WO2011120968A3 - Procédé de valorisation de l'essence - Google Patents
Procédé de valorisation de l'essence Download PDFInfo
- Publication number
- WO2011120968A3 WO2011120968A3 PCT/EP2011/054824 EP2011054824W WO2011120968A3 WO 2011120968 A3 WO2011120968 A3 WO 2011120968A3 EP 2011054824 W EP2011054824 W EP 2011054824W WO 2011120968 A3 WO2011120968 A3 WO 2011120968A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- crystalline
- catalyst
- stream
- olefins
- aluminophosphates
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 abstract 4
- 150000001336 alkenes Chemical class 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/38—Base treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/40—Special temperature treatment, i.e. other than just for template removal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/83—Aluminophosphates [APO compounds]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1088—Olefins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1096—Aromatics or polyaromatics
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/301—Boiling range
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La présente invention concerne un procédé permettant d'ajuster l'équilibre essence/diesel en convertissant une charge d'alimentation initiale contenant des oléfines de 4 à 20 atomes de carbone au moyen d'un catalyseur cristallin avec des limitations de diffusion réduites. Le procédé comprend : - le traitement d'un courant de charge d'alimentation contenant des oléfines de 4 à 20 atomes de carbone en présence ou en l'absence d'un courant contenant des substances aromatiques, - la mise en contact dudit ou desdits courants avec un catalyseur dans des conditions efficaces pour oligomériser au moins une partie des oléfines et finalement alkyler au moins une partie des substances aromatiques, le catalyseur étant un composé cristallin ayant une structure micro/mésoporeuse, choisi parmi les aluminosilicates cristallins, les aluminophosphates cristallins, les silico-aluminophosphates cristallins, les zéolites cristallines, ou le catalyseur étant un matériau composite comprenant au moins 20 % en poids d'au moins un des composés cristallins mentionnés ci-dessus, et le volume mésoporeux du composé cristallin étant au moins égal à 0,22 ml/g.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/637,549 US20130037446A1 (en) | 2010-03-30 | 2011-03-29 | Gazoline upgrading process |
EP11710517A EP2553053A2 (fr) | 2010-03-30 | 2011-03-29 | Procédé de valorisation de l'essence |
CN2011800167771A CN102822320A (zh) | 2010-03-30 | 2011-03-29 | 汽油升级方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1052318A FR2958297B1 (fr) | 2010-03-30 | 2010-03-30 | Procede de valorisation d'essence |
FR1052318 | 2010-03-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2011120968A2 WO2011120968A2 (fr) | 2011-10-06 |
WO2011120968A3 true WO2011120968A3 (fr) | 2012-06-07 |
Family
ID=43125488
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2011/054824 WO2011120968A2 (fr) | 2010-03-30 | 2011-03-29 | Procédé de valorisation de l'essence |
Country Status (5)
Country | Link |
---|---|
US (1) | US20130037446A1 (fr) |
EP (1) | EP2553053A2 (fr) |
CN (1) | CN102822320A (fr) |
FR (1) | FR2958297B1 (fr) |
WO (1) | WO2011120968A2 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3009207B1 (fr) * | 2013-08-02 | 2021-04-30 | Ifp Energies Now | Modification de zeolithe de type euo et son utilisation en isomerisation des composes c8 aromatiques |
KR102068312B1 (ko) | 2013-10-18 | 2020-01-20 | 에스케이이노베이션 주식회사 | 활성화된 eu-2 제올라이트 및 이의 용도 |
US9670425B2 (en) | 2013-12-17 | 2017-06-06 | Uop Llc | Process for oligomerizing and cracking to make propylene and aromatics |
US9732285B2 (en) | 2013-12-17 | 2017-08-15 | Uop Llc | Process for oligomerization of gasoline to make diesel |
