WO2011096580A1 - Transparent planar body and transparent touch switch - Google Patents
Transparent planar body and transparent touch switch Download PDFInfo
- Publication number
- WO2011096580A1 WO2011096580A1 PCT/JP2011/052669 JP2011052669W WO2011096580A1 WO 2011096580 A1 WO2011096580 A1 WO 2011096580A1 JP 2011052669 W JP2011052669 W JP 2011052669W WO 2011096580 A1 WO2011096580 A1 WO 2011096580A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- transparent
- transparent conductive
- refractive
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- G—PHYSICS
- G06—COMPUTING OR CALCULATING; COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
- G06F3/044—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
- G06F3/0445—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using two or more layers of sensing electrodes, e.g. using two layers of electrodes separated by a dielectric layer
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/13338—Input devices, e.g. touch panels
Definitions
- the present invention relates to a transparent planar body and a transparent touch switch.
- a capacitive touch switch for detecting the location of input.
- a capacitive touch switch is known.
- a touch switch disclosed in Patent Document 1 comprises a dielectric layer lying between a pair of transparent planar bodies each provided with a transparent electric conductor patterned into a predetermined shape.
- a finger or the like touches the operation surface, utilizing the change in capacitance caused by grounding through the human body, the touch location can be detected.
- Patent Document 1 JP-A-2003-173238 (Figs. 1 and 5)
- Such a touch switch is mounted on the surface of a liquid crystal display, CRT, or the like.
- the pattern shape of the transparent electric conductor formed in the transparent planar body is conspicuous, resulting in reduced visibility.
- Such a problem is present not only in capacitive touch switches but also in touch switches with a matrix pattern, etc .
- an object of the invention is to provide a transparent planar body and a transparent touch switch, which are capable of providing improved visibility.
- a transparent planar body comprising a silicon-containing layer; an adhesive layer disposed on at least one side of the silicon-containing layer; and a patterned transparent conductive layer disposed between the silicon-containing layer and the adhesive layer.
- the difference between the maximum and minimum of the absolute value is 0.65 or less at 450 nm to 700 ran.
- the silicon-containing layer includes a low-refractive-index layer and a high-refractive-index layer having a higher optical refractive index than the low-refractive-index layer, and the transparent conductive layer is formed on the low-refractive-index-layer side of the silicon-containing layer.
- the low-refractive-index layer has an optical refractive index of 1.45 to 1.47, and the high-refractive-index layer has an optical refractive index of more than 1.47 and not more than 1.53.
- the low-refractive-index layer is made of Si0 2
- the high-refractive-index layer is made of a glass material.
- the transparent conductive layer has a thickness of 12 nm or less.
- the transparent conductive layer has a thickness of 12 nm or more and 14nm or less, and the low-refractive-index layer has a thickness of 10 nm to 45 nm.
- the thickness of the low-refractive-index layer is not greater than the value calculated by the following equation 1: Equation 1: 0.3409X 2 - 16.705X + 217.73
- X represents the thickness of the transparent conductive layer.
- the thickness of the low-refractive-index layer is not greater than the value calculated by the following equation 2 :
- Equation 2 -10X + 185
- -X represents the thickness of the transparent conductive layer.
- the object of the present invention can also be achieved by a transparent touch switch comprising the above transparent planar body, the transparent planar body being arranged in such a manner that the transparent conductive layer of the transparent planar body and a second transparent conductive layer that is different from the transparent conductive layer of the transparent planar body face each other or face the same direction.
- a transparent planar body and a transparent touch switch which are capable of providing improved visibility, can be provided.
- Fig. 1 a schematic cross-sectional view of a transparent touch switch according to an embodiment of the invention.
- Fig. 2 is a plane view of a portion of the transparent touch switch shown in Fig. 1.
- Fig. 3 is a plane view of another portion of the transparent touch switch shown in Fig. 1.
- Fig. 4 is a plane view of a portion of a variation of the transparent touch switch shown in Fig. 1.
- Fig. 5 is a plane view showing another portion of the variation of the transparent touch switch shown in Fig. 1.
- Fig. 6 is a schematic cross-sectional view of a transparent planar body forming the transparent touch switch shown in Fig. 1.
- Fig. 7 shows the results of measurement of the difference in reflectance depending on the presence of a transparent conductive layer in a sample.
- Fig.8 shows the results of simulation of the difference in reflectance depending on the presence of a transparent conductive layer when the transparent conductive layer thickness is 8 nm.
- Fig. 9 shows the results of simulation of the difference in reflectance depending on the presence of a transparent conductive layer when the transparent conductive layer thickness is 10 nm.
- Fig. 10 shows the results of simulation of the difference in reflectance depending on the presence of a transparent conductive layer when the transparent conductive layer thickness is 12 nm.
- Fig. 11 shows the results of simulation of the difference in reflectance depending -on the presence of a transparent conductive layer when the transparent conductive layer thickness is 14 nm.
- Fig. 12 is a graph showing the ' relation between the thickness of a low-refractive-index layer that allows the difference between the maximum and minimum of the reflectance difference to be 0.65 or less or 0.5 or less and the thickness of a transparent conductive layer.
- Fig. 13 is a graph showing the relation between the thickness of a low-refractive-index layer that allows where the maximum of the reflectance difference to be. 0.8 or less or 0.7 or less and the thickness of a transparent conductive layer.
- Fig. 1 is a schematic cross-sectional view of a transparent touch switch according to one embodiment of the invention.
- the transparent touch switch 101 is a capacitive touch switch, and includes a first transparent planar body 1 and a second transparent planar body 2.
- the first transparent planar body 1 includes a transparent silicon-containing layer 11, an adhesive layer 13 disposed on at least one side of the silicon-containing layer 11, and a patterned transparent conductive layer 12 disposed between the silicon-containing layer 11 and the adhesive layer 13.
- the second transparent planar body 2 includes a patterned transparent conductive layer 22 on one side of a transparent substrate 21.
- the first transparent planar body 1 and the second transparent planar body 2 are arranged in such a manner that the transparent conductive layers 12 and 22 face each other. They may also be arranged in such a manner that the transparent .conductive layers 12 and 22 face the same direction.
- the silicon-containing layer 11 includes a low-refractive-index layer 111 and a high-refractive-index layer 112 having a higher optical refractive index than the low-refractive-index layer 111.
- the transparent conductive layer 12 is formed on the low-refractive-index-layer-111 side of the silicon-containing layer 11.
- the low-refractive-index layer 111 may be made of Si0 2 , for example.
- the low-refractive-index layer 111 preferably has an optical refractive index within a range of 1.45 to 1.47.
- the high-refractive-index layer 112 may be made of a glass material, such as soda glass, alkali-free glass, or borosilicate glass, for example.
- the thickness of the high-refractive-index layer 112 is not limited. However, it is preferable that the high-refractive-index layer 112 has a thickness of about 0.3 to about 5.0 mm and an optical refractive index of more than 1.47 and not more than 1.53. If the surface of the silicon-containing layer 11 is to be touched by a pen or a finger, such a surface maybe treated for improving transparency, abrasion resistance, wear resistance, and non-glare properties. It is also possible to put a film thereon for preventing cracks.
- the transparent substrate 21 is preferably made of a highly transparent material.
- a highly transparent material include flexible films of polyethylene terephthalate (PET), polyimide (PI), polyethylene naphthalate (PEN) , polyethersulfone (PES), , polyetheretherketone (PEEK), polycarbonate (PC), polypropylene (PP), polyamide (PA), polyacryl (PAC) , acryl, amorphous polyolefinic resins, cyclic polyolefinic resins, alicyclic polyolefins, transparent thermoplastic norbornene resins, and the like; laminates of two or more kinds thereof; glass; etc.
- Examples of materials for the transparent conductive layers 12 and 22 include transparent conductive materials such as indium tin oxide (ITO) , indium oxide, antimony-doped tin oxide, fluorine-doped tin oxide, aluminum-doped zinc oxide, potassium-doped zinc oxide, silicon-doped zinc oxide, zinc-oxide- and tin-oxide-based materials, indium-oxide- and tin-oxide-based materials, zinc-oxide-, indium-oxide-, and magnesium-oxide-based materials, zinc oxide, and tin oxide films; metal materials such as tin, copper, aluminum, nickel, and chromium; and metal oxide materials. Combined use of two or more kinds of these materials is also possible.
- ITO indium tin oxide
- ITO indium tin oxide
- antimony-doped tin oxide fluorine-doped tin oxide
- aluminum-doped zinc oxide potassium-doped zinc oxide
- Elemental metals sensitive to acid and alkali may also be used as conductive materials .
- the transparent conductive layers 12 and 22 can be formed by a PVD method, such as sputtering, vacuum deposition, or ion plating, a CVD method, a coating method, a printing method, etc., for example.
- the transparent conductive layers 12 and 22 each preferably have a thickness of 14 nm or less, andmore preferably 12 nm or less. When the thickness is 5 nm or less, such a layer is less likely to be a continuous film, making it difficult to form a stable conductive layer.
