WO2012134803A3 - Oxiranes fluorés en tant que fluides de travail pour cycle de rankine à fluide organique et procédés d'utilisation associés - Google Patents

Oxiranes fluorés en tant que fluides de travail pour cycle de rankine à fluide organique et procédés d'utilisation associés Download PDF

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Publication number
WO2012134803A3
WO2012134803A3 PCT/US2012/028855 US2012028855W WO2012134803A3 WO 2012134803 A3 WO2012134803 A3 WO 2012134803A3 US 2012028855 W US2012028855 W US 2012028855W WO 2012134803 A3 WO2012134803 A3 WO 2012134803A3
Authority
WO
WIPO (PCT)
Prior art keywords
rankine cycle
methods
same
working fluids
organic rankine
Prior art date
Application number
PCT/US2012/028855
Other languages
English (en)
Other versions
WO2012134803A2 (fr
Inventor
Bamidele O. FAYEMI
Zhongxing Zhang
Michael G. Costello
Michael J. Bulinski
John G. Owens
Phillip E. Tuma
Richard M. Minday
Richard M. Flynn
Original Assignee
3M Innovative Properties Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Company filed Critical 3M Innovative Properties Company
Priority to CN201280015020.5A priority Critical patent/CN103702988A/zh
Priority to JP2014501139A priority patent/JP2014514488A/ja
Priority to US14/007,057 priority patent/US20140311146A1/en
Priority to EP12712012.9A priority patent/EP2689199A2/fr
Priority to KR1020137027729A priority patent/KR20140031226A/ko
Publication of WO2012134803A2 publication Critical patent/WO2012134803A2/fr
Publication of WO2012134803A3 publication Critical patent/WO2012134803A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/48—Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • F01K25/10—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
    • F25B15/02—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/11—Ethers
    • C09K2205/116—Halogenated cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/24—Only one single fluoro component present

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

La présente invention concerne un procédé et un appareil permettant de convertir de l'énergie thermique en énergie mécanique dans un cycle de Rankine. Le procédé et l'appareil font appel à un fluide de travail qui comprend un oxirane fluoré. L'oxirane fluoré peut ne contenir sensiblement aucun atome d'hydrogène lié aux atomes de carbone et peut contenir d'environ 4 à environ 9 atomes de carbone. Le procédé permet de faire fonctionner une turbine et, dans certains modes de réalisation, de produire de l'électricité.
PCT/US2012/028855 2011-03-25 2012-03-13 Oxiranes fluorés en tant que fluides de travail pour cycle de rankine à fluide organique et procédés d'utilisation associés WO2012134803A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201280015020.5A CN103702988A (zh) 2011-03-25 2012-03-13 作为有机兰金循环工作流体的氟化环氧化物和使用其的方法
JP2014501139A JP2014514488A (ja) 2011-03-25 2012-03-13 有機ランキンサイクル作動流体としてのフッ素化オキシラン及びその使用方法
US14/007,057 US20140311146A1 (en) 2011-03-25 2012-03-13 Fluorinated oxiranes as organic rankine cycle working fluids and methods of using same
EP12712012.9A EP2689199A2 (fr) 2011-03-25 2012-03-13 Oxiranes fluorés en tant que fluides de travail pour cycle de rankine à fluide organique et procédés d'utilisation associés
KR1020137027729A KR20140031226A (ko) 2011-03-25 2012-03-13 유기 랜킨 사이클 작동 유체로서의 플루오르화 옥시란 및 이의 사용 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161467452P 2011-03-25 2011-03-25
US61/467,452 2011-03-25

Publications (2)

Publication Number Publication Date
WO2012134803A2 WO2012134803A2 (fr) 2012-10-04
WO2012134803A3 true WO2012134803A3 (fr) 2013-11-28

Family

ID=45929014

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/028855 WO2012134803A2 (fr) 2011-03-25 2012-03-13 Oxiranes fluorés en tant que fluides de travail pour cycle de rankine à fluide organique et procédés d'utilisation associés

Country Status (7)

