WO2011122650A1 - 歯車およびその製造方法 - Google Patents
歯車およびその製造方法 Download PDFInfo
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- WO2011122650A1 WO2011122650A1 PCT/JP2011/057934 JP2011057934W WO2011122650A1 WO 2011122650 A1 WO2011122650 A1 WO 2011122650A1 JP 2011057934 W JP2011057934 W JP 2011057934W WO 2011122650 A1 WO2011122650 A1 WO 2011122650A1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/20—Carburising
- C23C8/22—Carburising of ferrous surfaces
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/06—Surface hardening
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/06—Surface hardening
- C21D1/09—Surface hardening by direct application of electrical or wave energy; by particle radiation
- C21D1/10—Surface hardening by direct application of electrical or wave energy; by particle radiation by electric induction
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/28—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for plain shafts
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/30—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for crankshafts; for camshafts
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/32—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for gear wheels, worm wheels, or the like
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/80—After-treatment
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16H—GEARING
- F16H55/00—Elements with teeth or friction surfaces for conveying motion; Worms, pulleys or sheaves for gearing mechanisms
- F16H55/02—Toothed members; Worms
- F16H55/06—Use of materials; Use of treatments of toothed members or worms to affect their intrinsic material properties
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Definitions
- the present invention relates to a gear used for transmission of torque that is high enough to stress not only the surface layer portion but also the core portion, such as a diff ring gear in a driving system of an automobile, and a method for manufacturing the same. More specifically, the present invention relates to a gear made of steel and hardened through processes such as carburizing and quenching, and a manufacturing method thereof.
- Steel members such as gears are often subjected to carburizing and quenching as a process for increasing the surface hardness while maintaining toughness.
- a steel member that has been subjected to carburizing treatment as appropriate is referred to as a carburized steel member.
- Carburizing and quenching treatment is performed in order to ensure the toughness of the core part and to increase the surface hardness after performing the carburizing treatment to increase the carbon concentration on the surface with the steel member heated to the austenitizing temperature or higher. It is processing of.
- Various methods have been proposed for producing steel members by applying carburizing and quenching. For example, in Patent Document 1, a steel material containing Cr or Mo is subjected to processes such as carburization, slow cooling, and quenching by high frequency heating.
- Mo content is high (for example, 0.1% by mass or more), although not as much as in the case of Cr, it causes hardness unevenness for the same reason. This is because Mo also forms carbides during slow cooling after carburizing. That is, in order to obtain a uniform quenched structure in the case of a steel material having a high content of Cr or Mo, it is necessary to perform high-frequency heating after slow cooling at a relatively high temperature.
- the surface layer portion is required to have high hardness, while the inner layer portion is required to be tougher than hardness. Furthermore, high shape accuracy is also required.
- induction hardening must be performed in a short time with high output. By keeping the heating time short, the heat conduction to the inner layer portion is suppressed and contour heating is performed. Since the heating output is high accordingly, the surface layer is relatively hot. In particular, the tip of the tooth may melt.
- gears are used for applications that transmit very high torque, such as automobile drive systems, especially diff ring gears.
- stress is applied not only to the surface layer portion of the gear but also to the inside of the tooth portion.
- hardness is required not only in the surface layer portion but also in a deeper layer portion deeper than that. Therefore, not only the surface layer portion but also the deep layer portion, particularly the inside of the tooth portion, must be heated to the austenite transformation temperature or higher during quenching.
- austenite transformation is performed at a relatively low temperature during quenching. For this reason, when the content ratio of Cr and Mo is high, Cr carbide and Mo carbide may remain in the matrix without being dissolved even by heating during quenching. This carbide residue causes a decrease in hardness and hardness unevenness.
- the present invention has been made in view of such a problem, and an object thereof is to provide a gear having no hardness unevenness, not only a surface layer portion but also a deep layer portion having a high hardness, and a high shape accuracy, and a manufacturing method thereof. To do.
- One aspect of the present invention made for the purpose of solving this problem is as a gear steel, C: 0.1 to 0.40 mass%, Si: 0.35 to 3.0% by mass, Mn: 0.1 to 3.0% by mass, Cr: less than 0.2% by mass, Mo: 0.1% by mass or less, P: 0.03 mass% or less, S: 0.15 mass% or less, Al: 0.05% by mass or less, N: 0.03 mass% or less, Fe and inevitable impurities: balance, The chemical component is used.
- the gear of the present invention has a disc portion and a plurality of teeth that are discretely formed on the disc portion in a circumferential shape, and is carburized after molding and then baked by high-density energy heating.
- the chemical composition of the material steel is as described above,
- the surface layer portion of the tooth portion and the surface layer portion of the tooth root portion which is a portion between the tooth portions in the disk portion are made to have a C concentration higher than the C concentration of the material steel by carburizing treatment, It is the first quench hardened layer including the site structure, A portion of the tooth portion other than the portion that is the first quench hardened layer, a portion of the disc portion below the first quench hardened layer of the tooth base portion, and the disc portion And the second quench hardened layer containing the martensite structure is formed while the C concentration is the C concentration of the material steel over the lower part of the tooth portion, A region deeper than the second quench hardened layer in the disk portion is a non-quenched layer that does not contain a marten
- Another aspect of the present invention is a method of manufacturing a gear having a disc portion and a plurality of teeth that are discretely formed on the disc portion.
- the material steel the one with the above chemical composition is used.
- a carburizing step in which a gear formed of the material steel is heated to a temperature equal to or higher than the austenitizing temperature of the material steel in a carburizing atmosphere having an oxygen concentration lower than the oxygen concentration in the atmosphere to form a carburized layer on the surface;
- By heating the gear after the cooling step by high-density energy heating the core in the disk part is not heated to a temperature equal to or higher than the austenitizing temperature of the material steel.
- the region shallower than the part and the tooth part are heated to a temperature equal to or higher than the austenitizing temperature of the raw steel, and from that state, the raw steel is cooled at a cooling rate equal to or higher than a cooling rate at which martensitic transformation is performed.
- This is a method for manufacturing a gear by performing a quenching step of forming a martensite structure in a region shallower than the core portion in the disc portion and the tooth portion.
- the present invention provides a carburized steel member produced through a carburizing step performed under reduced pressure, a cooling step of gradual cooling under the specific conditions, and a quenching step employing heating at the high density energy.
- This gear is specialized in the gear and its manufacturing method.
- the chemical component of the said range was employ
- the content of Cr and Mo is limited to an impurity content level or even if added, the content is limited to less than 0.2% and 0.1% or less, respectively.
- Cr is an effective element for improving hardenability and increasing temper softening resistance when added in an amount of less than 0.2%.
- Cr carbide is generated in the pearlite and ferrite in the carburized layer during the slow cooling after the carburizing treatment. If this Cr carbide is not dissolved in the matrix in the subsequent quenching step, it causes a non-uniform quenching structure and causes unevenness in hardness.
- it is difficult to dissolve Cr carbide in the matrix.
- the content is limited to less than 0.2%.
- carbonized_material at the time of above-mentioned slow cooling is suppressed. Therefore, even if the heating means in the quenching step is heating using high-density energy, even if Cr carbide is present before heating, it can be reliably dissolved in the matrix, Organizational unevenness can be reduced. In addition, by reducing the amount of expensive Cr added, the material cost can be reduced.
- Mo is an element effective for improving hardenability and increasing temper softening resistance.
- Si or Mn particularly Si
- a uniform martensite structure can be obtained without depending on the effect of improving the hardenability by Mo. . Therefore, as described above, by limiting the heating means in the quenching process to heating using high-density energy, the material cost can be reduced while improving the carburizing process productivity.
- Mo content when the Mo content is large, Mo carbides are formed, which may be combined with the above-described structure unevenness due to Cr to further deteriorate the structure unevenness. Therefore, the addition of Mo is suppressed to a small amount of 0.1% or less, thereby reducing the unevenness of the structure.
- the following effects are obtained by the material steel and the manufacturing method described above.
- grain boundary oxidation is suppressed by carburizing in a carburizing atmosphere having a lower oxygen concentration than the atmosphere.
- second quench hardened layer not only the surface layer (first quench hardened layer) but also the portion below it (second quench hardened layer) is made to have a quenching effect.
