WO2011087296A2 - Environmentally friendly diffusing agent including starch - Google Patents

Environmentally friendly diffusing agent including starch Download PDF

Info

Publication number
WO2011087296A2
WO2011087296A2 PCT/KR2011/000243 KR2011000243W WO2011087296A2 WO 2011087296 A2 WO2011087296 A2 WO 2011087296A2 KR 2011000243 W KR2011000243 W KR 2011000243W WO 2011087296 A2 WO2011087296 A2 WO 2011087296A2
Authority
WO
WIPO (PCT)
Prior art keywords
weight
parts
starch
environmentally friendly
oil
Prior art date
Application number
PCT/KR2011/000243
Other languages
French (fr)
Korean (ko)
Other versions
WO2011087296A3 (en
Inventor
유정민
Original Assignee
늘푸른주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=43512380&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2011087296(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 늘푸른주식회사 filed Critical 늘푸른주식회사
Publication of WO2011087296A2 publication Critical patent/WO2011087296A2/en
Publication of WO2011087296A3 publication Critical patent/WO2011087296A3/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof

Definitions

  • the present invention relates to a fume diffusion agent used for spray diffusion of insecticides, fungicides or herbicides.
  • the above object of the present invention 20 to 30 parts by weight of animal and vegetable refined oil; 10 to 30 parts by weight of starch hydrolyzate; And it is achieved by providing an environmentally friendly mist diffusion agent comprising 50 to 70 parts by weight of water.
  • the environment-friendly mist diffusion agent According to the environment-friendly mist diffusion agent according to the present invention, there is an excellent effect of not contaminating the environment at all due to biodegradation by using the plant and vegetable refined oil purified purified plant and animal waste oil, not mineral oil.
  • the environment-friendly mist diffusion agent according to the present invention, by using a starch hydrolyzate instead of a surfactant containing a large amount of glycerin to bring the surface active effect has an excellent effect that can be solved environmental problems or problems caused by glycerin have.
  • the environmentally friendly mist diffusion agent according to the present invention further comprises mineral powder
  • it is not only excellent in adsorption effect of pesticides, fungicides or herbicides to be added later, but also removes unpleasant odors by releasing large amounts of anions and far infrared rays from the mineral powder. It also has a beneficial effect on the human body.
  • Eco-friendly mist diffusion agent when spray diffusion by adding insecticides, fungicides or herbicides, so that there is no concern of environmental pollution, so that all problems due to odor can be solved, 20 to 30 weight Negative animal and vegetable refined oils; 10 to 30 parts by weight of starch hydrolyzate; And 50 to 70 parts by weight of water.
  • Eco-friendly mist diffusion agent instead of mineral oil that causes environmental pollution and unpleasant smell, vegetable oil (soybean oil, soybean oil, rice bran oil, corn oil, pine oil, palm oil, olive oil, tall oil, palm oil, etc.) Animal and vegetable oils (pig oil, beef tallow, fish oil, horse oil, etc.) are mixed with animal and vegetable oils in an amount of 20 to 30 parts by weight to be biodegraded when sprayed and diffused with pesticides, fungicides or herbicides. It is not left, and it is better in terms of the environment by recycling the used vegetable or animal oil, not the vegetable or animal oil itself.
  • starch is mixed and used in an amount of 10 to 30 parts by weight, and this starch is a polysaccharide which is made by long connection while numerous D-glucose (glucose) causes a condensation reaction. It is a mixture of amylose and amylopectin, and is divided into sweet potato starch, potato starch, wheat starch, corn starch (corn starch) and the like depending on the raw materials thereof.
  • starch hydrolyzate may be used as the starch.
  • the starch hydrolyzate can be formed by acid treatment or enzyme treatment of starch.
  • the acid treatment of the starch may be carried out by organic or inorganic acid treatment.
  • starch may be hydrolyzed by treating organic acids such as acetic acid, formic acid, citric acid, malic acid, or inorganic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, and the like.
  • the enzyme treatment of the starch may be carried out by one or more enzymes selected from the group consisting of, for example, alpha amylase, heat resistant alpha amylase, flulanase, isoamylase, glucoamylase and beta amylase. .
