WO2012134078A9 - Procédé de fabrication continue d'hydrate de gaz - Google Patents

Procédé de fabrication continue d'hydrate de gaz Download PDF

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Publication number
WO2012134078A9
WO2012134078A9 PCT/KR2012/001823 KR2012001823W WO2012134078A9 WO 2012134078 A9 WO2012134078 A9 WO 2012134078A9 KR 2012001823 W KR2012001823 W KR 2012001823W WO 2012134078 A9 WO2012134078 A9 WO 2012134078A9
Authority
WO
WIPO (PCT)
Prior art keywords
pipe
gas
hydrate
reactor
gas hydrate
Prior art date
Application number
PCT/KR2012/001823
Other languages
English (en)
Korean (ko)
Other versions
WO2012134078A3 (fr
WO2012134078A2 (fr
Inventor
김철호
김호경
이재익
정태석
허주호
신재웅
Original Assignee
에스티엑스조선해양 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에스티엑스조선해양 주식회사 filed Critical 에스티엑스조선해양 주식회사
Priority to JP2013558784A priority Critical patent/JP2014512943A/ja
Priority to US14/008,452 priority patent/US20140018583A1/en
Publication of WO2012134078A2 publication Critical patent/WO2012134078A2/fr
Publication of WO2012134078A9 publication Critical patent/WO2012134078A9/fr
Publication of WO2012134078A3 publication Critical patent/WO2012134078A3/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/108—Production of gas hydrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1812—Tubular reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30207—Sphere
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30242—Star

Abstract

La présente invention concerne un procédé de fabrication continue d'un hydrate de gaz au moyen de cristaux d'hydrates potentiels. Plus particulièrement, la présente invention concerne un procédé de fabrication continue d'un hydrate de gaz qui comprend: une onzième étape destinée à injecter des cristaux d'hydrates potentiels dans une solution aqueuse contenant un tensioactif dans un réacteur en forme de tuyau; une douzième étape destinée à produire des hydrates de gaz par injection d'un gaz dans le réacteur en forme de tuyau dans lequel les cristaux d'hydrates potentiels ont été injectés lors de la onzième étape; et la treizième étape destinée à maximiser un taux de conversion par transport, selon un mouvement circulaire, des hydrates de gaz produit au cours de la douzième étape dans toute la longueur du réacteur en forme de tuyau. Dans la présente invention, la treizième étape consiste à transporter les hydrates de gaz dans le réacteur en forme de tuyau selon un mouvement circulaire par l'action des tournants sphériques, qui sont reliés entre eux à intervalles prédéfinis et se déplacent selon un mouvement circulaire à l'intérieur du réacteur en forme de tuyau. Du fait de l'abandon du procédé classique qui consiste à déshydrater après production d'une boue d'hydrate de gaz, et de l'adoption de la fabrication d'hydrate de gaz sans procédé de déshydratation, le dispositif de fabrication continue d'un hydrate de gaz de la présente invention résout, dès le début, le problème de nécessité d'un dispositif supplémentaire de lavage d'un tamis ou d'un filtre, ainsi que celui de la difficulté posée pour la production de masse en vue de la commercialisation due à une augmentation dans la dimension de l'équipement nécessaire étant donné que le procédé de déshydratation s'effectue à l'intérieur du réacteur.
PCT/KR2012/001823 2011-03-29 2012-03-14 Procédé de fabrication continue d'hydrate de gaz WO2012134078A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2013558784A JP2014512943A (ja) 2011-03-29 2012-03-14 ガス水和物連続製造方法
US14/008,452 US20140018583A1 (en) 2011-03-29 2012-03-14 Successive gas hydrate manufacturing method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2011-0028089 2011-03-29
KR1020110028089A KR101274310B1 (ko) 2011-03-29 2011-03-29 가스 수화물 연속 제조 방법

Publications (3)

Publication Number Publication Date
WO2012134078A2 WO2012134078A2 (fr) 2012-10-04
WO2012134078A9 true WO2012134078A9 (fr) 2013-01-03
WO2012134078A3 WO2012134078A3 (fr) 2013-02-28

