WO2011038882A1 - Confectionery products containing erythritol - Google Patents

Confectionery products containing erythritol Download PDF

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Publication number
WO2011038882A1
WO2011038882A1 PCT/EP2010/005904 EP2010005904W WO2011038882A1 WO 2011038882 A1 WO2011038882 A1 WO 2011038882A1 EP 2010005904 W EP2010005904 W EP 2010005904W WO 2011038882 A1 WO2011038882 A1 WO 2011038882A1
Authority
WO
WIPO (PCT)
Prior art keywords
erythritol
inulin
based polymers
hard candy
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/005904
Other languages
English (en)
French (fr)
Inventor
Ravindra Nana
Ronny Leontina Marcel Vercauteren
Mary A. Watson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cargill Inc
Original Assignee
Cargill Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cargill Inc filed Critical Cargill Inc
Priority to JP2012531277A priority Critical patent/JP2013506402A/ja
Priority to CN201080045146.8A priority patent/CN102548426B/zh
Priority to ES10775700T priority patent/ES2423328T3/es
Priority to EP10775700.7A priority patent/EP2482669B1/en
Priority to CA2775768A priority patent/CA2775768A1/en
Priority to MX2012003470A priority patent/MX2012003470A/es
Priority to US13/499,360 priority patent/US20120237659A1/en
Priority to PL10775700T priority patent/PL2482669T3/pl
Publication of WO2011038882A1 publication Critical patent/WO2011038882A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/42Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • A23L29/37Sugar alcohols
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