  • the starch can be hydrolyzed by the addition of 3 to 6 parts by weight of sulfuric acid and then mixed with the animal and vegetable refined oil and water.
  • glucose hydrolyzed from starch acts as a natural surfactant, and thus, in the case of the environmentally friendly mist diffusion agent according to the present invention, even if a chemical surfactant including glycerin is not used, animal and vegetable oils and water are emulsified. It can be mixed well, and even spray diffusion with the addition of pesticides, fungicides or herbicides will not generate any contaminants due to glycerin.
  • water is used in an amount of 50 to 70 parts by weight, which is used as a main component of the environmentally friendly mist diffusion agent according to the present invention, insecticides, fungicides or herbicides to be added later.
  • This serves as a solvent to be evenly mixed in the environment-friendly mist spreader according to the present invention.
  • a small amount of an organic solvent such as ethanol may be included as necessary.
  • the environmentally friendly mist diffusion agent according to the present invention may further comprise 8 to 24 parts by weight of mineral powder.
  • This mineral powder not only adsorbs insecticides, fungicides or herbicides to be added later, but also releases far infrared rays and anions, thereby neutralizing the unpleasant odor generated when spraying the environment-friendly mist diffusion agent according to the present invention, and at the same time, has a beneficial effect on the human body. can do.
  • the mineral powder may be 4 to 12 parts by weight of bentonite powder; 3 to 9 parts by weight of zeolite powder; And it may include 1 to 3 parts by weight of the cornerstone powder.
  • the mineral powder may be a powder of various particle sizes, but nanoparticles are preferably used.
  • Bentonite refers to clay containing mainly montmorillonite, a mineral belonging to a monoclinic system having a crystalline structure like mica.
  • Phosphorus mineral is a general term known to have excellent adsorption properties
  • the cornerstone is a mineral belonging to a tetragonal system having a crystal structure such as olivine, and acts as a fertilizer component to soil when spraying an environment-friendly mist diffusion agent according to the present invention.
  • These bentonites, zeolites, and cornerstones also have the property of emitting large amounts of far infrared rays and anions.
  • the starch hydrolyzate although no surfactant is required, depending on the embodiment, it may further comprise 0.5 to 2 parts by weight of the surfactant.
  • the content of animal and vegetable refined oil, starch, water, sulfuric acid, mineral powder, and surfactant was found to be selected in the range to obtain the optimum mist diffusion effect through various experiments of the applicant
  • the environmentally friendly mist diffusion agent according to the present invention described above is preferably agitated at a high speed of 1600 to 2000rpm in a stirrer at a temperature of 60 to 80 °C in the stirrer, spray diffusion through a hot-dry smoke screen device Do.
  • 25 parts by weight of purified soybean oil, 20 parts by weight of pre-hydrolyzed starch, 4 parts by weight of sulfuric acid, 60 parts by weight of water, 8 parts by weight of bentonite powder, 6 parts by weight of zeolite powder, 2 parts by weight of salt powder and 2 parts by weight of surfactant were added to the stirrer, and stirred at a high speed of 1800 rpm for 30 minutes at a temperature of 70 ° C. to prepare an environmentally friendly mist diffusion agent according to the present invention, and then applied to the surface of the vehicle through a hot-dry smoke screen device.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Toxicology (AREA)
  • Mycology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Disclosed is an environmentally-friendly diffusing agent that includes purified animal and vegetable oil instead of mineral oil, and starch instead of a surfactant containing a large amount of glycerin, to thereby prevent environmental pollution and the generation of offensive odors. The diffusing agent further includes mineral powder to improve the adsorption characteristics of insecticides, bactericides, and weed-killers. In addition, a large amount of anions and far infrared rays emitted by the mineral powder eliminate offensive odors and are beneficial to the human body.

