WO2011134621A3 - Verfahren zur herstellung von alkylphosphonigsäuresalzen - Google Patents
Verfahren zur herstellung von alkylphosphonigsäuresalzen Download PDFInfo
- Publication number
- WO2011134621A3 WO2011134621A3 PCT/EP2011/002015 EP2011002015W WO2011134621A3 WO 2011134621 A3 WO2011134621 A3 WO 2011134621A3 EP 2011002015 W EP2011002015 W EP 2011002015W WO 2011134621 A3 WO2011134621 A3 WO 2011134621A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- alkylphosphonous acid
- transition metal
- salts
- producing
- acid salts
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 title abstract 6
- 239000002253 acid Substances 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229910052732 germanium Inorganic materials 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 2
- 150000002830 nitrogen compounds Chemical class 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 229910052712 strontium Inorganic materials 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003623 transition metal compounds Chemical class 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
- C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
- C07F9/4816—Acyclic saturated acids or derivatices which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5393—Phosphonous compounds, e.g. R—P(OR')2
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
- C09K21/04—Inorganic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Die Erfindung betrifft ein Verfahren zur Herstellung von Alkylphosphonigsäuresalzen, dadurch gekennzeichnet, dass man a) eine Phosphinsäurequelle (I) mit Olefinen (IV) in Gegenwart eines Katalysators A zu einer Alkylphosphonigsäure, deren Salz oder Ester (II) umsetzt, b) die so entstandene Alkylphosphonigsäure, deren Salz oder Ester (II) mit Metallverbindungen von Mg, Ca, AI, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K und/oder einer protonierte Stickstoffbase zu den entsprechenden Alkylphosphonigsäuresalzen (III) dieser Metalle und/oder einer Stickstoffverbindung umsetzt, wobei R1, R2, R3, R4 gleich oder verschieden sind und unabhängig voneinander H, C1-C18-Alkyl, C6-C18-Aryl, C7-C18-Arylalkyl, C7-C18-Alkylaryl bedeuten und Y für Mg, Ca, AI, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K und/oder einer Stickstoffverbindung und n für 1/4, 1/3, 1/2, 1 steht und es sich bei dem Katalysator A um Übergangsmetalle und/oder Übergangsmetallverbindungen und/oder Katalysatorsysteme handelt, die sich aus einem Übergangsmetall und/oder einer Übergangsmetallverbindung und mindestens einem Liganden zusammensetzen.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11715885A EP2563798A2 (de) | 2010-04-29 | 2011-04-20 | Verfahren zur herstellung von alkylphosphonigsäuresalzen |
| JP2013506527A JP2013531615A (ja) | 2010-04-29 | 2011-04-20 | アルキル亜ホスホン酸塩の製造方法 |
| US13/643,859 US20130126805A1 (en) | 2010-04-29 | 2011-04-20 | Method For Producing Alkylphosphonous Acid Salts |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010018682A DE102010018682A1 (de) | 2010-04-29 | 2010-04-29 | Verfahren zur Herstellung von Alkylphosphonigsäuresalzen |
| DE102010018682.1 | 2010-04-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2011134621A2 WO2011134621A2 (de) | 2011-11-03 |
| WO2011134621A3 true WO2011134621A3 (de) | 2012-04-26 |
Family
ID=44146871
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2011/002015 WO2011134621A2 (de) | 2010-04-29 | 2011-04-20 | Verfahren zur herstellung von alkylphosphonigsäuresalzen |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20130126805A1 (de) |
| EP (1) | EP2563798A2 (de) |
| JP (1) | JP2013531615A (de) |
| DE (1) | DE102010018682A1 (de) |
| WO (1) | WO2011134621A2 (de) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010018681A1 (de) | 2010-04-29 | 2011-11-03 | Clariant International Ltd. | Flammschutzmittel-Stabilisator-Kombination für thermoplastische und duroplastische Polymere |
| DE102010018680A1 (de) | 2010-04-29 | 2011-11-03 | Clariant International Limited | Flammschutzmittel-Stabilisator-Kombination für thermoplastische und duroplastische Polymere |
