WO2011037272A1 - 高強度薄鋼板の隅肉アーク溶接方法 - Google Patents
高強度薄鋼板の隅肉アーク溶接方法 Download PDFInfo
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- WO2011037272A1 WO2011037272A1 PCT/JP2010/067194 JP2010067194W WO2011037272A1 WO 2011037272 A1 WO2011037272 A1 WO 2011037272A1 JP 2010067194 W JP2010067194 W JP 2010067194W WO 2011037272 A1 WO2011037272 A1 WO 2011037272A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/3093—Fe as the principal constituent with other elements as next major constituents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/23—Arc welding or cutting taking account of the properties of the materials to be welded
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/3066—Fe as the principal constituent with Ni as next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/368—Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/38—Selection of media, e.g. special atmospheres for surrounding the working area
- B23K35/383—Selection of media, e.g. special atmospheres for surrounding the working area mainly containing noble gases or nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/02—Seam welding; Backing means; Inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/16—Arc welding or cutting making use of shielding gas
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/02—Iron or ferrous alloys
- B23K2103/04—Steel or steel alloys
Definitions
- the present invention relates to a fillet arc welding method for a high-strength thin steel sheet, and more specifically, improves the toe shape of a fillet arc welded joint produced by gas shielded arc welding, and fillet arc welding.
- the present invention relates to a fillet arc welding method for a high-strength thin steel sheet that can improve the fatigue characteristics of a joint.
- Favorable target members to which the present invention can be applied include automobile body structural members, in particular, suspension parts that are important safety parts.
- the welding speed is usually set higher than in other industrial fields in order to improve the efficiency of the production line. Generally, it is 60 cm / min or more, and is often set to 100 cm / min or more.
- the plate thickness of the steel plate used in the automobile industry is often 6 mm or less, for example, even in the case of a suspension part having a relatively large plate thickness. This is because it is usually 4 mm or less in many cases. That is, because the plate is thin as described above, a predetermined joint strength can be ensured even if the amount of welding in arc welding is small.
- the plate thickness is as thick as over 6 mm
- arc welding is performed at a welding speed of 60 cm / min or more so as to secure a welding amount necessary to obtain a predetermined joint strength
- the welding current and welding voltage must be increased, which increases the risk of adversely affecting the weld bead shape.
- arc welding in the automotive industry field has a higher welding speed than other industries.
- the weld bead shape deteriorates, that is, the flank angle (see FIG. 2) of the weld toe increases.
- stress concentration is caused at the weld toe, and the problem is that the fatigue strength of the welded joint decreases.
- the reason that the weld bead shape deteriorates at a high welding speed is that the faster the welding speed, the longer the molten pool becomes, and the molten metal tends to solidify before it spreads sufficiently.
- Reducing the weight of the automobile itself is an effective means for improving fuel efficiency, and reducing the thickness of the steel sheet forming the automobile can be an effective means.
- the reduction in the thickness of the steel sheet means an increase in the stress applied to the steel sheet, and the increase in stress causes not only a problem of static strength but also a problem of fatigue strength. That is, there is a problem that even if the static strength is sufficient, the plate thickness is reduced, that is, the weight cannot be reduced from the viewpoint of fatigue strength.
- the fatigue strength of a welded joint has almost no material dependence and is governed by mechanical factors such as stress concentration determined by the weld bead shape and residual stress in the weld.
- the weld toe is used as a means for improving the shape of the weld toe at high welding speeds and as means for improving the fatigue strength of welded joints.
- methods such as smoothing by finishing or applying a compressive residual stress to the weld toe by shot peening or the like. These are so-called post-processes and are not preferable because they increase manufacturing costs.
- Patent Documents 3 and 4 and Non-Patent Document 1 there is a technique for widening the weld bead shape by limiting the components of the welding material and the steel plate.
- the technique disclosed in Patent Document 3 and Non-Patent Document 1 is a technique of adding more than 0.01% to 0.06% or less of S, thereby reducing the surface tension of the molten pool to form a weld toe shape. It is a technology that improves
- Patent Document 4 is a technique for adjusting the sum of Si and Mn of a steel sheet.
