WO2012042492A2 - Nouvelle composition pour film transparent conducteur - Google Patents

Nouvelle composition pour film transparent conducteur Download PDF

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Publication number
WO2012042492A2
WO2012042492A2 PCT/IB2011/054283 IB2011054283W WO2012042492A2 WO 2012042492 A2 WO2012042492 A2 WO 2012042492A2 IB 2011054283 W IB2011054283 W IB 2011054283W WO 2012042492 A2 WO2012042492 A2 WO 2012042492A2
Authority
WO
WIPO (PCT)
Prior art keywords
particles
polymer
composition
conductive
dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2011/054283
Other languages
English (en)
French (fr)
Other versions
WO2012042492A3 (fr
Inventor
Stéphane ROGER
Marie Dieudonne
Alexandre Marchat
Philippe Sonntag
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hutchinson SA
Original Assignee
Hutchinson SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hutchinson SA filed Critical Hutchinson SA
Priority to KR20137010858A priority Critical patent/KR20130133766A/ko
Priority to AU2011309701A priority patent/AU2011309701B2/en
Priority to CN2011800564846A priority patent/CN103228729A/zh
Priority to BR112013007408A priority patent/BR112013007408A2/pt
Priority to EP11773888.0A priority patent/EP2622017A2/fr
Priority to US13/876,912 priority patent/US20130309423A1/en
Priority to MX2013003513A priority patent/MX2013003513A/es
Priority to CA 2812618 priority patent/CA2812618A1/fr
Priority to JP2013530845A priority patent/JP2013544904A/ja
Publication of WO2012042492A2 publication Critical patent/WO2012042492A2/fr
Publication of WO2012042492A3 publication Critical patent/WO2012042492A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20—Conductive material dispersed in non-conductive organic material
    • H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/04—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of carbon-silicon compounds, carbon or silicon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/041—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/06—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/04—Charge transferring layer characterised by chemical composition, i.e. conductive
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31507—Of polycarbonate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31533—Of polythioether

Definitions

  • Transparent conductive electrodes having both high transmittance and electrical conductivity properties are currently undergoing considerable development in the field of electronic equipment, this type of electrodes being increasingly used in photovoltaic cells, screens liquid crystal displays, touch screens, organic light-emitting diodes (OLEDs) or polymeric light-emitting diodes (PLEDs).
  • OLEDs organic light-emitting diodes
  • PLEDs polymeric light-emitting diodes
  • compositions disclosed in the documents WO 2006/137846 and US 6,984,341 the latter notably disclosing compositions obtained from aqueous dispersions of polythiophene and of polyanionic compounds, such as polystyrenesulfonates, in the presence of additional additives chosen. among ketals, lactones, carbonates, cyclic oxides, diketones, anhydrides, aminocarbonic acids, phenols and inorganic acids.
  • the application US 2009/0252967 relates to new transparent electrodes comprising a first layer consisting essentially of carbon nanotubes, covered with a second polymeric layer loaded with conductive particles, the electrodes obtained having improved electrical conductivity and roughness.
  • the manufacturing process of these electrodes is nevertheless complex insofar as it requires a step of washing the layer of carbon nanotubes, as well as the application of a second polymeric layer.
  • compositions of the invention are prepared according to a method that is simple to implement, in comparison with the processes described in the prior art, said process not involving additional steps of washing or application of polymeric layers. additional. It is in fact a performance compromise difficult to achieve, all these advantages being obtained without negatively affecting the electrical properties of the film or conductive coating obtained, or even making significant improvements in terms of transparency and conductivity.
  • the flexible or rigid substrate contained in the article as defined according to the invention may be coated with a conductive metal grid, the latter being made of gold, silver or platinum, or a grid of particles and / or self-assembled conductive metal filaments, the latter may be gold, silver or platinum.
  • Said gate may have a thickness of between 0.01 and 1 ⁇ .
  • the conductive metal grid may be deposited using an evaporation technique (PVD-CVD) or a printing technique such as slot-die deposition, doctor blade deposition, or deposition to engraved rolls.
  • the Haze ratio is the ratio of diffuse transmittance to total transmittance. It is measured on 50 x 50 mm specimens, using a Perkin Elmer Lambda 35 spectrophotometer on a UV-visible spectrum [300 nm-900 nm].

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacturing Of Electric Cables (AREA)
  • Conductive Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Non-Insulated Conductors (AREA)
PCT/IB2011/054283 2010-09-29 2011-09-29 Nouvelle composition pour film transparent conducteur Ceased WO2012042492A2 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
KR20137010858A KR20130133766A (ko) 2010-09-29 2011-09-29 전도성 투명 필름용 신규 조성물
AU2011309701A AU2011309701B2 (en) 2010-09-29 2011-09-29 Novel composition for conductive transparent film
CN2011800564846A CN103228729A (zh) 2010-09-29 2011-09-29 用于透明导电膜的新型组合物
BR112013007408A BR112013007408A2 (pt) 2010-09-29 2011-09-29 composição para película transparente condutora
EP11773888.0A EP2622017A2 (fr) 2010-09-29 2011-09-29 Nouvelle composition pour film transparent conducteur
US13/876,912 US20130309423A1 (en) 2010-09-29 2011-09-29 Composition for Conductive Transparent Film
MX2013003513A MX2013003513A (es) 2010-09-29 2011-09-29 Composicion novedosa para pelicula conductora transparente.
CA 2812618 CA2812618A1 (fr) 2010-09-29 2011-09-29 Nouvelle composition pour film transparent conducteur
JP2013530845A JP2013544904A (ja) 2010-09-29 2011-09-29 導電性透明フィルム用の新規組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1003858 2010-09-29
FR1003858A FR2965268B1 (fr) 2010-09-29 2010-09-29 Nouvelle composition pour film transparent conducteur

