WO2011150397A2 - Traitement laser pour fabrication de cellules solaires en silicium cristallin mince à efficacité élevée - Google Patents

Traitement laser pour fabrication de cellules solaires en silicium cristallin mince à efficacité élevée Download PDF

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Publication number
WO2011150397A2
WO2011150397A2 PCT/US2011/038444 US2011038444W WO2011150397A2 WO 2011150397 A2 WO2011150397 A2 WO 2011150397A2 US 2011038444 W US2011038444 W US 2011038444W WO 2011150397 A2 WO2011150397 A2 WO 2011150397A2
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WIPO (PCT)
Prior art keywords
silicon
laser
approximately
crystalline silicon
oxide
Prior art date
Application number
PCT/US2011/038444
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English (en)
Other versions
WO2011150397A3 (fr
Inventor
Virendra V. Rana
Jian Jun Liang
Pranav Anbalagan
Mehrdad M. Moslehi
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Solexel, Inc.
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Filing date
Publication date
Application filed by Solexel, Inc. filed Critical Solexel, Inc.
Priority to EP11787543.5A priority Critical patent/EP2577750A4/fr
Priority to KR1020127033876A priority patent/KR101289787B1/ko
Publication of WO2011150397A2 publication Critical patent/WO2011150397A2/fr
Publication of WO2011150397A3 publication Critical patent/WO2011150397A3/fr

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier
    • H01L31/068Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PN homojunction type, e.g. bulk silicon PN homojunction solar cells or thin film polycrystalline silicon PN homojunction solar cells
    • H01L31/0682Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PN homojunction type, e.g. bulk silicon PN homojunction solar cells or thin film polycrystalline silicon PN homojunction solar cells back-junction, i.e. rearside emitter, solar cells, e.g. interdigitated base-emitter regions back-junction cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/0445PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/062Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam
    • B23K26/0622Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses
    • B23K26/0624Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses using ultrashort pulses, i.e. pulses of 1ns or less
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/08Devices involving relative movement between laser beam and workpiece
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36Removing material
    • B23K26/38Removing material by boring or cutting
    • B23K26/382Removing material by boring or cutting by boring
    • B23K26/389Removing material by boring or cutting by boring of fluid openings, e.g. nozzles, jets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36Removing material
    • B23K26/40Removing material taking account of the properties of the material involved
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic System
    • H01L31/182Special manufacturing methods for polycrystalline Si, e.g. Si ribbon, poly Si ingots, thin films of polycrystalline Si
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00Articles made by soldering, welding or cutting
    • B23K2101/36Electric or electronic devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/16Composite materials, e.g. fibre reinforced
    • B23K2103/166Multilayered materials
    • B23K2103/172Multilayered materials wherein at least one of the layers is non-metallic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/30Organic material
    • B23K2103/40Paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/50Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/546Polycrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Power Engineering (AREA)
  • Plasma & Fusion (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Mechanical Engineering (AREA)
  • Electromagnetism (AREA)
  • Sustainable Development (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Photovoltaic Devices (AREA)
  • Recrystallisation Techniques (AREA)

Abstract

L'invention concerne des techniques de traitement laser pour produire des types variés de cellules solaires à hétérojonction et à homojonction. Les procédés consistent à ouvrir une base et un contact d'émetteur, à réaliser un dopage sélectif et à effectuer une ablation de métal. Les techniques de traitement laser sont également appropriées pour effectuer une ablation sélective de silicium amorphe et un dopage sélectif pour des cellules solaires à hétérojonction. Les techniques de traitement laser peuvent être appliquées sur des substrats à semi-conducteurs, notamment des substrats en silicium cristallin, et d'autres substrats en silicium cristallin qui sont produits au moyen de procédés de découpage en tranches par une scie à fil ou de procédés de dépôt épitaxial, qui sont plats ou texturés/tridimensionnels. Ces techniques sont hautement appropriées pour un semi-conducteur à silicium cristallin comprenant les films en silicium cristallin mince.
PCT/US2011/038444 2010-05-27 2011-05-27 Traitement laser pour fabrication de cellules solaires en silicium cristallin mince à efficacité élevée WO2011150397A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP11787543.5A EP2577750A4 (fr) 2010-05-27 2011-05-27 Traitement laser pour fabrication de cellules solaires en silicium cristallin mince à efficacité élevée
KR1020127033876A KR101289787B1 (ko) 2010-05-27 2011-05-27 고효율 박형 결정질 실리콘 태양전지 제조를 위한 레이저 가공방법

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US34912010P 2010-05-27 2010-05-27
US61/349,120 2010-05-27
US201113057104A 2011-02-01 2011-02-01
US13/057,104 2011-02-01

Publications (2)

Publication Number Publication Date
WO2011150397A2 true WO2011150397A2 (fr) 2011-12-01
WO2011150397A3 WO2011150397A3 (fr) 2012-04-05

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PCT/US2011/038444 WO2011150397A2 (fr) 2010-05-27 2011-05-27 Traitement laser pour fabrication de cellules solaires en silicium cristallin mince à efficacité élevée

