WO2011063082A2 - Adhésifs à surface modifiée - Google Patents

Adhésifs à surface modifiée Download PDF

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Publication number
WO2011063082A2
WO2011063082A2 PCT/US2010/057168 US2010057168W WO2011063082A2 WO 2011063082 A2 WO2011063082 A2 WO 2011063082A2 US 2010057168 W US2010057168 W US 2010057168W WO 2011063082 A2 WO2011063082 A2 WO 2011063082A2
Authority
WO
WIPO (PCT)
Prior art keywords
adhesive
adhesive layer
electrically conductive
layer
substrate
Prior art date
Application number
PCT/US2010/057168
Other languages
English (en)
Other versions
WO2011063082A3 (fr
Inventor
Encai Hao
Audrey A. Sherman
Kevin R. Schaffer
Daniel W. Hennen
John P. Baetzold
Mark J. Pellerite
Michael L. Steiner
John J. Stradinger
Kalc C. Vang
John D. Le
Kanta Kumar
Original Assignee
3M Innovative Properties Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Company filed Critical 3M Innovative Properties Company
Publication of WO2011063082A2 publication Critical patent/WO2011063082A2/fr
Publication of WO2011063082A3 publication Critical patent/WO2011063082A3/fr

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    • B32B7/04—Interconnection of layers
    • B32B7/06—Interconnection of layers permitting easy separation
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    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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    • B32B7/04—Interconnection of layers
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/10—Adhesives in the form of films or foils without carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C—CHEMISTRY; METALLURGY
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    • C—CHEMISTRY; METALLURGY
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Definitions

  • the present disclosure relates generally to surface-modified adhesives, methods for modifying adhesive surfaces and articles prepared from surface-modified adhesive surfaces.
  • Adhesives have been used for a variety of marking, holding, protecting, sealing and masking purposes. Adhesives are used in a wide array of products including tapes, decorative articles, optical and electronic devices, medical uses, structural bonding, and the like. One type of adhesive, a pressure sensitive adhesive, is particularly desirable for many applications.
  • Pressure sensitive adhesives are well known to one of ordinary skill in the art to possess certain properties at room temperature including the following: (1) aggressive and permanent tack, (2) adherence with no more than finger pressure, (3) sufficient ability to hold onto an adherend, and (4) sufficient cohesive strength to be removed cleanly from the adherend.
  • Materials that have been found to function well as pressure sensitive adhesives are polymers designed and formulated to exhibit the requisite viscoelastic properties resulting in a desired balance of tack, peel adhesion, and shear strength.
  • methods of modifying the surface of an adhesive comprise providing an adhesive layer, providing a releasing substrate with an electrically conductive layer on the surface of the substrate, contacting the adhesive layer to the electrically conductive layer on the surface of the substrate, and removing the adhesive layer from the surface of the substrate, such that the electrically conductive layer at least partially adheres to the surface of the adhesive layer upon removal to form an electrically conductive adhesive surface.
  • Also disclosed are surface-modified adhesives comprising an adhesive layer comprising a first surface and a second surface wherein the first surface comprises an electrically conductive adhesive surface.
  • adhesive articles comprising an adhesive layer, wherein the adhesive layer comprises a first surface and a second surface, wherein the first surface comprises an electrically conductive adhesive surface, and a first substrate attached to the first surface of the adhesive layer.
  • Figure 1 shows a side view of an exemplary embodiment of this disclosure.
  • Figure 2 shows a side view of an exemplary embodiment of this disclosure. Detailed Description
  • modified adhesive surfaces methods for modifying adhesive surfaces and articles prepared from modified adhesive surfaces are presented.
  • the surface-modified adhesive comprises an electrically conductive layer on the adhesive surface, and yet the adhesive surface retains its adhesive properties.
  • the modification of the adhesive surface with an electrically conductive layer does not render the surface non-adhesive.
  • the adhesive surface is modified by contacting the surface of an adhesive layer to a releasing substrate with a substantially continuous electrically conductive layer on the surface of the releasing substrate and removing the adhesive layer from the releasing substrate such that at least a portion of the electrically conductive layer adheres to the adhesive surface.
  • the thus formed surface-modified adhesive layer is an electrically conductive adhesive layer.
  • adhesive refers to polymeric compositions useful to adhere together two adherends.
  • adhesives are heat activated adhesives, and pressure sensitive adhesives.
  • Heat activated adhesives are non-tacky at room temperature but become tacky and capable of bonding to a substrate at elevated temperatures. These adhesives usually have a Tg or melting point (Tm) above room temperature. When the temperature is elevated above the Tg or Tm, the storage modulus usually decreases and the adhesive become tacky.
  • Pressure sensitive adhesive compositions are well known to those of ordinary skill in the art to possess at room temperature properties including the following: (1) aggressive and permanent tack, (2) adherence with no more than finger pressure, (3) sufficient ability to hold onto an adherend, and (4) sufficient cohesive strength to be cleanly removable from the adherend.
  • Materials that have been found to function well as PSAs are polymers designed and formulated to exhibit the requisite viscoelastic properties resulting in a desired balance of tack, peel adhesion, and shear holding power. Obtaining the proper balance of properties is not a simple process.
  • substantially continuous electrically conductive layer refers to a continuous layer of electrically conductive polymer, electrically conductive particles or a combination thereof, disposed on a releasing substrate.
  • electrically conductive layer refers to a continuous or discontinuous layer on an adhesive layer that has conductive or antistatic properties.
  • conductive or antistatic mean that the concentration of conductive or antistatic particles at the adhesive surface is above the percolation threshold. The percolation threshold may be viewed as the point at which a dramatic drop in resistivity is observed for the adhesive layer, indicative of sufficient conductive particle concentration in the adhesive surface to provide a conductive pathway.
  • releasing surface refers to a surface that provides low adhesive strength to adhesives, especially pressure sensitive adhesives. Examples of releasing surfaces include the surfaces of release liners.
  • release liners refers to articles containing at least one release surface. When adhered to an adhesive layer, release liners adhere only lightly and are easily removed.
  • a release liner may be a single layer (with only the base layer) or it may be a multilayer construction (with one or more coatings or additional layers in addition to the base layer).
  • the release liner may also contain a structure such as a micro structure.
  • optically clear refers to an adhesive or article that has a high light transmittance over at least a portion of the visible light spectrum (about 400 to about 700 nanometers), and that exhibits low haze.
  • An optically clear material often has a luminous transmission of at least about 90 percent and a haze of less than about 2 percent in the 400 to 700 nm wavelength range. Both the luminous transmission and the haze can be determined using, for example, the method of ASTM-D 1003-95.
  • nanoparticle as used herein (unless an individual context specifically implies otherwise) will generally refer to particles, groups of particles, particulate molecules (i.e., small individual groups or loosely associated groups of molecules) and groups of particulate molecules that while potentially varied in specific geometric shape have an effective, or average, diameter that can be measured on a nanoscale (i.e., less than about 100 nanometers).
  • a wide variety of adhesives are suitable for forming the adhesive layer which can be modified to form the surface-modified adhesives of this disclosure.
  • Especially suitable are pressure sensitive adhesives.
  • the adhesive used is chosen to have properties suitable for the desired application.
  • Pressure sensitive adhesives useful in adhesive articles of the present disclosure include those based on natural rubbers, synthetic rubbers, styrene block copolymers, polyvinyl ethers, acrylics, poly-a-olefms, silicones, polyurethanes or polyureas.
  • Useful natural rubber pressure sensitive adhesives generally contain masticated natural rubber, from 25 parts to 300 parts of one or more tackifying resins to 100 parts of natural rubber, and typically from 0.5 to 2.0 parts of one or more antioxidants.
  • Natural rubber may range in grade from a light pale crepe grade to a darker ribbed smoked sheet and includes such examples as CV-60, a controlled viscosity rubber grade and SMR-5, a ribbed smoked sheet rubber grade.
  • Tackifying resins used with natural rubbers generally include, but are not limited to, wood rosin and its hydrogenated derivatives; terpene resins of various softening points, and petroleum-based resins, such as, the "ESCOREZ 1300" series of C5 aliphatic olefm- derived resins from Exxon, and "PICCOLYTE S” series, polyterpenes from Hercules, Inc.
  • Antioxidants are used to retard the oxidative attack on natural rubber, which can result in loss of the cohesive strength of the natural rubber adhesive.
  • antioxidants include, but are not limited to, amines, such as N-N'-di-B-naphthyl-l,4-phenylenediamine, available as "AGERITE D”; phenolics, such as 2,5-di-(t-amyl) hydroquinone, available as "SANTOVAR A", available from Monsanto Chemical Co., tetrakis [methylene 3-(3',5'-di- tert-butyl-4'-hydroxyphenyl)propionate]methane, available as "IRGANOX 1010" from Ciba-Geigy Corp., and 2-2'-methylenebis(4-methyl-6-tert butyl phenol), available as Antioxidant 2246; and dithiocarbamates, such as zinc dithiodibutyl carbamate.
  • Other materials can be added to natural rubber adhesives for special purposes, wherein the additives can include plasticizers, pigments, and curing agents to partially
  • Another useful class of pressure sensitive adhesives are those comprising synthetic rubber.
  • Such adhesives are generally rubbery elastomers, which are either self-tacky or non-tacky and require tackifiers.
  • Self-tacky synthetic rubber pressure sensitive adhesives include for example, butyl rubber, a copolymer of isobutylene with less than 3 percent isoprene, polyisobutylene, a homopolymer of isoprene, polybutadiene, such as "TAKTENE 220 BAYER” or styrene/butadiene rubber.
  • Butyl rubber pressure sensitive adhesives often contain an antioxidant such as zinc dibutyldithiocarbamate.
  • Polyisobutylene pressure sensitive adhesives do not usually contain antioxidants.
