WO2012029663A1 - Nitrogen-treated-water generating device, nitrogen-treated-water generating method, nitrogen-treated water, and processing method for maintaining freshness of fresh fishery products processed by means of nitrogen-treated water - Google Patents
Nitrogen-treated-water generating device, nitrogen-treated-water generating method, nitrogen-treated water, and processing method for maintaining freshness of fresh fishery products processed by means of nitrogen-treated water Download PDFInfo
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- WO2012029663A1 WO2012029663A1 PCT/JP2011/069322 JP2011069322W WO2012029663A1 WO 2012029663 A1 WO2012029663 A1 WO 2012029663A1 JP 2011069322 W JP2011069322 W JP 2011069322W WO 2012029663 A1 WO2012029663 A1 WO 2012029663A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
- B01F23/23313—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements through a separate conduit substantially parallel with the stirrer axis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F21/00—Dissolving
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
- B01F23/2323—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2334—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements provided with stationary guiding means surrounding at least partially the stirrer
- B01F23/23341—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements provided with stationary guiding means surrounding at least partially the stirrer with tubes surrounding the stirrer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2335—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the direction of introduction of the gas relative to the stirrer
- B01F23/23353—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the direction of introduction of the gas relative to the stirrer the gas being sucked towards the rotating stirrer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2336—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer
- B01F23/23362—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer the gas being introduced under the stirrer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2376—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
- B01F23/23765—Nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/421—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path
- B01F25/422—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path between stacked plates, e.g. grooved or perforated plates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
- B01F25/53—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle in which the mixture is discharged from and reintroduced into a receptacle through a recirculation tube, into which an additional component is introduced
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/25—Mixers with both stirrer and drive unit submerged in the material being mixed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/27—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices
- B01F27/271—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed radially between the surfaces of the rotor and the stator
- B01F27/2712—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed radially between the surfaces of the rotor and the stator provided with ribs, ridges or grooves on one surface
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
Definitions
- the present invention mixes treated water for treating fresh fish and shellfish and refined nitrogen gas to reduce the amount of dissolved oxygen in the treated water, and also contains the refined nitrogen gas in the treated water.
- the apparatus which can produce
- the present invention relates to an apparatus that can generate the method, a method for generating the nitrogen-treated water, the nitrogen-treated water, and a method for maintaining freshness of fresh fish and shellfish processed with the nitrogen-treated water.
- the nitrogen-treated water can be used not only for maintaining the freshness of fresh fish and shellfish but also for cleaning the pipe.
- the treated water tap water, seawater, salt water (water having a salt concentration of 2.8% to 4% by adding an appropriate amount of brine) can be used as the treated water.
- Patent Document 1 discloses a nitrogen gas cylinder that supplies nitrogen gas, a processing water tank that stores processing water used for processing pickles of fresh food together with fresh food to be processed, and nitrogen supplied from the nitrogen gas cylinder.
- a processing water production apparatus comprising a nitrogen gas dissolver that dissolves gas in the processing water in the processing water tank is disclosed. And according to this processed water manufacturing apparatus, processed water with a low amount of dissolved oxygen can be provided.
- the amount of dissolved oxygen in water decreases from 499 DO to 1,36 DO by injecting nitrogen gas into water, but it takes 3 hours to decrease to that level. It takes 30 minutes. During this 3 hours and 30 minutes, nitrogen gas is continuously injected into the water at 0.2 Pascal continuously. This means that even if the amount of dissolved oxygen in water decreases, the amount of dissolved oxygen in the water is unnecessarily large, and the efficiency of reducing the amount of dissolved oxygen in water is not necessarily good. There will be no.
- the present invention can greatly improve the efficiency of reducing the amount of dissolved oxygen in the treated water and can produce nitrogen treated water containing refined nitrogen gas.
- An object is to provide a device, a method for generating the nitrogen-treated water, the nitrogen-treated water, and a method for maintaining freshness of fresh seafood using the nitrogen-treated water.
- a nitrogen treated water generating apparatus provides a circulation channel for circulating a fluid, a tank provided in the middle of the circulation channel for containing treated water, and supplying nitrogen gas to the treated water flowing out of the tank
- the nitrogen gas supply part connected to the middle part of the circulation channel, and the nitrogen gas supplied from the nitrogen gas supply part and the gas-liquid mixed phase of the treated water are subjected to a shearing force, so that the nitrogen gas is converted into ultrafine bubbles.
- a fluid mixing treatment section provided in the middle of the circulation channel to mix with the treated water as a bubble group having a bubble group, and the treated water mixed with the bubble group flowing out from the fluid mixing treatment section is circulated into the tank.
- the oxygen dissolved in the treated water in the tank is diffused into the nitrogen gas in the form of fine bubbles, so that the fine nitrogen gas from which oxygen has diffused floats up in the treated water and escapes from the treated water. It is characterized by letting .
- the fluid mixing treatment unit causes the pair of plate-like mixing elements extending along the circulation flow path to face the polymerized state, and between the mixing elements.
- the mixing channel extending in the extending direction is formed, and the inflow hole formed on one side of the mixing element is connected to the start end of the mixing channel, while the end of the mixing channel is connected to the other side of the mixing element.
- the formed outflow hole is configured to communicate with each other, and the mixing flow path includes a plurality of flow dividing sections that flow the fluid flowing in from the inflow hole in the extending direction of the mixing flow path to be divided, and the fluid divided by the flow dividing section And a plurality of merging portions that join together by flowing in the extending direction of the mixing channel.
- a start-side temporary residence space is formed between the start end of the mixing flow path and the inflow hole formed in one side of the mixing element,
- the start-side temporary retention space is formed to have substantially the same width as the start end of the mixing channel and communicates with the start end of the mixing channel over substantially the entire width, while the end of the mixing channel and the other side of the mixing element.
- a terminal-side temporary residence space is formed between the formed outflow holes, and the terminal-side temporary residence space is formed to have substantially the same width as the terminal end of the mixing channel and communicates with the terminal part of the mixing channel over substantially the entire width. It was made to be characterized.
- the nitrogen treated water generating method according to the second invention is a nitrogen gas in which a shearing force is applied to a gas-liquid mixed phase of treated water and nitrogen gas to form a group of bubbles having ultrafine bubbles and mix with the treated water.
- an oxygen escape step for allowing the fine nitrogen gas from which oxygen has been released to float in the treated water and to escape from the treated water.
- the nitrogen-treated water according to the third aspect of the present invention mixes nitrogen gas, which has become a group of bubbles having ultrafine bubbles, with the treated water and accommodates it in the tank, and oxygen dissolved in the treated water in the tank. It is characterized in that the fine nitrogen gas from which oxygen is diffused is floated in the treated water by being diffused into the nitrogen gas formed into fine bubbles, and is generated by escaping from the treated water.
- the freshness-keeping method for fresh seafood is a method of mixing nitrogen gas, which has become a group of bubbles having ultrafine bubbles, with treated water and storing it in a tank, and dissolving it in the treated water in the tank.
- nitrogen gas which has become a group of bubbles having ultrafine bubbles
- the fine nitrogen gas from which oxygen has been released floats up in the treated water, and escapes from the treated water to produce nitrogen treated water. It is characterized by immersing fresh seafood in the treated water for a certain period of time.
- fresh seafood processed by immersing in nitrogen-treated water for a certain period of time is stored in a storage bag, and the storage bag is degassed and sealed, and refrigerated in the degassed / sealed state. It can also be processed.
- fresh fish and shellfish treated by immersing in nitrogen-treated water for a certain period of time can be frozen while being immersed in nitrogen-treated water.
- the amount of nitrogen on the gas phase is enormous, the amount of released oxygen is negligibly small, and if the oxygen partial pressure in the gas phase is apparently kept at 0, oxygen in the water disappears (dissolved oxygen concentration 0) The release of oxygen continues. Nitrogen is absorbed into water by contact with pure nitrogen, and the nitrogen concentration in water increases to 19.4 mg / L.
- gas_flowing of nitrogen to water It is set as the bubble group in a continuous phase (liquid) as a gas-liquid contact form.
- the liquid is water having a dissolved oxygen concentration of DO 0 , and the bubbles are considered to be gas-liquid contact with pure nitrogen bubbles. Since the oxygen partial pressure in pure nitrogen is 0, oxygen is diffused from the liquid into the bubbles. In other words, dissolved oxygen is taken into nitrogen bubbles (oxygen dissipation). Since the volume of the bubble is finite, the oxygen partial pressure in the bubble increases as oxygen is released.
- Bubbles in which oxygen is released rise in the liquid and eventually escape from the liquid (bubble disappearance), but if the liquid is deep enough, while the bubbles stay in the liquid, Equilibrium (gas-liquid equilibrium) is established between the oxygen partial pressure and the oxygen concentration in the liquid (water). At that time, the release of oxygen stops. However, the liquid depth is not so great that the bubbles stay until gas-liquid equilibrium is established. Rather, in the water phase at a realistic depth, the bubbles (bubbles larger in diameter than nanobubbles) are liquid before the gas-liquid equilibrium is reached. Escape from.
- water with dissolved oxygen concentration DO 0 is continuously supplied to the fluid mixing unit at a flow rate Li [m 3 / h] and pure nitrogen is supplied at a flow rate Ga [m 3 / h]. If the dissolved oxygen is diffused into the nitrogen bubble group by forming a gas-liquid two-phase flow in which water is dispersed, water with a reduced dissolved oxygen concentration (dissolved oxygen concentration DO) can be continuously generated in one pass.
- the decrease rate DO / DO 0 of the dissolved oxygen concentration varies depending on the ratio Ga / Li (gas-liquid ratio) of the water flow rate Li and the nitrogen flow rate Ga when the design variable of the fluid mixing processing unit is constant (Hidehiro Kumazawa, Niimi) Tomio: Food and Development, Vol.33, No.3, pp.54-55 (1998). "Development of new mixing and dispersion processes in food processing and manufacturing and new static mixers. Lamond Stirler VIII. Lamond. Application of supermixer to gas-liquid mixing and dispersion (2)-diffusion "). As the gas / liquid ratio increases, the dissolved oxygen residual ratio DO / DO 0 decreases (decrease rate 1 ⁇ DO / DO 0 increases).
- Nitrogen nanobubbles (nanobubbleized nitrogen gas)
- the nitrogen nanobubbles are not limited to the surface of fresh foods, for example, seafood, but are effective in the body, so the aerobic properties in the body are reduced. Therefore, it is expected that at least the growth of aerobic bacteria in the body is suppressed.
- Nitrogen-treated water containing nitrogen nanobubbles significantly suppresses the growth of aerobic bacteria that inhabit the body as well as the surface of fish and shellfish, and maintains the freshness of fish and shellfish (this is an indicator of the freshness of fish and shellfish K value can be kept low).
- the K value is the ratio of inosine (HxR) and hypoxanthine (Hx) in the entire ATP-related compound. Since ATP of fish meat is decomposed by the route of ATP ⁇ ADP ⁇ AMP ⁇ IMP ⁇ HxR ⁇ Hx after death, the lower the ratio of HxR or Hx, the better the freshness.
- the K value suitable for sashimi is 20% or less.
- the present invention has the following effects. That is, the present invention is to ventilate nitrogen gas into treated water for treating fresh food, etc., and form nitrogen gas into a group of bubbles having ultrafine bubbles (nanobubbles), so that oxygen dissolved in the treated water is reduced. It is diffused into nitrogen gas that has become fine bubbles (larger than nanobubbles), and the fine nitrogen gas from which oxygen has diffused floats up in the treated water and escapes from the treated water (deoxygenated). Nitrogen-treated water in which nitrogen gas in the form of bubbles (nanobubbles) is mixed (contained) in the treated water can be generated.
- the efficiency of reducing the amount of dissolved oxygen in the treated water is greatly improved (for example, the amount of dissolved oxygen (DO value) in 800 liters of treated water is drastically reduced to less than 1.0 (mg / L) in 25 minutes).
- nitrogen-treated water containing nitrogen nanobubbles and having a reduced amount of dissolved oxygen can be applied not only to the surface of fresh food, for example, seafood, but also to the body, thereby reducing the aerobic properties of the body.
- the nitrogen-treated water containing nitrogen nanobubbles significantly suppresses the growth of aerobic bacteria that live not only on the surface of fish and shellfish but also in the body, maintaining the freshness of fish and shellfish (an index of freshness of fish and shellfish) (K value which is a value is kept low).
- Nitrogen nanobubbles are mixed (contained) in nitrogen-treated water for a long time because the particle size is too small. Over time, nitrogen in nitrogen nanobubbles is dissolved in nitrogen-treated water, The amount of nitrogen dissolved can be brought into a supersaturated state.
- the conceptual explanatory drawing of the nitrogen treated water generating device as a 1st embodiment concerning the present invention.
- generation apparatus as 1st Embodiment which concerns on this invention.
- the conceptual explanatory drawing of the nitrogen treated water generating device as a 2nd embodiment concerning the present invention.
- FIG. 14 is a bottom view taken along line I-I in FIG. 13.
- FIG. 14 is a plan view taken along line II-II in FIG. 13.
- FIG. 3 is a partially cutaway explanatory view of a fluid stirring unit as the first embodiment. Explanatory drawing of the cross section of the III-III line direction view of FIG. FIG.
- FIG. 26 is a cross-sectional plan view taken along line IV-IV in FIG. 25.
- FIG. 26 is a cross-sectional plan view of the VV line direction view of FIG. 25.
- Explanatory drawing of the bottom face of a movable side stirring body Plane explanatory drawing of a stationary side stirring body.
- Bottom explanatory drawing which shows the basic form of both stirring bodies.