- Patent Document 10 discloses a technique regarding a welding method from the viewpoint of fatigue characteristics in lap fillet gas shielded arc welding of thin steel plates. This technique defines the chemical composition of the weld metal in order to improve the bead toe shape.
- Patent Documents 5 to 9 disclose techniques relating to steel sheets having excellent fatigue strength.
- Patent Documents 3 and 4 and Non-Patent Document 1 are all techniques aimed at making the weld bead width wider than the conventional technique.
- the weld bead width can certainly be a convenient index for representing the overall shape of the weld joint, but its fatigue strength largely depends on the shape of the weld toe that is the stress concentration portion. That is, there is a tendency peculiar to fatigue strength that is not present in static strength, in which the shape of a part of the welded joint determines the characteristics of the entire welded joint. Therefore, in order to improve fatigue strength, it is necessary to pay attention to the shape of a part of the welded joint called the weld toe shape rather than the characteristic of the entire welded joint called the weld bead width.
- the techniques disclosed in Patent Documents 3 and 4 and Non-Patent Document 1 are suitable for improving the static strength, that is, the tensile fracture strength of the welded joint. Not clear.
- Patent Document 9 discloses a technique related to the fatigue strength of a weld heat affected zone (also referred to as heat-affected zone, HAZ), but the welded joint being taken up is a butt welded joint. Stress concentration is not as high as fillet arc welded joints. By the way, most of automobile underbody parts and the like are manufactured by fillet arc welding. From this, it is clear whether or not the technique described in Patent Document 9 can improve the fatigue strength of a structure having a fillet arc welded joint that is frequently used in the automotive industry and the like and has a high stress concentration. Absent.
- Patent Documents 5 to 9 relate to the fatigue strength of a base material without a welded joint or the fatigue strength of a butt joint having a relatively small stress concentration.
- a fatigue crack is generated from the place where the stress concentration is the largest, and this determines the fatigue strength of the entire structure. That is, unless the fatigue strength of the lap fillet joint having a higher stress concentration than the butt joint is improved, the fatigue of the structure will not be improved.
- Patent Document 10 is aimed at improving the fatigue strength of a lap fillet joint of thin steel plates, but the welding speed is an embodiment targeting 80 to 110 cm / min, which was conventionally called high-speed welding, It cannot cope with the further high-speed welding that is required.
- Patent Document 10 provides a technique in which the fatigue strength of a joint is 12% or more of the fatigue strength of a steel plate.
- the fatigue strength required as a welded joint for thin steel sheets is about 250 MPa
- the fatigue strength of at least 250 MPa is taken as a criterion for acceptance.
- the reason why 250 MPa is the object of the present invention is as follows. First, the reason for selecting a uniform value regardless of the steel strength is that the fatigue strength of the welded joint does not depend on the type of steel, that is, the joint fatigue strength is the same for both 490 MPa class steel and 780 MPa class steel. Is taken into account.
- the fatigue strength of the steel material depends on the tensile strength of the steel material, but in the case of a welded joint, the characteristic that it does not depend on the steel material is taken into consideration.
- the fatigue strength of the welded joint as it is welded is approximately 200 MPa. If the fatigue strength is 250 MPa, it corresponds to an increase in strength of 20% or more, which is preferable for fatigue design. In some cases, the possibility of changing the plate thickness is also a value. Therefore, in the present invention, 250 MPa is a guide.
- the present invention provides a good shape of the weld toe portion in the gas shielded arc welding even when the welding speed is more than 80 cm / min, particularly more than 110 cm / min.
- Fillet arc welding method for high-strength thin steel sheet which can improve the fatigue characteristics of arc-welded joints, and in particular, a method for improving fatigue of welded joints in steel sheets having a tensile strength of 700 MPa or more, which is strongly desired to improve fatigue strength
- the purpose is to provide.