- the quenching heating itself is made relatively low temperature and relatively long so that the deeper region than the second quench hardened layer becomes a non-quenched layer, thereby suppressing distortion and improving fatigue strength. ing.
- the gear obtained by the present invention reduces the unevenness of the hardness by reducing the unevenness of the structure and has excellent cost performance.
- FIG. 2 is an enlarged view of a part of the gear of FIG. 1.
- It is sectional drawing which shows stress distribution at the time of use of the gearwheel which concerns on embodiment.
- It is sectional drawing which shows distribution of the carburized layer and the hardening hardening layer in the gearwheel which concerns on embodiment.
- It is explanatory drawing which shows the structure of the heat processing equipment used in the Example. It is a heat pattern of a reduced pressure carburizing process and a reduced pressure slow cooling process. It is a heat pattern of a quenching process. It is a temperature rising chart in the temperature rising period of a quenching process. It is another example of the heat pattern of a hardening process. It is a graph which shows the relationship between hardness and depth after a hardening process. It is a figure which is another example of the gearwheel which can apply this invention.
- C 0.1 to 0.40%
- C is an element added to secure the strength of the steel material, particularly the strength of the deep layer. Therefore, in the present invention, the inner strength is ensured by setting the lower limit of the addition amount of C to 0.1%.
- the amount of C exceeds 0.40%, there are the following two disadvantages. One is that toughness decreases while hardness increases. The other is that the machinability of steel materials deteriorates. For this reason, the upper limit of the amount of C added is set to 0.40%. A more preferable range of the addition amount is 0.15 to 0.3%.
- Si 0.35 to 3.0%
- Si is an element effective for deoxidation in the steelmaking process, and is an element effective for imparting necessary strength and hardenability to the steel material and improving temper softening resistance.
- the present invention is characterized by the fact that expensive Cr and Mo can be greatly reduced.
- the CrMo steel which is a conventional steel, is compared with the CrMo steel. Reduction of Mo and Mo may be disadvantageous. Therefore, in order to obtain the necessary temper softening resistance even when Cr and Mo are reduced, Si is contained in an amount of 0.35% or more. However, since this effect due to the inclusion of Si is saturated at about 3.0%, there is no positive meaning of adding Si any more. If the Si content exceeds 3.0%, the hardness is rather increased and the machinability of the material is deteriorated. Therefore, the Si content needs to be in the range of 0.35% to 3.0%. A more preferable range is more than 0.45% to 1.5%.
- the present invention employs a process of performing a carburizing process in a carburizing atmosphere in which the oxygen concentration is reduced by reducing the pressure. As a result, the problem of grain boundary oxidation can be eliminated as will be described later. For this reason, it is possible to use a steel material with a positive Si content.
- Mn 0.1 to 3.0%
- Mn is an element effective for deoxidation in the steelmaking process and an element effective for improving the hardenability.
- the content is less than 0.1%, the effect is insufficient.
- this effect due to the inclusion of Mn is saturated at about 3.0%, there is no positive meaning of containing Mn any more. If the Mn content exceeds 3.0%, the hardness is rather increased and the machinability of the material is deteriorated. Therefore, the Mn content needs to be in the range of 0.1% to 3.0%. A more preferred range is 0.5% to 1.5%.
- P 0.03% or less
- P segregates at grain boundaries in steel and has the effect of reducing toughness. For this reason, it is necessary to reduce as much as possible. Although it is difficult to make it 0, it is necessary to limit it to 0.03% or less.
- S 0.15% or less
- S Since S forms MnS in steel, it is an element added for the purpose of improving the machinability of the material. However, since this effect due to the inclusion of S is saturated at about 0.15%, there is no positive meaning of further containing S. If the S content exceeds 0.15%, grain boundary segregation is rather caused and grain boundary embrittlement is caused. For this reason, the S content needs to be 0.15% or less. If the S content is less than 0.001%, the effect of improving the machinability is not remarkable. For this reason, if the lower limit is specified, the content is made 0.001% or more. A more preferred range is in the range of 0.005 to 0.06%.
- Al 0.05% or less, Al is precipitated and dispersed in the steel as a nitride. For this reason, Al is considered to be an effective element for preventing coarsening of the austenite structure during carburizing. However, if it exceeds 0.05%, the precipitates become coarse and the steel becomes brittle. For this reason, 0.05% is made the upper limit. Note that recrystallization occurs at the site where the high-density energy quenching is performed, and the coarsened austenite structure is refined. For this reason, it is not essential to contain Al when high intensity
- the content is made 0.005% or more.
- a more preferred range is 0.02 to 0.04%.
- N 0.03% or less
- N forms various nitrides and has the effect of preventing coarsening of the austenite structure during carburizing and high-density energy quenching.
- it exceeds 0.03% the forgeability is remarkably deteriorated.
- 0.03% is made an upper limit.
- the inclusion of N is essential only when high strength is required even in a region not heated with high-density energy. In that case, if the N content is less than 0.003%, the effect of preventing coarsening of the austenite structure is insufficient. For this reason, if the lower limit is specified, 0.003% or more is necessary. A more preferred range is 0.005 to 0.02%.
- Cr less than 0.2%
- Cr is an effective element for improving hardenability and temper softening resistance when added in an amount of less than 0.2%.
- the addition amount is 0.2% or more
- Cr carbide is generated in the pearlite and ferrite in the carburized layer during slow cooling after carburizing. This is particularly noticeable in the case of a hypoeutectoid composition in which the C concentration during carburization is 0.5 to less than 0.8%.
- a relatively high temperature for example, 950 ° C. or higher
- this Cr carbide dissolves in the matrix. For this reason, austenite transformation during high frequency heating occurs uniformly, and a uniform quenched structure can be obtained. This makes the hardness uniform.
- the Cr carbide can be easily dissolved in the matrix when the desired portion is heated to the austenite region with high-density energy in the quenching process. For this reason, the input energy at the time of high-density energy heating (the integrated value of the heating temperature during the period when the temperature is equal to or higher than the transformation point) can be reduced. For this reason, the process can be energy-saving and cost-effective.
- Mo 0.1% or less
- One object of the present invention is to reduce Mo, which is a rare metal and is relatively expensive.
- Mo may be added if the amount is extremely small.
- Mo is an element effective in improving hardenability and temper softening resistance.
- the inclusion of a large amount of Mo not only increases the cost, but is not as significant as in the case of Cr, but causes hardness unevenness for the same reason as Cr. This is because Mo also forms carbides during slow cooling after carburizing. For this reason, the upper limit needs to be 0.1%. If other elements can ensure the necessary hardenability and temper softening resistance, it is desirable not to add Mo. In that case, it is good to make it less than 0.01% which is a condition that can be said not to be actively added. As in the case of Cr, the reduction of the Mo content also causes a decrease in hardenability and temper softening resistance. However, in the present invention, this is addressed by the inclusion of Si and Mn as described above. ing.
- the steel material used in the present invention may further contain Ti: 0.005 to 0.2% and B: 0.0006 to 0.005%.
- Ti: 0.005 to 0.2% Ti is an element that easily binds to N. For this reason, there exists an effect which prevents that B becomes BN and the hardenability improvement effect of B lose
- B becomes BN the hardenability improvement effect of B lose
- the effect is not remarkable if it is less than 0.005%.
- it exceeds 0.2% the precipitates become coarse and the steel becomes brittle. For this reason, the upper limit was made 0.2%.
- the most preferable range of the amount of Ti added is 0.01 to 0.03%.
- B 0.0006 to 0.005%
- B is an element effective for imparting hardenability and strengthening the grain boundary strength when added.
- the effect is not remarkable if it is less than 0.0006%.
- this effect is saturated at about 0.005%, so there is no positive meaning to add more. Therefore, 0.0006% to 0.005% is a preferable range.
- the most preferred range is 0.001% to 0.003%.
- the steel material used in the present invention may further contain one or two of Nb: 0.01 to 0.3% and V: 0.01 to 0.2%.
- Nb: 0.01 to 0.3%, V: 0.01 to 0.2%, Nb and V are elements that precipitate and disperse in the steel as carbonitrides. Therefore, it is effective in preventing the austenite structure from becoming coarse during carburizing and induction hardening.
- Nb and V are both less than 0.01%, the effect is not remarkable.
