WO2012073737A1 - Ultrafine polyamide fiber, and melt-spinning method and device therefor - Google Patents
Ultrafine polyamide fiber, and melt-spinning method and device therefor Download PDFInfo
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- WO2012073737A1 WO2012073737A1 PCT/JP2011/076780 JP2011076780W WO2012073737A1 WO 2012073737 A1 WO2012073737 A1 WO 2012073737A1 JP 2011076780 W JP2011076780 W JP 2011076780W WO 2012073737 A1 WO2012073737 A1 WO 2012073737A1
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- single yarn
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
- D01D5/092—Cooling filaments, threads or the like, leaving the spinnerettes in shafts or chimneys
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/096—Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
- D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
Definitions
- the present invention relates to an ultrafine polyamide fiber having a very small single yarn fineness, and relates to a polyamide ultrafine fiber that can impart excellent softness, smoothness, drape, high water absorption, high density, and high quality after dyeing to a woven or knitted fabric. Is.
- Polyamide fibers are widely used for clothing and industrial materials because they have many excellent properties including mechanical properties.
- false twisted yarn is widely used for woven fabrics, knitted fabrics, etc.
- an ultrafine false twisted yarn having a single yarn fineness of 1.2 dtex or less can provide a very soft texture when made into a fabric, and has better heat retention and water absorption than a normal single yarn fineness false twisted yarn. improves. Therefore, the market demand for ultra fine false twisted yarn is increasing and becoming a standard.
- polyamide ultrafine fiber by using a polyamide ultrafine fiber for false twisting that defines a friction coefficient, elongation, and hot water shrinkage in a fiber made of a polyamide resin having a single yarn fineness of 1.2 dtex or less, a fabric can be obtained.
- a polyamide ultrafine fiber for false twisting that can impart a soft feeling (Patent Document 1).
- each single yarn is brought into contact with a plate arranged inside the plurality of filaments discharged from the discharge holes on the downstream side of the spinneret including the plurality of discharge holes arranged in an annular shape.
- a method of supplying an oil agent uniformly between yarns has been proposed (Patent Document 4).
- Japanese Unexamined Patent Publication No. 2005-320655 Japanese Unexamined Patent Publication No. 2009-84749 Japanese Unexamined Patent Publication No. 2007-126759 Japanese Patent Application Laid-Open No. 2010-126846
- the object of the present invention is to solve the problems of the prior art described above, and to provide a woven or knitted fabric with excellent softness, smoothness, drape, high water absorption, high density, and high quality after dyeing. To provide fiber.
- a polyamide ultrafine fiber characterized in that, in a polyamide fiber having a single yarn fineness of 0.10 dtex or more and 0.50 dtex or less, the average number of fluffs per 12000 m in the longitudinal direction of the filament is 1.0 or less.
- Polyamide ultrafine fiber having a single yarn with a circular cross-sectional shape of the filament, and the orientation parameter of the single yarn surface portion relative to the orientation parameter of the single yarn central portion with respect to the orientation parameter of the single yarn having a circular cross-sectional shape
- the polyamide ultrafine fiber according to any one of the above (1) to (3), wherein the ratio of is 1.10.
- a melt spinning method of polyamide ultrafine fibers having a single yarn fineness of 0.10 dtex or more and 0.50 dtex or less and an average number of fluffs per 12000 m in the longitudinal direction of the filament of 1.0 or less, and the outer periphery of the spinneret A melt-spun yarn spun from a spinneret having discharge holes arranged circumferentially in the part, at the bottom of the center of the spinneret, inside the melt-spun yarn discharged from the discharge holes or
- After supplying oil using an annular oil supply device having an annular slit for discharging an oil agent formed along the outer periphery of the guide the yarn is converged by a converging guide type oil supply device and
- the cooling device is a cooling device that cools the melt spun yarn by blowing cooling air from the inside of the melt spun yarn discharged from the discharge hole.
- the distance (L) from the spinneret surface to the cooling start position of the cooling device is 10 mm ⁇ L ⁇ 70 mm
- the speed of the cooling air blown out at the cooling start position is 15 to 60 m / min.
- Spinneret with discharge holes arranged circumferentially in the part, and melted by blowing cooling air from the inside or outside of the melt-spun yarn discharged from the discharge hole at the bottom of the center part of the spinneret A cooling device for cooling the spun yarn, and further, a disc-shaped guide portion in which the single yarn contacts the outer peripheral portion of the disc at a lower portion in the vertical direction of the cooling device, and an outer periphery of the guide immediately above the guide portion.
- the average number of fluffs per 12000 m in the longitudinal direction of the filament is 1.0 or less.
- Excellent softness, smoothness, drape, high water absorption, high density, and high quality after dyeing can be obtained for woven and knitted fabrics, which cannot be obtained with polyamide ultrafine fibers. .
- excellent anti-penetration properties can also be imparted.
- FIG. 1 is a diagram showing an example of a method for producing polyamide ultrafine fibers according to the present invention.
- FIG. 2 is a diagram showing an example of the shape of a cap hole used for producing the polyamide ultrafine fiber of the present invention.
- FIG. 3 is a view showing another example of the shape of the cap hole used for producing the polyamide ultrafine fiber of the present invention.
- FIG. 4 is a diagram showing an example of an annular oil supply device preferably used when producing the polyamide ultrafine fiber of the present invention.
- FIG. 5 is a diagram showing another example of the method for producing polyamide ultrafine fibers according to the present invention.
- the polyamide used in the polyamide ultrafine fiber of the present invention is a polyamide homopolymer or copolymer, and these polyamides are melt-molded having an amide bond formed from a lactam, an aminocarboxylic acid or a salt of a diamine and a dicarboxylic acid. It is a possible polymer.
- polyamide various polyamides can be used, and are not particularly limited, but polycaproamide (nylon 6) and polyhexamethylene adipamide (nylon 66) are preferable in terms of fiber forming ability and mechanical properties.
- polyamide copolymers such as nylon 6 and nylon 66, those copolymerized with other aminocaproic acid, lactam, etc. at a ratio of 20 mol% or less with respect to the total monomer units can be used.
- the sulfuric acid relative viscosity of the polyamide used in the present invention is preferably 2.0 to 3.5, more preferably 2.4 to 3.0, and still more preferably 2.5 from the viewpoint of yarn production stability. ⁇ 2.7.
- the method for measuring the relative viscosity of sulfuric acid will be described later.
- the second and third components may be copolymerized or mixed in addition to the main components within the range not departing from the object of the present invention.
- polyvinyl pyrrolidone in the polyamide.
- additives such as matting agents, flame retardants, antioxidants, ultraviolet absorbers, infrared absorbers, crystal nucleating agents, fluorescent whitening agents and the like are added to the polyamide used in the present invention as necessary. It may be mixed.
- the method for producing the polyamide ultrafine fiber of the present invention is not particularly limited as long as the polyamide ultrafine fiber of the present invention is obtained.
- the polyamide is melted and discharged from the discharge holes arranged circumferentially on the outer periphery of the spinneret. After cooling, using a cooling device that cools the melt spun yarn uniformly and rapidly by blowing cooling air from the inside or outside of the melt spun yarn discharged from the discharge hole at the lower part of the center of the base,
- a method is preferably used in which an oil agent is applied to each single yarn by an annular oiling device at the lower part of the cooling device in the vertical direction, and then the yarn is converged by a converging guide type oiling device and the second stage of oiling is performed.
- the cooling device is preferably an annular cooling device, more preferably an outer blown annular cooling device that blows cooling air from the inside to the outside of the spun yarn running on the circumference of the circle, from the outside of the spun yarn.
- An internal blowing type annular cooling device that blows cooling air to the inside is preferable.
- an outer blowing type annular cooling device is preferable.
- FIGS. 1 and FIG. 5 are schematic views showing an example of a synthetic fiber manufacturing process according to the present invention
- FIG. 1 is an example using an outer blown annular cooling device 3
- FIG. 5 is an inner blown annular cooling device. This is another example using 18.
- the basic configuration of the manufacturing process of FIGS. 1 and 5 is the same, and description of common reference numerals is omitted.
- an outer-blow-type annular type cooling installed at the lower center of the die for the purpose of reducing fineness unevenness in the longitudinal direction.
- the apparatus 3 blows cooling air from the inside to the outside of the spun yarn, and rapidly cools and solidifies each single yarn at a uniform distance from the die surface.
- an annular oil supply device having a disk-shaped guide portion in which a single yarn contacts with the outer peripheral portion of the disk before focusing the yarn, and an annular slit for discharging the oil agent formed along the outer periphery of the guide immediately above the guide portion.
- the yarn is converged by the converging guide type oiling device 5 and the second-stage oiling is performed.
- an interlace is applied by an interlace nozzle 6 as necessary, passes through a take-up roller 7 and a drawing roller 8, and is taken up by a winder (winding device) 9.
- 10 is a fiber filament
- 11 is a fiber product package.
- it may be stretched by two or more sets of rollers before being wound on the package, in this case, since the interlace provided by stretching may be unraveled, the stretching ratio is lowered, or You may give an interlace again after extending
- the heat retaining zone 2 below the base steam is ejected toward the surface of the base and the heat retaining zone 2 is filled with steam because the polymer around the discharge hole of the base and the oligomer contained in the polymer react with oxygen. It is preferably used since it has an effect of suppressing solidification and so-called base stain.
- the vapor jet pressure is preferably 0.1 to 0.5 kPa. If the jet pressure is too small, the oxygen concentration in the heat retention zone below the base becomes high, and the effect of suppressing the contamination of the base surface becomes small. If the ejection pressure is too high, the discharged yarn will sway, leading to worsening of Wooster spots.
- the outer blown annular cooling device 3 is used, but the inner blown annular cooling device 18 shown in FIG. 5 is used instead of the outer blown annular cooling device 3. You can also.