- FIG. 32 is a cross-sectional explanatory view taken along line VI-VI in FIG. 31. Partial cutaway explanatory drawing of the fluid stirring part as 2nd Embodiment.
- Cross-sectional side explanatory drawing of the middle part of a fluid stirring part Cross-sectional side explanatory drawing of the lower part of a fluid stirring part.
- FIG. 34 is a cross-sectional plan view taken along line VII-VII in FIG. 33.
- FIG. 34 is an explanatory bottom view of a cross section taken along line VIII-VIII in FIG. 33.
- FIG. 34 is an explanatory cross-sectional bottom view taken along the line IX-IX in FIG. 33. Bottom explanatory drawing which shows the basic form of both stirring bodies.
- a shown in FIG. 1 is a nitrogen treated water generator as a first embodiment according to the present invention.
- the nitrogen treated water generator A connects the base end of the circulation pipe J to the bottom of the tank T containing the treated water W, and inserts the tip of the circulation pipe J into the treated water W in the tank T from above.
- the circulation flow path R is formed.
- the treated water W is a solvent that dissolves pure nitrogen gas (for example, high-purity nitrogen gas having a concentration of 99.99% or higher) to form low-concentration oxygen-treated water (high-concentration nitrogen-treated water).
- Tap water, sea water, salt water, etc. can be used.
- the salt water is obtained by adding an appropriate amount of brine to a salt concentration of 2.8% to 4%. For example, salt water having a salt concentration of about 3.5% can be applied.
- a pressure feed pump P is attached in the middle of the circulation pipe J, and a nitrogen gas supply portion N for supplying pure nitrogen gas is provided in the middle of the circulation pipe J located in the vicinity of the suction port (right upstream side) of the pressure feed pump P. It is connected.
- Pure nitrogen gas supplied into the treated water W from the nitrogen gas supply unit N can be sucked into the pressure pump P from the suction side of the pressure pump P by the ejector effect.
- the intake amount of pure oxygen gas can be set to about 3% (STP; 0 ° C., 1 atm) of the circulating flow rate of the treated water W flowing in the circulation pipe J.
- a nitrogen gas supply unit N is connected to the middle part of the circulation pipe J located in the vicinity of the discharge port of the pressure pump P (directly downstream), and pure nitrogen gas is pumped from the nitrogen gas supply unit N into the circulation pipe J.
- the supply amount of the pure nitrogen gas can be set to a predetermined amount that is larger than the above-described intake amount of the pure nitrogen gas.
- a fluid mixing processing unit M that mixes gas and liquid, which are fluids, is provided in the present embodiment.
- the fluid mixing treatment unit M causes a high shear force to be applied to the treated water W forming a cluster of several water molecules by causing the gas-liquid mixed phase of the treated water W and pure nitrogen gas to flow in the meandering flow path. It is made to be a modified treated water having a smaller cluster size of the treated water W, and a high shear force is applied to the gas-liquid mixed phase of the modified treated water and pure nitrogen gas to modify the solvent.
- Low concentration oxygen treated water (high concentration nitrogen treated water) in which pure nitrogen gas is dissolved in treated water is used.
- the nitrogen treated water generator A is provided with a treated water supply unit K that can supply treated water W as a solvent as needed in the tank T.
- a pressure regulating valve V is attached to the tip of the circulation pipe J.
- the circulation pipe J is provided with a heat exchanger H located on the downstream side of the gas-liquid mixing processing unit M, and the high-concentration oxygen-treated water generated in the gas-liquid mixing processing unit M by the heat exchanger H. Is set to a predetermined low temperature (for example, 1 ° C. to 5 ° C.), and high concentration oxygen treated water at a predetermined low temperature is recovered by a recovery unit G disposed downstream thereof.
- the circulation pipe J is provided with a three-way switching valve Va positioned downstream of the heat exchanger H, and the high-concentration oxygen-treated water is circulated through the circulation pipe J by switching operation of the three-way switching valve Va. It is possible to circulate a predetermined number of times (for example, 20 times) or a predetermined time (for example, 25 minutes) in the R, and to send it to the recovery unit G through the recovery pipe Jb.
- the tank T is provided with dissolved oxygen amount detection means D, and the dissolved oxygen amount detection means D detects the dissolved oxygen amount (DO value) of the treated water W in the tank T.
- the tank T is provided with a temperature detection means Ta, and the temperature detection means Ta detects the temperature of the treated water W in the tank T.
- the nitrogen treated water generator A is provided with a control means C shown in FIG.
- the control means C has a control function like a personal computer or the like, and connects the dissolved oxygen amount detection means D and the temperature detection means Ta to its input side interface, while treating the treated water supply unit K to its output side interface.
- a nitrogen gas supply unit N a pressure pump P, a heat exchanger H, a pressure regulating valve V, and a three-way switching valve Va.
- control means C receives the detection information of the dissolved oxygen amount detection means D and the temperature detection means Ta, respectively, and based on the detection information, the treated water supply part K, the nitrogen gas supply part N, the pressure feed pump P, and the heat Control information is transmitted to the exchanger H, the pressure regulating valve V, and the three-way switching valve Va, respectively, and these operations are appropriately controlled.
- the nitrogen treated water generating apparatus A supplies pure nitrogen gas to the treated water W, and a circulation pipe J and a tank provided with a pressure feed pump P and a fluid mixing treatment unit M in the middle of these. It is possible to circulate through the circulation channel R formed by T. At this time, the fluid mixing processing unit M applies a shearing force to the gas-liquid mixed phase of the treated water W and the pure nitrogen gas, and causes the pure nitrogen gas to pass through the nanovalve (ultrafine bubbles with a diameter of nanometer level (1 ⁇ m or less)). The bubbles can be mixed with the treated water W.
- the treated water W containing such a group of bubbles is circulated in the tank T, so that oxygen dissolved in the treated water W in the tank T becomes fine bubbles (larger diameter than nanobubbles). Can be diffused into pure nitrogen gas. By doing so, fine pure nitrogen gas from which oxygen has diffused can be floated in the treated water W, and oxygen can be escaped (deoxygenated) from the treated water W, that is, released into the atmosphere. As a result, the amount of dissolved oxygen in the treated water W can be greatly reduced to obtain nitrogen treated water containing nitrogen nanobubbles.
- the heat exchange of the heat exchanger H is controlled by the controller C based on the detection result of the temperature detector Ta, and the treated water W is held at a predetermined temperature in the range of 1 ° C.
- the treated water W is controlled by the control means C so that the pressure regulating valve V and the three-way switching valve Va are opened / closed based on the detection result of the dissolved oxygen amount detection means D, and the circulation flow path for the required time or the required number of times. It is circulated through and becomes nitrogen treated water.
- the fluid mixing processing unit M can convert the nitrogen gas into a group of bubbles having nanovalves, but the treated water W is supplied to the circulating flow path R for a predetermined time (for example, 25).
- the number of nitrogen nanobubbles can be increased by circulating for more than a minute) or a predetermined number of times (for example, 20 times) or more. Therefore, until the time or number of times the treated water W is circulated in the circulation flow path R reaches a predetermined time or a predetermined number of times, oxygen dissolved in the treated water W is fine bubbles (larger diameter than nanobubbles).
- Treated water W with the emphasis on letting the fine nitrogen gas diffused in the treated water W float up in the treated water W, and let the oxygen escape (deoxygenate) from the treated water W Reduction of the amount of dissolved oxygen can be realized.
- the treated water W is circulated in the circulation flow path R until the predetermined time or the predetermined number of times is reached, so that the amount of dissolved oxygen is reduced and the generation of nitrogen treated water containing a large amount of nitrogen nanobubbles is realized.
- the nitrogen treated water generation method according to the first embodiment includes a nitrogen gas / treated water mixing step, a containing step, and an oxygen escape step.
- a shear force is applied to the gas-liquid mixed phase of the treated water W and the pure nitrogen gas by the fluid mixing treatment unit M to make the pure nitrogen gas into a group of bubbles having ultrafine bubbles.
- the storing step is a step of storing the treated water mixed with bubbles obtained in the nitrogen gas / treated water mixing step in the tank T.
- the oxygen dissolved in the treated water W stored in the tank T in the storing process is diffused into the pure nitrogen gas formed into fine bubbles, thereby processing the fine nitrogen gas from which oxygen has been released. It is a step of floating oxygen in the water W and escaping oxygen from the treated water W.
- Such nitrogen-treated water generation method can generate nitrogen-treated water in a short time. That is, the efficiency of reducing the amount of dissolved oxygen in the treated water W can be greatly improved.
- the amount of dissolved oxygen (DO value) in 800 liters of treated water W can be drastically reduced to less than 1.0 (mg / L) and further around 0.5 (mg / L) in 25 minutes. That is, a large amount of low-concentration oxygen-treated water whose dissolved oxygen amount (DO value) is less than 1.0 (mg / L) can be generated within one hour.
- a shown in FIG. 3 is a nitrogen treated water generating apparatus as a second embodiment according to the present invention.
- the nitrogen-treated water generating apparatus A includes oxygen diffusion / release promotion means A1 and nitrogen nanobubble mixing promotion means A2. And in the nitrogen treated water production
- the oxygen diffusion / release promotion means A1 stores the treated water W supplied from the treated water supply unit K in the tank T1 and arranges the fluid stirring unit S in the treated water W. Then, the fluid agitating unit S agitates the treated water W while applying a shearing force to the gas-liquid mixed phase of the sucked treated water W in the tank T1 and the nitrogen gas supplied from the nitrogen gas supply unit N1, Pure nitrogen gas is mixed into the treated water W in the form of fine bubbles (nitrogen microbubbles having a larger diameter than nanobubbles, for example, 50 ⁇ m to 100 ⁇ m).
- the treated water W mixed with pure nitrogen gas is discharged into the treated water W in the tank T1, and the treated water W in the tank T1 contains pure nitrogen gas that is made into fine bubbles.
- the treated water W in the tank T1 contains pure nitrogen gas that is made into fine bubbles.
- the water W is stirred so that pure nitrogen gas is mixed into the treated water W as fine bubbles.
- U is a discharge pipe that hangs down from the bottom of the tank T1, and an open / close valve V1 is attached to the middle of the discharge pipe U. By opening the on-off valve V1, the treated water W in the tank T1 can be discharged into the tank T2 of the nitrogen nanobubble mixing promoting means A2 described later.
- the tank T1 is provided with dissolved oxygen amount detection means D1, and the dissolved oxygen amount detection means D1 detects the dissolved oxygen amount (DO value) of the treated water W in the tank T1.
- the tank T1 is provided with temperature detection means Ta1, and the temperature detection means Ta1 detects the temperature of the treated water W in the tank T1.
- the nitrogen nanobubble mixing promoting means A2 is configured in the same manner as the nitrogen treated water generating apparatus A as the first embodiment described above. Then, the nitrogen treated water can be discharged (outflowed) from the tank T1 through the discharge pipe U to the tank T2.
- N2 is a nitrogen gas supply unit
- V2 is a pressure regulating valve.
- the tank T2 is provided with dissolved oxygen amount detection means D2, and the dissolved oxygen amount detection means D2 detects the dissolved oxygen amount (DO value) of the treated water W in the tank T2.
- the tank T2 is provided with temperature detection means Ta2, and the temperature detection means Ta2 detects the temperature of the treated water W in the tank T2.
- the dissolved oxygen amount detection means D1 and D2 and the temperature detection means Ta1 and Ta2 are connected to the input side interface of the control means C, respectively, while the electric motor part 1 and the nitrogen gas supply parts N1 and N2 of the fluid stirring part S described later are respectively controlled. It is connected to the output side interface of means C.
- control means C each receives the detection information of dissolved oxygen amount detection means D1 and D2, and temperature detection means Ta1 and Ta2, and based on the detection information, the motor part 1 and the treated water supply part of the fluid stirring part S Control information is transmitted to K, nitrogen gas supply units N1, N2, a pressure pump P, a heat exchanger H, an on-off valve V1, a pressure regulating valve V2, and a three-way switching valve Va, respectively, so that the operation thereof is appropriately controlled.
- the heat exchanger H is subjected to heat exchange control by the controller C based on the detection results of the temperature detectors Ta1 and Ta2, and the treated water W is held at a predetermined temperature in the range of 1 ° C to 5 ° C.
- the treated water W is controlled by the control means C to open and close the pressure regulating valves V1, V2 and the three-way switching valve Va based on the detection results of the dissolved oxygen amount detection means D1, D2, and the required time or the required number of times. Only the circulation channel is circulated to become nitrogen treated water.
- the nitrogen treated water generating method according to the second embodiment includes an oxygen diffusion / release promotion step and a nitrogen gas ultrafine refinement promotion step.
- the oxygen diffusion / release promotion step which is the preceding step, is a step of deoxygenating the treated water W to generate nitrogen treated water.
- pure nitrogen gas is mixed into the treated water W as nitrogen microbubbles of, for example, 50 ⁇ m to 100 ⁇ m, so that the dissolved oxygen concentration can be efficiently lowered by the nitrogen microbubbles (for example, DO (Values up to 1 mg / L).
- the subsequent nitrogen gas ultrafine refinement promoting process is a process of accumulating nitrogen nanobubbles in the nitrogen treated water generated in the preceding process.
- nitrogen nanobubbles of 50 nm to 900 nm can be efficiently accumulated in the nitrogen-treated water, and the nitrogen nano-treated water can be generated steadily.
- the oxygen diffusion / release promotion step is a step of processing by the oxygen diffusion / release promotion means A1, and in this step, the treated water W and the pure nitrogen gas in the tank T1 are fed by the fluid stirring unit S.
- the concentration of pure nitrogen gas contained in the treated water W can be increased.
