WO2011078442A1 - 의료용 부직포 및 그의 제조방법 - Google Patents
의료용 부직포 및 그의 제조방법 Download PDFInfo
- Publication number
- WO2011078442A1 WO2011078442A1 PCT/KR2010/001999 KR2010001999W WO2011078442A1 WO 2011078442 A1 WO2011078442 A1 WO 2011078442A1 KR 2010001999 W KR2010001999 W KR 2010001999W WO 2011078442 A1 WO2011078442 A1 WO 2011078442A1
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- WO
- WIPO (PCT)
- Prior art keywords
- nonwoven fabric
- medical
- cellulose
- layer
- present
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
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- A61F13/02—Adhesive plasters or dressings
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- A61F13/00—Bandages or dressings; Absorbent pads
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- A—HUMAN NECESSITIES
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- A61L31/125—Composite materials, i.e. containing one material dispersed in a matrix of the same or different material having a macromolecular matrix
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- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/659—Including an additional nonwoven fabric
- Y10T442/668—Separate nonwoven fabric layers comprise chemically different strand or fiber material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/659—Including an additional nonwoven fabric
- Y10T442/668—Separate nonwoven fabric layers comprise chemically different strand or fiber material
- Y10T442/669—At least one layer of inorganic strand or fiber material and at least one layer of synthetic polymeric strand or fiber material
Definitions
- the present invention relates to a medical nonwoven fabric in the form of a wet nonwoven fabric made of cellulose-based short fibers gelling by a papermaking method, a method for manufacturing the same and an anti-adhesion film using the same, and more particularly in accordance with an optimal manufacturing method for improving the non-woven fabric strength It provides a single-phase medical nonwoven fabric, and provides a composite nonwoven fabric with improved shape stability and procedure convenience, and relates to an anti-adhesion film using the same.
- Nonwoven fabric is a planar fiber made by tangling a variety of fibers such as natural fibers, chemical fibers, glass fibers, and metal fibers to form entangled webs, and combining them by mechanical or physical methods. It can be defined as a structure.
- nonwoven fabrics are widely consumed in our industry and living surroundings, and the use, characteristics, and functions of nonwoven fabrics are becoming known to real users, and various uses using nonwoven fabrics are being created.
- Non-woven products applied to the medical market, as well as wear products such as surgical gowns, masks, as well as surgical drapes, pads, dressings, filter materials, as well as tissue supports that are inserted for the regeneration of internal organs.
- FIG. 1 shows a manufacturing process of a wet nonwoven fabric using a paper making process, in which a process (2) of dispersing the pulped fiber obtained through the grinding process (1) in an aqueous medium is repeatedly performed as necessary.
- a process (2) of dispersing the pulped fiber obtained through the grinding process (1) in an aqueous medium is repeatedly performed as necessary.
- the sheet obtained by the step (5) of winding up the wet nonwoven fabric is formed by dispersing fibers of extremely short lengths, for example, 1 to 7 mm in water, in order to ensure uniform dispersion of the fibers, so that uniformity is better than that of the dry nonwoven fabric.
- the present inventors have endeavored to apply the wet nonwoven fabric manufactured by the papermaking method to medical use, and thus provide a medical nonwoven fabric made of cellulose-based short fibers in which gelation occurs from optimum conditions for improving the nonwoven fabric's strength.
- a medical nonwoven fabric made of cellulose-based short fibers in which gelation occurs from optimum conditions for improving the nonwoven fabric's strength.
- the shape stability, ease of procedure and The present invention was completed by developing a composite nonwoven fabric or a colored nonwoven fabric for improving visibility during the procedure, and confirming the applicability as an anti-adhesion film using the same.
- An object of the present invention is to provide a medical nonwoven fabric in the form of a wet nonwoven fabric consisting of cellulose short fibers in which gelation occurs by papermaking.
- Another object of the present invention is to provide a method for producing the medical nonwoven fabric made of short cellulose-based fibers in which gelation occurs.
- Still another object of the present invention is to provide a method for manufacturing a medical composite nonwoven fabric capable of controlling the gelation rate on a wet nonwoven fabric made of cellulose short fibers in which gelation occurs.
- Another object of the present invention is to provide a medical use of the anti-adhesion film using a medical nonwoven fabric.
- the present invention provides a medical nonwoven fabric using a paper making process.
- a first preferred embodiment of the present invention provides a medical nonwoven fabric in the form of a wet-laid nonwoven made of cellulose-based short fibers in which gelation occurs.