- the inner-blow-type annular cooling device 18 is installed at the lower part of the center of the base so as to surround the spun yarn, and blows cooling air from the outer side to the inner side of the spun yarn, so that each single yarn is uniform from the base surface. Cool and solidify quickly at a short distance.
- the cooling start point distance that is, the distance (L) from the base surface to the upper end of the cooling air blowing part in the annular cooling device is preferably 10 to 70 mm, more preferably 10 to 60 mm, still more preferably 10 to 50 mm. is there. If the cooling start point distance is too short, the cooling air blown out from the annular cooling device hits the die surface, and the die surface temperature decreases, so that the discharge stability of the thermoplastic polymer deteriorates, and spun yarn and fluff increase. . Also, if the cooling start point distance is too long, the polyamide solidifies before uniform and rapid cooling with cooling air, so that the fiber fineness fluctuation (Worster spots) tends to increase, and when the fabric is made There is a tendency for the quality to decline.
- the wind speed of the cooling air in the annular cooling device is preferably 15 to 60 m / min, more preferably 20 to 55 m / min, and further preferably 25 to 50 m / min. If the cooling air speed is too low, uniform and rapid cooling of the single yarn will be insufficient, and the tension of the cooling yarn will be reduced. Further, since the fluff and spun yarn breakage occur frequently by contacting the guide with insufficient cooling of the polymer, the quality of the fabric is inferior. When the cooling air speed is too high, tension is applied to each single yarn, causing the yarn to vibrate slightly, increasing Worcester spots, and increasing yarn breakage during spinning.
- the temperature of the cooling air in the annular cooling device is preferably 5 to 50 ° C., more preferably 10 to 40 ° C., and further preferably 15 to 35 ° C. If the temperature of the cooling air is too low, the temperature of the heat retention zone below the base decreases and the temperature of the base surface decreases, so the strength of the yarn tends to decrease. If the temperature of the cooling air is too high, the yarn In addition to the fact that the uniform cooling of the yarn becomes difficult and the cooling of the yarn is liable to be insufficient, and Worcester spots increase, the yarn breakage during spinning tends to increase.
- the vertical length of the cooling air blowing part in the annular cooling device is preferably 100 to 500 mm, more preferably 150 to 400 mm, still more preferably 200 to 350 mm. If the cooling air blowing length is too long, the tension applied to the single yarn will increase, causing spun yarn breakage, and if the cooling air blowing length is too short, the oil will be applied with insufficient cooling of the single yarn, reducing fluff. , And spun yarn breakage.
- the single yarn that has passed through the annular cooling device can be processed by the annular oiling device.
- This annular oil supply device is arranged inside a spun yarn that runs on a circular circumference.
- FIG. 4 is a conceptual diagram showing an example of an annular fueling device preferably used in the present invention.
- the annular oil supply device 4 includes an oil discharge slit 12 and a disk-shaped guide 13.
- the annular oil supply device 4 is arranged so that the fiber filament (single yarn) 14 that has passed through the annular cooling device contacts the disk-shaped guide 13.
- An annular oil discharge slit 12 is formed along the outer periphery of the disk-shaped guide 13 so that the oil is supplied directly above the contact point of the disk-shaped guide 13 with the yarn.
- the oil agent is supplied from the oil agent supply pipe 17 to the oil agent reservoir 15.
- the oil agent filled in the oil agent reservoir 15 is discharged from the oil agent discharge slit 12 and comes into contact with each single yarn of the discharge yarn at the contact point with the yarn in the disk-shaped guide 13, and the oil agent is applied to each single yarn. .
- the annular cooling device prevents the single yarn blown by cooling air from shaking, promotes uniform cooling of the single yarn, and reduces Worcester spots. Therefore, it is preferably used. Further, before converging the yarn, the oil agent is discharged from an annular slit for discharging the oil agent formed along the outer periphery of the guide just above the contact point with the yarn in the disk-shaped guide described above.
- the method using the annular oil supply device applied to the yarn is because the yarn with high friction resistance before applying the oil agent comes into contact with the disk-shaped guide, or the single yarn not applied with the oil agent is rubbed together when the yarn is bundled.
- a single yarn that has the effect of suppressing the generation of fuzz and that is not provided with an oil agent by a converging guide type oiling device, and that is not provided with an oil agent in the spinning process. It is preferably used because generation of fluff due to rubbing and generation of dyeing spots at the time of dyeing are suppressed, and fibers having high-order processability are obtained.
- the position where the oil agent is applied by the annular oiling device is preferably 300 to 1000 mm below the base surface, more preferably 350 to 700 mm, and still more preferably 400 to 600 mm.
- the oil agent is applied with insufficient cooling of the single yarn, which causes a decrease in filament strength and fluffing. If the oil supply position is too low, the single yarn discharged from the base surface Longer distance to converge makes yarn swinging more likely, leading to fluffing and worsening of Wooster's spots, and also increases the accompanying airflow effect of single yarn, increasing the running yarn tension. , Causing yarn breakage.
- annular oil supply apparatus is not specifically limited, It is preferable that it is an emulsion type. In the case of an emulsion oil agent, an oil film is likely to be formed on the guide due to surface tension, and the oil agent can be applied uniformly along the circumferential direction of the disk-shaped guide.
- the method of adopting the two-stage oil supply method in which the single yarn is converged by the converging guide type oil supply device 5 after the oil supply by the annular oil supply device 4 and the oil supply is further performed is the double-sided between the single yarns of the fibers and in the longitudinal direction. It can be preferably used because it can achieve the uniform oil agent application.
- the annular oil supply device 4 although the oil agent is uniformly applied between the single yarns, it is difficult to obtain fibers uniformly oiled in the longitudinal direction, and the converged guide type oil supply device that enables the application of the uniform oil agent in the longitudinal direction is possible.
- the focusing guide type oiling device used for the second stage oiling can use a normal oiling guide, and for example, an oiling guide as shown in the above-mentioned Patent Document 3 is preferably used.
- the take-up speed of the yarn in the take-up roller 7 is preferably 3500 to 4500 m / min. If the take-up speed is too low, the orientation of the polyamide in the longitudinal direction becomes unstable, and dyeing spots in the longitudinal direction are likely to occur, and if the take-up speed is too high, the tension applied to the yarn increases. Or cause spun yarn breakage.
- the draw ratio at the drawing roller 8 is preferably 1.0 to 1.3. If the draw ratio is too high, the elongation of the resulting fiber becomes too low, and in addition, the single yarn breaks and fluff is likely to occur.
- the polyamide ultrafine fiber of the present invention is required to have a single yarn fineness of 0.1 dtex or more and 0.5 dtex or less, preferably 0.25 to 0.45 dtex.
- the single yarn fineness is too thick, the yarn has high rigidity, and when it is made into a woven or knitted fabric, it is possible to obtain a woven or knitted fabric excellent in desired softness, smoothness, drape, high water absorption and high density.
- the single yarn fineness is too thin, single yarn breakage is likely to occur when making the fabric, and the fluff and smoothness of the fabric tend to be inferior. There is a tendency for the quality to deteriorate.
- the single yarn fineness is measured by the method described later.
- the average number of fluffs per 12000 m in the longitudinal direction of the filament is required to be 1.0 or less for the polyamide ultrafine fiber of the present invention.
- the average number of fluffs per 12000 m in the longitudinal direction is preferably 0.5 or less, and more preferably 0.
- it is preferable to prevent single yarns having high frictional resistance before applying the oil agent and a method of applying the oil agent before the yarns are bundled by the above-described annular oil supply guide is preferable.
- the average number of fluffs is measured by the method described later.
- the fiber generally shows a variation in the fineness of the yarn in the longitudinal direction, and the thick portion of the yarn tends to be deeply dyed at the time of dyeing, and this appears particularly when the fineness of the single yarn is small.
- the Wooster spots are preferably 1.0% or less. If the Wooster spots are too high, smoothness and a difference in shade at the time of dyeing are greatly developed, and the quality as a product tends to be inferior. Wooster spots are preferably 0.9% or less.
- the method for reducing Wooster spots is not particularly limited, but a method in which the cooling air blowing device is brought close to the base surface and rapidly cooled, or a method in which cooling air is blown in an annular shape from the outer periphery and / or inner periphery is preferably used. It is done. More preferably, after cooling the single yarn uniformly by blowing cooling air in an annular shape from the inner periphery of the yarn, each single yarn is brought into contact with a disk-shaped guide to prevent the yarn from shaking. In the present invention, Wooster spots (thick spots) are measured by the method described later.
- the orientation parameter of the surface portion and the orientation parameter of the central portion of the single yarn are different.
- the difference in the orientation parameter between the surface portion and the central portion results in a difference in the refractive index of light passing through the central portion and the surface portion of the polyamide ultrafine fiber, and an anti-penetration effect can be obtained even with a circular cross section.
- the ratio of the orientation parameter of the single yarn surface part to the orientation parameter of the single yarn central part is preferably 1.10 or more, more preferably 1.15 times or more and 2.00 times or less, further preferably 1.20 or more and 1.80 times or less.
- the orientation parameter of the surface portion is in the above range with respect to the orientation parameter of the center portion of the single yarn, light passing through the cross-sectional direction of the single yarn is irregularly reflected, so that when the fabric is used, a see-through effect is obtained, and The strain in the fiber internal structure does not become too large, and sufficient filament strength can be maintained.
- the orientation parameter is measured by the method described later.
- the polyamide ultrafine fiber having such an orientation parameter is manufactured by selecting the above-mentioned preferable conditions so that the cooling air velocity (cooling air velocity) is not too small so as not to make the cooling start point distance too long. Obtainable.
- the polyamide ultrafine fiber of the present invention has a very fine single yarn fineness and is a fiber in which the structure of the orientation parameter of the surface portion and the orientation parameter of the central portion is different by cooling the melt-spun yarn uniformly and rapidly. By adopting cooling conditions that allow more rapid and uniform cooling, the ratio of the orientation parameter of the single yarn surface portion to the orientation parameter of the single yarn central portion tends to increase.
