WO2012036382A2 - 4급 암모늄염 화합물을 유효성분으로 포함하는 정전기 방지 및 항균용 표면처리제 및 이를 이용한 고분자 섬유의 정전기 방지방법 - Google Patents
4급 암모늄염 화합물을 유효성분으로 포함하는 정전기 방지 및 항균용 표면처리제 및 이를 이용한 고분자 섬유의 정전기 방지방법 Download PDFInfo
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- WO2012036382A2 WO2012036382A2 PCT/KR2011/005865 KR2011005865W WO2012036382A2 WO 2012036382 A2 WO2012036382 A2 WO 2012036382A2 KR 2011005865 W KR2011005865 W KR 2011005865W WO 2012036382 A2 WO2012036382 A2 WO 2012036382A2
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- WO
- WIPO (PCT)
- Prior art keywords
- quaternary ammonium
- antistatic
- ammonium salt
- surface treatment
- polymer fiber
- Prior art date
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Definitions
- the present invention relates to an antistatic and antimicrobial surface treatment agent comprising a quaternary ammonium salt compound as an active ingredient and an antistatic method of polymer fibers using the surface treatment agent.
- Antistatic materials are used to dissipate static or static charges, and enhancement of electrostatic charging is associated with various problems in the processing and use of many industrial supplies and materials. Electrostatic charging can cause materials to stick together or to repel one another. In addition, the build-up of electrostatic charging may cause dirt and dust to adhere to the object may cause manufacturing problems and contamination problems, and may damage the performance of the product.
- Electrostatic charge enhancement can be controlled by increasing the electrical conductivity of the material. This can be achieved by increasing the ionic conductivity or the electrical conductivity.
- the most common means of controlling static accumulation is to increase electrical conductivity through moisture adsorption. This is typically accomplished by adding moisture to the ambient air or by using a hygroscopic antistatic agent, commonly referred to as a humectant. Most antistatic agents work by dissipating static charge when static charge is enhanced.
- Known antistatic agents include organic amines and amides, esters of fatty acids, organic acids, polyoxyethylene derivatives, polyhydric alcohols, metals, carbon blacks, semiconductors, and a wide variety of compounds including various organic and inorganic salts. Also included are a number of surfactants, which may be neutral or ionic in nature.
- nonmetallic antistatic materials are wetting agents that rely on the adsorption and conduction of moisture for dissipation of charge. Therefore, when the humidity in the air is low, their effectiveness usually decreases. In addition, since many of these antistatic agents are water-soluble, they are easily removed when the material is exposed to moisture, resulting in poor durability.
- Metal salts of inorganic, organic and fluoroorganic anions are also useful as antistatic agents in certain polymer compositions.
- Alkali metal salts are most commonly used in terms of cost and toxicity, and because of their high affinity for alkali metal cations, especially lithium, for water.
- most metal salts are incompatible with polymers of medium to low polarity, such as polypropylene, polyester and polycarbonate. Such compatible members can improperly perform the performance of the antistatic material, unacceptably degrade the physical properties, or unacceptably reduce the transparency of the finished polymeric article. Consequently, the use of metal salts as antistatic agents for internal use is generally limited to highly polar or high hydrophilic polymer matrices.
- the present inventors newly found quaternary ammonium salt compounds useful as antistatic agents and antibacterial agents, and completed the present invention by discovering that the quaternary ammonium salt compounds can be treated with fibers to prevent or improve static electricity of the fibers. .
- An object of the present invention is to provide a novel quaternary ammonium salt compound for antistatic and antibacterial that can prevent or improve the static electricity of the fiber.
- Another object of the present invention is to provide an antistatic method of polymer fibers, characterized in that the quaternary ammonium salt compound is treated with fibers.