- the cellulose short fibers are short fibers made of a cellulose material chemically treated from natural cellulose or regenerated cellulose.
- the wet nonwoven fabric made of short fibers has a micropores of 1 to 500 ⁇ m, preferably 1 to 200 ⁇ m, more preferably 1 to 100 ⁇ m, the gelation rate is controlled by the capillary phenomenon due to the micropores Can be.
- the size of the micropores may be adjusted without particular limitation depending on the intended use as long as it is within the above range.
- the single phase medical nonwoven fabric consisting of cellulose-based short fibers in which the gelation takes place may be colored with a biocompatible dye or pigment.
- a first nonwoven fabric layer in the form of a wet nonwoven fabric consisting of cellulose short fibers in which gelation occurs; And a second nonwoven layer made of a heterogeneous biodegradable polymer material that does not cause gelation compared to the nonwoven material.
- This laminated medical composite nonwoven fabric is provided.
- the composite non-woven fabric is further formed with a colored layer adhered to a biocompatible dye or pigment harmless to the human body, thereby improving visibility during the procedure.
- the colored layer may be colored on the first nonwoven fabric layer, but is preferably easy to be applied to the second nonwoven fabric layer.
- the wet nonwoven fabric made of short fibers on the first nonwoven fabric layer may have a micropores of 1 to 500 ⁇ m, thereby controlling the gelation rate.
- the medical composite nonwoven fabric of the second embodiment of the present invention is provided in a form in which the first nonwoven fabric layer and the second nonwoven fabric layer are fully laminated or partially laminated by ultrasonic bonding.
- the medical composite nonwoven fabric of the second embodiment of the present invention is a nonwoven fabric using a fiber produced from a biodegradable polymer.
- Preferred biodegradable polymeric materials may be homopolymers or copolymers of compounds selected from the group consisting of glycolide, glycolic acid, lactide, lactic acid, caprolactone, dioxanone, trimethylenecarbonate and ethylene glycol. More preferably, the second nonwoven layer is composed of a homopolymer or a copolymer prepared from glycolide or glycolic acid.
- the medical nonwoven fabric of the first embodiment or the second embodiment of the present invention can be applied to any one of medical applications selected from anti-adhesion, anti-air injection barrier membranes, hemostatic agents, cell culture supports or suture reinforcing fiber structures.
- the present invention is a method for producing a medical nonwoven fabric, 1) 0 to 50 parts by weight of a binder resin and 0 to 10 parts by weight of a biocompatible dispersant are kneaded and kneaded with respect to 100 parts by weight of natural cellulose or regenerated cellulose fibers, and 2)
- the present invention provides a method for producing a wet nonwoven fabric for medical use in the form of a wet nonwoven fabric made of cellulose-based short fibers in which gelation occurs by solvent treatment.
- the manufacturing method of the medical nonwoven fabric of the present invention may add a dispersant to improve the dispersibility in the wet solvent when manufacturing the wet nonwoven fabric, and adding a binder resin in the form of powder or fiber to improve the strength of the prepared nonwoven fabric It features.
- the binder resin that can be used is a polymer resin containing a hydroxyl group selected from polyvinyl alcohol or chitosan; Or any one polymer resin selected from the group consisting of homopolymers or copolymers prepared from glycolide, lactide, caprolactone, dioxanone, trimethylene carbonate.
- a preferred dispersant is any one selected from the group consisting of a polyethylene oxide-propylene oxide nonionic surfactant having a biocompatibility, a twin surfactant of a polysorbate component, and polyacrylamide. Can be used.
- the second nonwoven layer made of a biodegradable polymer material is placed on a first nonwoven fabric layer of a wet nonwoven fabric made of cellulose-based short fibers in which the gelation occurs. It can be produced by laminating the whole surface by, or by partially laminating by ultrasonic bonding.
- the method for manufacturing a medical composite nonwoven fabric of the present invention may further perform a coloring process using a dye or pigment-containing solution having biocompatibility that can be inserted into the body on the first nonwoven fabric layer.
- the method for producing a medical composite nonwoven fabric of the present invention is characterized by controlling the biodegradation rate of the biodegradable polymer by additionally performing a gamma irradiation step after the production of the second nonwoven fabric layer or the composite nonwoven fabric.
- the present invention provides a use as an anti-adhesion film in which prolonged adhesion is prevented.
- a medical nonwoven fabric in the form of a wet nonwoven fabric made of cellulose short fibers in which gelation is produced by a papermaking method, and a method of manufacturing the same, which can promote the gelation rate.
