KR100998469B1 - Non-nuisance fog and cloud spread agent contained starch - Google Patents
Non-nuisance fog and cloud spread agent contained starch Download PDFInfo
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Abstract
Description
본 발명은 연무 확산제에 관한 것으로, 더욱 상세하게는 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산시키는 연무확산제에 관한 것이다.The present invention relates to a fume diffusing agent, and more particularly to a fume diffusing agent to spray diffusion by adding insecticides, fungicides or herbicides.
살충제, 살균제 또는 제초제 등을 첨가하여 사용하는 종래의 연무확산제에는 주로 등유, 경유 등과 같은 광물유가 주성분으로 함유됨에 따라, 인체, 가축의 우리, 목초, 농작물 등에 분무될 경우에 불쾌한 냄새가 발생함은 물론 분해가 용이하지 아니하여 환경을 오염시키는 문제점이 있었다.Conventional fume spreaders that use pesticides, fungicides, or herbicides contain mineral oils such as kerosene and diesel as their main components, resulting in unpleasant odors when sprayed onto humans, livestock, grasses and crops. Of course, there was a problem in that it is not easy to decompose to pollute the environment.
또한 물과의 혼합시 사용되는 계면활성제의 경우 글리세린이 다량 함유되어 있어, 분무확산시에 글리세린의 경화로 인해 얼룩이 묻어나는 문제점이 있을 뿐만 아니라 이로 인해 환경이 오염되는 문제점이 있었다.In addition, in the case of the surfactant used when mixing with water contains a large amount of glycerin, there is a problem that stains due to the curing of the glycerin during spray diffusion, as well as contaminating the environment due to this.
최근에는 광물유 대신에 바이오디젤을 사용하기도 하지만, 이 경우에도 바이오디젤 특유의 콩기름 냄새로 인해 그 사용이 기피되고 있는 실정이다. Recently, biodiesel is used instead of mineral oil, but even in this case, its use is avoided due to the unique smell of soybean oil.
본 발명의 목적은, 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산될 경우에 환경오염의 염려가 전혀 없고, 냄새로 인한 제반 문제점이 해소될 수 있도록 한 전분이 함유된 친환경 연무확산제를 제공하기 위한 것이다.It is an object of the present invention to provide an environment-friendly mist diffusion agent containing starch, which is free from concerns about environmental pollution when sprayed and diffused by adding insecticides, fungicides or herbicides, and all problems caused by odor. It is for.
전술한 본 발명의 목적은, 20 내지 30 중량부의 동식물성 정제유와, 10 내지 30 중량부의 전분과, 50 내지 70 중량부의 물을 포함하여 이루어지는 전분이 함유된 친환경 연무확산제를 제공함에 의해 달성된다.The object of the present invention described above is achieved by providing an environment-friendly mist spreader containing 20 to 30 parts by weight of animal and vegetable refined oil, 10 to 30 parts by weight of starch and 50 to 70 parts by weight of water. .
본 발명의 바람직한 특징에 의하면, 상기 전분은 3 내지 6 중량부의 황산의 첨가에 의해 가수분해된 후 상기 동식물성 정제유와 상기 물과 혼합된다.According to a preferred feature of the invention, the starch is hydrolyzed by the addition of 3 to 6 parts by weight of sulfuric acid and then mixed with the animal and vegetable refined oil and the water.
본 발명의 더 바람직한 특징에 의하면, 8 내지 24 중량부의 광물분말을 더 포함하여 이루어지고, 상기 광물분말은 4 내지 12 중량부의 벤토나이트분말과, 3 내지 9 중량부의 제올라이트분말과, 1 내지 3 중량부의 초석분말로 이루어지16 내지 24 중량부의 광물분말을 더 포함하여 이루어진다.According to a further preferred feature of the invention, it further comprises 8 to 24 parts by weight of mineral powder, the mineral powder is 4 to 12 parts by weight of bentonite powder, 3 to 9 parts by weight of zeolite powder, 1 to 3 parts by weight Consisting of the salt powder is made of 16 to 24 parts by weight of mineral powder.
본 발명의 더욱 바람직한 특징에 의하면, 0.5 내지 2 중량부의 계면활성제를 더 포함하여 이루어진다.
According to a further preferred feature of the invention, it further comprises 0.5 to 2 parts by weight of the surfactant.