- oxygen dissolved in the treated water W in the tank T can be diffused into pure nitrogen gas (nitrogen microbubbles) formed into fine bubbles, and the efficiency of diffusion can be promoted.
- the fine pure nitrogen gas from which oxygen has diffused can be floated in the treated water W, and oxygen can be escaped (deoxygenated) from the treated water W, that is, efficiently released into the atmosphere. As a result, the amount of dissolved oxygen in the treated water W can be significantly reduced.
- the nitrogen gas ultrafine refinement promoting process is a process of treating with the nitrogen nanobubble mixing promoting means A2, and in this process, the treated water W in which oxygen diffusion / release is promoted, that is, in the treated water W by the oxygen diffusion / release promoting means A1.
- the nitrogen-treated water after promoting the release of dissolved oxygen into the nitrogen gas and further releasing the oxygen gas into the atmosphere together with the nitrogen gas is further treated with the nitrogen nanobubble mixing promoting means A2. By doing so, it can be made nitrogen treated water in which a large amount of nitrogen nanobubbles are contained (accumulated) in nitrogen treated water in which the amount of dissolved oxygen is greatly reduced.
- the particle size of nitrogen nanobubbles (for example, 50 nm to 900 nm) is too small, so that nitrogen nanobubbles can contribute to maintaining the freshness of seafood.
- the nitrogen nanobubbles are mixed (contained) in the nitrogen-treated water for a long time, and the nitrogen in the nitrogen nanobubbles is dissolved in the nitrogen-treated water over time. As a result, the amount of nitrogen dissolved in the nitrogen-treated water is maintained in a supersaturated state for a long time.
- the freshness-keeping method for fresh fishery products basically involves treating fresh fishery products by immersing them in nitrogen-treated water for a certain period of time.
- the first freshness-keeping treatment method is to fill a box-type container such as a foamed polystyrene box with a lid with nitrogen-treated water (in addition, slurry ice can be added), and immerse fresh seafood in the nitrogen-treated water.
- a box-type container such as a foamed polystyrene box with a lid
- nitrogen-treated water in addition, slurry ice can be added
- immerse fresh seafood in the nitrogen-treated water in this immersion method, the box-shaped container is sealed, and the box-shaped container is refrigerated in the refrigerator.
- a bag-type container such as a vacuum plastic bag is filled with nitrogen-treated water, fresh seafood is immersed in the nitrogen-treated water, and the bag-type container is sealed in the soaked state.
- the bag-type container is refrigerated in a refrigerator.
- the constant temperature for refrigeration is not particularly limited as long as it can be stored after being cooled to a low temperature that does not freeze fresh fish and shellfish, and is preferably a temperature between 0 ° C. and 4 ° C.
- the time for refrigeration can be set within 192 hours depending on the desired freshness of fresh seafood.
- Fresh fish and shellfish immersion step (b) immersed in water Wn extraction step (c) for extracting fresh fish Fi from nitrogen-treated water Wn, and deaeration for accommodating the extracted fresh fish Fi in a container Ca and deaeration It includes a step (d), a sealing step (e) for sealing the deaerated fresh fish Fi in the container Ca, and a refrigeration step (f) for refrigeration of the fresh fish Fi sealed in the container Ca.
- the nitrogen-treated water Wn is filled in an immersion container Ca having a volume that can open and accommodate fresh fish Fi, and the fresh fish Fi is immersed (immersed) for a certain period of time.
- the nitrogen-treated water Wn can be deeply penetrated to the inside of the meat of the fresh fish Fi.
- the immersion time (dipping time), which is a fixed time, can be appropriately set according to the type and size of fresh fish, and is, for example, 30 minutes to 150 minutes, preferably 60 minutes to 120 minutes. can do.
- the fresh fish Fi in which the nitrogen-treated water Wn penetrates deeply into the meat is contained in the container Ba and the inside of the container Ba is deaerated, and then the sealing step ( In e), the container Ba is sealed. At this time, fresh fish Fi is accommodated in the container Ba in advance, and after the air is removed, the container Ba is vacuum-sealed (vacuum seal).
- a plastic bag plastic back
- VP is a vacuum pump
- Hp is a suction hose with one end connected to the vacuum pump VP
- the other end of the suction hose Hp is connected to the container Ba.
- the container Ba is refrigerated in the refrigerator Re, for example, at a constant temperature of 0 ° C. to 4 ° C., for example, for a predetermined time within 192 hours.
- the fourth freshness-keeping treatment method is a treatment method in which fresh seafood is immersed in nitrogen-treated water for a certain period of time (for example, 1 hour) and then frozen while the fresh seafood is immersed in nitrogen-treated water.
- the fourth freshness-keeping treatment method is a treatment method in which a freezing step is provided after the preparation step (a) and the fresh seafood immersion step (b) in the third freshness-keeping treatment method.
- a freezing process is performed in which fresh seafood is frozen while immersed in nitrogen-treated water at a normal freezer temperature of ⁇ 18 ° C.
- the 4th freshness maintenance processing method after immersing fresh fish and shellfish in nitrogen treatment water, it can also consider that time until nitrogen treatment water freezes by performing freezing treatment immediately as immersion treatment time.
- nitrogen treatment water freezes by performing freezing treatment immediately as immersion treatment time.
- crustaceans such as shrimps and crabs may be frozen immediately after being immersed in nitrogen-treated water.
- the commercial value of the fresh seafood can be prevented from being lowered by applying the fourth freshness maintaining method.
- shrimp, crab and other crustaceans produce a large amount of melanin upon freezing and cause blackening, but when they are frozen while immersed in nitrogen-treated water Wn, melanin is produced. It is possible to prevent the blackening phenomenon from being suppressed. As a result, the commercial value of crustaceans can be maintained or improved for a certain period of time.
- the nitrogen-treated water generation apparatus A results of the nitrogen-treated water generation experiment and the first to third freshness maintaining treatment methods are shown. That is, about 0.8 m 3 of seawater subjected to ultraviolet sterilization treatment was used as the treated water W as an experiment for generating nitrogen-treated water.
- the tank T is a container with a volume of 1 m 3
- the pumping pump P is a pump with an output of 7.5 kW manufactured by Kawamoto Seisakusho
- the dissolved oxygen amount detection means D is a DO METER ID-100, pH meter manufactured by Iijima Electronics Co., Ltd. Used a SK-620PH manufactured by Sato Meters Co., Ltd.
- the pressure feed pump P was operated for 25 minutes to circulate the mixed fluid of seawater and nitrogen gas in the circulation flow path R.
- the flow rate of seawater flowing through the circulation pipe J to the fluid mixing processing unit M is set to 200 to 150 (L / min)
- the amount of nitrogen gas is set to 5.0 (L / min)
- ultrafine (nano level) bubbles are generated.
- Nitrogen seawater with was produced.
- FIGS. In 25 minutes, the amount of dissolved oxygen (DO value) drastically decreased from 6.30 (mg / L) to 0.40 (mg / L). This shows that oxygen escaped from seawater by nitrogen gas.
- the results of processing the nitrogen seawater generated as described above by the first freshness maintaining method will be described.
- it was filled in a foamed polystyrene box with a lid, and the lid was closed after immersing the fresh sea bream, a fresh fish, in the nitrogen seawater.
- the expanded polystyrene box was stored in a refrigerator having an internal temperature of 2 to 3 ° C.
- the freshness index K value test and the bacteria test were conducted at the Kitakyushu Life Science Center on the first day, the 4th day, the 6th day, and the 8th day for the true horse mackerel in the polystyrene foam box.
- the K value test method used was an ion exchange resin column-absorbance measurement method (hereinafter, the K value measurement of the resultant product treated by the second and third freshness maintaining methods was also the same). The results are shown in FIGS.
- FIG. 7 As shown in FIG. 7, with K value, it was found that true horse mackerel can be completely used for sashimi with less than 20% until 6th. In addition, although it was 20.1% on the 8th day, the result of sensory / tasting was able to eat deliciously as sashimi. In addition, as shown in FIG. 8, the number of bacteria was far less than 1 million / g to 100 million / g, which is the criterion for initial rot, and there was no problem until the 8th day.
- FIG. 9 and FIG. 10 are sensory test evaluations 1 and 2 on the fourth, sixth, and eighth days of the fresh mackerel subjected to the freshness keeping process. On the 4th and 6th day, the overall evaluation was very high, and on the 8th day it was as high as 3.5.
- FIG. 11 shows the DO value, seawater temperature, salinity concentration, and K value on the first day, the fourth day, the fifth day, the seventh day, and the eighth day.
- true horse mackerel As a result of tasting, there is no smell, it is crunchy and delicious.
- true horse mackerel was not considered a fish that had a beautiful silver under skin and had passed days.
- true horse mackerel there was no decolorization of the eyelids until the 7th day, but some decolorization was observed in the eyelids on the 8th day.
- the nitrogen seawater generated as described above was filled in the immersion container 12, and the true horse mackerel and Isaki were immersed therein for 60 minutes.
- the nitrogen seawater temperature at this time was 2.0 ° C., and the DO value was 0.45 mg / L.
- the true horse mackerel and Isaki were accommodated in individual containers 14 to degas the container 14 and the container 14 was sealed.
- the pure mackerel and Isaki that were sealed in the individual container 14 were stored in a refrigerator with an internal temperature of 2 to 3 ° C. for 6 days.
- the K value after storage for 6 days was 2.4% for Shinji and 5.6% for Isaki.
- FIG. 12 shows an example of actually measured particle size distribution.
- the pressure of the pressure pump P is 1.2 MPa
- the flow rate of distilled water is 3 L / min
- the flow rate of air is 0.2 L / min
- the circulation time in the circulation channel R is 3 minutes. did.
- LM10-HS manufactured by Nanosite, UK was used as the measuring instrument.
- the measuring method using the measuring instrument is the tracking method (tracking method), and the measurer is Nippon Quantum Design Co., Ltd.
- nano bubbles with a mode diameter of 120 nm are present. There are about 700 million pieces / mL, and its volume concentration is less than 1 ppm. Nanobubbles coexist in nanowater, and the surface of nanobubbles is negatively charged. That is, the surface of the nanobubble is covered with electrons.
- the nitrogen treated water will provide an antioxidant environment. That is, the nitrogen-treated water affects the redox potential (ORP) (suppresses ORP).
- ORP redox potential
- nitrogen-treated water having a low DO value for example, 0.5 mg / L or less
- the fluid mixing processing unit M as the first embodiment includes a pair of upper and lower horizontal rectangular plate-like mixing elements 210 and 220 extending in one direction (in this embodiment, the left-right direction).
- a mixing channel 230 extending in the extending direction is formed between both mixing elements 210 and 220 so as to face the polymerization state.
- an inflow side connection portion 211 is formed at the left end portion of the mixing element 210.
- the inflow side connecting portion 211 has one end opened on the left end surface of the mixing element 210 and the other end opened on the lower surface of the left end portion of the mixing element 210.
- An inflow side of the circulation pipe J is detachably connected to an inflow hole 212 formed at one end of the inflow side connection portion 211.
- the other end of the inflow side connection portion 211 is communicated with the start end portion of the mixing channel 230 via the start end side temporary retention space 240.
- an outflow side connection portion 213 is formed at the right end portion of the mixing element 210.
- the outflow side connection portion 213 has one end opened on the right end surface of the mixing element 210 and the other end opened on the lower surface of the right end portion of the mixing element 210.
- the outflow side of the circulation pipe J is detachably connected to the outflow hole 214 formed at one end of the outflow side connection portion 213.
- the other end of the outflow side connection portion 213 is communicated with the end portion of the mixing channel 230 through the end side temporary staying space 250.
- the mixing channel 230 includes a mixing channel forming pattern surface Pa composed of a plurality of recesses 215 formed on the lower surface of the mixing element 210 and a mixing channel forming pattern surface Pb composed of a plurality of recesses 225 formed on the upper surface of the mixing element 220. They are formed to face each other.
- Each of the mixed flow path forming pattern surfaces Pa and Pb is formed in a so-called honeycomb shape by forming a large number of recesses 215 and 225 in a regular hexagonal shape with no gaps.
- the recesses 215 and 225 are formed in the same shape and the same hexagonal opening shape and are opposed to each other in the arrangement as shown in FIG.
- a plurality of flow dividing portions that flow in the extending direction of 230 and flow-divide, and a plurality of combined portions that flow and merge the fluid divided in the flow dividing portion in the extending direction of the mixing channel 230 are formed. .
- the mixed flow path forming pattern surface Pa is formed by arranging the concave portions 215 of the mixing element 210 in a staggered manner in five rows in the width direction and in the left-right extension direction, as shown by a one-dot chain line in FIG. .
- the mixed flow path forming pattern surface Pb is formed by arranging a plurality of concave portions 225 of the mixing element 220 in six rows in the width direction and in a staggered manner in the left-right extension direction, as shown by a solid line in FIG. Then, the corner portion 226 of the concave portion 225 of the mixing element 220 is in contact with the central position of the concave portion 215 of the mixing element 210.
- fluid treated water W and nitrogen gas
- the corner portion 226 is a position where the corner portions of the three concave portions 225 are gathered.
- the corner 216 of the recess 215 of the mixing element 210 is also located at the center position of the recess 225 of the mixing element 220.
- the corner 216 is a position where the corners of the three recesses 215 are gathered. In this case, the corner portion 216 of the mixing element 210 functions as the diversion portion or the merge portion described above.
- the fluid when the case where the fluid flows from the concave portion 215 side of the mixing element 210 to the concave portion 225 side of the mixing element 220, the fluid is divided into two flow paths. That is, the corner portion 226 of the mixing element 220 positioned at the center position of the concave portion 215 of the mixing element 210 functions as a diversion portion that diverts the fluid. Conversely, considering the case where fluid flows from the mixing element 220 side to the mixing element 210 side, the fluid flowing from two directions flows into one concave portion 215 and merges. In this case, the corner portion 226 located at the center position of the mixing element 220 functions as a merging portion.