- Medical nonwoven fabric of the present invention is a porous thin film nonwoven fabric using a biocompatible material, it is possible to improve the convenience of the procedure by coloring the nonwoven fabric.
- the present invention by providing a composite nonwoven fabric of a composite of a heterogeneous material of the cellulosic material gelation and the biodegradable polymer material that does not gelation, medical composite non-woven fabric and the non-woven fabric that can maximize the stability and procedure convenience It is possible to provide a method for producing a medical nonwoven fabric that is easy to control the characteristics of micropores and a simple process.
- the present invention can provide a use as an anti-adhesion film using a single nonwoven fabric or a composite nonwoven fabric made of cellulose short fibers in which gelation occurs.
- FIG. 1 shows a manufacturing process diagram of a wet nonwoven fabric using a papermaking method
- FIG. 2 is an electron microscope measurement result of the surface of the wet nonwoven fabric made of the short fibers of Example 1 as a first embodiment of the medical nonwoven fabric of the present invention
- Example 4 is an electron microscope measurement result of the surface of the wet nonwoven fabric made of the short fibers of Example 3 as a first embodiment of the medical nonwoven fabric of the present invention
- FIG. 5 is a second embodiment of the medical nonwoven fabric of the present invention, schematically showing the structure of a partially laminated composite nonwoven fabric
- FIG. 6 is an electron microscope measurement result of the surface of the second nonwoven fabric of Example 4 as a second embodiment of the medical nonwoven fabric of the present invention
- Fig. 8 is a photograph of the surface of the second nonwoven fabric layer of Example 4 as a second embodiment of the medical nonwoven fabric of the present invention.
- Fig. 9 is a photograph of the surface of the first nonwoven fabric layer of Example 4 as a second embodiment of the medical nonwoven fabric of the present invention.
- Fig. 10 is a second embodiment of the medical nonwoven fabric of the present invention, schematically showing the structure of a composite nonwoven fabric laminated on the front surface;
- FIG. 11 is an electron microscope measurement result of the surface of the second nonwoven fabric of Example 5 as a second embodiment of the medical nonwoven fabric of the present invention.
- Example 13 is a surface photograph of the colored medical composite nonwoven fabric of Example 6 of the present invention.
- the present invention provides a medical nonwoven fabric having micropores in the form of a wet-laid nonwoven by a paper making process.
- a medical nonwoven fabric in the form of a wet nonwoven fabric made of cellulose short fibers comprising a cellulose material chemically treated from natural cellulose or regenerated cellulose material.
- the medical nonwoven fabric of the present invention is made of short fibers manufactured by the papermaking method, unlike conventional medical products limited to long fiber use, not only regenerated cellulose, but also short fibers such as natural cellulose can be utilized. Moreover, when the wet nonwoven fabric by the papermaking method of this invention is used, compared with the nonwoven fabric conventionally manufactured by the dry method, thin film is advantageous, and it is suitable for medical use.
- the wet nonwoven fabric of the present invention is a porous thin film nonwoven fabric having micropores, and the micropores can control the gelation rate faster by inducing capillary action.
- the pore size of the micropores does not exceed 1000 ⁇ m, it is not particularly limited, it may also be satisfied to the pore size inherent in the non-woven fabric formed between short fibers.
- the pore size of the wet nonwoven fabric of the present invention is 1 to 500 ⁇ m, it is preferable for medical purposes. If the pore size is less than 1 ⁇ m, the function of the micropores between the fibers is lowered, so that the absorption / absorption rate is lowered.
- the pore size exceeds 500 ⁇ m even if gelation of the material by moisture occurs, the inter-fiber pores become too large and the barrier properties tend to be inferior.
- the pore size of the nonwoven fabric of Example 2 which is fibrillated, may be smaller than the pore size of Example 3, even when nonwoven fabric having the same basis weight is used.
- a first nonwoven fabric layer in the form of a wet nonwoven fabric consisting of cellulose short fibers in which gelation occurs; And a second nonwoven layer made of a heterogeneous biodegradable polymer material in which gelation does not occur compared to the nonwoven material.
- This laminated medical composite nonwoven fabric is provided.
- the medical nonwoven fabric of the second embodiment of the present invention is a cellulose nonwoven fabric in which gelation occurs, and is intended to solve the problem that gelation occurs and is easily moved when a small amount of water is wet during the procedure, and it is difficult to catch with a facet or the like.
- the biodegradable polymer used for the second nonwoven fabric layer has a structure in which a material that is not gelled is compounded. .