- a material for a transparent conductive layer a composite material prepared by dispersing ultrafine conductive carbon fibers, such as carbon nanotubes, carbon nanohorns, carbon nanowires, carbon nanofibers, or graphite fibrils, in a non-conductive polymer material.
- the transparent conductive layers 12 and 22 are formed as assemblies of a plurality of parallel, belt-like conductive members 12a and 22a, respectively.
- the belt-like conductive members 12a and 22a of the transparent conductive layers 12 and 22 are arranged orthogonal to each other.
- the transparent conductive layers 12 and 22 are connected to an external drive circuit (not illustrated) via a routing circuit (not illustrated) made bf conductive ink, etc.
- the pattern shapes of the transparent conductive films 12 and 22 are not limited to those described in this embodiment, and any shapes are possible as long as the finger contact area, for example, can be detected. For example, as shown in Figs.
- the transparent conductive films 12 and 22 may be configured to include a plurality of linearly connected, diamond-shaped conductive members 12b and 22b, respectively. They may be arranged in such a manner that the direction in which the diamond-shaped conductive members 12b of the transparent conductive layer 12 are connected is orthogonal to the direction in which the diamond-shaped conductive members 22b of the transparent conductive layer 22 are connected, and also that, in plane view, upper and lower diamond-shaped conductive members 12b/22b do not overlap each other.
- the operation performance such as resolution, of the transparent touch switch 101
- the configuration having a plurality of linearly connected, diamond-shaped conductive members 12b and 22b is preferred to a configuration having rectangular pattern shapes .
- the transparent conductive layers 12 and 22 can be patterned as follows. A mask portion having a desired pattern shape is formed on the surface of each of the transparent conductive films 12 and 22 formed on a silicon-containing layer and a transparent substrate, respectively, and exposed portions are removed by etching with an acid liquid or the like. The mask portion is then dissolved by an alkaline liquid, etc.
- the adhesive layer 13 may be made of an ordinary transparent adhesive, such an epoxy-based or acrylic adhesive, and may include a core material formed of a transparent film of a norbornene resin.
- the adhesive layer may be formed by stacking several sheets of an adhesive material or by stacking sheets of several kinds of adhesive materials .
- the thickness of the adhesive layer 13 is not limited. In practical application, the thickness is preferably 100 ⁇ or less, and particularly preferably 25 to 75 ⁇ .
- the adhesive layer preferably has an optical refractive index of 1.40 to 1.70, andmore preferably 1.46 to 1.57.
- the difference in refractive index at the interface decreases, resulting in improved effects in making the pattern shape inconspicuous .
- the adhesive layer in order to increase the refractive index of the adhesive layer, it is neccessary to add particulates of a high-refractive-index material thereto, for example, and this causes a problem in that the transmittance as a transparent planar body decreases.
- the adhesive layer preferably contains no material that may damage the transparent conductive layer, such as acid.
- the method for detecting the touch location is the same in known capacitive touch switches .
- the transparent conductive layers 12 and 22 are grounded through the capacitance of the human body at the touch location, and the value of current flowing through the transparent conductive layers 12 and 22 is detected, thereby calculating the coordinates of the touch location.
- the difference between the maximum ' and minimum of the absolute value is 0.65 or less, more preferably 0.5 or less, and still more preferably 0.4 or less, at a wavelength in the visible range, 450 nm to 700 nm.
- the difference between the maximum and the minimum is 0.65 or less, the pattern shape of the transparent conductive layer 12 can be made inconspicuous, thereby improving visibility.
- the present inventors produced samples of transparent planar bodies configured as above. With respect to the absolute value of the difference between the reflectance of a pattern-forming region, where the transparent conductive layer 12 was formed, at each wavelength of reflection LI of light applied thereto through the silicon-containing layer 11 and the reflectance of a pattern-non-forming region, where the transparent conductive layer 12 was not formed, at each wavelength of reflection L2 of light applied thereto through the silicon-containing layer 11, the difference between the maximum and the minimum of the absolute value was measured. The maximum of the reflectance difference was also measured. At the same time, sensory testing was performed to determine whether the pattern shape of the transparent conductive layer 12 was conspicuous.
- the samples have a structure as shown in Fig. 6.
- the high-refractive-index layer 112 and the low-refractive-index layer 111 forming the silicon-containing layer 11 were formed of a soda glass plate and a Si0 2 thin film, respectively.
- An ITO film was employed as the transparent conductive layer 12, and a film made of an acrylic pressure sensitive adhesive (refractive index: 1.52) was employed as the adhesive layer 13.
- the samples were thus configured. Five kinds of samples were prepared, varying the thickness of the transparent conductive layer 12 (ITO film) (8 nm, 10 nm, 12 nm, 14 nm, 16 nm) .
- the thickness of the high-refractive-index layer 112 was 1.1 mm
- the thickness of the low-refractive-index layer 111 was 12.5 nm
- the thickness of the adhesive layer 13 was 25 ⁇ .
- the low-refractive-index layer 111 (Si0 2 thin film) and the transparent conductive layer 12 (ITO film) were deposited by sputtering on the glass plate.
- spectral reflectance For the measurement of spectral reflectance, an apparatus manufactured by JASCO (V670+ integrating sphere unit) was used. The measurement conditions were as follows: photometry mode: %R, measurement range: 800 to 300 nm, data collection interval: 5 nm, UV/Vis bandwidth: 5.0 nm, NIR bandwidth: 2.0 nm, response: Medium, scattering rate: 400 nm/min, light source switching: 340 nm, diffraction grating switching: 850 nm, light source: D2/WI, filter switching: step, correction: baseline.
- the maximum and minimum of the absolute value of the difference between the above-obtained first spectral reflectance and second spectral reflectance were calculated. The difference between the maximum and the minimum was also calculated. Table 1 shows the difference between the maximum and the minimum (reflectance difference ⁇ ) , as well as the maximum of the reflectance difference, obtained by calculation.
- the surface resistance (Rs) of each sample is also shown in Table 1. Surface resistance (Rs) was measured using a resistivity meter Loresta EP MCP-T360 manufactured by MITSUBISHI CHEMICAL ANALYTECH. Table 1 also shows the results of sensory testing for each sample about the conspicuousness of the pattern shape. The test was performed under an ordinary fluorescent lamp in a room and under a three-band fluorescent lamp in a booth covered with a black sheet .
- the results in Table 1 show that when the thickness of the transparent conductive layer 12 (ITO film) is 8 nm, 10 nm, or 12 nm, the pattern shape of the transparent conductive layer 12 (ITO film) is barely noticeable, achieving excellent visibility .
- Fig.7 shows that in such cases, at a wavelength in the visible range, 450 nm to 700 nm, the difference (reflectance difference ⁇ ) between the maximum and minimum of the absolute value of the difference between the first spectral reflectance and the second spectral reflectance is 0.5 or less, and the absolute value of the difference between the first spectral reflectance and the second spectral reflectance is 0.7 or less.
- the thickness of the transparent conductive layer 12 is 14 nm
- the pattern shape is recognizable under severe evaluation conditions, i.e., under a three-band fluorescent lamp
- the pattern shape is barely visible under an ordinary fluorescent lamp.
- the reflectance difference ⁇ is 0.65 or less
- the absolute value of the difference between the first spectral reflectance and the second spectral reflectance is 0.8 or less
- practically usable visibility is achieved.
- the results also show that in the case where the thickness of the ITO film is 16 nm, where the reflectance difference ⁇ is more than 0.65 and the absolute value of the difference between the first spectral reflectance and the second spectral reflectance is more than 0.8, poor visibility is resulted.
- the surface resistance (Rs) increases with a decrease in the thickness of the transparent conductive layer 12 (ITO film) .
- the thickness of the transparent conductive layer 12 (ITO film) is particularly preferably 8 nm or more.
- the present inventors simulated a transparent planar body configured as above.
- the model used in the simulation has a structure as shown in Fig. 6, and the settings for the simulation were as follows.
- the silicon-containing layer 11 was formed to include a low-refractive-index layer 111 made of Si0 2 (optical refractive index: 1.46) and a high-refractive-index layer 112 made of soda glass (optical refractive index: 1.52) .
- the transparent conductive layer 12 was an ITO film (optical refractive index: 2.0) .
- the adhesive layer 13 was made of an acrylic pressure sensitive adhesive (optical refractive index: 1.52).
- the thickness of the transparent conductive layer 12 (ITO film) and the thickness of the low-refractive-index layer 111 of the silicon-containing layer 11 were each varied, and the difference in light reflectance (%) between the part in which the transparent conductive layer 12 was formed (pattern-forming region) and the part in which the transparent conductive layer 12 was not formed (pattern-non-forming region) was determined by the simulation.
- the reflectance was calculated using a thin-film designing software (OPTAS-FILM) manufactured by CYBERNET SYSTEMS .
- the high-refractive-index layer 112 of the silicon-containing layer 11 and the adhesive layer 13 are members of much greater thickness; in this simulation, reflectance was calculated assuming the thickness of such a member as ⁇ (infinite) .