- the present invention provides a surface treatment agent for antistatic and antibacterial comprising a quaternary ammonium salt compound represented by the following formula (1) as an active ingredient:
- R 1 is a functional group containing one or more double bonds and is selected from alkenyl of C2 to C32, alkylacryloyl of C1 to C32, or alkylmethacryloyl of C1 to C32,
- R 2 to R 4 are the same as or different from each other and do not include or include a double bond, C1 to C32 alkyl or hydroxyalkyl, C6 to C32 aryl, C7 to C32 benzyl, C2 to C32 alkenyl ), C1 to C32 alkylacryloyl, C1 to C32 alkylmethacryloyl, or a combination thereof, the carbon chains may include covalent bonds in the molecule with ester, amide, ether, sulfide, urethane or urea bonds.
- X is F, Cl, Br, I, CN, NO 3 , CH 3 COO, CF 3 COO, OH, ClO, ClO 2 , ClO 3 , SCN, ClO 4 , HCO 3 , H 2 PO 4 , BF 4 , TFSI , CF 3 SO 3 or CH 3 SO 3 It can be selected.
- the quaternary ammonium salt compound according to the present invention has excellent antistatic effect and antibacterial effect to prevent or improve the generation of static electricity of the polymer fiber
- the quaternary ammonium salt compound is treated to the polymer fiber with a fabric softener, an antistatic agent, etc. It can prevent or improve the generation of static electricity and can also be very useful for improving the antimicrobial properties of polymer fibers.
- the present invention provides an antistatic and antibacterial surface treatment agent comprising a quaternary ammonium salt compound represented by the following Chemical Formula 1 as an active ingredient:
- R 1 is a functional group containing one or more double bonds and is selected from alkenyl of C2 to C32, alkylacryloyl of C1 to C32, or alkylmethacryloyl of C1 to C32,
- R 2 to R 4 are the same as or different from each other and do not include or include a double bond, C1 to C32 alkyl or hydroxyalkyl, C6 to C32 aryl, C7 to C32 benzyl, C2 to C32 alkenyl ), C1 to C32 alkylacryloyl, C1 to C32 alkylmethacryloyl, or a combination thereof, the carbon chains may include covalent bonds in the molecule with ester, amide, ether, sulfide, urethane or urea bonds.
- X is F, Cl, Br, I, CN, NO 3 , CH 3 COO, CF 3 COO, OH, ClO, ClO 2 , ClO 3 , SCN, ClO 4 , HCO 3 , H 2 PO 4 , BF 4 , TFSI , CF 3 SO 3 or CH 3 SO 3 It can be selected.
- the quaternary ammonium salt compound is preferably R 1 is allyl, R 2 to R 4 is ethyl, X is Br or Cl.
- the quaternary ammonium salt compound according to the present invention can provide not only an antistatic effect, but also an antibacterial effect.
- the present invention provides a method for preventing the static discharge of polymer fibers, comprising the step of treating the polymer fibers with a surface treatment agent comprising a quaternary ammonium salt compound represented by the formula (1) as an active ingredient.
- the antistatic method according to the present invention comprises the steps of dipping the polymer fibers in a solvent; And treating and reacting the polymer fiber with a surface treatment agent and a reaction catalyst comprising a quaternary ammonium salt compound represented by Formula 1 as an active ingredient.
- the antistatic method according to the present invention comprises the step of treating the polymer fiber to the surface treatment mixture containing a solvent, a quaternary ammonium salt compound represented by the formula (1) as an active ingredient and a surface treatment mixture including a reaction catalyst and reacting. .
- cerium ammonium nitrate CAN
- Tertiary amine-based basic catalysts such as DBU (1,8-diazabicyclo [5.4.0] undec-7-ene), DMAP (4-N, N-dimethylaminopyridine), 3-HQD (3-hydroxyquinyclidine), 1,2,2,6,6-pentamethylpiperidine (1,2,2,6,6-pentamethylpiperidine), triethylamine (TEA), etc .
