WO2012148143A3 - 유기술폰산계 화합물, 이를 포함하는 도판트, 및 상기 도판트를 포함하는 전도성 고분자 복합체 - Google Patents

유기술폰산계 화합물, 이를 포함하는 도판트, 및 상기 도판트를 포함하는 전도성 고분자 복합체 Download PDF

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Publication number
WO2012148143A3
WO2012148143A3 PCT/KR2012/003114 KR2012003114W WO2012148143A3 WO 2012148143 A3 WO2012148143 A3 WO 2012148143A3 KR 2012003114 W KR2012003114 W KR 2012003114W WO 2012148143 A3 WO2012148143 A3 WO 2012148143A3
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WO
WIPO (PCT)
Prior art keywords
dopant
conductive polymer
sulfonic acid
polymer complex
organic sulfonic
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PCT/KR2012/003114
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English (en)
French (fr)
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WO2012148143A2 (ko
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이석현
권오필
김태자
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아주대학교산학협력단
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Publication of WO2012148143A2 publication Critical patent/WO2012148143A2/ko
Publication of WO2012148143A3 publication Critical patent/WO2012148143A3/ko
Priority to US14/063,864 priority Critical patent/US20140051815A1/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/128—Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/07—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton
    • C07C309/09—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing etherified hydroxy groups bound to the carbon skeleton
    • C07C309/11—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing etherified hydroxy groups bound to the carbon skeleton with the oxygen atom of at least one of the etherified hydroxy groups further bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20—Conductive material dispersed in non-conductive organic material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3221—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more nitrogen atoms as the only heteroatom, e.g. pyrrole, pyridine or triazole
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3222—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more oxygen atoms as the only heteroatom, e.g. furan
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/34—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
    • C08G2261/342—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3422—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms conjugated, e.g. PPV-type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/026—Wholly aromatic polyamines
    • C08G73/0266—Polyanilines or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

본원은 유기술폰산계 화합물 및 이의 제조방법, 이를 포함하는 도판트 및 상기 도판트를 포함하는 전도성 고분자 복합체에 관한 것으로, 보다 상세하게는 치환기를 갖는 벤젠고리에 술폰산기가 유연한 사슬로 연결된 유도체 화합물을 포함하는 도판트를 제공함으로써, 일반 용매에서의 용해도와 분산성이 증가하고 내환경성도 향상되어 전기 전도도가 증가하고 가공성은 물론 기계적 특성이 현저하게 개선되는 효과를 제공한다.
PCT/KR2012/003114 2011-04-25 2012-04-23 유기술폰산계 화합물, 이를 포함하는 도판트, 및 상기 도판트를 포함하는 전도성 고분자 복합체 WO2012148143A2 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US14/063,864 US20140051815A1 (en) 2011-04-25 2013-10-25 Organic sulfonic acid compound, dopant having same, and conductive polymer complex having the dopant

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020110038650A KR101365014B1 (ko) 2011-04-25 2011-04-25 유기술폰산계 화합물, 이를 포함하는 도판트, 및 상기 도판트를 포함하는 전도성 고분자 복합체
KR10-2011-0038650 2011-04-25

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US14/063,864 Continuation US20140051815A1 (en) 2011-04-25 2013-10-25 Organic sulfonic acid compound, dopant having same, and conductive polymer complex having the dopant

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WO2012148143A2 WO2012148143A2 (ko) 2012-11-01
WO2012148143A3 true WO2012148143A3 (ko) 2013-01-17

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US (1) US20140051815A1 (ko)
KR (1) KR101365014B1 (ko)
WO (1) WO2012148143A2 (ko)

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Publication number Priority date Publication date Assignee Title
KR101436089B1 (ko) * 2012-02-01 2014-08-29 아주대학교산학협력단 전도성 고분자 블랜드 조성물 및 이의 제조 방법
KR101458721B1 (ko) * 2013-11-20 2014-11-05 롯데케미칼 주식회사 고내열성 및 고분산성 폴리올레핀/폴리아닐린 나노파이버 복합재 제조방법
CN110190196B (zh) * 2019-04-23 2020-09-08 河南大学 氢卤酸二次掺杂聚苯胺薄膜及其制备方法和应用
KR102672314B1 (ko) * 2022-02-17 2024-06-05 한국생산기술연구원 벤젠설포네이트기를 갖는 유기전기소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치

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DE1813072A1 (de) * 1968-12-06 1970-06-25 Glanzstoff Ag Verfahren zur Verbesserung der Farbstoffaufnahmefaehigkeit von hochpolymeren faserbildenden Polyestern
US4883880A (en) * 1982-05-03 1989-11-28 Agfa-Gevaert Aktiengessellschaft Process for the preparation of sulfoalkyl quaternary salts and for the production of alkane sultones
JP2005171087A (ja) * 2003-12-11 2005-06-30 Samsung Sdi Co Ltd プロトン伝導性電解質及び燃料電池

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DE1813072A1 (de) * 1968-12-06 1970-06-25 Glanzstoff Ag Verfahren zur Verbesserung der Farbstoffaufnahmefaehigkeit von hochpolymeren faserbildenden Polyestern
US4883880A (en) * 1982-05-03 1989-11-28 Agfa-Gevaert Aktiengessellschaft Process for the preparation of sulfoalkyl quaternary salts and for the production of alkane sultones
JP2005171087A (ja) * 2003-12-11 2005-06-30 Samsung Sdi Co Ltd プロトン伝導性電解質及び燃料電池

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KHALAFI-NEZHAD, A. ET AL.: "Efficient Synthesis of Sodium Aryloxymethanesulfonates Using Microwave Irradiation", J. CHEM. RESEARCH (S), 1999, pages 720 - 721 *
SAITO, KEI ET AL.: "Oxidative Polymerization in Water to Form Sulfoalkoxy Poly(phenylene oxide)s", BULL. CHEM. SOC. JPN., vol. 78, 30 August 2005 (2005-08-30), pages 1699 - 1701 *

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WO2012148143A2 (ko) 2012-11-01
KR101365014B1 (ko) 2014-02-20
KR20120120851A (ko) 2012-11-02
US20140051815A1 (en) 2014-02-20

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