EP3310883B1 (fr) * | 2015-06-22 | 2021-04-28 | Patrick James Cadenhouse-Beaty | Procédé de production d'un mélange de carburant pour le transport |
US11149214B2 (en) | 2018-12-17 | 2021-10-19 | Saudi Arabian Oil Company | Method and process to maximize diesel yield |
CN115716651B (zh) * | 2021-08-25 | 2024-04-30 | 中国石油天然气股份有限公司 | Zsm-35分子筛及其制备方法、异构化催化剂及其制备方法、异构化方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2931818A1 (fr) * | 2008-05-28 | 2009-12-04 | Inst Francais Du Petrole | Procede d'oligomerisation des olefines legeres utilisant un catalyseur a base d'un materiau amorphe a porosite hierarchisee et organisee |
FR2931708A1 (fr) * | 2008-05-28 | 2009-12-04 | Inst Francais Du Petrole | Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4150062A (en) | 1976-12-20 | 1979-04-17 | Mobil Oil Corporation | Light olefin processing |
US4227992A (en) | 1979-05-24 | 1980-10-14 | Mobil Oil Corporation | Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil |
US4482772A (en) | 1983-11-03 | 1984-11-13 | Mobil Oil Corporation | Multistage process for converting oxygenates to hydrocarbons |
US4506106A (en) | 1984-01-04 | 1985-03-19 | Mobil Oil Corporation | Multistage process for converting oxygenates to distillate hydrocarbons with interstage ethene recovery |
US4543435A (en) | 1985-01-17 | 1985-09-24 | Mobil Oil Corporation | Multistage process for converting oxygenates to liquid hydrocarbons with ethene recycle |
DE3838710A1 (de) | 1988-11-15 | 1990-05-17 | Sued Chemie Ag | Katalysator auf der basis von kristallinen alumosilikaten |
US5601798A (en) | 1993-09-07 | 1997-02-11 | Pq Corporation | Process for preparing zeolite Y with increased mesopore volume |
DE102005003109B4 (de) * | 2005-01-22 | 2015-02-12 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren zur Herstellung von synthetischen Kraftstoffen aus Oxigenaten |
US8299312B2 (en) * | 2005-10-28 | 2012-10-30 | Neste Oil Oyj | Process for dimerizing olefins |
-
2010
- 2010-03-30 FR FR1052318A patent/FR2958297B1/fr not_active Expired - Fee Related
-
2011
- 2011-03-29 CN CN2011800167771A patent/CN102822320A/zh active Pending
- 2011-03-29 US US13/637,549 patent/US20130037446A1/en not_active Abandoned
- 2011-03-29 EP EP11710517A patent/EP2553053A2/fr not_active Withdrawn
- 2011-03-29 WO PCT/EP2011/054824 patent/WO2011120968A2/fr active Application Filing
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2931818A1 (fr) * | 2008-05-28 | 2009-12-04 | Inst Francais Du Petrole | Procede d'oligomerisation des olefines legeres utilisant un catalyseur a base d'un materiau amorphe a porosite hierarchisee et organisee |
FR2931708A1 (fr) * | 2008-05-28 | 2009-12-04 | Inst Francais Du Petrole | Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres |
Non-Patent Citations (2)
Title |
---|
J. GROEN, J. JANSEN, J. MOULIJN, J. PEREZ-RAMIREZ: "OPTIMAL ALUMINUM-ASSISTED MESOPOROSITY DEVELOPMENT IN MFI ZEOLITES BY DESILICATION", JOURNAL OF PHYSICAL CHEMISTRY B 20040902 AMERICAN CHEMICAL SOCIETY US, vol. 108, no. 35, 2 September 2004 (2004-09-02), pages 13062 - 13065, XP002611652, DOI: DOI:10.1021/JP047194F * |
OGURA M ET AL: "Alkali-treatment technique - new method for modification of structural and acid-catalytic properties of ZSM-5 zeolites", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 219, no. 1-2, 5 October 2001 (2001-10-05), pages 33 - 43, XP004303345, ISSN: 0926-860X, DOI: DOI:10.1016/S0926-860X(01)00645-7 * |
Also Published As
Publication number | Publication date |
---|---|
FR2958297B1 (fr) | 2013-11-29 |
FR2958297A1 (fr) | 2011-10-07 |
WO2011120968A2 (fr) | 2011-10-06 |
CN102822320A (zh) | 2012-12-12 |
US20130037446A1 (en) | 2013-02-14 |
EP2553053A2 (fr) | 2013-02-06 |
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