WO2011086677A1 - 濃度検出装置 - Google Patents
濃度検出装置 Download PDFInfo
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- WO2011086677A1 WO2011086677A1 PCT/JP2010/050331 JP2010050331W WO2011086677A1 WO 2011086677 A1 WO2011086677 A1 WO 2011086677A1 JP 2010050331 W JP2010050331 W JP 2010050331W WO 2011086677 A1 WO2011086677 A1 WO 2011086677A1
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- Prior art keywords
- frequency
- concentration
- component value
- fuel
- resistance component
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- 238000001514 detection method Methods 0.000 title claims abstract description 62
- 239000000446 fuel Substances 0.000 claims abstract description 131
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 80
- 238000010586 diagram Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 230000006866 deterioration Effects 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003990 capacitor Substances 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2835—Specific substances contained in the oils or fuels
- G01N33/2852—Alcohol in fuels
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/06—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a liquid
Definitions
- This invention relates to a concentration detection apparatus. More specifically, the present invention relates to a concentration detection apparatus suitable for detecting the alcohol concentration in an alcohol mixed fuel supplied to an internal combustion engine.
- Patent Document 1 discloses a conventional concentration detecting device for detecting the alcohol concentration in an alcohol mixed fuel.
- concentration detection device of Patent Document 1 an alcohol concentration sensor and a coil L are connected in series.
- the conductivity of the alcohol concentration sensor is detected by applying a low current to the circuit.
- the resonance frequency generated in the LC resonance circuit composed of the alcohol concentration sensor and the coil L is detected as a capacitance-corresponding value.
- the capacitance of the alcohol concentration sensor is calculated by calculating the voltage value by frequency-voltage conversion of this frequency.
- the alcohol concentration in the mixed fuel is detected based on this capacitance.
- the detected value includes a component value resulting from, for example, the electrode of the sensor itself, a capacitor, a coil, a lead wire (hereinafter referred to as an electrode), and the like. Therefore, the amount of change in conductivity and capacitance includes the amount due to deterioration of the electrodes and the like in addition to the amount of change caused by the alcohol concentration. Therefore, when the deterioration of the electrode or the like is large, it is conceivable that the amount of change in the conductivity or capacitance due to the deterioration becomes large, and the deviation between the calculated alcohol concentration and the actual concentration becomes large.
- an object of the present invention is to provide an improved concentration detection apparatus capable of detecting an alcohol concentration while minimizing a deviation of a detection value caused by electrode deterioration or the like. .
- a first invention is a concentration detection device for detecting an alcohol concentration in an alcohol-mixed fuel,
- a frequency control means for controlling the frequency of an alternating voltage applied to a pair of spaced electrodes;
- a resistance component value detecting means for detecting a second resistance component value between the electrodes when an AC voltage having a second frequency different from the first frequency is applied;
- Concentration estimating means for estimating an alcohol concentration according to a difference between the first resistance component value and the second resistance component value; Is provided.
- a second invention further comprises a temperature detection means for detecting the temperature of the alcohol-mixed fuel in the first invention,
- the concentration estimation unit estimates an alcohol concentration according to a difference between the first resistance component value and the second resistance component value and a temperature detected by the temperature detection unit.
- a capacitance component value calculating means for calculating a capacitance component value between the electrodes when a predetermined third frequency between the first frequency and the second frequency is applied;
- Temperature estimation means for detecting the temperature of the alcohol-mixed fuel according to the difference between the first resistance component value and the second resistance component value and the capacity component value; Is further provided.
- 4th invention is 1st or 2nd invention, Temperature detecting means for detecting the temperature of the alcohol mixed fuel; A capacitance component value calculating means for calculating a capacitance component value between the electrodes when a predetermined third frequency between the first frequency and the second frequency is applied; Moisture concentration for calculating the moisture concentration in the alcohol-mixed fuel according to the difference between the first resistance component value and the second resistance component value, the capacitance component value, and the temperature detected by the temperature detection means A calculation means; Is further provided.
- the capacitance component value of the impedance becomes zero, and alcohol is used according to the difference between the first resistance component value and the second resistance component value with respect to AC voltages having different first and second frequencies.
- the concentration is detected.
- the alcohol concentration is estimated according to the difference between the first resistance component value and the second resistance component value and the temperature of the mixed fuel.