Definitions

  • the present invention relates to a confectionery product more in particular the hard candy, containing edible acids, inulin-based polymers, optionally carrageenan and at least 85% w/w erythritol.
  • EP 0 533 334 describes a process for the production of hard candy characterized in that the maltitol content of the sugar alcohol mixture is more than 77% but less than 86% by weight based on dry substance.
  • US 4,883,685 describes a hard candy which comprises erythritol and saccharides selected from among sugars and sugar alcohols other than erythritol as well as a process for producing the hard candy.
  • the current invention relates to a confectionery product more in particular the hard candy, containing an edible acid, inulin-based polymers and at least 85% w/w erythritol and wherein the ratio of inulin-based polymers to erythritol is 1/99 to 15/85. More specifically it relates to a hard candy consisting of inulin-based polymers, 85-98% w/w erythritol, an edible acid and flavours. Furthermore the current invention relates to a process for preparing a hard candy by heating at a temperature from 120 to 160°C an erythritol-containing mixture wherein the dry matter is containing inulin-based polymers and at least 85% w/w erythritol.
  • the current invention relates to a confectionery product, preferably a hard candy containing an edible acid, inulin-based polymers and at least 85% w/w erythritol and wherein the ratio of inulin-based polymers to erythritol is 1/99 to 15/85, preferably erythritol is present in an amount of at least 90% w/w.
  • Confectionery product within the scope of the present invention include grained products such as hard candies, brittle, caramel, and toffee, preferably hard candies.
  • Inulin-based polymers is a class of polymers related to inulin. Inulin itself which has been extracted from plants for nearly 100 years. Inulin is composed of a mixture of polysaccharides having various molecular weights or degrees of polymerization (DP). In general, inulin consists of fructose units with beta 1-2 bonds and ending in a glucose unit. The addition or subtraction of fructose units affects inulin's molecular weight or degree of polymerization (DP).
  • Inulin is the main carbohydrate in a variety of plants, such as agave, chicory root, dahlia tuber, Jerusalem Artichoke and salsify. Because of the ease of cultivation and harvesting, chicory has become the principal source of inulin today.
  • US 7,045,166 further discloses novel fractions of inulin containing at least two preferably at least three, desirably at least four, different polysaccharides each with differing molecular weights in the range of about 2288 and below and in which said fractions have less than 25% by weight of polysaccharides with molecular weights above 2288, and which exhibit improved water solubility and/or water miscibility.
  • Carrageenan is a collective term for polysaccharides prepared by alkaline extraction from red seaweed.
  • the regular backbone structure of the basic structure of carrageenan is disrupted by a more or less ordered distribution of sulphate ester groups.
  • Carrageenan can also contain some methoxy and pyruvate groups.
  • Carrageenans are linear polymers of about 25,000 galactose derivatives.
  • Erythritol is a carbohydrate-based polyol, i;e; a tetriitol represented by the chemical formula C 4 H 10 O 4 and which has an excellent appearance in the form of white crystals and it is similar to the appearance of granulated sugar, sucrose. It is non-digestive, providing zero calories and is non cariogenic.
  • the ratio of inulin-based polymers to erythritol in the confectionary product is 1/99 to 15/85, preferably 1/99 to 10/90, more preferably 2/98 to 8/92, even more preferably 2.5/97.5 to 7/93 while erythritol is being present for at least 85%, preferably 90% based on dry weight of the confectionery product.
  • the confectionery product more in particular the hard candy, is comprising an edible acid.
  • Suitable acids are selected from the group consisting of malic acid, fumaric acid, lactic acid, tartaric acid, glucono-delta lactone, salts of gluconic acid, phosphoric acid, succinic acid, adipic acid, ascorbic acid, acetic acid, citric acid and mixture of two or more thereof.
  • the acids are added in a quantity based on dry matter of the confectionery product in an amount of 0.2 to 4%, preferably from 0.2 to 2%, more preferably from 0.2% to 0.5%.
  • carrageenan is added in an amount such that the confectionery product is still containing at least 85%, preferably at least 90% of erythritol based upon dry weight of confectionery.
  • the confectionery product more in particular the hard candy is further comprising flavours, high-intensity sweeteners and/or colouring agents.
  • flavours are selected from mint flavour, chocolate mint flavour, bubblegum flavour, apple spice flavour, black cherry flavour, pineapple flavour, cola flavour, grape flavour, cherry flavour, apple flavour and citrus flavours such as orange flavour, lemon flavour, lime flavour, fruit punch and mixtures of two or more thereof.
  • Preferred flavours are chocolate mint, bubblegum, apple spice, black cherry, and pineapple.
  • the amount of flavour depends upon the flavor or flavors selected, the flavor impression desired and the form of flavour used.
  • a high-intensity sweetener, which can be used as non-nutritive sweetener can be selected from the group consisting of aspartame, acesulfame salts such as acesulfame-K, saccharins (e.g.
  • any other natural derived high-intensity sweetener is suitable as well.
  • colouring agents can also be added as well. Any water-soluble colouring agent approved for food use can be utilized for the current invention.
  • the current invention relates to a process for preparing a hard candy by heating at a temperature from 120 to 160°C an erythritol-containing mixture wherein the dry matter is containing inulin-based polymers and at least 85% w/w erythritol.
  • the process is further characterised in that at the end of the heating period a vacuum of 0.6 to 0.8 bar is applied.
  • the current invention relates to a dry mix containing inulin-based polymers and at least 85% w/w erythritol wherein the ratio of inulin-based polymers to erythritol is 1/99 to 15/85, or a dry mix which is further containing carrageenan and/or an edible acid.
  • Carrageenan is added in an amount such that the confectionery product is still containing at least 85%, preferably at least 90% of erythritol based upon dry weight of confectionery.
  • the edible acid is added in a quantity based on dry matter of the confectionery product in an amount of 0.2 to 4%, preferably from 0.2 to 2%, more preferably from 0.2% to 0.5%.
  • confectionery product more in particular the hard candy, is sugar free, provides zero calories and can be labeled as natural and/or organic.
  • Probe P0.5HS 1 ⁇ 2" Hemispherical Plastic using a 25kg load cell.
  • HDP/90 Heavy Duty Platform
  • Test Set Up Secured the HDP/90 onto the machine base. Calibrate the probe prior to testing samples. Placed the sample on the blank plate of the HDP/90 and position centrally under the probe. Commence test.
  • Hardness is the peak force of the first compression of the candy.
  • Hardness and fracturability are two completely different parameters that are not comparable with each other.
  • Flavor, acid and coloring agent were mixed in. Final step vacuum 0.6 to 0.8 bar.
  • the hot mass was dosed in Teflon coated aluminum moulds and allowed cooling further, followed by demoulding.
  • erythritol containing mixture (erythritol, inulin and carrageenan) was placed in a cooking vessel on a heating plate without water addition.
  • the dry blend was cooked to 130°C until liquefaction of the mixture.
  • erythritol containing mixture (erythritol and inulin) was placed in a cooking vessel on a heating plate without water addition.
  • the dry blend was cooked to 130°C until liquefaction of the mixture.
  • Flavor, gluconolactone and coloring agent were mixed in Final step vacuum 0.6 to 0.8 bar.
  • the hot mass was dosed in Teflon coated aluminum moulds and allowed cooling further, followed by demoulding.
  • Flavor, ascorbic acid, and coloring agent were mixed in.Final step vacuum 0.6 to 0.8 bar.
  • the hot mass was dosed in Teflon coated aluminum moulds and allowed cooling further, followed by demoulding.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Nutrition Science (AREA)
  • Inorganic Chemistry (AREA)
  • Confectionery (AREA)
PCT/EP2010/005904 2009-10-01 2010-09-28 Confectionery products containing erythritol Ceased WO2011038882A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP2012531277A JP2013506402A (ja) 2009-10-01 2010-09-28 エリトリトールを含有する菓子製品
CN201080045146.8A CN102548426B (zh) 2009-10-01 2010-09-28 含赤藓醇的糖果制品
ES10775700T ES2423328T3 (es) 2009-10-01 2010-09-28 Productos de confitería que contienen eritritol
EP10775700.7A EP2482669B1 (en) 2009-10-01 2010-09-28 Confectionery products containing erythritol
CA2775768A CA2775768A1 (en) 2009-10-01 2010-09-28 Confectionery products containing erythritol
MX2012003470A MX2012003470A (es) 2009-10-01 2010-09-28 Productos de confiteria que contienen eritritol.
US13/499,360 US20120237659A1 (en) 2009-10-01 2010-09-28 Confectionery products containing erythritol
PL10775700T PL2482669T3 (pl) 2009-10-01 2010-09-28 Produkty cukiernicze zawierające erytrytol