- the amount added is too large, the precipitates become coarse and the steel becomes brittle. For this reason, the upper limit is set to 0.3% for Nb and 0.2% for V.
- Nb is added in the range of 0.01 to 0.02%
- V is added in the range of 0.01 to 0.05%.
- the steel material used in the present invention can further contain Ni: 0.1 to 3.0%.
- Ni: 0.1-3.0% Ni is an element effective for improving toughness. However, the effect is not remarkable if it is less than 0.1%. However, since this effect is saturated at about 3.0%, there is no positive meaning to add more. If it contains more than 3.0% Ni, rather, the hardness increases and the machinability of the material deteriorates. For this reason, it is necessary to be within the range of 0.1% to 3.0%. The most preferred range is 0.5% to 1.5%.
- the gear 8 is provided with tooth portions 81 at equal intervals on the periphery of a circular disc portion 82.
- the disc portion 82 shown in FIG. 1 is an annular shape rather than a disc shape, but such a shape is also included in the “disc”.
- the tooth portion 81 has a tooth wall surface 811 and a tooth crest surface 812. An angular side between the tooth wall surface 811 and the tooth top surface 812 is referred to as a tooth tip corner portion 813.
- a tooth root portion 815 exists between the tooth portion 81 and the tooth portion 81.
- Examples of the use of the gear 8 of the present embodiment include various gears in a driving system of an automobile. In addition to cost reduction, there are strict requirements for the gears of automobile drive systems in terms of strength and shape accuracy, but the present invention is very effective in meeting those requirements. Examples of the gears in the drive system include gears in automatic transmissions, differentials, and the like.
- FIG. 3 shows a simulation result of stress distribution during use in the cross section of the gear 8.
- FIG. 3 shows a situation where a driving force is applied to the tooth wall surface 811 on the right side of the tooth portion 81.
- the region 71 is a region where the strongest stress is applied.
- the areas 72, 73, and 74 become weaker in stress.
- Fig. 3 it can be seen that there are two places where stress is concentrated during driving.
- One location is near the boundary between the tooth wall surface 811 and the tooth root portion 815. This is mainly subjected to bending stress.
- the other location is a position in the tooth wall surface 811 where the distance from the tooth tip corner portion 813 is slightly shorter than the distance from the tooth root portion 815. This is mainly subject to shear stress.
- a strong stress is applied not only to the vicinity of the surface layer of the gear 8 but also to a considerably deep part.
- the region 71 alone is deeper than the general carburized layer depth. Therefore, in the gear 8 used for this type of application, not only the surface hardness of the tooth portion 81 is required, but also the internal toughness of the tooth portion 81 is required.
- the raw material of the gear 8 of this embodiment is a hot rolled steel material having a chemical component within the above range. Using this raw material steel as a starting material, rough forming is performed by hot forging, followed by annealing, and tooth portions 81 are formed by cutting. Thereby, the gear 8 is completed in terms of the outer shape. However, the gear 8 of the present embodiment is further processed by the following process.
- Carburizing step This is a step of performing a process of forming a carburized layer on the surface layer portion of the gear 8 by heating the gear 8 in a carburizing atmosphere.
- Cooling step is a step of cooling the gear 8 after the carburizing step. This cooling must be carried out at least until the structural transformation due to the temperature drop after carburization is completed.
- the quenching process is a process in which the gear 8 after the cooling process is locally heated to austenite region by high-density energy, and after the heating, it is quenched and hardened.
- the carburizing process is performed in a carburized gas under reduced pressure that is lower than the atmospheric pressure, that is, a reduced-pressure carburizing process.
- the carburizing process can be performed with a relatively small amount of carburizing gas while maintaining the inside of the high-temperature carburizing furnace in a reduced pressure state. For this reason, carburizing treatment can be performed more efficiently than before.
- long-time heat treatment as in the case of using a conventional large heat treatment furnace is unnecessary. For this reason, it is possible to shorten the processing time, reduce the energy consumption, and further reduce the size of the carburizing and quenching equipment itself.
- the above-described Cr carbide generation may proceed more remarkably when the variation in the degree of carburization is larger than in the case of normal gas carburization.
- the Cr content is kept low, the formation of such Cr carbide is suppressed.
- the effect of limiting Cr is particularly effective by adopting a reduced pressure carburizing process.
- the carburizing atmosphere is depressurized with respect to atmospheric pressure in the carburizing process. For this reason, the oxygen concentration in the atmosphere can be kept low. Thereby, grain boundary oxidation of the carburized layer can be prevented.
- Carburizing is generally a hydrocarbon gas (carburizing gas such as methane, propane, ethylene, acetylene, etc.) introduced directly into the furnace, and the target steel material (here, gear 8) is introduced into the atmosphere. It is a process of forming a carburized layer by intruding carbon into the surface layer of the target steel material by placing and heating. In this carburizing process, first, during the diffusion phase, carburized gas molecules come into contact with the surface of the steel and decompose, generating active carbon. This active carbon is supplied to the surface of the steel to form carbides. This stores carbon on the surface of the steel.
- hydrocarbon gas carburizing gas such as methane, propane, ethylene, acetylene, etc.
- the route of carbon entry is not limited to the route via carbide, but there is also a route of direct dissolution of active carbon into the matrix.
- the atmospheric pressure in the reduced pressure carburizing process is preferably in the range of 1 to 100 hPa. If the atmospheric pressure in the reduced-pressure carburizing process is reduced to less than 1 hPa, expensive equipment is required to realize and maintain the degree of vacuum. On the other hand, when the pressure is higher than 100 hPa, soot is generated during carburizing. This may cause a problem of uneven carburization.
- hydrocarbon-type gas such as acetylene, propane, butane, methane, ethylene, ethane, can be applied, for example.
- the carburized layer has a carbon content equal to or less than that of eutectoid steel. For this reason, the austenite transformation is performed by heating at the time of subsequent quenching, followed by rapid cooling, thereby making it possible to obtain a martensite structure without precipitation of cementite.
- the gear of the present embodiment has a first part and a second part that have different diffusion rates of carbon that has entered during the carburizing process due to its shape, and the above-described first part (carbon easy diffusion part) is more than the first part.
- the second part (difficult carbon part) has a shape in which the diffusion rate of carbon that has entered is slower.
- the carburizing step is preferably performed under the condition that the carbon concentration on the surface of the first portion is in the range of 0.65 ⁇ 0.1%.
- the tooth wall surface 811, the tooth root portion 815, and the tooth crest surface 812 (not including the tooth tip corner portion 813) correspond to the first portion
- the tooth tip corner portion 813 corresponds to the second portion. .
- the reduced pressure carburizing process is a non-equilibrium reaction. For this reason, when the steel member which has an uneven
- the surface carbon concentration obtained is different between immediately after the carburizing period in which carburizing is carried out and after the diffusion period in which the diffusion of carbon that has penetrated into the interior thereafter is passed. .
- the carbon concentration of the carburized layer is expressed using the value after the diffusion period. Accordingly, all the carbon concentrations in the carburized layer in the present specification are values of the carbon concentration after the diffusion period, not immediately after the carburization period (hereinafter the same).
- the conditions for performing the reduced-pressure carburizing step on the gear 8 having the first part (carbon easy diffusion part) and the second part (carbon difficult diffusion part) due to the shape are as described above.
- the carbon concentration on the surface of the first portion is within the range of 0.65 ⁇ 0.1%.
- the inventor of the present invention performs the reduced pressure carburizing process under such conditions, so that the second part of the gear 8 obtained, that is, the diffusion rate is slower than the first part, and the carbon concentration on the surface after the carburizing process is reduced.
- the carbon concentration on the surface of the part higher than the first part can be suppressed to a range of 0.85% or less.
- the carbon concentration on the almost entire surface of the portion to be surface-modified by the carburizing process of the gear 8 can be kept within the range of 0.60 to 0.85%.
- a portion where the surface carbon concentration is close to the lower limit (first part) by applying a special quenching process in which the surface carbon concentration is kept within this range, followed by rapid cooling after heating using high-frequency energy.
- the effect of quenching can be sufficiently obtained, and defects due to excess carbon can be suppressed in the portion where the surface carbon concentration is close to the upper limit (second portion).