- the inconspicuousness of the pattern shape of a transparent conductive layer 12 is correlated to the difference in reflectance between the part in which the transparent conductive film 12 is formed and the part in which it is not formed.
- the maximum of the reflectance difference is 0.8 or less, good visibility can be achieved. A maximum of 0.7 or less provides better visibility, and a maximum of 0.5 or less provides even better visibility.
- the pattern shape of the transparent conductive layer is even less conspicuous, resulting in even better visibility.
- Fig. 8 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 8 nm, and the thickness of the low-refractive-index layer 111 (Si0 2 film) of the silicon-containing layer 11 ' was varied (0 nm, 10 nm, 20 nm, 30 nm) .
- Fig. 9 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 10 nm, and the thickness of the low-refractive-index layer 111 (Si0 2 film) of the silicon-containing layer 11 was varied (0 nm, 10 nm, 20 rati, 30 nm) .
- Fig. 9 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 10 nm, and the thickness of the low-refractive-index layer 111 (Si0 2 film) of the silicon-containing layer 11 was varied (0 nm, 10 nm, 20 rati, 30 nm) .
- FIG. 10 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 12 nm, and the thickness of the low-refractive-index layer 111 (Si0 2 film) of the silicon-containing layer 11 was varied (0 nm, 10 nm, 20 nm, 30 nm) .
- Fig. 11 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 14 nm, and the thickness of the low-refractive-index layer 111 (Si0 2 film) of the silicon-containing layer 11 was varied (0 nm, 10 nm, 20 nm, 30 nm) .
- Table 2 shows the difference between the maximum and minimum of the reflectance difference at a wavelength in the visible range, 450 nm to 700 nm, which was derived from the simulation results shown in Figs. 8 to 11.
- the maximum of the reflectance difference is the value of reflectance difference at a wavelength of 450 nm
- the minimum of the reflectance difference is the value of reflectance difference at a wavelength of 700 nm.
- Table 3 shows the derived maximum of the reflectance difference at a wavelength in the visible range, 450 nm to 700 nm.
- Figs. 8 to 11 and Tables 2 and 3 show that in the case where the thickness of the transparent conductive layer 12 (ITO film) is 14 nm, when the thickness of the low-refractive-index layer 111 (Si0 2 film) is within a range of 0 to 30 nm, the difference between the maximum and minimum of the reflectance difference is 0.65 or less.
- the results show that when the thickness of the low-refractive-index layer 111 (Si0 2 film) is 10 nm, 20 nm, or 30 nm, the maximum of the reflectance difference is 0.8 or less, while when the thickness of the low-refractive-index layer 111 (Si0 2 film) is 0 nm, the maximum of the reflectance difference is more than 0.8.
- the thickness of the low-refractive-index layer 111 (Si0 2 film) was further varied, and the maximum thickness of the low-refractive-index layer 111 (Si0 2 film) that ' allowed the difference between the maximum and minimum of the reflectance difference to be 0.65 or less was calculated by the above simulation.
- Table 4 shows the derived difference between the maximum and minimum of the reflectance difference at a wavelength in the visible range, 450 nm to 700 nm.
- Table 4 shows that the maximum thickness of the low-refractive-index layer 111 (Si0 2 film) that allows the difference between the maximum and minimum of the reflectance difference to be 0.65 or less is about 85 nm when the thickness of the transparent conductive layer 12 (ITO film) is 10 nm, while it is about 65 nm when the thickness of the transparent conductive layer 12 (ITO film) is 12 nm. It is also shown that the maximum thickness is 60 nm when the thickness of the transparent conductive layer 12 (ITO film) is 13 nm, while it is 50 nm when the thickness of the transparent conductive layer 12 (ITO film) is 14 nm.
- Fig. 12 shows the ' relation between the maximum thickness of a low-refractive-index layer 111 (Si0 2 film) that allows the difference between the maximum and minimum of the reflectance difference to be 0.65 or less and the thickness of the transparent conductive layer 12 (ITO film) , plotting the maximum thickness on the ordinate and the thickness of the transparent conductive layer 12 (ITO film) on the abscissa.
- Fig. 12 also shows approximate curves obtained from the relation between the maximum thickness and the thickness of the transparent conductive layer 12 (ITO film) .
- Fig. 12 also shows the relation between the maximum thickness of a low-refractive-index layer 111 (Si0 2 film) that allows the difference between the maximum and minimum of the reflectance difference to be 0.5 or less and the thickness of the transparent conductive layer 12 (ITO film), as well as approximate curves obtained from the relation.
- Si0 2 film a low-refractive-index layer 111
- ITO film transparent conductive layer 12
- the difference between the maximum and minimum of the difference in reflectance at each wavelength between the part in which the transparent conductive layer 12 is formed (pattern-forming region) and the part in which the transparent conductive layer 12 is not formed (pattern-non-forming region) can be 0.65 or less. Therefore, in a transparent touch switch 101 configured as shown in Fig. 1, in relation with the thickness of a transparent conductive layer 12, by forming a low-refractive-index layer 111 to have a thickness not greater than the value calculated by the equation 1, the transparent touch switch 101 can be provided with excellent visibility, where the pattern shape of the transparent conductive layer 12 is inconspicuous.
- the maximum thickness of a low-refractive-index layer 111 (Si0 2 film) that allowed the maximum of the reflectance difference at a wavelength in the visible range, 450 nm to 700 nm, to be 0.8 or less was also calculated by the simulation. The results are shown in Table 5. With an increase in the thickness of the low-refractive-index layer 111 (Si0 2 film) , the maximum of the reflectance difference changes from a downward trend to an upward trend. Therefore, the calculation of the maximum of the reflectance difference is partially omitted. Table 5
- Table 5 shows that the maximum -thickness of the low-refractive-index layer 111 (Si0 2 film) that allows the maximum of the reflectance difference to be 0.8 or less is 85 nm when the thickness of the transparent conductive layer 12 (ITO film) is 10 nm, while it is 65 nm when the thickness of the transparent conductive layer 12 (ITO film) is 12 nm. It is also shown that in the case where the thickness of the transparent conductive layer 12 (ITO film) is 8 nm, even when the maximum thickness is 100 nm, the maximum of the reflectance difference is 0.8 or less.
- the maximum thickness of the low-refractive-index layer 111 that allows the maximum of the reflectance difference to be 0.8 or less is 45 nm.
- Fig. 13 shows the relation between the maximum thickness of a low-refractive-index layer 111 (Si0 2 film) that allows the maximum of the reflectance difference to be 0.8 or less and the thickness of the transparent conductive layer 12 (ITO film), plotting the maximum thickness on the ordinate ' and the thickness of the transparent conductive layer 12 (ITO film) on the abscissa.
- Fig. 13 also shows approximate lines obtained from the relation between the maximum thickness and the thickness of the transparent conductive layer 12 (ITO film) .
- the maximum of the reflectance difference will be 0.8 or less (however, when the thickness of the transparent conductive layer 12 (ITO film) is 12 nm to 14 nm, the cases where the thickness of the low-refractive-index layer 111 (Si0 2 film) is less than 10 nm are excluded) .
- Fig. 13 also shows the relation between the maximum thickness of a low-refractive-index layer 111 (Si0 2 film) that allows the maximum of the reflectance difference to be 0.7 or less and the thickness of the transparent conductive layer 12 (ITO film), as well as approximate lines obtained from the relation.
- the maximum of the difference in reflectance at each wavelength between the part where the transparent conductive layer 12 is formed (pattern-forming region) and the part where the transparent conductive layer 12 is not formed (pattern-non-forming region) ' can be 0.8 or less. Therefore, in a transparent touch switch 101 configured as shown in Fig. 1, in relation with the thickness of a transparent conductive layer 12, by forming a low-refractive-index layer 111 to have a thickness not greater than the value calculated by the equation 2,. the transparent touch switch 101 can be provided with excellent visibility, where the pattern shape of the transparent conductive layer 12 is inconspicuous.
- Embodiments of the transparent planar body 1 and the transparent touch switch 101 using the same according the invention have been described above; however, the specific configurations are not limited to the above embodiments.
- the patterned transparent conductive layer 22 is formed on one side of the transparent substrate 21 to form the second transparent planar body 2 in the above embodiments, it is also possible to use a silicon-containing layer 11 in place of the transparent substrate 21, and provide the second transparent planar body 2 with the same configuration as the first transparent planar body 1.
- the silicon-containing layer 11 includes the low-refractive-index layer 111 and the high-refractive-index layer 112 in the above embodiments, the silicon-containing layer 11 may be formed only of a high-refractive-index layer 112. With reference to the simulation results shown in Figs.
