WO2011153969A2 - Cosmetic polymer gel with healing effects - Google Patents

Cosmetic polymer gel with healing effects Download PDF

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Publication number
WO2011153969A2
WO2011153969A2 PCT/CZ2010/000127 CZ2010000127W WO2011153969A2 WO 2011153969 A2 WO2011153969 A2 WO 2011153969A2 CZ 2010000127 W CZ2010000127 W CZ 2010000127W WO 2011153969 A2 WO2011153969 A2 WO 2011153969A2
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WO
WIPO (PCT)
Prior art keywords
weight percent
amount
agent
polymer gel
solution
Prior art date
Application number
PCT/CZ2010/000127
Other languages
French (fr)
Other versions
WO2011153969A3 (en
Inventor
Oyunchimeg Zandraa
Nabanita Saha
Tomas SÁHA
Original Assignee
Univerzita Tomase Bati Ve Zline
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univerzita Tomase Bati Ve Zline filed Critical Univerzita Tomase Bati Ve Zline
Publication of WO2011153969A2 publication Critical patent/WO2011153969A2/en
Publication of WO2011153969A3 publication Critical patent/WO2011153969A3/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A61P17/02—Drugs for dermatological disorders for treating wounds, ulcers, burns, scars, keloids, or the like
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A61P17/04—Antipruritics
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A61P17/06—Antipsoriatics
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P21/00—Drugs for disorders of the muscular or neuromuscular system
    • A61P21/02—Muscle relaxants, e.g. for tetanus or cramps
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P3/00—Drugs for disorders of the metabolism
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P35/00—Antineoplastic agents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/08—Anti-ageing preparations

Definitions

  • Technical solution relates to cosmetic polymer gel with healing effects, intended for external use on living (especially human) bodies.
  • Cosmetic polymer gel according to the technical solution further contains 0,5 to 1 ,0 weight percent of softening agent, primarily glycerine or sea-buckthorn oil.
  • the aromatic agent is ideally cinnamon and/or clove aroma.
  • the consistency of the resulting gel substance is sufficiently stable which enables long- term reliable treatment at given skin area after gel application.
  • the gel consistency enables massage of the affected body part and thereby also all the desirable effects further increase.
  • the cosmetic polymer gel also prevents bacterial growth and has also provable analgesic, anti-inflammatory and healing effects not only on skin, but, after absorption of active substances, these favourable effects develop also at other body parts.
  • Polymer gel according to the technical solution is well tolerated also in people who suffer from various types of allergic reactions. Since the eventual constituents of the cosmetic polymer gel according to the technical solution are water-soluble, it can be easily removed from skin by simply washing off, whereas there are practically no visual or odour marks left in the area of application.
  • cosmetic polymer gel according to the technical solution regarding its lifetime is that it is resistant and easy to store, because it tolerates room temperature and the only demand is to prevent the entry of light.
  • Cosmetic polymer gel contains 2% mumio solution in the amount of 93,5 weight percent as active substance, polyacrylic acid in the amount of 1 ,3 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 4,2 weight percent as pH controller, sodium salicylate in the amount of 0,5 weight percent as preservative and analgesic agent and cinnamon in the amount of 0,5 weight percent as aromatic agent.
  • Cosmetic polymer gel contains 4% mumio solution in the amount of 91 ,5 weight percent as active substance, polyacrylic acid in the amount of 2,0 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 4,0 weight percent as pH controller, sodium salicylate in the amount of 2,0 weight percent as preservative and analgesic agent and cinnamon/clove 2:3 combination in the amount of 0,5 weight percent as two component aromatic agent.
  • Cosmetic polymer gel contains 1% mumio solution in the amount of 93,0 weight percent as active substance, polyacrylic acid in the amount of 1,4 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 3,8 weight percent as pH controller, sodium salicylate in the amount of 1 ,0 weight percent as preservative and analgesic agent, clove in the amount of 0,3 weight percent as aromatic agent, and glycerine in the amount of 0,5 weight percent as softening agent.
  • Cosmetic polymer gel contains 2% mumio solution in the amount of 91,5 weight percent as active substance, polyacrylic acid in the amount of 1 ,5 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 4,3 weight percent as pH controller, sodium salicylate in the amount of 1 ,2 weight percent as preservative and analgesic agent, cinnamon/clove 1 : 1 in the amount of 1 ,0 weight percent as two component aromatic agent and the last is glycerine in the amount of 0,5 weight percent as softening agent.
  • Cosmetic polymer gel contains 2% mumio solution in the amount of.92 weight percent, polyacrylic acid in the amount of 1 ,2 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 4,5 weight percent as pH controller, sodium salicylate in the amount of 0,7 weight percent as preservative and analgesic agent, cinnamon/clove 1 : 1 in the amount of 0,6 weight percent as two component aromatic agent and sea-buckthorn oil in the amount of 1 ,0 weight percent as softening agent.
  • Cosmetic polymer gel according to the technical solution distinctively regenerates skin. Furthermore it is intended for use especially as external healing agent not only for injuries, dermatitis, eczema and refractory (non-healing) wounds, but also shows supporting curative effect in wide range of hardly manageable or chronic diseases, as e. g. skin cancer, spastic states of muscles, circulatory system diseases, and others, because it accelerates metabolism, cleans organism and slows down aging.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Organic Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Gerontology & Geriatric Medicine (AREA)
  • Obesity (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Hematology (AREA)
  • Diabetes (AREA)
  • Pain & Pain Management (AREA)
  • Neurology (AREA)
  • Orthopedic Medicine & Surgery (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Cosmetic polymer gel with healing effects which is made from natural and synthetic substances, contains 1 to 5 % solution of mumio powder in the amount of 91 to 94 weight percent as the active substance, polyacrylic acid in the amount of 1,2 to 5,0 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 3,8 to 5 weight percent as pH controller, sodium salicylate in the amount of 0,5 to 2,0 weight percent as preservative and analgesic agent, and finally aromatic agent in the amount of 0,2 to 1,0 weight percent, eventually also other regular additives. The said cosmetic polymer gel further contains 0,5 to 1,0 weight percent of softening agent, primarily glycerine or sea-buckthorn oil. The aromatic agent is ideally cinnamon and/or clove aroma.