- an excellent modified surface is obtained after quenching.
- Conditions such as temperature, type of carburizing gas, pressure, and processing time in the reduced-pressure carburizing process are adjusted so that the carbon concentration on the surface of the first part is in the specific range. There is a need. For that purpose, it is preferable to carry out under these conditions by changing these conditions in various ways and conducting a plurality of preliminary experiments to find appropriate conditions. If the gear 8 that is a material to be processed has the same shape, the number of preliminary experiments can be reduced by accumulating data. The determination of the first part and the second part in the gear 8 can be made by actually measuring the carbon concentration at a plurality of places in the preliminary experiment. Moreover, since it can be judged relatively easily from the shape, it may be determined by observing the shape.
- a carburized layer 91 having a carbon concentration higher than the carbon concentration of steel shown in the cross-sectional view of FIG. 4 is formed. That is, carbon supplied to the surface of the steel penetrates from the surface through diffusion, and a carburized layer 91 is formed on the surface layer portion.
- the carbon concentration in the carburized layer is within the range of 0.60 to 0.85% on the surface as described above, but gradually decreases to the carbon concentration of the material steel as it goes inside.
- the carburized layer 91 is formed on the surface layer of the tooth portion 81 and the tooth root portion 815.
- the thickness of the carburized layer 91 is about 0.7 to 1.3 mm.
- the hardened and hardened layer 92 is depicted as if it existed under the carburized layer 91. However, the hardened layer 92 is formed through a quenching process to be described later. Therefore, at this stage, the hardened hardening layer 92 is not yet formed.
- the cooling process is performed under slow cooling conditions. More specifically, the steel material of the gear 8 is cooled to a temperature lower than the temperature at which the structural transformation by cooling is completed at a cooling rate lower than the cooling rate at which the steel material of the gear 8 undergoes martensite transformation during cooling. Thereby, generation
- the cooling is performed at a cooling rate in the range of 0.1 ° C./second to 3.0 ° C./second at least while the temperature of the gear 8 is equal to or higher than the A1 transformation point temperature of the material steel. It is preferable. If the cooling rate exceeds 3.0 ° C./second before the temperature falls below the A1 transformation point temperature, the effect of suppressing strain generation during cooling may not be sufficiently obtained. On the other hand, when the cooling rate in the cooling step is less than 0.1 ° C./second during a period equal to or higher than the A1 transformation point temperature of the steel member, a long time is required until the temperature falls to the A1 transformation point.
- the cooling step is preferably performed in a cooling atmosphere reduced in pressure below atmospheric pressure. That is, it is preferable to use a reduced pressure cooling process. Thereby, generation
- the reason is that the heat exchange rate between the steel and the atmosphere can be reduced. Due to the heat exchange between the steel and the atmosphere, there is a difference in the ambient temperature between the windward and leeward of the wind flow in the atmosphere, and the ambient temperature at the leeward position is higher. If the atmospheric pressure is as high as atmospheric pressure, this temperature difference is significant because the heat exchange rate is fast. For this reason, a temperature difference is caused by a portion in the gear 8 and a thermal distortion is caused.
- the heat exchange rate becomes slow in the first place by using the reduced pressure cooling process. For this reason, the temperature difference between the windward and leeward is small, and the cooling proceeds relatively uniformly. Therefore, thermal distortion is suppressed.
- reduced pressure cooling causes less thermal distortion than cooling at atmospheric pressure. This is because the difference in cooling rate due to residence of cooling atmospheres with different temperatures is small.
- the pressure difference between the two processes is small.
- the carburizing chamber and the slow cooling chamber can be directly connected to perform both processes continuously. That is, it is not necessary to provide a spare chamber for pressure adjustment between the two chambers. That is, the product that has been subjected to the reduced pressure carburizing process can be subjected to the reduced pressure annealing process without being exposed to the atmospheric pressure state. This also contributes to the reduction of distortion.
- the atmospheric pressure in the cooling process is preferably in the range of 100 hPa to 650 hPa. If the pressure during cooling is higher than 650 hPa, the effect of the reduced pressure is insufficient. On the other hand, reducing the pressure to less than 100 hPa has a difficulty in equipment configuration. A more preferable range of the pressure during cooling is 100 hPa to 300 hPa.
- the quenching process of “3.” will be described. What is important in the quenching process is that the desired portion of the gear 8 is partially heated to the austenitizing temperature or higher, and at least the carburized layer portion is martensitic transformed by subsequent rapid cooling. For this reason, it is necessary to perform heating by high-density energy heating. Moreover, it is necessary to perform rapid cooling at a cooling rate higher than the critical cooling rate for martensitic transformation. Examples of the high-density energy heating include heating by irradiating a high-density energy beam such as an electron beam or a laser beam. Alternatively, as other than beam irradiation, high-frequency heating is also included in high-density energy heating. By using high-density energy heating, the heating time is shortened. Further, in this embodiment, a low Cr steel type that is easily austenitized may be used, and the gear 8 can be hardened reliably and sufficiently.
- high-density energy heating the most preferable is high-frequency heating.
- high-frequency heating a desired part can be accurately heated by induction heating without contact. It is also highly efficient.
- a known method can be used as the method of high-frequency heating itself.
- the rapid cooling in the quenching process is preferably performed by water cooling.
- the heating before quenching is performed by high-density energy heating instead of gas heating or the like, even if water cooling at a very high cooling rate is performed thereafter, the occurrence of quenching distortion is small. This is because high-density energy heating can accurately heat the gear 8 instead of the entire gear 8.
- the high quenching effect is obtained by the excellent rapid cooling by water cooling. That is, further strengthening of the quenched portion is achieved.
- the required strength may be ensured even if the carburizing process is simplified, that is, the carburizing time is shortened, that is, the carburized layer is made thinner. In this case, the entire heat treatment process can be further shortened.
- the gear 8 is processed by flowing one, and at the time of water cooling after heating, cooling is performed by jetting cooling water from the surroundings toward the gear 8 while rotating the gear 8. In this way, uniform cooling can be achieved. For this reason, generation
- the high-density energy heating in the quenching process is performed under the condition that the surface of the gear 8 is not melted and is austenitized from the surface to a relatively deep portion.
- the input energy of the high-density energy heating is made smaller, and the heating time is made a little longer (for example, about 15 to 25 seconds) instead.
- the heating target temperature is set to a temperature within a relatively low range (for example, 750 ° C. to 960 ° C.) as the austenite region of the steel material, and heating is performed a little longer by that amount. By doing so, the entire region slightly thicker than 2 to 5 mm in depth can be heated by heat conduction from the surface.
- the quenching effect can be obtained not only in the carburized layer region but also in a deeper region.
- the quenching effect can be obtained not only in the carburized layer region but also in a deeper region.
- by suppressing austenitization by high-density energy heating to a relatively low temperature there is also an effect of suppressing distortion during subsequent water cooling.
- the gear 8 is the object.
- the object having the protruding tooth portion 81 such as the gear 8 is an object, it is preferable to perform the high-density energy heating under the condition that the entire surface of the tooth portion 81 and the inside thereof are austenitic.
- the gear 8 is required to have both high surface hardness of the tooth portion 81 and high internal toughness.
- the shape accuracy of the tooth portion 81 is also high. Therefore, as described above, it is effective to make the heating in the quenching process relatively low temperature and relatively long. This is because the quenching effect is exerted not only on the carburized layer but also on the entire tooth portion 81, and high shape accuracy can be obtained by suppressing distortion.
- a hardened and hardened layer 92 as shown in FIG. 4 is formed.
- a hardened and hardened layer 92 exists under the carburized layer 91 on the surface of the gear 8.
- the entire inside of the tooth portion 81 is a hardened and hardened layer 92.
- the hardened layer 92 is formed on the surface portion of the tooth root portion 815 below the carburized layer 91 and the portion below the tooth portion 81.
- the total thickness of the carburized layer 91 and the hardened and hardened layer 92 is about 2 to 5 mm.
- the hardened and hardened layer 92 contains a martensite structure as described above.
- the carburized layer 91 is also a layer subjected to quenching effect and includes a martensite structure.
- the carburized layer 91 is referred to as a “first quench hardened layer”, and the quench hardened layer 92 is referred to as a “second quench hardened layer”.