Description

전분이 함유된 친환경 연무확산제Eco-friendly mist spreader containing starch
본 발명은 살충제, 살균제 또는 제초제 등을 분무 확산시키기 위해 사용하는 연무확산제에 관한 것이다.TECHNICAL FIELD The present invention relates to a fume diffusion agent used for spray diffusion of insecticides, fungicides or herbicides.
살충제, 살균제 또는 제초제 등을 첨가하여 사용하는 종래의 연무확산제에는 주로 등유, 경유 등과 같은 광물유가 주성분으로 함유됨에 따라, 인체, 가축의 우리, 목초, 농작물 등에 분무될 경우에 불쾌한 냄새가 발생함은 물론 분해가 용이하지 아니하여 환경을 오염시키는 문제점이 있었다.Conventional fume spreaders that use pesticides, fungicides, or herbicides contain mineral oils such as kerosene and diesel as their main components, resulting in unpleasant odors when sprayed onto humans, livestock, grasses and crops. Of course, there was a problem in that it is not easy to decompose to pollute the environment.
또한 물과의 혼합시 사용되는 계면활성제의 경우 글리세린이 다량 함유되어 있어, 분무확산시에 글리세린의 경화로 인해 얼룩이 묻어나는 문제점이 있을 뿐만 아니라 이로 인해 환경이 오염되는 문제점이 있었다.In addition, in the case of the surfactant used when mixing with water contains a large amount of glycerin, there is a problem that stains due to the curing of the glycerin during spray diffusion, as well as contaminating the environment due to this.
최근에는 광물유 대신에 바이오디젤을 사용하기도 하지만, 이 경우에도 바이오디젤 특유의 콩기름 냄새로 인해 그 사용이 기피되고 있는 실정이다.Recently, biodiesel is used instead of mineral oil, but even in this case, its use is avoided due to the unique smell of soybean oil.
본 발명의 목적은, 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산될 경우에 환경오염의 염려가 전혀 없고, 냄새로 인한 제반 문제점이 해소될 수 있도록 한 전분이 함유된 친환경 연무확산제를 제공하기 위한 것이다.It is an object of the present invention to provide an environment-friendly mist diffusion agent containing starch, which is free from concerns about environmental pollution when sprayed and diffused by adding insecticides, fungicides or herbicides, and all problems caused by odor. It is for.
전술한 본 발명의 목적은, 20 내지 30 중량부의 동식물성 정제유; 10 내지 30 중량부의 전분 가수분해물; 및 50 내지 70 중량부의 물을 포함하는 친환경 연무확산제를 제공함에 의해 달성된다.The above object of the present invention, 20 to 30 parts by weight of animal and vegetable refined oil; 10 to 30 parts by weight of starch hydrolyzate; And it is achieved by providing an environmentally friendly mist diffusion agent comprising 50 to 70 parts by weight of water.
본 발명에 따른 친환경 연무확산제에 의하면, 광물유가 아니라 동식물성 폐유를 정제한 동식물성 정제유를 사용함에 따라 생분해로 인해 환경을 전혀 오염시키지 않는 탁월한 효과가 있다.According to the environment-friendly mist diffusion agent according to the present invention, there is an excellent effect of not contaminating the environment at all due to biodegradation by using the plant and vegetable refined oil purified purified plant and animal waste oil, not mineral oil.
또한 본 발명에 따른 친환경 연무확산제에 의하면, 글리세린이 다량 포함된 계면활성제 대신에 전분 가수분해물을 이용하여 계면활성효과를 가져옴에 따라 글리세린으로 인한 환경오염이나 제반 문제점이 해소될 수 있는 탁월한 효과가 있다.In addition, according to the environment-friendly mist diffusion agent according to the present invention, by using a starch hydrolyzate instead of a surfactant containing a large amount of glycerin to bring the surface active effect has an excellent effect that can be solved environmental problems or problems caused by glycerin have.
뿐만 아니라 본 발명에 따른 친환경 연무확산제가 광물 분말을 추가로 포함하는 경우 추후 첨가될 살충제, 살균제 또는 제초제 등의 흡착효과가 우수할 뿐만 아니라 광물 분말로부터 음이온과 원적외선이 다량 방출됨으로 불쾌한 냄새가 제거되고 인체에도 유익한 효과가 있다.In addition, when the environmentally friendly mist diffusion agent according to the present invention further comprises mineral powder, it is not only excellent in adsorption effect of pesticides, fungicides or herbicides to be added later, but also removes unpleasant odors by releasing large amounts of anions and far infrared rays from the mineral powder. It also has a beneficial effect on the human body.
본 발명에 따른 친환경 연무확산제는, 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산될 경우에 환경오염의 염려가 전혀 없고, 냄새로 인한 제반 문제점이 해소될 수 있도록 하기 위한 것으로, 20 내지 30 중량부의 동식물성 정제유; 10 내지 30 중량부의 전분 가수분해물; 및 50 내지 70 중량부의 물을 포함한다.Eco-friendly mist diffusion agent according to the present invention, when spray diffusion by adding insecticides, fungicides or herbicides, so that there is no concern of environmental pollution, so that all problems due to odor can be solved, 20 to 30 weight Negative animal and vegetable refined oils; 10 to 30 parts by weight of starch hydrolyzate; And 50 to 70 parts by weight of water.