- the difference between the maximum and minimum of the difference in reflectance at each wavelength between the part in which the -transparent conductive layer 12 is formed (pattern-forming region) and the part in which the transparent conductive layer 12 is not formed (pattern-non-forming region) can be 0.65 or less. Accordingly, a transparent planar body 1 and a transparent touch switch 101 with excellent visibility, where the pattern of the transparent conductive layer 12 is inconspicuous, can be obtained.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Human Computer Interaction (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Position Input By Displaying (AREA)
- Laminated Bodies (AREA)
- Non-Insulated Conductors (AREA)
Abstract
Disclosed are a transparent planar body and a transparent touch switch, which are capable of providing improved visibility. The transparent planar body I includes a silicon-containing layer 11, an adhesive layer 13 disposed on at least one side of the silicon-containing layer 11, and a patterned transparent conductive layer 12 disposed between the silicon-containing layer 11 and the adhesive layer 13. With respect to the absolute value of the difference between the reflectance of a pattern-forming region, where the transparent conductive layer 12 is formed, at each wavelength of light applied thereto through the silicon-containing layer II and the reflectance of a pattern-non-forming region, where the transparent conductive layer 12 is not formed, at each wavelength of light applied thereto through the silicon-containing layer 11, the difference between the maximum and minimum of the absolute value is 0.65 or less at 450 nm to 700 nm.
Description
Description
TRANSPARENT PLANAR BODY AND TRANSPARENT TOUCH SWITCH
Technical Field
[0001]
The present invention relates to a transparent planar body and a transparent touch switch.
Background Art
[0002]
Various structures have been proposed for touch switches for detecting the location of input. As an example thereof, a capacitive touch switch is known. For example, a touch switch disclosed in Patent Document 1 comprises a dielectric layer lying between a pair of transparent planar bodies each provided with a transparent electric conductor patterned into a predetermined shape. When a finger or the like touches the operation surface, utilizing the change in capacitance caused by grounding through the human body, the touch location can be detected.
[0003]
Patent Document 1: JP-A-2003-173238 (Figs. 1 and 5)
Disclosure of the Invention
Problems to be Solved by the Invention
[0004]
Such a touch switch is mounted on the surface of a liquid crystal display, CRT, or the like. However, there is a problem in that the pattern shape of the transparent electric conductor formed in the transparent planar body is conspicuous, resulting in reduced visibility. Such a problem is present not only in capacitive touch switches but also in touch switches with a matrix pattern, etc .
[0005]
Thus, an object of the invention is to provide a transparent planar body and a transparent touch switch, which are capable of providing improved visibility.
Means for Solving the Problems
[0006]
The object of the invention mentioned above can be achieved by a transparent planar body comprising a silicon-containing layer; an adhesive layer disposed on at least one side of the silicon-containing layer; and a patterned transparent conductive layer disposed between the silicon-containing layer and the adhesive layer. With respect to the absolute value of the difference between the reflectance of a pattern-forming region, where the transparent conductive layer is formed, at each wavelength of light applied thereto through the silicon-containing layer and the reflectance of a pattern-non-forming region, where the transparent conductive layer is not formed, at each wavelength of light applied thereto through the silicon-containing layer, the difference between the maximum and minimum of the absolute value is 0.65 or less at 450 nm to 700 ran.
[0007]
In the transparent planar body, it is preferable that the maximum is
0.8 or less.
[0008]
It is preferable that the silicon-containing layer includes a low-refractive-index layer and a high-refractive-index layer having a higher optical refractive index than the low-refractive-index layer, and the transparent conductive layer is formed on the low-refractive-index-layer side of the silicon-containing layer.
[0009]
It is preferable that the low-refractive-index layer has an optical refractive index of 1.45 to 1.47, and the high-refractive-index layer has an optical refractive index of more than 1.47 and not more than 1.53.
[0010]
It is preferable that the low-refractive-index layer is made of Si02, and the high-refractive-index layer is made of a glass material.
[0011]
It is preferable that the transparent conductive layer has a thickness of 12 nm or less.
[0012]
It is also preferable that the transparent conductive layer has a thickness of 12 nm or more and 14nm or less, and the low-refractive-index layer has a thickness of 10 nm to 45 nm.
[0013]
It is preferable that the thickness of the low-refractive-index layer is not greater than the value calculated by the following equation 1:
Equation 1: 0.3409X2 - 16.705X + 217.73
wherein X represents the thickness of the transparent conductive layer.
[0014]
It is preferable that the thickness of the low-refractive-index layer is not greater than the value calculated by the following equation 2 :
Equation 2: -10X + 185
wherein -X represents the thickness of the transparent conductive layer.
[0015]
The object of the present invention can also be achieved by a transparent touch switch comprising the above transparent planar body, the transparent planar body being arranged in such a manner that the transparent conductive layer of the transparent planar body and a second transparent conductive layer that is different from the transparent conductive layer of the transparent planar body face each other or face the same direction.
Advantage of the Invention
[0016]
According to the invention, a transparent planar body and a transparent touch switch, which are capable of providing improved visibility, can be provided.
Brief Description of the Drawings
[0017]
Fig. 1 a schematic cross-sectional view of a transparent touch switch according to an embodiment of the invention.
Fig. 2 is a plane view of a portion of the transparent touch switch shown in Fig. 1.
Fig. 3 is a plane view of another portion of the transparent touch switch shown in Fig. 1.
Fig. 4 is a plane view of a portion of a variation of the transparent touch switch shown in Fig. 1.
Fig. 5 is a plane view showing another portion of the variation of the transparent touch switch shown in Fig. 1.
Fig. 6 is a schematic cross-sectional view of a transparent planar body forming the transparent touch switch shown in Fig. 1.
Fig. 7 shows the results of measurement of the difference in reflectance depending on the presence of a transparent conductive layer in a sample.
Fig.8 shows the results of simulation of the difference in reflectance
depending on the presence of a transparent conductive layer when the transparent conductive layer thickness is 8 nm.
Fig. 9 shows the results of simulation of the difference in reflectance depending on the presence of a transparent conductive layer when the transparent conductive layer thickness is 10 nm.
Fig. 10 shows the results of simulation of the difference in reflectance depending on the presence of a transparent conductive layer when the transparent conductive layer thickness is 12 nm.
Fig. 11 shows the results of simulation of the difference in reflectance depending -on the presence of a transparent conductive layer when the transparent conductive layer thickness is 14 nm.
Fig. 12 is a graph showing the' relation between the thickness of a low-refractive-index layer that allows the difference between the maximum and minimum of the reflectance difference to be 0.65 or less or 0.5 or less and the thickness of a transparent conductive layer.
Fig. 13 is a graph showing the relation between the thickness of a low-refractive-index layer that allows where the maximum of the reflectance difference to be. 0.8 or less or 0.7 or less and the thickness of a transparent conductive layer.
Best Mode for Carrying Out the Invention
[0018]
Hereinafter, some embodiments of the invention will be described with reference to the attached drawings. In order to facilitate understanding of the configuration, the drawings are not to scale, and components are partially enlarged or reduced.
[0019]
Fig. 1 is a schematic cross-sectional view of a transparent touch switch according to one embodiment of the invention. The transparent touch switch 101 is a capacitive touch switch, and includes a first transparent planar body 1 and a second transparent planar body 2. The first transparent planar body 1 includes a transparent silicon-containing layer 11, an adhesive layer 13 disposed on at least one side of the silicon-containing layer 11, and a patterned transparent conductive layer 12 disposed between the silicon-containing layer 11 and the adhesive layer 13. The second transparent planar body 2 includes a patterned transparent conductive layer 22 on one side of a transparent substrate 21. The first transparent planar body 1 and the second transparent planar body 2 are arranged
in such a manner that the transparent conductive layers 12 and 22 face each other. They may also be arranged in such a manner that the transparent .conductive layers 12 and 22 face the same direction.
[0020]
The silicon-containing layer 11 includes a low-refractive-index layer 111 and a high-refractive-index layer 112 having a higher optical refractive index than the low-refractive-index layer 111.· The transparent conductive layer 12 is formed on the low-refractive-index-layer-111 side of the silicon-containing layer 11. The low-refractive-index layer 111 may be made of Si02, for example. The low-refractive-index layer 111 preferably has an optical refractive index within a range of 1.45 to 1.47. The high-refractive-index layer 112 may be made of a glass material, such as soda glass, alkali-free glass, or borosilicate glass, for example. The thickness of the high-refractive-index layer 112 is not limited. However, it is preferable that the high-refractive-index layer 112 has a thickness of about 0.3 to about 5.0 mm and an optical refractive index of more than 1.47 and not more than 1.53. If the surface of the silicon-containing layer 11 is to be touched by a pen or a finger, such a surface maybe treated for improving transparency, abrasion resistance, wear resistance, and non-glare properties. It is also possible to put a film thereon for preventing cracks.
[0021]
The transparent substrate 21 is preferably made of a highly transparent material. Specific examples thereof include flexible films of polyethylene terephthalate (PET), polyimide (PI), polyethylene naphthalate (PEN) , polyethersulfone (PES), , polyetheretherketone (PEEK), polycarbonate (PC), polypropylene (PP), polyamide (PA), polyacryl (PAC) , acryl, amorphous polyolefinic resins, cyclic polyolefinic resins, alicyclic polyolefins, transparent thermoplastic norbornene resins, and the like; laminates of two or more kinds thereof; glass; etc.
