WO2012055582A2 - Agents de traitement capillaire comprenant du 3-méthyl-1,3-butanediol et un/des tensioactif(s) amphotère(s) - Google Patents

Agents de traitement capillaire comprenant du 3-méthyl-1,3-butanediol et un/des tensioactif(s) amphotère(s) Download PDF

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Publication number
WO2012055582A2
WO2012055582A2 PCT/EP2011/058367 EP2011058367W WO2012055582A2 WO 2012055582 A2 WO2012055582 A2 WO 2012055582A2 EP 2011058367 W EP2011058367 W EP 2011058367W WO 2012055582 A2 WO2012055582 A2 WO 2012055582A2
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WO
WIPO (PCT)
Prior art keywords
weight
alkyl
hair
polyquaternium
group
Prior art date
Application number
PCT/EP2011/058367
Other languages
German (de)
English (en)
Other versions
WO2012055582A3 (fr
Inventor
Erik Schulze Zur Wiesche
Volker Scheunemann
Original Assignee
1/Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 1/Henkel Ag & Co. Kgaa filed Critical 1/Henkel Ag & Co. Kgaa
Publication of WO2012055582A2 publication Critical patent/WO2012055582A2/fr
Publication of WO2012055582A3 publication Critical patent/WO2012055582A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)

Definitions

  • the present invention relates to hair treatment compositions which cause special care effects.
  • the known active ingredients can not cover all needs sufficiently. Particularly in the case of hair cleansing, an increased awareness of hygiene leads to an ever more frequent cleaning of the hair. In order to be here in addition to optimal cleaning and hair care long-term, the funds used must be particularly mild to the hair and scalp. There is therefore still a need for active ingredients or combinations of active ingredients for hair treatment compositions which not only do not have the properties of the fibers treated with them but improve on the contrary. In addition, the new ingredients should also be compatible with a broad range of other common ingredients and, at best, even more effective.
  • Hair treatment compositions for the purposes of the present invention are, for example, hair shampoos, hair conditioners, conditioning shampoos, hairsprays, hair conditioners, hair treatments, hair wraps, hair tonics, perming solutions, hair dye shampoos, hair dyes, hair fixatives, hair dressings, hairstyling preparations, hair lotions, mousses, hair gels , Hair waxes or their combinations.
  • Preferred agents according to the invention are shampoos, conditioners or hair tonics, in particular shampoos.
  • Particularly preferred hair treatment compositions contain as amphoteric surfactants betaines of the formula (VI)
  • agents according to the invention are preferred which, based on their weight, are from 0.25 to 8% by weight, more preferably from 0.5 to 7% by weight, more preferably from 0.75 to 6.5% by weight and in particular 1 to 5.5 wt .-% of surfactant (s) of the formula (VI).
  • R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms.
  • R and R 2 are independently a hydrogen atom, an alkali or alkaline earth metal cation, an ammonium group, the cation of an ammonium organic base or a radical Z derived from a polyhydroxylated organic compound selected from the group of etherified (C 6 -C 8) -Alkylpolysaccharide having 1 to 6 monomeric saccharide units and / or etherified aliphatic (C 6 -C 6) -hydroxyalkylpolyols is selected having 2 to 16 hydroxyl radicals, among the proviso that at least one of the groups R or R 2 Rest Z is,
  • Monoglyceride sulfates and monoglyceride ether sulfates Monoglyceride sulfates and monoglyceride ether sulfates.
  • alkyl monoglucoside alkyl- ⁇ -D- and ⁇ -D-glucopyranoside and small amounts of glucofuranoside
  • alkyldiglucosides -isomaltosides, maltosides, etc.
  • alkyl oligoglucosides maltotriosides, tetraosides, etc.
  • the average degree of polymerization of commercial products whose alkyl radicals are in the range C8-C16 is 1, 2-1, 5.
  • compositions according to the invention can be further enhanced by using certain care substances.
  • care substances are preferably selected from certain groups of known care substances, since these care substances perfectly harmonize with the combination according to the invention in terms of formulation and the care effect.
  • the 3-methyl-1,3-butanediol / surfactant combination is combined with at least one conditioner selected from L-carnitine and / or its salts, panthenol and / or pantothenic acid, 2-furanones and / or their derivatives, in particular pantolactone, taurine and / or its salts, niacinamide, ubiquinones, ectoine, allantoin.
  • conditioners are described below
  • L-carnitine (IUPAC name (R) - (3-carboxy-2-hydroxypropyl) -A /, A /, A / -trimethylammonium hydroxide) is a naturally occurring, vitamin-like substance.