| DE102010018684A1 (de) | 2010-04-29 | 2011-11-03 | Clariant International Ltd. | Verfahren zur Herstellung von Mischungen aus Alkylphosphonigsäuresalzen und Dialkylphosphinsäuresalzen |
| JP6151678B2 (ja) * | 2014-10-15 | 2017-06-21 | 大和化学工業株式会社 | 難燃性ポリウレタン樹脂および難燃性合成皮革 |
| WO2017043552A1 (ja) | 2015-09-11 | 2017-03-16 | 丸善石油化学株式会社 | アルケニルリン化合物の製造方法 |
| JP7112422B2 (ja) * | 2017-03-30 | 2022-08-03 | ブローミン コンパウンズ リミテッド | 難燃性スチレン含有配合物 |
| CN107163076B (zh) * | 2017-05-25 | 2019-11-12 | 四川大学 | 含磷三嗪环盐化合物及其制备方法和应用 |
| DE102017212098A1 (de) | 2017-07-14 | 2019-01-17 | Clariant Plastics & Coatings Ltd | Flammhemmende Polyamidzusammensetzungen mit hoher Wärmeformbeständigkeit und deren Verwendung |
| WO2024120190A1 (zh) * | 2022-12-05 | 2024-06-13 | 金发科技股份有限公司 | 一种烷基亚膦酸复合盐及其制备方法和应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007032669A1 (de) * | 2007-07-13 | 2009-01-15 | Clariant International Limited | Alkylphosphonigsäuren, -salze und -ester, Verfahren zu deren Herstellung und ihre Verwendung |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE1008947A3 (nl) | 1994-12-01 | 1996-10-01 | Dsm Nv | Werkwijze voor de bereiding van condensatieproducten van melamine. |
| DE19608006A1 (de) | 1996-03-04 | 1997-09-11 | Hoechst Ag | Salze von phosphonigen Säuren und deren Verwendung als Flammschutzmittel in Kunststoffen |
| DE19614424A1 (de) | 1996-04-12 | 1997-10-16 | Hoechst Ag | Synergistische Flammschutzmittel-Kombination für Polymere |
| TW491843B (en) | 1997-03-04 | 2002-06-21 | Nissan Chemical Ind Ltd | 1,3,5-triazine derivative salts of polyacids comprising phosphorus, sulfur, and oxygen and process for producing the same |
| DE19734437A1 (de) | 1997-08-08 | 1999-02-11 | Clariant Gmbh | Synergistische Flammschutzmittel-Kombination für Polymere |
| DE19737727A1 (de) | 1997-08-29 | 1999-07-08 | Clariant Gmbh | Synergistische Flammschutzmittel-Kombination für Kunststoffe |
| EP1047700B1 (de) * | 1997-11-28 | 2003-10-08 | Clariant GmbH | Verfahren zur herstellung von salzen der dialkylphosphinsäuren |
| EP1034179B1 (de) * | 1997-11-28 | 2003-02-26 | Clariant GmbH | Verfahren zur herstellung von dialkylphosphinsäuren |
| DE10359815A1 (de) * | 2003-12-19 | 2005-07-28 | Clariant Gmbh | Verfahren zur Herstellung von Dialkylphosphinsäure-Salzen |
| DE10359814A1 (de) * | 2003-12-19 | 2005-07-28 | Clariant Gmbh | Dialkylphosphinsäure-Salze |
| US8097747B2 (en) * | 2004-04-23 | 2012-01-17 | ICL-IP America Inc | Process for the alkylation of phosphorus-containing compounds |
| US20060045770A1 (en) | 2004-08-24 | 2006-03-02 | Fei-Tyh Chuang | Piston rod for oil-less air compressor |
| WO2007007663A1 (ja) * | 2005-07-08 | 2007-01-18 | Polyplastics Co., Ltd. | 難燃性樹脂組成物 |
| EP1969052B2 (de) * | 2005-12-01 | 2013-06-05 | ICL-IP America Inc. | Flammwidrige zusammensetzungen, die mischungen von disubstiutierten phosphinatsalzen und monosubtituierten phosphinatsalzen enthalten |
| DE102010018684A1 (de) * | 2010-04-29 | 2011-11-03 | Clariant International Ltd. | Verfahren zur Herstellung von Mischungen aus Alkylphosphonigsäuresalzen und Dialkylphosphinsäuresalzen |
-
2010
- 2010-04-29 DE DE102010018682A patent/DE102010018682A1/de not_active Withdrawn
-
2011
- 2011-04-20 US US13/643,859 patent/US20130126805A1/en not_active Abandoned
- 2011-04-20 JP JP2013506527A patent/JP2013531615A/ja active Pending
- 2011-04-20 WO PCT/EP2011/002015 patent/WO2011134621A2/de active Application Filing
- 2011-04-20 EP EP11715885A patent/EP2563798A2/de not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007032669A1 (de) * | 2007-07-13 | 2009-01-15 | Clariant International Limited | Alkylphosphonigsäuren, -salze und -ester, Verfahren zu deren Herstellung und ihre Verwendung |
Also Published As
| Publication number | Publication date |
|---|---|
| US20130126805A1 (en) | 2013-05-23 |
| EP2563798A2 (de) | 2013-03-06 |
| JP2013531615A (ja) | 2013-08-08 |
| WO2011134621A2 (de) | 2011-11-03 |
| DE102010018682A1 (de) | 2011-11-03 |
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