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US24764609P 2009-10-01 2009-10-01
US61/247,646 2009-10-01

Publications (1)

Publication Number Publication Date
WO2011038882A1 true WO2011038882A1 (en) 2011-04-07

Family

ID=43231920

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/005904 Ceased WO2011038882A1 (en) 2009-10-01 2010-09-28 Confectionery products containing erythritol

Country Status (10)

Country Link
US (1) US20120237659A1 (enExample)
EP (1) EP2482669B1 (enExample)
JP (1) JP2013506402A (enExample)
KR (1) KR20120081176A (enExample)
CN (1) CN102548426B (enExample)
CA (1) CA2775768A1 (enExample)
ES (1) ES2423328T3 (enExample)
MX (1) MX2012003470A (enExample)
PL (1) PL2482669T3 (enExample)
WO (1) WO2011038882A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2658387A4 (en) * 2010-12-30 2014-11-12 Wrigley W M Jun Co HARD CARROT WITH REDUCED SUGAR CONTENT
EP2802218A4 (en) * 2012-01-09 2016-10-12 Wrigley W M Jun Co GELIERTE SWEETS WITH REDUCED SUGAR

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4883685A (en) 1987-08-14 1989-11-28 Mitsubishi Kasei Corporation Meso-erythritol hard candy and process for producing the same
US4971798A (en) 1989-11-30 1990-11-20 Miles Inc. Hard confections containing hydrogenated isomaltulose and medicinally active ingredient
EP0533334A1 (en) 1991-08-15 1993-03-24 Cerestar Holding Bv Process for the production of hard candy
WO2001019204A1 (en) * 1999-09-13 2001-03-22 Nabisco, Inc. Breath freshening comestible product
US20030207003A1 (en) * 1998-08-27 2003-11-06 Silver Barnard S. Sweetener compositions containing fractions of inulin
US20070224323A1 (en) * 2006-03-23 2007-09-27 Fred Goldman Sugar Replacement and Baked Goods and Caramels Using the Sugar Replacement

Family Cites Families (14)