Description

Cosmetic polymer gel with heaiing effects
Field of technical solution
Technical solution relates to cosmetic polymer gel with healing effects, intended for external use on living (especially human) bodies.
State of the art
So far various devices for cosmetic applications have been known, which demonstrably have favourable effect not only on skin itself, but also on other factors of state of health and they eventually have an overall positive effect on condition and regeneration of human organism.
The world has known and used healing and curative effects of the substance called mumio since long time ago. Mumio in its original shape is thick glossy dark brown substance of natural origin, obtained in rocks and caves of the Altai mountains in Mongolia, Russia and China, in form of exudates and stalactites.
It has a specific resin aroma; it is water-soluble and softens at human hands temperature. Mumio in piire :state is light brown powder. It is a very complex chemical system containing - according to the analyses available, - in addition to 14 - 20% of water 18 - 20% mineral substances, 13 -d 7% proteins, 4 - 4,5% fats 3,3 - 6,5% steroids, 18 - 20% niitrogen-free compounds, 1,5 - 2% saccharides and 0,05 - 0,08%) other substances. Mumio is a natural biostimulator with universal regenerative, analgesic, antiinflammatory and antibacterial properties. Therefore it has supporting effect in both healing of external injuries and , in minimizing symptoms and in treatment of many illnesses. The effects of mumio had been known in . Babylon, Persia, Egypt, Mongolia, China, i Greece and in Rome as well.
However, with regard to consistency of mumio, people used to struggle for finding the appropriate form of its application.- Since the original form of mumio as a thick material which becomes plastic at regular temperatures is inconvenient for most applications, mumio is being processed into powder form which is further being encapsulated or converted into aqueous solution.
Mumio is; often intended for external applications: In these cases, pills represent only transient form- facilitating- ;the- distribution : and dosage and it is necessary to , ake into account that before the proper use the pills must be used for preparation of the solution of suitable concentration. In addition, in this form, multiplication and growth of undesirable bacteria cannot be suspended, thus the durability of the prepared solution lies within a range of several days and longrterm storage is practically impossible. Therefore ;the dry form is not very efficient, in terms of application and not. very popular, among, consumers. Generally the customers prefe the already prepared mumio solutions. Nevertheless, using.the low mumio concentrations, they involve extreme increase in weight and thereby also increase in packaging and transportation costs of the solutions. Simultaneously, the solution form is problematic where long-term effect of mumio on skin is. requested and it is uneasy to sustain the solution in the area of application for a longer period Nature of technical solution
The above mentioned disadvantages of the so far known mumio application forms are largely eliminated in cosmetic polymer gel with healing effects, made from natural and synthetic substances, according/due to the technical solution. Nature of technical solution consists in the fact that the polymer gel contains 1 to 5 %. solution of mumio powder in the amount of 91 to 94 weight percent as the active substance, polyacrylic acid in the amount of 1 ,2 to 5,0 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the. amount of 3,8 to 5 weight percent as pH controller, sodium salicylate in the amount of 0,5 to 2,0 weight percent as preservative and analgesic agent, and finally aromatic agent in the amount of 0,2 to 1 ,0 weight percent, eventually also other regular additives.
Cosmetic polymer gel according to the technical solution further contains 0,5 to 1 ,0 weight percent of softening agent, primarily glycerine or sea-buckthorn oil. The aromatic agent is ideally cinnamon and/or clove aroma.