- a start-side temporary staying space 240 is formed between the start end of the mixing channel 230 and the inflow side connecting portion 211 formed on the left side of the mixing element 210.
- the start-side temporary residence space 240 has a concave space forming portion 241 formed on the lower surface of the left side of the mixing element 210 and a concave space forming portion 242 formed on the upper surface of the left side of the mixing element 220 facing each other in the vertical direction. Formed.
- the width W1 in the front-rear direction of the start-side temporary staying space 240 formed by the space forming portions 241 and 242 is substantially the same as the width W2 in the front-rear direction of the start end of the mixing channel 230. They are formed to have the same width and communicate with the start end of the mixing channel 230 over substantially the entire width of the start end side temporary staying space 240.
- a terminal-side temporary retention space 250 is formed between the terminal end of the mixing channel 230 and the outflow side connecting part 213 formed on the other side of the mixing element 210.
- the terminal-side temporary stay space 250 has a concave space forming portion 251 formed on the lower surface of the right side of the mixing element 210 and a concave space forming portion 252 formed on the upper surface of the right side of the mixing element 220 facing each other in the vertical direction. Formed.
- the width W3 in the front-rear direction of the terminal-side temporary retention space 250 formed by both space forming portions 251 and 252 is formed to be substantially the same width as the width W4 in the front-rear direction of the terminal end of the mixing channel 230,
- the terminal-side temporary residence space 250 is communicated with the terminal portion of the mixing channel 230 over substantially the entire width.
- Numeral 260 is an upper screw hole formed in a large number around the upper mixing element 210
- numeral 261 is a lower screw hole formed in a large number around the lower mixing element 220.
- Each screw hole 260, 261 is formed with the axis line in the vertical direction, and the screw 262 is screwed into the upper and lower screw holes 260, 261 that are aligned vertically, thereby superposing both mixing elements 210, 220. It can be easily and firmly connected to the state. Further, by removing the screws, the connection between the mixing elements 210 and 220 can be easily released, and the concave portions 215 and 225 can be cleaned.
- Reference numeral 270 denotes an O-ring arrangement groove formed on the upper surface of the mixing element 220 so as to surround a large number of the recesses 225 and the space forming portions 242 and 252.
- Reference numeral 271 denotes an O-ring arranged in the O-ring arrangement groove 270. The O-ring 271 can ensure the sealing performance of the mixing elements 210 and 220.
- the inflow side connection portion 211 In this way, between the mixing elements 210 and 220 facing each other and facing each other, the inflow side connection portion 211, the start side temporary residence space 240, the mixing channel 230, the end side temporary residence space 250, and the outflow.
- the side connection part 213 is communicated in series. As shown in FIG. 18, the fluid supplied from the inflow hole 212 of the inflow side connection portion 211 flows into the start-side temporary residence space 240 and is mixed substantially uniformly in the width direction from the start-side temporary residence space 240. After flowing into the flow path 230 and flowing in the mixing flow path 230, the flow flows out from the outflow hole 214 of the outflow side connection portion 213 through the terminal side temporary retention space 250.
- the fluid flows in a meandering state in the extending direction of the mixing elements 210 and 220 while repeating the diversion and merging (dispersing and mixing) in the mixing flow path 230. Therefore, for example, when a liquid and a gas are allowed to flow into the mixing channel 230 as a fluid, the gas is superfine and uniformed to a submicron level (nano level), and the gas is uniformly dispersed in the liquid.
- a submicron level nano level
- the fluid mixing processing unit M as the second embodiment has the same basic structure as the fluid mixing processing unit M as the first embodiment, but as shown in FIG.
- the intermediate element 280 is thinner than the mixing elements 210 and 220, so that the mixing elements 210, 220, and 280 are in a laminated state.
- the intermediate mixing element 280 forms the mixing channel forming pattern surface Pb on the upper surface facing the mixing channel forming pattern surface Pa of the mixing element 210, while facing the mixing channel forming pattern surface Pb of the mixing element 220.
- a mixed flow path forming pattern surface Pa is formed on the lower surface.
- the mixing flow path forming pattern surface Pa of the intermediate mixing element 280 is formed by arranging a large number of concave portions 281 having the same shape as the concave portions 215 so as to face each other, and the mixing flow path forming pattern surface Pb of the intermediate mixing element 280 is formed. Is formed by arranging a large number of concave portions 282 having the same shape as the concave portions 225 in an opposing state.
- a space forming portion 243 is formed on the left side of the intermediate mixing element 280.
- the space forming portion 243 penetrates in the vertical direction (thickness direction) and is aligned with the space forming portions 241 and 242 of the mixing elements 210 and 220.
- the start-side temporary staying space 240 is formed by these space forming portions 241 to 243.
- a space forming portion 253 is formed on the right side portion of the intermediate mixing element 280.
- the space forming portion 253 penetrates in the vertical direction (thickness direction) and is aligned with the space forming portions 251 and 252 of the mixing elements 210 and 220.
- the end-side temporary staying space 250 is formed by these space forming portions 251 to 253.
- Reference numeral 283 denotes an O-ring arrangement groove
- reference numeral 284 denotes an O-ring.
- Screw holes (not shown) that coincide with the screw holes 260 and 261 of the mixing elements 210 and 220 are formed at the peripheral edge of the intermediate mixing element 280, and the screws 262 are screwed into these screw holes in a penetrating manner. I am doing so.
- the mixing flow paths 230 are formed between the mixing element 210 and the intermediate mixing element 280 and between the intermediate mixing element 280 and the mixing element 220, respectively.
- Two mixing channels 230 are arranged in parallel in the vertical direction. Then, the fluid supplied from the inflow hole 212 of the inflow side connection portion 211 flows into the start end side temporary stay space 240 and is parallel to each mixing channel 230 in the width direction from the start end side temporary stay space 240 substantially evenly. Inflow.
- the ultrafine and uniform fluid by the mixing channel 230 is efficiently performed in parallel.
- the required number of mixing channels 230 can be arranged, and the work of ultra-fine and uniform fluid can be made more efficient.
- the fluid mixing processing unit M as the third embodiment has the same basic structure as the fluid mixing processing unit M as the first embodiment, but as shown in FIGS. 20 and 21, a pair of upper and lower mixing elements 210, Two intermediate mixing elements 290 and 291 that are thinner than the mixing elements 210 and 220 are interposed between the two mixing elements 210 and 220, and the mixing elements 210, 220, 290, and 291 are stacked. .
- the intermediate mixing element 290 is formed with a large number of through holes 292 that penetrate in the thickness direction, and the through holes 292 are formed in a hexagonal columnar space having the same shape as that of the concave portion 225 and arranged in a large number, A mixed flow path forming pattern surface Pc whose plane shape matches the mixed flow path forming pattern surface Pb is formed.
- the mixing channel forming pattern surface Pc that forms the mixing channel 230 facing the mixing channel forming pattern surface Pa of the mixing element 210 is formed on the upper and lower surfaces of the intermediate mixing element 290.
- the intermediate mixing element 291 has a large number of through holes 293 penetrating in the thickness direction, and the through holes 293 are formed in a hexagonal columnar space having the same shape as that of the concave portion 215 and arranged in a large number, A mixed flow path forming pattern surface Pd whose plane shape matches the mixed flow path forming pattern surface Pa is formed.
- the mixing channel forming pattern surface Pd that forms the mixing channel 230 is formed on the upper and lower surfaces of the intermediate mixing element 291 so as to face the mixing channel forming pattern surface Pb of the mixing element 220.
- Space forming portions 244 and 45 that are aligned with each other are formed on the left side portions of the intermediate mixing elements 290 and 291, and the space forming portions 244 and 245 penetrate in the vertical direction (thickness direction), and the mixing element 210.
- 220 are aligned with the space forming portions 241 and 242, and the space forming portions 241, 242, 244, and 245 form a starting end side temporary staying space 240.
- Space forming portions 254 and 255 that are aligned with each other are formed on the right side portions of the intermediate mixing elements 290 and 291, respectively. The space forming portions 254 and 255 penetrate in the vertical direction (thickness direction) and the mixing element 210.
- 220 are aligned with the space forming portions 251 and 252, and the space forming portions 251, 252, 254, and 255 form the terminal-side temporary staying space 250.
- 294 and 295 are O-ring disposition grooves
- 296 and 297 are O-rings.
- Screw holes (not shown) that coincide with the screw holes 260 and 261 of the mixing elements 210 and 220 are also formed in the peripheral portions of the intermediate mixing elements 290 and 291, and screws are screwed into these screw holes in a penetrating manner. Like to do.
- mixing is performed between the mixing element 210 and the intermediate mixing element 290, between the intermediate mixing elements 290 and 291, and between the intermediate mixing element 291.
- a mixing flow path 230 is formed between the mixing element 210 and 220 passing through the element 220 and the intermediate mixing elements 290 and 291, respectively.
- Such a mixing channel 230 becomes an irregular meandering channel in which it is unclear which element the fluid flows through. As a result, the fluid flowing through the mixing channel 230 meanders as a complex flow / pulsating flow.
- the complex flow is a flow in which the fluid flows while rubbing the surfaces of the recesses 215, 225 or the through holes 292, 293 of the mixing elements 210, 220, 290, 291.
- the pulsating flow is a flow in which the flow path cross-sectional area changes periodically or irregularly.
- a local high-pressure portion and a local low-pressure portion are generated in the fluid.
- a low-pressure part for example, a negative pressure part such as a vacuum part
- a so-called foaming phenomenon occurs, gas is generated in the liquid, or minute bubbles expand (explode).
- a phenomenon called so-called cavitation occurs in which the generated gas (bubbles) collapses (disappears). The force generated when such cavitation occurs refines the gas and promotes fluid mixing. As a result, it is possible to make the fluid ultrafine and uniform work more efficient.
- the fluid mixing processing unit M as the fourth embodiment has the same basic structure as the fluid mixing processing unit M as the first embodiment, but as shown in FIGS. 22 and 23, a pair of upper and lower mixing elements 210, One difference is that one intermediate mixing element 290 that is thinner than the mixing elements 210 and 220 is interposed between the mixing elements 210 and 220 so that these mixing elements 210, 220, and 290 are in a laminated state.
- a mixing channel forming pattern surface Pa is formed on the upper surface of the mixing element 220 instead of the mixing channel forming pattern surface Pb.
- the mixing channel forming pattern surface Pc is placed between the mixing element 210 having the mixing channel forming pattern surface Pa and the mixing element 220 having the mixing channel forming pattern surface Pa.
- the mixed flow path forming pattern surface Pa and the mixed flow path forming pattern surface Pc are opposed to each other with the intermediate mixing element 290 included therebetween.
- a mixing channel 230 is formed between the mixing elements 210 and 220 through the element 290.
- Such a mixing channel 230 becomes an irregular meandering channel in which it is unclear which element the fluid flows through.
- the fluid flowing through the mixing channel 230 meanders as a complex flow / pulsating flow.
- the fluid supplied from the inflow hole 212 of the inflow side connection portion 211 flows into the start end side temporary stay space 240 and is parallel to each mixing channel 230 in the width direction from the start end side temporary stay space 240 substantially evenly. Inflow.
- the ultrafine and uniform fluid by the mixing channel 230 is efficiently performed in parallel.
- the fluid mixing processing unit M as the fifth embodiment has the same basic structure as the fluid mixing processing unit M as the third embodiment, but as shown in FIG. These are different in that these mixing elements 210, 220, 280, 290 and 291 are in a laminated state by interposing intermediate mixing elements 280, 290 and 291 that are thinner than the mixing elements 210 and 220.
- the fluid mixing processing unit M includes a mixing element 210 having a mixing channel forming pattern surface Pa, an intermediate mixing element 290 having a mixing channel forming pattern surface Pc, and a mixing channel forming pattern surface Pd.
- An intermediate mixing element 291 having a mixing channel forming pattern surface Pb, Pa on the upper and lower surfaces, an intermediate mixing element 290 having a mixing channel forming pattern surface Pc, and a mixing channel forming pattern surface Pd The intermediate mixing element 291 having the above and the mixing element 220 having the mixing flow path forming pattern surface Pb are laminated.
- the start-side temporary residence space 240 is formed by space forming portions 241, 244, 245, 243, 244, 245, and 242.
- the terminal-side temporary residence space 250 is formed by space forming portions 251, 254, 255, 253, 254, 255, and 252.
- the fluid mixing processing unit M in the first to fifth embodiments described above includes a single or a plurality of mixing channels 30 between the start-side temporary residence space 240 and the termination-side temporary residence space 250 in parallel. Since the fluid can be made to flow almost uniformly into each mixing channel 230, pressure loss can be reduced. As a modification, the thickness of the intermediate mixing elements 280, 290, 291 and the diameters of the through holes 292, 293 in the second to fifth embodiments can be appropriately changed. In that case, it is possible to change the ultra-fine and uniform efficiency of the fluid.
- connection means between the pair of mixing elements 210 and 220 is not limited to the screw of the present embodiment, and modifications thereof can be applied as appropriate.
- the mixing channel 230 can be opened.
- one of the long side edges of the mixing element 210 and the mixing element 220 can be pivotally mounted in a double-spreading manner, and the other long side edges can be connected to each other so as to be connected / released.
- connection operation for connecting the mixing elements 210 and 220 to the superposed state can be performed steadily, and the connection release operation for bringing the mixing elements 210 and 220 into the open state can be performed. Can be done easily. For this reason, such a double spread structure is suitable when there is a need to frequently perform the cleaning operation of the mixing channel 230.