[0022]
Examples of materials for the transparent conductive layers 12 and 22 include transparent conductive materials such as indium tin oxide (ITO) , indium oxide, antimony-doped tin oxide, fluorine-doped tin oxide, aluminum-doped zinc oxide, potassium-doped zinc oxide, silicon-doped zinc oxide, zinc-oxide- and tin-oxide-based materials, indium-oxide- and tin-oxide-based materials, zinc-oxide-, indium-oxide-, and magnesium-oxide-based materials, zinc oxide, and tin oxide films; metal materials such as tin, copper, aluminum, nickel, and chromium; and metal oxide materials. Combined use of two or more kinds of these materials
is also possible. Elemental metals sensitive to acid and alkali may also be used as conductive materials . The transparent conductive layers 12 and 22 can be formed by a PVD method, such as sputtering, vacuum deposition, or ion plating, a CVD method, a coating method, a printing method, etc., for example. The transparent conductive layers 12 and 22 each preferably have a thickness of 14 nm or less, andmore preferably 12 nm or less. When the thickness is 5 nm or less, such a layer is less likely to be a continuous film, making it difficult to form a stable conductive layer.
[0023]
It is also possible to use, as a material for a transparent conductive layer, a composite material prepared by dispersing ultrafine conductive carbon fibers, such as carbon nanotubes, carbon nanohorns, carbon nanowires, carbon nanofibers, or graphite fibrils, in a non-conductive polymer material.
[0024]
As shown in Fig. 2 and Fig. 3, the transparent conductive layers 12 and 22 are formed as assemblies of a plurality of parallel, belt-like conductive members 12a and 22a, respectively. The belt-like conductive members 12a and 22a of the transparent conductive layers 12 and 22 are arranged orthogonal to each other. The transparent conductive layers 12 and 22 are connected to an external drive circuit (not illustrated) via a routing circuit (not illustrated) made bf conductive ink, etc. The pattern shapes of the transparent conductive films 12 and 22 are not limited to those described in this embodiment, and any shapes are possible as long as the finger contact area, for example, can be detected. For example, as shown in Figs. 4 and 5, the transparent conductive films 12 and 22 may be configured to include a plurality of linearly connected, diamond-shaped conductive members 12b and 22b, respectively. They may be arranged in such a manner that the direction in which the diamond-shaped conductive members 12b of the transparent conductive layer 12 are connected is orthogonal to the direction in which the diamond-shaped conductive members 22b of the transparent conductive layer 22 are connected, and also that, in plane view, upper and lower diamond-shaped conductive members 12b/22b do not overlap each other. Regarding the operation performance, such as resolution, of the transparent touch switch 101, when the first transparent planar body 1 and the second transparent planar body 2 are put together, if there is a smaller area that has no conductive member, then such a configuration achieves higher performance. From this point of view, with respect to the pattern shapes of the transparent conductive layers 12 and 22, the configuration having a plurality of linearly connected, diamond-shaped conductive members 12b and 22b is preferred to a configuration having rectangular pattern
shapes .
[0025]
The transparent conductive layers 12 and 22 can be patterned as follows. A mask portion having a desired pattern shape is formed on the surface of each of the transparent conductive films 12 and 22 formed on a silicon-containing layer and a transparent substrate, respectively, and exposed portions are removed by etching with an acid liquid or the like. The mask portion is then dissolved by an alkaline liquid, etc.
[0026]
The adhesive layer 13 may be made of an ordinary transparent adhesive, such an epoxy-based or acrylic adhesive, and may include a core material formed of a transparent film of a norbornene resin. The adhesive layer may be formed by stacking several sheets of an adhesive material or by stacking sheets of several kinds of adhesive materials . The thickness of the adhesive layer 13 is not limited. In practical application, the thickness is preferably 100 μπι or less, and particularly preferably 25 to 75 μιη. The adhesive layer preferably has an optical refractive index of 1.40 to 1.70, andmore preferably 1.46 to 1.57. As-the refractive index of the adhesive layer approaches the refractive index of the transparent conductive layer (increase) , the difference in refractive index at the interface decreases, resulting in improved effects in making the pattern shape inconspicuous . However, in order to increase the refractive index of the adhesive layer, it is neccessary to add particulates of a high-refractive-index material thereto, for example, and this causes a problem in that the transmittance as a transparent planar body decreases. Further, because the adhesive layer is in contact with the transparent conductive layer, the adhesive layer preferably contains no material that may damage the transparent conductive layer, such as acid.
[0027]
In the transparent touch switch 101 configured as above, the method for detecting the touch location is the same in known capacitive touch switches . When a finger or the like touches the first transparent planar body 1 at any position on its surface, the transparent conductive layers 12 and 22 are grounded through the capacitance of the human body at the touch location, and the value of current flowing through the transparent conductive layers 12 and 22 is detected, thereby calculating the coordinates of the touch location.
[0028]
As shown in the schematic cross-sectional view of the transparent planar body 1 in Fig. 6, with respect to the absolute value of the difference between
the reflectance of a pattern-forming region, where the transparent conductive layer 12 is formed, at each wavelength of reflection LI of light applied thereto through the silicon-containing layer 11 and the reflectance of a pattern-non-forming region, where the transparent conductive layer 12 is not formed, at each wavelength of reflection L2 of light applied thereto through the silicon-containing layer 11, it is preferable that the difference between the maximum' and minimum of the absolute value is 0.65 or less, more preferably 0.5 or less, and still more preferably 0.4 or less, at a wavelength in the visible range, 450 nm to 700 nm. When the difference between the maximum and the minimum is 0.65 or less, the pattern shape of the transparent conductive layer 12 can be made inconspicuous, thereby improving visibility.
[0029]
The present inventors produced samples of transparent planar bodies configured as above. With respect to the absolute value of the difference between the reflectance of a pattern-forming region, where the transparent conductive layer 12 was formed, at each wavelength of reflection LI of light applied thereto through the silicon-containing layer 11 and the reflectance of a pattern-non-forming region, where the transparent conductive layer 12 was not formed, at each wavelength of reflection L2 of light applied thereto through the silicon-containing layer 11, the difference between the maximum and the minimum of the absolute value was measured. The maximum of the reflectance difference was also measured. At the same time, sensory testing was performed to determine whether the pattern shape of the transparent conductive layer 12 was conspicuous. The samples have a structure as shown in Fig. 6. The high-refractive-index layer 112 and the low-refractive-index layer 111 forming the silicon-containing layer 11 were formed of a soda glass plate and a Si02 thin film, respectively. An ITO film was employed as the transparent conductive layer 12, and a film made of an acrylic pressure sensitive adhesive (refractive index: 1.52) was employed as the adhesive layer 13. The samples were thus configured. Five kinds of samples were prepared, varying the thickness of the transparent conductive layer 12 (ITO film) (8 nm, 10 nm, 12 nm, 14 nm, 16 nm) . In each of the samples, the thickness of the high-refractive-index layer 112 (glass plate) was 1.1 mm, the thickness of the low-refractive-index layer 111 (Si02 thin film) was 12.5 nm, and the thickness of the adhesive layer 13 was 25 μτη. The low-refractive-index layer 111 (Si02 thin film) and the transparent conductive layer 12 (ITO film) were deposited by sputtering on the glass plate.
[0030]
These five kinds of samples were each measured for the spectral
reflectance (first spectral reflectance) of a pattern-forming region, where the transparent conductive layer 12 was formed, at each wavelength of reflection of light applied thereto through the silicon-containing layer 11 and the spectral reflectance (second spectral reflectance) of a pattern-non-forming region, where the transparent conductive layer 12 was not formed, at each wavelength of reflection of light applied thereto through the silicon-containing layer 11. Fig. 7 shows the relation between the absolute value of the difference between the obtained first spectral reflectance and second spectral reflectance and wavelength. Fig. 7 shows the results of measurement at wavelengths within the visible range of light, 450 nm to 700 run. For the measurement of spectral reflectance, an apparatus manufactured by JASCO (V670+ integrating sphere unit) was used. The measurement conditions were as follows: photometry mode: %R, measurement range: 800 to 300 nm, data collection interval: 5 nm, UV/Vis bandwidth: 5.0 nm, NIR bandwidth: 2.0 nm, response: Medium, scattering rate: 400 nm/min, light source switching: 340 nm, diffraction grating switching: 850 nm, light source: D2/WI, filter switching: step, correction: baseline.
[0031]
The maximum and minimum of the absolute value of the difference between the above-obtained first spectral reflectance and second spectral reflectance were calculated. The difference between the maximum and the minimum was also calculated. Table 1 shows the difference between the maximum and the minimum (reflectance difference Δ) , as well as the maximum of the reflectance difference, obtained by calculation. The surface resistance (Rs) of each sample is also shown in Table 1. Surface resistance (Rs) was measured using a resistivity meter Loresta EP MCP-T360 manufactured by MITSUBISHI CHEMICAL ANALYTECH. Table 1 also shows the results of sensory testing for each sample about the conspicuousness of the pattern shape. The test was performed under an ordinary fluorescent lamp in a room and under a three-band fluorescent lamp in a booth covered with a black sheet .