- Acidic catalysts such as (CF 3 SO 2 ) 2 NH, Para-Toluenesulfonic Acid (PTSA), triflic acid, HCl, CH 3 SO 3 H, and the like
- Organometallic catalysts such as Rh compounds, Pd compounds, Zn compounds, Cu compounds, Ni compounds, Bi compounds, La compounds and the like
- Pro-azaphosphatranes-based catalysts Trialkylphosphines-based catalysts
- the quaternary ammonium salt compound is preferably treated with 0.1 to 50 parts by weight with respect to 100 parts by weight of the polymer fiber, and if it is treated in excess of the above range, the thermal stability is lowered and the mechanical properties are lowered. This can cause problems such as a decrease in warmth, and a small amount of treatment can cause problems that are not effective antistatic.
- reaction catalyst is preferably treated with 0.01 to 20 parts by weight with respect to 100 parts by weight of the polymer fiber, if the treatment in excess of the above range may cause the residual catalyst or discoloration of the fiber after washing, Small amounts of treatment can cause the problem that sufficient quaternary ammonium salts are not grafted or covalently attached to the fibers.
- any solvent may be used as long as it can wet or dissolve the polymer fibers and dissolve the reaction catalyst.
- the reaction catalyst may be reacted by treating at 5 to 100 ° C., preferably at room temperature.
- the antistatic method according to the present invention is carried out before or after the step of treating the surface treating agent to the polymer fibers, or (i) treatment of a reaction catalyst such as cerium ammonium nitrate (DBU), (ii) gamma irradiation, (iii) Forming a radical of the polymer fiber according to any one of E-beam irradiation, (iv) ion-beam irradiation (v) deep UV radiation or (vi) plasma treatment.
- a reaction catalyst such as cerium ammonium nitrate (DBU),
- DBU cerium ammonium nitrate
- gamma irradiation gamma irradiation
- Forming a radical of the polymer fiber according to any one of E-beam irradiation iv) ion-beam irradiation (v) deep UV radiation or (vi) plasma treatment.
- the antistatic method according to the present invention comprises i) treatment of the reaction catalyst, (ii) gamma irradiation, (iii) E-beam irradiation, (iv) ion-beam irradiation, (v) deep UV Forming radicals of the polymer fibers according to any one selected from a) treatment or (vi) plasma treatment; And adding a surface treatment agent containing a quaternary ammonium salt compound represented by Formula 1 as an active ingredient to the radical of the polymer fiber to form a double bond and a covalent bond of the quaternary ammonium salt, or to several radicals of one fiber (Graft) radical polymerization of the ammonium salt molecule.
- a surface treatment agent containing a quaternary ammonium salt compound represented by Formula 1 as an active ingredient to the radical of the polymer fiber to form a double bond and a covalent bond of the quaternary ammonium salt, or to several radicals of one fiber (Graft) radical polymer
- the fiber used in the present invention may be a natural fiber or a synthetic fiber, in particular may be a polymer fiber having a hydroxyl group, an amine group or an imine group, but is not limited thereto.
- ABTEA 0.1 mol of allybromide and 0.105 mol of triethylamine were added to 100 mL of THF and stirred at 40 ° C. for one day.
- the synthesized ABTEA precipitated as a white solid, and washed the precipitated ABTEA with THF several times to remove the remaining reactants and stabilizers without reacting.
