WO2012096774A1 - Method of transferring and electrically joining a high density multilevel thin film to a circuitized and flexible organic substrate and associated devices - Google Patents
Method of transferring and electrically joining a high density multilevel thin film to a circuitized and flexible organic substrate and associated devices Download PDFInfo
- Publication number
- WO2012096774A1 WO2012096774A1 PCT/US2011/066734 US2011066734W WO2012096774A1 WO 2012096774 A1 WO2012096774 A1 WO 2012096774A1 US 2011066734 W US2011066734 W US 2011066734W WO 2012096774 A1 WO2012096774 A1 WO 2012096774A1
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- Prior art keywords
- electrical conductor
- substrate
- lcp
- layer stack
- interconnect layer
- Prior art date
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- 239000000758 substrate Substances 0.000 title claims abstract description 145
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000005304 joining Methods 0.000 title abstract description 8
- 239000010409 thin film Substances 0.000 title description 4
- 229920000106 Liquid crystal polymer Polymers 0.000 claims abstract description 127
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 claims abstract description 123
- 239000004020 conductor Substances 0.000 claims abstract description 115
- 230000008878 coupling Effects 0.000 claims abstract description 7
- 238000010168 coupling process Methods 0.000 claims abstract description 7
- 238000005859 coupling reaction Methods 0.000 claims abstract description 7
- 238000010030 laminating Methods 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 7
- 238000000427 thin-film deposition Methods 0.000 claims description 7
- 239000010410 layer Substances 0.000 description 200
- 238000003475 lamination Methods 0.000 description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000004065 semiconductor Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 3
- 229910000679 solder Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229910018082 Cu3Sn Inorganic materials 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005441 electronic device fabrication Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000001947 vapour-phase growth Methods 0.000 description 1
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- H01L23/498—Leads, i.e. metallisations or lead-frames on insulating substrates, e.g. chip carriers
- H01L23/4985—Flexible insulating substrates
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- Y10T29/49224—Contact or terminal manufacturing with coating
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24917—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
Definitions
- the present invention relates to the field of electronic device fabrication and, more particularly, to methods of forming portions of electronic devices on sacrificial substrates and electrically joining them to circuitized thin flexible organic substrates.
- LCP liquid crystal polymer
- a method of making an electronic device including forming an interconnect layer stack on a sacrificial substrate comprising a plurality of alternating patterned electrically conducting and dielectric layers.
- the method also includes laminating and electrically joining a circuitized liquid crystal polymer (LCP) substrate to the interconnect layer stack on a side thereof opposite the sacrificial substrate, and removing the sacrificial substrate to expose a lowermost patterned electrical conductor layer.
- the method further includes electrically coupling at least one first device to the lowermost patterned electrical conductor layer. This method advantageously allows the formation of an electronic device on an interconnect layer stack that would be difficult to form on a circuitized LCP substrate.
- Laminating the LCP substrate and the interconnect layer stack together may comprise applying heat and pressure to the LCP substrate and the interconnect layer stack.
- the heat and pressure may be applied in an autoclave.
- Forming the interconnect layer stack may be performed by forming the plurality of patterned electrical conductor layers by thin film deposition.
- the LCP substrate may be relatively thin, that is, it may have a thickness of less than 0.0025 inches.
- the at least one first device may include a first integrated circuit (IC) die in a flip chip arrangement.
- At least one electrical conductor via may be formed in the LCP substrate.
- At least one second device may be connected to the LCP substrate, and the at least one second device may be electrically coupled to the uppermost patterned electrical conductor layer using the at least one electrical conductor via.
- the sacrificial substrate may be glass or any atomically smooth material.
- the LCP substrate may have at least one electrical conductor via therein, and the method may also include forming an other interconnect layer stack on an other sacrificial substrate and comprising a plurality of patterned electrical conductor layers, and a dielectric layer between adjacent patterned electrical conductor layers.
- the other interconnect layer stack may be laminated and electrically joined to the LCP substrate on a side thereof opposite the other sacrificial substrate.
- the other sacrificial substrate may be removed to expose a lowermost patterned electrical conductor layer.
- the method may further include electrically coupling at least one other device to the lowermost patterned electrical conductor layer, and electrically coupling the interconnect layer stack and the other interconnect layer stack together.