- a non-quenched layer 93 exists under the hardened hardening layer 92.
- the non-quenched layer 93 does not contain a martensite structure. This is because the temperature was not raised to the austenitizing temperature during heating in the quenching process.
- the C concentration on the surface of the carburized layer 91 is in the range of 0.60 to 0.85% due to carburization as described above. And as it goes inside, the C concentration gradually decreases to the C concentration of the original steel material.
- the C concentration of the hardened and hardened layer 92 and the non-quenched layer 93 is the C concentration of the original steel material and is in the range of 0.1 to 0.40%.
- the portion that should become the non-quenched layer 93 is called a “core portion”.
- the heat treatment including the carburizing step, the cooling step, and the quenching step in the present invention is a treatment method that suppresses the occurrence of distortion. That is, in the cooling process after carburizing, cooling is performed at a cooling rate lower than the cooling rate at which martensitic transformation occurs. Thereby, not only in the carburized layer but also in the core deeper than the carburized layer, a martensite structure is not generated, and either ferrite, pearlite, bainite, or a mixed structure thereof is formed. Therefore, the martensitic transformation distortion does not occur in the cooling in the cooling process, and the shape accuracy of the gear 8 does not deteriorate.
- high-density energy heating is used for heating in the quenching process after the cooling process.
- the machined gear 8 was subjected to the carburizing step, the subsequent cooling step, and the subsequent quenching step.
- the gear 8 after these processes was subjected to material investigation and fatigue test.
- the heat treatment equipment 5 used in the present embodiment has a pre-cleaning tank 51, a reduced pressure carburizing and slow cooling device 52, an induction hardening machine 53, and a magnetic flaw detection device 54.
- the pre-washing tank 51 is a part for washing the gear 8 before the heat treatment is started.
- the reduced-pressure carburizing and slow cooling device 52 includes a heating chamber 521, a reduced-pressure carburizing chamber 522, and a reduced-pressure slow cooling chamber 523.
- the gear 8 is heated in the heating chamber 521, and then the reduced pressure carburizing in the reduced pressure carburizing chamber 522 and the reduced pressure annealing in the reduced pressure annealing chamber 523 are performed. There is no spare chamber between the reduced pressure carburizing chamber 522 and the reduced pressure annealing chamber 523.
- the induction hardening machine 53 is a part that performs high frequency heating and subsequent water cooling on the gear 8 after the reduced pressure annealing.
- the magnetic flaw detector 54 is a part that performs a defect inspection of the gear 8 after quenching.
- the reduced pressure carburizing process in the reduced pressure carburizing chamber 522 of the reduced pressure carburizing slow cooling device 52 will be described.
- the carburizing process in this embodiment is a reduced-pressure carburizing process performed in a carburizing gas whose pressure is reduced to a pressure lower than the atmospheric pressure.
- FIG. 6 shows a heat pattern in this reduced-pressure carburizing process and the subsequent reduced-pressure slow cooling process.
- the horizontal axis represents time and the vertical axis represents temperature.
- “a” indicates the heating period in the heating chamber 521.
- What is indicated by “b1” and “b2” is the holding period in the reduced pressure carburizing chamber 522.
- the first period “b1” of the holding period is a carburizing period in the carburizing process
- the subsequent period “b2” is a diffusion period in the carburizing process.
- the carburizing temperature that is, the holding temperature in the holding periods “b1” and “b2” was set to 950 ° C., which is a temperature higher than the austenitizing temperature of the steel material.
- the gear 8 was heated to this holding temperature during the heating period “a”.
- the temperature of the gear 8 was maintained at a constant temperature, that is, the above-described holding temperature.
- the pressure of the carburizing gas in the reduced pressure carburizing process was set within the range of 1 to 3.5 hPa. Further, acetylene was used as the carburizing gas in the carburizing period “b1”.
- the carburizing conditions were determined as follows through preliminary experiments. That is, the gear 8 of this embodiment is a diff ring gear, and has a first part (carbon easy diffusion part) and a second part (carbon difficult diffusion part) due to its shape.
- the tooth root part 815 and the tooth wall surface 811 shown in FIG. 2 are the first part, and the tooth tip corner part 813 is the second part.
- a condition was adopted in which the carbon concentration of the surface layer of the tooth root portion 815 which is the first part is in the range of 0.65 ⁇ 0.05%.
- the slow cooling process in the present embodiment is a reduced pressure slow cooling process performed in an atmosphere reduced to a pressure lower than the atmospheric pressure.
- the period indicated by “c” is the slow cooling period.
- the atmospheric pressure in the reduced pressure annealing process was set to 600 hPa.
- the gas type of the atmosphere was N 2 gas.
- the cooling rate in the reduced pressure gradual cooling treatment was set within the range of 0.1 to 3.0 ° C./second.
- cooling was performed from a temperature equal to or higher than the austenitizing temperature immediately after the carburizing treatment to 150 ° C., which is lower than the A1 transformation point.
- the heat pattern shown in FIG. 6 is one example, and can be changed to an optimum condition for the type of steel material to be used by appropriately performing a preliminary test.
- the quenching process in the induction hardening machine 53 will be described.
- high-frequency heating was used as a means for high-density energy heating.
- water cooling was used as a rapid cooling means.
- the heat pattern of the quenching process of a present Example is shown in FIG.
- FIG. 7 as in FIG. 6, the horizontal axis represents time and the vertical axis represents temperature.
- “d1” indicates a temperature rising period
- “d2” indicates a rapid cooling period.
- the tooth portion 81 on the outer peripheral side of the gear 8 is heated to a temperature equal to or higher than the austenitizing temperature by high-frequency heating.
- the gear 8 is rapidly cooled in the carburized layer at a cooling rate equal to or higher than the critical cooling rate by water injection.
- the critical cooling rate is a cooling rate necessary for the martensitic transformation of the austenitized steel material, particularly the carburized layer.
- the high-frequency heating in the temperature rising period “d1” was performed by setting the amount of energy input to be smaller than the conditions used in normal high-frequency heating, and the heating time was relatively long for 15 to 25 seconds.
- the heating time was relatively long for 15 to 25 seconds.
- not only the vicinity of the surface of the tooth portion 81 but also the entire interior including the inside thereof was set to a temperature in the range of 750 ° C. to 960 ° C.
- the reached temperature on the surface of the tooth root portion 815 was in the range of 920 ° C. to 940 ° C.
- FIG. 8 is an actual temperature increase chart on the surface of the tooth root portion 815 in the temperature increase period “d1”.
- This high-frequency heating was performed individually one by one while flowing (transporting) the gears 8 in units of one.
- Water cooling in the rapid cooling period “d2” was about 13 seconds, and the cooling rate during that period was 50 to 65 ° C./second.
- the gear 8 was rotated, and cooling water was sprayed toward the gear 8 from the periphery, thereby cooling one by one.
- the quenching process was performed by a method that can suppress the occurrence of distortion most.
- the heat pattern of FIG. 7 is also an example, and can be changed to an optimum condition for the type of steel material to be used by appropriately performing a preliminary test. For example, as shown in FIG. 9, the cooling after the temperature rise may be performed in two stages.
- the gear 8 was subjected to three types of tests including a machinability test, a material investigation, and a fatigue test.
- machinability test was performed when the gear 8 was manufactured from hot-rolled steel by machining.
- the conditions for the machinability test were the conditions for turning in a dry environment with a peripheral speed of 250 m / min, a feed rate of 0.3 mm / rev, and a cutting depth of 1.5 mm using a carbide tool.
- Ten gears 8 were manufactured under these conditions, and when the chip did not occur in the cemented carbide tool, it was determined as “good”, and when the chip occurred, it was determined as “defective”.
- ⁇ Material survey> The material investigation was performed on a sample taken from the tooth wall surface 811 of the gear 8 after completion of the heat treatment but not subjected to the fatigue test described later. Two items were examined: hardness and grain size. Regarding the hardness, the Vickers hardness at a load of 2.9 N was measured at each depth of 0.05 mm from the surface of the sample, and the effective hardened layer depth defined by JIS G 0557 was measured. The crystal grain size was evaluated by obtaining the austenite grain size number defined in JIS G 0551 at a location 0.4 mm deep from the surface of the sample.