- FIG. 25 shows a fluid stirring unit S as the first embodiment.
- B is a liquid storage part.
- the liquid storage part B stores liquid Li such as water, and the fluid stirring part S is disposed in the liquid Li.
- Lo is a bottom surface portion of the liquid storage portion B.
- the liquid reservoir B is not limited to a tank or the like that artificially stores the liquid Li to be processed, but also includes a lake or the like in which the liquid Li to be processed is naturally stored.
- the fluid agitation unit S is integrally configured by linking the fluid agitation unit 20 to the lower end of the electric motor unit 1 and linking the pump chamber 60 to the lower end of the fluid agitation unit 20. is doing.
- the pump chamber 60 driven by the electric motor unit 1 constitutes a non-volumetric turbo pump.
- the electric motor unit 1 and the pump chamber 60 are integrally formed in the liquid Li. The arrangement can be used.
- the fluid stirring unit S configured in this manner is arranged in the liquid Li to be processed, and the liquid Li is sucked by the pump chamber 60 and discharged to the fluid stirring unit 20 side.
- another type of fluid in this embodiment, gas E
- Li and gas E are pumped toward the fluid stirring unit 20.
- the liquid Li and the gas E that are pressure-fed to the fluid stirring unit 20 are mixed and stirred by the fluid stirring unit 20.
- a mixture in which the gas E is ultrafine and uniform in this embodiment, a liquid containing ultrafine bubbles
- FIG. 25 the configuration of the fluid stirring unit S will be described more specifically with reference to FIGS. 25 to 32.
- the electric motor unit 1 extends a drive shaft 4 having an axis line in the vertical direction downward from the lower end surface portion 3 of the electric motor case 2.
- Reference numeral 5 denotes an electric cable.
- a plate-like mounting body 10 is connected to the lower end surface portion 3 of the motor case 2 by a connecting bolt 11.
- the fluid stirring portion 20 and the pump chamber portion 60 are integrally attached to the attachment body 10 via a plurality of (four in this embodiment) attachment bolts 12 extending in the vertical direction.
- Reference numeral 17 denotes a carry-out hose connected to the attachment body 10.
- the carry-out hose 17 communicates with a stirring chamber 22 described later so as to carry out the mixture.
- Reference numeral 18 denotes a stay for supporting the fluid stirring unit S in the liquid Li via the attachment body 10.
- Reference numeral 19 denotes a mounting bolt.
- the fluid stirring unit 20 includes a stirring chamber 22 formed in the casing body 21, and a movable side stirring body 23 as one stirring body and the other stirring body in the stirring chamber 22.
- the fixed side stirring body 24 is arranged.
- a required number (two in the present embodiment) of fluid agitating units 20 are arranged on the drive shaft 4 in a skewered manner, and communicate with each other in a heavy box shape.
- the casing body 21 has an upper surface opening from a cylindrical peripheral wall forming piece 25 whose axis is directed in the vertical direction and a disk-shaped bottom forming piece 26 stretched on the lower end of the peripheral wall forming piece 25. It is formed in a box shape.
- a stepped fitting concave portion 27 is formed on the peripheral edge of the upper end of the peripheral wall forming piece 25.
- the stepped fitting concave portion 27 is connected in a close contact state by fitting from a lower portion through a O-ring (not shown) to a stepped fitting convex portion 13 formed in a downwardly bulging shape on the lower surface of the mounting body 10. is doing.
- a support portion 28 that bulges upward is formed near the center of the bottom forming piece 26.
- the support portion 28 is formed in a cylindrical support piece 29 having an axis line in the vertical direction and an inwardly projecting shape on the inner peripheral surface of the upper end of the support piece 29.
- the plate-shaped upper surface piece 30 is formed.
- On the upper surface piece 30, a disk-like support main piece 31 is connected in a superposed state by a connecting bolt 32.
- the outer diameter of the support main piece 31 is formed to be substantially the same as the outer diameter of the stationary stirring member 24.
- 33 and 34 are communication holes formed in the upper surface piece 30 and the support main piece 31, respectively.
- the communication holes 33 and 34 also function as insertion holes through which the peristaltic shaft 4 is inserted.
- the axial position of the stirring chamber 22, that is, the axial position of the peripheral wall forming piece 25 is deviated by a certain width with respect to the axial position of the drive shaft 4, as shown in FIG.
- the width of the outer diameter of the stationary stirring member 24 is biased by about one-sixth.
- the center of rotation of the disk-shaped movable side stirring body 23 is attached.
- the movable stirring member 23 can be rotated integrally with the drive shaft 4.
- a disk-shaped fixed-side stirring body 24 is arranged in a face-to-face state at a position directly below the movable-side stirring body 23 with a constant gap t (for example, around 1 mm).
- An inflow port 35 is formed in the central portion of the fixed side stirring body 24, and an agitating flow path 36 formed in the radial direction from the inflow port 35 in the central portion is formed between both the stirring bodies 23 and 24.
- the liquid Li and the gas E are mixed and stirred by both the stirring bodies 23 and 24, so that a liquid containing ultrafine bubbles as a mixture is generated.
- the movable side stirring body 23 and the fixed side stirring body 24 will be described more specifically with reference to FIGS.
- the movable side agitator 23 is formed on the lower surface of the movable side main body 40 formed in the shape of a constant thickness disk, except for the central portion 41 and the outer peripheral portion 42 having a constant width.
- hexagonal channel-forming recesses 43 having a bottom view are formed in an orderly and dense manner to form a honeycomb shape.
- the central portion 41 of the movable side body 40 is flush with the lower surface of the flow path forming recess 43, while the outer peripheral portion 42 is the upper surface and surface of the flow path forming recess 43. It is done.
- a drive shaft insertion hole 44 is formed at the center of the upper surface of the movable side main body 40, and a cylindrical connecting piece 45 is connected to the upper surface of the movable side main body 40 so as to communicate with the drive shaft insertion hole 44. is doing.
- 46 is a bolt hole formed in a transversely penetrating manner in the middle portion of the cylindrical connecting piece 45, 47 is a fixing bolt, and the bolt hole 46 is in a state where the cylindrical connecting piece 45 is fitted in the middle portion of the drive shaft 4.
- the cylindrical connecting piece 45 is fastened and fixed to the drive shaft 4 by screwing the fixing bolt 47 onto the drive shaft 4.
- the fixed-side stirring body 24 is substantially the same shape as the above-described movable-side main body 40, i.e., the central portion of the fixed-side main body 50 formed with substantially the same thickness and substantially the same outer diameter.
- a flow passage forming recess 53 having a hexagonal shape in a bottom view in the radial direction and the circumferential direction is formed on the upper surface of the stationary main body 50 except for the outer peripheral portion 52 having a constant width on the upper surface of the fixed-side main body 50. It is neatly formed densely and has a honeycomb shape.
- the shape of the flow path forming recesses 43 and 53 is not limited to the hexagonal shape in the bottom view. For example, it can also be formed in a semispherical concave shape.
- the fixed side stirring body 24 is connected with the superposition
- the inlet 35 of the fixed side stirring body 24 is matched with the communication holes 33 and 34.
- the flow path forming recesses 43 and 53 formed in both the stirring bodies 23 and 24 face each other in a shifted state as a basic form. That is, the center portion of the three adjacent flow path forming recesses 43 is positioned at the center portion of the one flow path forming recess portion 53 facing, and the center portions of the three adjacent flow path forming recess portions 53 are The liquid Li and the gas E, which are to be stirred, are positioned between the two flow path forming recesses 43 and 53 in the center of the one flow path forming recess 43 facing each other.
- outflow port 38 opened over the perimeter of an outer periphery is formed as the outflow part between the outer peripheral part 42 of the movable side stirring body 23, and the outer peripheral part 52 of the stationary side stirring body 24. As shown in FIG. The mixed and stirred mixture flows out from the outlet 38.
- the movable side stirring body 23 is connected to the drive shaft 4 while maintaining a constant gap t between the movable side stirring body 23 and the fixed side stirring body 24. It is integrally rotated in the rotation direction X (clockwise in plan view).
- the liquid Li and the gas E which are to be stirred, are separated (dispersed) while meandering in the stirring channel 36 in the vertical direction from the inlet 35 on the central side toward the outlet 38 on the outer peripheral edge by centrifugal force.
- the merging aggregation
- the gas E and the liquid Li flowing in the meandering direction are subjected to a shearing action in the meandering direction and a cutting action in the rotation direction X of the movable stirring body 23.
- the liquid Li and the gas E are mixed and stirred by flowing while being subjected to a shearing action and a cutting action in the resultant direction of the meandering direction and the rotational direction X, and the ultrafine refinement of the gas E in the liquid Li Uniformity is achieved steadily.
- the movable-side stirring body 23 and the fixed-side stirring body 24 are relatively displaced around the axis, the area where the flow path forming concave portion 43 and the flow path forming concave portion 53 communicate with each other is periodically changed. To do. That is, the flow is divided (dispersed) into two flow path forming recesses 53 (43) facing from one flow path forming recess 43 (53), and is also faced from the two flow path forming recesses 43 (53).
- the communication area at the time of merging (collecting) into one flow path forming recess 53 (43) periodically changes. Therefore, the liquid Li and the gas E, which are the objects to be stirred, repeatedly form a pulsating flow.
- the pulsating flow is a flow in which the flow path cross-sectional area changes periodically.
- a local high pressure portion and a local low pressure portion are generated in the fluid.
- a low-pressure part for example, a negative pressure part such as a vacuum part
- foaming phenomenon occurs, gas is generated in the liquid, or minute bubbles expand (explode).
- cavitation occurs in which the generated gas (bubbles) collapses (disappears).
- a stepped fitting concave portion 27 of the casing body 21 formed in the same manner is fitted to the lower portion of the casing body 21 formed as described above from below through an O-ring. By doing so, the two fluid stirring parts 20, 20 are connected in a close contact state.
- the pump chamber 60 has a pump chamber 62 formed in the casing body 61 as shown in FIGS.
- An impeller 63 is disposed in the pump chamber 62, and the center portion of the impeller 63 is attached to the lower end portion of the drive shaft 4.
- the casing body 61 is formed in a box shape with an upper surface opening by placing a cylindrical peripheral wall forming piece 64 having an axis line in the vertical direction on a disc-like bottom forming piece 65. is doing.
- the lower end portion of the peripheral wall forming piece 64 is detachably fitted in a groove portion 81 formed in the peripheral edge portion of the bottom portion forming piece 65.
- a stepped fitting recess 66 is formed on the peripheral edge of the upper end of the peripheral wall forming piece 64.
- Reference numeral 85 denotes a cylindrical support leg piece integrally formed on the peripheral edge of the bottom surface of the bottom forming piece 65.
- Reference numeral 86 denotes a plurality of inflow openings formed in the peripheral wall of the support leg 85, and the liquid Li in the liquid storage part B is sucked into the suction port 70 through the inflow openings 86.
- the stepped fitting concave portion 66 is connected to the lower portion of the casing body 21 located at the lowermost step through an O-ring (not shown) so as to be in close contact. ing.
- a bearing portion 67 for receiving the lower end portion of the drive shaft 4 is provided at a position near the center of the bottom portion forming piece 65 so as to bulge downward.
- the impeller 63 is disposed so as to rotate integrally with the drive shaft 4 on the bottom forming piece 65, and is disposed above the bearing portion 67.
- the bearing portion 67 is formed of a cylindrical peripheral wall forming piece 68 whose axis is directed in the vertical direction, and a disc-shaped bearing forming piece 69 stretched on the lower end of the peripheral wall forming piece 68.
- a plurality of suction ports 70 are formed in the peripheral wall forming piece 68 at intervals in the circumferential direction.
- a suction passage 71 for sucking fluid into the pump chamber 62 through the suction port 70 is formed by the rotation of the impeller 63.
- the bearing forming piece 69 is formed with a pivotal recess, and the lower end of the drive shaft 4 is pivotally supported by a bearing 72 disposed in the pivotal recess.
- a swirling flow guide body 73 is integrally formed on the bottom forming piece 65, as shown in FIGS. 25 and 28, a swirling flow guide body 73 is integrally formed.
- the swirl flow guide body 73 has a guide side surface 82 that guides the fluid swirled by the rotation of the impeller 63 in the swivel direction, and the guide side surface 82 is formed to be curved in the guide direction.
- a swirl flow path 74 is formed along the swirl flow guide body 73.
- a discharge flow path forming body 75 is disposed on the swirling flow guide body 73.
- the discharge flow path forming body 75 includes a disk-shaped shielding piece 76 that shields a portion directly above the impeller 63, and a bottom portion of the casing body 21 that positions the shielding piece 76 at the lowest level. It is formed from four attachment pieces 77 attached to the formation piece 26 in a hanging manner. A discharge passage 78 is formed between the shielding piece 76 and the bottom forming piece 26 so as to flow upward on the drive shaft 4 side and along the drive shaft 4. 79 is a screw.
- the upstream end of the swirl flow path 74 communicates with the downstream end of the suction flow path 71
- the upstream end of the discharge flow path 78 communicates with the downstream end of the swirl flow path 74
- the downstream end of the discharge flow path 78 The communication holes 33, 34 communicate with the agitation channel 36
- the communication holes 33, 34 communicate with the agitation channel 36.
- the communication hole 80 communicates with the communication holes 33 and 34 of the second stage fluid agitation unit 20 via the communication channel 80
- the communication holes 33 and 34 communicate with the agitation channel 36, and finally the unloading hose 17.
- a series of continuous flow paths communicating with each other are formed. Mixing / stirring is performed firmly in two stirring channels 36 in the continuous channel.