  • Synthetic rubber pressure sensitive adhesives, which generally require tackifiers, are also generally easier to melt process.
  • polystyrene/butadiene rubber comprise polybutadiene or styrene/butadiene rubber, from 10 parts to 200 parts of a tackifier, and generally from 0.5 to 2.0 parts per 100 parts rubber of an antioxidant such as "IRGANOX 1010".
  • An example of a synthetic rubber is "AMERIPOL 1011 A", a styrene/butadiene rubber available from BF Goodrich.
  • Tackifiers that are useful include derivatives of rosins such as "FORAL 85", a stabilized rosin ester from Hercules, Inc., the “SNOWTACK” series of gum rosins from Tenneco, and the “AQUATAC” series of tall oil rosins from Sylvachem; and synthetic hydrocarbon resins such as the “PICCOLYTE A” series, polyterpenes from Hercules, Inc., the "ESCOREZ 1300” series of C 5 aliphatic olefin-derived resins, the “ESCOREZ 2000” Series of C 9 aromatic/aliphatic olefm-derived resins, and polyaromatic C 9 resins, such as the "PICCO 5000" series of aromatic hydrocarbon resins, from Hercules, Inc.
  • synthetic hydrocarbon resins such as the "PICCOLYTE A” series, polyterpenes from Hercules, Inc., the "ESCOREZ 1300” series of C 5 aliphatic o
  • Styrene block copolymer pressure sensitive adhesives generally comprise elastomers of the A-B or A-B-A type, where A represents a thermoplastic polystyrene block and B represents a rubbery block of polyisoprene, polybutadiene, or poly(ethylene/butylene), and resins.
  • block copolymers useful in block copolymer pressure sensitive adhesives include linear, radial, star and tapered styrene -isoprene block copolymers such as "KRATON D1107P", available from Shell Chemical Co., and "EUROPRENE SOL TE 9110", available from EniChem Elastomers Americas, Inc.; linear styrene-(ethylene-butylene) block copolymers such as "KRATON G1657”, available from Shell Chemical Co.; linear styrene-(ethylene -propylene) block copolymers such as "KRATON G1750X”, available from Shell Chemical Co.; and linear, radial, and star styrene-butadiene block copolymers such as "KRATON D1118X", available from Shell Chemical Co., and "EUROPRENE SOL TE 6205", available from EniChem Elastomers Americas, Inc.
  • the polystyrene blocks tend to form domains in the shape of spheroids, cylinders, or plates that causes the block copolymer pressure sensitive adhesives to have two-phase structures. Resins that associate with the rubber phase generally develop tack in the pressure sensitive adhesive.
  • rubber phase associating resins examples include aliphatic olefm-derived resins, such as the "ESCOREZ 1300" series and the “WINGTACK” series, available from Goodyear; rosin esters, such as the “FORAL” series and the “STAYBELITE” Ester 10, both available from Hercules, Inc.; hydrogenated hydrocarbons, such as the "ESCOREZ 5000" series, available from Exxon; polyterpenes, such as the "PICCOLYTE A” series; and terpene phenolic resins derived from petroleum or terpentine sources, such as "PICCOFYN A100", available from Hercules, Inc. Resins that associate with the thermoplastic phase tend to stiffen the pressure sensitive adhesive.
  • Thermoplastic phase associating resins include polyaromatics, such as the "PICCO 6000" series of aromatic hydrocarbon resins, available from Hercules, Inc.; coumarone-indene resins, such as the "CUMAR” series, available from Neville; and other high-solubility parameter resins derived from coal tar or petroleum and having softening points above about 85° C, such as the "AMOCO 18" series of alpha-methyl styrene resins, available from Amoco, "PICCOVAR 130" alkyl aromatic polyindene resin, available from Hercules, Inc., and the "PICCOTEX” series of alpha-methyl styrene/vinyltoluene resins, available from Hercules.
  • polyaromatics such as the "PICCO 6000” series of aromatic hydrocarbon resins, available from Hercules, Inc.
  • coumarone-indene resins such as the "CUMAR” series,
  • Rubber phase plasticizing hydrocarbon oils such as, "TUFFLO 6056”, available from Lyondell Petrochemical Co., Polybutene-8 from Chevron, “KAYDOL”, available from Witco, and “SHELLFLEX 371", available from Shell Chemical Co.
  • pigments such as "IRGANOX 1010” and “IRGANOX 1076”, both available from Ciba-Geigy Corp., “BUTAZATE”, available from Uniroyal Chemical Co., "CYANOX LDTP”, available from American Cyanamid, and “BUTASAN”, available from Monsanto Co.
  • antiozonants such as "NBC", a nickel dibutyldithiocarbamate, available from DuPont
  • liquid rubbers such as "VISTANEX LMMH” polyisobutylene rubber
  • ultraviolet light inhibitors such as "IRGANOX 1010” and “TINUVIN P", available from Ciba-Geigy Corp.
  • Polyvinyl ether pressure sensitive adhesives are generally blends of homopolymers of vinyl methyl ether, vinyl ethyl ether or vinyl iso-butyl ether, or blends of homopolymers of vinyl ethers and copolymers of vinyl ethers and acrylates to achieve desired pressure sensitive properties.
  • homopolymers may be viscous oils, tacky soft resins or rubber-like substances.
  • Polyvinyl ethers used as raw materials in polyvinyl ether adhesives include polymers based on: vinyl methyl ether such as "LUTANOL M 40", available from BASF, and "GANTREZ M 574" and “GANTREZ 555", available from ISP Technologies, Inc.; vinyl ethyl ether such as “LUTANOL A 25", “LUTANOL A 50” and “LUTANOL A 100”; vinyl isobutyl ether such as “LUTANOL 130", “LUTANOL 160”, “LUTANOL IC”, “LUTANOL I60D” and “LUTANOL I 65D”; methacrylate/vinyl isobutyl ether/acrylic acid such as “ACRONAL 550 D", available from BASF.
  • vinyl methyl ether such as "LUTANOL M 40", available from BASF, and "GANTREZ M 574" and “GANTREZ 555”, available from ISP Technologies, Inc.
  • vinyl ethyl ether such as “LUTANOL A 25
  • Antioxidants useful to stabilize the polyvinylether pressure sensitive adhesive include, for example, "IONOX 30" available from Shell, “IRGANOX 1010” available from Ciba-Geigy, and antioxidant “ZKF” available from Bayer Leverkusen. Other materials can be added for special purposes as described in BASF literature including tackifiers, plasticizers and pigments.
  • Acrylic pressure sensitive adhesives generally have a glass transition temperature of about -20° C. or less and may comprise from 100 to 80 weight percent of a C3 -C12 alkyl ester component such as, for example, isooctyl acrylate, 2-ethylhexyl acrylate and n- butyl acrylate and from 0 to 20 weight percent of a polar component such as, for example, acrylic acid, methacrylic acid, ethylene -vinyl acetate units, N-vinylpyrrolidone, and styrene macromer.
  • the acrylic pressure sensitive adhesives comprise from 0 to 20 weight percent of acrylic acid and from 100 to 80 weight percent of isooctyl acrylate.
  • the acrylic pressure sensitive adhesives may be self-tacky or tackified.
  • Useful tackifiers for acrylics are rosin esters such as "FORAL 85", available from Hercules, Inc., aromatic resins such as “PICCOTEX LC-55WK”, aliphatic resins such as “PICCOTAC 95”, available from Hercules, Inc., and terpene resins such as a-pinene and B-pinene, available as "PICCOLYTE A-115" and “ZONAREZ B-100” from Arizona Chemical Co.
  • Other materials can be added for special purposes, including hydrogenated butyl rubber, pigments, and curing agents to vulcanize the adhesive partially.
  • Poly-a-olefm pressure sensitive adhesives also called a poly(l-alkene) pressure sensitive adhesives, generally comprise either a substantially uncrosslinked polymer or an uncrosslinked polymer that may have radiation activatable functional groups grafted thereon as described in U.S. Pat. No. 5,209,971 (Babu, et al).
  • the poly-a-olefm polymer may be self tacky and/or include one or more tackifying materials. If uncrosslinked, the inherent viscosity of the polymer is generally between about 0.7 and 5.0 dL/g as measured by ASTM D 2857-93, "Standard Practice for Dilute Solution Viscosity of Polymers". In addition, the polymer generally is predominantly amorphous.
  • Useful poly-a-olefm polymers include, for example, C3 -Ci g poly(l-alkene) polymers, generally C5 -C ⁇ 2 a- olefins and copolymers of those with C3 or Cg -Cg and copolymers of those with C3.
  • Tackifying materials are typically resins that are miscible in the poly-a-olefm polymer.
  • the total amount of tackifying resin in the poly-a-olefm polymer ranges from 0 to 150 parts by weight per 100 parts of the poly-a-olefm polymer depending on the specific application.
  • Useful tackifying resins include resins derived by polymerization of C5 to C9 unsaturated hydrocarbon monomers, polyterpenes, synthetic polyterpenes and the like. Examples of such commercially available resins based on a C5 olefin fraction of this type are "WINGTACK 95" and "WINGTACK 15" tackifying resins available from Goodyear Tire and Rubber Co.
  • hydrocarbon resins include “REGALREZ 1078” and “REGALREZ 1 126” available from Hercules Chemical Co., and “ARKON PI 15” available from Arakawa Chemical Co.
  • Other materials can be added for special purposes, including antioxidants, fillers, pigments, and radiation activated crosslinking agents.
  • Silicone pressure sensitive adhesives comprise two major components, a polymer or gum, and a tackifying resin.
  • the polymer is typically a high molecular weight polydimethylsiloxane or polydimethyldiphenylsiloxane, that contains residual silanol functionality (SiOH) on the ends of the polymer chain, or a block copolymer comprising polydiorganosiloxane soft segments and urea or oxamide terminated hard segments.
