WO2011125616A1 - Electrolyte solide polymère et transducteur polymère utilisant cet électrolyte - Google Patents

Electrolyte solide polymère et transducteur polymère utilisant cet électrolyte Download PDF

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Publication number
WO2011125616A1
WO2011125616A1 PCT/JP2011/057675 JP2011057675W WO2011125616A1 WO 2011125616 A1 WO2011125616 A1 WO 2011125616A1 JP 2011057675 W JP2011057675 W JP 2011057675W WO 2011125616 A1 WO2011125616 A1 WO 2011125616A1
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WO
WIPO (PCT)
Prior art keywords
polymer
group
cation
solid electrolyte
electrolyte
Prior art date
Application number
PCT/JP2011/057675
Other languages
English (en)
Japanese (ja)
Inventor
利典 加藤
壮敏 奥野
望 須郷
Original Assignee
株式会社クラレ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社クラレ filed Critical 株式会社クラレ
Priority to JP2012509463A priority Critical patent/JP5638065B2/ja
Publication of WO2011125616A1 publication Critical patent/WO2011125616A1/fr

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes

Definitions

  • substituents that may have are, for example, methyl group, ethyl group, propyl group, isopropyl group, butyl group, isobutyl group, sec-butyl group, tert-butyl group, pentyl group, neopentyl group And alkyl groups such as hexyl group, octyl group and 2-ethylhexyl group, alkoxy groups such as methoxy group, ethoxy group, isopropoxy group, tert-butoxy group, methylethoxy group and ethylethoxy group.
  • Anion Y - and the polymer chains may be bonded directly or may be bonded through a linking group.
  • No particular limitation on the kind of the linking group R 4 is, from the viewpoint of ease of introduction, an alkylene group, an arylene group, and the like (poly) alkylene glycol group. These groups may have a substituent.
  • a method may be exemplified in which phosphorus trichloride and anhydrous aluminum chloride are added to the copolymer and reacted to introduce a phosphinic acid group into the aromatic ring, and then the phosphinic acid group is oxidized with nitric acid to form a phosphonic acid group.
  • the present inventors selected from imidazolium salts, pyridinium salts, and ammonium salts having a conjugated anion of an acid (weak acid) having a pKa larger than the acid dissociation constant (pKa) of the acid group with respect to the sulfonic acid group. It was found that the cation of the sulfonic acid group can be directly and easily converted into an onium cation containing a Group 15 element such as an imidazolium cation, a pyridinium cation, or an ammonium cation by acting at least one salt.
  • a Group 15 element such as an imidazolium cation, a pyridinium cation, or an ammonium cation by acting at least one salt.
  • Production Example 4 Polymer solid electrolyte (IV)
  • a polymer solid electrolyte (IV) was obtained by performing the same operation except that sulfonated SEBS was used instead of sulfonated mSEBmS.
  • a portion of the obtained polymer solid electrolyte (IV) was immersed in saline overnight, and after removing the electrolyte, the sodium chloride aqueous solution was regulated with a 0.01 N aqueous sodium hydroxide solution.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Conductive Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Transmission And Conversion Of Sensor Element Output (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La présente invention concerne un électrolyte solide polymère, léger et flexible, au fonctionnement stable même en environnement sans eau, et ayant une excellente souplesse. L'invention concerne également un transducteur polymère utilisant cet électrolyte. L'électrolyte solide polymère est solide à température ambiante, et sa chaîne polymère comporte des cations mobiles non liés, incluant un cation d'onium contenant un élément du groupe 15. De plus, le transducteur polymère comporte au moins une paire d'électrodes et, disposé entre les électrodes, un électrolyte solide polymère qui est solide à température ambiante. Les cations qui ne sont pas liés à la chaîne polymère formant l'électrolyte solide polymère et qui peuvent se déplacer à travers l'électrolyte solide polymère incluent un cation d'onium contenant un élément du groupe 15.
PCT/JP2011/057675 2010-03-31 2011-03-28 Electrolyte solide polymère et transducteur polymère utilisant cet électrolyte WO2011125616A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2012509463A JP5638065B2 (ja) 2010-03-31 2011-03-28 高分子固体電解質、及びそれを用いた高分子トランスデューサ