본 발명에 따른 친환경 연무확산제는, 환경오염과 불쾌한 냄새를 초래하는 광물유 대신에, 이미 사용한 식물성유(대두유, 체종유, 미강유, 옥수수유, 소나무유, 야자유, 올리브유, 톨유, 팜유 등)나 동물성유(돈유, 우지, 어유, 말향유 등를 정제한 동식물성 정제유를 20 내지 30 중량부의 양으로 혼합하여 사용함에 따라 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산될 경우에 생분해되어 환경오염물질을 남기지 않게 되며, 식물성유나 동물성유 그 자체가 아니라 이미 사용한 식물성유나 동물성유를 재활용함에 따라 환경적인 면에서 더욱 우수하다.Eco-friendly mist diffusion agent according to the present invention, instead of mineral oil that causes environmental pollution and unpleasant smell, vegetable oil (soybean oil, soybean oil, rice bran oil, corn oil, pine oil, palm oil, olive oil, tall oil, palm oil, etc.) Animal and vegetable oils (pig oil, beef tallow, fish oil, horse oil, etc.) are mixed with animal and vegetable oils in an amount of 20 to 30 parts by weight to be biodegraded when sprayed and diffused with pesticides, fungicides or herbicides. It is not left, and it is better in terms of the environment by recycling the used vegetable or animal oil, not the vegetable or animal oil itself.
또한 본 발명에 따른 친환경 연무확산제의 경우에는, 전분이 10 내지 30 중량부의 양으로 혼합되어 사용되는데, 이 전분은 수많은 D-글루코스(포도당)가 축합반응을 일으키면서 길게 연결되어 만들어지는 다당류로서 아밀로오스와 아밀로펙틴의 혼합물로서, 그 원료에 따라 고구마녹말·감자녹말·밀녹말·옥수수녹말(콘스타치) 등으로 나뉘어진다.In addition, in the case of the environmentally friendly mist diffusion agent according to the present invention, starch is mixed and used in an amount of 10 to 30 parts by weight, and this starch is a polysaccharide which is made by long connection while numerous D-glucose (glucose) causes a condensation reaction. It is a mixture of amylose and amylopectin, and is divided into sweet potato starch, potato starch, wheat starch, corn starch (corn starch) and the like depending on the raw materials thereof.
본 발명에 있어서, 상기 전분으로는 전분 가수분해물을 사용할 수 있다. 상기 전분 가수분해물은 전분을 산 처리 또는 효소 처리함으로써 형성할 수 있다. In the present invention, starch hydrolyzate may be used as the starch. The starch hydrolyzate can be formed by acid treatment or enzyme treatment of starch.
상기 전분의 산 처리는 유기산 또는 무기산 처리에 의해 수행될 수 있다. 예컨대, 아세트산, 포름산, 시트르산, 말산 등과 같은 유기산 또는 염산, 황산, 인산 등과 같은 무기산을 처리함으로써 전분을 가수분해할 수 있다. The acid treatment of the starch may be carried out by organic or inorganic acid treatment. For example, starch may be hydrolyzed by treating organic acids such as acetic acid, formic acid, citric acid, malic acid, or inorganic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, and the like.
또한 상기 전분의 효소 처리는 예를 들어, 알파아밀레이즈, 내열성 알파아밀레이즈, 플루라네이즈, 이소아밀레이즈, 글루코아밀레이즈 및 베타아밀레이즈로 이루어진 군으로부터 선택되는 하나 이상의 효소에 의해 수행될 수 있다.In addition, the enzyme treatment of the starch may be carried out by one or more enzymes selected from the group consisting of, for example, alpha amylase, heat resistant alpha amylase, flulanase, isoamylase, glucoamylase and beta amylase. .
본 발명의 한 구체예에서, 상기 전분은 3 내지 6 중량부의 황산의 첨가에 의해 가수분해된 후 상기 동식물성 정제유 및 물과 혼합될 수 있다. In one embodiment of the invention, the starch can be hydrolyzed by the addition of 3 to 6 parts by weight of sulfuric acid and then mixed with the animal and vegetable refined oil and water.
전분 가수분해물을 사용할 경우 전분으로부터 가수분해된 글루코스가 천연 계면활성제 역할을 함에 따라 본 발명에 따른 친환경 연무확산제의 경우에는 글리세린을 포함하는 화학적 계면활성제를 사용하지 않더라도 동식물성 정제유와 물이 유화되어 잘 혼합될 수 있게 되며, 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산되더라도 글리세린으로 인한 오염물질이 전혀 발생되지 않게 된다.When starch hydrolyzate is used, glucose hydrolyzed from starch acts as a natural surfactant, and thus, in the case of the environmentally friendly mist diffusion agent according to the present invention, even if a chemical surfactant including glycerin is not used, animal and vegetable oils and water are emulsified. It can be mixed well, and even spray diffusion with the addition of pesticides, fungicides or herbicides will not generate any contaminants due to glycerin.
