacturing |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012174949A1 true WO2012174949A1 (fr) | 2012-12-27 |
Family
ID=44779250
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2012/075070 WO2012174949A1 (fr) | 2011-06-20 | 2012-05-04 | Dispositif semi-conducteur d'émission de lumière en ultraviolet profond |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN102222760B (fr) |
WO (1) | WO2012174949A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112951957A (zh) * | 2021-03-21 | 2021-06-11 | 南通大学 | 一种耦合量子阱结构深紫外AlGaN基发光二极管 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102222760B (zh) * | 2011-06-20 | 2013-05-15 | 厦门市三安光电科技有限公司 | 一种深紫外半导体发光器件 |
TWI591848B (zh) | 2013-11-28 | 2017-07-11 | 晶元光電股份有限公司 | 發光元件及其製造方法 |
CN104701435A (zh) * | 2013-12-06 | 2015-06-10 | 晶元光电股份有限公司 | 发光元件及其制造方法 |
US10236413B2 (en) | 2015-04-20 | 2019-03-19 | Epistar Corporation | Light-emitting device and manufacturing method thereof |
CN107611233B (zh) * | 2017-08-24 | 2019-05-03 | 西安交通大学 | 基于复合转移衬底的垂直结构深紫外led器件及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW495999B (en) * | 2001-03-26 | 2002-07-21 | Jang Guo Ying | Structure and manufacturing method of micro-channel LED |
US20070085101A1 (en) * | 2005-10-19 | 2007-04-19 | Lg Innotek Co., Ltd. | Light emitting diode package |
CN101521252A (zh) * | 2008-09-26 | 2009-09-02 | 钜亨电子材料元件有限公司 | 具有导电导热基板的发光二极管制造方法及其结构 |
CN101656286A (zh) * | 2008-08-18 | 2010-02-24 | 台湾积体电路制造股份有限公司 | 发光二极管与其制造方法 |
CN101673794A (zh) * | 2008-09-12 | 2010-03-17 | 日立电线株式会社 | 发光元件 |
CN102222760A (zh) * | 2011-06-20 | 2011-10-19 | 厦门市三安光电科技有限公司 | 一种深紫外半导体发光器件 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3152708B2 (ja) * | 1991-12-12 | 2001-04-03 | 株式会社東芝 | 半導体発光素子 |
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2011
- 2011-06-20 CN CN2011101652973A patent/CN102222760B/zh active Active
-
2012
- 2012-05-04 WO PCT/CN2012/075070 patent/WO2012174949A1/fr active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW495999B (en) * | 2001-03-26 | 2002-07-21 | Jang Guo Ying | Structure and manufacturing method of micro-channel LED |
US20070085101A1 (en) * | 2005-10-19 | 2007-04-19 | Lg Innotek Co., Ltd. | Light emitting diode package |
CN101656286A (zh) * | 2008-08-18 | 2010-02-24 | 台湾积体电路制造股份有限公司 | 发光二极管与其制造方法 |
CN101673794A (zh) * | 2008-09-12 | 2010-03-17 | 日立电线株式会社 | 发光元件 |
CN101521252A (zh) * | 2008-09-26 | 2009-09-02 | 钜亨电子材料元件有限公司 | 具有导电导热基板的发光二极管制造方法及其结构 |
CN102222760A (zh) * | 2011-06-20 | 2011-10-19 | 厦门市三安光电科技有限公司 | 一种深紫外半导体发光器件 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112951957A (zh) * | 2021-03-21 | 2021-06-11 | 南通大学 | 一种耦合量子阱结构深紫外AlGaN基发光二极管 |
Also Published As
Publication number | Publication date |
---|---|
CN102222760B (zh) | 2013-05-15 |
CN102222760A (zh) | 2011-10-19 |
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