- the elongation of the polyamide ultrafine fiber is preferably 40 to 70%. If the elongation becomes too low, the tensile resistance of the filament becomes high, and the number of actual twists twisted in the false twisting process decreases, so that it becomes difficult to give sufficient crimp to the obtained processed yarn. In yarn, yarn breakage and fluff are likely to occur, and high-order passability tends to be inferior. On the other hand, if the elongation is too high, the actual number of twists to be twisted becomes excessive, fluffing occurs in the obtained processed yarn, the strength tends to decrease, and the drawn yarn has a high residual elongation. There is a tendency that streaks are likely to appear in the woven or knitted fabric, and the quality tends to be inferior. The measurement of the said elongation shall be based on the below-mentioned method.
- the stress is 1.0 to 2.0 gf / dtex (9.8 ⁇ 10 ⁇ 3 to 19.6 ⁇ 10 ⁇ 3 N / dtex). And more preferably 1.2 to 1.8 gf / dtex (11.8 ⁇ 10 ⁇ 3 to 17.6 ⁇ 10 ⁇ 3 N / dtex). If the stress at 15% elongation is too low, the tension at the time of false twisting becomes too low, and the processed yarn is likely to break or change in the working tension, so that the quality of the processed yarn is lowered and the yield is likely to deteriorate.
- the total fineness of the polyamide ultrafine fiber of the present invention is preferably 15 to 300 dtex, more preferably 15 to 200 dtex. If the total fineness is too small, the breaking strength of the fiber becomes small, the tear strength of the last fabric made into a fabric becomes small, and if the total fineness is too large, it becomes difficult for the dye to penetrate into the fiber at the time of dyeing. Dyeing spots are likely to occur, making it difficult to obtain a high-quality fabric. The total fineness is measured by the method described later.
- the number of filaments of the polyamide ultrafine fiber of the present invention is preferably 30 or more, more preferably 30 to 500 filaments, and still more preferably 50 to 400 filaments. If the number of filaments is less than 30, it will be difficult to obtain the desired softness, drape, high water absorption, and high density, and if the number of filaments is too large, it will be difficult to uniformly interlace and release. Is easily deteriorated, and it is difficult to apply a uniform oil agent between filaments, and the occurrence of fluff due to single yarn breakage is likely to increase.
- the cross-sectional shape of the polyamide ultrafine fiber of the present invention is not particularly limited, and examples thereof include a circular cross section and an irregular cross section.
- a circular cross section is excellent in terms of spinning stability, excellent softness and draping properties.
- the polyamide ultrafine fiber has a circular cross section and the center part and the surface part have the ratio of the preferred orientation parameters, the light passing through the cross-sectional direction of the single yarn is irregularly reflected due to the structural difference in orientation,
- a material having a global cross section or a hollow cross section is preferable in that light passing through the surface of the single yarn is diffusely reflected, and therefore, when a cloth is used, high anti-transparency due to irregular reflection of transmitted light is obtained.
- the trilobal cross section, multi-lobe cross section, and cross-sectional configurations in which multi-lobe cross sections and circular cross-section filaments are mixed high voids are obtained between single yarns when made into fabrics, resulting in high water absorption due to capillary action.
- it is excellent in that it can be imparted with high bulk density, and is also preferably used because it is excellent in imparting the anti-permeability due to irregular reflection of transmitted light.
- the polyamide ultrafine fiber of the present invention thus obtained can give the fabric excellent softness, smoothness, drape, high water absorption, high density, and high quality after dyeing, and in a preferred embodiment it is further opaque. Excellent in properties. Therefore, when using the ultrafine fiber of the present invention as a woven fabric, it is used as an outer material such as a down jacket fabric excellent in heat retention and light weight, and when used as a knitted fabric, it is used for a high-class inner with the above functions, and tights. It can be preferably used for a covering yarn or the like.
- Single yarn fineness (dtex) total fineness (dtex) / number of single yarns
- the area ratio of the cross section of the single yarn in the cross-sectional shape was calculated, and the value obtained by multiplying the total fineness by the area ratio and dividing by the total number of filaments of the same shape.
- Area ratio of section A area of section A / (area of section A + area of section B)
- Area ratio of section B area of section B / (area of section A + area of section B)
- Single yarn fineness (dtex) of cross section A in mixed filaments (total fineness (dtex) ⁇ area ratio of cross section A) / number of filaments of cross section A
- Single yarn fineness (dtex) of cross section B in mixed filaments ( Total fineness (dtex) ⁇ area ratio of section B) / number of filaments in section B
- Average number of fluff The average number of fluff is set using the MALUTI-POINT FRAY COUNTER MFC-200 (sensor part F type) from Toray Engineering Co., Ltd. (current name is tmt machinery) (sensor optical axis center) To U-Guide bottom): 2.0 mm, yarn speed: 600 m / min, measurement time: 20 minutes, feed tension: within the range of 0.25 g / dtex to 0.75 g / dtex The number of measurements was measured 10 times, and the measurement average value was defined as the average number of fluffs (pieces / 12,000 m).
- Orientation parameter ratio Orientation parameters were measured by Raman spectroscopy for a sample (single yarn) having a circular cross-sectional shape, using T-64000 manufactured by Jobin Yvon / Ehime Bussan Co., Ltd., measurement mode: microscopic Raman, objective Lens: ⁇ 100, beam diameter: 1 ⁇ m, light source: Ar + laser / 514.5 nm, laser power: 100 mW, diffraction grating: Single 600, 1800 gr / mm, slit: 100 ⁇ m, detector: CCD 1024 ⁇ 256 manufactured by Jobin Yvon The measurement was performed under the following conditions.
- a measurement sample was embedded in a resin (bisphenol-based epoxy resin, cured for 24 hours) and then sectioned with a microtome at a cutting angle of 5 ° or less from the fiber longitudinal direction.
- the slice sample had a thickness of 1.5 ⁇ m and was cut out so as to pass through the center of the fiber.
- the measurement of the orientation is performed under polarization conditions. When the polarization direction coincides with the longitudinal direction of the fiber, the parallel polarization ( ⁇ ) and when perpendicular, the vertical polarization ( ⁇ ) are obtained, and in the obtained Raman band, the vicinity of 1130 cm ⁇ 1 is obtained.
- orientation parameter (I 1130 / I 1635 ) ⁇ / (I 1130 / I 1635 ) ⁇ It is.
- the orientation parameter of the single yarn surface portion was irradiated with a laser at a point 1 ⁇ m inside from the single yarn surface portion, and the central orientation parameter was calculated at the center portion of the single yarn to calculate the orientation parameter. From this result, the ratio of the orientation parameter of the single yarn surface part to the orientation parameter of the single yarn central part was calculated by the following formula.
- Orientation parameter ratio (Orientation parameter of single yarn surface portion) / (Orientation parameter of single yarn central portion)
- Wooster plaques Wooster plaques were measured using a ZELLWEGER USTER USTER TESTER UT-4, measuring at a yarn speed of 50 m / min, S twist, and a twist number of 8000 rpm for 3 min. Was measured.
- Elongation The elongation is measured using a TENSIRON RPC-1210A manufactured by ORIENTEC, gripped at a gripping interval of 50 cm, stretched at a pulling speed of 50 cm / min, and the tensile length when the yarn breaks is measured three times. The average value was divided by 50 cm and multiplied by 100.
- Example 1 Nylon 66 with a 98% sulfuric acid relative viscosity of 2.63 is melted at 285 ° C., then supplied to a melt spinneret pack, and discharged from a die hole having a 98-hole circular hole. Each single yarn is directed to the spinneret surface.
- a cooling air blowing section having a cooling start point distance of 30 mm and a vertical length of 300 mm is provided downstream of the steam ejection zone.
- a single outer-blow-type annular cooling device is passed through, and 20 ° C.
- an annular oil supply having a disk-shaped guide part in contact with the single yarn at the outer peripheral part of the disk and an annular slit for discharging the oil agent formed along the outer periphery of the guide immediately above the guide part.
- Emulsion oil agent is applied by the device, and further, the second stage of oil is supplied by the convergence guide type oil supply device, the yarn is converged, and the interlace is applied, and it is taken up at 4000 m / min, and the draw ratio is 1.10 times.
- nylon 66 is abbreviated as N66.
- Example 2 Nylon 6 having a 98% sulfuric acid relative viscosity of 2.63 was melted at 255 ° C. and then spun in the same manner as in Example 1 except that it was used in a melt spinneret pack to obtain a nylon 6 fiber of 40 dtex / 98 filament. It was. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1. In the table, nylon 6 is abbreviated as N6.
- Example 3 Spinning was carried out in the same manner as in Example 1 except that a die having a 268 hole circular hole was used, and a nylon 66 fiber of 40 dtex / 268 filament was obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1.
- Example 4 Spinning was carried out in the same manner as in Example 1 except that a base having a circular hole of 82 holes was used to obtain a nylon 66 fiber of 40 dtex / 82 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1.
- Example 5 Example 1 except that the length in the vertical direction of the cooling air blowing portion in the outer-blow-type annular cooling device installed downstream of the steam blow zone below the mouthpiece is 100 mm, and the fueling position by the annular fueling device is 300 mm below the mouthpiece. Spinning was carried out in the same manner as described above to obtain 40 dtex / 98 filament nylon 66 fibers. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1.
- Example 6 Spinning was carried out in the same manner as in Example 1 except that nylon 66 having a 98% sulfuric acid relative viscosity of 2.63 was melted at 275 ° C. to obtain a nylon 66 fiber of 40 dtex / 98 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1.
- Example 7 Spinning was performed in the same manner as in Example 1 except that a die having a 42 hole circular hole was used and the fineness was changed to 17 dtex to obtain a nylon 66 fiber of 17 dtex / 42 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 2.