- the LCP substrate may have an area greater than an area of the sacrificial substrate, and at least one other LCP substrate having an aperture therein aligned with the at least one first device may be laminated to the LCP substrate.
- At least one electrical conductor via may be formed in the at least one additional LCP substrate.
- An other interconnect layer stack may be formed on an other sacrificial substrate and comprising a plurality of patterned electrical conductor layers, and a dielectric layer between adjacent patterned electrical conductor layers.
- the other interconnect layer stack may be laminated and electrically joined to an other LCP substrate on a side thereof opposite the other sacrificial substrate, and the other sacrificial substrate may be removed to expose a lowermost patterned electrical conductor layer.
- the LCP substrate may comprise at least one conductor via in each of a plurality of LCP layers, and which may comprise aligning, laminating, and electrically joining the LCP substrate to the interconnect layer stack. Remaining LCP layers of the plurality thereof may be laminated to the LCP layer that was laminated to the interconnect stack. At least one second device may be electrically coupled to the uppermost patterned electrical conductor layer using the at least one electrical conductor via of each of the plurality of LCP layers.
- a device aspect is directed to an electronic device comprising a liquid crystal polymer (LCP) substrate.
- LCP liquid crystal polymer
- There is a an interconnect layer stack on the LCP substrate comprising a plurality of patterned electrical conductor layers, and a dielectric layer between adjacent patterned electrical conductor layers, the dielectric layer comprising a material different than LCP.
- At least one first device is electrically coupled to a lowermost patterned electrical conductor layer.
- FIG. 1 is a flowchart of a method of making an electronic device according to the present invention.
- FIGS. 2A-2D are sequential schematic cross sectional views of an electronic device of the present invention as formed via the method shown in FIG. 1
- FIG. 3 is a flowchart of another embodiment of a method of making an electronic device according to the present invention.
- FIGS. 4A-4E are sequential schematic cross sectional views of an electronic device of the present invention as formed via the method shown in FIG. 3.
- FIG. 5 is a flowchart of a further embodiment of a method of making an electronic device according to the present invention.
- FIG. 7 is a flowchart of a yet another embodiment of a method of making an electronic device according to the present invention.
- FIGS. 8A-8E are sequential schematic cross sectional views of an electronic device of the present invention as formed via the method shown in FIG. 7.
- the interconnect layer stack 14 may be thinner than 0.0004 inches, for example, with patterned electrical conductor layers 16 as small as (or even smaller than) 0.00004 inches, and dielectric layers 17 as small as (or smaller than) 0.00016 inches.
- the sacrificial substrate 12 is preferably glass, although other materials with a sufficiently smooth surface may also be used.
- the interconnect layer stack 14, and therefore the plurality of patterned electrical conductor layers 16, may be formed by semiconductor thin film deposition processes.
- a liquid crystal polymer (LCP) substrate 18 is laminated to the interconnect layer stack 14 on a side thereof opposite the sacrificial substrate 12 (at Block 53).
- the LCP substrate 18 may have a thickness of less than 0.0025 inches, for example.
- This lamination is performed via the application of heat and pressure to the LCP substrate 18 and the interconnect layer stack 14, such as in an autoclave.
- An autoclave advantageously provides isostatic pressure (i.e., equal pressure from all directions), and helps to keep the LCP from deforming during the lamination process. While the use of an autoclave for lamination is preferred, a press (possibly in an inert atmosphere) may also be used to perform the lamination.
- the lamination is preferably performed at approximately 260°C and lOOpsi.
- LCP is a particularly advantageous material from which to form printed circuit boards for a variety of reasons, including the fact that it has a high tensile strength, providing a high resistance to abrasion and damage. Typically, LCP also has a high mechanical strength at high temperatures, high chemical resistance, inherent flame retardancy, and good weatherability. In addition, LCP is relatively inert. LCP resists stress cracking in the presence of most chemicals at elevated temperatures, including aromatic or halogenated hydrocarbons, strong acids, bases, ketones, and other aggressive industrial substances. Those skilled in the art should understand that there are a variety of LCPs that may be used in the production of electronic devices according to the present invention. The use of LCP as the substrate 18 advantageously allows the lamination without an adhesive layer, thereby reducing the overall thickness of the resulting electronic device 10.