- the present inventors have focused on the welding speed, the steel plate, and the welding wire components, and have intensively studied the influence of the weld toe shape. And among steel plates and welding wires, it has been found that the welding toe shape can be improved even when the welding speed is more than 80 cm / min, particularly more than 110 cm / min and 150 cm / min or less, by limiting the amount of Si in particular. Furthermore, the relationship between the steel plate-containing Si amount and the welding wire-containing Si amount in which the effect of improving the weld toe shape is also found. This invention is made
- the welding speed is more than 80 cm / min, particularly more than 110 cm / min and not more than 150 cm / min
- the said thin steel plate is mass%, C: 0.02 to 0.15%, Si: 0.2 to 1.8%, Mn: 0.5 to 2.5% P: 0.03% or less, S: a thin steel plate containing 0.02% or less, characterized in that the thin steel plate and Si contained in the welding wire are combined so that the value of the following (formula 1) is 0.32 or more
- a fillet arc welding method for high strength thin steel sheet is more than 80 cm / min, particularly more than 110 cm / min and not more than 150 cm / min
- the said thin steel plate is mass%, C: 0.02 to 0.15%, Si: 0.2 to 1.8%, Mn: 0.5 to 2.5% P: 0.03% or less
- S a thin steel plate containing 0.02% or less, characterized in that the thin steel plate and Si contained in the welding wire are combined so that the value of the following (formula 1) is 0.
- Si (steel plate) + 0.1 ⁇ Si (wire) (Formula 1)
- Si (steel plate) represents the Si amount of the thin steel plate
- Si (wire) represents the total Si amount of the welding wire.
- the thin steel sheet is further in mass%, Al: 0.005 to 0.1%
- the thin steel sheet is further in mass%, Ti: 0.005 to 0.1%, Nb: 0.005 to 0.1%, V: 0.01 to 0.2%, Cr: 0.1 to 1.0%, Mo: 0.05 to 0.5%
- the fillet arc welding method for high-strength thin steel sheet according to any one of (1) to (3) above, comprising any one or more of the above.
- the welding solid wire is further in mass%, Ti: 0.01 to 0.5%, Nb: 0.01 to 0.1%, V: 0.05-0.3% Cr: 0.05 to 1.0%, Mo: 0.05 to 0.7%, Ni: 0.3 to 12.0%
- the S contained in the welding solid wire is limited to 0.02 to 0.08% by mass%.
- the welding wire is a flux-cored wire for gas shield arc welding in which a slit-like seamless steel outer shell is filled with flux,
- the total mass% of the entire wire C (excluding C in SiC): 0.01 to 0.20%, Si (excluding Si in SiC and SiO 2 ): 0.05 to 1.2%, Mn: 0.2 to 2.5% P: 0.03% or less, S: 0.06% or less
- a flux-cored wire for welding containing 0.05 to 0.4% in total of one or more of SiO 2 , Al 2 O 3 , Na 2 O and K 2 O, with the balance being iron and inevitable impurities;
- the fillet arc welding method for a high-strength thin steel sheet according to any one of the above items (1) to (4), wherein:
- the flux-cored wire for welding is a mass% of the whole wire, and further, as a flux filled in the steel outer sheath, Graphite: It is characterized by being a flux-cored wire for welding containing 0.02% or more and having a total amount of C conversion values defined by the following (formula 2) of 0.15 to 0.45%.
- the flux-cored wire for welding is, in one or both of the steel outer sheath and the flux, in mass% of the whole wire, Ni: 0.1 to 5.0%, Cr: 0.1 to 2.0%, Mo: 0.1 to 2.0%, Cu: 0.1 to 0.5%
- the welding flux-cored wire is in one or both of the steel outer sheath and the flux, and the mass% of the whole wire.
- B 0.001 to 0.015%
- the welding flux-cored wire is in the steel outer sheath and the flux in one or both of the mass% of the whole wire, and further, one or more of Nb, V and Ti is added in total to 0.005 to
- the welding flux-cored wire contains 0.05% to 0.5% of an arc stabilizer other than an oxide based on the mass% of the whole wire as a flux filled in the steel sheath.
- the fillet arc welding method for a high-strength thin steel sheet according to any one of the above items (9) to (13).
- the flux-cored wire for welding is, in one or both of the steel outer sheath and the flux, in mass% of the whole wire, S: 0.02 to 0.06%
- the fillet arc welding method of the high-strength thin steel sheet is gas shielded arc welding, and the shielding gas is in mass%, CO 2 : 5% or more and 25% or less, O 2 : 4% or less (including 0%)
- the fillet arc welding method for high-strength thin steel sheet according to any one of (1) to (15) above, wherein a shielding gas comprising the remainder Ar and inevitable impurities is used.