Table 1
Fair: Pattern shape is hardly recognizable under an ordinary fluorescent lamp, but is recognizable under a three-band fluorescent lamp
Poor: Pattern shape confirmation is recognizable even under an ordinary fluorescent lamp
[0032]
The results in Table 1 show that when the thickness of the transparent conductive layer 12 (ITO film) is 8 nm, 10 nm, or 12 nm, the pattern shape of the transparent conductive layer 12 (ITO film) is barely noticeable, achieving excellent visibility . Fig.7 shows that in such cases, at a wavelength in the visible range, 450 nm to 700 nm, the difference (reflectance difference Δ) between the maximum and minimum of the absolute value of the difference between the first spectral reflectance and the second spectral reflectance is 0.5 or less, and the absolute value of the difference between the first spectral reflectance and the second spectral reflectance is 0.7 or less. Further, even when the thickness of the transparent conductive layer 12 (ITO film) is 14 nm, although the pattern shape is recognizable under severe evaluation conditions, i.e., under a three-band fluorescent lamp, the pattern shape is barely visible under an ordinary fluorescent lamp. This shows that when the reflectance difference Δ is 0.65 or less, and the absolute value of the difference between the first spectral reflectance and the second spectral reflectance is 0.8 or less, practically usable visibility is achieved. The results also show that in the case where the thickness of the ITO film is 16 nm, where the reflectance difference Δ is more than 0.65 and the absolute value of the difference between the first spectral reflectance and the second spectral reflectance is more than 0.8, poor visibility is resulted. In Table 1, the surface resistance (Rs) increases with a decrease in the thickness of the transparent conductive layer 12 (ITO film) . However, when the thickness is less than 8 nm, the surface resistance exceeds 500 Ω/sq, and this may cause a decrease in the sensing accuracy of the touch switch. Therefore, the thickness of the transparent conductive layer 12 (ITO film) is particularly preferably 8 nm or more.
[0033]
The present inventors simulated a transparent planar body configured as above. The model used in the simulation has a structure as shown in Fig. 6, and the settings for the simulation were as follows. The silicon-containing layer 11 was formed to include a low-refractive-index layer 111 made of Si02 (optical refractive index: 1.46) and a high-refractive-index layer 112 made of soda glass
(optical refractive index: 1.52) . The transparent conductive layer 12 was an ITO film (optical refractive index: 2.0) . The adhesive layer 13 was made of an acrylic pressure sensitive adhesive (optical refractive index: 1.52).
[0034]
In the transparent planar body 11 having such settings, the thickness of the transparent conductive layer 12 (ITO film) and the thickness of the low-refractive-index layer 111 of the silicon-containing layer 11 were each varied, and the difference in light reflectance (%) between the part in which the transparent conductive layer 12 was formed (pattern-forming region) and the part in which the transparent conductive layer 12 was not formed (pattern-non-forming region) was determined by the simulation. The reflectance was calculated using a thin-film designing software (OPTAS-FILM) manufactured by CYBERNET SYSTEMS . As compared with the low-refractive-index layer 111 of the silicon-containing layer 11 and the transparent conductive layer 12, which have nano-scale thickness, the high-refractive-index layer 112 of the silicon-containing layer 11 and the adhesive layer 13 are members of much greater thickness; in this simulation, reflectance was calculated assuming the thickness of such a member as ∞ (infinite) .
[0035]
The inconspicuousness of the pattern shape of a transparent conductive layer 12 is correlated to the difference in reflectance between the part in which the transparent conductive film 12 is formed and the part in which it is not formed. The smaller the absolute value of the reflectance difference in the entire visible region (wavelength: 450 to 700 nm) , the less conspicuous the pattern shape and the better the visibility. When the maximum of the reflectance difference is 0.8 or less, good visibility can be achieved. A maximum of 0.7 or less provides better visibility, and a maximum of 0.5 or less provides even better visibility. Further, when the difference between the maximum and minimum of the absolute value of the reflectance difference is 0.65 or less at a wavelength in the visible range, 450 nm to 700 nm, the pattern shape of the transparent conductive layer is even less conspicuous, resulting in even better visibility.
[0036]
The following explains the simulation results. Fig. 8 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 8 nm, and the thickness of the low-refractive-index layer 111 (Si02 film) of the silicon-containing layer 11' was varied (0 nm, 10 nm, 20 nm, 30 nm) . Fig. 9 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 10 nm, and the thickness of the
low-refractive-index layer 111 (Si02 film) of the silicon-containing layer 11 was varied (0 nm, 10 nm, 20 rati, 30 nm) . Fig. 10 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 12 nm, and the thickness of the low-refractive-index layer 111 (Si02 film) of the silicon-containing layer 11 was varied (0 nm, 10 nm, 20 nm, 30 nm) . Fig. 11 shows the results of simulation where the thickness of the transparent conductive layer 12 (ITO film) was 14 nm, and the thickness of the low-refractive-index layer 111 (Si02 film) of the silicon-containing layer 11 was varied (0 nm, 10 nm, 20 nm, 30 nm) .
[0037]
Table 2 shows the difference between the maximum and minimum of the reflectance difference at a wavelength in the visible range, 450 nm to 700 nm, which was derived from the simulation results shown in Figs. 8 to 11. In the simulation results shown in Figs. 8 to 11, the maximum of the reflectance difference is the value of reflectance difference at a wavelength of 450 nm, while the minimum of the reflectance difference is the value of reflectance difference at a wavelength of 700 nm.
Table 2
;0038]
Table 3 shows the derived maximum of the reflectance difference at a wavelength in the visible range, 450 nm to 700 nm.
Table 3
[0039]
As shown in Figs. 8 to 11 and Table 2, when the thickness of the transparent conductive layer 12 (ITO film) was 12 nm or less, the difference between
the maximum and minimum of the reflectance difference was 0.65 or less. As shown in Figs. 8 to 11 and Table 3, when the thickness of the transparent conductive layer 12 (ITO film) was 12 nm or less, the maximum of the reflectance difference was 0.8 or less. These simulation results are accepted as consistent with the measurement values obtained above from the samples .
[0040]
Further, the results in Figs. 8 to 11 and Tables 2 and 3 show that in the case where the thickness of the transparent conductive layer 12 (ITO film) is 14 nm, when the thickness of the low-refractive-index layer 111 (Si02 film) is within a range of 0 to 30 nm, the difference between the maximum and minimum of the reflectance difference is 0.65 or less. The results also show that when the thickness of the low-refractive-index layer 111 (Si02 film) is 10 nm, 20 nm, or 30 nm, the maximum of the reflectance difference is 0.8 or less, while when the thickness of the low-refractive-index layer 111 (Si02 film) is 0 nm, the maximum of the reflectance difference is more than 0.8.
[0041]
Next, the thickness of the low-refractive-index layer 111 (Si02 film) was further varied, and the maximum thickness of the low-refractive-index layer 111 (Si02 film) that' allowed the difference between the maximum and minimum of the reflectance difference to be 0.65 or less was calculated by the above simulation. The results are shown in Table 4. Table 4 shows the derived difference between the maximum and minimum of the reflectance difference at a wavelength in the visible range, 450 nm to 700 nm. With an increase in the thickness of the low-refractive-index layer 111 (Si02 film) , the difference between the maximum and minimum of the reflectance difference changes from a downward trend to an upward trend. Therefore, the calculation of the difference between the maximum and minimum of the reflectance difference is partially omitted.
Table 4
55 - - 0.529 0.587 - -
60 - - 0.59 0.644 - -
65 - 0.47 0.653 - - -
70 - 0.52 0.714 - - -
75 - 0.571 - - - -
80 - 0.615 - - - -
85 - 0.651 - - - -
90 0.489 0.680 - - - -
95 0.504 - - - - -
100 0.511 - - - - -
[0042]
Table 4 shows that the maximum thickness of the low-refractive-index layer 111 (Si02 film) that allows the difference between the maximum and minimum of the reflectance difference to be 0.65 or less is about 85 nm when the thickness of the transparent conductive layer 12 (ITO film) is 10 nm, while it is about 65 nm when the thickness of the transparent conductive layer 12 (ITO film) is 12 nm. It is also shown that the maximum thickness is 60 nm when the thickness of the transparent conductive layer 12 (ITO film) is 13 nm, while it is 50 nm when the thickness of the transparent conductive layer 12 (ITO film) is 14 nm.