- 87 is a hook-like locking piece projecting outward from the upper part of the support leg piece 85.
- the locking piece 87 is formed with four bolt insertion holes 89 penetrating in the vertical direction at intervals in the circumferential direction.
- the mounting bolts 12 are inserted into the respective bolt insertion holes 89 from below, and the heads of the mounting bolts 12 are locked to the locking pieces 87 from below to be mounted on the female screw portions 14 formed on the mounting body 10.
- Reference numeral 88 denotes a reinforcing piece.
- the fluid agitation unit S can release the sandwiched state of the fluid agitation units 20 and 20 by removing the tip of the mounting bolt 12 screwed to the female screw part 14 of the mounting body 10. Then, the fluid agitating unit 20 and the pump chamber 60 that are interlocked and connected to the drive shaft 4 in a skewered manner are slid downward along the drive shaft 4 so that they can be removed from the drive shaft 4. . Moreover, the fluid stirring parts 20 and 20 can be made into the clamping state by following the reverse procedure. Therefore, the fluid stirring unit 20 stacked in a heavy box shape can be freely attached to and detached from the drive shaft 4, and the number of the increase / decrease adjustment operations can be easily performed.
- reference numeral 90 denotes a pipe-like fluid supply unit, and a distal end side supply body 91 is attached to the casing body 61 so as to protrude inward.
- the body 92 is connected in communication, and the base end side supply body 92 is piped along the peripheral wall forming piece 25.
- a required amount of gas E such as nitrogen, oxygen, or air is supplied from the fluid supply unit 90 into the casing body 21.
- the liquid Li and the gas E are sucked from the inflow port 35 by the discharge pressure from the pump chamber 60 and the suction pressure by the rotation of the movable stirring body 23. Then, it flows into the stirring channel 36 and is mixed and stirred by flowing in the radial direction and the rotational direction X, and flows out from the outlet 38 which is the end of the stirring channel 36 into the stirring chamber 22 as a mixture. Is done.
- the mixture that has flowed into the stirring chamber 22 is carried out to a required place through the carrying-out hose 17.
- the gas E since the gas E is supplied from the downstream side of the pump chamber 60, it is possible to avoid the gas E from adversely affecting the impeller 63 and the like of the pump chamber 60.
- At least one of the movable-side stirring body 23 and the fixed-side stirring body 24 disposed in the facing state can be adjusted to advance and retract in the facing direction, and the constant gap t facing each other can be adjusted. Then, according to the type of gas E or solid that is to be mixed and stirred with the liquid Li, it is possible to achieve appropriate ultrafineness and uniformity by adapting the constant gap t. For example, by adjusting the vertical mounting position of the cylindrical connecting piece 45 shown in FIG. 32 on the drive shaft 4 via the fixing bolt 47, the movable side stirring body 23 is moved back and forth with respect to the fixed side stirring body 24. Can be adjusted.
- the fixed-side stirring body 24 can be rotated integrally by connecting the movable-side stirring body 23 to the movable-side stirring body 23 with a connecting screw or the like in the above-described basic form without being connected to the support main piece 31. It can also be.
- the liquid Li and the gas E flow in the radiation direction while meandering in the vertical direction along the stirring flow path 36 by centrifugal force. At this time, the liquid Li and the gas E are flowed while receiving a shearing action.
- both the stirring bodies 23 and 24 which rotate integrally can be applied also when a plurality of stirring chambers 22 are continuously formed in the axial direction of the drive shaft 4.
- the movable side stirring body 23 and the fixed side stirring body 24 are arranged in the upper stage (downstream side) stirring chamber 22 to rotate only the movable side stirring body 23, while the lower stage (upstream side) stirring chamber. It is also possible to arrange both stirring bodies 23 and 24 that rotate integrally in 22.
- the gas E is refined by the two stirring bodies 23 and 24 that rotate integrally in the lower stirring chamber 22, and both the stirring bodies 23 in which only the movable stirring body 23 rotates in the upper stirring chamber 22. , 24, the gas E can be further refined by further stirring.
- both the stirring bodies 23 and 24 which rotate integrally in the upper and lower stirring chambers 22 can be arranged.
- a baffle plate (not shown) extending in the vertical direction is disposed in the stirring chamber 22, and the baffle plate is allowed to act on the mixture that flows out of the outlet 38 and turns into a swirling flow, whereby the mixture Can be a turbulent flow that also flows in the vertical direction.
- the homogenization (homogenization) of the mixture is improved.
- FIGS. 33 to 39 show a fluid agitating unit S as a second embodiment, which has the same basic structure as the first embodiment, but is a connection structure between the upper and lower casing bodies 21, 21. And the fixing structure of the fixed stirring member 24 are greatly different.
- the casing body 21 has an upper connecting piece 100 and a lower connecting piece 110 formed in a bowl shape at the upper peripheral edge and the lower peripheral edge of a cylindrical peripheral wall forming piece 25 whose axis is directed in the vertical direction. It is formed by overhanging.
- the upper connecting piece 100 has an upper surface 101 formed as a flat surface, and the upper surface 101 is positioned slightly below the upper end surface 102 of the peripheral wall forming piece 25.
- a fitting recess 27 is formed by the upper surface 101 and the outer peripheral surface of the upper end portion of the peripheral wall forming piece 25.
- An O-ring insertion groove 103 is formed in the inner peripheral edge of the upper surface 101, and the O-ring 104 is inserted into the O-ring insertion groove 103.
- the lower connecting piece 110 forms a fitting recess 111 into which the upper edge 105 of the peripheral wall forming piece 25 is fitted at the inner peripheral edge, and a fitting convex 112 to be fitted into the fitting recess 27 at the outer peripheral edge. is doing.
- a connection hole 188 for connecting the carry-out hose 17 is provided in the uppermost casing body 21.
- the lower casing body 21 is formed in the fitting recess 111 of the lower connecting piece 110 formed in the upper casing body 21.
- the upper peripheral edge portion 105 of the peripheral wall forming piece 25 is fitted, and the upper connecting piece 100 formed on the lower casing body 21 is fitted to the fitting convex portion 112 of the lower connecting piece 110 formed on the upper casing body 21.
- the combination recess 27 is fitted from below.
- the upper and lower casing bodies 21 and 21 are integrated with each other by tightening (fastening) the upper and lower connecting pieces 100 and 110 with a fastening connector (so-called clamp band) 200.
- a fastening connector so-called clamp band
- the fixed-side agitator 24 includes a ring-plate-like support 120 connected to the lower surface of the fixed-side main body 50 in a superposed state, and the outer peripheral edge 121 of the support 120 is placed outside. It has an overhanging shape (saddle shape).
- the outer peripheral edge 121 of the support body 120 is disposed in the fitting recess 111 of the lower connecting piece 110 formed in the upper casing body 21 and is formed in the lower casing body 21 fitted in the fitting recess 111.
- the upper and lower connecting pieces 100 and 110 are integrally fastened by the fastening connector 200 by bringing the upper end peripheral edge portion 105 of the peripheral wall forming piece 25 into contact with the lower surface of the outer peripheral edge portion 121 of the support 120.
- the outer peripheral edge 121 of the body 120 is fixed in a clamped state by the upper and lower connecting pieces 100 and 110.
- the support 120 is sandwiched between the upper and lower casing bodies 21 and 21 and fastened integrally. Moreover, the support body 120 can also be removed simultaneously by releasing the fastening between the casing bodies 21 and 21. Therefore, the disassembling and assembling work when performing the cleaning work and the maintenance work can be easily and quickly performed.
- the drive shaft 4 of the second embodiment is linked to the output shaft 6 of the electric motor unit 1 as shown in FIG. That is, the output shaft 6 protrudes downward from the lower end surface portion 3 of the motor case 2, and the upper end portion of the drive shaft 4 formed by extending vertically from the lower end portion of the output shaft 6 via the interlocking coupling body 130 is detachable. It is linked to.
- Reference numeral 131 denotes a drive shaft support. The drive shaft support 131 is interposed between the lower end surface portion 3 of the electric motor case 2 and the mounting body 10, and the upper portion of the drive shaft 4 is rotated about the vertical axis. Supports freely.
- An insertion hole 132 through which the drive shaft 4 is inserted is formed in the central portion of the attachment body 10.
- Reference numeral 140 denotes an upper halfway bearing portion that is suspended from the mounting body 10.
- the midway bearing portion 140 hangs a cylindrical peripheral wall forming piece 141 from the mounting body 10, and a bush 143 via a bush support piece 142 at the lower end of the inner peripheral surface of the peripheral wall forming piece 141 as shown in FIG. And the bush 143 receives the middle part of the drive shaft 4 in a freely rotatable manner.
- a lower connecting piece 144 is formed in a flange shape at the lower end of the outer peripheral surface of the peripheral wall forming piece 141.
- the lower connecting piece 144 forms an indentation recess 145 into which the upper peripheral edge 105 of the peripheral wall forming piece 25 formed in the casing body 21 is fitted in the inner peripheral edge, and the fitting recess 27 of the casing body 21 in the outer peripheral edge.
- a fitting convex portion 146 to be fitted is formed.
- the upper end of the peripheral wall forming piece 25 formed in the casing body 21 is fitted into the fitting recess 145 of the lower connecting piece 144 formed in the peripheral wall forming piece 141.
- the peripheral portion 105 is inserted, and the fitting concave portion 27 of the upper connecting piece 100 formed in the casing body 21 is fitted from below to the fitting convex portion 146 of the lower connecting piece 144 formed in the peripheral wall forming piece 141.
- the upper and lower connecting pieces 100 and 144 are fastened by the fastening connector 200 to integrally connect the upper and lower casings 21 to each other.
- Stepped small diameter portions 149 to 153 are formed at positions where the movable-side stirring body 23, which is the middle portion of the drive shaft 4, is attached.
- the stepped small diameter portions 149 to 153 formed in five steps are formed so as to gradually become smaller diameter steps downward so that each movable-side stirring body 23 and the impeller 154 can be positioned. That is, as shown in FIGS. 34 and 35, the inner diameter of the drive shaft insertion hole 44 of the cylindrical connecting piece 45 of each movable side stirring body 23 is matched to the outer diameter of each stepped small diameter portion 149 to 153, The upward sliding is regulated.
- the pump chamber part 60 forms a pump chamber 62 in the casing body 61 as shown in FIGS. 35 and 38.
- An impeller 154 is disposed in the pump chamber 62, and the central portion of the impeller 154 is attached to the lower end portion of the drive shaft 4.
- the casing body 61 is formed by projecting an upper connecting piece 170 like a bowl on the upper outer peripheral surface of a cylindrical peripheral wall forming piece 160 whose axis is directed in the vertical direction.
- the upper connecting piece 170 has an upper surface 171 formed as a flat surface, and the upper surface 171 is positioned slightly below the upper end surface of the peripheral wall forming piece 160.
- a fitting recess 172 is formed by the upper surface 171 and the outer peripheral surface of the upper end portion of the peripheral wall forming piece 160.
- An O-ring insertion groove 174 is formed on the inner peripheral edge of the upper surface 171, and the O-ring 173 is inserted into the O-ring insertion groove 174.
- the peripheral wall forming piece 160 formed in the lower casing body 61 is inserted into the fitting recess 111 of the lower connecting piece 110 formed in the casing body 21.
- the upper peripheral edge 161 of the upper connecting piece 170 is fitted into the fitting convex portion 112 of the lower connecting piece 110 formed on the casing body 21, and the fitting concave portion 172 of the upper connecting piece 170 formed on the casing body 61 is fitted from below.
- the upper and lower connecting pieces 170 and 110 are fastened by the fastening connector 200 to integrally connect the upper and lower casing bodies 21 and 61 to each other.
- a lower end bearing portion 180 is attached to the lower portion of the inner peripheral surface of the casing body 61.
- the lower end bearing portion 180 includes a cylindrical attachment piece 181 attached to the inner peripheral surface of the peripheral wall forming piece 160 in a superposed state, a ring plate-like bearing peripheral portion 182 provided continuously with the upper surface of the attachment piece 181, and a bearing peripheral portion 182. It is formed from the bearing center part 184 attached to the center part of this through the support piece 183.
- the lower end portion of the drive shaft 4 is supported by the bearing center portion 184.
- Reference numeral 185 denotes a suction port formed between the bearing peripheral part 182 and the bearing center part 184 via a support piece 183.
- Reference numeral 186 denotes a screw for detachably connecting the peripheral wall forming piece 160 and the mounting piece 181.
- Reference numeral 187 denotes an attachment hole for attaching the fluid supply part 90.
- the fluid stirring part S as a mixing stirring apparatus was demonstrated, it replaced with the gas used as mixing stirring object from the fluid supply part 90, and suitably supplied solids, such as a liquid or a granule, powder. Therefore, it can be applied as a required mixing and stirring device.
- a Nitrogen treated water generation device A1 Oxygen emission / release promotion means A2 Nitrogen nanobubble mixing promotion means J Circulation pipe K Treated water supply part M Fluid mixing treatment part N Nitrogen gas supply part P Pressure pump R Circulation flow path S Fluid stirring part T Tank V Pressure regulating valve W Treated water
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Abstract
Description
20℃(293K)、1気圧(0.1013MPa)において、純水への純酸素と純窒素の溶解度は、それぞれ44.4g/m3(44.4mg/L)と19.4g/m3(19.4mg/L)であり、酸素の方が2.3倍溶解する。大気中の酸素の割合は21%であるので、20℃、1気圧において空気が水に溶解するときは、酸素の溶解度は(44.4×0.21=)9.3mg/Lで、窒素の溶解度は(19.4×0.79=)15.3mg/Lとなり,窒素の方が1.7倍よく溶ける。これは酸素と窒素の分圧の差による。 (1) Absorption (dissolution) of oxygen in water and release of oxygen from water in which oxygen is dissolved At 20 ° C (293K) and 1 atmosphere (0.1013 MPa), the solubility of pure oxygen and pure nitrogen in pure water is are each 44.4g / m 3 (44.4mg / L ) and 19.4g / m 3 (19.4mg / L ), towards the oxygen is 2.3 times dissolution. Since the proportion of oxygen in the atmosphere is 21%, when air dissolves in water at 20 ° C. and 1 atm, the solubility of oxygen is (44.4 × 0.21 =) 9.3 mg / L and the solubility of nitrogen is (19.4 × 0.79 =) 15.3mg / L, and nitrogen dissolves 1.7 times better. This is due to the difference in partial pressure between oxygen and nitrogen.