- a gas shielded arc welded joint performed at a welding speed of more than 80 cm / min, particularly more than 110 cm / min and not more than 150 cm / min.
- the said thin steel plate is mass%, C: 0.02 to 0.15%, Si: 0.2 to 1.8%, Mn: 0.5 to 2.5% P: 0.03% or less, S: A thin steel plate containing 0.02% or less and the balance iron and unavoidable impurities, and the Si contained in the thin steel plate and the welding wire has a value of (Formula 1) of 0.32 or more.
- a fillet arc welded joint of high-strength thin steel sheet characterized by being combined as described above.
- the weld toe shape is smooth even in the case of high-speed welding with a welding speed of more than 80 cm / min, particularly more than 110 cm / min and not more than 150 cm / min.
- the stress concentration at the weld toe can be reduced accordingly, and the fatigue strength of the welded joint can be improved.
- the fillet arc welding method for high-strength thin steel sheets provided by the present invention is particularly effective not only in the automobile industry but also in industrial fields where there is a strong need for increased welding speed, and it is possible to achieve both improvement in productivity and improvement in fatigue strength. Because it is a technology, its industrial significance is extremely large.
- Metal fatigue is a phenomenon that, unlike static strength, breaks when stress in the elastic range is applied. Stress is repeatedly applied, and the number of repetitions determines the fatigue life. In general, if a fracture does not occur even when a stress is repeatedly applied 2 million times or more, the applied stress at that time is called fatigue strength. Metal fatigue is a phenomenon that breaks due to an applied stress within the elastic range, and thus is often different from static strength. For example, static strength is not significantly affected by stress concentration or residual stress existing in a welded joint. Even if the grinder finish of the weld toe is extremely effective in improving fatigue strength, the static strength is almost unchanged. This is because static strength is accompanied by plastic deformation.
- the fatigue strength of a welded joint is a phenomenon in which the characteristics of the entire welded joint are determined by a very small stress state of the welded joint.
- the portion where the fatigue crack occurs is a weld toe portion where stress concentration is high.
- the residual stress is self-equilibrium, and a compressive residual stress that cancels out this tensile residual stress always exists inside the welded joint.
- the fatigue strength is determined by a small part of the stress state of the welded joint, even if a compressive residual stress exists, this compressive residual stress will not be fatigued unless it exists at the place where the fatigue crack occurs. Does not affect strength. This trend is also true for stress concentrations.
- Non-Patent Document 1 discloses a technique for widening the weld bead width. However, according to this, it is not always clear that the flank angle is reduced when the width of the weld bead is increased.
- the technology for widening the weld bead width and the technology for narrowing the flank angle of the weld toe are not necessarily the same.
- the present invention provides a technique aimed at improving the shape of the weld toe, and its purpose is to improve the fatigue strength of the welded joint.
- As for static strength since it does not depend on stress concentration or residual stress, it can be sufficiently ensured unless there is a defect in the welded joint. In the scope of the present invention, such a welded joint defect is generated. There are no such factors.
- the present invention aims to provide a technique different from Patent Documents 3 and 4 and Non-Patent Document 1.
- Patent Documents 1 and 2 are techniques aimed at improving the fatigue strength of welded joints, and are the same as the objects of the present invention.
- means for improving the fatigue strength of welded joints there are relaxation of stress concentration and relaxation of residual stress, and the techniques disclosed in Patent Documents 1 and 2 improve fatigue strength using residual stress relaxation. This technique is different from the technique using stress concentration relaxation disclosed in the present invention.
- techniques that have been used for a long time include techniques for peening and grinder processing after welding, but these are post-processing steps, and there is a problem in terms of manufacturing efficiency. Conceivable.
- the material factors that determine the weld bead shape including the weld toe shape include the surface tension of the molten pool and the gravity acting on the molten metal, and the weld bead shape is determined by the mechanical balance between these factors.