- the conductivity of alcohol also varies with temperature. Accordingly, the alcohol concentration can be estimated more accurately by estimating the concentration according to the temperature.
- the capacitance component value for the predetermined third frequency is calculated together with the first resistance component value and the second resistance component value.
- both the resistance component value and the capacitance component value have a correlation with temperature. Therefore, by detecting the difference between the first resistance component value and the second resistance component value and the capacitance component value, the temperature can be detected together with the alcohol concentration. Thereby, it is not necessary to separately install a temperature sensor or the like, and the cost of the system can be reduced.
- the alcohol concentration in the mixed fuel is detected and the moisture concentration is detected using the difference between the first resistance component value and the second resistance component value, the capacitance component value, and the temperature as parameters. can do. Therefore, the fuel property can be detected more accurately, and air-fuel ratio control or the like with high accuracy can be realized.
- Embodiment 1 of this invention It is a schematic diagram for demonstrating the whole structure of the system in Embodiment 1 of this invention. It is an equivalent circuit diagram of the concentration detection apparatus in Embodiment 1 of this invention. It is a figure for demonstrating the change of the resistance with respect to temperature of a metal electrode and an electroconductive substance. It is a complex impedance plot figure at the time of applying an alternating frequency to the concentration detection apparatus in Embodiment 1 of this invention. It is a figure for demonstrating the routine of control which a control apparatus performs in Embodiment 1 of this invention. It is a figure for demonstrating the relationship between the electrical conductivity of the density
- FIG. 1 is a schematic diagram for explaining an installation state of the concentration detection apparatus according to Embodiment 1 of the present invention.
- the concentration detection device 2 is used to detect the alcohol concentration in the mixed fuel, for example, when a mixed fuel in which alcohol is mixed with gasoline is used.
- FIG. 1 shows an example in which the concentration detection device is mounted on the fuel path 6 of the internal combustion engine 4 mounted on a vehicle or the like.
- the installation / use location of the concentration detection device 2 is not limited to this, and the concentration detection device 2 can be widely used in locations necessary for detecting the fuel concentration.
- the concentration detection device 2 includes a pair of electrodes 8 that are spaced apart. At least a part of the electrode 8 is installed in the fuel path 6 so as to be in contact with the mixed fuel.
- the concentration detection device 2 is connected to the electrode 8 and includes an AC power source 10 for applying AC and DC voltage to the electrode 8.
- the concentration detection device 2 constitutes a detection circuit to which an impedance detector for detecting the impedance between the electrodes 8 and a frequency detector for detecting an AC frequency are connected.
- the concentration detection device 2 further includes a control device 12.
- the control device 12 is connected to various detectors of the concentration detection device 2 and the AC power supply 10.
- the control device 12 receives the output signals of these detectors, detects the impedance and the like of the concentration detection device 2, and performs various calculations according to the detected information. Further, for example, a control signal is issued to the AC power source 10 to control the frequency of the voltage applied to the concentration detection device 2.
- the gasoline and alcohol in the mixed fuel differ greatly in conductivity and dielectric constant, and alcohol is larger. Therefore, the dielectric constant and conductivity in the mixed fuel change following the change in the alcohol concentration. By utilizing this, the alcohol concentration in the mixed fuel can be detected by detecting the resistance value and capacitance between the electrodes 8.
- the impedance generated when an AC voltage is applied to the concentration detection device 2 can be considered as divided into the following components.
- Component derived from fuel between electrodes 8 (2) Component derived from parts other than fuel, such as electrode 8
- the concentration detection apparatus 2 has an equivalent circuit diagram as shown in FIG.
- FIG. 2 is an equivalent circuit diagram of the concentration detection apparatus 2 according to Embodiment 1 of the present invention.
- the fuel resistance component Rf and the fuel capacity component Cf are components derived from the mixed fuel of the electrode 8 winding in (1) above, and the electrode resistance component Re is the electrode 8 in (2) other than the fuel.
- the resistance component derived from is shown.
- the fuel resistance component Rf and the fuel capacity component Cf are components that change according to the alcohol concentration of the mixed fuel. Therefore, the change in the alcohol concentration can be detected by detecting the change in the fuel resistance component Rf.