  • the tackifying resin is generally a three-dimensional silicate structure that is endcapped with trimethylsiloxy groups (OSiMe3) and also contains some residual silanol functionality.
  • tackifying resins examples include SR 545, from General Electric Co., Silicone Resins Division, Waterford, N.Y., and MQD-32-2 from Shin-Etsu Silicones of America, Inc., Torrance, Calif.
  • Manufacture of typical silicone pressure sensitive adhesives is described in U.S. Pat. No. 2,736,721 (Dexter).
  • Manufacture of silicone urea block copolymer pressure sensitive adhesive is described in U.S. Pat. No. 5,214,119 (Leir, et al).
  • Other materials can be added for special purposes, including pigments, plasticizers, and fillers. Fillers are typically used in amounts from 0 parts to 10 parts per 100 parts of silicone pressure sensitive adhesive.
  • fillers examples include zinc oxide, silica, carbon black, pigments, metal powders and calcium carbonate.
  • Polyurethane and polyurea pressure sensitive adhesives useful in this disclosure include, for example, those disclosed in WO 00/75210 (Kinning et al.) and in U.S. Patent Nos. 3,718,712 (Tushaus); 3,437,622 (Dahl); and 5,591,820 (Kydonieus et al).
  • the optically clear adhesive has a % Transmission of 95% or greater, or even 99% or greater. Also, in some embodiments the optically clear adhesive has a haze value of 3% or less, or even 1% or less. In some embodiments the optically clear adhesive has a clarity value of 99% or greater. In some embodiments, the adhesive is an optically clear pressure sensitive adhesive.
  • the pressure sensitive adhesive component can be a single pressure sensitive adhesive or the pressure sensitive adhesive can be a combination of two or more pressure sensitive adhesives.
  • Optically clear pressure sensitive adhesives useful in the present disclosure include, for example, those based on natural rubbers, synthetic rubbers, styrene block copolymers, (meth)acrylic block copolymers, polyvinyl ethers, polyolefms, and poly(meth)acrylates.
  • the terms (meth)acrylate and (meth)acrylic include both acrylates and methacrylates.
  • One particularly suitable class of optically clear pressure sensitive adhesives are (meth)acrylate-based pressure sensitive adhesives and may comprise either an acidic or basic copolymer.
  • the (meth)acrylate -based pressure sensitive adhesive is an acidic copolymer.
  • the proportion of acidic monomers is usually adjusted depending on the proportion of acidic copolymer present in the blends of the present disclosure.
  • the corresponding copolymer can be tailored to have a resultant glass transition temperature (Tg) of less than about 0°C.
  • Particularly suitable pressure sensitive adhesive copolymers are (meth)acrylate copolymers.
  • Such copolymers typically are derived from monomers comprising about 40%> by weight to about 98%> by weight, often at least 70%> by weight, or at least 85% by weight, or even about 90%> by weight, of at least one alkyl (meth)acrylate monomer that, as a homopolymer, has a Tg of less than about 0°C.
  • alkyl (meth)acrylate monomers examples include those in which the alkyl groups comprise from about 4 carbon atoms to about 12 carbon atoms and include, but are not limited to, n-butyl acrylate, 2-ethylhexyl acrylate, isooctyl acrylate, isononyl acrylate, isodecyl acrylate, and mixtures thereof.
  • vinyl monomers and alkyl (meth)acrylate monomers which, as homopolymers, have a Tg greater than 0°C, such as methyl acrylate, methyl methacrylate, isobornyl acrylate, vinyl acetate, styrene, and the like, may be utilized in conjunction with one or more of the low Tg alkyl (meth)acrylate monomers and copolymerizable basic or acidic monomers, provided that the Tg of the resultant (meth)acrylate copolymer is less than about 0°C.
  • (meth)acrylate monomers that are free of alkoxy groups.
  • Alkoxy groups are understood by those skilled in the art.
  • basic (meth)acrylate copolymers useful as the pressure sensitive adhesive matrix typically are derived from basic monomers comprising about 2% by weight to about 50% by weight, or about 5% by weight to about 30%> by weight, of a copolymerizable basic monomer.
  • Exemplary basic monomers include N,N- dimethylaminopropyl methacrylamide (DMAPMAm); N,N-diethylaminopropyl methacrylamide (DEAPMAm); ⁇ , ⁇ -dimethylaminoethyl acrylate (DMAEA); N,N- diethylaminoethyl acrylate (DEAEA); ⁇ , ⁇ -dimethylaminopropyl acrylate (DMAPA); ⁇ , ⁇ -diethylaminopropyl acrylate (DEAPA); ⁇ , ⁇ -dimethylaminoethyl methacrylate (DMAEMA); ⁇ , ⁇ -diethylaminoethyl methacrylate (DEAEMA); N,N-dimethylaminoethyl acrylamide (DMAEAm); ⁇ , ⁇ -dimethylaminoethyl methacrylamide (DMAEMAm); N,N- diethylaminoethyl acrylamide (DEAEAm);
  • tertiary amino-functionalized styrene e.g., 4-(N,N- dimethylamino)-styrene (DMAS), 4-(N,N-diethylamino)-styrene (DEAS)
  • DMAS 4-(N,N- dimethylamino)-styrene
  • DEAS 4-(N,N-diethylamino)-styrene
  • N- vinylpyrrolidone N-vinylcaprolactam
  • acrylonitrile N-vinylformamide
  • (meth)acrylamide and mixtures thereof.
  • acidic (meth)acrylate copolymers When used to form the pressure sensitive adhesive matrix, acidic (meth)acrylate copolymers typically are derived from acidic monomers comprising about 2% by weight to about 30%) by weight, or about 2%> by weight to about 15%> by weight, of a
  • copolymerizable acidic monomer examples include, but are not limited to, those selected from ethylenically unsaturated carboxylic acids, ethylenically unsaturated sulfonic acids, ethylenically unsaturated phosphonic acids, and mixtures thereof.
  • Such compounds include those selected from acrylic acid, methacrylic acid, itaconic acid, fumaric acid, crotonic acid, citraconic acid, maleic acid, oleic acid, beta- carboxyethyl acrylate, 2-sulfoethyl methacrylate, styrenesulfonic acid, 2-acrylamido-2- methylpropanesulfonic acid, vinylphosphonic acid, and the like, and mixtures thereof. Due to their availability, typically ethylenically unsaturated carboxylic acids are used.
  • the poly(meth)acrylic pressure sensitive adhesive matrix is derived from between about 1 and about 20 weight percent of acrylic acid and between about 99 and about 80 weight percent of at least one of isooctyl acrylate, 2-ethylhexyl acrylate or n-butyl acrylate composition. In some embodiments, the pressure sensitive adhesive matrix is derived from between about 2 and about 10 weight percent acrylic acid and between about 90 and about 98 weight percent of at least one of isooctyl acrylate, 2- ethylhexyl acrylate or n-butyl acrylate composition.
  • optically clear (meth)acrylate-based pressure sensitive adhesives are those which are (meth)acrylic block copolymers. Such copolymers may contain only (meth)acrylate monomers or may contain other co-monomers such as styrenes. Examples of such pressure sensitive adhesives are described, for example in US Patent No. 7,255,920 (Everaerts et al).
  • the pressure sensitive adhesive may be inherently tacky. If desired, tackifiers may be added to a base material to form the pressure sensitive adhesive.
  • Useful tackifiers include, for example, rosin ester resins, aromatic hydrocarbon resins, aliphatic
  • hydrocarbon resins and terpene resins.
  • Other materials can be added for special purposes, including, for example, oils, plasticizers, antioxidants, ultraviolet ("UV”) stabilizers, hydrogenated butyl rubber, pigments, curing agents, polymer additives, thickening agents, chain transfer agents and other additives provided that they do not reduce the optical clarity of the pressure sensitive adhesive.
  • oils plasticizers, antioxidants, ultraviolet (“UV”) stabilizers, hydrogenated butyl rubber, pigments, curing agents, polymer additives, thickening agents, chain transfer agents and other additives provided that they do not reduce the optical clarity of the pressure sensitive adhesive.
  • UV ultraviolet
  • the composition may contain a crosslinking agent.
  • crosslinking agent depends upon the nature of polymer or copolymer which one wishes to crosslink.
  • the crosslinking agent is used in an effective amount, by which is meant an amount that is sufficient to cause crosslinking of the pressure sensitive adhesive to provide adequate cohesive strength to produce the desired final adhesion properties to the substrate of interest.
  • the crosslinking agent is used in an amount of about 0.1 part to about 10 parts by weight, based on the total amount of monomers.
  • Multifunctional (meth)acrylates include tri(meth)acrylates and di(meth)acrylates (that is, compounds comprising three or two (meth)acrylate groups).
  • Multifunctional (meth)acrylates include tri(meth)acrylates and di(meth)acrylates (that is, compounds comprising three or two (meth)acrylate groups).
  • di(meth)acrylate crosslinkers that is, compounds comprising two (meth)acrylate groups
  • tri(meth)acrylates include, for example, trimethylolpropane
  • trimethylolpropane triacrylates tris(2-hydroxy ethyl)isocyanurate triacrylate, and pentaerythritol triacrylate.
  • Useful di(meth)acrylates include, for example, ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, 1 ,4-butanediol di(meth)acrylate, 1 ,6-hexanediol di(meth)acrylate, alkoxylated 1,6-hexanediol diacrylates, tripropylene glycol diacrylate, dipropylene glycol diacrylate, cyclohexane dimethanol di(meth)acrylate, alkoxylated cyclohexane dimethanol diacrylates, ethoxylated bisphenol A di(meth)acrylates, neopentyl glycol di
  • crosslinking agents contain functionality which is reactive with carboxylic acid groups on the acrylic copolymer.
