WO2012141523A3 - 당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매, 이의 제조방법 및 이를 이용한 당알코올류의 제조방법 - Google Patents
당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매, 이의 제조방법 및 이를 이용한 당알코올류의 제조방법 Download PDFInfo
- Publication number
- WO2012141523A3 WO2012141523A3 PCT/KR2012/002810 KR2012002810W WO2012141523A3 WO 2012141523 A3 WO2012141523 A3 WO 2012141523A3 KR 2012002810 W KR2012002810 W KR 2012002810W WO 2012141523 A3 WO2012141523 A3 WO 2012141523A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- supported catalyst
- preparing
- sugar alcohols
- catalyst
- sugar
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 12
- 150000005846 sugar alcohols Chemical class 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 6
- 238000009903 catalytic hydrogenation reaction Methods 0.000 title abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- KFKXDXMQVFMFET-UHFFFAOYSA-N boron ruthenium Chemical compound [Ru].[B] KFKXDXMQVFMFET-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 230000002779 inactivation Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 1
- -1 nickel metal oxides Chemical class 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
- C07H3/02—Monosaccharides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/44—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7415—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
본 발명은 당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매, 이의 제조방법 및 이를 이용하여 당알코올류를 제조하는 방법에 관한 것으로, 보다 상세하게는 실리카, 알루미나 및 티타니아 중에서 선택되는 단독 또는 혼합물 담체, 제올라이트 담체, 또는 니켈금속 산화물로 된 피막을 갖는 실리카, 알루미나 및 티타니아 중에서 선택되는 단독 또는 혼합물 담체에 루테늄 또는 루테늄보론을 담지한 촉매, 이의 제조방법 및 비교적 적은 양의 상기 담지촉매를 재생없이 반복사용하여 당류를 수소화함으로써 그에 상응하는 당알코올류를 고수율로 제조하는 방법에 관한 것이다. 본 발명의 담지 촉매를 사용하면 수소화 반응 중 반복 사용하는 동안 촉매성분의 용해나 비활성화가 없이 고순도의 당알코올류를 제조함으로써 부산물 및 폐기물이 거의 발생하지 않고, 복잡한 분리공정 없이 당알코올류를 제조할 수 있다.
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2011-0034706 | 2011-04-14 | ||
KR20110034706 | 2011-04-14 | ||
KR10-2011-0036290 | 2011-04-19 | ||
KR10-2011-0036273 | 2011-04-19 | ||
KR20110036273 | 2011-04-19 | ||
KR20110036290 | 2011-04-19 | ||
KR1020120028318A KR101359446B1 (ko) | 2011-04-19 | 2012-03-20 | 당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매 및 이의 제조방법 |
KR10-2012-0028318 | 2012-03-20 | ||
KR1020120028423A KR101332303B1 (ko) | 2011-04-19 | 2012-03-20 | 당류의 촉매 수소화에 의한 당알코올류의 제조방법 |
KR10-2012-0028423 | 2012-03-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2012141523A2 WO2012141523A2 (ko) | 2012-10-18 |
WO2012141523A3 true WO2012141523A3 (ko) | 2013-03-07 |
Family
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Application Number | Title | Priority Date | Filing Date |
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PCT/KR2012/002810 WO2012141523A2 (ko) | 2011-04-14 | 2012-04-13 | 당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매, 이의 제조방법 및 이를 이용한 당알코올류의 제조방법 |
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WO (1) | WO2012141523A2 (ko) |
Families Citing this family (4)
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PL3416740T3 (pl) | 2016-02-19 | 2021-05-17 | Intercontinental Great Brands Llc | Procesy tworzenia wielu strumieni wartości ze źródeł biomasy |
CN112916011A (zh) * | 2019-12-05 | 2021-06-08 | 中国科学院大连化学物理研究所 | 来源于硅酸镍的木糖加氢生产木糖醇催化剂及其制备和应用 |
CN112206769A (zh) * | 2020-09-21 | 2021-01-12 | 浙江工业大学 | 一种多壁碳纳米管负载钌催化剂及其制备与应用 |
CN113559854B (zh) * | 2021-07-23 | 2022-07-29 | 中国地质大学(武汉) | 一种高比表面积载钌催化剂及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3963788A (en) * | 1974-08-20 | 1976-06-15 | Kruse Walter M | Polyhydric alcohol production using ruthenium zeolite catalyst |
US20040176619A1 (en) * | 2001-06-11 | 2004-09-09 | Dominic Vanoppen | Ruthenium catalysts on a s102-based carrier material for catalytic hydrogenation of saccharides |
KR20050024230A (ko) * | 2003-09-03 | 2005-03-10 | 에스케이 주식회사 | 당류의 수소화에 의한 당알코올류 제조방법 |
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2012
- 2012-04-13 WO PCT/KR2012/002810 patent/WO2012141523A2/ko active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3963788A (en) * | 1974-08-20 | 1976-06-15 | Kruse Walter M | Polyhydric alcohol production using ruthenium zeolite catalyst |
US20040176619A1 (en) * | 2001-06-11 | 2004-09-09 | Dominic Vanoppen | Ruthenium catalysts on a s102-based carrier material for catalytic hydrogenation of saccharides |
KR20050024230A (ko) * | 2003-09-03 | 2005-03-10 | 에스케이 주식회사 | 당류의 수소화에 의한 당알코올류 제조방법 |
Non-Patent Citations (1)
Title |
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HONG SHAN LUO ET AL., CHINESE CHEMICAL LETTERS, vol. 13, no. 12, 31 December 2002 (2002-12-31), pages 1221 - 1224 * |
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Publication number | Publication date |
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WO2012141523A2 (ko) | 2012-10-18 |
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