- the resistance value detected when an AC or DC voltage is applied to the entire circuit includes the electrode resistance component Re of (2) above. If the electrode resistance component Re is a constant value, it is easy to detect only the change in the fuel resistance component Rf. However, changes due to deterioration and changes due to temperature occur in the electrode resistance component Re.
- FIG. 3 is a diagram for explaining the change in resistance according to the temperature of the metal electrode and the conductive material, in which the horizontal axis represents temperature and the vertical axis represents resistance.
- the broken line (a) represents the resistance of the metal electrode
- the curve (b) represents the change in the resistance of the conductive material.
- the resistance of the metal electrode increases as the temperature increases.
- the resistance of the conductive material decreases as the temperature increases. Therefore, also in the concentration detection device 2, the resistance of the electrode resistance component Re that is a resistance component of the electrode 8 and the like increases as the temperature increases, and the resistance of the fuel resistance component Rf caused by the mixed fuel that is a conductive substance is increased. It can be seen that the resistance decreases with increasing temperature.
- the electrode resistance component Re and the fuel resistance component Rf have a characteristic that shows opposite changes with respect to temperature.
- the resistance change with respect to the temperature change appearing in the electrode resistance component Re and the fuel resistance component Rf is removed. Therefore, it is necessary to measure a change according to the alcohol concentration change of the fuel resistance component Rf.
- the resistance values of the electrodes 8 and the lead wires constituting the detection circuit of the concentration detection device 2 change due to deterioration over time.
- the electrode 8 is installed in the mixed fuel, and its deterioration is large and the change in resistance value may be large. Therefore, in order to accurately detect a change in resistance due to the alcohol concentration, it is also important to remove a change in resistance value due to deterioration that appears in the electrode resistance component Re.
- FIG. 4 is a diagram showing a change in impedance of the concentration detection device 2 detected when the frequency of the alternating voltage is swept (changed) and applied to the detection circuit of the concentration detection device 2 in a complex impedance plot.
- the horizontal axis represents the real component (resistance component) of the impedance
- the vertical axis represents the imaginary component (capacitance component).
- the resistance value R1 (first resistance component value) at the intersection of the curve representing the complex impedance and the x-axis is the value of the electrode resistance component Re.
- the first frequency f1 and the second frequency f2 corresponding to the resistance values R1 and R2 are values that can be determined if the components in the mixed fuel, the temperature range in which the mixed fuel is used, etc. are specified to some extent. Therefore, in the first embodiment, the first frequency f1 and the second frequency f2 are set to appropriate values by experiments or the like according to the components of the mixed fuel and the use environment, and stored in the control device 12 in advance. When detecting the concentration, the resistance values R1 and R2 are detected by detecting the impedance by applying the first frequency f1 and the second frequency f2 stored in advance as described above.
- the first frequency f1 is set to 10 [kHz] to 1 [MHz] and the second frequency f2 is set to 100 [Hz] in consideration of using a mixed fuel of gasoline and alcohol. ] ⁇ 10 [kHz].
- the fuel resistance component Rf detected from R1 and R2 does not include the resistance caused by the electrode of the sensor, but is purely the resistance caused by the fuel.
- the fuel resistance component Rf has a correlation with the alcohol concentration and also has a correlation with the temperature. Therefore, in the first embodiment, the relationship between the fuel resistance component Rf, the alcohol concentration, and the temperature is obtained in advance and stored in the control device 12 as a map.
- the fuel resistance component Rf and the temperature T of the mixed fuel obtained from the output of the temperature sensor or the like are used as parameters, and the alcohol concentration is calculated according to this map.
- FIG. 5 is a flowchart for illustrating a control routine executed by the control device in the first embodiment of the present invention.
- the routine of FIG. 5 is a routine that is repeatedly executed at regular intervals during the operation of the internal combustion engine 4. In the routine of FIG. 5, it is first detected whether or not the internal combustion engine 4 has been started (S12). If the internal combustion engine 4 is stopped, it is not necessary to detect the fuel concentration, and thus this routine ends.
- the concentration detection device 2 is in a normal state (S14).
- the normal state is not recognized.
- the current routine ends.
- step S16 the temperature T is detected (S16).
- the temperature T is detected by the control device 12 in accordance with an output signal of a temperature sensor (not shown) installed in the fuel path 6.
- an alternating voltage of the first frequency is applied to the circuit of the concentration detection device 2 and the impedance is detected (S18).