Publications (2)

Publication Number Publication Date
WO2012042492A2 true WO2012042492A2 (fr) 2012-04-05
WO2012042492A3 WO2012042492A3 (fr) 2012-06-21

Family

ID=44201202

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2011/054283 Ceased WO2012042492A2 (fr) 2010-09-29 2011-09-29 Nouvelle composition pour film transparent conducteur

Country Status (11)

Country Link
US (1) US20130309423A1 (enExample)
EP (1) EP2622017A2 (enExample)
JP (1) JP2013544904A (enExample)
KR (1) KR20130133766A (enExample)
CN (1) CN103228729A (enExample)
AU (1) AU2011309701B2 (enExample)
BR (1) BR112013007408A2 (enExample)
CA (1) CA2812618A1 (enExample)
FR (1) FR2965268B1 (enExample)
MX (1) MX2013003513A (enExample)
WO (1) WO2012042492A2 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102938262A (zh) * 2012-11-20 2013-02-20 上海交通大学 一种透明导电薄膜及其制备方法
WO2013170755A1 (zh) * 2012-05-15 2013-11-21 中国科学院上海有机化学研究所 石墨烯和金属纳米线复合的导电膜、制备方法及其用于制备透明导电膜的用途
FR3012462A1 (fr) * 2013-10-31 2015-05-01 Arkema France Compositions stables de poly (3,4-ethylenedioxythiophene) et de stabilisants anioniques a acidite limitee
JP2016535135A (ja) * 2013-10-31 2016-11-10 アルケマ フランス Ｐｅｄｏｔ−電解質（コ）ポリマーの合成方法

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WO2013087112A1 (de) * 2011-12-15 2013-06-20 Siemens Aktiengesellschaft Verfahren zur herstellung eines glimmschutzes, schnellhärtendes glimmschutzsystem und elektrische maschine
KR101620668B1 (ko) * 2013-09-02 2016-05-12 주식회사 엘지화학 탄소나노물질 함유 수지 조성물 및 플라스틱 성형품
FR3023746B1 (fr) * 2014-07-21 2016-07-29 Univ Paul Sabatier - Toulouse Iii Procede de preparation d'une structure composite stratifiee electriquement conductrice
CN104987610A (zh) * 2015-08-04 2015-10-21 金宝丽科技（苏州）有限公司 一种高韧性透明ps塑胶材料及其制备方法
US11104814B2 (en) 2016-02-15 2021-08-31 Momentive Performance Materials Inc. Primer formulations with improved photostability
JP2018002819A (ja) * 2016-06-30 2018-01-11 倉持　浩 熱可塑性エラストマー混合物およびそれを用いた連続体形成方法
CN106674571B (zh) * 2016-12-14 2020-07-24 乐凯胶片股份有限公司 一种透明导电膜
CN107556741B (zh) * 2017-09-18 2020-05-22 重庆市中光电显示技术有限公司 一种用于触摸屏的防电磁辐射透明材料及其制备方法
WO2019181486A1 (ja) * 2018-03-19 2019-09-26 日本ゼオン株式会社 繊維状炭素ナノ構造体分散液の製造方法および複合材料の製造方法
WO2021131653A1 (ja) * 2019-12-25 2021-07-01 京セラ株式会社 フィルムコンデンサ用誘電体フィルム、これを用いたフィルムコンデンサおよび連結型コンデンサ、ならびにインバータ、電動車輌
US12174464B2 (en) * 2020-07-02 2024-12-24 Purdue Research Foundation Contact lens having sensors and methods for producing the same
TWI767738B (zh) * 2021-06-03 2022-06-11 位速科技股份有限公司 導電油墨樹脂組成物、透明導電膜以及透明導電基板結構及其製作方法
CN113818236B (zh) * 2021-10-27 2022-05-17 四川大学 一种柔性可拉伸电子纤维膜材料及其制备方法
CN114497346B (zh) * 2022-01-27 2025-01-17 南京大学 一种基于喷涂非金属电极的柔性电致动器及其制备方法