- Example 8 Spinning was performed in the same manner as in Example 1 except that a die having a circular hole of 680 holes was used and the fineness was changed to 280 dtex to obtain nylon 66 fibers of 280 dtex / 680 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 2.
- Example 9 Spinning was carried out in the same manner as in Example 1 except that a die having a 32-hole circular hole was used and the fineness was changed to 15 dtex to obtain nylon 66 fibers of 15 dtex / 32 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 2.
- Example 10 Nylon 6 with a 98% sulfuric acid relative viscosity of 2.63 is melted at 255 ° C. and then supplied to a melt spinning die pack, and discharged from a die outlet hole having a three-leaf slit shape as shown in FIG. Except for the above, spinning was carried out in the same manner as in Example 1 to obtain a three-leaf section nylon 6 fiber having 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 2.
- Example 11 Spinning was carried out in the same manner as in Example 10 except that a 49-hole die discharge hole having a cross-sectional shape of 49 holes as shown in FIG. 3 and a 98-hole die mixed with the same number of round holes were used, A nylon 6 fiber in which a 6-leaf section and a round section of 40 dtex / 98 filament were mixed was obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 2.
- Example 12 After applying interlace, it was taken out at 3000 m / min, drawn at a draw ratio of 1.50, and then wound up at 4300 m / min under relaxed conditions in the same manner as in Example 1. Spinning was performed to obtain nylon 66 fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
- Example 13 Spinning was carried out in the same manner as in Example 1 except that a single inner-blow-type annular cooling device having a cooling air blowing portion having a vertical length of 300 mm was passed instead of the outer-blow-type annular cooling device. , 40 dtex / 98 filament nylon 66 fiber was obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
- Example 14 Spinning was carried out in the same manner as in Example 1 except that the cooling start point distance was 20 mm to obtain 40 dtex / 98 filament nylon 66 fibers. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
- Example 15 Spinning was carried out in the same manner as in Example 1 except that the cooling start point distance was 40 mm, to obtain nylon 66 fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
- Example 16 Spinning was performed in the same manner as in Example 1 except that the cooling start point distance was set to 10 mm, to obtain nylon 66 fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
- Example 17 Spinning was carried out in the same manner as in Example 1 except that the cooling start point distance was 60 mm to obtain 40 dtex / 98 filament nylon 66 fibers. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
- Example 18 Spinning was carried out in the same manner as in Example 1 except that the air velocity of the cooling air at 20 ° C. blown radially from the outer blown annular cooling device to 27 m / min, and nylon 66 fiber of 40 dtex / 98 filament was obtained. Obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
- Example 19 Spinning was carried out in the same manner as in Example 1 except that the air velocity of the cooling air at 20 ° C. blown radially from the outer blown annular cooling device to 49 m / min, and nylon 66 fibers of 40 dtex / 98 filaments were obtained. Obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
- Example 20 Spinning was performed in the same manner as in Example 1 except that the air speed of the cooling air at 20 ° C. blown radially outward from the outer blown annular cooling device was changed to 17 m / min, and nylon 66 fiber of 40 dtex / 98 filament was obtained. Obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
- Example 21 Spinning was carried out in the same manner as in Example 1 except that the air velocity of the cooling air at 20 ° C. blown radially outward from the outer blown annular cooling device was set to 58 m / min, and nylon 66 fiber of 40 dtex / 98 filament was obtained. Obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
- Comparative Example 1 Spinning was carried out in the same manner as in Example 1 except that the material was discharged from a die hole having a 160-hole circular hole and the fineness was set to 15 dtex to obtain nylon 66 fiber of 15 dtex / 160 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
- Comparative Example 2 Spinning was carried out in the same manner as in Example 1 except that the fineness was 56 dtex to obtain nylon 66 fiber of 56 dtex / 98 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
- Comparative Example 3 At a position 500 mm from the base surface of the lower part in the vertical direction of the outer blow type annular cooling device, a disk-shaped guide having no annular slit for discharging the oil is used, and the single thread is brought into contact with the disk-shaped guide without supplying the oil. Except for the above, spinning was performed in the same manner as in Example 1 to obtain a nylon 66 fiber of 40 dtex / 98 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
- Comparative Example 4 Spinning was performed in the same manner as in Example 1 except that the polyethylene terephthalate resin was melted at 290 ° C. and then used in a melt spinneret pack to obtain polyethylene terephthalate fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
- Comparative Example 5 Spinning was performed in the same manner as in Example 1 except that the cooling device was a one-way type uniflow chimney, the yarn was converged by an oil supply guide, and oil was supplied to obtain nylon 66 fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
- Comparative Example 6 Spinning is carried out in the same manner as in Example 1 except that the second stage oiling is performed and the yarn is converged by the converging guide after the second lubrication, and the nylon 66 of 40 dtex / 98 filament is used. Fiber was obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
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Abstract
Description
(1)単糸繊度が0.10dtex以上0.50dtex以下のポリアミド繊維において、フィラメントの長手方向12000mあたりの平均毛羽数が1.0個以下であることを特徴とするポリアミド極細繊維。
(2)フィラメントの長手方向のウースター斑が1.0%以下であることを特徴とする前記(1)に記載のポリアミド極細繊維。
(3)総繊度が15~300dtex、フィラメント数が30以上であることを特徴とする前記(1)または(2)に記載のポリアミド極細繊維。
(4)フィラメントの断面形状が異形断面であることを特徴とする前記(1)~(3)のいずれかに記載のポリアミド極細繊維。
(5)ポリアミド極細繊維において、フィラメントの断面形状が円形である単糸を有し、かつ円形断面形状を有する単糸の配向パラメーターについて、単糸中央部の配向パラメーターに対する単糸表面部の配向パラメーターの比が、1.10以上であることを特徴とする、前記(1)~(3)のいずれかに記載のポリアミド極細繊維。
(6)単糸繊度が0.10dtex以上0.50dtex以下であり、フィラメントの長手方向12000mあたりの平均毛羽数が1.0個以下であるポリアミド極細繊維の溶融紡糸方法であって、紡糸口金外周部に円周状に配された吐出孔を有する紡糸口金から紡出した溶融紡糸糸条を、前記紡糸口金の中心部の下部にあって、吐出孔から吐出された溶融紡糸糸条の内側または外側から冷却風を吹き付けて溶融紡糸糸条を冷却する冷却装置を用いて冷却し、さらに該冷却装置の鉛直方向下部に円盤の外周部で単糸が接触する円盤形のガイド部と、ガイド部の直上にガイドの外周にそって形成した油剤吐出用の環状スリットを有する環状給油装置を用いて給油を行った後、集束ガイド型給油装置にて糸条を集束させるとともに2段目の給油を行うことを特徴とするポリアミド極細繊維の溶融紡糸方法。
(7)冷却装置が、吐出孔から吐出された溶融紡糸糸条の内側から冷却風を吹き付けて溶融紡糸糸条を冷却する冷却装置であることを特徴とする、前記(6)に記載のポリアミド極細繊維の溶融紡糸方法。
(8)冷却装置が下記を満足することを特徴とする、前記(6)または(7)に記載のポリアミド極細繊維の溶融紡糸方法。
(i)紡糸口金面から冷却装置の冷却開始位置までの距離(L)が10mm≦L≦70mm
(ii)冷却開始位置にて吹き出している冷却風の風速が15~60m/min
(9)単糸繊度が0.10dtex以上0.50dtex以下であり、フィラメントの長手方向12000mあたりの平均毛羽数が1.0個以下であるポリアミド極細繊維の溶融紡糸装置であって、紡糸口金外周部に円周状に配された吐出孔を有する紡糸口金と、該紡糸口金の中心部の下部にあって、吐出孔から吐出された溶融紡糸糸条の内側または外側から冷却風を吹き付けて溶融紡糸糸条を冷却する冷却装置を有しており、さらに該冷却装置の鉛直方向下部に円盤の外周部で単糸が接触する円盤形のガイド部と、ガイド部の直上にガイドの外周にそって形成した油剤吐出用の環状スリットを有する環状給油装置と、その下流に糸条を集束させるとともに2段目の給油を行うための集束ガイド型給油装置を有することを特徴とするポリアミド極細繊維の溶融紡糸装置。
(10)冷却装置が、吐出孔から吐出された溶融紡糸糸条の内側から冷却風を吹き付けて溶融紡糸糸条を冷却する冷却装置であることを特徴とする、前記(9)に記載のポリアミド極細繊維の溶融紡糸装置。 The present invention adopts the following configuration in order to solve the above problems.
(1) A polyamide ultrafine fiber characterized in that, in a polyamide fiber having a single yarn fineness of 0.10 dtex or more and 0.50 dtex or less, the average number of fluffs per 12000 m in the longitudinal direction of the filament is 1.0 or less.
(2) The polyamide ultrafine fiber as described in (1) above, wherein Worcester spots in the longitudinal direction of the filament are 1.0% or less.
(3) The polyamide ultrafine fiber as described in (1) or (2) above, wherein the total fineness is 15 to 300 dtex and the number of filaments is 30 or more.
(4) The polyamide ultrafine fiber as described in any one of (1) to (3) above, wherein the filament has an irregular cross-section.
(5) Polyamide ultrafine fiber having a single yarn with a circular cross-sectional shape of the filament, and the orientation parameter of the single yarn surface portion relative to the orientation parameter of the single yarn central portion with respect to the orientation parameter of the single yarn having a circular cross-sectional shape The polyamide ultrafine fiber according to any one of the above (1) to (3), wherein the ratio of is 1.10.