- the chargeability of the surface-treated polymer fiber as in Example 2 was requested by the Korea Fiber Research Institute and measured according to JIS L 1094 (friction large voltage measurement method), and the results are shown in Table 1 below.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
처리직물 | 마찰포 | 대전압(V) | 암모늄염 종류 | |||||
변수 : 무게비 | 50% | 25% | 10% | 5% | 2% | |||
모직물 | 면 | 경사 | 10 | 30 | 1030 | 2090 | 3420 | ABTEA |
위사 | 10 | 50 | 1180 | 3200 | 3380 | |||
모 | 경사 | 10 | 10 | 160 | 1220 | 1620 | ||
위사 | 0 | 20 | 390 | 1750 | 1860 | |||
면 | 경사 | 10 | ACTEA | |||||
위사 | 10 | |||||||
모 | 경사 | 10 | ||||||
위사 | 10 | |||||||
면 | 경사 | 80 | E2M | |||||
위사 | 70 | |||||||
모 | 경사 | 10 | ||||||
위사 | 10이하 | |||||||
마찰포 | 대전압(V) | E2M50% | ||||||
변수: 시간(분) | 1분 | 5분 | 10분 | 30분 | 60분 | |||
면 | 경사 | 80 | 80 | 130 | 130 | 120 | ||
위사 | 70 | 20 | 70 | 90 | 60 | |||
모 | 경사 | 10 | 10이하 | 60 | 150 | 130 | ||
위사 | 10이하 | 10이하 | 10이하 | 70 | 110 |
마찰포 | 대전압(V) | 비고 | |||||
변수 : 시간 | 20 min | 40 min | 1hr | 2hr | 4hr | ||
면 | 경사 | 6160 | 8750 | 3410 | 2780 | 1960 | E2M 사용실시예 3 |
위사 | 4510 | 8780 | 4910 | 6050 | 4640 | ||
모 | 경사 | 8400 | 7260 | 9930 | 7860 | 3860 | |
위사 | 8680 | 5480 | 11620 | 4000 | 2690 |
마찰포 | 대전압(V) | 비고 | |||
변수 : 섬유 | 실크 | 나일론 | 모직물 | ||
면 | 경사 | 10이하 | 10이하 | 10이하 | E2M 사용 실시예 4 |
위사 | 10이하 | 10이하 | 10이하 | ||
모 | 경사 | 10이하 | 10이하 | 10이하 | |
위사 | 10이하 | 10이하 | 10이하 |
Claims (6)
- 하기 화학식 1로 표시되는 4급 암모늄염 화합물을 유효성분으로 포함하는 정전기 방지 및 항균용 표면처리제:[화학식 1]상기 화학식 1에서,R1은 이중 결합을 한 개 이상 포함하는 기능기로서, C2 내지 C32의 알케닐(alkenyl), C1 내지 C32의 알킬아크릴로일 또는 C1 내지 C32의 알킬메타크릴로일 중에서 선택되고,R2 내지 R4는 각각 같거나 다르며, 이중 결합을 포함하거나 포함하지 않으며, C1 내지 C32의 알킬 또는 하이드록시알킬, C6 내지 C32의 아릴, C7 내지 C32의 벤질, C2 내지 C32의 알케닐(alkenyl), C1 내지 C32의 알킬아크릴로일, C1 내지 C32의 알킬메타크릴로일, 또는 이들의 조합으로서 탄소사슬들은 에스테르, 아마이드, 에테르, 설파이드, 우레탄 또는 우레아 결합이 분자 내에 공유결합으로 포함되어 있을 수 있으며,X는 F, Cl, Br, I, CN, NO3, CH3COO, CF3COO, OH, ClO, ClO2, ClO3, SCN, ClO4, HCO3, H2PO4, BF4, TFSI, CF3SO3 또는 CH3SO3 중에서 선택됨.
- 청구항 1에 따른 표면처리제를 고분자 섬유에 처리하는 단계를 포함하는 고분자 섬유의 정전기 방지방법.
- 청구항 2에 있어서, 상기 정전기 방지방법은 고분자 섬유를 용매에 담그는 단계; 및 상기 고분자 섬유에 청구항 1에 따른 표면처리제 및 반응촉매를 처리하여 반응시키는 단계를 포함하는 것을 특징으로 하는 고분자 섬유의 정전기 방지방법.
- 청구항 3에 있어서, 상기 반응촉매는 실온에서 처리하여 반응시키는 것을 특징으로 하는 고분자 섬유의 정전기 방지방법.