- the sacrificial substrate 12 is removed, thereby exposing a lowermost patterned electrical conductor layer 16 (Block 54).
- This sacrificial substrate 12 removal is performed by dissolution in hydrofluoric acid, mechanical polishing, or a combination of chemical mechanical polishing, for example.
- At least one first device 20 is coupled to the lowermost patterned electrical conductor layer 16 (Block 55), as shown in FIG. 2D.
- This device 20 may be an integrated circuit (IC) die, and may be coupled in a flip chip arrangement, as will be appreciated by those skilled in the art.
- Block 56 indicates the end of the method.
- the method therefore results in an electronic device 10 comprising an LCP substrate 18 with an interconnect layer stack 14 formed thereon.
- the interconnect layer stack 14 comprises a plurality of patterned electrical conductor layers 16, with dielectric layers 17 between adjacent patterned electrical conductor layers.
- Three integrated circuit dies 20 are coupled to the lowermost patterned electrical conductor layer 16 in a flip chip arrangement. It should be appreciated that there may instead be any number of devices 20, and that they need not be integrated circuit dies.
- flowchart 150 of FIG. 3 and FIGS. 4A-4E a further embodiment of the method of making an electronic device 110 according to the present invention is now described. It should be understood that steps in this method are performed similar to those in the flowchart 50 of FIG. 1, and that detailed descriptions of those steps are therefore not necessary.
- an interconnect layer stack 114 is formed on a sacrificial substrate 112 using thin film deposition (at Block 152).
- the interconnect layer stack 114 comprises a plurality of patterned electrical conductor layers 116, and a dielectric layer 117 between adjacent patterned electrical conductor layers. Apertures are defined in the uppermost dielectric layer 117 such that pads of the uppermost patterned electrical conductor layer 116 are exposed by the apertures.
- At least one electrical conductor via 122 is formed in an LCP substrate 118 (Block 153), as shown in FIG. 4B.
- the electrical conductor vias 122 are formed by mechanical or laser drilling the LCP substrate 118, then selectively depositing copper in the resulting holes. Tin is then deposited on a lowermost layer of the electrical conductor vias 122.
- the LCP substrate 118 and the interconnect layer stack 114 may be aligned. Alignment is defined as having the electrical conductive vias 122 centered in the pads of the uppermost patterned electrical conductor layer 116. This alignment may be performed by first using a fixture or guide to roughly align the LCP substrate 118 and the interconnect layer stack 114, and then finely adjusting the alignment under a microscope to reach the final alignment. This advantageously allows a positional accuracy of alignment in the range of 0.0005 inches to 0.001 inches.
- the LCP substrate 118 is then laminated and electrically joined to the interconnect layer stack 114 on a side thereof opposite the sacrificial substrate 112 (Block 154), as shown in FIG. 4C.
- the temperature reaches a suitable level, such as 260°C, which is the melting point of tin, and at which point the copper and tin diffuse and react to form an intermetallic compound, such as Cu 3 Sn.
- This intermetallic compound which is responsible for establishing electrical connection between the LCP substrate and the interconnect layer stack, is thermally stable up to its melting point of at least 600°C.
- the temperature required for successful lamination and intermetallic compound formation fall within the same range.
- an electronic device 110 comprising a LCP substrate 118 with a plurality of conductor vias 122 formed therein.
- An interconnect layer stack 114 is formed on the LCP substrate 118.
- the interconnect layer stack 114 comprises a plurality of patterned electrical conductor layers 116, with dielectric layers 117 between adjacent patterned electrical conductor layers. There is a fused seam between the interconnect layer stack 114 and the LCP substrate 118.
- Three integrated circuit dies 120 are coupled to the lowermost patterned electrical conductor layer 116 in a flip chip arrangement.
- a radiofrequency device 124 is electrically coupled to the uppermost patterned electrical conductor layer 116 and electrically coupled to the integrated circuit dies 120 via the electrical conductor vias 122.
- an interconnect layer stack 214 is formed on a sacrificial substrate 212 using thin film deposition (at Block 252).