  • Hydrogen -OH, a methyl, methoxy, aminomethyl or hydroxymethyl radical, --C 2 - C 4 - saturated or mono- or diunsaturated, branched or linear hydrocarbon radical,
  • R 5 and R 6 each represent hydrogen, methyl, a -C 2
  • Vitamins provitamins or vitamin precursors. These are described below:
  • vitamin A The group of substances referred to as vitamin A include retinol (vitamin A-1) and 3,4-didehydroretinol (vitamin A 2 ).
  • the ß-carotene is the provitamin of retinol.
  • Vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate in
  • Vitamin B 3 the compounds nicotinic acid and nicotinamide (niacinamide) are often performed.
  • Preferred according to the invention is the nicotinic acid amide which is contained in the agents used according to the invention preferably in amounts of from 0.05 to 1% by weight, based on the total agent.
  • R 4 is -CH 3 , -CH 2 CH 3 , - (CH 2 ) 2 CH 2 , -CH (CH 3 ) 2 ,
  • m has the value 2.
  • Copolymers contain monomer units having the formula (G1-I) as a non-ionic monomer, preferably acrylamide, methacrylamide, acrylic acid and methacrylic acid alkyl esters CI_ 4 d-4-alkyl ester.
  • acrylamide is particularly preferred.
  • copolymers can also be crosslinked, as described above in the case of the homopolymers.
  • a copolymer preferred according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer.
  • Such copolymers in which the monomers are present in a weight ratio of about 20:80 are commercially available as approximately 50% non-aqueous polymer dispersion 92 under the name Salcare ® SC.
  • Further preferred cationic polymers are, for example
  • Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers.
  • agents according to the invention are preferred which, based on their weight, are from 0.05 to 7.5% by weight, preferably from 0.1 to 5% by weight, particularly preferably from 0.2 to 3.5% by weight and in particular from 0.25% to 2.5% by weight of cationic polymer (s), preferred cationic polymer (s) being / are selected from
  • R 1 -CH CR 2 -CO-Z- (C n H 2n ) -N ( + ) R 3 R 4 R 5 A ⁇ " ) ( ⁇ ⁇ ')
  • the monomers containing a tertiary amino group are then quaternized in a known manner, methyl chloride, dimethyl sulfate or diethyl sulfate being particularly suitable as alkylating reagents.
  • the quaternization reaction can be carried out in aqueous solution or in the solvent.
  • Anionic polymers which contain 2-acrylamido-2-methylpropanesulfonic acid as the sole or co-monomer can be found to be particularly effective, it being possible for all or some of the sulfonic acid group to be present as sodium, potassium, ammonium, mono- or triethanolammonium salt ,
  • copolymers of at least one anionic monomer and at least one nonionic monomer may be preferable to use copolymers of at least one anionic monomer and at least one nonionic monomer.
  • anionic monomers reference is made to the substances listed above.
  • Preferred nonionic monomers are acrylamide, methacrylamide, acrylic esters, methacrylic esters, vinylpyrrolidone, vinyl ethers and vinyl esters.
  • Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with sulfonic acid-containing monomers.
  • Suitable nonionic polymers are, for example:
  • Cellulose ethers such as hydroxypropylcellulose, hydroxyethylcellulose and methylhydroxypropylcellulose
  • compositions according to the invention comprise the silicone (s) preferably in amounts of from 0.1 to 10% by weight, preferably from 0.25 to 7% by weight and in particular from 0.5 to 5% by weight. , in each case based on the total mean.
  • silicones are described below.
  • x is a number from 0 to 100, preferably from 0 to 50, more preferably from 0 to 20 and in particular 0 to 10.
  • Particularly preferred agents according to the invention contain one or more amino-functional silicones.
  • Such silicones may e.g. through the formula
  • - G is -H, a phenyl group, -OH, -O-CH 3 , -CH 3 , -O-CH 2 CH 3 , -CH 2 CH 3 , -O-CH 2 CH 2 CH 3 , -CH 2 CH 2 CH 3 , -O-CH (CH 3 ) 2, -CH (CH 3) 2, -O-CH 2 CH 2 CH 2 CH 3, CH 2 CH 2 CH 2 CH 3, -O-CH 2 CH (CH 3 ) 2 , -CH 2 CH (CH 3 ) 2 , -O-CH (CH 3 ) CH 2 CH 3 , - CH (CH 3 ) CH 2 CH 3 , -O -C (CH 3 ) 3 , -C (CH 3 ) 3 ;
  • a is a number between 0 and 3, in particular 0;
  • n and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10,
  • particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.1 to 10% by weight, preferably from 0.25 to 7% by weight and in particular from 0.5 to 5% by weight of silicone ( e) of the formula Si-lia and / or Si-Ilb
  • om and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10
  • agents according to the invention which contain at least one silicone of the formula Si-III
  • x is a number from 3 to 200, preferably from 3 to 10, more preferably from 30 to 7 and in particular 3, 4, 5 or 6.
  • amphoteric surfactant (s) 0.1 to 20% by weight of amphoteric surfactant (s).
  • Citric Acid 1 0