- the control device 12 reads the first frequency f1 stored in advance, and outputs a predetermined control signal to the AC power supply 10, whereby an AC voltage having the first frequency f1 is generated between the electrodes 8. Applied.
- the impedance generated here is detected.
- an AC voltage having the second frequency f2 is applied to the circuit of the concentration detection device 2 to detect the impedance (S20).
- the control device 12 reads the second frequency f2 stored in advance. Then, by outputting a predetermined control signal to the AC power supply 10, an AC voltage having the second frequency f2 is applied between the electrodes 8, and the impedance generated here is detected.
- the fuel resistance component Rf is detected based on the impedance detected in steps S18 and S20 (S22).
- the fuel resistance component Rf is the difference between the resistance value R1 detected from the impedance with respect to the first frequency and the resistance value R2 detected from the resistance component with respect to the second frequency.
- Fuel resistance component Rf resistance value R2 ⁇ resistance value R1 Is required.
- the alcohol concentration is calculated according to the fuel resistance component Rf and the current temperature T (S24).
- the alcohol concentration is obtained according to a map indicating the relationship between the temperature T, the fuel resistance component Rf, and the alcohol concentration. This map is stored in the control device 12 in advance. Thereafter, the current routine ends.
- the electrode resistance component Re caused by the electrode 8 and the like and the fuel resistance component Rf caused by the fuel can be detected separately. It is possible to detect the alcohol concentration of the mixed fuel according to only the change in the fuel resistance component Rf caused by the fuel by removing the influence of the deterioration of the electrode 8 and the resistance value caused by the temperature change. Therefore, the alcohol concentration is detected more accurately.
- the present invention is not limited to this.
- the frequency is swept from a high frequency to a low frequency, detection is performed a plurality of times, and the resistance values R1 and R2 are determined by the AC impedance method. It can also be detected.
- the present invention is not limited to this, and if the change in the resistance value of the fuel resistance component Rf with respect to the temperature change is negligible, the fuel concentration is detected only according to the resistance value of the fuel resistance component Rf. You can also.
- the “temperature detecting means” of the present invention is realized by executing step S16, and the “resistance component detecting means” is realized by executing steps S18, S20, and S22.
- the “concentration estimation means” is realized.
- Embodiment 2 The concentration detection apparatus of the second embodiment has the same configuration as that of the apparatus of FIG.
- the concentration detection device according to the second embodiment is the same as the device according to the first embodiment except that the alcohol concentration is detected and the temperature of the mixed fuel is detected.
- FIG. 6 is a diagram for explaining the relationship between the electric conductivity of the fuel (the reciprocal of the resistance value) and the capacitance.
- the resistance component of the fuel has a correlation with the temperature.
- the capacitance of the fuel also has a correlation with the temperature and changes according to the temperature. Specifically, the conductivity increases as the temperature increases, and the capacitance decreases as the temperature increases. Further, as described above, the conductivity has a correlation with the alcohol concentration. Therefore, alcohol concentration and temperature can be detected simultaneously by using conductivity and capacitance as parameters.
- the control device 12 stores the relationship among conductivity, capacitance, and temperature as shown in FIG. 6 as a map. By detecting the conductivity (resistance value) and the capacitance, the fuel concentration and the temperature can be detected simultaneously.
- the electrostatic capacity of the mixed fuel is a value when the fuel capacity component Cf is the maximum value in FIG.
- the frequency at which the fuel capacity component Cf is maximized is the third frequency f3 and the resistance component value is the resistance value R3, the relationship of the following equation (1) is established.
- R3Cf 1 / (2 ⁇ f3) (1)
- the third frequency f3 a frequency that becomes the resistance value R3 is specified in advance. Similar to the first and second frequencies f1 and f2, the third frequency f3 is a suitable value that can be determined if the components in the mixed fuel, the temperature range in which the mixed fuel is used, and the like are specified to some extent. Therefore, in the second embodiment, the third frequency f3 is obtained together with the first frequency f1 and the second frequency f2 by experiments or the like according to the components of the mixed fuel and the use environment, and stored in the control device 12 in advance.
- the fuel capacity component Cf can be calculated by substituting the third frequency f3 and the resistance value R3 into the equation (1).
- FIG. 7 is a flowchart for illustrating a control routine according to the second embodiment of the present invention.