- the interconnect layer stack 214 comprises a plurality of patterned electrical conductor layers 216, and a dielectric layer 217 between adjacent patterned electrical conductor layers. Apertures are defined in the uppermost dielectric layer 217 such that pads of the uppermost patterned electrical conductor layer 216 are exposed by the apertures.
- At least one electrical conductor via 222 is formed in a LCP substrate 218 (Block 253), as shown in FIG. 5B.
- the LCP substrate 218 is laminated and electrically joined through an intermetallic bond to the interconnect layer stack 214 on a side thereof opposite the sacrificial substrate 212 (Block 254), as shown in FIG. 6C.
- An other interconnect layer stack 234 is formed on an other sacrificial substrate 232 (Block 255), as shown in FIG. 6C.
- This other interconnect layer stack 234 likewise comprises a plurality of patterned electrical conductor layers 236 and a dielectric layer 237 between adjacent patterned electrical conductor layers.
- This other interconnect layer stack 235 is then laminated and electrically coupled to the LCP substrate 218 on a side thereof opposite the interconnect layer stack 214 (Block 256), thereby electrically coupling the interconnect layer stack and the other interconnect layer stack together.
- Both sacrificial substrates 212, 232 are then removed to expose the lowermost patterned electrical conductor layers 216, 236 of the interconnect layer stack 214 and interconnect layer stack 234, respectively (Block 257), as shown in FIG. 6D.
- At least one first device 220 is electrically coupled to the lowermost patterned electrical conductor layer 216 of the interconnect layer stack 214 (Block 258), as shown in FIG. 6E.
- At least one other device 250 is then electrically coupled to the uppermost patterned electrical conductor layer 236 of the interconnect layer stack 234 (Block 259).
- an electronic device 210 comprising an LCP substrate 218 with a plurality of conductor vias 222 formed therein, as shown in FIG. 6E.
- An interconnect layer stack 214 and an other interconnect layer stack 234 are formed on opposing sides of the LCP substrate 218.
- the interconnect layer stacks 214, 234 each comprise a plurality of patterned electrical conductor layers 216, 236 with dielectric layers 217, 237 between adjacent patterned electrical conductor layers. There is a fused seam between each interconnect layer stack 214, 234 and the LCP substrate 218.
- An integrated circuit die 220 is coupled to the lowermost patterned electrical conductor layer 216 in a flip chip arrangement.
- a pair of integrated circuit dies 250 are electrically coupled to the uppermost patterned electrical conductor layer 236 and electrically coupled to the integrated circuit die 220 via the electrical conductor vias 222.
- an interconnect layer stack 314 is formed on a sacrificial substrate 312 using thin film deposition (at Block 352).
- the interconnect layer stack 314 comprises a plurality of patterned electrical conductor layers 316, and a dielectric layer 317 between adjacent patterned electrical conductor layers. The uppermost patterned electrical conductor layer 316 is exposed.
- the sacrificial substrate 312 is removed to expose a lowermost patterned electrical conductor layer 316 (Block 355). At least one first device 320 is electrically coupled to the lowermost patterned electrical conductor layer 316 (Block 355)
- At least one electrical conductor via 326 is formed in at least one additional LCP substrate 328, illustratively three additional LCP substrates (Block
- the additional LCP substrates 328 have an aperture therein aligned with the device 320 which is formed by laser milling or mechanical punching.
- the additional LCP substrates 328 are laminated to the LCP substrate 318 (Block 358), preferably at 270°C and at 200psi, although other temperatures and pressures may be used.
- An other interconnect layer stack 334 is formed on another sacrificial substrate 350.
- This other interconnect layer stack 334 also comprises a plurality of patterned electrical conductor layers 336 and a dielectric layer 337 between adjacent patterned electrical conductor layers (Block 359).
- the other interconnect layer stack 334 is then laminated to and intermetallically bonded with an other LCP substrate 338 (Block 360), which has had a circuit layer 344 formed thereon.
- the sacrificial substrate is then removed to expose the lowermost patterned electrical conductor layer 336 (Block 361).
- Three additional LCP substrate layers 328 are laminated to the LCP substrate 318 on a same side as the interconnect layer stack 314 and have apertures defined therein that are aligned with the integrated circuit die 320.
- the LCP substrate layers 328 have electrical conductor vias 326 formed therein. There is a fused seam between each of the three additional LCP substrate layers 328, and between the topmost additional LCP substrate layer and the LCP substrate 318.