- 청구항 2에 있어서, 상기 청구항 1에 따른 표면처리제를 고분자 섬유에 처리하는 단계 이전에 (i) 반응촉매의 처리, (ii) 감마선 조사, (iii) E-빔 조사, (iv) 이온-빔 조사 (v) 원자외선(deep UV) 조사 또는 (vi) 플라즈마 처리 중에서 선택된 어느 하나의 처리에 따라 고분자 섬유의 라디칼을 형성시키는 단계를 추가로 포함하는 것을 특징으로 하는 고분자 섬유의 정전기 방지방법.
- 청구항 5에 있어서, 상기 정전기 방지방법은 (i) 반응촉매의 처리, (ii) 감마선 조사, (iii) E-빔 조사, (iv) 이온-빔 조사, (v) 원자외선(deep UV) 처리 또는 (vi) 플라즈마 처리 중에서 선택된 어느 하나의 처리에 따라 고분자 섬유의 라디칼을 형성시키는 단계; 및 상기 고분자 섬유의 라디칼에 청구항 1에 따른 표면처리제를 처리하여 섬유의 라디칼 하나에 4급 암모늄 분자 하나를 공유 결합시키거나, 하나의 라디칼에 여러 개의 4급 암모늄 분자를 라디칼 중합시키는 단계를 포함하는 것을 특징으로 하는 고분자 섬유의 정전기 방지방법.
Priority Applications (2)
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JP2013529045A JP2013542332A (ja) | 2010-09-16 | 2011-08-10 | 4級アンモニウム塩化合物を有効成分として含む静電気防止及び抗菌用表面処理剤、並びにそれを利用した高分子繊維の静電気防止方法 |
US13/824,130 US9029602B2 (en) | 2010-09-16 | 2011-08-10 | Anti-microbial and anti-static surface treatment agent with quaternary ammonium salt as active ingredient and method for preventing static electricity in polymer fibers using same |
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KR10-2010-0091109 | 2010-09-16 | ||
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KR1020110036313A KR101227761B1 (ko) | 2010-09-16 | 2011-04-19 | 4급 암모늄염 화합물을 유효성분으로 포함하는 정전기 방지 및 항균용 표면처리제 및 이를 이용한 고분자 섬유의 정전기 방지방법 |
KR10-2011-0036313 | 2011-04-19 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103397509A (zh) * | 2013-08-07 | 2013-11-20 | 武汉纺织大学 | 一种抗菌吸液纱布的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4822529A (en) * | 1984-10-31 | 1989-04-18 | Takemoto Yushi Kabushiki Kaisha | Antistatic agents for synthetic fibers and methods of producing same |
JP2005154645A (ja) * | 2003-11-27 | 2005-06-16 | Lion Corp | 帯電防止剤組成物 |
KR20070113365A (ko) * | 2006-05-23 | 2007-11-29 | 한국원자력연구원 | 방사선 그라프트 중합법을 이용한 항균성 섬유 제조방법 및항균성 섬유 |
KR100797098B1 (ko) * | 2006-11-23 | 2008-01-22 | 요업기술원 | 항균 섬유 가공제 조성물, 및 상기 조성물로 처리된 기능성섬유 |
-
2011
- 2011-08-10 WO PCT/KR2011/005865 patent/WO2012036382A2/ko active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4822529A (en) * | 1984-10-31 | 1989-04-18 | Takemoto Yushi Kabushiki Kaisha | Antistatic agents for synthetic fibers and methods of producing same |
JP2005154645A (ja) * | 2003-11-27 | 2005-06-16 | Lion Corp | 帯電防止剤組成物 |
KR20070113365A (ko) * | 2006-05-23 | 2007-11-29 | 한국원자력연구원 | 방사선 그라프트 중합법을 이용한 항균성 섬유 제조방법 및항균성 섬유 |
KR100797098B1 (ko) * | 2006-11-23 | 2008-01-22 | 요업기술원 | 항균 섬유 가공제 조성물, 및 상기 조성물로 처리된 기능성섬유 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103397509A (zh) * | 2013-08-07 | 2013-11-20 | 武汉纺织大学 | 一种抗菌吸液纱布的制备方法 |
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