- the biodegradable polymer used in the second nonwoven layer is preferably a biodegradable polymer material that does not cause gelation, compared to a cellulose-based material in which the gelation of the first nonwoven layer occurs, and examples thereof include glycolide, glycolic acid, and rock. It is to use a homopolymer of a compound selected from the group consisting of tide, lactic acid, caprolactone, dioxanone, trimethylene carbonate and ethylene glycol or a copolymer containing them.
- the biodegradable polymeric material of the second nonwoven layer is a homopolymer or copolymer prepared from glycolide or glycolic acid.
- FIG. 5 is a medical nonwoven fabric of a second embodiment of the present invention, which schematically illustrates a composite nonwoven fabric having a partially laminated layer structure, wherein the first nonwoven fabric layer in the form of a wet nonwoven fabric made of cellulose-based short fibers in which gelation occurs ( 10) on the second non-woven fabric layer 20 made of a biodegradable polymer material does not occur compared to the non-woven fabric material; This is a partially laminated composite nonwoven fabric.
- FIG. 6 is a polyglycolic acid (2).
- FIG. 7 shows a surface photograph of a carboxymethyl cellulose (CMC) nonwoven fabric of the first nonwoven fabric layer 10.
- the first nonwoven fabric layer 10 is in the form of a porous nonwoven fabric having micropores, and a fast gelation rate may be realized by capillary action.
- the second nonwoven fabric layer 20 has a pore shape, the shape stability before and after the procedure can be improved by supporting the first nonwoven fabric layer on which gelation has occurred without reducing the capillary phenomenon of the first nonwoven fabric layer. .
- FIG. 8 shows the second nonwoven fabric layer 20 side or FIG. 9 shows the first nonwoven fabric layer 10 side, and it can be observed that the nonwoven fabric is ultrasonically bonded in a predetermined pattern.
- FIG. 10 is another example of the medical nonwoven fabric of the second embodiment of the present invention, which schematically illustrates a composite nonwoven fabric having a laminated structure of a front surface, wherein the first nonwoven fabric is formed of a wet nonwoven fabric made of cellulose-based short fibers in which gelation occurs.
- the second nonwoven layer 20 made of a heterogeneous biodegradable polymer material that does not cause gelation compared to the nonwoven material; This is a composite nonwoven fabric in full laminated form.
- FIG. 11 is a second nonwoven fabric layer 20 of a polyglycolic acid (PGA) nonwoven fabric
- FIG. 12 is a first nonwoven fabric layer 10 of a carboxymethyl cellulose (CMC) nonwoven fabric.
- PGA polyglycolic acid
- CMC carboxymethyl cellulose
- the first nonwoven fabric layer 10 is observed in the micropores formed between the cellulose-based short fibers in which gelation occurs, resulting in a fast gelation rate due to the capillary phenomenon.
- the pore size of the micropores is preferably 1 to 500 ⁇ m, the efficient gelation rate is controlled.
- the second nonwoven layer 20 made of a biodegradable polymer material that does not cause gelation on the first nonwoven layer 10 which is easily gelled by water during the procedure, morphological stability and procedure convenience are increased. It is easy to cut to fit the size of the surgical site.
- the composite nonwoven fabric of the second embodiment can be irradiated with gamma rays to the second nonwoven fabric layer 20 or the final composite nonwoven fabric thus produced, thereby promoting biodegradation rate in vivo.
- FIG. 13 is a photograph showing that the medical composite nonwoven fabric of the first embodiment of the present invention is colored, and after preparing a nonwoven fabric of a cellulose-based material in which gelation occurs, a dye or pigment having biocompatibility is colored by a coating method or the like. Provide convenience.
- the dye or pigment can be selected from harmless substances known to the human body known in the art, and after the procedure, it is preferable to select and use the color of blood and complementary colors so as to easily identify whether the medical nonwoven fabric is attached to the organ and the attachment position. Do.
- a purple pigment is used, but is not limited thereto.
- the colored nonwoven fabric of the present invention can improve the convenience of the procedure by eliminating the problem that it is difficult to check whether the product is applied during the procedure due to the colorless / white product of the conventional medical product.
- the thickness of a colored layer is not limited, It will be possible if it is a grade which can improve visibility.
- the medical nonwoven fabric of the present invention is a porous thin film nonwoven fabric using a biocompatible material, and unlike the conventional anti-adhesion film, color can be provided, thereby improving the convenience of the procedure.