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des agents de lavage capillaire qui ont un effet traitant accru sur les cheveux et améliorent en particulier la souplesse, l'aspect lisse, et la brillance des cheveux, comprenant, en pourcentage en poids : entre 0,01 et 40 % en poids de 3-méthyl-1,3-butanediol et entre 0,1 et 20 % en poids d'un ou de plusieurs tensioactifs(s) amphotère(s).
PCT/EP2011/058367 2010-10-28 2011-05-23 Agents de traitement capillaire comprenant du 3-méthyl-1,3-butanediol et un/des tensioactif(s) amphotère(s) WO2012055582A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE201010043067 DE102010043067A1 (de) 2010-10-28 2010-10-28 Haarbehandlungsmittel mit-3-Methyl-1,3-Butandiol und Amphotensid(en)
DE102010043067.6 2010-10-28

Publications (2)

Publication Number Publication Date
WO2012055582A2 true WO2012055582A2 (fr) 2012-05-03
WO2012055582A3 WO2012055582A3 (fr) 2013-03-07

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PCT/EP2011/058367 WO2012055582A2 (fr) 2010-10-28 2011-05-23 Agents de traitement capillaire comprenant du 3-méthyl-1,3-butanediol et un/des tensioactif(s) amphotère(s)

Country Status (2)

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DE (1) DE102010043067A1 (fr)
WO (1) WO2012055582A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140171351A1 (en) * 2012-12-18 2014-06-19 Kimberly-Clark Worldwide, Inc. Wet wipes including silicone reactive amino containing dimethicone copolyols

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3725030A1 (de) 1987-07-29 1989-02-09 Henkel Kgaa Oberflaechenaktive hydroxysulfonate

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US5136093A (en) 1991-02-06 1992-08-04 Smith Ronald J Quaternized panthenol compounds and their use
JP2912504B2 (ja) * 1992-10-05 1999-06-28 サンスター株式会社 毛髪用洗浄剤組成物
DE4413686C2 (de) 1994-04-20 1996-10-24 Henkel Kgaa Kationische Zuckertenside, Verfahren zu ihrer Herstellung und deren Verwendung
JPH0826944A (ja) * 1994-07-08 1996-01-30 Lion Corp 泡沫エアゾール型毛髪化粧料
JPH08176588A (ja) * 1994-12-26 1996-07-09 Kao Corp 安定なシリコーン乳化物及びそれを含有する液体洗浄剤組成物
JP2002121131A (ja) * 2000-10-16 2002-04-23 Pola Chem Ind Inc 安定なパール感を有する洗浄料
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140171351A1 (en) * 2012-12-18 2014-06-19 Kimberly-Clark Worldwide, Inc. Wet wipes including silicone reactive amino containing dimethicone copolyols
US8987180B2 (en) * 2012-12-18 2015-03-24 Kimberly-Clark Worldwide, Inc. Wet wipes including silicone reactive amino containing dimethicone copolyols
KR20150097566A (ko) * 2012-12-18 2015-08-26 킴벌리-클라크 월드와이드, 인크. 다이메티콘 코폴리올을 함유하는 실리콘 반응성 아미노를 포함하는 습식 티슈
AU2013365880B2 (en) * 2012-12-18 2017-12-14 Kimberly-Clark Worldwide, Inc. Wet wipes including silicone reactive amino containing dimethicone copolyols
KR102122828B1 (ko) * 2012-12-18 2020-06-15 킴벌리-클라크 월드와이드, 인크. 실리콘 반응성 아미노 함유 다이메티콘 코폴리올을 포함하는 습식 티슈

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Publication number Publication date
WO2012055582A3 (fr) 2013-03-07
DE102010043067A1 (de) 2012-05-03

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