(6) A melt spinning method of polyamide ultrafine fibers having a single yarn fineness of 0.10 dtex or more and 0.50 dtex or less and an average number of fluffs per 12000 m in the longitudinal direction of the filament of 1.0 or less, and the outer periphery of the spinneret A melt-spun yarn spun from a spinneret having discharge holes arranged circumferentially in the part, at the bottom of the center of the spinneret, inside the melt-spun yarn discharged from the discharge holes or A disk-shaped guide unit in which cooling is performed using a cooling device that blows cooling air from the outside to cool the melt-spun yarn, and a single yarn is in contact with the outer periphery of the disk at the lower part in the vertical direction of the cooling device, and a guide unit After supplying oil using an annular oil supply device having an annular slit for discharging an oil agent formed along the outer periphery of the guide, the yarn is converged by a converging guide type oil supply device and the second stage oil supply is performed. Melt spinning method of the polyamide ultrafine fiber characterized Ukoto.
(7) The polyamide according to (6), wherein the cooling device is a cooling device that cools the melt spun yarn by blowing cooling air from the inside of the melt spun yarn discharged from the discharge hole. A method for melt spinning ultrafine fibers.
(8) The melt spinning method for polyamide ultrafine fibers according to (6) or (7) above, wherein the cooling device satisfies the following conditions.
(I) The distance (L) from the spinneret surface to the cooling start position of the cooling device is 10 mm ≦ L ≦ 70 mm
(Ii) The speed of the cooling air blown out at the cooling start position is 15 to 60 m / min.
(9) A melt spinning apparatus for polyamide ultrafine fibers having a single yarn fineness of 0.10 dtex or more and 0.50 dtex or less and an average number of fluffs per 12000 m in the longitudinal direction of the filament of 1.0 or less. Spinneret with discharge holes arranged circumferentially in the part, and melted by blowing cooling air from the inside or outside of the melt-spun yarn discharged from the discharge hole at the bottom of the center part of the spinneret A cooling device for cooling the spun yarn, and further, a disc-shaped guide portion in which the single yarn contacts the outer peripheral portion of the disc at a lower portion in the vertical direction of the cooling device, and an outer periphery of the guide immediately above the guide portion. Characterized in that it has an annular oil supply device having an annular slit for discharging an oil agent and a converging guide type oil supply device for converging the yarn downstream and supplying the second stage oil supply. Melt spinning apparatus of the ultra-fine fibers.
(10) The polyamide according to (9), wherein the cooling device is a cooling device that cools the melt-spun yarn by blowing cooling air from the inside of the melt-spun yarn discharged from the discharge hole. Ultra-fine fiber melt spinning equipment.
試料(糸条)を枠周1.000mの検尺機にて、27デシテックス以下の品種は1000回巻カセ、28デシテックス以上の品種は500回巻カセを作成し、熱風乾燥機にて105±2℃×60分乾燥した後、天秤にて計量した値により次式(i)または(ii)にて算出したものを総繊度とした。また得られた総繊度を糸条単糸数で割り返した値を単糸繊度とした。
(i)27デシテックス以下の品種
総繊度(dtex)=計量値(g)×(10000/1000)×{1+(公定水分率(%)/100)}
(ii)28デシテックス以上の品種
総繊度(dtex)=計量値(g)×(10000/500)×{1+(公定水分率(%)/100)}
ここで、実施例中で使用したナイロン6およびナイロン66ポリマーについては、公定水分率を4.5%として繊度の算出を行った。
単糸繊度(dtex)=総繊度(dtex)/単糸数
ただし、異なる2種類の断面形状(断面Aおよび断面B)の混繊フィラメントにおける単糸繊度については、以下に示す式にて、それぞれの断面形状における単糸断面の面積比を算出し、上記総繊度に面積比を乗じ、同形状のフィラメントの総数で割った値とした。
断面Aの面積比=断面Aの面積/(断面Aの面積+断面Bの面積)
断面Bの面積比=断面Bの面積/(断面Aの面積+断面Bの面積)
混繊フィラメント中の断面Aの単糸繊度(dtex)=(総繊度(dtex)×断面Aの面積比)/断面Aのフィラメント数
混繊フィラメント中の断面Bの単糸繊度(dtex)=(総繊度(dtex)×断面Bの面積比)/断面Bのフィラメント数 (1) Total fineness and single yarn fineness Using a measuring machine with a frame circumference of 1.000 m, create a 1000-turn casserole for varieties below 27 decitex and a 500-turn casserole for varieties above 28 decitex Then, after drying at 105 ± 2 ° C. for 60 minutes with a hot air dryer, the value calculated by the following formula (i) or (ii) based on the value measured with a balance was taken as the total fineness. Further, the value obtained by dividing the obtained total fineness by the number of single yarns was defined as the single yarn fineness.
(I) Varieties of 27 dtex or less Total fineness (dtex) = Weighed value (g) × (10000/1000) × {1+ (official moisture content (%) / 100)}
(Ii) Varieties of 28 dtex or more Total fineness (dtex) = Weighed value (g) × (10000/500) × {1+ (official moisture content (%) / 100)}
Here, for the
Single yarn fineness (dtex) = total fineness (dtex) / number of single yarns However, for the single yarn fineness in the mixed filaments of two different types of cross-sectional shapes (cross-section A and cross-section B), The area ratio of the cross section of the single yarn in the cross-sectional shape was calculated, and the value obtained by multiplying the total fineness by the area ratio and dividing by the total number of filaments of the same shape.
Area ratio of section A = area of section A / (area of section A + area of section B)
Area ratio of section B = area of section B / (area of section A + area of section B)
Single yarn fineness (dtex) of cross section A in mixed filaments = (total fineness (dtex) × area ratio of cross section A) / number of filaments of cross section A Single yarn fineness (dtex) of cross section B in mixed filaments = ( Total fineness (dtex) × area ratio of section B) / number of filaments in section B
試料を秤量し、98重量%濃硫酸に試料濃度(C)が1g/100mlとなるように溶解し、該溶液についてオストワルド粘度計にて25℃での落下秒数(T1)を測定する。さらに試料を溶解していない98重量%濃硫酸について、同様に25℃での落下秒数(T2)を測定した後、試料の相対粘度(ηr)を下式により算出する。
(ηr)=(T1/T2)+{1.891×(1.000-C)} (2) Sulfuric acid relative viscosity A sample is weighed and dissolved in 98% by weight concentrated sulfuric acid so that the sample concentration (C) is 1 g / 100 ml, and the solution is dropped by an Ostwald viscometer at 25 ° C. (T1 ). Furthermore, about 98 weight% concentrated sulfuric acid which has not melt | dissolved the sample, after similarly dropping seconds (T2) at 25 degreeC are measured, the relative viscosity ((eta) r) of a sample is computed by the following Formula.
(Ηr) = (T1 / T2) + {1.891 × (1.000−C)}
平均毛羽数は、東レエンジニアリング社(現在の社名はtmtマシナリー)のMALUTI-POINT FRAY COUNTER MFC-200(センサー部 F型)を使用して、毛羽長設定(センサー光軸中心からU-Guide底部までの距離):2.0mm、糸速:600m/min、測定時間:20分間の条件において、給糸張力:0.25g/dtex~0.75g/dtexの範囲にあることを確認しながら、測定回数:10回測定し、その測定平均値を平均毛羽数(個/12000m)とした。 (3) Average number of fluff The average number of fluff is set using the MALUTI-POINT FRAY COUNTER MFC-200 (sensor part F type) from Toray Engineering Co., Ltd. (current name is tmt machinery) (sensor optical axis center) To U-Guide bottom): 2.0 mm, yarn speed: 600 m / min, measurement time: 20 minutes, feed tension: within the range of 0.25 g / dtex to 0.75 g / dtex The number of measurements was measured 10 times, and the measurement average value was defined as the average number of fluffs (pieces / 12,000 m).
配向パラメーターは断面形状が円形であるサンプル(単糸)について、ラマン分光法により測定し、Jobin Yvon/愛宕物産社製 T-64000を使用し、測定モード:顕微ラマン、対物レンズ:×100、ビーム径:1μm、光源:Ar+レーザー/514.5nm、レーザーパワー:100mW、回折格子:Single 600、1800gr/mm、スリット:100μm、検出器:Jobin Yvon社製CCD 1024×256の条件にて測定を行った。測定試料は樹脂(ビスフェノール系エポキシ樹脂、24時間硬化)包埋後、繊維長手方向から5°以下の切削角にてミクロトームにより切片化した。切片試料の厚みは1.5μmであり、繊維の中心を通るように切り出した。配向の測定は偏光条件下で行い、偏光方向が繊維長手方向と一致する場合を平行偏光(∥)、直交する場合を垂直偏光(⊥)とし、それぞれ得られるラマンバンドにおいて、1130cm-1付近のC-C変角振動モードに帰属されるピーク強度(I1130)と、1635cm-1付近のC=C伸縮振動に帰属されるピーク強度(I1635)の比から配向の程度を評価した。すなわち
配向パラメーター=(I1130/I1635)∥/(I1130/I1635)⊥
である。このうち、測定点について、単糸表面部の配向パラメーターは単糸表面部から1μm内部の点、中央部の配向パラメーターは単糸中央部の点についてレーザーを照射し、配向パラメーターを算出した。この結果より、単糸中央部の配向パラメーターに対する単糸表面部の配向パラメーター比は以下の式にて算出した。なお、単糸中央部と単糸表面部の配向パラメーターについては、フィラメント中より無作為に採取した単糸5本における平均値を用いて算出した。
配向パラメーター比=(単糸表面部の配向パラメーター)/(単糸中央部の配向パラメーター) (4) Orientation parameter ratio Orientation parameters were measured by Raman spectroscopy for a sample (single yarn) having a circular cross-sectional shape, using T-64000 manufactured by Jobin Yvon / Ehime Bussan Co., Ltd., measurement mode: microscopic Raman, objective Lens: × 100, beam diameter: 1 μm, light source: Ar + laser / 514.5 nm, laser power: 100 mW, diffraction grating: Single 600, 1800 gr / mm, slit: 100 μm, detector: CCD 1024 × 256 manufactured by Jobin Yvon The measurement was performed under the following conditions. A measurement sample was embedded in a resin (bisphenol-based epoxy resin, cured for 24 hours) and then sectioned with a microtome at a cutting angle of 5 ° or less from the fiber longitudinal direction. The slice sample had a thickness of 1.5 μm and was cut out so as to pass through the center of the fiber. The measurement of the orientation is performed under polarization conditions. When the polarization direction coincides with the longitudinal direction of the fiber, the parallel polarization (∥) and when perpendicular, the vertical polarization (⊥) are obtained, and in the obtained Raman band, the vicinity of 1130 cm −1 is obtained. The degree of orientation was evaluated from the ratio of the peak intensity (I 1130 ) attributed to the CC deformation vibration mode and the peak intensity (I 1635 ) attributed to C = C stretching vibration near 1635 cm −1 . That is, orientation parameter = (I 1130 / I 1635 ) ∥ / (I 1130 / I 1635 ) ⊥
It is. Among the measurement points, the orientation parameter of the single yarn surface portion was irradiated with a laser at a
Orientation parameter ratio = (Orientation parameter of single yarn surface portion) / (Orientation parameter of single yarn central portion)
ウースター斑は、ZELLWEGER USTER社のUSTER TESTER UT-4を使用し、糸速50m/分、S撚り、撚り数8000rpmで3分間の測定条件において、1/2inertのウースター斑U%を測定した。 (5) Wooster plaques Wooster plaques were measured using a ZELLWEGER USTER USTER TESTER UT-4, measuring at a yarn speed of 50 m / min, S twist, and a twist number of 8000 rpm for 3 min. Was measured.