[0043]
Fig. 12 shows the' relation between the maximum thickness of a low-refractive-index layer 111 (Si02 film) that allows the difference between the maximum and minimum of the reflectance difference to be 0.65 or less and the thickness of the transparent conductive layer 12 (ITO film) , plotting the maximum thickness on the ordinate and the thickness of the transparent conductive layer 12 (ITO film) on the abscissa. Fig. 12 also shows approximate curves obtained from the relation between the maximum thickness and the thickness of the transparent conductive layer 12 (ITO film) . Taking the thickness of the transparent conductive layer 12 (ITO film) as X[nm] and the maximum thickness of the low-refractive-index layer 111 (Si02 film) as Yl[nm], such an approximate curve is represented by the following equation:
Equation 1: Yl = 0.3409X2 - 16.705X + 217.73.
Fig. 12 also shows the relation between the maximum thickness of a low-refractive-index layer 111 (Si02 film) that allows the difference between the maximum and minimum of the reflectance difference to be 0.5 or less and the thickness of the transparent conductive layer 12 (ITO film), as well as approximate curves
obtained from the relation.
[0044]
As shown above, when the thickness of the low-refractive-index layer 111 is not greater than the value calculated by the equation 1, the difference between the maximum and minimum of the difference in reflectance at each wavelength between the part in which the transparent conductive layer 12 is formed (pattern-forming region) and the part in which the transparent conductive layer 12 is not formed (pattern-non-forming region) can be 0.65 or less. Therefore, in a transparent touch switch 101 configured as shown in Fig. 1, in relation with the thickness of a transparent conductive layer 12, by forming a low-refractive-index layer 111 to have a thickness not greater than the value calculated by the equation 1, the transparent touch switch 101 can be provided with excellent visibility, where the pattern shape of the transparent conductive layer 12 is inconspicuous.
[0045]
The maximum thickness of a low-refractive-index layer 111 (Si02 film) that allowed the maximum of the reflectance difference at a wavelength in the visible range, 450 nm to 700 nm, to be 0.8 or less was also calculated by the simulation. The results are shown in Table 5. With an increase in the thickness of the low-refractive-index layer 111 (Si02 film) , the maximum of the reflectance difference changes from a downward trend to an upward trend. Therefore, the calculation of the maximum of the reflectance difference is partially omitted. Table 5
75 - 0.651 - - - -
80 - 0.711 - - - -
85 - 0.765 - - - -
90 0.552 0.814 - - - -
95 0.585 - - - - -
100 0.611 - - - - -
Table 5 shows that the maximum -thickness of the low-refractive-index layer 111 (Si02 film) that allows the maximum of the reflectance difference to be 0.8 or less is 85 nm when the thickness of the transparent conductive layer 12 (ITO film) is 10 nm, while it is 65 nm when the thickness of the transparent conductive layer 12 (ITO film) is 12 nm. It is also shown that in the case where the thickness of the transparent conductive layer 12 (ITO film) is 8 nm, even when the maximum thickness is 100 nm, the maximum of the reflectance difference is 0.8 or less. It is also shown that when the thickness of the transparent conductive layer 12 (ITO film) is 14 nm, the maximum thickness of the low-refractive-index layer 111 (Si02 film) that allows the maximum of the reflectance difference to be 0.8 or less is 45 nm.
[0047]
Fig. 13 shows the relation between the maximum thickness of a low-refractive-index layer 111 (Si02 film) that allows the maximum of the reflectance difference to be 0.8 or less and the thickness of the transparent conductive layer 12 (ITO film), plotting the maximum thickness on the ordinate' and the thickness of the transparent conductive layer 12 (ITO film) on the abscissa. Fig. 13 also shows approximate lines obtained from the relation between the maximum thickness and the thickness of the transparent conductive layer 12 (ITO film) . Taking the thickness of the transparent conductive layer 12 (ITO film) as X[nm] and the maximum thickness of the low-refractive-index layer 111 (Si02 film) as Y2 [nm] , such an approximate line is represented by the following equation:
Equation 2 : Y2 = -10X + 185.
When the thickness of the low-refractive-index layer 111 (Si02 film) is not greater than the value calculated by the equation, the maximum of the reflectance difference will be 0.8 or less (however, when the thickness of the transparent conductive layer 12 (ITO film) is 12 nm to 14 nm, the cases where the thickness of the low-refractive-index layer 111 (Si02 film) is less than 10 nm are excluded) . Fig. 13 also shows the relation between the maximum thickness of a low-refractive-index
layer 111 (Si02 film) that allows the maximum of the reflectance difference to be 0.7 or less and the thickness of the transparent conductive layer 12 (ITO film), as well as approximate lines obtained from the relation.
[0048]
As shown above, when the thickness of the low-refractive-index layer 111 is not greater the value calculated by the equation 2, the maximum of the difference in reflectance at each wavelength between the part where the transparent conductive layer 12 is formed (pattern-forming region) and the part where the transparent conductive layer 12 is not formed (pattern-non-forming region)' can be 0.8 or less. Therefore, in a transparent touch switch 101 configured as shown in Fig. 1, in relation with the thickness of a transparent conductive layer 12, by forming a low-refractive-index layer 111 to have a thickness not greater than the value calculated by the equation 2,. the transparent touch switch 101 can be provided with excellent visibility, where the pattern shape of the transparent conductive layer 12 is inconspicuous.
[0049]
Embodiments of the transparent planar body 1 and the transparent touch switch 101 using the same according the invention have been described above; however, the specific configurations are not limited to the above embodiments. For example, although the patterned transparent conductive layer 22 is formed on one side of the transparent substrate 21 to form the second transparent planar body 2 in the above embodiments, it is also possible to use a silicon-containing layer 11 in place of the transparent substrate 21, and provide the second transparent planar body 2 with the same configuration as the first transparent planar body 1.
[0050]
In addition, although the silicon-containing layer 11 includes the low-refractive-index layer 111 and the high-refractive-index layer 112 in the above embodiments, the silicon-containing layer 11 may be formed only of a high-refractive-index layer 112. With reference to the simulation results shown in Figs. 8 to 11, even when the silicon-containing layer 11 is formed only of a high-refractive-index layer 112 (even when the thickness of the low-refractive-index layer 111 made of Si02 is 0 nm) , at a wavelength in the visible range, 450 nm to 700 nm, the difference between the maximum and minimum of the difference in reflectance at each wavelength between the part in which the -transparent conductive layer 12 is formed (pattern-forming region) and the part in which the transparent conductive layer 12 is not formed (pattern-non-forming region) can be 0.65 or less. Accordingly, a transparent planar body 1 and a
transparent touch switch 101 with excellent visibility, where the pattern of the transparent conductive layer 12 is inconspicuous, can be obtained.
Explanation of Reference Numerals
[0051]
101 Transparent touch switch
1 First transparent planar body
2 Second transparent planar body
11 Silicon-containing layer
111. Low-refractive-index layer
112 High-refractive-index layer
12 Transparent conductive layer
13 Adhesive layer
21 Transparent substrate
22 Transparent conductive layer
Claims
1. A transparent planar body comprising
a silicon-containing layer;
an adhesive layer disposed on at least one side of the silicon-containing layer; and
a patterned transparent conductive layer disposed between the silicon-containing layer and the adhesive layer,
with respect. to an absolute value of the difference between the reflectance of a pattern-forming region, where the transparent conductive layer is formed, at each wavelength of light applied thereto through the silicon-containing layer and the reflectance of a pattern-non-forming region, where the transparent conductive layer is not formed, at each wavelength of light applied thereto through the silicon-containing layer, the difference between the maximum and minimum of the absolute value being 0.65 or less at 450 nm to 700 nm.
2. A transparent planar body according to claim 1, wherein the maximum is 0.8 or less.
3. A transparent planar body according to claim 1 or' 2, wherein
the silicon-containing layer includes a low-refractive-index layer and a high-refractive-index layer having a higher optical refractive index than the low-refractive-index layer, and
the transparent conductive layer is formed on the low-refractive-index-layer side of the silicon-containing layer.
4. A transparent planar body according to claim 3, wherein
- the low-refractive-index layer has an optical refractive index of 1.45 to 1.47, and
the high-refractive-index layer has an optical refractive index of more than 1.47 and not more than 1.53.
5. A transparent planar body according to claim 3 or 4, wherein
the low-refractive-index layer is made of Si02,- and the high-refractive-index layer is made of a glass material.
6. A transparent planar body according to any one of claims 1 to 5, wherein the transparent conductive layer has a thickness of 12 nm or less.
7. A transparent planar body according to any one of claims 1 to 5, wherein the transparent conductive layer has a thickness of 12 nm or more and 14nm or less, and
the low-refractive-index layer has a thickness of 10 nm to 45 nm.
8. A transparent planar body according to any one of claims 3 to 7 , wherein the thickness of the low-refractive-index layer is not greater than a value calculated by the following equation 1:
Equation 1: 0.3409X2 - 16.705X + 217.73
wherein X represents the thickness of the transparent conductive layer.
9. A transparent planar body according to claim 8, wherein the thickness of the low-refractive-index layer is not greater than a value calculated by the following equation 2 :
Equation 2: -10X + 185
wherein X represents the thickness of the transparent conductive layer.