- the surface tension of the molten pool is affected by its chemical components, such as C, Si, S, O, and the like. Therefore, it has been considered that appropriately controlling these elements has an effect on improving the weld bead shape. From this point of view, the surface tension may be lowered in order to reduce the flank angle of the weld toe, but this also brings about the effect of widening the weld bead width as it is.
- the technique for increasing the weld bead width and the technique for increasing the contact angle of the weld toe portion tend to be identified.
- this is also a technique for widening the weld bead width.
- the invention described in Patent Document 10 has been made based on such a concept.
- the component range of the molten pool becomes a problem.
- the problem can be solved by supplementing it with the welding material.
- the welding material This means that one of the components of the steel plate and the molten material can be supplemented with the other component.
- a phenomenon in which such a steel plate component cannot be supplemented with a welding material is used. In order for such a phenomenon to occur, it is considered that there are material factors other than the surface tension of the molten pool as factors determining the shape of the weld bead, but it is not always clear what mechanism is affecting it. .
- the fact that the material factor that determines the weld toe shape exists in addition to the components of the molten pool is also a discovery of a factor that has not been noticed so far, and has been expected in the past. The above shape improvement can be expected.
- the inventors determined the weld toe shape as a welding condition by paying attention to a welding speed exceeding 80 cm / min, particularly a speed exceeding 110 cm / min exceeding the conventional high-speed welding speed.
- a welding speed exceeding 80 cm / min particularly a speed exceeding 110 cm / min exceeding the conventional high-speed welding speed.
- the Si amount of the steel plate greatly affects the weld toe shape.
- the influence of the Si content of the steel sheet is not limited to the influence on the weld metal component due to dilution. If this is the case, the same result should be obtained even if the Si amount of the welding wire is adjusted according to the dilution rate, but it can be obtained only by adjusting the Si amount in the welding wire as described later. No effect.
- the additive element Si in the steel sheet is a substitutional element, and is the element having the smallest atomic radius among the substitutional elements normally contained in the steel sheet, such as Mn, Ni, and Cr.
- Si is arranged in the order of Na, Mg, Al, Si, P, S, Cl, Ar, and the right element increases the number of protons in the nucleus, so it attracts electrons more strongly. For this reason, the atomic radius decreases in this order.
- P and S located on the right side of Si have an atomic radius smaller than that of Si.
- addition of a large amount of P or S causes deterioration of properties of the steel material itself or deterioration of weldability, and thus the present invention is intended. A degree of addition cannot be expected. Therefore, practically, Si may be regarded as an element having the smallest atomic radius among substitutional elements. The present inventors paid attention to Si in the steel material from the above.
- the ease of electron emission from the steel sheet means that when arc welding is performed, the welding arc is likely to spread farther. This means that the weld bead tends to spread. Furthermore, widening of the welding arc also has the function of keeping the temperature of the surface of the molten pool at a high temperature, which means that the surface tension of the pool can be kept small by this effect. The shape can be made smooth. Such an effect is an effect that cannot be obtained by the method of reducing the surface tension of the molten pool by adjusting the components of the welding material. 1 and 2 are conceptual diagrams illustrating this effect.
- FIG. 1 shows Fe atoms after Si addition when Si3 having a small atomic radius is arranged on Fe atoms before Si addition in which iron atoms are regularly arranged (circles indicated by dotted lines in FIG. 1).
- the comparison of the positional relationship of the atom 2 is shown (circle shown by the black line in FIG. 1). Since the radius of the Si atom is small, the position of the iron atom changes slightly, and it can be understood that the interatomic distance, in FIG. 1, the gap portion between the atoms is large. Therefore, it is considered that the free electron restraint becomes lower and the electron emission becomes easier.
- FIG. 2 is a conceptual diagram showing the influence on the weld bead shape when free electrons become easy and the welding arc by the welding wire 4 becomes wide.
- 2A illustrates the arc phenomenon when Si is not added so much
- FIG. 2B illustrates the arc phenomenon when Si is added.
- FIG. 2 (b) since the welding arc spreads far away, the steel sheet is melted as much, that is, the weld bead width tends to be widened. Furthermore, the surface temperature of the molten pool existing in the rear part of the arc Therefore, the surface tension of the molten pool can be kept low. Thereby, the toe shape of a weld bead can be made smooth.