- the evaluation of material evaluation was performed according to the following criteria. (Good) Those satisfying all the following three conditions were judged as “good”. -The effective hardened layer depth should be 0.8mm or more. ⁇ There is no unevenness in Vickers hardness. Specifically, the difference between all adjacent measurement points is less than HV50. -Fine grain with austenite grain size number of "6" or more. (Bad) Those that did not satisfy any one of the above three conditions were judged as “defect”, and under which conditions the defect was identified. In the fatigue test described later, the fracture surface was observed with an SEM (scanning electron microscope) to confirm whether it was a grain boundary brittle fracture surface.
- SEM scanning electron microscope
- ⁇ Fatigue test> As a fatigue test, the tooth root bending fatigue strength (Nm) and the pitching strength (Nm) were measured with a power circulating gear tester.
- the specifications of the gear 8 subjected to the test are a module 2.03, a pressure angle of 18 °, and a helix angle of 27 °.
- the root bending fatigue strength was evaluated based on an input torque that could endure 10 million times under the conditions of a lubricating oil temperature of 80 ° C. and a rotational speed of 2000 rpm.
- the pitching strength was evaluated by an input torque at which the pitching area ratio became 3% or less of the total tooth contact area after 50 million tests under conditions of a lubricating oil temperature of 120 ° C. and a rotational speed of 4000 rpm. In all cases, ATF (automatic transmission fluid) was used as the lubricating oil.
- FIG. 10 shows test No. 1 which is one example of the present invention.
- 3 shows the details of the measurement results of Vickers hardness of No. 3.
- the vertical axis represents the Vickers hardness
- the horizontal axis represents the depth from the surface (tooth root portion 815).
- there is a Vickers hardness of about 800 on the surface and the Vickers hardness decreases as the depth increases.
- the depth is 2.6 mm or more
- the Vickers hardness is almost constant. From this, it can be seen that in this example, the effect of quenching is exerted on the portion from the surface to a depth of 2.6 mm, and the portion having a depth of about 2.6 mm or more is the non-quenched layer 93.
- the carburized layer 91 is in the range from the surface to a depth of 0.9 mm
- the hardened layer 92 is in the range from a depth of 0.9 mm to a depth of 2.6 mm.
- test No. There were items with poor results in any of 24-32. In Table 4, the poor results are shown in bold italics. Individually, it is as follows. Test No. In 24, the pitching strength was low. This is probably because the temper softening resistance was not sufficiently improved due to the amount of Si in the steel material being less than 0.35%. Test No. In No. 25, the machinability of the material was poor, and the gear 8 as a test piece could not be manufactured. It is thought that the material was too hard due to the C content in the steel material exceeding 0.40%. Test No. From 26 to 28, hardness unevenness was observed and fatigue strength was low (both tooth root and pitching).
- Test No. 30 the fatigue strength was remarkably low (both tooth root and pitching). For this reason, the SEM observation of the fracture surface confirmed that it was a grain boundary brittle fracture surface. This is probably because the S content in the steel material exceeds 0.15%, which causes segregation of S grain boundaries and causes grain boundary brittleness. Test No. In 31 and 32, hardness unevenness was seen and the tooth root fatigue strength was low. These comparative examples are those using conventional steel SCM420 (chromoly steel), which is considered to be due to poor penetration of cementite because both Cr and Mo are excessive. In particular, test no. In 33, the pitching strength was slightly low. This is thought to be due to the lack of Si in the steel material.
- the gear 8 of the present invention and the manufacturing method thereof reduce the material cost by reducing the Cr amount and the Mo amount as compared with the conventional chromoly steel. It was found that the fatigue strength was excellent, and other characteristics were equivalent or better.
- this Embodiment and an Example are only a mere illustration, and do not limit this invention at all. Therefore, the present invention can naturally be improved and modified in various ways without departing from the gist thereof.
- an example of the external gear having the tooth portion 81 formed outward has been described as the gear 8.