10. A transparent touch switch comprising at least one transparent planar body of any one of claims- 1 to 9, the transparent planar body being arranged in such a manner that the transparent conductive layer of the transparent planar body and a second transparent conductive layer that is different from the transparent conductive layer of the transparent planar body face each other or face the same direction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012524982A JP5131628B1 (en) | 2010-02-03 | 2011-01-31 | Transparent sheet and transparent touch switch |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010-022006 | 2010-02-03 | ||
| JP2010022006 | 2010-02-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011096580A1 true WO2011096580A1 (en) | 2011-08-11 |
Family
ID=44355572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2011/052669 Ceased WO2011096580A1 (en) | 2010-02-03 | 2011-01-31 | Transparent planar body and transparent touch switch |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5131628B1 (en) |
| TW (1) | TW201133514A (en) |
| WO (1) | WO2011096580A1 (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013069033A (en) * | 2011-09-21 | 2013-04-18 | Toppan Printing Co Ltd | Transparent conductive laminate and manufacturing method therefor |
| CN103135869A (en) * | 2011-11-25 | 2013-06-05 | 日东电工株式会社 | Touch panel sensor |
| WO2013100031A1 (en) * | 2011-12-27 | 2013-07-04 | 積水化学工業株式会社 | Light transmissive conductive film and capacitance-type touch panel using same |
| US9018536B2 (en) | 2011-03-22 | 2015-04-28 | Polyic Gmbh & Co. Kg | Layered body, production method and use thereof |
| WO2015191232A1 (en) * | 2014-06-11 | 2015-12-17 | Carestream Health, Inc. | Method of producing a revealable invisible pattern in a transparent conductive film |
| CN104011806B (en) * | 2011-12-27 | 2016-11-30 | 积水化学工业株式会社 | Light-transmitting conductive film and capacitive touch panel with light-transmitting conductive film |
| EP3183395A4 (en) * | 2015-03-16 | 2018-11-21 | DIRTT Environmental Solutions, Ltd. | Glass panel reconfigurable wall panels |
| US11085184B2 (en) | 2014-02-20 | 2021-08-10 | Dirtt Environmental Solutions Ltd. | Interface for mounting interchangable components |
| US11093087B2 (en) | 2016-06-10 | 2021-08-17 | Dirtt Environmental Solutions Ltd. | Glass substrates with touchscreen technology |
| US11240922B2 (en) | 2016-06-10 | 2022-02-01 | Dirtt Environmental Solutions Ltd. | Wall system with electronic device mounting assembly |
| US11550178B2 (en) | 2016-07-08 | 2023-01-10 | Dirtt Environmental Solutions Inc. | Low-voltage smart glass |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5630774B1 (en) * | 2013-06-05 | 2014-11-26 | グンゼ株式会社 | Transparent sheet and transparent touch panel |
| JP5683734B1 (en) * | 2014-07-01 | 2015-03-11 | グンゼ株式会社 | Transparent conductive laminate, touch panel, and method for producing transparent conductive laminate |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008137190A (en) * | 2006-11-30 | 2008-06-19 | Jsr Corp | Anti-reflection laminate |
| JP2008268569A (en) * | 2007-04-20 | 2008-11-06 | Innovation & Infinity Global Corp | Low resistance light-attenuating antireflection film having a transparent conductive surface layer |
| JP2009076432A (en) * | 2007-01-18 | 2009-04-09 | Nitto Denko Corp | Transparent conductive film, method for producing the same, and touch panel provided with the same |
| JP2009259203A (en) * | 2008-03-25 | 2009-11-05 | Epson Imaging Devices Corp | Capacitive input device, display device with input function, and electronic apparatus |
-
2011
- 2011-01-31 JP JP2012524982A patent/JP5131628B1/en not_active Expired - Fee Related
- 2011-01-31 WO PCT/JP2011/052669 patent/WO2011096580A1/en not_active Ceased
- 2011-02-01 TW TW100103947A patent/TW201133514A/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008137190A (en) * | 2006-11-30 | 2008-06-19 | Jsr Corp | Anti-reflection laminate |
| JP2009076432A (en) * | 2007-01-18 | 2009-04-09 | Nitto Denko Corp | Transparent conductive film, method for producing the same, and touch panel provided with the same |
| JP2008268569A (en) * | 2007-04-20 | 2008-11-06 | Innovation & Infinity Global Corp | Low resistance light-attenuating antireflection film having a transparent conductive surface layer |
| JP2009259203A (en) * | 2008-03-25 | 2009-11-05 | Epson Imaging Devices Corp | Capacitive input device, display device with input function, and electronic apparatus |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9018536B2 (en) | 2011-03-22 | 2015-04-28 | Polyic Gmbh & Co. Kg | Layered body, production method and use thereof |
| JP2013069033A (en) * | 2011-09-21 | 2013-04-18 | Toppan Printing Co Ltd | Transparent conductive laminate and manufacturing method therefor |
| CN103135869A (en) * | 2011-11-25 | 2013-06-05 | 日东电工株式会社 | Touch panel sensor |
| JP2013114344A (en) * | 2011-11-25 | 2013-06-10 | Nitto Denko Corp | Touch panel sensor |
| US8742772B2 (en) | 2011-11-25 | 2014-06-03 | Nitto Denko Corporation | Touch panel sensor |
| WO2013100031A1 (en) * | 2011-12-27 | 2013-07-04 | 積水化学工業株式会社 | Light transmissive conductive film and capacitance-type touch panel using same |
| CN104011806A (en) * | 2011-12-27 | 2014-08-27 | 积水化学工业株式会社 | Light-transmitting conductive film and capacitive touch panel with light-transmitting conductive film |
| CN104011806B (en) * | 2011-12-27 | 2016-11-30 | 积水化学工业株式会社 | Light-transmitting conductive film and capacitive touch panel with light-transmitting conductive film |
| US11085184B2 (en) | 2014-02-20 | 2021-08-10 | Dirtt Environmental Solutions Ltd. | Interface for mounting interchangable components |
| WO2015191232A1 (en) * | 2014-06-11 | 2015-12-17 | Carestream Health, Inc. | Method of producing a revealable invisible pattern in a transparent conductive film |
| EP3183395A4 (en) * | 2015-03-16 | 2018-11-21 | DIRTT Environmental Solutions, Ltd. | Glass panel reconfigurable wall panels |
| US10400448B2 (en) | 2015-03-16 | 2019-09-03 | Dirtt Environmental Solutions, Ltd. | Reconfigurable wall panels |
| US11093087B2 (en) | 2016-06-10 | 2021-08-17 | Dirtt Environmental Solutions Ltd. | Glass substrates with touchscreen technology |
| US11240922B2 (en) | 2016-06-10 | 2022-02-01 | Dirtt Environmental Solutions Ltd. | Wall system with electronic device mounting assembly |
| US11550178B2 (en) | 2016-07-08 | 2023-01-10 | Dirtt Environmental Solutions Inc. | Low-voltage smart glass |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201133514A (en) | 2011-10-01 |
| JP2013513136A (en) | 2013-04-18 |
| JP5131628B1 (en) | 2013-01-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2011096580A1 (en) | Transparent planar body and transparent touch switch | |
| JP4874145B2 (en) | Transparent sheet and transparent touch switch | |
| US8603611B2 (en) | Transparent planar body and transparent touch switch | |
| US9941877B2 (en) | Electrode pattern of touch panel | |
| KR101839719B1 (en) | Touch panel sensor | |
| KR101092405B1 (en) | Touch panel sensor | |
| KR101879220B1 (en) | Transparent electrode pattern structure and touch screen panel having the same | |
| KR101676546B1 (en) | Touch panel sensor | |
| KR101765950B1 (en) | Touch panel | |
| KR20120134955A (en) | Touch panel having improved visibility and method for manufacturing the same | |
| JP2013214173A (en) | Capacitance-type film sensor, and sensor module and cover module using the same | |
| JP5305807B2 (en) | Transparent sheet and transparent touch switch | |
| KR102077548B1 (en) | Transparent electrode pattern structure and touch screen panel having the same | |
| JP2015118682A (en) | Touch panel | |
| CN104793778A (en) | Touch control device | |
| CN105468184B (en) | Transparent electrode laminate and touch screen panel including the same | |
| KR101373242B1 (en) | Touch panel sensor | |
| KR101926587B1 (en) | Touch panel | |
| JP6446209B2 (en) | Transparent electrode pattern laminate and touch screen panel provided with the same | |
| KR20130115692A (en) | Conductive pattern of touch panel | |
| KR101916306B1 (en) | Touch panel | |
| TWI623873B (en) | Transparent electrode layer board and touch screen panel containing the same | |
| KR20140079074A (en) | Touch panel with anti reflection film | |
| KR101370402B1 (en) | Fabrication method of electrode-pattern of touch panel and structure of electrode-pattern using the same | |
| KR20090101568A (en) | Two layer -electric capacity type touch screen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 11739927 Country of ref document: EP Kind code of ref document: A1 |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2012524982 Country of ref document: JP |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 11739927 Country of ref document: EP Kind code of ref document: A1 |