  • crosslinkers include multifunctional aziridine, isocyanate and epoxy compounds.
  • aziridine-type crosslinkers include, for example 1,4- bis(ethyleneiminocarbonylamino)benzene, 4,4'- bis(ethyleneiminocarbonylamino)diphenylmethane, 1 ,8- bis(ethyleneiminocarbonylamino)octane, and l,l'-(l,3-phenylene dicarbonyl)-bis-(2- methylaziridine).
  • the aziridine crosslinker l,l'-(l,3-phenylene dicarbonyl)-bis-(2- methylaziridine) (CAS No. 7652-64-4), referred to herein as "Bisamide” is particularly useful.
  • Common polyfunctional isocyanate crosslinkers include, for example,
  • the adhesive may be coated onto a surface to form the adhesive layer.
  • the adhesive can be applied to films or sheeting products (e.g., optical, decorative, reflective, and graphical), labelstock, tape backings, release liners, and the like.
  • the substrate can be any suitable type of material depending on the desired application.
  • the adhesive layer can be formed by either continuous or batch processes.
  • An example of a batch process is the placement of a portion of the adhesive between a substrate to which the film or coating is to be adhered and a surface capable of releasing the adhesive film or coating to form a composite structure.
  • the composite structure can then be compressed at a sufficient temperature and pressure to form an adhesive layer of a desired thickness after cooling.
  • the adhesive can be compressed between two release surfaces and cooled to form an adhesive transfer tape useful in laminating applications.
  • Continuous forming methods include drawing the adhesive out of a film die and subsequently contacting the drawn adhesive to a moving plastic web or other suitable substrate.
  • a related continuous method involves extruding the adhesive and a coextruded backing material from a film die and cooling the layered product to form an adhesive tape.
  • Other continuous forming methods involve directly contacting the adhesive to a rapidly moving plastic web or other suitable preformed substrate. Using this method, the adhesive is applied to the moving preformed web using a die having flexible die lips, such as a rotary rod die.
  • the adhesive films or layers can be solidified by quenching using both direct methods (e.g., chill rolls or water baths) and indirect methods (e.g., air or gas impingement).
  • Adhesives can also be coated using a solvent-based method.
  • the adhesive can be coated by such methods as knife coating, roll coating, gravure coating, rod coating, curtain coating, and air knife coating.
  • the adhesive mixture may also be printed by known methods such as screen printing or inkjet printing.
  • the coated solvent- based adhesive is then dried to remove the solvent.
  • the coated solvent-based adhesive is subjected to elevated temperatures, such as those supplied by an oven, to expedite drying of the adhesive.
  • the thickness of the adhesive layer tends to be at least about 1 micrometer, at least 5 micrometers, at least 10 micrometers, at least 15 micrometers, or at least 20 micrometers.
  • the thickness is often no greater than about 200 micrometers, no greater than about 175 micrometers, no greater than about 150 micrometers, or no greater than about 125 micrometers.
  • the thickness can be 1 to 200 micrometers, 5 to 100 micrometers, 10 to 50 micrometers, 20 to 50 micrometers, or 1 to 15 micrometers.
  • the adhesive layer is contacted to a releasing substrate surface which contains a substantially continuous electrically conductive layer.
  • the releasing substrate may be any suitable releasing substrate such as a release liner or a substrate containing a releasing surface.
  • Suitable substrates containing a releasing surface include plates, sheets and film substrates.
  • Exemplary release liners include those prepared from paper (e.g., Kraft paper) or polymeric material (e.g., polyolefms such as polyethylene or polypropylene, ethylene vinyl acetate, polyurethanes, polyesters such as polyethylene terephthalate, and the like). At least some release liners are coated with a layer of a release agent such as a silicone- containing material or a fluorocarbon-containing material.
  • Exemplary release liners include, but are not limited to, liners commercially available from CP Film (Martinsville, Va.) under the trade designation "T-30" and "T-10" that have a silicone release coating on polyethylene terephthalate film.
  • the liner can have a micro structure on its surface that is imparted to the adhesive to form a microstructure on the surface of the adhesive layer. The liner can then be removed to expose an adhesive layer having a microstructured surface.
  • substrates containing a releasing surface include, for example, substrates that contain low surface energy surfaces such as TEFLON substrates, and polyolefm substrates such as polypropylene or polyethylene, or substrates which contain a release coating such as a silicone, olefmic, long alkyl chains, or fluorochemical coating.
  • the substantially continuous electrically conductive layer is not bond to the release surface, i.e. the substantially continuous electrically conductive layer can be easily removed (for example, peeled away) from the release surface by the adhesive layer.
  • This release liner comprises a release material, where the release material can be formed by irradiating (for example, by using an UV ray or electron beam) a release material precursor having shear storage modulus of about 1 x 10 2 Pa to about 3 x 10 6 Pa at 20°C and a frequency of 1 Hz.
  • the release material (after irradiation) has a contact angle of 15° or more, measured using a mixed solution of methanol and water (volume ratio 90: 10) having a wet tension of 25.4 mN/m.
  • suitable release material precursors include polymers having a shear storage modulus within the above-described range, such as, for example, a poly(meth)acrylic ester, a polyolefm, or a polyvinyl ether.
  • An example of a useful release material precursor is a copolymer having two kinds of acrylic monomer components such as, for example, a (meth)acrylate containing an alkyl group having from about 12 to about 30 carbon atoms (hereinafter referred to as a "first alkyl (meth)acrylate”) and a (meth)acrylate containing an alkyl group having from 1 to about 12 carbon atoms (hereinafter referred to as a "second alkyl (meth)acrylate”).
  • first alkyl (meth)acrylate containing an alkyl group having from about 12 to about 30 carbon atoms
  • second alkyl (meth)acrylate a (meth)acrylate containing an alkyl group having from 1 to about 12 carbon atoms
  • the first alkyl (meth)acrylate contains a relatively long alkyl side chain having from about 12 to about 30 carbon atoms that helps to decrease the surface energy of the release material. Accordingly, the first alkyl (meth)acrylate acts to impart a low release strength to the release material.
  • the first alkyl (meth)acrylate typically does not contain a polar group (for example, a carboxyl group, a hydroxyl group, or a nitrogen- or phosphorus-containing polar group) on the side chain. Accordingly, the first alkyl (meth)acrylate can impart relatively low release strength to the release material, not only at low temperatures, but also even after exposure to relatively high temperatures.
  • first alkyl (meth)acrylate having a long chain alkyl group examples include lauryl (meth)acrylate, cetyl (meth)acrylate, (iso)octadecyl (meth)acrylate, and behenyl (meth)acrylate.
  • the first alkyl (meth)acrylate is typically present in an amount of about 10% to about 90% by weight based on the total amount of the first alkyl (meth)acrylate and the second alkyl (meth)acrylate.
  • the second alkyl (meth)acrylate contains a relatively short alkyl side chain having from 1 to about 12 carbon atoms. This relatively short alkyl side chain decreases the glass transition temperature of the release material to about 30°C or less. In turn, the release material precursor is reduced in crystallinity and also in the shear storage modulus.
  • the second alkyl (meth)acrylate containing an alkyl group having 12 carbon atoms is the same as the first alkyl (meth)acrylate having 12 carbon atoms.
  • the release material can be formed from a release material precursor containing a homopolymer.
  • the second alkyl (meth)acrylate typically does not contain a polar group on the side chain. Therefore, similarly to the first alkyl (meth)acrylate, the second alkyl (meth)acrylate imparts a relatively low release strength, not only at a low temperature, but also at a relatively high temperature.
  • Suitable examples of the second (meth)acrylate having a short chain alkyl group include butyl (meth)acrylate, hexyl (meth)acrylate, octyl (meth)acrylate, and lauryl (meth)acrylate.
  • the second alkyl (meth)acrylate is typically present in an amount of about 10% to about 90% by weight based on the total amount of the first alkyl (meth)acrylate and the second alkyl (meth)acrylate.
  • the first and/or the second alkyl (meth)acrylates may be a (meth)acrylate having a branched side chain such as 2-heptylundecyl acrylate, 2-ethylhexyl (meth)acrylate, or isononyl (meth)acrylate.
  • (Meth)acrylates having a branched side chain reduce the crystallinity and therefore decrease the shear storage modulus and the surface energy.
  • a homopolymer consisting of a monomer component of alkyl (meth)acrylate containing a branched alkyl group having from about 8 to about 30 carbon atoms can be useful as the release material precursor.
  • a homopolymer of 2-heptylundecyl acrylate is a desirable release material precursor from the standpoint that the obtained release material can be reduced in surface energy and shear storage modulus.
  • a copolymer comprising a monomer component of alkyl (meth)acrylate containing a straight alkyl group and a monomer component of alkyl (meth) acrylate containing a branched alkyl group having from about 8 to about 30 carbon atoms can also be useful as the release material precursor.
  • a copolymer of stearyl acrylate and isostearyl acrylate is also a desirable release material precursor from the standpoint that the obtained release material can be reduced in surface energy and shear storage modulus.
  • Suitable release material precursors can be obtained by polymerization of alkyl (meth)acrylates in the presence of a polymerization initiator.
  • the polymerization initiator is not particularly limited as long as it can bring about the polymerization.
  • useful polymerization initiators include azobis compounds such as 2,2'- azobisisobutyronitrile, 2,2'-azobis(2-methylbutyronitrile), and 2,2'-azobis(2- methylvaleronitrile and peroxides such as benzoyl peroxide and lauroyl peroxide.
  • polymerization initiators are commercially available, such as 2,2'-azobisisobutyronitrile and 2,2'-azobis(2-methylbutyronitrile), which are available as V-60 and V-59 from Wako Pure Chemical Industries, Ltd. (Osaka, Japan).
  • the amount of polymerization initiator can vary, but the polymerization initiator is typically used in an amount of about 0.005% to about 0.5% by weight based on the weight of the monomer.