- the medical nonwoven fabric of the first and second embodiments of the present invention is applied to any one of medical uses selected from anti-adhesion, anti-air intake barrier membrane, hemostatic agent, cell culture support or suture reinforcing fiber structure. can do.
- the present invention provides a method for producing a medical nonwoven fabric.
- FIG. 1 illustrates a manufacturing process of a wet nonwoven fabric using a papermaking method.
- a papermaking method when manufacturing a nonwoven fabric using a papermaking method, it is difficult to manufacture a nonwoven fabric because of the smooth surface of the fabric. It is easy to fall off, and it is necessary to improve the strength of the nonwoven fabric.
- a method of fibrillation to prepare a nonwoven fabric and then pressing through calendaring is preferable.
- another method for improving the nonwoven fabric strength is to add a separate binder resin, the method of manufacturing a medical nonwoven fabric of the present invention by optimizing the composition for improving the optimum binder resin and dispersibility, It provides a single-phase nonwoven fabric manufacturing method that can be implemented by improving the shape stability.
- 1) 0 to 50 parts by weight of binder resin and 0 to 10 parts by weight of a biocompatible dispersant are kneaded with an aqueous solvent for kneading, and 2) the solvent is removed to obtain a short fiber nonwoven fabric.
- 3) provides a method for producing a medical nonwoven fabric is produced in the form of a wet nonwoven fabric consisting of cellulose-based short fibers in which the nonwoven fabric is subjected to a solvent treatment step.
- the binder resin usable above is a polymer resin containing a hydroxyl group selected from polyvinyl alcohol or chitosan; Or any one polymer resin selected from the group consisting of homopolymers or copolymers prepared from glycolide, lactide, caprolactone, dioxanone, trimethylene carbonate.
- the binder resin may be used in powder form or fiber form.
- binder resin it is preferable to contain 0-50 weight part of binder resin with respect to 100 weight part of cellulose material fibers, and when it exceeds 50 weight part, gelation by an oxidation process will not occur easily and it is unpreferable. More preferably, it contains 0-10 weight part of binder resins with respect to 100 weight part of cellulose material fibers.
- a biocompatible dispersant known to those skilled in the art may be used as a composition for increasing dispersibility in the method of manufacturing the nonwoven fabric.
- cationic surfactants include alkylammoniums such as alkyltrimethylammonium or alkyltriethylmonium, alkyldimethylbenzylammonium salts, phosphate amine salts and the like.
- Anionic surfactants include alkyl sulfates, alkylsulfonates, alkylcarboxylic acids, and also include sulfates of polyethoxylated derivatives of straight or branched chain aliphatic alcohols and carboxylic acids; Alkylbenzenes or alkylnaphthalene sulfonates and sulfates such as sodium octylbenzenesulfonate; Alkylcarboxylates such as dodecylcarboxylate; And alkali metal and (alkyl) ammonium salts of ethoxylated and polyethoxylated alkyl and aralkyl alcohol carboxylates.
- Amphoteric surfactants include alanine-based, imidazolium betaine-based, amidepropyl betaine-based, aminodipropionate and the like.
- nonionic surfactants include poly (ethylene oxide), (octaethylene glycol) monododecyl ether (C12EO8), (octaethylene glycol) monohexadecyl ether (C16EO8), poly (ethylene oxide) and poly (propylene oxide).
- poly (alkylene oxide) triblock copolymers such as poly (ethylene oxide) -poly (propylene oxide) -poly (ethylene oxide) (PEO-PPO-PEO) or inverse (PPO-PEO-PPO) ).
- any one selected from the group consisting of a polyethylene oxide-propylene oxide nonionic surfactant having a biocompatibility, a twin surfactant of a polysorbate component, and a polyacrylamide can be used.
- a polyethylene oxide-propylene oxide-based nonionic surfactant is used as the most preferable example, but is not limited thereto.
- the content of the dispersant is preferably 0 to 10 parts by weight based on 100 parts by weight of cellulose material fiber.
- the present invention after placing the second nonwoven fabric layer 20 made of a biodegradable polymer material on the first nonwoven fabric layer 10 in the form of a wet nonwoven fabric made of cellulose-based short fibers in which the gelation takes place, Provided is a method for producing a medical composite nonwoven fabric that is laminated all over.
- a second nonwoven fabric layer made of a biodegradable polymer material on the first nonwoven fabric layer 10 in the form of a wet nonwoven fabric made of cellulose-based short fibers in which the gelation of the present invention occurs ( After positioning 20), there is provided a method for producing a medical composite nonwoven fabric that is partially laminated by ultrasonic bonding.