気液の接触形態として連続相(液)中の気泡群とする。液は溶存酸素濃度DO0の水、気泡は純窒素気泡の気液接触を考える。純窒素中の酸素分圧は0であるので、液中から気泡中へ酸素が放散する。換言すると、溶存酸素が窒素気泡に取り込まれる(酸素放散)。気泡の容積は有限であるので、酸素の放散につれて気泡中の酸素分圧は上昇する。酸素が放散した気泡(ナノバブルよりも大径の気泡)は液中を上昇し,ついには液から脱出する(気泡消滅)が、液が充分に深いと気泡が液に滞在する間に、気泡中の酸素分圧と液(水)中の酸素濃度の間で平衡(気液平衡)が成立する。そのとき酸素の放散は停止する。しかし,気液平衡が成り立つまで気泡が滞在するほど液深は大きくなく、むしろ現実的な深さの水相では、気液平衡に達するはるか以前に気泡(ナノバブルよりも大径の気泡)は液から脱出する。 (2) About the ventilation | gas_flowing of nitrogen to water It is set as the bubble group in a continuous phase (liquid) as a gas-liquid contact form. The liquid is water having a dissolved oxygen concentration of DO 0 , and the bubbles are considered to be gas-liquid contact with pure nitrogen bubbles. Since the oxygen partial pressure in pure nitrogen is 0, oxygen is diffused from the liquid into the bubbles. In other words, dissolved oxygen is taken into nitrogen bubbles (oxygen dissipation). Since the volume of the bubble is finite, the oxygen partial pressure in the bubble increases as oxygen is released. Bubbles in which oxygen is released (bubbles with a larger diameter than nanobubbles) rise in the liquid and eventually escape from the liquid (bubble disappearance), but if the liquid is deep enough, while the bubbles stay in the liquid, Equilibrium (gas-liquid equilibrium) is established between the oxygen partial pressure and the oxygen concentration in the liquid (water). At that time, the release of oxygen stops. However, the liquid depth is not so great that the bubbles stay until gas-liquid equilibrium is established. Rather, in the water phase at a realistic depth, the bubbles (bubbles larger in diameter than nanobubbles) are liquid before the gas-liquid equilibrium is reached. Escape from.
一般に、ナノバブルは生体に対して細胞レベルで何らかの影響を与える可能性がある。このため,窒素ナノバブルは生鮮食品、例えば、魚介類の表面にとどまらず、体内まで効果が及ぶので、体内の好気性が低下する。したがって、少なくとも体内の好気的バクテリアの増殖が抑制されるものと期待される。窒素ナノバブル含有窒素処理水は、魚介類に対してその表面だけでなく、体内に生息する好気性バクテリアの増殖を著しく抑制して、魚介類の鮮度を保つ(魚介類の鮮度の指標値であるK値を低く保つ)ことが期待できる。ここで、K値とは、ATP関連化合物全体に占めるイノシン(HxR)とヒポキサンチン(Hx)の割合である。魚肉のATPは、死後ATP→ADP→AMP→IMP→HxR→Hxの経路で分解するので、HxRやHxの割合が低い程鮮度が良いとされる。刺身用に適当とされているK値は20%以下である。 (3) Nitrogen nanobubbles (nanobubbleized nitrogen gas) In general, nanobubbles may have some influence on the living body at the cellular level. For this reason, the nitrogen nanobubbles are not limited to the surface of fresh foods, for example, seafood, but are effective in the body, so the aerobic properties in the body are reduced. Therefore, it is expected that at least the growth of aerobic bacteria in the body is suppressed. Nitrogen-treated water containing nitrogen nanobubbles significantly suppresses the growth of aerobic bacteria that inhabit the body as well as the surface of fish and shellfish, and maintains the freshness of fish and shellfish (this is an indicator of the freshness of fish and shellfish K value can be kept low). Here, the K value is the ratio of inosine (HxR) and hypoxanthine (Hx) in the entire ATP-related compound. Since ATP of fish meat is decomposed by the route of ATP → ADP → AMP → IMP → HxR → Hx after death, the lower the ratio of HxR or Hx, the better the freshness. The K value suitable for sashimi is 20% or less.
図1に示すAは本発明に係る第1実施形態としての窒素処理水生成装置である。かかる窒素処理水生成装置Aは、処理水Wを収容したタンクTの底部に循環パイプJの基端部を連結し、循環パイプJの先端部をタンクT内の処理水W中に上面から挿入して循環流路Rを形成している。 [Description of Nitrogen Treated Water Generation Apparatus as First Embodiment]
A shown in FIG. 1 is a nitrogen treated water generator as a first embodiment according to the present invention. The nitrogen treated water generator A connects the base end of the circulation pipe J to the bottom of the tank T containing the treated water W, and inserts the tip of the circulation pipe J into the treated water W in the tank T from above. Thus, the circulation flow path R is formed.
次に、第1実施形態に係る窒素処理水生成方法について説明する。すなわち、第1実施形態に係る窒素処理水生成方法は、窒素ガス・処理水混合工程と収容工程と酸素脱出工程とを有する。窒素ガス・処理水混合工程は、流体混合処理部Mにより処理水Wと純窒素ガスの気液混相にせん断力を作用させて純窒素ガスを超微細な気泡を有する気泡群となして処理水Wと混合する工程である。収容工程は、窒素ガス・処理水混合工程で得られた気泡群混じりの処理水をタンクT内に収容する工程である。酸素脱出工程は、収容工程でタンクT内に収容した処理水W中に溶存している酸素を微細な気泡となした純窒素ガスに放散させることで、酸素が放散した微細な窒素ガスを処理水W中にて浮上させるとともに、処理水Wから酸素を脱出させる工程である。 [Description of Method for Generating Nitrogen Treated Water as First Embodiment]
Next, the nitrogen treated water generation method according to the first embodiment will be described. That is, the nitrogen treated water generation method according to the first embodiment includes a nitrogen gas / treated water mixing step, a containing step, and an oxygen escape step. In the nitrogen gas / treated water mixing step, a shear force is applied to the gas-liquid mixed phase of the treated water W and the pure nitrogen gas by the fluid mixing treatment unit M to make the pure nitrogen gas into a group of bubbles having ultrafine bubbles. It is a step of mixing with W. The storing step is a step of storing the treated water mixed with bubbles obtained in the nitrogen gas / treated water mixing step in the tank T. In the oxygen escape process, the oxygen dissolved in the treated water W stored in the tank T in the storing process is diffused into the pure nitrogen gas formed into fine bubbles, thereby processing the fine nitrogen gas from which oxygen has been released. It is a step of floating oxygen in the water W and escaping oxygen from the treated water W.
図3に示すAは本発明に係る第2実施形態としての窒素処理水生成装置である。かかる窒素処理水生成装置Aは、酸素放散・放出促進手段A1と窒素ナノバブル混合促進手段A2を備えている。そして、本実施形態の窒素処理水生成装置Aでは、酸素放散・放出促進手段A1による酸素放散・放出促進工程と、窒素ナノバブル混合促進手段A2による窒素ガス超微細化促進工程との二段階工程を順次経ることで、窒素処理水を効率良く生成することができる。 [Description of Nitrogen Treated Water Generation Device as Second Embodiment]
A shown in FIG. 3 is a nitrogen treated water generating apparatus as a second embodiment according to the present invention. The nitrogen-treated water generating apparatus A includes oxygen diffusion / release promotion means A1 and nitrogen nanobubble mixing promotion means A2. And in the nitrogen treated water production | generation apparatus A of this embodiment, the two-stage process of the oxygen diffusion / release promotion process by the oxygen diffusion / release promotion means A1 and the nitrogen gas ultra-fine refinement promotion process by the nitrogen nanobubble mixing promotion means A2 is performed. By sequentially passing, nitrogen-treated water can be efficiently generated.
次に、第2実施形態に係る窒素処理水生成方法について説明する。すなわち、第2実施形態に係る窒素処理水生成方法は、酸素放散・放出促進工程と窒素ガス超微細化促進工程を有する。前段工程である酸素放散・放出促進工程は、処理水Wを脱酸素化して窒素処理水を生成する工程である。かかる工程では、処理水W中に純窒素ガスを、例えば、50μm~100μmの窒素マイクロバブルとなして混入させることで、窒素マイクロバブルにより溶存酸素濃度を効率的に下げることができる(例えば、DO値=1mg/Lまで)。つまり、効率的に処理水Wの脱酸素化を実現することができる。後段工程である窒素ガス超微細化促進工程は前段工程で生成された窒素処理水に窒素ナノバブルを蓄積する工程である。かかる工程では、窒素処理水中に、例えば、50nm~900nmの窒素ナノバブルを効率良く蓄積することができて、窒素ナノ処理水を堅実に生成することができる。この際、溶存酸素濃度をさらに低減させることができる(例えば、DO値=0.5mg/L前後まで)。 [Description of Nitrogen Treated Water Generation Method as Second Embodiment]
Next, a method for generating nitrogen-treated water according to the second embodiment will be described. That is, the nitrogen treated water generating method according to the second embodiment includes an oxygen diffusion / release promotion step and a nitrogen gas ultrafine refinement promotion step. The oxygen diffusion / release promotion step, which is the preceding step, is a step of deoxygenating the treated water W to generate nitrogen treated water. In such a process, pure nitrogen gas is mixed into the treated water W as nitrogen microbubbles of, for example, 50 μm to 100 μm, so that the dissolved oxygen concentration can be efficiently lowered by the nitrogen microbubbles (for example, DO (Values up to 1 mg / L). That is, deoxygenation of the treated water W can be realized efficiently. The subsequent nitrogen gas ultrafine refinement promoting process is a process of accumulating nitrogen nanobubbles in the nitrogen treated water generated in the preceding process. In this process, for example, nitrogen nanobubbles of 50 nm to 900 nm can be efficiently accumulated in the nitrogen-treated water, and the nitrogen nano-treated water can be generated steadily. At this time, the dissolved oxygen concentration can be further reduced (for example, up to around DO value = 0.5 mg / L).
次に、前記した第1・第2実施形態に係る窒素処理水生成装置Aにより生成した窒素処理水により生鮮魚介類を鮮度保持処理(加工)する方法(生鮮魚介類の鮮度保持処理法)について説明する。
生鮮魚介類の鮮度保持処理法は、基本的に、窒素処理水中に生鮮魚介類を一定時間浸漬させて処理するものである。そして、本実施形態では第1~第4の鮮度保持処理法がある。 [Freshness preservation method for fresh seafood]
Next, a method for maintaining (processing) fresh fish and shellfish using the nitrogen-treated water generated by the nitrogen-treated water generating apparatus A according to the first and second embodiments described above (fresh fish keeping method for fresh fish and shellfish) explain.
The freshness-keeping method for fresh fishery products basically involves treating fresh fishery products by immersing them in nitrogen-treated water for a certain period of time. In the present embodiment, there are first to fourth freshness maintaining methods.
第3の鮮度保持処理法を具体的に説明すると、図4に示すように、鮮度保持処理を施す生鮮魚介類としての鮮魚Fiを準備する準備工程(a)と、準備した鮮魚Fiを窒素処理水Wn中に浸漬する生鮮魚介類浸漬工程(b)と、窒素処理水Wn中から鮮魚Fiを取り出す取出工程(c)と、取り出した鮮魚Fiを容器Ca内に収容して脱気する脱気工程(d)と、脱気した鮮魚Fiを容器Ca中に密封する密封工程(e)と、容器Ca中に密封した鮮魚Fiを冷蔵する冷蔵工程(f)とを有する。 In the third freshness-keeping treatment method, fresh seafood is immersed in nitrogen-treated water for a certain period of time (for example, 1 hour), and then the fresh seafood is stored in a bag-type container and the inside of the bag-type container is deaerated. And then refrigerated in the refrigerator in the deaerated and sealed state. Here, the constant temperature for refrigeration is not particularly limited as long as it can be stored after being cooled to a low temperature that does not freeze fresh fish and shellfish, and is preferably a temperature between 0 ° C. and 4 ° C. The time for refrigeration can be set within 192 hours depending on the desired freshness of fresh seafood.
The third freshness-keeping treatment method will be described in detail. As shown in FIG. 4, a preparation step (a) for preparing fresh fish Fi as fresh seafood to be subjected to freshness-keeping treatment, and nitrogen treatment of the prepared fresh fish Fi Fresh fish and shellfish immersion step (b) immersed in water Wn, extraction step (c) for extracting fresh fish Fi from nitrogen-treated water Wn, and deaeration for accommodating the extracted fresh fish Fi in a container Ca and deaeration It includes a step (d), a sealing step (e) for sealing the deaerated fresh fish Fi in the container Ca, and a refrigeration step (f) for refrigeration of the fresh fish Fi sealed in the container Ca.