- the routine of FIG. 7 does not have the process of step S16 of the routine of FIG. 5, but differs from the routine of FIG. 5 only in that it has the processes of steps S30 and S32 after the process of step S22.
- the value of the fuel capacity component Cf is calculated after the process of step S22 (S30). Specifically, the fuel capacity component is calculated by substituting the resistance values R1 and R2 calculated in step S22 and the third frequency f3 stored in advance in the control device 12 into the above equation (1).
- the temperature of the mixed fuel is calculated (S32).
- the temperature is calculated according to a map stored in advance in the control device 12 according to the reciprocal of the fuel resistance component Rf (that is, conductivity) calculated in step S22 and the value of the fuel capacity component Cf.
- the alcohol concentration is detected (S24).
- the alcohol concentration corresponding to the temperature calculated in step S32 and the fuel resistance component Rf is detected.
- the temperature of the mixed fuel can be detected by the same apparatus as that for detecting the alcohol concentration. Accordingly, it is not necessary to install a temperature sensor or the like, so that the cost and size of the system can be reduced.
- the present invention is not limited to this, and by changing the frequency a plurality of times, for example, a curve of complex impedance as shown in FIG. 4 is obtained, thereby obtaining the fuel capacity component Cf. it can.
- capacitor component calculation means of the present invention is realized by executing step S30
- temperature estimation means of the present invention is realized by executing step S32.
- FIG. FIG. 8 is a diagram for explaining the change in the concentration conversion value based on the concentration detection device with respect to the change in the amount of water mixed in the mixed fuel in Embodiment 3 of the present invention, and the horizontal axis represents the amount of water mixed [wt%]. The vertical axis represents the concentration conversion value [wt%]. Line segments (a), (b), and (c) represent examples when the initial concentration of ethanol mixed into the mixed fuel is 100%, 85%, and 22%.
- the dielectric constant of water is about 3.3 times that of ethanol. Therefore, when a mixed fuel in which ethanol is mixed with gasoline is used as the fuel, the capacitance increases by 1.5% when the amount of water mixed in ethanol further increases by 1%. Therefore, for example, as in the case of the line (b) in which the ethanol concentration mixed into gasoline as fuel is 85%, when the water mixing amount increases by 1%, a detected value in which the ethanol concentration increases by 1.5% is shown.
- the amount of moisture mixed into the mixed fuel and the change in capacitance have a correlation. Further, since the alcohol concentration in the mixed fuel changes, the conductivity also changes accordingly. Therefore, the fuel resistance component Rf and the amount of mixed water have a specific correlation.
- the alcohol concentration in the mixed fuel is specified by using the fuel capacity component Cf, the fuel resistance component Rf, and the temperature detected by the temperature sensor as parameters. And the moisture concentration can be detected.
- the relationship among the fuel capacity component Cf, the fuel resistance component Rf, the temperature T, the alcohol concentration, and the water concentration is obtained in advance by experiments and stored in the control device 12 as a map.
- the fuel capacity component Cf, the fuel resistance component Rf, and the temperature T are detected by the method described in the first and second embodiments, and the alcohol concentration and the water concentration are detected according to the map.
- the water concentration in the mixed fuel can be detected by detecting the fuel capacity component Cf and the fuel resistance component Rf. Accordingly, both the alcohol concentration and the water concentration can be detected by one apparatus, and the fuel properties can be grasped more accurately without increasing the size of the apparatus.