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US5766515A (en) 1994-05-06 1998-06-16 Bayer Aktiengessellschaft Conductive coatings
US6984341B2 (en) 2002-01-22 2006-01-10 Elecon, Inc. Mixtures comprising thiophene/anion dispersions and certain additives for producing coatings exhibiting improved conductivity, and methods related thereto
WO2006137846A2 (en) 2004-09-17 2006-12-28 Eastman Kodak Company Coatable conductive polyethylenedioxythiophene with carbon nanotubes
EP2036941A1 (en) 2007-09-13 2009-03-18 Stichting Dutch Polymer Institute Process for the preparation of a conductive polymer composition
WO2009117460A1 (en) 2008-03-19 2009-09-24 E. I. Du Pont De Nemours And Company Electrically conductive polymer compositions and films made therefrom
US20090252967A1 (en) 2008-04-03 2009-10-08 Samsung Electronics, Co., Ltd. Carbon nanotube transparent electrode and method of manufacturing the same
US20100116527A1 (en) 2008-11-12 2010-05-13 Khosla Ajit Electrically conductive, thermosetting elastomeric material and uses therefor
WO2010112680A1 (fr) 2009-03-31 2010-10-07 Hutchinson Films ou revetements transparents conducteurs

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JP2008056765A (ja) * 2006-08-30 2008-03-13 Mitsubishi Rayon Co Ltd カーボンナノチューブ含有構造体及びその製造方法
US8241526B2 (en) * 2007-05-18 2012-08-14 E I Du Pont De Nemours And Company Aqueous dispersions of electrically conducting polymers containing high boiling solvent and additives
KR100917709B1 (ko) * 2007-10-23 2009-09-21 에스케이씨 주식회사 전도성 고분자 용액 조성물을 이용한 고분자 막

Patent Citations (8)

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Publication number Priority date Publication date Assignee Title
US5766515A (en) 1994-05-06 1998-06-16 Bayer Aktiengessellschaft Conductive coatings
US6984341B2 (en) 2002-01-22 2006-01-10 Elecon, Inc. Mixtures comprising thiophene/anion dispersions and certain additives for producing coatings exhibiting improved conductivity, and methods related thereto
WO2006137846A2 (en) 2004-09-17 2006-12-28 Eastman Kodak Company Coatable conductive polyethylenedioxythiophene with carbon nanotubes
EP2036941A1 (en) 2007-09-13 2009-03-18 Stichting Dutch Polymer Institute Process for the preparation of a conductive polymer composition
WO2009117460A1 (en) 2008-03-19 2009-09-24 E. I. Du Pont De Nemours And Company Electrically conductive polymer compositions and films made therefrom
US20090252967A1 (en) 2008-04-03 2009-10-08 Samsung Electronics, Co., Ltd. Carbon nanotube transparent electrode and method of manufacturing the same
US20100116527A1 (en) 2008-11-12 2010-05-13 Khosla Ajit Electrically conductive, thermosetting elastomeric material and uses therefor
WO2010112680A1 (fr) 2009-03-31 2010-10-07 Hutchinson Films ou revetements transparents conducteurs

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013170755A1 (zh) * 2012-05-15 2013-11-21 中国科学院上海有机化学研究所 石墨烯和金属纳米线复合的导电膜、制备方法及其用于制备透明导电膜的用途
CN102938262A (zh) * 2012-11-20 2013-02-20 上海交通大学 一种透明导电薄膜及其制备方法
FR3012462A1 (fr) * 2013-10-31 2015-05-01 Arkema France Compositions stables de poly (3,4-ethylenedioxythiophene) et de stabilisants anioniques a acidite limitee
WO2015063416A3 (fr) * 2013-10-31 2015-06-25 Arkema France Compositions stables de poly (3,4-ethylenedioxythiophene) et de stabilisants anioniques a acidité limitée
CN105899547A (zh) * 2013-10-31 2016-08-24 阿科玛法国公司 包含聚(3,4-亚乙基二氧噻吩)和具有有限酸性的阴离子稳定剂的稳定成分
JP2016535135A (ja) * 2013-10-31 2016-11-10 アルケマ フランス Ｐｅｄｏｔ−電解質（コ）ポリマーの合成方法
KR101818382B1 (ko) 2013-10-31 2018-01-12 아르끄마 프랑스 한정된 산도를 갖는 음이온성 안정화제 및 폴리（３,４-에틸렌디옥시펜）을 포함하는 안정한 조성물
CN105899547B (zh) * 2013-10-31 2018-07-10 阿科玛法国公司 包含聚(3,4-亚乙基二氧噻吩)和具有有限酸性的阴离子稳定剂的稳定成分

Also Published As

Publication number Publication date
KR20130133766A (ko) 2013-12-09
CA2812618A1 (fr) 2012-04-05
AU2011309701A1 (en) 2013-05-02
FR2965268B1 (fr) 2012-09-21
FR2965268A1 (fr) 2012-03-30
US20130309423A1 (en) 2013-11-21
MX2013003513A (es) 2013-10-28
CN103228729A (zh) 2013-07-31
BR112013007408A2 (pt) 2016-07-12
EP2622017A2 (fr) 2013-08-07
JP2013544904A (ja) 2013-12-19
WO2012042492A3 (fr) 2012-06-21
AU2011309701B2 (en) 2015-05-07

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