또한 본 발명에 따른 친환경 연무확산제의 경우에는, 물이 50 내지 70 중량부의 양으로 혼합되어 사용되는데, 이 물은 본 발명에 따른 친환경 연무확산제의 주성분으로 추후 첨가될 살충제, 살균제 또는 제초제 등이 본 발명에 따른 친환경 연무확산제에 골고루 혼합될 수 있도록 하는 용매 역할을 한다. 이러한 용매로는 필요에 따라 에탄올과 같은 유기 용매를 소량 포함시킬 수 있다.In addition, in the case of an environmentally friendly mist diffusion agent according to the present invention, water is used in an amount of 50 to 70 parts by weight, which is used as a main component of the environmentally friendly mist diffusion agent according to the present invention, insecticides, fungicides or herbicides to be added later. This serves as a solvent to be evenly mixed in the environment-friendly mist spreader according to the present invention. As such a solvent, a small amount of an organic solvent such as ethanol may be included as necessary.
한 구체예에서, 본 발명에 따른 친환경 연무확산제는, 8 내지 24 중량부의 광물 분말을 추가로 포함할 수 있다. 이 광물 분말은 추후 첨가될 살충제, 살균제 또는 제초제 등을 흡착하는 것은 물론 원적외선과 음이온을 방출함에 따라 본 발명에 따른 친환경 연무확산제의 분무시 발생하는 불쾌한 냄새를 중화시킴과 동시에 인체에도 유익한 작용을 할 수 있다. 이에 제한되는 것은 아니나, 한 구체예에서, 상기 광물 분말은 4 내지 12 중량부의 벤토나이트 분말; 3 내지 9 중량부의 제올라이트 분말; 및 1 내지 3 중량부의 초석 분말을 포함할 수 있다. 상기 광물 분말은 다양한 입도의 분말이 사용될 수 있으나 나노 단위의 미립자가 사용되는 것이 바람직하다.In one embodiment, the environmentally friendly mist diffusion agent according to the present invention may further comprise 8 to 24 parts by weight of mineral powder. This mineral powder not only adsorbs insecticides, fungicides or herbicides to be added later, but also releases far infrared rays and anions, thereby neutralizing the unpleasant odor generated when spraying the environment-friendly mist diffusion agent according to the present invention, and at the same time, has a beneficial effect on the human body. can do. Although not limited thereto, in one embodiment, the mineral powder may be 4 to 12 parts by weight of bentonite powder; 3 to 9 parts by weight of zeolite powder; And it may include 1 to 3 parts by weight of the cornerstone powder. The mineral powder may be a powder of various particle sizes, but nanoparticles are preferably used.
벤토나이트는 운모와 같은 결정구조를 하는 단사정계에 속하는 광물인 몬모릴로나이트가 주로 들어있는 점토를 말하는 것으로, 양이온을 띈 천연미네랄이 다량 함유되어 높은 흡착성을 발휘하며, 제올라이트는 알칼리 및 알칼리토금속의 규산알루미늄 수화물인 광물을 총칭하는 말로 흡착성이 우수한 것으로 알려져 있으며, 초석은 감람석과 같은 결정구조를 가지는 사방정계에 속하는 광물로 본 발명에 따른 친환경 연무확산제의 분무시 토양에 대한 비료성분으로 작용한다. 이러한 벤토나이트, 제올라이트, 초석은 원적외선과 음이온을 다량 방출하는 특성도 가지고 있다.Bentonite refers to clay containing mainly montmorillonite, a mineral belonging to a monoclinic system having a crystalline structure like mica. Phosphorus mineral is a general term known to have excellent adsorption properties, and the cornerstone is a mineral belonging to a tetragonal system having a crystal structure such as olivine, and acts as a fertilizer component to soil when spraying an environment-friendly mist diffusion agent according to the present invention. These bentonites, zeolites, and cornerstones also have the property of emitting large amounts of far infrared rays and anions.
뿐만 아니라 본 발명에 따른 친환경 연무확산제의 경우에는, 전분 가수분해물의 사용으로 인해 계면활성제가 전혀 필요 없긴 하지만 실시예에 따라서는 0.5 내지 2 중량부의 계면활성제를 더 포함하여 이루어질 수도 있다.In addition, in the case of the environmentally friendly mist diffusion agent according to the present invention, due to the use of the starch hydrolyzate, although no surfactant is required, depending on the embodiment, it may further comprise 0.5 to 2 parts by weight of the surfactant.
전술한 본 발명에 따른 친환경 연무확산제에 있어서, 동식물성 정제유, 전분, 물, 황산, 광물 분말, 계면활성제의 함량은 출원인의 다양한 실험을 통해 최적의 연무확산효과를 가져오는 범위로 선택되었음을 밝혀두며, 전술한 본 발명에 따른 친환경 연무확산제는 각각의 조성성분들이 교반기 내에서 60 내지 80℃의 온도하에서 1600 내지 2000rpm으로 고속교반되는 것이 바람직하며, 열건식 연막장치를 통해 분무확산되는 것이 바람직하다.In the environmentally friendly mist diffusion agent according to the present invention described above, the content of animal and vegetable refined oil, starch, water, sulfuric acid, mineral powder, and surfactant was found to be selected in the range to obtain the optimum mist diffusion effect through various experiments of the applicant In addition, the environmentally friendly mist diffusion agent according to the present invention described above is preferably agitated at a high speed of 1600 to 2000rpm in a stirrer at a temperature of 60 to 80 ℃ in the stirrer, spray diffusion through a hot-dry smoke screen device Do.