- Concentration detection device 4 Internal combustion engine 6 Fuel path 8 Electrode 10 AC power supply 12 Control device Cf Fuel capacity component Re Electrode resistance component Rf Fuel resistance component
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Abstract
Description
離間して配置された一対の電極に印加される交流電圧の、周波数を制御する周波数制御手段と、
前記電極間に、インピーダンスの容量成分値がゼロとなる第1周波数の交流電圧を印加した場合の、前記電極間の第1抵抗成分値を検出すると共に、インピーダンスの容量成分値がゼロとなり、かつ、前記第1周波数とは異なる第2周波数の交流電圧を印加した場合の、前記電極間の第2抵抗成分値を検出する抵抗成分値検出手段と、
前記第1抵抗成分値と前記第2抵抗成分値との差に応じて、アルコール濃度を推定する濃度推定手段と、
を備える。
前記濃度推定手段は、前記第1抵抗成分値と前記第2抵抗成分値との差と、前記温度検出手段により検出された温度に応じて、アルコール濃度を推定する。
前記第1周波数と前記第2周波数との間の、所定の第3の周波数を印加した場合の、前記電極間の容量成分値を算出する容量成分値算出手段と、
前記第1抵抗成分値と前記第2抵抗成分値との差と、前記容量成分値とに応じて、アルコール混合燃料の温度を検出する温度推定手段と、
を更に備える。
アルコール混合燃料の温度を検出する温度検出手段と、
前記第1周波数と前記第2周波数との間の、所定の第3の周波数を印加した場合の、前記電極間の容量成分値を算出する容量成分値算出手段と、
前記第1抵抗成分値と第2抵抗成分値との差と、前記容量成分値と、前記温度検出手段により検出された温度と、に応じて、アルコール混合燃料中の水分濃度を算出する水分濃度算出手段と、
を更に備える。
図1はこの発明の実施の形態1における濃度検出装置の設置状態について説明するための模式図である。図1に示すように、濃度検出装置2は、例えばガソリンにアルコールが混合された混合燃料を用いる場合などに、混合燃料中のアルコール濃度を検出するために用いられる。図1では、濃度検出装置が、車両等に搭載される内燃機関4の燃料経路6等に搭載された例を表している。但し、この発明において、濃度検出装置2の設置・使用箇所はこれに限るものではなく、この濃度検出装置2は燃料濃度の検出に必要な箇所において広く用いることができる。
(1)電極8間の燃料に由来する成分
(2)電極8等、燃料以外の部分に起因する成分
実施の形態2の濃度検出装置は、図1の装置と同様の構成をする。実施の形態2の濃度検出装置は、アルコール濃度の検出と共に、混合燃料の温度の検出を行なう点を除き、実施の形態1の装置と同様である。
R3Cf=1/(2πf3) ・・・・(1)
図8はこの発明の実施の形態3における混合燃料中の水分混入量の変化に対する濃度検出装置に基づく濃度換算値の変化を説明するための図であり、横軸は水分混入量[wt%]、縦軸は濃度換算値[wt%]を表している。線分(a)、(b)、(c)は、混合燃料中に混合されたエタノールの最初の濃度が100%、85%、22%の場合の例を表している。
4 内燃機関
6 燃料経路
8 電極
10 交流電源
12 制御装置
Cf 燃料容量成分
Re 電極抵抗成分
Rf 燃料抵抗成分
Claims (4)
- アルコール混合燃料におけるアルコール濃度を検出する濃度検出装置であって、
離間して配置された一対の電極に印加される交流電圧の、周波数を制御する周波数制御手段と、
前記電極間に、インピーダンスの容量成分値がゼロとなる第1周波数の交流電圧を印加した場合の、前記電極間の第1抵抗成分値を検出すると共に、インピーダンスの容量成分値がゼロとなり、かつ、前記第1周波数とは異なる第2周波数の交流電圧を印加した場合の、前記電極間の第2抵抗成分値を検出する抵抗成分値検出手段と、
前記第1抵抗成分値と前記第2抵抗成分値との差に応じて、アルコール濃度を推定する濃度推定手段と、
を備えることを特徴とする濃度検出装置。 - アルコール混合燃料の温度を検出する温度検出手段を更に備え、
前記濃度推定手段は、前記第1抵抗成分値と前記第2抵抗成分値との差と、前記温度検出手段により検出された温度に応じて、アルコール濃度を推定することを特徴とする請求項1に記載の濃度検出装置。 - 前記第1周波数と前記第2周波数との間の、所定の第3の周波数を印加した場合の、前記電極間の容量成分値を算出する容量成分値算出手段と、
前記第1抵抗成分値と前記第2抵抗成分値との差と、前記容量成分値とに応じて、アルコール混合燃料の温度を検出する温度推定手段と、
を更に備えることを特徴とする請求項1に記載の濃度検出装置。 - アルコール混合燃料の温度を検出する温度検出手段と、
前記第1周波数と前記第2周波数との間の、所定の第3の周波数を印加した場合の、前記電極間の容量成分値を算出する容量成分値算出手段と、
前記第1抵抗成分値と第2抵抗成分値との差と、前記容量成分値と、前記温度検出手段により検出された温度と、に応じて、アルコール混合燃料中の水分濃度を算出する水分濃度算出手段と、
を更に備えることを特徴とする請求項1又は2に記載の濃度検出装置。
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DE112010005131T DE112010005131T5 (de) | 2010-01-14 | 2010-01-14 | Konzentrationserfassungsvorrichtung |
JP2011549813A JP5299522B2 (ja) | 2010-01-14 | 2010-01-14 | 濃度検出装置 |
US13/522,295 US20120291530A1 (en) | 2010-01-14 | 2010-01-14 | Concentration detecting apparatus |