  • the polymerization of the above-described alkyl (meth)acrylates can be performed by any known method.
  • a solution polymerization method which involves dissolving the alkyl (meth)acrylates in a solvent and polymerizing them in solution can be used.
  • the polymer solution can be directly taken out and used after the completion of polymerization.
  • the solvent to be used is not particularly limited.
  • suitable solvents include ethyl acetate, methyl ethyl ketone, and heptane.
  • a chain transfer agent can also be incorporated into the solvent in order to control molecular weight.
  • the solution polymerization of the polymerizable composition can typically be performed at a reaction temperature of about 50°C to about 100°C for about 3 to about 24 hours in an atmosphere of an inert gas such as nitrogen.
  • the release material polymer When the release material precursor is a poly(meth)acrylate, the release material polymer typically has a weight average molecular weight of about 100,000 to about 2,000,000. If the weight average molecular weight is less than about 100,000, the release strength may increase, whereas if the weight average molecular weight exceeds about 2,000,000, the viscosity of the polymer solution may be increased during synthesis, making handling of the polymer solution relatively difficult.
  • the release material can be a polyolefm.
  • the polyolefin can be formed from an olefin monomer having from about 2 to about 12 carbon atoms.
  • useful olefin monomers include linear olefins such as ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1- heptene, 1-octene, 1-nonene, 1-decene, 1-undecene, 1-dodecene, and branched olefins such as 4-methyl- 1-pentene, 5 -methyl- 1-hexene, 4-methyl- 1-hexene, 7 -methyl- 1-octene, and 8 -methyl- 1-nonene.
  • a homopolymer of ethylene or propylene namely polyethylene and polypropylene
  • the shear storage modulus is typically decreased by copolymerization, for example, with 1-butene, 1-octene, or the like.
  • a random copolymer is desirable from the standpoint of reducing crystallinity.
  • a block copolymer can be used.
  • the weight average molecular weight is typically from about 100,000 to about 2,000,000.
  • Polyolefms having a high molecular weight can be produced by conventionally known polymerization methods such as, for example, ionic polymerization, generally coordinated anionic polymerization.
  • Examples of useful commercially available polyolefms include ethylene/propylene copolymers available from JSR Corporation (Tokyo, Japan) as EP01P and EP912P, and an ethylene/octene copolymer available from Dow Chemical as ENGAGE 8407.
  • the release material precursor can also be a polyvinyl ether having the above- described properties.
  • the starting monomer for a polyvinyl ether include linear or branched vinyl ethers such as n-butyl vinyl ether, 2-hexyl vinyl ether, dodecyl vinyl ether, and octadecyl vinyl ether.
  • polyoctadecyl vinyl ether does not satisfy the above-described physical properties for the shear storage modulus. Therefore, when using octadecyl vinyl ether, the shear storage modulus is typically decreased by copolymerization, for example, with 2-ethylhexyl vinyl ether.
  • a random copolymer is desirable from the standpoint of reducing crystallinity.
  • a block copolymer can be used.
  • the weight average molecular weight is typically from about 100,000 to about 2,000,000.
  • the polyvinyl ether can be produced by ionic polymerization such as, for example, by cationic polymerization.
  • the release material precursor can be provided on a liner substrate, generally a liner substrate comprising polyester, polyolefm, or paper.
  • the release material precursor can then be subjected to a treatment of radiation, for example, by using an electron beam or UV rays.
  • the release material precursor generally has no polar functional groups such as carboxyl groups, hydroxyl groups, or amide groups. Therefore, it would be expected that the release material precursor would exhibit poor anchoring to the liner substrate. However, despite the absence of a polar functional group in the release material precursor, the anchoring between the liner substrate and the release material can be increased by treatment with radiation.
  • the release liner can be manufactured as follows.
  • a solution of the release material precursor can be diluted with a diluent, for example, containing at least one of ethyl acetate, butyl acetate, methyl ethyl ketone, methyl isobutyl ketone, hexane, heptane, toluene, xylene, and methylene chloride, and then coated on a liner substrate to a predetermined thickness, thereby forming a release material precursor layer on the liner substrate.
  • the diluent can be the same as or different from the solvent used in the solution polymerization.
  • liner substrates examples include plastics such as polyesters
  • the thickness of the release material precursor depends on the type of liner substrate but is generally from about 0.01 to about 1 micrometer (typically, from about 0.05 to about 0.5 micrometer).
  • the release material precursor can be irradiated by, for example, an electron beam or ultraviolet ray.
  • the irradiation is typically performed under an inert gas such as nitrogen.
  • the absorbed dose depends on the thickness and composition of the release material precursor layer and is usually from about 1 to about lOOkGy. If an ultraviolet ray is used, the irradiation energy of the release material precursor layer is usually from about 10 to about 300 mJ/cm 2 (typically, from about 20 to about 150 mJ/cm 2 ).
  • an acrylic release agent precursor which comprises a poly(meth)acrylate ester having a group capable of being activated by ultraviolet radiation (also referred to as "an ultraviolet active group”) and has a shear storage modulus of about 1 x 10 2 to about 3 x 10 6 Pa at 20° C and a frequency of 1 Hz.
  • the acrylic release agent precursor after irradiation with ultraviolet radiation, has a contact angle of about 15° or more to a mixed solution of methanol and water (volume ratio of 90:10) having a wetting tension of 25.4 mN/m.
  • the acrylic release agent precursor can be a polymer composition comprising a polymer such as a poly(meth)acrylate ester having an ultraviolet active group.
  • the poly(meth)acrylate is, for example, a copolymer formed from a first alkyl (meth)acrylate as described above, a second alkyl (meth)acrylate as described above, and a (meth)acrylate ester having an ultraviolet active group.
  • Suitable first alkyl (meth)acrylates containing a long alkyl side chain for the acrylic release agent precursor include lauryl (meth)acrylate, cetyl (meth)acrylate, stearyl (meth)acrylate, and behenyl (meth)acrylate.
  • the copolymer typically contains the first alkyl (meth)acrylate or second alkyl (meth)acrylate in an amount from about 10 to about 90% by weight based on the total weight of the first and second alkyl (meth)acrylates.
  • the poly (meth)acrylate ester can also be derived from a monomer component containing an alkyl (meth)acrylate having a branched alkyl group having from about 8 to about 30 carbon atoms and a (meth)acrylate ester having an ultraviolet active group.
  • suitable alkyl (meth)acrylate having a branched alkyl group include 2- ethylhexyl (meth)acrylate, 2-hexyldodecyl acrylate, 2-heptylundecyl acrylate, 2-octyldecyl acrylate, and isononyl (meth)acrylate.
  • Such a (meth)acrylate having a branched side chain can reduce the shear storage modulus and surface energy by lowering the crystallinity.
  • the acrylic release agent precursor it is not necessary for the acrylic release agent precursor to contain two components such as a first alkyl (meth)acrylate and a second alkyl (meth)acrylate described above if it has a branched alkyl group having from about 8 to about 30 carbon atoms.
  • the polymer of 2-hexyldecyl acrylate or 2-octyldecyl acrylate can reduce the surface energy of the release agent.
  • the monomer component has no polar groups on the side chain.
  • the monomer component may, for example, have a polar functional group on the side chain as long as the acrylic release agent precursor has a shear storage modulus as described above.
  • the poly(meth)acrylate ester has an ultraviolet active group.
  • This ultraviolet active group can generate a free radical in the acrylic release agent precursor by irradiation with ultraviolet radiation.
  • the generated free radical promotes crosslinking of the acrylic release agent precursor and adhesion to the liner substrate, resulting in an improvement in adhesion between the liner substrate and the release agent.
  • the amount of the acrylic release agent precursor can generate a free radical in the acrylic release agent precursor by irradiation with ultraviolet radiation.
  • the generated free radical promotes crosslinking of the acrylic release agent precursor and adhesion to the liner substrate, resulting in an improvement in adhesion between the liner substrate and the release agent.
  • (meth)acrylate ester having an ultraviolet active group is within a range of about 0.01 to about 1% by weight of polymer.
  • the ultraviolet active group is not specifically limited, but is generally derived from benzophenone or acetophenone.
  • Introduction of the ultraviolet active group into the poly(meth)acrylate ester can be conducted by incorporating a (meth)acrylate ester having an ultraviolet active group as a monomer component and polymerizing the monomer component containing the (meth)acrylate ester.
  • the polymer of the acrylic release agent precursor generally has a weight-average molecular weight within a range from about 100,000 to about 2,000,000.
  • the monomer component described above can be polymerized in the presence of a polymerization initiator to form an acrylic release agent precursor.
  • the polymerization is carried out in solution.
  • Solution polymerization can typically be conducted in the state where the monomer component is dissolved in a solvent, together with the polymerization initiator, in an atmosphere of an inert gas such as nitrogen at about 50° to about 100°C.
  • Solvents such as, for example, ethyl acetate, methyl ethyl ketone, or heptane can be used.
  • the molecular weight of the polymer can be controlled by adding a chain transfer agent to the solvent.
  • the polymerization initiator is not specifically limited.
  • an azobis compound such as 2,2'-azobisisobutyronitrile, 2,2'-azobis(2-methylbutyronitrile) or 2,2'- azobis(2,4-dimethylvaleronitrile), dimethyl 2,2'-azobis(2-methylpropionate) or a peroxide such as benzoyl peroxide or lauroyl peroxide can be used as the polymerization initiator.
  • the polymerization initiator is used in the amount within a range from 0.005 to 0.5% by weight based on the total weight of the monomer component.
  • the acrylic release agent precursor as described above is converted into an acrylic release agent by irradiating with ultraviolet radiation, after the precursor is coated on a liner substrate.
  • the acrylic release agent is formed on the liner substrate in the thickness within a range from 0.01 to 1 micrometer.