15%伸長時応力はORIENTEC社製TENSIRON RPC-1210Aを使用し、つかみ間隔50cmで把持し、50cm/minの引っ張り速度で伸長させ、57.5cmまで伸長させたときの張力を3回測定し、その平均値を繊維の繊度で割り返した値とした。 (6) 15
伸度はORIENTEC社製TENSIRON RPC-1210Aを使用し、つかみ間隔50cmで把持し、50cm/minの引っ張り速度で伸張させ、糸が破断した際の引っ張り長を3回測定し、その平均値を50cmで割り、100を掛けた値とした。 (7) Elongation The elongation is measured using a TENSIRON RPC-1210A manufactured by ORIENTEC, gripped at a gripping interval of 50 cm, stretched at a pulling speed of 50 cm / min, and the tensile length when the yarn breaks is measured three times. The average value was divided by 50 cm and multiplied by 100.
得られた繊維からなり染色した布帛について、柔らかさ、表面のなめらかさ、ドレープ性、布帛の色の深みを触感および目視で判定し、以下の4段階で判定した。
(A)・・・極めて良好(染色した布帛が柔らかく、表面がなめらかであり、ドレープ性がある。布帛表面に毛羽立ちはみられない。)
(B)・・・良好(柔らかさ、ドレープ性に優れるものの、なめらかさに劣り、一部表面に毛羽立ちが見られる。)
(C)・・・やや不良(ドレープ性があるものの、柔らかさ、なめらかさに劣り、一部に毛羽立ちが見られる。)
(D)・・・不良(布帛が硬く、なめらかさ、ドレープ性に劣り、表面に毛羽立ちがみられる。)。 (8) Softness of cloth The softness, the smoothness of the surface, the drapeability, and the color depth of the cloth were determined visually and tactilely, and the following four stages were determined.
(A)... Very good (the dyed fabric is soft, the surface is smooth and draped. No fuzz is observed on the fabric surface)
(B) ... good (although it is excellent in softness and drapeability, it is inferior in smoothness, and some surfaces are fluffy.)
(C) ··· Slightly poor (although it has drape properties, it is inferior in softness and smoothness, and some fluff is seen.)
(D) Defective (the fabric is hard, smooth and drape is inferior, and the surface is fuzzy).
得られた繊維をタテ・ヨコ両方に用い、かつヨコ打ち込み長180cmの平織物を作成し、布帛を酸性染料(Mitsui Nylon Black GL)を用いて染色した。染色後の平織物を透視検反機によって検査者(10人)の評価により、長手方向で100m検反し、次の基準で相対評価した。
(A)・・・スジ、濃淡ムラが全くない。
(B)・・・弱いスジ、濃淡ムラが多少見られるが実用可能レベル。
(C)・・・弱いスジ、濃淡ムラが多く見られ実用可能レベルではない。
(D)・・・強いスジ、濃淡ムラが多く見られ実用可能レベルではない。 (9) Dyeing quality of the fabric The obtained fiber was used for both vertical and horizontal, and a plain woven fabric having a length of 180 cm was created, and the fabric was dyed with an acid dye (Mitsui Nylon Black GL). The plain fabric after dyeing was inspected 100 m in the longitudinal direction by an inspector (10 persons) using a fluoroscopic inspection machine, and subjected to relative evaluation according to the following criteria.
(A) ... there are no streaks or shading.
(B) ... Slight streaks and uneven shading are seen, but at a practical level.
(C) ···················································· Practical level
(D) A lot of strong streaks and shading unevenness is observed, which is not at a practical level.
JIS L1096(1999)「バイレック法」により測定した。この測定で得られる吸水高さについて次の基準で評価した。
(A)・・・90mm以上
(B)・・・65mm以上90mm未満
(C)・・・55mm以上65mm未満
(D)・・・55mm未満。 (10) Water absorbency of fabric (Bilec method)
Measured according to JIS L1096 (1999) “Bilec method”. The water absorption height obtained by this measurement was evaluated according to the following criteria.
(A) ... 90 mm or more (B) ... 65 mm or more and less than 90 mm (C) ... 55 mm or more and less than 65 mm (D) ... less than 55 mm.
得られた繊維にて筒編みを作成した後、検査者(10人)の評価により、精練後の布帛の防透け性を次の基準で相対評価した。
(A)・・・極めて良好(透け感が全く無く、防透け素材として使用可能。)
(B)・・・良好(若干透け感が認められるが、防透け素材として実用可能なレベル)
(C)・・・実用可能(通常の用途において問題ないレベル)
(D)・・・不良(透明感が強く、インナー用には使用不可能) (11) The sheerness of the fabric After the tube was knitted with the obtained fiber, the sheerness of the fabric after scouring was relatively evaluated according to the following criteria by the evaluation of an inspector (10 persons).
(A) ... very good (no sense of sheer, can be used as a sheer-proof material)
(B) ... good (a slight sense of sheerness is recognized, but a practical level as a sheerproof material)
(C): Practical (level that is not a problem in normal use)
(D) ・ ・ ・ Bad (Transparency is strong and cannot be used for inner)
布帛の総合評価として次の基準によって評価した。
(A)・・・布帛のソフト性、染色品位、吸水性、防透け性の4項目全てについて(A)もしくは(B)評価であり、2項目以上が(A)である。
(B)・・・布帛のソフト性、染色品位、吸水性、防透け性の4項目において、(C)評価が1項目以下であるが、(D)評価の項目は無い。
(C)・・・布帛のソフト性、染色品位、吸水性、防透け性の4項目全てについて(D)評価の項目はないが、(C)評価の項目が2項目以上ある。
(D)・・・布帛のソフト性、染色品位、吸水性、防透け性の4項目のうち1項目以上に(D)評価の項目がある。 (12) Comprehensive evaluation of fabrics The following criteria were evaluated as comprehensive evaluations of fabrics.
(A)... (A) or (B) evaluation for all four items of fabric softness, dyeing quality, water absorption, and see-through property, and two or more items are (A).
(B) ... In four items of fabric softness, dyeing quality, water absorption, and see-through property, (C) evaluation is 1 item or less, but there is no (D) evaluation item.
(C)... There are no (D) evaluation items for all four items of fabric softness, dyeing quality, water absorption, and anti-peeling properties, but (C) there are two or more evaluation items.
(D): One or more items among the four items of fabric softness, dyeing quality, water absorption, and see-through property include (D) evaluation items.
98%硫酸相対粘度2.63のナイロン66を285℃で溶融後、溶融紡糸口金パックに供し、98ホールの円形孔を持った口金孔から吐出し、各単糸を、紡糸口金面に向けて0.25kPaの圧力で蒸気が噴出されている蒸気噴出ゾーンを通過させた後、該蒸気噴出ゾーン下流側で、冷却開始点距離が30mmで、鉛直方向の長さが300mmの冷却風吹き出し部を有する単体の外吹き式環状型冷却装置を通過させ、外吹きに放射状に吹く20℃の冷却風を40m/minの風速にて吹き付け、冷却固化を行わせる。その後、口金面より500mmの位置で、円盤の外周部で単糸が接触する円盤形のガイド部と、ガイド部の直上にガイドの外周にそって形成した油剤吐出用の環状スリットを有する環状給油装置によりエマルジョン油剤を付与し、さらに収束ガイド型給油装置にて2段目の給油を行うとともに糸条を収束させ、インターレースの付与を行いながら、4000m/分で引き取り、延伸倍率1.10倍にて延伸を行った後、リラックス条件下において4200m/分でパッケージに巻き取り、40dtex/98フィラメント、伸度45%のナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表1に示す。なお表中、ナイロン66をN66と略記する。 Example 1
Nylon 66 with a 98% sulfuric acid relative viscosity of 2.63 is melted at 285 ° C., then supplied to a melt spinneret pack, and discharged from a die hole having a 98-hole circular hole. Each single yarn is directed to the spinneret surface. After passing through a steam ejection zone where steam is ejected at a pressure of 0.25 kPa, a cooling air blowing section having a cooling start point distance of 30 mm and a vertical length of 300 mm is provided downstream of the steam ejection zone. A single outer-blow-type annular cooling device is passed through, and 20 ° C. cooling air blown radially is blown to the outer blow at a wind speed of 40 m / min to cause cooling and solidification. Thereafter, at a position 500 mm from the base surface, an annular oil supply having a disk-shaped guide part in contact with the single yarn at the outer peripheral part of the disk and an annular slit for discharging the oil agent formed along the outer periphery of the guide immediately above the guide part. Emulsion oil agent is applied by the device, and further, the second stage of oil is supplied by the convergence guide type oil supply device, the yarn is converged, and the interlace is applied, and it is taken up at 4000 m / min, and the draw ratio is 1.10 times. Then, the film was wound at 4200 m / min under relaxing conditions to obtain a nylon 66 fiber having 40 dtex / 98 filament and 45% elongation. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1. In the table, nylon 66 is abbreviated as N66.