The consistency of the resulting gel substance is sufficiently stable which enables long- term reliable treatment at given skin area after gel application.
Furthermore, the gel consistency enables massage of the affected body part and thereby also all the desirable effects further increase. Besides the cooling and calming effect, the cosmetic polymer gel also prevents bacterial growth and has also provable analgesic, anti-inflammatory and healing effects not only on skin, but, after absorption of active substances, these favourable effects develop also at other body parts.
Polymer gel according to the technical solution is well tolerated also in people who suffer from various types of allergic reactions. Since the eventual constituents of the cosmetic polymer gel according to the technical solution are water-soluble, it can be easily removed from skin by simply washing off, whereas there are practically no visual or odour marks left in the area of application.
The advantage of cosmetic polymer gel according to the technical solution regarding its lifetime is that it is resistant and easy to store, because it tolerates room temperature and the only demand is to prevent the entry of light.
Technical solution embodiment
Technical solution is defined in detail by means of the following examples of particular solution:
Example I
Cosmetic polymer gel contains 2% mumio solution in the amount of 93,5 weight percent as active substance, polyacrylic acid in the amount of 1 ,3 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 4,2 weight percent as pH controller, sodium salicylate in the amount of 0,5 weight percent as preservative and analgesic agent and cinnamon in the amount of 0,5 weight percent as aromatic agent.
Example 2
Cosmetic polymer gel contains 4% mumio solution in the amount of 91 ,5 weight percent as active substance, polyacrylic acid in the amount of 2,0 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 4,0 weight percent as pH controller, sodium salicylate in the amount of 2,0 weight percent as preservative and analgesic agent and cinnamon/clove 2:3 combination in the amount of 0,5 weight percent as two component aromatic agent.
Example 3
Cosmetic polymer gel contains 1% mumio solution in the amount of 93,0 weight percent as active substance, polyacrylic acid in the amount of 1,4 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 3,8 weight percent as pH controller, sodium salicylate in the amount of 1 ,0 weight percent as preservative and analgesic agent, clove in the amount of 0,3 weight percent as aromatic agent, and glycerine in the amount of 0,5 weight percent as softening agent.
Example 4
Cosmetic polymer gel contains 2% mumio solution in the amount of 91,5 weight percent as active substance, polyacrylic acid in the amount of 1 ,5 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 4,3 weight percent as pH controller, sodium salicylate in the amount of 1 ,2 weight percent as preservative and analgesic agent, cinnamon/clove 1 : 1 in the amount of 1 ,0 weight percent as two component aromatic agent and the last is glycerine in the amount of 0,5 weight percent as softening agent.
Example 5
Cosmetic polymer gel contains 2% mumio solution in the amount of.92 weight percent, polyacrylic acid in the amount of 1 ,2 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 4,5 weight percent as pH controller, sodium salicylate in the amount of 0,7 weight percent as preservative and analgesic agent, cinnamon/clove 1 : 1 in the amount of 0,6 weight percent as two component aromatic agent and sea-buckthorn oil in the amount of 1 ,0 weight percent as softening agent.
Industrial applicability
Cosmetic polymer gel according to the technical solution distinctively regenerates skin. Furthermore it is intended for use especially as external healing agent not only for injuries, dermatitis, eczema and refractory (non-healing) wounds, but also shows supporting curative effect in wide range of hardly manageable or chronic diseases, as e. g. skin cancer, spastic states of muscles, circulatory system diseases, and others, because it accelerates metabolism, cleans organism and slows down aging.