- the manufacturing method of the composite nonwoven fabric which is partially laminated by ultrasonic bonding is performed by a simple ultrasonic bonding method, and the characteristics of the micropores of the nonwoven fabric can be easily controlled, rather than the front lamination method performed by the calendering method under high temperature and high pressure. It is more preferable to prevent the phenomenon that the pore size decreases rapidly [Figs. 5 and 6-9].
- the method for manufacturing a medical composite nonwoven fabric of the present invention may further perform a coloring process for coloring a harmless dye or pigment-containing solution on the first nonwoven fabric layer 10, wherein the method used in the coloring process is impregnated. , Coating or spraying.
- dyes / pigments which can be inserted into a human body [D & C violoet No. 2, D & C Green No. 6, etc.] can be attached by dipping or coating with a biodegradable resin that can form a film to allow dye / pigment to adhere to the nonwoven surface.
- a method of manufacturing a composite nonwoven fabric by producing a second nonwoven fabric layer using colored yarns is also possible.
- the method for manufacturing a medical composite nonwoven fabric of the present invention may further perform a gamma irradiation step after the manufacture of the second nonwoven fabric layer or after the production of the composite nonwoven fabric to control the biodegradation rate.
- the present invention provides a medical use as an anti-adhesion film using the medical nonwoven fabric or the medical composite nonwoven fabric.
- an anti-adhesion film in the form of a knit or a film is commercially available.
- an inter-fiber gap is too large and a region that is not blocked by gelation may occur.
- the knit anti-adhesion film may be manufactured in the form of knit only by using long fibers ( ⁇ ⁇ ).
- the anti-adhesion film using the nonwoven fabric of the present invention can control the fine pore size than the conventional knit form by using a wet nonwoven fabric made of short fibers by the papermaking method.
- the conventional film-type anti-adhesion film has no micropores and has a low absorption / absorption rate due to capillary action
- the anti-adhesion film using a single phase nonwoven fabric or composite nonwoven fabric of the present invention is formed between fibers on the first nonwoven fabric layer 10 By inducing capillary phenomena due to the micropores, it is possible to realize a faster gelation rate than the conventional film anti-adhesion film.
- the anti-adhesion film of the present invention may be provided with a color, thereby improving the convenience of the procedure.
- a crude solution was prepared by using a pulp solution of 2.0 g of wood pulp in 12 L of water, and sufficiently kneaded, and then a 50 g / m 2 nonwoven fabric was prepared using a hand sheet former.
- the prepared nonwoven fabric was calendered in a roll calender maintained at a temperature of 170 ° C. and a pressure of 500 psi to prepare a cellulose nonwoven fabric.
- the prepared cellulose nonwoven fabric was manufactured into a carboxymethyl cellulose (CMC) nonwoven fabric through a conventional chemical treatment process.
- CMC carboxymethyl cellulose
- the chemical treatment process impregnated 3g of the cellulose nonwoven fabric prepared in the above step into a mixed solution of 2-propanol 400ml and 400ml of ethanol, in the solution, 45% (w / v) sodium hydroxide solution in 800ml solution 36 ml was added to the prepared solution, followed by stirring for 15 minutes.
- the cellulose nonwoven fabric and MCA Mono chloroacetic acid
- MCA mono chloroacetic acid
- the mixing ratio of mono chloroacetic acid (MCA) to the cellulose nonwoven fabric was a molar ratio of 3: 1.
- the CMC nonwoven fabric was placed in 99.5% methanol and neutralized with acetic acid and stirred for 10 minutes.
- Nonwoven fabric was prepared.
- An initial solution was prepared using 1.2 g of wood pulp in 12 L of water and kneaded sufficiently, and then a 30 g / m 2 nonwoven fabric was prepared using a hand sheet former.
- the prepared nonwoven fabric was calendered into a roll calender maintained at a temperature of 100 ° C. and a pressure of 500 psi to prepare a cellulose nonwoven fabric.
- the prepared cellulose nonwoven fabric was manufactured into a carboxymethyl cellulose (CMC) nonwoven fabric through the chemical treatment process of Example 1.
- the prepared carboxymethyl cellulose nonwoven fabric was calendered at a pressure of 500 psi at room temperature, and the final average pore size was 12 ⁇ m.
- a carboxymethyl cellulose (CMC) nonwoven fabric was prepared.