PCT/JP2010/050331 WO2011086677A1 (ja) | 2010-01-14 | 2010-01-14 | 濃度検出装置 |
CN201080054254.1A CN102713590B (zh) | 2010-01-14 | 2010-01-14 | 浓度检测装置 |
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JP6023759B2 (ja) * | 2014-08-01 | 2016-11-09 | ヤマハ発動機株式会社 | センサ、相分離検出システム、及び相分離検出方法 |
DE102018130953A1 (de) * | 2018-12-05 | 2020-06-10 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Verfahren und Vorrichtung zum Ermitteln eines Mischungsverhältnisses |
WO2021070705A1 (ja) * | 2019-10-11 | 2021-04-15 | アルプスアルパイン株式会社 | ガス濃度測定装置 |
CN111157584A (zh) * | 2020-01-07 | 2020-05-15 | 广东博智林机器人有限公司 | 酒精含量检测方法、装置及检测设备 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57101753A (en) * | 1980-12-17 | 1982-06-24 | Toyota Motor Corp | Method and apparatus for measuring concentration of alcohol in alcohol mixed fuel |
JPH02132362A (ja) * | 1988-07-01 | 1990-05-21 | Stefan Reich | 液体の特徴を測定するための装置および方法 |
JPH0289354U (ja) * | 1988-12-28 | 1990-07-16 | ||
JPH0572160A (ja) * | 1991-09-12 | 1993-03-23 | Hitachi Ltd | 過酸化水素濃度の測定方法及び装置 |
JPH0541943B2 (ja) * | 1987-01-09 | 1993-06-25 | Hitachi Ltd |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2684468B2 (ja) | 1991-07-25 | 1997-12-03 | 新日本製鐵株式会社 | 鏡面方向性珪素鋼帯の製造方法 |
JP3126872B2 (ja) | 1994-05-12 | 2001-01-22 | 三菱電機株式会社 | 燃料の混合比率検知装置 |
KR100472644B1 (ko) * | 2002-01-09 | 2005-03-08 | 금호석유화학 주식회사 | 가황 시료의 임피던스 측정과 분석을 통한 최적의 실시간가황 조절 및 가황용 조성물을 구성하는 성분의 최적 함량결정 방법 |
WO2004113897A1 (en) * | 2003-06-16 | 2004-12-29 | Siemens Vdo Automotive Corporation | Method of apparatus for determoning the concentration of a component in a fluid |
CN1266470C (zh) * | 2003-12-01 | 2006-07-26 | 贾柏青 | 甲烷浓度检测方法及检测装置 |
US8268629B2 (en) * | 2005-06-21 | 2012-09-18 | dTEC Systems L.L.C. | Method for the measurement of water and water-soluble components in non-aqueous liquids |
JP4416033B2 (ja) | 2007-12-12 | 2010-02-17 | 株式会社デンソー | 濃度センサ装置 |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57101753A (en) * | 1980-12-17 | 1982-06-24 | Toyota Motor Corp | Method and apparatus for measuring concentration of alcohol in alcohol mixed fuel |
JPH0541943B2 (ja) * | 1987-01-09 | 1993-06-25 | Hitachi Ltd | |
JPH02132362A (ja) * | 1988-07-01 | 1990-05-21 | Stefan Reich | 液体の特徴を測定するための装置および方法 |
JPH0289354U (ja) * | 1988-12-28 | 1990-07-16 | ||
JPH0572160A (ja) * | 1991-09-12 | 1993-03-23 | Hitachi Ltd | 過酸化水素濃度の測定方法及び装置 |
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US20120291530A1 (en) | 2012-11-22 |
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JPWO2011086677A1 (ja) | 2013-05-16 |
DE112010005131T5 (de) | 2012-10-25 |
JP5299522B2 (ja) | 2013-09-25 |
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