[실시예] EXAMPLE
기 사용한 대두유를 정제한 정제 대두유 25 중량부와, 4 중량부의 황산 첨가를 통해 사전 가수분해된 전분 20 중량부와, 물 60 중량부와, 벤토나이트분말 8 중량부와, 제올라이트분말 6 중량부와, 초석분말 2 중량부와, 계면활성제 2중량부를 교반기에 투입하고, 70℃의 온도하에서 1800rpm으로 30분간 고속교반시켜 본 발명에 따른 친환경 연무확산제를 제조한 후 열건식 연막장치를 통해 자동차 표면에 분무확산시킨 결과, 5분 경과 후 본 발명에 따른 친환경 연무확산제의 흔적이 육안으로 약간 발견되기는 하였으나, 마른걸레로 훔친 결과 깨끗하게 제거되었고, 특이한 식물성 기름 냄새나 기타 불쾌한 냄새는 전혀 나지 않았으며, 연막기의 노즐 막힘 시험에서도 완전 연소로 인해 전혀 노즐 막힘이 없었음을 확인할 수 있었다.25 parts by weight of purified soybean oil, 20 parts by weight of pre-hydrolyzed starch, 4 parts by weight of sulfuric acid, 60 parts by weight of water, 8 parts by weight of bentonite powder, 6 parts by weight of zeolite powder, 2 parts by weight of salt powder and 2 parts by weight of surfactant were added to the stirrer, and stirred at a high speed of 1800 rpm for 30 minutes at a temperature of 70 ° C. to prepare an environmentally friendly mist diffusion agent according to the present invention, and then applied to the surface of the vehicle through a hot-dry smoke screen device. As a result of spray diffusion, after 5 minutes, traces of the environmentally friendly mist spreader according to the present invention were found with the naked eye, but it was removed cleanly by sterilization with a dry rag, and there was no unusual vegetable oil or other unpleasant odors. The nozzle clogging test of the smoke screen also confirmed that there was no nozzle clogging due to complete combustion.