Country Link
US (1) US20140311146A1 (fr)
EP (1) EP2689199A2 (fr)
JP (1) JP2014514488A (fr)
KR (1) KR20140031226A (fr)
CN (1) CN103702988A (fr)
TW (1) TW201247858A (fr)
WO (1) WO2012134803A2 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103443238A (zh) * 2011-03-25 2013-12-11 3M创新有限公司 作为热传递流体的氟化环氧化物
US20140260252A1 (en) * 2013-03-15 2014-09-18 Honeywell International Inc. Stabilized hfo and hcfo compositions for use in high temperature heat transfer applications
KR102309799B1 (ko) 2013-12-20 2021-10-08 쓰리엠 이노베이티브 프로퍼티즈 컴파니 작동 유체로서의 플루오르화 올레핀 및 이의 사용 방법
CN106152586A (zh) * 2015-03-11 2016-11-23 邱纪林 一种不向环境排放冷凝热的制冷方法
RU2720873C2 (ru) * 2015-11-13 2020-05-13 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ генерирования энергии с помощью комбинированного цикла
CN107126660B (zh) 2016-02-26 2021-02-05 中化蓝天集团有限公司 一种包含含氟酮的组合物
WO2018165623A1 (fr) * 2017-03-10 2018-09-13 The Chemours Company Fc, Llc Utilisations d'époxydes fluorés et de nouveaux mélanges de ceux-ci
EP3614069A1 (fr) * 2018-08-24 2020-02-26 ClimaSolutions GmbH Procédé et dispositif de récupération de l'énergie utile à partir de la chaleur géothermique
AU2019398117B2 (en) 2018-12-11 2021-04-15 Disruption Labs Inc. Compositions for the delivery of therapeutic agents and methods of use and making thereof
CN112177697B (zh) * 2020-09-09 2022-02-22 西安交通大学 基于热分解反应的热防护耦合开式布雷顿发电系统
CN113654034B (zh) * 2021-07-20 2023-08-29 山东联盟化工股份有限公司 一种含酸性不凝气的低品位蒸汽综合回收利用方法

Citations (3)

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WO2006069362A2 (fr) * 2004-12-21 2006-06-29 Honeywell International Inc. Compositions d'iodocarbone stabilisees
WO2008065011A1 (fr) * 2006-11-29 2008-06-05 Solvay Fluor Gmbh Compositions comprenant des composés hydrofluorocarbonés insaturés, et procédés de chauffage et de refroidissement utilisant les compositions
FR2948679A1 (fr) * 2009-07-28 2011-02-04 Arkema France Procede de transfert de chaleur

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US3393515A (en) 1965-09-16 1968-07-23 Israel State Power generating units
US5041588A (en) * 1989-07-03 1991-08-20 Dow Corning Corporation Chemically reactive fluorinated organosilicon compounds and their polymers
US5254774A (en) 1992-12-28 1993-10-19 Minnesota Mining And Manufacturing Company Preparation of hexafluoropropene oligomers
US6660828B2 (en) * 2001-05-14 2003-12-09 Omnova Solutions Inc. Fluorinated short carbon atom side chain and polar group containing polymer, and flow, or leveling, or wetting agents thereof
WO2002092660A2 (fr) * 2001-05-14 2002-11-21 Omnova Soltions Inc Surfactants polymeres derives de monomeres cycliques possedant des groupes lateraux de carbone fluore
US7100380B2 (en) 2004-02-03 2006-09-05 United Technologies Corporation Organic rankine cycle fluid
EP1869293B1 (fr) * 2005-03-29 2013-05-08 UTC Power Corporation Cycles de rankine organiques en cascade utilises pour recuperer la chaleur
US20070172666A1 (en) * 2006-01-24 2007-07-26 Denes Ferencz S RF plasma-enhanced deposition of fluorinated films
JP4302759B2 (ja) * 2007-09-14 2009-07-29 株式会社デンソー 廃熱利用装置
JP5163659B2 (ja) 2008-01-30 2013-03-13 ダイキン工業株式会社 含フッ素エポキシドの製造方法
US8820079B2 (en) 2008-12-05 2014-09-02 Honeywell International Inc. Chloro- and bromo-fluoro olefin compounds useful as organic rankine cycle working fluids

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006069362A2 (fr) * 2004-12-21 2006-06-29 Honeywell International Inc. Compositions d'iodocarbone stabilisees
WO2008065011A1 (fr) * 2006-11-29 2008-06-05 Solvay Fluor Gmbh Compositions comprenant des composés hydrofluorocarbonés insaturés, et procédés de chauffage et de refroidissement utilisant les compositions
FR2948679A1 (fr) * 2009-07-28 2011-02-04 Arkema France Procede de transfert de chaleur

Also Published As

Publication number Publication date
US20140311146A1 (en) 2014-10-23
CN103702988A (zh) 2014-04-02
EP2689199A2 (fr) 2014-01-29
KR20140031226A (ko) 2014-03-12
WO2012134803A2 (fr) 2012-10-04
JP2014514488A (ja) 2014-06-19
TW201247858A (en) 2012-12-01

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