- an interconnect layer stack 414 is formed on a sacrificial substrate 412 using thin film deposition (at Block 452).
- the interconnect layer stack 414 comprises a plurality of patterned electrical conductor layers 416, and a dielectric layer 417 between adjacent patterned electrical conductor layers. Apertures are defined in the uppermost dielectric layer 417 such that pads of the uppermost patterned electrical conductor layer 416 are exposed by the apertures.
- a layer 418 of the LCP substrate is laminated to the interconnect layer stack 414 on a side thereof opposite the sacrificial substrate 412 (Block 454), as shown in FIG. IOC. This bonding process also serves to intermetallically bond the vias 422 with the patterned electrical conductor layers 416. Before lamination, the LCP substrate 418 and the interconnect layer stack 414 may be aligned. Remaining LCP layers 418 are then laminated to the LCP layer that was laminated to the interconnect layer stack 414 (Block 455).
- the sacrificial substrate 412 is then removed to expose a lowermost patterned electrical conductor layer 416 (Block 456), as shown in FIG. 10D.
- At least one first device 420 illustratively a trio of integrated circuit dies, is electrically coupled to the lowermost patterned electrical conductor layer 416 (Block 457), as shown in FIG. 10E.
- At least one second device 429 illustratively a RF device, is electrically coupled to the conductor vias 422 of the LCP substrate 418, and resides on a side of the LCP substrate 418 opposite the interconnect layer stack 414 (Block 458).
- Block 459 indicates the end of the method.
- an electronic device 410 comprising a LCP substrate 418 with a plurality of conductor vias 422 formed therein.
- the LCP substrate 418 comprises a pair of LCP layers.
- An interconnect layer stack 414 is formed on the LCP substrate 418.
- the interconnect layer stack 414 comprises a plurality of patterned electrical conductor layers 416, with dielectric layers 417 between adjacent patterned electrical conductor layers. There is a fused seam between the interconnect layer stack 414 and the LCP substrate 418, and between the LCP layers.
- a radio frequency device 429 is coupled to a side of the LCP substrate 418 opposite the interconnect layer stack 414, and is electrically coupled to the uppermost patterned electrical conductor layer 416 and the integrated circuit dies 420 via the electrical conductor vias 422. There is also a fused seam between the LCP substrate 418 and the second device 429.
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Abstract
Description
Claims
Priority Applications (3)
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KR1020137018792A KR101494988B1 (en) | 2011-01-14 | 2011-12-22 | Method of transferring and electrically joining a high density multilevel thin film to a circuitized and flexible organic substrate and associated devices |
EP11815828.6A EP2664224A1 (en) | 2011-01-14 | 2011-12-22 | Method of transferring and electrically joining a high density multilevel thin film to a circuitized and flexible organic substrate and associated devices |
CN201180064598.5A CN103314649B (en) | 2011-01-14 | 2011-12-22 | By the method for RF magnetron sputtering extremely circuit and flexible to the transfer of high-density multi-layered thin film and electric interlock and associated devices |
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US13/006,973 | 2011-01-14 | ||
US13/006,973 US8867219B2 (en) | 2011-01-14 | 2011-01-14 | Method of transferring and electrically joining a high density multilevel thin film to a circuitized and flexible organic substrate and associated devices |
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EP (1) | EP2664224A1 (en) |
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2011
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- 2011-12-22 WO PCT/US2011/066734 patent/WO2012096774A1/en active Application Filing
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2014
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TW201230222A (en) | 2012-07-16 |
KR20130115323A (en) | 2013-10-21 |
TWI578417B (en) | 2017-04-11 |
CN103314649B (en) | 2016-06-01 |
US20160322284A1 (en) | 2016-11-03 |
US9691698B2 (en) | 2017-06-27 |
CN103314649A (en) | 2013-09-18 |
US20120182701A1 (en) | 2012-07-19 |
US20140376197A1 (en) | 2014-12-25 |
US9420687B2 (en) | 2016-08-16 |
KR101494988B1 (en) | 2015-02-23 |
EP2664224A1 (en) | 2013-11-20 |
US8867219B2 (en) | 2014-10-21 |
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