- the present invention is not limited to the external gear.
- the present invention can also be applied to an internal gear (for example, a ring gear of a planetary gear device) as shown in FIG.
- it can be applied to a bevel gear.
- the outer side in the radial direction corresponds to “down” or “deep”.
- FIG. 11 is a diagram in which a part is omitted, but in actuality, of course, the tooth profile is formed over the entire circumference.
Abstract
Description
C :0.1 ~0.40質量%,
Si:0.35~3.0 質量%,
Mn:0.1 ~3.0 質量%,
Cr:0.2 質量%未満,
Mo:0.1 質量%以下,
P :0.03質量%以下,
S :0.15質量%以下,
Al:0.05質量%以下,
N :0.03質量%以下,
Feおよび不可避不純物:残部,
という化学成分のものを用いる。
前記歯部の表層部,および,前記円板部における前記歯部同士の間の箇所である歯元部の表層部が,浸炭処理によりC濃度が前記素材鋼のC濃度より高くされるとともに,マルテンサイト組織を含む第1焼き入れ硬化層とされており,
前記歯部のうち前記第1焼き入れ硬化層とされている部分以外の部分と,前記円板部のうち前記歯元部の前記第1焼き入れ硬化層の下の部分と,前記円板部のうち前記歯部の下の部分とにわたり,C濃度が前記素材鋼のC濃度とされるとともに,マルテンサイト組織を含む第2焼き入れ硬化層が形成されており,
前記円板部における前記第2焼き入れ硬化層より深い領域が,C濃度が前記素材鋼のC濃度とされるとともに,マルテンサイト組織を含まない非焼き入れ層とされているものである。
素材鋼として,前記の化学成分のものを用い,
前記素材鋼で成形された歯車を,大気の酸素濃度より低い酸素濃度の浸炭雰囲気中で,前記素材鋼のオーステナイト化温度以上の温度に加熱して表面に浸炭層を形成する浸炭工程と,
前記浸炭工程後の前記歯車を,前記素材鋼がマルテンサイト変態する冷却速度より遅い冷却速度で,冷却による組織変態が完了する温度以下の温度まで冷却する冷却工程と,
前記冷却工程後の前記歯車を高密度エネルギー加熱により加熱することで,前記円板部における芯部を前記素材鋼のオーステナイト化温度以上の温度まで昇温させることなく,前記円板部における前記芯部より浅い領域と前記歯部とを前記素材鋼のオーステナイト化温度以上の温度まで昇温させ,その状態から,前記素材鋼がマルテンサイト変態する冷却速度以上の冷却速度で冷却することにより,前記円板部における前記芯部より浅い領域と前記歯部とにマルテンサイト組織を形成する焼入工程とを行うことにより歯車を製造する方法である。
Cは鋼素材の強度,特に深層部の強度を確保するために添加する元素である。そこで,本発明ではCの添加量の下限を0.1%として内部の強度を確保している。しかし,Cの添加量が0.40%を超えると,次の2点の不利がある。1つは,硬さが増加する一方で靱性が低下することである。もう1つは,鋼素材の切削性が悪化することである。このため,Cの添加量の上限を0.40%とした。より好ましい添加量の範囲は0.15~0.3%である。
Siは製鋼過程での脱酸に有効な元素であるとともに,鋼素材に必要な強度,焼入れ性を与え,焼戻し軟化抵抗を向上させるのに有効な元素である。本発明は,高価なCrやMoを大幅に削減できることを特徴としているが,歯車のピッチング強度のように焼き戻し軟化抵抗が必要とされる部品については,従来鋼であるCrMo鋼に対し,CrやMoの削減は不利となる場合がある。よって,CrやMoを削減しても必要とする焼き戻し軟化抵抗を得るために,Siを0.35%以上含有させることとした。しかし,Siの含有によるこの効果は3.0%程度で飽和するので,それ以上Siを含有させる積極的な意味はない。Si含有率が3.0%を超えていると,むしろ硬さの上昇を招き素材の切削性が悪化する。そこでSi含有量を0.35%~3.0%の範囲内にする必要がある。より好ましい範囲は0.45%超~1.5%である。
Mnは製鋼過程での脱酸に有効な元素であるとともに,焼き入れ性を向上させるのに有効な元素である。ただし,含有量が0.1%未満ではその効果は不十分である。しかし,Mnの含有によるこの効果は3.0%程度で飽和するので,それ以上Mnを含有させる積極的な意味はない。Mn含有率が3.0%を超えていると,むしろ硬さの上昇を招き素材の切削性が悪化する。そこでMn含有量を0.1%~3.0%の範囲内にする必要がある。より好ましい範囲は0.5%~1.5%である。
Pは鋼中で粒界に偏析して靱性を低下させる作用を有する。このため極力低減する必要がある。0にすることは困難であるが,0.03%以下に制限する必要がある。
Sは鋼中でMnSを形成するので,これによる素材の切削性の向上を目的として添加される元素である。ただし,Sの含有によるこの効果は,0.15%程度で飽和するので,それ以上Sを含有させる積極的な意味はない。S含有率が0.15%を超えていると,むしろ粒界偏析を起こし粒界脆化を招く。このため,Sの含有量を0.15%以下にする必要がある。なお,S量が0.001%未満であると切削性向上効果が顕著でない。このため,下限を規定するのであれば0.001%以上とする。より好ましい範囲は0.005~0.06%の範囲内である。
Alは窒化物として鋼中に析出分散する。このことによりAlは,浸炭処理時のオーステナイト組織の粗大化を防止するのに有効な元素とされている。ただし,0.05%を超えていると,析出物が粗大化して鋼を脆化させる。このため0.05%を上限とする。なお,高密度エネルギー焼入処理が行われた部位では再結晶が起こり,粗大化したオーステナイト組織が微細化される。このため,高密度エネルギー焼入処理が行われる部位だけ高い強度が必要とされ,高密度エネルギーで加熱しない領域では高い強度が必要とされない場合には,Alを含有させることは必須ではない。しかし,高密度エネルギーで加熱しない領域にも高い強度が必要とされる場合には,Alを含有させる必要性がある。その場合には,Al量が0.005%未満であるとオーステナイト組織の粗大化防止効果が不十分である。このため,下限を規定するのであれば0.005%以上とする。より好ましい範囲は0.02~0.04%である。
Nは各種の窒化物を形成して浸炭処理時および高密度エネルギー焼入処理時のオーステナイト組織の粗大化を防止する効果がある。しかし,0.03%を超えていると鍛造性が著しく悪くなる。このため0.03%を上限とする。なお,Alのところで述べたのと同様の理由により,高密度エネルギーで加熱しない領域にも高い強度が必要とされる場合にのみ,Nの含有が必須となる。その場合には,N量が0.003%未満であるとオーステナイト組織の粗大化防止効果が不十分である。このため,下限を規定するのであれば0.003%以上が必要である。より好ましい範囲は0.005~0.02%である。
Crは,0.2%未満の添加量では焼入れ性,および焼戻し軟化抵抗を向上させるのに有効な元素である。しかし,0.2%以上の添加量では浸炭後の徐冷時に,浸炭層内のパーライト,フェライト中にCr炭化物が生成されてしまう。特に浸炭時のC濃度が0.5~0.8%未満の亜共析組成の場合にこれが顕著である。徐冷後の高密度エネルギーによる加熱を比較的高温(例えば950℃以上)で行うと,このCr炭化物はマトリックス中に溶解する。このため,高周波加熱時のオーステナイト変態が均一に起こり,均一な焼き入れ組織が得られる。これにより硬度も均一となる。一方,徐冷後の高密度エネルギーによる加熱を比較的低温(例えば950℃未満)で行うと,Cr炭化物のマトリックス中への溶解があまり起こらない。このためオーステナイト変態が不均一となり,焼き入れ組織も不均一となる。このことが硬度ムラの発生要因となる。そのため浸炭時のC濃度が0.5~0.8%未満のときはCr量を必要最小限に抑え,Cr炭化物の生成自体を抑えることが好ましい。
[Si%]+[Ni%]+[Cu%]-[Cr%]>0.5
の条件を満たす化学成分とすることで,Cr炭化物の生成をかなり抑制できることが知られている。しかしそれでも,上記硬さムラを抑制するには十分とは言えない。Cr含有量のより好ましい範囲は0.1%以下である。なお,Crの含有量の低減は,焼入れ性および焼戻し軟化抵抗を低下させてしまう要因となるが,本発明では上述の通り,Si,Mnの適量の含有により,焼入れ性および焼戻し軟化抵抗を確保している。
本発明は,レアメタルでありその中でも比較的高価なMoを削減させることを1つの目的としている。ただし,きわめて少量であればMoを添加してもかまわない。Moは焼入れ性および焼戻し軟化抵抗を向上させるのに有効な元素である。しかし,Moの多量の含有はコストが上昇するだけでなく,Crの場合ほど顕著ではないが,Crと同じ理由で硬度ムラの発生要因となる。Moも浸炭後の徐冷の際に炭化物を形成するからである。このため,上限を0.1%とする必要がある。他の元素によって必要な焼き入れ性や焼戻し軟化抵抗を確保できるのであれば,Moを添加しないことが望ましい。その場合には,積極的には添加していないといえる条件である0.01%未満とするのがよい。なお,Moの含有量の低減も,Crの場合と同様に,焼入れ性および焼戻し軟化抵抗を低下させてしまう要因となるが,本発明では上述の通り,Si,Mnの含有によりこれに対処している。
Ti:0.005~0.2%,
TiはNと結合しやすい元素である。このため,BがBNとなってBの焼き入れ性向上効果が消失するのを防止する効果がある。また,炭窒化物として鋼中に析出分散するので,浸炭処理時及び高周波焼入処理時のオーステナイト組織の粗大化を防止するのに有効な元素である。ただし,0.005%未満ではその効果は顕著でない。しかし,0.2%を超えていると析出物が粗大化して鋼を脆化させる。このため上限を0.2%とした。Tiの添加量の最も好ましい範囲は0.01~0.03%である。