Claims (5)

  1. 20 내지 30 중량부의 동식물성 정제유; 10 내지 30 중량부의 전분 가수분해물; 및 50 내지 70 중량부의 물을 포함하는 친환경 연무확산제.20 to 30 parts by weight of animal and vegetable refined oils; 10 to 30 parts by weight of starch hydrolyzate; And 50 to 70 parts by weight of water.
  2. 청구항 1에 있어서,
    상기 전분 가수분해물은 전분을 산 처리 또는 효소 처리함으로써 형성된 것인 친환경 연무확산제.    The method according to claim 1,
    The starch hydrolyzate is an environmentally friendly mist diffusion agent formed by acid treatment or enzyme treatment of starch.
  3. 청구항 1 또는 청구항 2에 있어서,
    상기 친환경 연무확산제는 8 내지 24 중량부의 광물 분말을 추가로 포함하는 것인 친환경 연무확산제.    The method according to claim 1 or 2,
    The environmentally friendly mist diffusion agent that further comprises 8 to 24 parts by weight of mineral powder.
  4. 청구항 3에 있어서,
    상기 광물 분말은 4 내지 12 중량부의 벤토나이트 분말; 3 내지 9 중량부의 제올라이트 분말; 및 1 내지 3 중량부의 초석 분말을 포함하는 것인 친환경 연무확산제.    The method according to claim 3,
    The mineral powder is 4 to 12 parts by weight of bentonite powder; 3 to 9 parts by weight of zeolite powder; And 1 to 3 parts by weight of the salt-free powder that comprises a salt-free powder.
  5. 청구항 3에 있어서,
    상기 친환경 연무확산제는 0.5 내지 2 중량부의 계면활성제를 추가로 포함하는 것인 친환경 연무확산제.    The method according to claim 3,
    The environmentally friendly mist diffusion agent that further comprises 0.5 to 2 parts by weight of surfactant.
PCT/KR2011/000243 2010-01-13 2011-01-13 Environmentally friendly diffusing agent including starch WO2011087296A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020100003140A KR100998469B1 (en) 2010-01-13 2010-01-13 Non-nuisance fog and cloud spread agent contained starch
KR10-2010-0003140 2010-01-13

Publications (2)

Publication Number Publication Date
WO2011087296A2 true WO2011087296A2 (en) 2011-07-21
WO2011087296A3 WO2011087296A3 (en) 2011-11-10

Family

ID=43512380

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2011/000243 WO2011087296A2 (en) 2010-01-13 2011-01-13 Environmentally friendly diffusing agent including starch

Country Status (2)

Country Link
KR (1) KR100998469B1 (en)
WO (1) WO2011087296A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101869197B1 (en) * 2017-06-19 2018-06-19 최명신 A vegetable smoke fogging agent for environment-friendly disease prevention method and a manufacturing method for the same
KR20200028557A (en) 2018-09-06 2020-03-17 주식회사 이노뷰텍 Eco-friendly mist fog and cloud spread agent with sterilization and insecticidal effect
KR20200137277A (en) 2019-05-29 2020-12-09 (주)공간파크 manufacturing method for spread agent
KR20210001430A (en) 2019-06-28 2021-01-06 (주)엠제이폴리텍 Dyd added eco-friendly smoke and fog dispersing agent