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Country Link
EP (1) EP2577750A4 (fr)
KR (1) KR101289787B1 (fr)
WO (1) WO2011150397A2 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013101846A1 (fr) * 2011-12-26 2013-07-04 Solexel, Inc. Systèmes et procédés permettant d'améliorer le piégeage de la lumière dans les piles photovoltaïques
GB2499192A (en) * 2012-02-02 2013-08-14 Rec Cells Pte Ltd Method for producing a solar cell with a selective emitter
JP2015516145A (ja) * 2012-04-02 2015-06-08 ソレクセル、インコーポレイテッド 高効率太陽電池構造体及びその製造方法
CN105122463A (zh) * 2013-02-12 2015-12-02 索莱克赛尔公司 使用体晶片的单片岛型背接触背结太阳能电池
US9236510B2 (en) 2004-11-30 2016-01-12 Solexel, Inc. Patterning of silicon oxide layers using pulsed laser ablation
US9419165B2 (en) 2006-10-09 2016-08-16 Solexel, Inc. Laser processing for high-efficiency thin crystalline silicon solar cell fabrication
US9455362B2 (en) 2007-10-06 2016-09-27 Solexel, Inc. Laser irradiation aluminum doping for monocrystalline silicon substrates
US9508886B2 (en) 2007-10-06 2016-11-29 Solexel, Inc. Method for making a crystalline silicon solar cell substrate utilizing flat top laser beam

Families Citing this family (2)

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US10553738B2 (en) 2013-08-21 2020-02-04 Sunpower Corporation Interconnection of solar cells in a solar cell module
KR20170025098A (ko) 2015-08-27 2017-03-08 삼성전자주식회사 펄스 레이저를 이용한 그래핀 홀 패터닝 방법 및 그래핀 투명전극 제조방법

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JP3035565B2 (ja) * 1991-12-27 2000-04-24 株式会社半導体エネルギー研究所 薄膜太陽電池の作製方法
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US20060088984A1 (en) * 2004-10-21 2006-04-27 Intel Corporation Laser ablation method
KR101084067B1 (ko) * 2006-01-06 2011-11-16 삼성에스디아이 주식회사 태양 전지 및 이의 제조 방법
JP5687837B2 (ja) * 2007-02-16 2015-03-25 ナノグラム・コーポレイションNanoGram Corporation 太陽電池構造体、光起電モジュール及びこれらに対応する方法
US7999175B2 (en) * 2008-09-09 2011-08-16 Palo Alto Research Center Incorporated Interdigitated back contact silicon solar cells with laser ablated grooves
EP2356675B1 (fr) * 2008-11-13 2016-06-01 Solexel, Inc. Cellule solaire tridimensionnelle en couches minces et méthode pour sa fabrication
US20100294349A1 (en) * 2009-05-20 2010-11-25 Uma Srinivasan Back contact solar cells with effective and efficient designs and corresponding patterning processes

Non-Patent Citations (1)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9236510B2 (en) 2004-11-30 2016-01-12 Solexel, Inc. Patterning of silicon oxide layers using pulsed laser ablation
US9419165B2 (en) 2006-10-09 2016-08-16 Solexel, Inc. Laser processing for high-efficiency thin crystalline silicon solar cell fabrication
US9455362B2 (en) 2007-10-06 2016-09-27 Solexel, Inc. Laser irradiation aluminum doping for monocrystalline silicon substrates
US9508886B2 (en) 2007-10-06 2016-11-29 Solexel, Inc. Method for making a crystalline silicon solar cell substrate utilizing flat top laser beam
WO2013101846A1 (fr) * 2011-12-26 2013-07-04 Solexel, Inc. Systèmes et procédés permettant d'améliorer le piégeage de la lumière dans les piles photovoltaïques
US20140017846A1 (en) * 2011-12-26 2014-01-16 Solexel, Inc. Systems and methods for enhanced light trapping in solar cells
JP2015506582A (ja) * 2011-12-26 2015-03-02 ソレクセル、インコーポレイテッド 太陽電池の光捕獲性を改善するシステム及び方法
AU2012362505B2 (en) * 2011-12-26 2015-08-20 Solexel, Inc. Systems and methods for enhanced light trapping in solar cells
US9583651B2 (en) 2011-12-26 2017-02-28 Solexel, Inc. Systems and methods for enhanced light trapping in solar cells
GB2499192A (en) * 2012-02-02 2013-08-14 Rec Cells Pte Ltd Method for producing a solar cell with a selective emitter
JP2015516145A (ja) * 2012-04-02 2015-06-08 ソレクセル、インコーポレイテッド 高効率太陽電池構造体及びその製造方法
CN105122463A (zh) * 2013-02-12 2015-12-02 索莱克赛尔公司 使用体晶片的单片岛型背接触背结太阳能电池

Also Published As

Publication number Publication date
EP2577750A4 (fr) 2014-04-09
KR101289787B1 (ko) 2013-07-26
KR20130027535A (ko) 2013-03-15
EP2577750A2 (fr) 2013-04-10
WO2011150397A3 (fr) 2012-04-05

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