본 발명에 따른 전분이 함유된 친환경 연무확산제에 의하면, 광물유가 아니라 동식물성 폐유를 정제한 동식물성 정제유를 사용함에 따라 생분해로 인해 환경을 전혀 오염시키지 않는 탁월한 효과가 있다.According to the environment-friendly mist diffusion agent containing starch according to the present invention, there is an excellent effect of not contaminating the environment at all due to biodegradation by using animal and vegetable refined oil purified from animal and vegetable waste oil instead of mineral oil.
또한 본 발명에 따른 전분이 함유된 친환경 연무확산제에 의하면, 글리세린이 다량 포함된 계면활성제 대신에 전분의 가수분해를 통해 계면활성효과를 가져옴에 따라 글리세린으로 인한 환경오염이나 제반문제점이 해소될 수 있는 탁월한 효과가 있다.In addition, according to the environment-friendly mist diffusion agent containing starch according to the present invention, instead of the surfactant containing a large amount of glycerin, the surface active effect through the hydrolysis of starch can be solved environmental problems or problems caused by glycerin That has an excellent effect.
뿐만 아니라 본 발명에 따른 전분이 함유된 친환경 연무확산제에 의하면, 벤토나이트분말, 제올라이트분말 및 초석분말과 같은 광물분말이 더 포함됨에 따라 추후 첨가될 살충제, 살균제 또는 제초제 등의 흡착효과가 우수할 뿐만 아니라 광물분말로부터 음이온과 원적외선이 다량 방출됨으로 불쾌한 냄새가 제거되고 인체에도 유익한 효과가 있다.In addition, according to the environment-friendly mist diffusion agent containing starch according to the present invention, as the mineral powder, such as bentonite powder, zeolite powder and salt stone powder is further included, the adsorption effect of insecticide, fungicide or herbicide to be added later is excellent. In addition, the anion and far infrared rays are emitted from the mineral powder in a large amount to remove the unpleasant odor and have a beneficial effect on the human body.
본 발명에 따른 전분이 함유된 친환경 연무확산제는, 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산될 경우에 환경오염의 염려가 전혀 없고, 냄새로 인한 제반 문제점이 해소될 수 있도록 하기 위한 것으로, 20 내지 30 중량부의 동식물성 정제유와, 10 내지 30 중량부의 전분과, 50 내지 70 중량부의 물을 포함하여 이루어진다.Environmentally friendly mist spreader containing starch according to the present invention, there is no concern of environmental pollution when spray diffusion by adding insecticides, fungicides or herbicides, so that all problems due to smell can be solved, 20 to 30 parts by weight of animal and vegetable refined oil, 10 to 30 parts by weight of starch, and 50 to 70 parts by weight of water.
본 발명에 따른 전분이 함유된 친환경 연무확산제의 경우에는, 환경오염과 불쾌한 냄새를 초래하는 광물유 대신에, 이미 사용한 식물성유(대두유, 체종유, 미강유, 옥수수유, 소나무유, 야자유, 올리브유, 톨유, 팜유 등)나 동물성유(돈유, 우지, 어유, 말향유 등를 정제한 동식물성 정제유가 20 내지 30 중량부의 양으로 혼합되어 사용됨에 따라 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산될 경우에 생분해되어 환경오염물질을 남기지 않게 되며, 식물성유나 동물성유 그 자체가 아니라 이미 사용한 식물성유나 동물성유를 재활용함에 따라 환경적인 면에서 더욱 우수하다.In the case of the environment-friendly mist diffusion agent containing starch according to the present invention, instead of mineral oil that causes environmental pollution and unpleasant odor, vegetable oils (soybean oil, soybean oil, rice bran oil, corn oil, pine oil, palm oil, olive oil, In case of spraying and spreading by adding insecticide, fungicide or herbicide, as animal and vegetable oil (purified oil, tallow, fish oil, horse oil, etc.) purified from tall oil, palm oil, etc. is mixed and used in an amount of 20 to 30 parts by weight. It is biodegradable and does not leave environmental pollutants. It is more environmentally friendly as it recycles vegetable or animal oil that has already been used, not vegetable or animal oil itself.