  • the acrylic release agent is generally obtained by irradiating with ultraviolet radiation after coating with the acrylic release agent precursor.
  • the acrylic release agent adheres to the liner substrate by the irradiation with ultraviolet radiation, even though the acrylic release agent typically has no polar functional group.
  • the liner substrate can be, for example, a film made of plastic such as polyester or polyolefin (for example, polyethylene terephthalate, polyethylene naphthalate or polybutylene terephthalate) or a paper.
  • Typical thickness of the liner substrate is within a range from about 10 to about 300 micrometers.
  • the acrylic release agent precursor is produced by solution polymerization as described above and exists in the state of a polymer solution. Therefore, the liner substrate can be coated with the polymer solution in a thickness typically within a range from about 0.01 to about 1 micrometer (typically from 0.05 to 0.5 micrometer), using coating means such as a bar coater. If necessary, the polymer solution can be applied after diluting with a diluent until a predetermined viscosity is achieved.
  • diluent examples include ethyl acetate, butyl acetate, methyl ethyl ketone, methyl isobutyl ketone, hexane, heptane, toluene, xylene, and methylene chloride.
  • the acrylic release agent precursor applied as described above is converted into an acrylic release agent by irradiation with ultraviolet radiation.
  • the dose of irradiation with ultraviolet radiation varies depending on the kind and structure of the poly(meth)acrylate, but can usually be a low dose within a range from 10 to 150 mJ/cm 2 .
  • Suitable materials include, for example, conductive polymers, graphene sheets, and polymers modified with conductive additives.
  • conductive additives include, for example, one dimensional conductive additives such as nanowires, nanorods, or nanotubes; metal or metal oxide nanoparticles; and carbon nanoparticles.
  • Graphene sheets are one-atom thick planar sheets of sp 2 -bonded carbon atoms that are densely packed in a honeycomb crystal lattice. Graphite consists of many graphene sheets stacked together.
  • Figure 1 shows a side view of construction 100 comprising releasing substrate 110 and a substantially continuous electrically conductive layer 120 disposed on the releasing substrate 110.
  • Releasing substrate 110 and substantially continuous electrically conductive layer 120 are not drawn to scale.
  • a precursor solution or mixture may be coated or printed onto the release surface and allowed to either dry or cure to form the substantially continuous electrically conductive layer.
  • the precursor solution or mixture may be a solution, suspension, dispersion, or 100% solids mixture.
  • the precursor is a suspension or dispersion of a conductive polymer or modified conductive polymer in liquid media.
  • the liquid media typically are water, a water miscible solvent or a combination thereof.
  • the precursor mixture can be coated onto the release surface using any suitable coating technique such as, for example, knife coating, roll coating, gravure coating, rod coating, curtain coating, and air knife coating.
  • the precursor mixture may also be printed by known methods such as screen printing and inkjet printing.
  • the coating is typically then dried to remove the liquid media.
  • the coating is subjected to increased temperatures such as supplied by an oven (e.g. a forced air oven) in order to expedite the drying.
  • Graphene layers could be deposited onto the releasing substrate by, for example, buffing graphite onto the releasing substrate resulting in layers of graphene on the releasing substrate.
  • the substantially continuous electrically conductive layer may be a very thin layer of conductive polymer.
  • conductive polymers include polyaniline and derivatives thereof, polypyrrole, and polythiophene and derivatives thereof.
  • PDOT poly(ethylenedioxythiophene)
  • PES poly(styrenesulfonic acid)
  • the conductive polymer may contain additives.
  • additives may be conductive particles such as one dimensional conductive particles like nanowires, nanorods, and nanotubes; metal or metal oxide nanoparticles; and carbon nanoparticles.
  • the additives may be added to the conductive polymer as dry powders or as solutions or dispersions.
  • Suitable one-dimensional conductive materials include nanowires, nanorods, and nanotubes.
  • Such conductive materials include silver nanowires (as described in Y. Sun, B. Gates, B. Mayers, and Y. Xia, Nanoletters, 2002, 2, 165-168) and those disclosed in the PCT Patent Publication WO 2007/022226 (Alden et al.), vanadium pentoxide nanowires, and carbon nanotubes (CNT).
  • CNT dispersions include CNTD-294 (17% wt CNT in methyl ethyl ketone), CNTD-268 (13% wt CNT in isopropanol), CNTDW-80 (11.5% wt CNT in water), CNTD-262 (1% wt CNT in water), CNTD-260 (1% wt CNT in isopropanol), CNTD-272 (1% wt CNT in methyl ethyl ketone), and CNTD-253 (1% wt in ethanol), from Mikuni-Color Ltd. Hyogo, Japan.
  • Suitable conductive or semi-conductive particles include metal and metal oxide nanoparticles. Such nanoparticles typically have a particle size or associated particle size of greater than 1 nm and less than 200 nm.
  • Conductive particles are generally metal nanoparticles, such as silver and gold, and binary metal oxides doped with appropriate donor heteroatoms or containing oxygen deficiencies.
  • Suitable conductive binary metal oxides may comprise: zinc oxide, titania, tin oxide, alumina, indium oxide, magnesia, zirconia, barium oxide, molybdenum trioxide, tungsten trioxide, and vanadium pentoxide.
  • Particularly useful doped conductive metal oxide granular particles include Sb-doped tin oxide, Al-doped zinc oxide, In-doped zinc oxide, and Sb-doped zinc oxide.
  • Metal oxide particles may also include antistatic particles.
  • antistatic particles are commercially available as water-based and solvent-based dispersions.
  • Antimony tin oxide (ATO) nanoparticle dispersions that can be used include a dispersion available from Air Products under the trade designation "NANO ATO S44A” (25 wt-% solids, water), 30 nm and 100 nm (20 wt-% solids, water) ATO dispersions available from Advanced Nano Products Co. Ltd.
  • ATO sols (30 wt-% in isopropanol) also available from ANP, a dispersion available from Keeling & Walker Ltd under the trade designation "CPM10C” (19.1 wt-% solids), and a dispersion commercially available from Ishihara Sangyo Kaisha, Ltd under the trade designation "SN-100 D” (20 wt-%) solids).
  • Antimony zinc oxide (AZO) sols (20 nm, 20.8 wt-% solids) are available from Nissan Chemical America, Houston TX under the trade designations "CELNAX CX- Z210IP” (in isopropanol), “CELNAX CX-Z300H” (in water), “CELNAX CX-Z401M”(in methanol), and “CELNAX CX-Z653M-F” (in methanol).
  • suitable carbon nanoparticles include, for example, suspensions of carbon black particles such as aqueous carbon black dispersions commercially available from Solution Dispersions under the trade names AJACK BLACK and AQUABLAK (printable formulations).
  • the substantially continuous electrically conductive layer when present on the releasing substrate, is very thin relative to the thickness of the adhesive layer.
  • the substantially continuous electrically conductive layer has an average thickness of from about 10 nanometers to about 10 micrometers. In some embodiments the thickness is 10 nanometers to 1 micrometer, or 10 nanometers to about 500 nanometers, or even 100 nanometers to 500 nanometers. In some embodiments, especially in embodiments where it is desirable that the electrically conductive layer provide antistatic properties to the surface, the thickness can be even less than 10 nanometers, such as 2-9 nanometers, 2-5 nanometers, or even 2-3 nanometers.
  • a surface-modified adhesive layer can be prepared by contacting an adhesive layer to a substantially continuous electrically conductive layer on a releasing substrate.
  • an electrically conductive adhesive is produced. Removal of the adhesive may be done quickly after the adhesive layer contacts the substantially continuous electrically conductive layer or the releasing substrate/substantially continuous electrically conductive/adhesive layer construction may remain together for extended periods of time, allowing for the construction to be transported to a different location before the modified adhesive layer is produced, for example.
  • the electrically conductive adhesive surface can have a wide range of surface conductivity values depending upon the desired use of the adhesive article. For example, if surface antistatic properties are desired, much lower surface conductivity values are suitable than for surfaces for which it is desirable that the surface be surface conductive.
  • the conductivity of the adhesive surface is in the range of from about 1 x 10 11 ohms/square to about 100 ohms/square. In some embodiments, the conductivity range is from about 1 x 10 9 ohms/square to 250 ohms/square or 1 x 10 7 ohms/square to 250 ohms/square or even 5,000 ohms/square to 250 ohms/square.
  • Figure 2 shows a side view of construction 200 comprising releasing substrate 210, substantially continuous electrically conductive layer 220 disposed on the releasing substrate 210, adhesive layer 230, and optional substrate layer 240.
  • Optional substrate layer 240 can be, for example, a tape backing, a film, etc.
  • multilayer adhesive articles Such articles may be prepared by adhering the surface modified adhesive layer to a variety of different substrates.
  • multilayer adhesive articles can be prepared directly as the surface modified adhesive layer is prepared by adding another layer between the releasing substrate and the electrically conductive layer.
  • Such techniques are presented in, for example, PCT Publication WO 2009/070643 (Condon et al.).
  • a non-adhesive continuous layer is formed on the releasing surface of the releasing substrate. This non-adhesive continuous layer may be prepared by lamination of a film to the releasing surface or by applying a coating to the releasing surface.
  • a coating may be supplied as a solution, dispersion, or 100% solids composition and may be a curable or a cured composition.
  • the coating may be applied to the release surface using any suitable coating technique such as, for example, knife coating, roll coating, gravure coating, rod coating, curtain coating, and air knife coating.
  • the coating may also be printed by known methods such as screen printing and inkjet printing. Additionally, 100% solids coatings may be applied using, for example, hot melt coating techniques. After application of the coating, the coating may be dried and/or cured if desired. Examples of suitable coatings include, for example, hard coats, antireflective coatings, antiglare coatings, and the like.