- the nonwoven fabric was ultrasonically bonded at a speed of 2 m / min at 1.2 A current condition using an ultrasonic bonding machine. Only part of them was combined in a regular pattern.
- the polyglycolic acid (PGA) nonwoven fabric prepared above and the carboxymethylcellulose (CMC) nonwoven fabric prepared in Example 3 were laminated, calendered in a roll calender maintained at a temperature of 150 ° C. and a pressure of 500 psi, and averaged porosity.
- a carboxymethylcellulose-polyglycolic acid composite nonwoven fabric having a size of 10 ⁇ m was prepared.
- Example 1 0.2 wt% of a copolymer having a 30:70 molar ratio of glycolide and lactide (PGLA 370) using ethyl acetate as a solvent in the carboxymethyl cellulose (CMC) nonwoven fabric prepared in Example 1 Violet no. 2)
- a dip solution was coated with a mixed solution containing 0.03% by weight, that is, a pigmented mixed solution, followed by drying to prepare a colored carboxymethylcellulose nonwoven fabric.
- the present invention provides a medical nonwoven fabric in the form of a wet nonwoven fabric made of cellulose-based short fibers in which gelation of short fibers occurs by a papermaking method.
- the present invention by providing a colored medical non-woven fabric, it is possible to easily determine whether the coating position and the application position of the anti-adhesion film using the non-woven fabric, unlike the colorless or white conventional products during the procedure.
- the present invention provides a method for producing a medical nonwoven fabric is easy to control the characteristics of the micropores of the nonwoven fabric, the process is simple.
- the present invention provides a single-phase nonwoven fabric made of cellulose-based short fibers in which gelation occurs, or a multi-layer nonwoven fabric comprising them as an anti-adhesion film. It is possible to efficiently control the gelation rate by capillary action of the ball.
Abstract
Description
Claims (19)
- 젤화가 일어나는 셀룰로오스계 단섬유로 이루어진 습식 부직포 형태의 의료용 부직포.
- 제1항에 있어서, 상기 단섬유로 이루어진 습식 부직포가 1 내지 500㎛의 미세공을 가지는 다공성 박막형 부직포인 것을 특징으로 하는 상기 의료용 부직포.
- 제1항에 있어서, 상기 단섬유로 이루어진 습식 부직포가 생체적합성 염료 또는 안료로 착색된 특징으로 하는 상기 의료용 부직포.
- 젤화가 일어나는 셀룰로오스계 단섬유로 이루어진 습식 부직포 형태의 제1부직포층; 및상기 부직포 소재 대비 젤화가 일어나지 않는 이종의 생분해성 고분자 소재로 이루어진 제2부직포층; 이 합지된 의료용 부직포.
- 제4항에 있어서, 제2부직포층상에 생체적합성 염료 또는 안료가 착색된 착색층이 더 형성된 상기 의료용 부직포.
- 제4항에 있어서, 상기 단섬유로 이루어진 습식 부직포가 1 내지 500㎛의 미세공을 가지는 것을 특징으로 하는 상기 의료용 부직포.
- 제4항에 있어서, 상기 제1부직포층 및 제2부직포층이 전면 합지 또는 초음파 본딩에 의해 부분 합지된 구조인 것을 특징으로 하는 상기 의료용 부직포.
- 제4항에 있어서, 상기 생분해성 고분자 소재가 글리콜라이드, 글리콜산, 락타이드, 젖산, 카프로락톤, 다이옥사논, 트리메틸렌카보네이트 및 에틸렌글리콜로 이루어진 군에서 선택되는 화합물의 단일 중합체 또는 이들을 포함하는 공중합체인 것을 특징으로 하는 상기 의료용 부직포.
- 제4항에 있어서, 상기 제2부직포층이 글리콜라이드나 글리콜산으로부터 제조한 단독 중합체 또는 공중합체로 이루어진 것을 특징으로 하는 상기 의료용 부직포.
- 제1항 내지 제9항 중 어느 한 항에 있어서, 상기 의료용 부직포가 유착방지용, 공기 투입 방지 차폐막용, 지혈제용, 세포배양 지지체 또는 봉합 강화용 섬유구조체에서 선택되는 어느 하나의 의료용도에 적용되는 것을 특징으로 하는 상기 의료용 부직포.
- 셀룰로오스 소재 섬유 100중량부에 대하여, 바인더수지 0 내지 50중량부 및 생체적합성 분산제0 내지 10 중량부를 초조용매에 풀어 혼련하고,용매를 제거한 후 압착하여 단섬유상의 부직포를 수득하고,상기 부직포를 용매 처리공정에 의해 젤화가 일어나는 셀룰로오스계 단섬유로 이루어진 습식 부직포 형태로 제조되는 의료용 부직포의 제조방법.