또한 본 발명에 따른 전분이 함유된 친환경 연무확산제의 경우에는, 전분이 10 내지 30 중량부의 양으로 혼합되어 사용되는데, 이 전분은 수많은 D-글루코스(포도당)가 축합반응을 일으키면서 길게 연결되어 만들어지는 다당류로서 아밀로오스와 아밀로펙틴의 혼합물로서, 그 원료에 따라 고구마녹말·감자녹말·밀녹말·옥수수녹말(콘스타치) 등으로 나뉘어진다.In addition, in the case of an environment-friendly mist diffusion agent containing starch according to the present invention, starch is used in an amount of 10 to 30 parts by weight, and this starch is connected long while numerous D-glucose (glucose) causes a condensation reaction. As a polysaccharide to be produced, it is a mixture of amylose and amylopectin, and is divided into sweet potato starch, potato starch, wheat starch, corn starch (corn starch) and the like depending on the raw materials.
전분은 3 내지 6 중량부의 황산의 첨가에 의해 가수분해된 후 동식물성 정제유와 물과 혼합되는 것이 바람직한데, 이 경우에 전분으로부터 가수분해된 글루코스가 천연 계면활성제 역할을 함에 따라 본 발명에 따른 전분이 함유된 친환경 연무확산제의 경우에는 글리세린을 포함하는 화학적 계면활성제를 사용하지 않더라도 동실물성 정제유와 물이 유화되어 잘 혼합될 수 있게 되며, 살충제, 살균제 또는 제초제 등을 첨가하여 분무확산되더라도 글리세린으로 인한 오염물질이 전혀 발생되지 않게 된다.The starch is preferably hydrolyzed by the addition of 3 to 6 parts by weight of sulfuric acid and then mixed with animal and vegetable refined oil and water, in which case the starch according to the invention as the hydrolyzed glucose from the starch acts as a natural surfactant In the case of the environmentally friendly mist diffusion agent containing the same, the same refined oil and water can be emulsified well even without using a chemical surfactant containing glycerin, and even if spray-diffused by adding insecticide, fungicide or herbicide, No contaminants are generated.
또한 본 발명에 따른 전분이 함유된 친환경 연무확산제의 경우에는, 물이 50 내지 70 중량부의 양으로 혼합되어 사용되는데, 이 물은 본 발명에 따른 전분이 함유된 친환경 연무확산제의 주성분으로 추후 첨가될 살충제, 살균제 또는 제초제 등이 본 발명에 따른 전분이 함유된 친환경 연무확산제에 골고루 혼합될 수 있도록 하는 용매역할을 한다.In addition, in the case of the environment-friendly mist diffusion agent containing starch according to the present invention, water is used in an amount of 50 to 70 parts by weight, which is used as a main component of the environment-friendly mist diffusion agent containing starch according to the present invention Insecticides, fungicides or herbicides to be added serves as a solvent to be evenly mixed with the starch-containing environmentally friendly mist diffusion agent according to the invention.
또한 본 발명에 따른 전분이 함유된 친환경 연무확산제의 경우에는, 광물분말이 8 내지 24 중량부의 양으로 혼합되어 사용되는 것이 바람직한데, 이 광물분말은 추후 첨가될 살충제, 살균제 또는 제초제 등을 흡착하는 것은 물론 원적외선과 음이온을 방출함에 따라 본 발명에 따른 전분이 함유된 친환경 연무확산제의 분무시 발생하는 불쾌한 냄새를 중화시킴과 동시에 인체에도 유익한 작용을 할 수 있도록 하는 것으로, 4 내지 12 중량부의 벤토나이트분말과, 3 내지 9 중량부의 제올라이트분말과, 1 내지 3 중량부의 초석분말로 이루어진다. 또한 광물분말은 다양한 입도의 분말이 사용될 수 있으나 나노 단위의 미립자가 사용되는 것이 바람직하다.In addition, in the case of an environment-friendly mist diffusion agent containing starch according to the present invention, it is preferable that the mineral powder is mixed and used in an amount of 8 to 24 parts by weight, and the mineral powder adsorbs pesticides, fungicides or herbicides to be added later. Of course, to neutralize the unpleasant odor generated when spraying the environment-friendly mist diffusion agent containing starch according to the present invention by emitting far infrared rays and anions, and at the same time to be beneficial to the human body, 4 to 12 parts by weight It consists of a bentonite powder, 3-9 weight part zeolite powder, and 1-3 weight part salt powder. In addition, the mineral powder may be a powder of various particle sizes, but nano-particles are preferably used.