98%硫酸相対粘度2.63のナイロン6を255℃で溶融後、溶融紡糸口金パックに供したこと以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン6繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表1に示す。なお表中、ナイロン6をN6と略記する。 Example 2
268ホールの円形孔を持った口金を使用する以外は実施例1と同様の方法で紡糸を行い、40dtex/268フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表1に示す。 Example 3
Spinning was carried out in the same manner as in Example 1 except that a die having a 268 hole circular hole was used, and a nylon 66 fiber of 40 dtex / 268 filament was obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1.
82ホールの円形孔を持った口金を使用する以外は実施例1と同様の方法で紡糸を行い、40dtex/82フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表1に示す。 Example 4
Spinning was carried out in the same manner as in Example 1 except that a base having a circular hole of 82 holes was used to obtain a nylon 66 fiber of 40 dtex / 82 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1.
口金下蒸気噴出ゾーンの下流に設置された外吹き式環状型冷却装置における冷却風吹き出し部の鉛直方向の長さを100mmとし、環状給油装置による給油位置を口金下300mmとした以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表1に示す。 Example 5
Example 1 except that the length in the vertical direction of the cooling air blowing portion in the outer-blow-type annular cooling device installed downstream of the steam blow zone below the mouthpiece is 100 mm, and the fueling position by the annular fueling device is 300 mm below the mouthpiece. Spinning was carried out in the same manner as described above to obtain 40 dtex / 98 filament nylon 66 fibers. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1.
98%硫酸相対粘度2.63のナイロン66を275℃で溶融した以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表1に示す。 Example 6
Spinning was carried out in the same manner as in Example 1 except that nylon 66 having a 98% sulfuric acid relative viscosity of 2.63 was melted at 275 ° C. to obtain a nylon 66 fiber of 40 dtex / 98 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 1.
42ホールの円形孔を持った口金を使用し、繊度を17dtexとした以外は実施例1と同様の方法で紡糸を行い、17dtex/42フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表2に示す。 Example 7
Spinning was performed in the same manner as in Example 1 except that a die having a 42 hole circular hole was used and the fineness was changed to 17 dtex to obtain a nylon 66 fiber of 17 dtex / 42 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 2.
680ホールの円形孔を持った口金を使用し、繊度を280dtexとした以外は実施例1と同様の方法で紡糸を行い、280dtex/680フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表2に示す。 Example 8
Spinning was performed in the same manner as in Example 1 except that a die having a circular hole of 680 holes was used and the fineness was changed to 280 dtex to obtain nylon 66 fibers of 280 dtex / 680 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 2.
32ホールの円形孔をもった口金を使用し、繊度を15dtexとした以外は実施例1と同様の方法で紡糸を行い、15dtex/32フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表2に示す。 Example 9
Spinning was carried out in the same manner as in Example 1 except that a die having a 32-hole circular hole was used and the fineness was changed to 15 dtex to obtain nylon 66 fibers of 15 dtex / 32 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 2.
98%硫酸相対粘度2.63のナイロン6を255℃で溶融後、溶融紡糸口金パックに供し、98ホールの図2に示すような断面形状が3葉のスリット形状を持った口金吐出孔から吐出した以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントの3葉断面ナイロン6繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表2に示す。 Example 10
49ホールの図3に示すような断面形状が6葉の口金吐出孔、及び同数の丸孔が混在している98ホールの口金を用いた以外は実施例10と同様の方法で紡糸を行い、40dtex/98フィラメントの6葉断面と丸断面の混在したナイロン6繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表2に示す。 Example 11
Spinning was carried out in the same manner as in Example 10 except that a 49-hole die discharge hole having a cross-sectional shape of 49 holes as shown in FIG. 3 and a 98-hole die mixed with the same number of round holes were used, A
インターレースの付与を行った後、3000m/分にて引き取り、延伸倍率1.50倍にて延伸を行った後に、リラックス条件下において4300m/分で巻取った以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表3に示す。 Example 12
After applying interlace, it was taken out at 3000 m / min, drawn at a draw ratio of 1.50, and then wound up at 4300 m / min under relaxed conditions in the same manner as in Example 1. Spinning was performed to obtain nylon 66 fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
鉛直方向の長さが300mmの冷却風吹き出し部を有する単体の内吹き式環状型冷却装置を、外吹き式環状型冷却装置の代わりに通過させる以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表3に示す。 Example 13
Spinning was carried out in the same manner as in Example 1 except that a single inner-blow-type annular cooling device having a cooling air blowing portion having a vertical length of 300 mm was passed instead of the outer-blow-type annular cooling device. , 40 dtex / 98 filament nylon 66 fiber was obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
冷却開始点距離を20mmとする以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表3に示す。 Example 14
Spinning was carried out in the same manner as in Example 1 except that the cooling start point distance was 20 mm to obtain 40 dtex / 98 filament nylon 66 fibers. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
冷却開始点距離を40mmとする以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表3に示す。 Example 15
Spinning was carried out in the same manner as in Example 1 except that the cooling start point distance was 40 mm, to obtain nylon 66 fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
冷却開始点距離を10mmとする以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表3に示す。 Example 16
Spinning was performed in the same manner as in Example 1 except that the cooling start point distance was set to 10 mm, to obtain nylon 66 fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 3.
冷却開始点距離を60mmとする以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表4に示す。 Example 17
Spinning was carried out in the same manner as in Example 1 except that the cooling start point distance was 60 mm to obtain 40 dtex / 98 filament nylon 66 fibers. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
外吹き式環状型冷却装置から外吹きに放射状に吹く20℃の冷却風の風速を27m/minとした以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表4に示す。 Example 18
Spinning was carried out in the same manner as in Example 1 except that the air velocity of the cooling air at 20 ° C. blown radially from the outer blown annular cooling device to 27 m / min, and nylon 66 fiber of 40 dtex / 98 filament was obtained. Obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
外吹き式環状型冷却装置から外吹きに放射状に吹く20℃の冷却風の風速を49m/minとした以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表4に示す。 Example 19
Spinning was carried out in the same manner as in Example 1 except that the air velocity of the cooling air at 20 ° C. blown radially from the outer blown annular cooling device to 49 m / min, and nylon 66 fibers of 40 dtex / 98 filaments were obtained. Obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
外吹き式環状型冷却装置から外吹きに放射状に吹く20℃の冷却風の風速を17m/minとした以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表4に示す。 Example 20
Spinning was performed in the same manner as in Example 1 except that the air speed of the cooling air at 20 ° C. blown radially outward from the outer blown annular cooling device was changed to 17 m / min, and nylon 66 fiber of 40 dtex / 98 filament was obtained. Obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
外吹き式環状型冷却装置から外吹きに放射状に吹く20℃の冷却風の風速を58m/minとした以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表4に示す。 Example 21
Spinning was carried out in the same manner as in Example 1 except that the air velocity of the cooling air at 20 ° C. blown radially outward from the outer blown annular cooling device was set to 58 m / min, and nylon 66 fiber of 40 dtex / 98 filament was obtained. Obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 4.
160ホールの円形孔を持った口金孔から吐出し、繊度を15dtexとした以外は実施例1と同様の方法で紡糸を行い、15dtex/160フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表5に示す。 Comparative Example 1
Spinning was carried out in the same manner as in Example 1 except that the material was discharged from a die hole having a 160-hole circular hole and the fineness was set to 15 dtex to obtain nylon 66 fiber of 15 dtex / 160 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
繊度を56dtexとした以外は実施例1と同様の方法で紡糸を行い、56dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表5に示す。 Comparative Example 2
Spinning was carried out in the same manner as in Example 1 except that the fineness was 56 dtex to obtain nylon 66 fiber of 56 dtex / 98 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
外吹き式環状型冷却装置の鉛直方向下部の口金面より500mmの位置において、油剤吐出用の環状スリットを持たない円盤形ガイドを用い、油剤供給を行わずに円盤形ガイドに単糸を接触させる以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表5に示す。 Comparative Example 3
At a position 500 mm from the base surface of the lower part in the vertical direction of the outer blow type annular cooling device, a disk-shaped guide having no annular slit for discharging the oil is used, and the single thread is brought into contact with the disk-shaped guide without supplying the oil. Except for the above, spinning was performed in the same manner as in Example 1 to obtain a nylon 66 fiber of 40 dtex / 98 filament. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
ポリエチレンテレフタレート樹脂を290℃で溶融後、溶融紡糸口金パックに供した以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのポリエチレンテレフタレート繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表5に示す。 Comparative Example 4
Spinning was performed in the same manner as in Example 1 except that the polyethylene terephthalate resin was melted at 290 ° C. and then used in a melt spinneret pack to obtain polyethylene terephthalate fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
冷却装置を一方向型のユニフローチムニーとし、給油ガイドにて糸条を収束し、給油する以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表5に示す。 Comparative Example 5
Spinning was performed in the same manner as in Example 1 except that the cooling device was a one-way type uniflow chimney, the yarn was converged by an oil supply guide, and oil was supplied to obtain nylon 66 fibers of 40 dtex / 98 filaments. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
環状給油装置にて給油を行ったのち、2段目の給油を行わずに集束ガイドにて糸条を集束する以外は実施例1と同様の方法で紡糸を行い、40dtex/98フィラメントのナイロン66繊維を得た。得られた原糸および布帛の特性評価を行った。結果を表5に示す。 Comparative Example 6
Spinning is carried out in the same manner as in Example 1 except that the second stage oiling is performed and the yarn is converged by the converging guide after the second lubrication, and the nylon 66 of 40 dtex / 98 filament is used. Fiber was obtained. The properties of the obtained raw yarn and fabric were evaluated. The results are shown in Table 5.