Claims

PROTECTION CLAIMS
1. Cosmetic polymer gel with healing effects made from natural and synthetic substances, characterized by that it contains 1 to 5% solution of mumio powder in the amount of 91 to 94 weight percent, polyacrylic acid in the amount of 1,2 to 5,0 weight percent as polymer carrier and thickening agent, 20% triethanolamine solution in the amount of 3,8 to 5 weight percent as pH controller, sodium salicylate in the amount of 0,5 to 2,0 weight percent as preservative and analgesic agent, aromatic agent in the amount of 0,2 to 0,5 weight percent, eventually other regular additives.
2. Cosmetic polymer gel with healing effects, according to claim 1, characterized by that it contains 0,5 to 1,0 weight percent of softening agent, primarily glycerine or sea- buckthorn oil.
3. Cosmetic polymer gel with healing effects, according to claim 1, characterized by that the aromatic agent is cinnamon and/or clove aroma.
PCT/CZ2010/000127 2010-06-08 2010-12-10 Cosmetic polymer gel with healing effects WO2011153969A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CZPUV2010-22819 2010-06-08
CZ201022819U CZ21108U1 (en) 2010-06-08 2010-06-08 Cosmetic polymeric gel exhibiting healing activity

Publications (2)

Publication Number Publication Date
WO2011153969A2 true WO2011153969A2 (en) 2011-12-15
WO2011153969A3 WO2011153969A3 (en) 2013-04-25

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PCT/CZ2010/000127 WO2011153969A2 (en) 2010-06-08 2010-12-10 Cosmetic polymer gel with healing effects

Country Status (7)

Country Link
AT (1) AT12342U1 (en)
CZ (1) CZ21108U1 (en)
DE (1) DE202011001708U1 (en)
HU (1) HUP1000695A2 (en)
PL (1) PL393565A1 (en)
SK (1) SK5963Y1 (en)
WO (1) WO2011153969A2 (en)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10253129A1 (en) * 2002-11-07 2004-09-02 Stierle, Nicolaus Wound healing or skin-care agent for treating skin defects or burns contains sea buckthorn oil, St. John's wort oil, propolis and 'Mumie'
RU2314791C1 (en) * 2006-04-11 2008-01-20 Общество с Ограниченной Ответственностью "Скимед" Cosmetic cream-balm for taking care of skin of face and neck
RU2326651C1 (en) * 2006-12-19 2008-06-20 Общество с Ограниченной Ответственностью "Скимед" Treatment and cosmetic cream for feet care
RU2326652C1 (en) * 2006-12-19 2008-06-20 Общество с Ограниченной Ответственностью "Скимед" Treatment and cosmetic cream for hand care
RU2326650C1 (en) * 2006-12-19 2008-06-20 Общество с Ограниченной Ответственностью "Скимед" Treatment and cosmetic cream for body care
RU2383356C1 (en) * 2008-09-25 2010-03-10 Общество с ограниченной ответственностью "Производственно-коммерческая фирма "Две линии" External preparation for local application with thermal effect (versions)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
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Also Published As

Publication number Publication date
CZ21108U1 (en) 2010-07-12
DE202011001708U1 (en) 2011-11-29
PL393565A1 (en) 2011-12-19
SK500962010U1 (en) 2011-07-06
HU1000695D0 (en) 2011-02-28
AT12342U1 (en) 2012-04-15
HUP1000695A2 (en) 2012-05-02
SK5963Y1 (en) 2011-12-05
WO2011153969A3 (en) 2013-04-25

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