벤토나이트는 운모와 같은 결정구조를 하는 단사정계에 속하는 광물인 몬모릴로나이트가 주로 들어있는 점토를 말하는 것으로, 양이온을 띈 천연미네랑이 다량 함유되어 높은 흡착성을 발휘하며, 제올라이트는 알칼리 및 알칼리토금속의 규산알루미늄 수화물인 광물을 총칭하는 말로 흡착성이 우수한 것으로 알려져 있으며, 초석은 감람석과 같은 결정구조를 가지는 사방정계에 속하는 광물로 본 발명에 따른 전분이 함유된 친환경 연무확산제의 분무시 토양에 대한 비료성분으로 작용한다. 이러한 벤토나이트, 제올라이트, 초석은 원적외선과 음이온을 다량 방출하는 특성도 가지고 있다.Bentonite refers to clay mainly containing montmorillonite, a mineral belonging to a monoclinic system having a crystalline structure such as mica. Phosphorus mineral is a general term known to have excellent adsorption property. The cornerstone is a mineral belonging to the tetragonal system having the same crystal structure as olivine, and acts as a fertilizer component to soil during spraying of environmentally friendly mist diffusion agent containing starch according to the invention. do. These bentonites, zeolites, and cornerstones also have the property of emitting large amounts of far infrared rays and anions.
뿐만 아니라 본 발명에 따른 전분이 함유된 친환경 연무확산제의 경우에는, 전분의 가수분해로 인해 계면활성제가 전혀 필요없긴 하지만 실시예에 따라서는 0.5 내지 2 중량부의 계면활성제를 더 포함하여 이루어질 수도 있다.In addition, in the case of the environment-friendly mist diffusion agent containing starch according to the present invention, due to the hydrolysis of the starch is not required at all, depending on the embodiment may further comprise a 0.5 to 2 parts by weight of the surfactant .
전술한 본 발명에 따른 전분이 함유된 친환경 연무확산제에 있어서, 동식물성 정제유, 전분, 물, 황산, 광물분말, 계면활성제의 함량은 출원인의 다양한 실험을 통해 최적의 연무확산효과를 가져오는 범위로 선택되었음을 밝혀두며, 전술한 본 발명에 따른 전분이 함유된 친환경 연무확산제는 각각의 조성성분들이 교반기 내에서 60 내지 80℃의 온도하에서 1600 내지 2000rpm으로 고속교반되는 것이 바람직하며, 열건식 연막장치를 통해 분무확산되는 것이 바람직하다.
In the environment-friendly mist diffusion agent containing starch according to the present invention described above, the content of plant and vegetable refined oil, starch, water, sulfuric acid, mineral powder, and surfactant ranges to obtain the optimum mist diffusion effect through the applicant's various experiments The environmentally friendly mist spreader containing starch according to the present invention described above is preferably stirred at a high speed at 1600 to 2000 rpm at a temperature of 60 to 80 ° C. in a stirrer, and a thermal dry smoke screen. Spray diffusion through the device is preferred.
[실시예] [Example]
기 사용한 대두유를 정제한 정제 대두유 25 중량부와, 중량부의 황산 첨가를 통해 사전 가수분해된 전분 20 중량부와, 물 60 중량부와, 벤토나이트분말 8 중량부와, 제올라이트분말 6 중량부와, 초석분말 2 중량부와, 계면활성제 2중량부를 교반기에 투입하고, 70℃의 온도하에서 1800rpm으로 30분간 고속교반시켜 본 발명에 따른 전분이 함유된 친환경 연무확산제를 제조한 후 열건식 연막장치를 통해 자동차 표면에 분무확산시킨 결과, 5분 경과후 본 발명에 따른 전분이 함유된 친환경 연무확산제의 흔적이 육안으로 약간 발견되기는 하였으나, 마른걸레로 훔친 결과 깨끗하게 제거되었고, 특이한 식물성 기름 냄새나 기타 불쾌한 냄새는 전혀 나지 않았으며, 연막기의 노즐 막힘 시험에서도 완전 연소로 인해 전혀 노즐 막힘이 없었음을 확인할 수 있었다.