2 口金下保温ゾーン
3 外吹き式環状型冷却装置
4 環状給油装置
5 集束ガイド型給油装置
6 インターレースノズル
7 引き取りローラー
8 延伸ローラー
9 ワインダー(巻取装置)
10 繊維フィラメント
11 繊維製品パッケージ
12 油剤吐出用スリット
13 円盤形ガイド
14 繊維フィラメント
15 油剤溜まり
16 スリットより吐出された油剤
17 油剤供給用配管
18 内吹き式環状型冷却装置 DESCRIPTION OF
DESCRIPTION OF
Claims (10)
- 単糸繊度が0.10dtex以上0.50dtex以下のポリアミド繊維において、フィラメントの長手方向12000mあたりの平均毛羽数が1.0個以下であることを特徴とするポリアミド極細繊維。 Polyamide ultrafine fiber characterized in that, in a polyamide fiber having a single yarn fineness of 0.10 dtex or more and 0.50 dtex or less, the average number of fluffs per 12000 m in the longitudinal direction of the filament is 1.0 or less.
- フィラメントの長手方向のウースター斑が1.0%以下であることを特徴とする、請求項1に記載のポリアミド極細繊維。 2. The polyamide ultrafine fiber according to claim 1, wherein a Wooster spot in the longitudinal direction of the filament is 1.0% or less.
- 総繊度が15~300dtex、フィラメント数が30以上であることを特徴とする請求項1または2に記載のポリアミド極細繊維。 The polyamide ultrafine fiber according to claim 1 or 2, wherein the total fineness is 15 to 300 dtex and the number of filaments is 30 or more.
- フィラメントの断面形状が異形断面であることを特徴とする請求項1~3のいずれかに記載のポリアミド極細繊維。 The polyamide ultrafine fiber according to any one of claims 1 to 3, wherein the filament has an irregular cross-section.
- ポリアミド極細繊維において、フィラメントの断面形状が円形である単糸を有し、かつ円形断面形状を有する単糸の配向パラメーターについて、単糸中央部の配向パラメーターに対する単糸表面部の配向パラメーターの比が、1.10以上であることを特徴とする、請求項1~3のいずれかに記載のポリアミド極細繊維。 In the polyamide ultrafine fiber, the filament has a single yarn with a circular cross-sectional shape, and the orientation parameter of the single yarn having a circular cross-sectional shape has a ratio of the orientation parameter of the single yarn surface portion to the orientation parameter of the single yarn central portion. The polyamide ultrafine fiber according to any one of claims 1 to 3, which is 1.10 or more.
- 単糸繊度が0.10dtex以上0.50dtex以下であり、フィラメントの長手方向12000mあたりの平均毛羽数が1.0個以下であるポリアミド極細繊維の溶融紡糸方法であって、紡糸口金外周部に円周状に配された吐出孔を有する紡糸口金から紡出した溶融紡糸糸条を、前記紡糸口金の中心部の下部にあって、吐出孔から吐出された溶融紡糸糸条の内側または外側から冷却風を吹き付けて溶融紡糸糸条を冷却する冷却装置を用いて冷却し、さらに該冷却装置の鉛直方向下部に円盤の外周部で単糸が接触する円盤形のガイド部と、ガイド部の直上にガイドの外周にそって形成した油剤吐出用の環状スリットを有する環状給油装置を用いて給油を行った後、集束ガイド型給油装置にて糸条を集束させるとともに2段目の給油を行うことを特徴とするポリアミド極細繊維の溶融紡糸方法。 A melt spinning method for polyamide ultrafine fibers having a single yarn fineness of 0.10 dtex or more and 0.50 dtex or less and an average number of fluffs per 12000 m in the longitudinal direction of the filament of 1.0 or less. A melt-spun yarn spun from a spinneret having discharge holes arranged in a circumferential shape is cooled from the inside or outside of the melt-spun yarn discharged from the discharge hole at the bottom of the center of the spinneret. Cool by using a cooling device that cools the melt-spun yarn by blowing air, and further, a disk-shaped guide part in which the single yarn contacts the lower part in the vertical direction of the cooling device at the outer periphery of the disk, and immediately above the guide part. After supplying oil by using an annular oil supply device having an annular slit for discharging an oil agent formed along the outer periphery of the guide, the yarn is converged by the converging guide type oil supply device and the second stage of oil supply is performed. Melt spinning method of the polyamide ultrafine fiber characterized and.
- 冷却装置が、吐出孔から吐出された溶融紡糸糸条の内側から冷却風を吹き付けて溶融紡糸糸条を冷却する冷却装置であることを特徴とする、請求項6に記載のポリアミド極細繊維の溶融紡糸方法。 The melt of polyamide ultrafine fiber according to claim 6, wherein the cooling device is a cooling device that cools the melt spun yarn by blowing cooling air from the inside of the melt spun yarn discharged from the discharge holes. Spinning method.
- 冷却装置が下記を満足することを特徴とする請求項6または7に記載のポリアミド極細繊維の溶融紡糸方法。
(1)紡糸口金面から冷却装置の冷却開始位置までの距離(L)が10mm≦L≦70mm
(2)冷却開始位置にて吹き出している冷却風の風速が15~60m/min The method for melt spinning polyamide ultrafine fibers according to claim 6 or 7, wherein the cooling device satisfies the following conditions.
(1) The distance (L) from the spinneret surface to the cooling start position of the cooling device is 10 mm ≦ L ≦ 70 mm
(2) The speed of the cooling air blown out at the cooling start position is 15 to 60 m / min. - 単糸繊度が0.10dtex以上0.50dtex以下であり、フィラメントの長手方向12000mあたりの平均毛羽数が1.0個以下であるポリアミド極細繊維の溶融紡糸装置であって、紡糸口金外周部に円周状に配された吐出孔を有する紡糸口金と、該紡糸口金の中心部の下部にあって、吐出孔から吐出された溶融紡糸糸条の内側または外側から冷却風を吹き付けて溶融紡糸糸条を冷却する冷却装置を有しており、さらに該冷却装置の鉛直方向下部に円盤の外周部で単糸が接触する円盤形のガイド部と、ガイド部の直上にガイドの外周にそって形成した油剤吐出用の環状スリットを有する環状給油装置と、その下流に糸条を集束させるとともに2段目の給油を行うための集束ガイド型給油装置を有することを特徴とするポリアミド極細繊維の溶融紡糸装置。 A melt spinning apparatus for polyamide ultrafine fibers having a single yarn fineness of 0.10 dtex or more and 0.50 dtex or less and an average number of fluffs per 12000 m in the longitudinal direction of the filament of 1.0 or less. A spinneret having discharge holes arranged in a circumferential shape and a melt-spun yarn by blowing cooling air from the inside or outside of the melt-spun yarn discharged from the discharge hole at the lower part of the center of the spinneret. A disk-shaped guide portion that contacts a single yarn at the outer peripheral portion of the disk at the lower portion in the vertical direction of the cooling device, and formed along the outer periphery of the guide directly above the guide portion. A polyamide electrode having an annular oil supply device having an annular slit for discharging an oil agent, and a converging guide type oil supply device for converging the yarn downstream and supplying the second stage of oil supply Melt spinning apparatus of the fiber.
- 冷却装置が、吐出孔から吐出された溶融紡糸糸条の内側から冷却風を吹き付けて溶融紡糸糸条を冷却する冷却装置であることを特徴とする、請求項9に記載のポリアミド極細繊維の溶融紡糸装置。 The melting device for polyamide ultrafine fibers according to claim 9, wherein the cooling device is a cooling device for cooling the melt spun yarn by blowing cooling air from the inside of the melt spun yarn discharged from the discharge holes. Spinning device.
Priority Applications (5)
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JP2012503140A JP5780237B2 (en) | 2010-11-29 | 2011-11-21 | Polyamide ultrafine fiber and melt spinning method and apparatus thereof |
EP11844483.5A EP2647746B1 (en) | 2010-11-29 | 2011-11-21 | Polyamide yarn comprising ultrafine filaments, and melt-spinning method and device therefor |
CN201180057162.3A CN103221589B (en) | 2010-11-29 | 2011-11-21 | Ultrafine polyamide fiber, and melt-pinning method and device therefor |
US13/989,140 US20130251992A1 (en) | 2010-11-29 | 2011-11-21 | Ultrafine polyamide fiber, and melt-spinning method and device therefor |
KR1020137009386A KR101580883B1 (en) | 2010-11-29 | 2011-11-21 | Ultrafine polyamide fiber, and melt-spinning method and device therefor |
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JP2010264475 | 2010-11-29 | ||
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EP (1) | EP2647746B1 (en) |
JP (1) | JP5780237B2 (en) |
KR (1) | KR101580883B1 (en) |
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KR20130141484A (en) | 2013-12-26 |
JP5780237B2 (en) | 2015-09-16 |
US20130251992A1 (en) | 2013-09-26 |
CN103221589B (en) | 2014-12-03 |
KR101580883B1 (en) | 2015-12-30 |
EP2647746B1 (en) | 2016-08-10 |
EP2647746A4 (en) | 2014-07-30 |
EP2647746A1 (en) | 2013-10-09 |
TW201231746A (en) | 2012-08-01 |
JPWO2012073737A1 (en) | 2014-05-19 |
TWI527945B (en) | 2016-04-01 |
CN103221589A (en) | 2013-07-24 |
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