  • the coatings are thin coatings of about 1-25 micrometers or even 1-10 micrometers or even 2-5 micrometers.
  • To the non-adhesive continuous layer on the release surface is applied the electrically conductive layer using the techniques described above.
  • the adhesive layer can at least partially penetrate the electrically conductive layer and adhere to the non-adhesive continuous layer.
  • the adhesive layer is removed, not only the particulate layer but also the continuous non-adhesive layer is at least partially adhered to the adhesive layer and removed from the releasing substrate.
  • An advantage of this embodiment is that it permits the preparation of adhesive articles which contain a surface- modified adhesive layer, without having to remove the surface-modified adhesive layer from the releasing surface and re-adhering it to a substrate.
  • the adhesive article is prepared at the same time as the surface-modified adhesive layer is prepared.
  • the surface-modified adhesive layer of the present disclosure may be used to prepare a variety of adhesive articles.
  • adhesive articles comprise at least 3 layers: substrate layer- 1 /adhesive layer/substrate layer-2.
  • the articles may also include additional layers.
  • the adhesive layer is a surface-modified adhesive layer wherein the surface modification is on the adhesive surface adhered to substrate layer-2.
  • Substrate layer- 1 may be a film, substrate or release liner.
  • the choice of film, substrate or release liner may depend upon the desired application for the surface-modified adhesive layer.
  • suitable films include sheeting products (e.g., decorative, reflective, and graphical), label stock, tape backings (e.g., polymeric films, metal films, paper, creped paper, foams, and the like), and optical films.
  • Suitable substrates can contain polymeric materials, glass materials, ceramic materials, metal-containing materials (e.g., metals or metal oxides), or a combination thereof.
  • the substrate can include multiple layers of material such as a support layer, a primer layer, a hard coat layer, a decorative design, and the like.
  • exemplary release liners include those prepared from paper (e.g., Kraft paper) or polymeric material (e.g., polyolefins such as polyethylene or polypropylene, ethylene vinyl acetate, polyurethanes, polyesters such as polyethylene terephthalate, and the like). At least some release liners are coated with a layer of a release agent such as a silicone- containing material or a fluorocarbon-containing material.
  • Exemplary release liners include, but are not limited to, liners commercially available from CP Film (Martinsville, Va.) under the trade designation "T-30" and "T-10" that have a silicone release coating on polyethylene terephthalate film.
  • the liner can have a micro structure on its surface that is imparted to the adhesive to form a microstructure on the surface of the adhesive layer. The liner can then be removed to expose an adhesive layer having a microstructured surface.
  • the surface-modified adhesive layer may be applied to a variety of substrate layer-2 surfaces to form articles.
  • Substrate layer-2 may be a film, substrate or release liner as described above for substrate layer- 1.
  • substrate layer-2 comprises an adhesive layer.
  • This adhesive layer (called adhesive layer-2) may be the same adhesive as the adhesive layer or it may be different. Additionally, adhesive layer-2 may be surface modified or non- surface-modified.
  • the adhesive layers may be the same or different, typically they are the same. In these embodiments, the conductive layer is sandwiched between two layers of adhesive and no longer resides on the adhesive surface.
  • the surface-modified adhesive layer may be used to make optical articles or optical elements.
  • optical element refers to an article that has an optical effect or optical application.
  • the optical elements can be used, for example, in electronic displays, architectural applications, transportation applications, projection applications, photonics applications, and graphics applications. Suitable optical elements include, but are not limited to, screens or displays, touch panels, cathode ray tubes, polarizers, reflectors, and the like.
  • optical film refers to a film that can be used to produce an optical effect.
  • the optical films are typically polymer-containing films that can be a single layer or multiple layers.
  • the optical films are flexible and can be of any suitable thickness.
  • the optical films often are at least partially transmissive, reflective, antireflective, polarizing, optically clear, or diffusive with respect to some wavelengths of the electromagnetic spectrum (e.g., wavelengths in the visible, ultraviolet, or infrared regions of the electromagnetic spectrum).
  • Exemplary optical films include, but are not limited to, visible mirror films, color mirror films, solar reflective films, infrared reflective films, ultraviolet reflective films, brightness enhancement films, reflective polarizer films such as dual brightness enhancement films, absorptive polarizer films, optically clear films, tinted films, and antireflective films.
  • Some optical films have multiple layers such as multiple layers of polymer- containing materials (e.g., polymers with or without dyes) or multiple layers of metal- containing material and polymeric materials. Some optical films have alternating layers of polymeric material with different indexes of refraction. Other optical films have alternating polymeric layers and metal-containing layers. Exemplary optical films are described in the following patents: U.S. Pat. No. 6,049,419 (Wheatley et al); U.S. Pat. No. 5,223,465 (Wheatley et al); U.S. Pat. No. 5,882,774 (Jonza et al); U.S. Pat. No. 6,049,419 (Wheatley et al); U.S. Pat.
  • Substrates in optical articles or optical elements can have a variety of functions such as, for example, providing flexibility, rigidity, strength or support, reflectivity, antireflectivity, polarization, or transmissivity (e.g., selective with respect to different wavelengths). That is, the substrate can be flexible or rigid; reflective or non-reflective; visibly clear; colored but transmissive, or opaque (e.g., not transmissive); and polarizing or non-polarizing.
  • Exemplary substrates include, but are not limited to, the outer surface of an electronic display such as liquid crystal display or a cathode ray tube, the outer surface of a window or glazing, the outer surface of an optical component such as a reflector, polarizer, diffraction grating, mirror, touch panel, or lens, another film such as a decorative film or another optical film, or the like.
  • an electronic display such as liquid crystal display or a cathode ray tube
  • the outer surface of a window or glazing the outer surface of an optical component such as a reflector, polarizer, diffraction grating, mirror, touch panel, or lens
  • another film such as a decorative film or another optical film, or the like.
  • polymeric substrates include those that contain polycarbonates, polyesters (e.g., polyethylene terephthalates and polyethylene naphthalates), polyurethanes, poly(meth)acrylates (e.g., polymethyl methacrylates), polyvinyl alcohols, polyolefins such as polyethylenes and polypropylenes, polyvinyl chlorides, polyimides, cellulose triacetates, acrylonitrile-butadiene-styrene copolymers, and the like.
  • WA-1 Wetting Agent- 1, fluorosurfactant commercially available as
  • Liner-3 Silicone release liner with very tight release commercially available as NSR700 from CP Films
  • Liner-4 Epoxysilicone release liner with easy release commercially available as 8600 from Loparex
  • Adhesive- 1 Laminating adhesive of 25 micrometers (1 mil) thickness commercially available from 3M Company, St. Paul, MN as "3M Optically Clear Adhesive 8271".
  • Adhesive -2 Laminating adhesive of 25 micrometers (1 mil) thickness commercially available from 3M Company, St. Paul, MN as "3M Optically Clear Adhesive 8172".
  • Adhesive-3 Laminating adhesive of 25 micrometers (1 mil) thickness commercially available from 3M Company, St. Paul, MN as "3M Optically Clear Adhesive 8142".
  • PET A primed polyester film of polyethylene terephthalate having a thickness of 50 micrometers (2 mils) commercially available from Teijin DuPont as "MELINEX 618" film.
  • % Transmission and Haze The optical properties of percent transmission and haze were measured using a HAZE-GARD Plus hazemeter from BYK-Gardner USA.
  • Sheet resistance also called surface resistivity
  • Model 717 conductance monitor commercially available from Delcom Instruments, Inc.
  • Static charge decay time was measured on laminates using an Electro-Tech Systems, Inc. Model 406C static decay meter by charging the sample to 5 kV 9either + polarity or - polarity) and measuring the time required for the static charge to decay to 10% of its initial value. Film samples approximately 13 centimeters (5 inches) on a side were cut and mounted between the meter electrodes using magnets. Static charge decay measurements were made at ambient laboratory humidity of 30-40% relative humidity.
  • Coating quality for dried coatings was determined by looking for areas where the coating did not completely wet out the liner surface and rating the coatings accordingly. "Good” quality represents fewer than 1 dewet per coating area of 15 centimeters by 30 centimeters (6 inches by 12 inches); “OK” quality represents 2-5 dewets/area; “Some” quality represents 5-10 dewets/area; and “poor” quality represents > 10 dewets/area.
  • Laminate constructions of release liner/ surface modified adhesive/ PET film were tested for liner release by hand peeling the adhesive layer from the liner. If the liner released from modified adhesive layer the sample was classified as "R” for releases, if the liner did not release from the modified adhesive layer the sample was classified as "DNR" for did not release. 180° Peel Adhesion:
  • Laminates of release liner/ modified adhesive coatings/ PET film were cut into 1 inch by 5 inch strips.
  • the release liner was removed and the strip adhered to a clean, solvent washed glass plate or primed PET film using a 2 kilogram roller passed 3 times over the strip.
  • the bonded assembly was aged at room temperature (25°C, 50% relative humidity) or 70°C (in a forced air oven) for 24 hours. Samples aged at 70°C were allowed to cool to room temperature prior to peel testing.
  • the samples were tested for 180° peel adhesion using an IMASS slip/peel tester (Model SP-2000, commercially available from Instrumentors Inc., Strongsville, OH) at a rate of 30.5 centimeters/minute (12 inches/minute) over a 10 second data collection time. Two samples were tested; the reported adhesion value is an average of the two samples.
  • the peel force was measured in ounces per half inch and converted to Newtons per decimeter (N/dm).
  • Step 1 Preparation of Release Material Precursor:
  • the acrylic release material precursor prepared in Step 1 above was diluted with a 50:50 blend of toluene and n-heptanes to prepare a diluted solution at 2.0% solids by weight.
  • a U-PET film was coated with the diluted solution, using a #3 Mayer bar and dried to remove the solvents to obtain an acrylic release precursor having a thickness of about 0.1 micrometers on a PET film.