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JPS5030703B2 (enExample) * 1972-12-25 1975-10-03
JP3100186B2 (ja) * 1991-08-01 2000-10-16 株式会社黄金糖 ハードキャンディの製造法
DE19549825B4 (de) * 1995-09-02 2010-11-04 Südzucker AG Mannheim/Ochsenfurt Zuckerfreie Hartkaramellen
EP0975236B1 (en) * 1997-04-18 2004-10-27 McNEIL-PPC, INC. Low calorie, palatable fiber-containing, sugar substitute
CA2262266C (en) * 1998-03-17 2005-12-27 Kraft Foods, Inc. Reduced calorie coated confections
US7147883B1 (en) * 1998-08-27 2006-12-12 Silver Barnard S Compositions containing at least one polyol and inulin characterized by reduced tendencies of the at least one polyol to induce acute diarrhea
US6875460B2 (en) * 2000-06-06 2005-04-05 Spi Polyols, Inc. Co-crystallized polyols and hydrogenated maltodextrin
US20040086615A1 (en) * 2002-11-04 2004-05-06 Cargill, Inc. & Cerestar Holding Bv Reduced calorie confectionery compositions
JP4216208B2 (ja) * 2004-02-26 2009-01-28 サラヤ株式会社 低エネルギーキャンディ
JP4563077B2 (ja) * 2004-05-28 2010-10-13 株式会社ロッテ キャンディ及びその製造方法
AU2006279716B2 (en) * 2005-08-12 2010-04-22 Intercontinental Great Brands Llc Mouth-moistening compositions, delivery systems containing same and methods of making same
FR2894435B1 (fr) * 2005-12-14 2010-09-03 Roquette Freres Confiserie sans sucre comprenant du xylitol sans effet rafraichissant
US20100203190A1 (en) * 2007-02-12 2010-08-12 Wm. Wrigley Jr. Company Coated confectionery products
EP2187759B1 (en) * 2007-09-21 2012-10-24 Cargill, Incorporated Erythritol-based hard coatings

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4883685A (en) 1987-08-14 1989-11-28 Mitsubishi Kasei Corporation Meso-erythritol hard candy and process for producing the same
US4971798A (en) 1989-11-30 1990-11-20 Miles Inc. Hard confections containing hydrogenated isomaltulose and medicinally active ingredient
EP0533334A1 (en) 1991-08-15 1993-03-24 Cerestar Holding Bv Process for the production of hard candy
US20030207003A1 (en) * 1998-08-27 2003-11-06 Silver Barnard S. Sweetener compositions containing fractions of inulin
US7045166B2 (en) 1998-08-27 2006-05-16 Silver Barnard S Sweetener compositions containing fractions of inulin
WO2001019204A1 (en) * 1999-09-13 2001-03-22 Nabisco, Inc. Breath freshening comestible product
US20070224323A1 (en) * 2006-03-23 2007-09-27 Fred Goldman Sugar Replacement and Baked Goods and Caramels Using the Sugar Replacement

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2658387A4 (en) * 2010-12-30 2014-11-12 Wrigley W M Jun Co HARD CARROT WITH REDUCED SUGAR CONTENT
US10390547B2 (en) 2010-12-30 2019-08-27 Wm. Wrigley Jr. Company Hard candy with reduced sugar
EP2802218A4 (en) * 2012-01-09 2016-10-12 Wrigley W M Jun Co GELIERTE SWEETS WITH REDUCED SUGAR
US10736333B2 (en) 2012-01-09 2020-08-11 Wm. Wrigley Jr. Company Gelled confection with reduced sugar

Also Published As

Publication number Publication date
CN102548426B (zh) 2015-05-20
US20120237659A1 (en) 2012-09-20
ES2423328T3 (es) 2013-09-19
EP2482669A1 (en) 2012-08-08
JP2013506402A (ja) 2013-02-28
EP2482669B1 (en) 2013-07-10
CN102548426A (zh) 2012-07-04
PL2482669T3 (pl) 2013-10-31
CA2775768A1 (en) 2011-04-07
MX2012003470A (es) 2012-04-19
KR20120081176A (ko) 2012-07-18

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