25 parts by weight of purified soybean oil, 20 parts by weight of pre-hydrolyzed starch by weight addition of sulfuric acid, 60 parts by weight of water, 8 parts by weight of bentonite powder, 6 parts by weight of zeolite powder, 2 parts by weight of powder and 2 parts by weight of surfactant were added to a stirrer, and stirred at a high speed of 1800 rpm for 30 minutes at a temperature of 70 ° C. to prepare an environmentally friendly mist diffusion agent containing starch according to the present invention, and then through a hot-dry smoke screen device. After spraying on the surface of the car, after 5 minutes, traces of the environmentally friendly mist spreader containing starch according to the present invention were found with the naked eye, but it was cleanly removed as a result of stealing with a dry mop. There was no smell at all, and the nozzle clogging test of the smoke screen showed that there was no nozzle clogging due to complete combustion.
Claims (4)
상기 전분은 3 내지 6 중량부의 황산의 첨가에 의해 가수분해된 후 상기 동식물성 정제유와 상기 물과 혼합되는 것을 특징으로 하는 전분이 함유된 친환경 연무확산제. 20 to 30 parts by weight of animal and vegetable refined oil, 10 to 30 parts by weight of starch, and 50 to 70 parts by weight of water,
The starch is an environmentally friendly mist diffusion agent containing starch, characterized in that the hydrolyzed by the addition of 3 to 6 parts by weight of sulfuric acid and then mixed with the animal and vegetable refined oil.
8 내지 24 중량부의 광물분말을 더 포함하여 이루어지고, 상기 광물분말은 4 내지 12 중량부의 벤토나이트분말과, 3 내지 9 중량부의 제올라이트분말과, 1 내지 3 중량부의 초석분말로 이루어지는 것을 특징으로 하는 전분이 함유된 친환경 연무확산제. The method according to claim 1,
It further comprises 8 to 24 parts by weight of the mineral powder, the mineral powder is starch, characterized in that consisting of 4 to 12 parts by weight of bentonite powder, 3 to 9 parts by weight of zeolite powder, 1 to 3 parts by weight of salt stone powder This environmentally friendly mist spreader contains.
0.5 내지 2 중량부의 계면활성제를 더 포함하여 이루어지는 것을 특징으로 하는 전분이 함유된 친환경 연무확산제.The method according to claim 1 or 2,
Eco-friendly misting agent containing starch, characterized in that it further comprises 0.5 to 2 parts by weight of surfactant.
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| KR101869197B1 (en) * | 2017-06-19 | 2018-06-19 | 최명신 | A vegetable smoke fogging agent for environment-friendly disease prevention method and a manufacturing method for the same |
| KR20200028557A (en) | 2018-09-06 | 2020-03-17 | 주식회사 이노뷰텍 | Eco-friendly mist fog and cloud spread agent with sterilization and insecticidal effect |
| KR20200137277A (en) | 2019-05-29 | 2020-12-09 | (주)공간파크 | manufacturing method for spread agent |
| KR20210001430A (en) | 2019-06-28 | 2021-01-06 | (주)엠제이폴리텍 | Dyd added eco-friendly smoke and fog dispersing agent |
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| JP2008019226A (en) * | 2006-07-14 | 2008-01-31 | Earth Chem Corp Ltd | Composition, spray product and method for controlling small flies |
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| AU779385B2 (en) * | 1999-08-11 | 2005-01-20 | Dow Agrosciences Llc | Oil in water flowable pesticide formulation |
| KR100456808B1 (en) * | 2000-03-29 | 2004-11-10 | 허원기 | Fog and cloud spread agent without public nuisance |
| DE102005016102B3 (en) * | 2005-04-08 | 2006-10-26 | Altana Pharma Ag | Device for metering and dry fogging |
| KR100987018B1 (en) * | 2007-11-27 | 2010-10-11 | 고려대학교 산학협력단 | Crystal nano starch -alcohols complex, and preparing method of crystal nano starch particles using the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR101869197B1 (en) * | 2017-06-19 | 2018-06-19 | 최명신 | A vegetable smoke fogging agent for environment-friendly disease prevention method and a manufacturing method for the same |
| KR20200028557A (en) | 2018-09-06 | 2020-03-17 | 주식회사 이노뷰텍 | Eco-friendly mist fog and cloud spread agent with sterilization and insecticidal effect |
| KR20200137277A (en) | 2019-05-29 | 2020-12-09 | (주)공간파크 | manufacturing method for spread agent |
| KR20210001430A (en) | 2019-06-28 | 2021-01-06 | (주)엠제이폴리텍 | Dyd added eco-friendly smoke and fog dispersing agent |
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