  • H type high-pressure mercury lamp
  • the acrylic release material precursor was irradiated with ultraviolet (UV) radiation with an energy density of 120mJ/cm 2 under nitrogen to give Release Liner-6.
  • Example 1 and Comparative Examples C1-C5 A series of surface modified adhesives were prepared and tested using the multistep procedure described below.
  • Step-1 Preparation of conductive polymer layer:
  • a series of conductive polymer layers were prepared on release liners by preparing the a mixture of CP-1 and 0.2 weight % WA-1 and coating the mixture on the release liners listed in Table 1 using a #16 Mayer rod, and allowing the coating to dry at room temperature. The coatings were evaluated for Coating Quality using the test method described above. The results are presented in Table 1.
  • Adhesive films were prepared by removing a liner from samples of Adhesive- 1 and laminating the adhesive to PET. These adhesive films were laminated to the conductive polymer layer on release liners prepared in Step 1 above by removing the additional liner from the adhesive films, hand laminating to the polymer coated release liner samples and passing a 1.4 kilogram (3 pound) rubber roller over the lamination.
  • Step-1 Preparation of conductive polymer layer:
  • a series of conductive polymer layers were prepared on Release Liner-6 by preparing a mixture of CP-1 and 2 weight % WA-1 and coating the mixture on the release liners using a #10 Mayer rod, and allowing the coatings to dry in an 80°C oven for 2 minutes.
  • Adhesive films were prepared by removing a liner from samples of Adhesive-2 (Example 2) and Adhesive-3 (Example 3) and laminating the adhesive to PET. These adhesive films were laminated to the conductive polymer layer on release liners prepared in Step 1 above by removing the additional liner from the adhesive films, hand laminating to the polymer coated release liner samples and passing a 1.4 kilogram (3 pound) rubber roller over the lamination.
  • Step 3 Testing of surface modified adhesive:
  • Step-1 Preparation of conductive polymer layer:
  • a series of conductive polymer layers were prepared on Release Liner-6 by preparing the a mixture of CP-1, 5 weight % ethylene glycol and 0.2 weight % WA-1 and coating the mixture on the release liners using a #3, #6, #13 or #16 Mayer rod as shown in Table 3, and drying the coating for 3 minutes in a 120°C oven.
  • the coated liners and a sample of unmodified Liner-6 (Comparative Example C6) were tested for % Transmission, Haze and Sheet Resistance using the test methods described above. The results are shown in Table 3.
  • Step 2 Preparation of surface modified adhesive: Adhesive films were prepared by removing a liner from samples of Adhesive-2 and laminating the adhesive to PET. These adhesive films were laminated to the conductive polymer layer on release liners prepared in Step 1 above by removing the additional liner from the adhesive films, hand laminating to the polymer coated release liner samples and passing a 2.3 kilogram (5 pound) rubber roller over the lamination.
  • Step 3 Testing of surface modified adhesive:
  • Additional laminates were prepared by removing the release liner from the laminates prepared in Step 2 above and laminating the adhesive film to an additional sample of Adhesive-2 with one liner removed to form laminates of 102 micrometer (4 mil) thickness of release liner/ adhesive/ conductive layer/ adhesive/ PET film. Samples of these laminate constructions and a sample of unmodified Adhesive-2 (Comparative Example C7) were tested for % Transmission, Haze, and Static Charge Decay using the test methods described above. The results are shown in Table 5.

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Abstract

L'invention porte sur des adhésifs à surface modifiée, qui peuvent être préparés en faisant venir en contact une couche adhésive avec une couche électriquement conductrice sur un substrat anti-adhérent, et en retirant la couche adhésive de telle sorte qu'au moins une partie de la couche électriquement conductrice adhère à la surface adhésive. La surface adhésive modifiée devient une surface adhésive électriquement conductrice. La couche adhésive modifiée peut être utilisée pour préparer des articles adhésifs, comprenant des articles contenant de multiples couches adhésives à surface modifiée.
PCT/US2010/057168 2009-11-20 2010-11-18 Adhésifs à surface modifiée WO2011063082A2 (fr)

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WO2013025330A2 (fr) * 2011-08-12 2013-02-21 3M Innovative Properties Company Adhésif conducteur optiquement transparent et articles à partir de celui-ci
WO2014038752A1 (fr) * 2012-09-06 2014-03-13 Samsung Techwin Co., Ltd Procédé de fabrication d'une couche de graphène
US20140146490A1 (en) * 2012-11-26 2014-05-29 Sony Corporation Laminated structure, method of manufacturing laminated structure, and electronic apparatus
JPWO2014010731A1 (ja) * 2012-07-12 2016-06-23 日本化薬株式会社 液晶シール剤及びそれを用いた液晶表示セル
WO2018129899A1 (fr) * 2017-01-12 2018-07-19 深圳市美信电子有限公司 Ruban adhésif facile à décoller, anti-déflagrant et sûr et procédé de préparation associé
US10334867B2 (en) 2014-03-03 2019-07-02 Intercontinental Great Brands Llc Method for manufacturing a comestible
US10973238B2 (en) 2011-03-11 2021-04-13 Intercontinental Great Brands Llc System and method of forming multilayer confectionery
US11077224B2 (en) 2015-02-02 2021-08-03 Coloplast A/S Ostomy device
US11122815B2 (en) 2011-07-21 2021-09-21 Intercontinental Great Brands Llc System and method for forming and cooling chewing gum
US11160681B2 (en) 2015-04-10 2021-11-02 Coloplast A/S Ostomy device
WO2022162550A1 (fr) * 2021-01-29 2022-08-04 3M Innovative Properties Company Agent de libération au polymère acrylique, feuille de décollement, ruban et ruban double face
CN115368845A (zh) * 2022-08-26 2022-11-22 3M中国有限公司 含有纳米粒子添加剂的导电压敏粘合剂
WO2023017392A1 (fr) * 2021-08-13 2023-02-16 3M Innovative Properties Company Article en tissu antistatique
CN117070149A (zh) * 2023-05-18 2023-11-17 宝力科技(宁国)有限公司 水性eau塑胶跑道胶粘剂及其制备方法
WO2024040582A1 (fr) * 2022-08-26 2024-02-29 3M Innovative Properties Company Adhésifs sensibles à la pression électroconducteurs contenant des additifs de nanoparticules

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Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10973238B2 (en) 2011-03-11 2021-04-13 Intercontinental Great Brands Llc System and method of forming multilayer confectionery
US11930830B2 (en) 2011-03-11 2024-03-19 Intercontinental Great Brands Llc System and method of forming multilayer confectionery
US11122815B2 (en) 2011-07-21 2021-09-21 Intercontinental Great Brands Llc System and method for forming and cooling chewing gum
WO2013025330A3 (fr) * 2011-08-12 2013-07-11 3M Innovative Properties Company Adhésif conducteur optiquement transparent et articles à partir de celui-ci
CN103732709A (zh) * 2011-08-12 2014-04-16 3M创新有限公司 光学透明的导电粘合剂及由其制得的制品
WO2013025330A2 (fr) * 2011-08-12 2013-02-21 3M Innovative Properties Company Adhésif conducteur optiquement transparent et articles à partir de celui-ci
JPWO2014010731A1 (ja) * 2012-07-12 2016-06-23 日本化薬株式会社 液晶シール剤及びそれを用いた液晶表示セル
WO2014038752A1 (fr) * 2012-09-06 2014-03-13 Samsung Techwin Co., Ltd Procédé de fabrication d'une couche de graphène
US10229768B2 (en) 2012-09-06 2019-03-12 Hanwha Aerospace Co., Ltd. Method for manufacturing graphene layer
US9137892B2 (en) * 2012-11-26 2015-09-15 Sony Corporation Laminated structure, method of manufacturing laminated structure, and electronic apparatus
US20140146490A1 (en) * 2012-11-26 2014-05-29 Sony Corporation Laminated structure, method of manufacturing laminated structure, and electronic apparatus
US10334867B2 (en) 2014-03-03 2019-07-02 Intercontinental Great Brands Llc Method for manufacturing a comestible
US11077224B2 (en) 2015-02-02 2021-08-03 Coloplast A/S Ostomy device
US11771798B2 (en) 2015-02-02 2023-10-03 Coloplast A/S Ostomy device with a switchable adhesive layer located between a backing layer and an absorbent adhesive layer
US11819444B2 (en) 2015-04-10 2023-11-21 Coloplast A/S Ostomy device with a switchable adhesive composition adapted to be switched by moisture activation of a switch initiator
US11160681B2 (en) 2015-04-10 2021-11-02 Coloplast A/S Ostomy device
WO2018129899A1 (fr) * 2017-01-12 2018-07-19 深圳市美信电子有限公司 Ruban adhésif facile à décoller, anti-déflagrant et sûr et procédé de préparation associé
WO2022162550A1 (fr) * 2021-01-29 2022-08-04 3M Innovative Properties Company Agent de libération au polymère acrylique, feuille de décollement, ruban et ruban double face
WO2023017392A1 (fr) * 2021-08-13 2023-02-16 3M Innovative Properties Company Article en tissu antistatique
CN115368845B (zh) * 2022-08-26 2023-11-14 3M中国有限公司 含有纳米粒子添加剂的导电压敏粘合剂
WO2024040582A1 (fr) * 2022-08-26 2024-02-29 3M Innovative Properties Company Adhésifs sensibles à la pression électroconducteurs contenant des additifs de nanoparticules
CN115368845A (zh) * 2022-08-26 2022-11-22 3M中国有限公司 含有纳米粒子添加剂的导电压敏粘合剂
CN117070149A (zh) * 2023-05-18 2023-11-17 宝力科技(宁国)有限公司 水性eau塑胶跑道胶粘剂及其制备方法

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