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010093489A (en) * 2000-03-29 2001-10-29 허원기 Fog lcquid spread agent
KR100347392B1 (en) * 1994-08-04 2002-11-09 상꾜 가부시키가이샤 Pesticide preparation
KR100675492B1 (en) * 1999-08-11 2007-02-05 다우 아그로사이언시즈 엘엘씨 Oil in water flowable pesticide formulation
KR20080003394A (en) * 2005-04-08 2008-01-07 니코메드 게엠베하 Device for dosing and dry nebulization
JP2008019226A (en) * 2006-07-14 2008-01-31 Earth Chem Corp Ltd Composition, spray product and method for controlling small flies
KR20090054547A (en) * 2007-11-27 2009-06-01 고려대학교 산학협력단 Crystal nano starch -alcohols complex, and preparing method of crystal nano starch particles using the same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100347392B1 (en) * 1994-08-04 2002-11-09 상꾜 가부시키가이샤 Pesticide preparation
KR100675492B1 (en) * 1999-08-11 2007-02-05 다우 아그로사이언시즈 엘엘씨 Oil in water flowable pesticide formulation
KR20010093489A (en) * 2000-03-29 2001-10-29 허원기 Fog lcquid spread agent
KR20080003394A (en) * 2005-04-08 2008-01-07 니코메드 게엠베하 Device for dosing and dry nebulization
JP2008019226A (en) * 2006-07-14 2008-01-31 Earth Chem Corp Ltd Composition, spray product and method for controlling small flies
KR20090054547A (en) * 2007-11-27 2009-06-01 고려대학교 산학협력단 Crystal nano starch -alcohols complex, and preparing method of crystal nano starch particles using the same

Also Published As

Publication number Publication date
WO2011087296A3 (en) 2011-11-10
KR100998469B1 (en) 2010-12-06

Similar Documents

Publication Publication Date Title
Pleanjai et al. Environmental evaluation of biodiesel production from palm oil in a life cycle perspective
CN107446585A (en) A kind of compound biological soil improver and preparation method thereof
KR101378577B1 (en) Liqiud film-forming compositions for mulching vinyl and manufacturing method thereof
WO2011087296A2 (en) Environmentally friendly diffusing agent including starch
CN104521768A (en) Low-density light-scented particulate cat litter and preparation method thereof
CN104396772A (en) Antibacterial health-care cat litter added with dandelion and other natural ingredients and preparation method thereof
CN104396768A (en) Antibacterial cat litter having health care effect on pets and preparation method of antibacterial cat litter
CN101265141A (en) Fertilizer synergist and its preparation method and application
CN103788955B (en) For the treatment of the cadmium fixing agent of contaminated soil and the treatment process of this soil
CN106242781A (en) A kind of preparation method of disease resistance vegetable seedling substrate
CN102358861A (en) Preparation method of biomass sludge regenerated fuel charcoal
CN104521766A (en) Health-care pet cat litter fully utilizing natural components, and preparation method thereof
KR100930653B1 (en) Fog and cloud spread agent without public nuisance
CN104521784A (en) Various-fiber-added highly-water-absorbent antibacterial cat litter used for pets and preparation method thereof
Gomes da Silva et al. Sustainable production cases
CN104396769A (en) Deodorant fragrant cat litter added with camphor and menthol and preparation method thereof
CN104521765A (en) Antibacterial breathable mixed cat litter with pumice, and preparation method thereof
Niazi et al. Biochar as a Fertilizer Replacement for Sustainable Agriculture
KR101779885B1 (en) A Method of producing deodorant and the liquid and solid deodorant prepared by the method
CN104521779A (en) Cat litter with added kelp and with modified straw charcoal as base layer, and preparation method thereof
Li et al. Exploration of converting food waste into value-added products via insect pretreatment-assisted hydrothermal catalysis
CN104521773A (en) Scented composite cat litter with added pelelith, and preparation method thereof
CN104396773B (en) A kind of house pet double-decker Novel cat litter and preparation method thereof
KR101429719B1 (en) Ecofriendly disinfection composition having excellent eliminating larva and spreading effect
CN104521782A (en) Lightweight mixed cat litter with fresh smell and preparation method thereof

Legal Events

Date Code Title Description
NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 11733083

Country of ref document: EP

Kind code of ref document: A2