Bは,添加することによって焼入れ性を与え,粒界強度を強化するのに有効な元素である。ただし,0.0006%未満ではその効果は顕著でない。しかし,0.005%程度でこの効果は飽和するので,それ以上添加することに積極的な意味はない。よって,0.0006%~0.005%が好ましい範囲である。最も好ましい範囲は0.001%~0.003%である。
Nb:0.01~0.3%,V:0.01~0.2%,
Nb,Vは炭窒化物として鋼中に析出分散する元素である。このため,浸炭処理時および高周波焼入処理時のオーステナイト組織の粗大化を防止するのに有効である。ただし,Nb,Vともに0.01%未満ではその効果は顕著でない。しかし,添加量が多すぎると析出物が粗大化して鋼を脆化させる。このため上限を,Nbは0.3%,Vは0.2%とした。最も好ましくは,Nbは0.01~0.02%の範囲内で,Vは0.01~0.05%の範囲内で添加するのがよい。
Ni:0.1~3.0%
Niは靱性を向上させるのに有効な元素である。ただし,0.1%未満ではその効果は顕著でない。しかし,3.0%程度でこの効果は飽和するので,それ以上添加することに積極的な意味はない。3.0%を超えるNiを含んでいるとむしろ,硬さの上昇を招き素材の切削性が悪化する。このため,0.1%~3.0%の範囲内にする必要がある。最も好ましい範囲は0.5%~1.5%である。
浸炭雰囲気中にて歯車8を加熱することにより,歯車8の表層部に浸炭層を形成する処理を行う工程である。
2.冷却工程
浸炭工程後の歯車8を冷却する工程である。この冷却は,少なくとも,浸炭後の温度降下による組織変態が完了するまで行う必要がある。
3.焼き入れ工程
冷却工程後の歯車8を,高密度エネルギーによってオーステナイト領域まで局所的に加熱し,加熱した後に急冷して硬化する工程である。
試験No.24では,Siが不足している。
試験No.25では,Cが過剰である。
試験No.26~28では,Crが過剰である。
試験No.29では,Pが過剰である。
試験No.30では,Sが過剰である。
試験No.31では,Siが不足しており,CrとMoが過剰である。
試験No.32では,CrとMoが過剰である。
このうちの試験No.32,33は,従来鋼であるJIS-SCM420(クロモリ鋼)を素材として用いた例である。
切削性試験は上述のように,機械加工により熱延鋼材から歯車8を製作した際に行った。切削性試験の条件は,超硬工具を用いて,周速250m/分,送り量0.3mm/rev,切り込み1.5mmのドライ環境による旋削を行う条件とした。この条件で歯車8を10個製作し,超硬工具に欠けが生じなかった場合を「良好」とし,欠けが生じた場合を「不良」とした。
材質調査は,熱処理完了後の歯車8であって後述する疲労試験に供していないものの歯壁面811から採取したサンプルについて行った。調査した項目は,硬度と結晶粒度の2つである。硬度については,サンプルの表面から0.05mmおきに各深さにて,荷重2.9Nでのビッカース硬さを測定して,JIS G 0557で規定する有効硬化層深さを測定した。結晶粒度については,サンプルの表面から0.4mmの深さの箇所において,JIS G 0551で規定するオーステナイト結晶粒度番号を求めて評価した。
(良好)
次の3つの条件をすべて満たしているものを「良好」と判定した。
・有効硬化層深さが0.8mm以上確保されていること。
・ビッカース硬さにムラがないこと。具体的にはすべての隣接する測定点間での差がHV50未満であること。
・オーステナイト粒度番号が「6」以上の細粒であること。
(不良)
上記の3つの条件のうちいずれか1つでも満たしていないものは「不良」と判定し,どの条件で不良となったかを特定した。なお,後述する疲労試験で著しく低強度であったものについては,破面をSEM(走査型電子顕微鏡)で観察して,粒界脆性破面となっているか否かを確認した。
疲労試験としては,動力循環式歯車試験機で,歯元曲げ疲労強度(Nm)とピッチング強度(Nm)とを測定した。試験に供した歯車8の諸元は,モジュール2.03,圧力角18°,ねじれ角27°である。歯元曲げ疲労強度は,潤滑油温80℃,回転数2000rpmの条件下で1000万回耐久する入力トルクにて評価した。ピッチング強度は,潤滑油温120℃,回転数4000rpmの条件下で5000万回供試後に,ピッチング面積率が全歯当たり面積の3%以下となる入力トルクにて評価した。いずれにおいても,潤滑油としてはATF(オートマチックトランスミッションフルード)を用いた。
試験No.24では,ピッチング強度が低かった。鋼素材中のSi量が0.35%に満たないことに起因して,焼き戻し軟化抵抗の向上が不十分であったためと考えられる。
試験No.25では,素材の切削性が悪く,試験片である歯車8を製作することができなかった。鋼素材中のC量が0.40%を超えていることに起因して,素材が硬すぎたためと考えられる。
試験No.26~28では,硬さムラが見られ,疲労強度が低かった(歯元,ピッチングとも)。鋼素材中のCr量が0.2%を超えていることによりセメンタイトの溶け込み不良が発生したためと考えられる。
試験No.29では,疲労強度が著しく低かった(歯元,ピッチングとも)。このため破面のSEM観察をしたところ,粒界脆性破面となっていることが確認された。鋼素材中のP量が0.03%を超えていることにより,Pの粒界偏析が生じて粒界脆性を起こしたためと考えられる。
試験No.31,32では,硬さムラが見られ,歯元疲労強度が低かった。これらの比較例は従来鋼SCM420(クロモリ鋼)を用いたものであり,Cr量とMo量とがともに過剰であるためにセメンタイトの溶け込み不良が発生したためと考えられる。特に試験No.33ではピッチング強度もやや低かった。これは,鋼素材中のSi量が不足していることによると考えられる。
815 歯元部
82 円板部
91 浸炭層
92 焼き入れ硬化層
93 非焼き入れ層
Claims (9)
- 円板部と,前記円板部に円周状に離散的に形成された複数の歯部とを有し,成形後に浸炭処理とその後の高密度エネルギー加熱による焼き入れ処理とを経ている歯車において, 素材鋼の化学成分が
C :0.1 ~0.40質量%,
Si:0.35~3.0 質量%,
Mn:0.1 ~3.0 質量%,
Cr:0.2 質量%未満,
Mo:0.1 質量%以下,
P :0.03質量%以下,
S :0.15質量%以下,
Al:0.05質量%以下,
N :0.03質量%以下,
Feおよび不可避不純物:残部,であり,
前記歯部の表層部,および,前記円板部における前記歯部同士の間の箇所である歯元部の表層部が,浸炭処理によりC濃度が前記素材鋼のC濃度より高くされるとともに,マルテンサイト組織を含む第1焼き入れ硬化層とされており,
前記歯部のうち前記第1焼き入れ硬化層とされている部分以外の部分と,前記円板部のうち前記歯元部の前記第1焼き入れ硬化層の下の部分と,前記円板部のうち前記歯部の下の部分とにわたり,C濃度が前記素材鋼のC濃度とされるとともに,マルテンサイト組織を含む第2焼き入れ硬化層が形成されており,
前記円板部における前記第2焼き入れ硬化層より深い領域が,C濃度が前記素材鋼のC濃度とされるとともに,マルテンサイト組織を含まない非焼き入れ層とされていることを特徴とする歯車。 - 請求項1に記載の歯車において,前記第1焼き入れ硬化層のC濃度が,
表面にて0.60~0.85質量%であるとともに,
内部では前記第2焼き入れ硬化層との境界に向かって徐々に低下していることを特徴とする歯車。 - 請求項1または請求項2に記載の歯車において,素材鋼の化学成分にさらに,
Ti:0.005 ~0.2 質量%,
B :0.0006~0.005質量%,
が含まれることを特徴とする歯車。 - 請求項1から請求項3までのいずれか1つに記載の歯車において,
素材鋼の化学成分中のMoの含有量が0.01%未満であることを特徴とする歯車。 - 請求項1から請求項4までのいずれか1つに記載の歯車において,
素材鋼の化学成分にさらに,
Nb:0.01~0.3質量%,
V :0.01~0.2質量%,
の1種または2種が含まれることを特徴とする歯車。 - 請求項1から請求項5までのいずれか1つに記載の歯車において,
素材鋼の化学成分にさらに,
Ni:0.1~3.0質量%,
が含まれることを特徴とする歯車。 - 円板部と,前記円板部に円周状に離散的に形成された複数の歯部とを有する歯車の製造方法において,
素材鋼として,化学成分が
C :0.1 ~0.40質量%,
Si:0.35~3.0 質量%,
Mn:0.1 ~3.0 質量%,
Cr:0.2 質量%未満,
Mo:0.1 質量%以下,
P :0.03質量%以下,
S :0.15質量%以下,
Al:0.05質量%以下,
N :0.03質量%以下,
Feおよび不可避不純物:残部,であるものを用い,
前記素材鋼で成形された歯車を,大気の酸素濃度より低い酸素濃度の浸炭雰囲気中で,前記素材鋼のオーステナイト化温度以上の温度に加熱して表面に浸炭層を形成する浸炭工程と,
前記浸炭工程後の前記歯車を,前記素材鋼がマルテンサイト変態する冷却速度より遅い冷却速度で,冷却による組織変態が完了する温度以下の温度まで冷却する冷却工程と,
前記冷却工程後の前記歯車を高密度エネルギー加熱により加熱することで,前記円板部における芯部を前記素材鋼のオーステナイト化温度以上の温度まで昇温させることなく,前記円板部における前記芯部より浅い領域と前記歯部とを前記素材鋼のオーステナイト化温度以上の温度まで昇温させ,その状態から,前記素材鋼がマルテンサイト変態する冷却速度以上の冷却速度で冷却することにより,前記円板部における前記芯部より浅い領域と前記歯部とにマルテンサイト組織を形成する焼入工程とを行うことを特徴とする歯車の製造方法。 - 請求項7に記載の歯車の製造方法において,
前記浸炭工程を,その浸炭工程の拡散期後における浸炭層内の炭素濃度が0.85質量%以下となる条件で行うことを特徴とする歯車の製造方法。 - 請求項7または請求項8に記載の歯車の製造方法において,
前記浸炭工程に供する歯車が,
その形状に起因して,浸炭処理時に侵入した炭素の拡散速度が異なる第1部位と第2部位とを有し,
前記第1部位よりも上記第2部位の方が侵入した炭素の拡散速度が遅いという形状を呈しているものであり,
前記浸炭工程を,その浸炭工程における拡散期後における前記第1部位の浸炭層内の炭素濃度が0.65±0.1質量%の範囲内となる条件で行うことを特徴とする歯車の製造方法。
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