=(π/6)(120×10-9)3
=9.05×10-22m3
=9.05×10-16cm3
7.12×108個のナノ気泡の体積
=7.12×108×9.05×10-16
=6.44×10-7cm3
したがって、ナノ気泡の体積分率
=6.44×10-7cm3/cm3≒10-6(1ppm弱) Volume of one bubble having a mode diameter of 120 nm = (π / 6) (120 × 10 −9 ) 3
= 9.05 × 10 −22 m 3
= 9.05 × 10 −16 cm 3
7.12 × 10 8 nanobubbles volume = 7.12 × 10 8 × 9.05 × 10 −16
= 6.44 × 10 −7 cm 3
Therefore, the volume fraction of nanobubbles = 6.44 × 10 −7 cm 3 / cm 3 ≈10 −6 (less than 1 ppm)
〔第1実施形態としての流体混合処理部M〕
第1実施形態としての流体混合処理部Mは、図13~図16に示すように、一方向(本実施形態では左右方向)に伸延する上下一対の横長四角形板状の混合エレメント210,220を重合状態に対面させて、両混合エレメント210,220間にその伸延方向に伸延する混合流路230を形成している。 [Configuration of fluid mixing processing unit M]
[Fluid Mixing Processing Unit M as First Embodiment]
As shown in FIGS. 13 to 16, the fluid mixing processing unit M as the first embodiment includes a pair of upper and lower horizontal rectangular plate-
第2実施形態としての流体混合処理部Mは、第1実施形態としての流体混合処理部Mと基本的構造を同じくするが、図19に示すように、上下一対の混合エレメント210,220間に、これら混合エレメント210,220よりも薄肉板状の中間混合エレメント280を一枚介在させて、これらの混合エレメント210,220,280を積層状態となしている点で異なる。 [Fluid Mixing Processing Unit M as Second Embodiment]
The fluid mixing processing unit M as the second embodiment has the same basic structure as the fluid mixing processing unit M as the first embodiment, but as shown in FIG. The
第3実施形態としての流体混合処理部Mは、第1実施形態としての流体混合処理部Mと基本的構造を同じくするが、図20及び図21に示すように、上下一対の混合エレメント210,220間に、これら混合エレメント210,220よりも薄肉板状の中間混合エレメント290,291を二枚介在させて、これらの混合エレメント210,220,290,291を積層状態となしている点で異なる。 [Fluid Mixing Processing Unit M as Third Embodiment]
The fluid mixing processing unit M as the third embodiment has the same basic structure as the fluid mixing processing unit M as the first embodiment, but as shown in FIGS. 20 and 21, a pair of upper and
第4実施形態としての流体混合処理部Mは、第1実施形態としての流体混合処理部Mと基本的構造を同じくするが、図22及び図23に示すように、上下一対の混合エレメント210,220間に、これら混合エレメント210,220よりも薄肉板状の中間混合エレメント290を一枚介在させて、これらの混合エレメント210,220,290を積層状態となしている点で異なる。ここで、混合エレメント220の上面には混合流路形成パターン面Pbに代えて混合流路形成パターン面Paを形成している。 [Fluid Mixing Processing Unit M as Fourth Embodiment]
The fluid mixing processing unit M as the fourth embodiment has the same basic structure as the fluid mixing processing unit M as the first embodiment, but as shown in FIGS. 22 and 23, a pair of upper and
第5実施形態としての流体混合処理部Mは、第3実施形態としての流体混合処理部Mと基本的構造を同じくするが、図24に示すように、上下一対の混合エレメント210,220間に、これら混合エレメント210,220よりも薄肉板状の中間混合エレメント280,290,291を介在させて、これらの混合エレメント210,220,280,290,291を積層状態となしている点で異なる。 [Fluid Mixing Processing Unit M as Fifth Embodiment]
The fluid mixing processing unit M as the fifth embodiment has the same basic structure as the fluid mixing processing unit M as the third embodiment, but as shown in FIG. These are different in that these mixing
〔第1実施形態としての流体撹拌部S〕
図25は第1実施形態としての流体撹拌部Sを示している。Bは貯液部である。貯液部Bには水等の液体Liを貯留させて、液体Li中に流体撹拌部Sを配置している。Loは貯液部Bの底面部である。なお、貯液部Bは処理対象となる液体Liを人工的に貯留しているタンク等に限らず、処理対象となる液体Liが自然に貯留されている湖等も含むものである。 [Configuration of fluid stirring unit S]
[Fluid Stirring Unit S as First Embodiment]
FIG. 25 shows a fluid stirring unit S as the first embodiment. B is a liquid storage part. The liquid storage part B stores liquid Li such as water, and the fluid stirring part S is disposed in the liquid Li. Lo is a bottom surface portion of the liquid storage portion B. The liquid reservoir B is not limited to a tank or the like that artificially stores the liquid Li to be processed, but also includes a lake or the like in which the liquid Li to be processed is naturally stored.
図33~図39は、第2実施形態としての流体撹拌部Sであり、前記した第1実施形態と基本構造を同じくしているが、上・下側のケーシング体21,21同士の連結構造と固定側撹拌体24の固定構造において大きく異なる。 [Fluid Stirring Unit S as Second Embodiment]
FIGS. 33 to 39 show a fluid agitating unit S as a second embodiment, which has the same basic structure as the first embodiment, but is a connection structure between the upper and
A1 酸素放散・放出促進手段
A2 窒素ナノバブル混合促進手段
J 循環パイプ
K 処理水供給部
M 流体混合処理部
N 窒素ガス供給部
P 圧送ポンプ
R 循環流路
S 流体撹拌部
T タンク
V 圧力調整弁
W 処理水 A Nitrogen treated water generation device A1 Oxygen emission / release promotion means A2 Nitrogen nanobubble mixing promotion means J Circulation pipe K Treated water supply part M Fluid mixing treatment part N Nitrogen gas supply part P Pressure pump R Circulation flow path S Fluid stirring part T Tank V Pressure regulating valve W Treated water
Claims (8)
- 流体を循環させる循環流路と、
循環流路の中途部に設けて処理水を収容するタンクと、
タンクから流出する処理水に窒素ガスを供給すべく循環流路の中途部に接続した窒素ガス供給部と、
窒素ガス供給部から供給された窒素ガスと処理水の気液混相にせん断力を作用させることで、窒素ガスを超微細な気泡を有する気泡群となして処理水と混合すべく循環流路の中途部に設けた流体混合処理部と、
を備え、
流体混合処理部から流出した気泡群混じりの処理水はタンク内に環流させて、タンク内にて処理水中に溶存している酸素を微細な気泡となした窒素ガスに放散させることで、酸素が放散した微細な窒素ガスを処理水中にて浮上させるとともに、処理水から脱出させるようにしたことを特徴とする窒素処理水生成装置。 A circulation channel for circulating the fluid;
A tank that is provided in the middle of the circulation flow path and contains treated water;
A nitrogen gas supply unit connected to the middle part of the circulation flow path to supply nitrogen gas to the treated water flowing out of the tank;
By applying a shearing force to the gas-liquid mixed phase of the nitrogen gas and the treated water supplied from the nitrogen gas supply unit, the circulation flow path is formed so that the nitrogen gas becomes a group of bubbles having ultrafine bubbles and is mixed with the treated water. A fluid mixing processing unit provided in the middle part;
With
The treated water mixed with bubbles that flowed out from the fluid mixing treatment unit is circulated into the tank, and the oxygen dissolved in the treated water in the tank is diffused into nitrogen gas formed into fine bubbles. A nitrogen treated water generating apparatus characterized in that fine nitrogen gas diffused is floated in the treated water and escaped from the treated water. - 流体混合処理部は、循環流路に沿って伸延する一対の板状の混合エレメントを重合状態に対面させて、両混合エレメント間にその伸延方向に伸延する混合流路を形成するとともに、混合流路の始端部に混合エレメントの一側部に形成した流入孔を連通させる一方、混合流路の終端部に混合エレメントの他側部に形成した流出孔を連通させて構成し、
前記混合流路は、前記流入孔から流入した流体を混合流路の伸延方向に流動させて分流させる複数の分流部と、分流部で分流された流体を混合流路の伸延方向に流動させて合流させる複数の合流部とを具備することを特徴とする請求項1記載の窒素処理水生成装置。 The fluid mixing processing unit faces a pair of plate-like mixing elements extending along the circulation flow path in a polymerized state, forms a mixing flow path extending in the extending direction between the mixing elements, and mixes the mixed flow. The inflow hole formed on one side of the mixing element is communicated with the start end of the path, while the outflow hole formed on the other side of the mixing element is communicated with the terminal end of the mixing channel.
The mixing flow path includes a plurality of flow dividing portions that flow the fluid flowing in from the inflow hole in the extending direction of the mixing flow channel and divert the fluid, and the fluid diverted in the flow dividing portion flows in the extending direction of the mixing flow channel. The nitrogen treated water generating apparatus according to claim 1, further comprising a plurality of merging portions to be merged. - 前記混合流路の始端部と前記混合エレメントの一側部に形成した流入孔との間には始端側一時滞留空間を形成するとともに、始端側一時滞留空間は混合流路の始端部と略同一幅に形成して略全幅にわたって混合流路の始端部と連通させる一方、
前記混合流路の終端部と前記混合エレメントの他側部に形成した流出孔との間には終端側一時滞留空間を形成するとともに、終端側一時滞留空間は混合流路の終端部と略同一幅に形成して略全幅にわたって混合流路の終端部と連通させたことを特徴とする請求項2記載の窒素処理水生成装置。 A start-side temporary stay space is formed between the start end of the mixing channel and an inflow hole formed in one side of the mixing element, and the start-side temporary stay space is substantially the same as the start end of the mixing channel. While formed into a width and communicated with the starting end of the mixing channel over substantially the entire width,
A termination-side temporary retention space is formed between the termination portion of the mixing channel and the outflow hole formed in the other side of the mixing element, and the termination-side temporary retention space is substantially the same as the termination portion of the mixing channel. The nitrogen-treated water generating device according to claim 2, wherein the nitrogen-treated water generating device is formed in a width and communicated with a terminal portion of the mixing channel over substantially the entire width. - 処理水と窒素ガスの気液混相にせん断力を作用させて窒素ガスを超微細な気泡を有する気泡群となして処理水と混合する窒素ガス・処理水混合工程と、
窒素ガス・処理水混合工程で得られた気泡群混じりの処理水をタンク内に収容する収容工程と、
収容工程でタンク内に収容した処理水中に溶存している酸素を微細な気泡となした窒素ガスに放散させることで、酸素が放散した微細な窒素ガスを処理水中にて浮上させるとともに、処理水から脱出させる酸素脱出工程と、
を具備することを特徴とする窒素処理水生成方法。 A nitrogen gas / treated water mixing step in which a shear force is applied to the gas-liquid mixed phase of treated water and nitrogen gas to form nitrogen gas into a group of bubbles having ultrafine bubbles and mixed with the treated water;
An accommodating step of accommodating the treated water mixed with bubbles obtained in the nitrogen gas / treated water mixing step in the tank;
The oxygen dissolved in the treated water contained in the tank in the containment process is diffused into the nitrogen gas in the form of fine bubbles, so that the fine nitrogen gas from which oxygen has been diffused floats up in the treated water. Oxygen escape step to escape from,
A method for producing nitrogen-treated water, comprising: - 超微細な気泡を有する気泡群となした窒素ガスを処理水と混合してタンク内に収容し、タンク内にて処理水中に溶存している酸素を微細な気泡となした窒素ガスに放散させることで、酸素が放散した微細な窒素ガスを処理水中にて浮上させるとともに、処理水から脱出させて生成されることを特徴とする窒素処理水。 Nitrogen gas in the form of bubbles with ultrafine bubbles is mixed with the treated water and stored in the tank, and oxygen dissolved in the treated water in the tank is diffused into the nitrogen gas formed into fine bubbles. Thus, the nitrogen-treated water is produced by causing fine nitrogen gas from which oxygen has been released to float in the treated water and escape from the treated water.
- 超微細な気泡を有する気泡群となした窒素ガスを処理水と混合してタンク内に収容し、タンク内にて処理水中に溶存している酸素を微細な気泡となした窒素ガスに放散させることで、酸素が放散した微細な窒素ガスを処理水中にて浮上させるとともに、処理水から脱出させて窒素処理水を生成し、
窒素処理水中に生鮮魚介類を一定時間浸漬させて処理することを特徴とする生鮮魚介類の鮮度保持処理法。 Nitrogen gas in the form of bubbles with ultrafine bubbles is mixed with the treated water and stored in the tank, and oxygen dissolved in the treated water in the tank is diffused into the nitrogen gas formed into fine bubbles. As a result, the fine nitrogen gas from which oxygen was released floats up in the treated water, and escapes from the treated water to produce nitrogen treated water,
A method for preserving freshness of fresh seafood, characterized by immersing fresh seafood in nitrogen-treated water for a certain period of time. - 窒素処理水中に一定時間浸漬させて処理した生鮮魚介類を、収容袋中に収容するとともに収容袋内を脱気して密封し、その脱気・密封状態にて冷蔵処理することを特徴とする請求項6記載の生鮮魚介類の鮮度保持処理法。 Fresh fish and shellfish treated by immersing in nitrogen-treated water for a certain period of time are stored in a storage bag, and the storage bag is deaerated and sealed, and refrigerated in the deaerated and sealed state. The method for maintaining freshness of fresh seafood according to claim 6.
- 窒素処理水中に一定時間浸漬させて処理した生鮮魚介類を、窒素処理水中に浸漬したままの状態で冷凍処理することを特徴とする請求項6記載の生鮮魚介類の鮮度保持処理法。 The method for maintaining the freshness of fresh fish and shellfish according to claim 6, wherein the fresh fish and shellfish that have been soaked in nitrogen-treated water for a certain period of time are frozen while being immersed in the nitrogen-treated water.
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