Family

ID=46932050

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2012/001823 WO2012134078A2 (fr) 2011-03-29 2012-03-14 Procédé de fabrication continue d'hydrate de gaz

Country Status (4)

Country Link
US (1) US20140018583A1 (fr)
JP (1) JP2014512943A (fr)
KR (1) KR101274310B1 (fr)
WO (1) WO2012134078A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109628183B (zh) * 2018-12-18 2020-10-30 中国科学院广州能源研究所 一种储存天然气水合物的方法
CN110835566A (zh) * 2019-11-28 2020-02-25 中国石油大学(华东) 一种高含气率甲烷水合物球及其制备方法
KR102600046B1 (ko) * 2020-12-17 2023-11-08 한국과학기술원 열역학적 촉진제가 흡수된 고흡수성 수지를 이용한 신속하고 반복적인 가스 하이드레이트의 형성방법

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4199834A (en) 1978-07-27 1980-04-29 Willis Oil Tool Co. Pig ball transfer unit
US6028234A (en) * 1996-12-17 2000-02-22 Mobil Oil Corporation Process for making gas hydrates
GB9724231D0 (en) * 1997-11-18 1998-01-14 British Gas Plc pipeline cleaning
ATE242050T1 (de) * 1998-08-07 2003-06-15 Akzo Nobel Nv Kontinuierlicher polymerisationsreaktor mit geschlossener schlaufe und polymerisationsverfahren
US6389820B1 (en) * 1999-02-12 2002-05-21 Mississippi State University Surfactant process for promoting gas hydrate formation and application of the same
FR2792997B1 (fr) * 1999-04-29 2001-06-29 Inst Francais Du Petrole Formulation d'additifs pour ameliorer le transport d'effluents petroliers susceptibles de contenir des hydrates et procede utilisant cette formulation
JP2001072615A (ja) 1999-09-01 2001-03-21 Ishikawajima Harima Heavy Ind Co Ltd ハイドレート製造方法及びその製造装置
JP2001240565A (ja) * 2000-02-29 2001-09-04 Natl Inst Of Advanced Industrial Science & Technology Meti ガスハイドレートの効率的製造方法及びガスハイドレート含有多孔質物質
JP2003105361A (ja) * 2001-09-27 2003-04-09 Mitsubishi Rayon Co Ltd ガスハイドレートの生成制御剤
JP4285600B2 (ja) * 2002-08-13 2009-06-24 三井造船プラントエンジニアリング株式会社 ガスハイドレート製造装置
US20040143145A1 (en) * 2003-01-07 2004-07-22 Servio Phillip D. Formation of gas hydrates by fluidized bed granulation
JP4511855B2 (ja) * 2004-03-22 2010-07-28 三井造船株式会社 ガスハイドレートの製造方法とその装置
JP4575206B2 (ja) * 2005-03-30 2010-11-04 中国電力株式会社 ガスハイドレートの製造方法及び製造装置
JP4559898B2 (ja) * 2005-03-31 2010-10-13 独立行政法人産業技術総合研究所 ガスハイドレート製造装置
US7914749B2 (en) * 2005-06-27 2011-03-29 Solid Gas Technologies Clathrate hydrate modular storage, applications and utilization processes
JP2007130524A (ja) * 2005-11-08 2007-05-31 Aquatech:Kk シアン含有廃液処理装置および処理方法
US8334141B2 (en) * 2008-01-03 2012-12-18 Baker Hughes Incorporated Hydrate inhibition test loop
KR101034138B1 (ko) * 2009-01-06 2011-05-13 에스티엑스조선해양 주식회사 잠재적 수화물 결정을 이용한 가스 수화물 제조 방법

Also Published As

Publication number Publication date
JP2014512943A (ja) 2014-05-29
WO2012134078A3 (fr) 2013-02-28
WO2012134078A2 (fr) 2012-10-04
US20140018583A1 (en) 2014-01-16
KR101274310B1 (ko) 2013-06-13
KR20120110309A (ko) 2012-10-10

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