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2010-083329 2010-03-31
JP2010083329 2010-03-31

Publications (1)

Publication Number Publication Date
WO2011125616A1 true WO2011125616A1 (fr) 2011-10-13

Family

ID=44762563

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2011/057675 WO2011125616A1 (fr) 2010-03-31 2011-03-28 Electrolyte solide polymère et transducteur polymère utilisant cet électrolyte

Country Status (2)

Country Link
JP (1) JP5638065B2 (fr)
WO (1) WO2011125616A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012069416A (ja) * 2010-09-24 2012-04-05 Kuraray Co Ltd 電極形成用ペースト及びその塗膜を電極膜とする高分子トランスデューサ
JP2013116934A (ja) * 2011-12-01 2013-06-13 Sumitomo Chemical Co Ltd イオン伝導体
JP2014215530A (ja) * 2013-04-26 2014-11-17 ソニー株式会社 ポリマー素子およびその製造方法、並びにカメラモジュールおよび撮像装置
WO2015083545A1 (fr) * 2013-12-02 2015-06-11 ソニー株式会社 Film à conduction ionique, élément polymère, dispositif électronique, module de caméra et dispositif d'imagerie

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015138606A1 (fr) * 2014-03-11 2015-09-17 Raven Industries, Inc. Correction gnss haute fiabilité

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001247635A (ja) * 1999-12-28 2001-09-11 Nippon Shokubai Co Ltd 重合体およびそれを含む高分子固体電解質
JP2005029655A (ja) * 2003-07-10 2005-02-03 Toyota Central Res & Dev Lab Inc 高分子電解質組成物
JP2007336790A (ja) * 2006-06-19 2007-12-27 Kuraray Co Ltd 高分子電気化学素子
WO2010024338A1 (fr) * 2008-08-28 2010-03-04 セントラル硝子株式会社 Polymère contenant du fluor et électrolyte polymère solide l’utilisant

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07335258A (ja) * 1994-06-13 1995-12-22 Nippon Telegr & Teleph Corp <Ntt> 高分子固体電解質
JPH08306385A (ja) * 1995-05-10 1996-11-22 Nippon Telegr & Teleph Corp <Ntt> 高分子電解質

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001247635A (ja) * 1999-12-28 2001-09-11 Nippon Shokubai Co Ltd 重合体およびそれを含む高分子固体電解質
JP2005029655A (ja) * 2003-07-10 2005-02-03 Toyota Central Res & Dev Lab Inc 高分子電解質組成物
JP2007336790A (ja) * 2006-06-19 2007-12-27 Kuraray Co Ltd 高分子電気化学素子
WO2010024338A1 (fr) * 2008-08-28 2010-03-04 セントラル硝子株式会社 Polymère contenant du fluor et électrolyte polymère solide l’utilisant

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012069416A (ja) * 2010-09-24 2012-04-05 Kuraray Co Ltd 電極形成用ペースト及びその塗膜を電極膜とする高分子トランスデューサ
JP2013116934A (ja) * 2011-12-01 2013-06-13 Sumitomo Chemical Co Ltd イオン伝導体
JP2014215530A (ja) * 2013-04-26 2014-11-17 ソニー株式会社 ポリマー素子およびその製造方法、並びにカメラモジュールおよび撮像装置
WO2015083545A1 (fr) * 2013-12-02 2015-06-11 ソニー株式会社 Film à conduction ionique, élément polymère, dispositif électronique, module de caméra et dispositif d'imagerie
JPWO2015083545A1 (ja) * 2013-12-02 2017-03-16 デクセリアルズ株式会社 イオン伝導膜、ポリマー素子、電子機器、カメラモジュールおよび撮像装置
US9752001B2 (en) 2013-12-02 2017-09-05 Dexerials Corporation Ion conductive film, polymer element, electronic device, camera module, and imaging device

Also Published As

Publication number Publication date
JPWO2011125616A1 (ja) 2013-07-08
JP5638065B2 (ja) 2014-12-10

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