- 제11항에 있어서, 상기 바인더수지가 폴리비닐알코올 또는 키토산에서 선택되는 하이드록시기를 함유하는 고분자 수지; 또는글리콜라이드, 락타이드, 카프로락톤, 다이옥사논, 트리메틸렌카보네이트로부터 제조된 단일 중합체 또는 공중합체로 이루어진 군에서 선택되는 어느 하나의 고분자 수지;인 것을 특징으로 하는 상기 의료용 부직포의 제조방법.
- 제12항에 있어서, 상기 바인더수지가 파우더 형태 또는 섬유 형태인 것을 특징으로 하는 상기 의료용 부직포의 제조방법.
- 제11항에 있어서, 상기 생체적합성 분산제가 폴리에틸렌옥사이드-프로필렌옥사이드계 비이온성 계면활성제, 폴리솔베이트성분의 트윈계 계면활성제 및 폴리아크릴아미드로 이루어진 군에서 선택되는 어느 하나인 것을 특징으로 하는 상기 의료용 부직포의 제조방법.
- 제11항의 젤화가 일어나는 셀룰로오스계 단섬유로 이루어진 습식 부직포 형태의 제1부직포층 상에,젤화가 일어나지 않는 생분해성 고분자 소재로 이루어진 제2부직포층을 위치시킨 후, 캘린더 방식에 의해 전면 합지시키는 것을 특징으로 하는 의료용 복합부직포의 제조방법.
- 제11항의 젤화가 일어나는 셀룰로오스계 단섬유로 이루어진 습식 부직포 형태의 제1부직포층 상에,젤화가 일어나지 않는 생분해성 고분자 소재로 이루어진 제2부직포층을 위치시킨 후, 초음파접합에 의해 부분 합지시키는 것을 특징으로 하는 의료용 복합부직포의 제조방법.
- 제15항 또는 제16항에 있어서, 제1부직포층 상에 생체적합성 염료 또는 안료 함유용액을 이용한 착색공정을 더 수행하는 것을 특징으로 하는 상기 의료용 복합부직포의 제조방법.
- 제15항 또는 제16항에 있어서, 제2부직포층 제조 후 또는 복합부직포 제조 후에 감마선 조사공정을 추가로 수행하는 것을 특징으로 하는 상기 의료용 복합부직포의 제조방법.
- 제1항 내지 제9항 중 어느 한 항의 의료용 부직포가 이용된 유착방지막.
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2009
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2010
- 2010-04-01 DE DE112010005001.5T patent/DE112010005001B4/de active Active
- 2010-04-01 US US13/517,356 patent/US20120270458A1/en not_active Abandoned
- 2010-04-01 WO PCT/KR2010/001999 patent/WO2011078442A1/ko active Application Filing
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2016
- 2016-02-05 US US15/016,810 patent/US10428458B2/en active Active
Patent Citations (4)
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EP0006647B1 (en) * | 1978-06-16 | 1983-07-20 | The Buckeye Cellulose Corporation | Disposable absorbent nonwoven structure |
US6123958A (en) * | 1991-09-10 | 2000-09-26 | Johnson & Johnson Medical, Inc. | Web dressing and method for its production |
US20050136769A1 (en) * | 2003-12-23 | 2005-06-23 | Astenjohnson, Inc. | Dewatering of a paper web in a press section of a papermaking machine |
KR100894377B1 (ko) * | 2004-07-01 | 2009-04-22 | 아사히 가세이 가부시키가이샤 | 셀룰로오스 부직포 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10428458B2 (en) | 2009-12-24 | 2019-10-01 | Korea Institute Of Industrial Technology | Medical nonwoven fabric, and preparation method thereof |
CN107187107A (zh) * | 2017-05-24 | 2017-09-22 | 盛亚红 | 一种用于高密度聚乙烯医用透析纸的高效率热封设备 |
Also Published As
Publication number | Publication date |
---|---|
US20120270458A1 (en) | 2012-10-25 |
KR101070358B1 (ko) | 2011-10-05 |
KR20110074006A (ko) | 2011-06-30 |
DE112010005001T5 (de) | 2013-01-03 |
US10428458B2 (en) | 2019-10-01 |
US20160153143A1 (en) | 2016-06-02 |
DE112010005001B4 (de) | 2021-07-15 |
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