- FIG. 2 is a conceptual diagram showing the influence on the weld bead shape when free electrons become easy and the welding arc by the welding wire 4 becomes wide.
- 2A illustrates the arc phenomenon when Si is not added so much
- FIG. 2B illustrates the arc phenomenon when Si is added.
- FIG. 2A shows a case where the welding arc is narrower than that shown in FIG.
- the region where the steel material can be melted is narrowed by the amount of the welding arc that is narrow.
- region which can heat the surface of the molten pool behind an arc also becomes narrow, the tendency for the temperature of a pool surface to become lower than the case of (b) arises. Since the surface tension tends to increase as the temperature decreases, the surface temperature of the molten pool is kept high in the A2 region in (b) thanks to the wide arc, thereby suppressing the surface tension to a low level. The width of is never narrowed.
- the pool surface temperature in the A1 region of FIG. 2A cannot be kept high, the surface tension is recovered, and the pool width is narrow. Tend to be. Behind the A1 region, the pool temperature becomes lower from the viewpoint of heat conduction, and furthermore, the temperature of the outer portion of the pool becomes lower than the inner side, so that a difference in surface tension occurs and the temperature is low, that is, the surface tension is low. A phenomenon occurs in which the pool is pulled to the large outside, and the pool width is widened again. This is the B1 region in FIG. However, since the pool is narrow in the A1 region, the tendency that the bead toe shape is difficult to be smooth is not solved. In FIG.
- the bead shape remains good because the pool width does not decrease in the A2 region.
- a component system that can keep the surface tension low even when the temperature of the pool surface is lowered is realized, or the welding speed is decreased as shown in FIG.
- this method has been adopted in which the A1 region of (a) enters the welding arc, that is, the A3 region of (c) of FIG. In the present invention, this method is solved by widening the welding arc, which is different from the prior art.
- the addition of Si should be a steel material, and even if it is performed on the welding material, a sufficient effect cannot be obtained. That is, in order for the welding arc to become wide, before the steel material or the molten material is melted, an arc must first be generated between the steel material and the molten material. For this purpose, electrons must be emitted from the steel material, and electricity must flow between the steel material and the molten material.
- the effect of Si in this phenomenon that is, the effect that electrons are easily emitted from the steel material cannot be solved by means of adding Si from the molten pool from the molten material to supplement Si diluted from the steel material. That is, Si in the steel material is important, and the same effect cannot be obtained even if supplemented from the molten material.
- the inventors further clarified the relationship between the appropriate Si amount of the steel sheet and the Si amount of the welding wire. That is, as the amount of Si in the welding wire increases, the minimum amount of Si in the steel sheet necessary to improve the weld toe shape tends to decrease. However, when Si is not added to the steel plate, the shape of the weld toe is not improved under the high-speed welding conditions even if the Si content of the welding wire is increased. As measures for improving the weld toe shape in this case, it is necessary to sacrifice the production efficiency such as reducing the welding speed (for example, 80 cm / min or less). The reason why the minimum amount of Si in the steel sheet necessary for improving the weld toe shape tends to decrease as the amount of Si in the welding wire increases is not necessarily clear. If the A1 region in (a) becomes narrow to some extent, it seems that the weld bead toe shape improvement can be achieved by adding Si that reduces the surface tension from the welding material.
- FIG. 3 plots the Si amount of solid wire for welding on the horizontal axis and the Si amount of steel plate on the vertical axis.
- the flank angle 5 defines the angle on the weld metal side as the flank angle among the angles formed by the tangent line of the weld bead and the extension lines of the surfaces of the steel plates 6 and 7.
- the flank angle of FIG. 4 defines the angle on the weld metal side as the flank angle among the angles formed by the tangent line of the weld bead and the extension lines of the surfaces of the steel plates 6 and 7.
- the angle in FIG. 4 is defined as the flank angle.
- FIG. 3 shows a distinction between the case where the flank angle is 55 ° or less and the case where the flank angle exceeds this.
- Lap fillet arc welding is performed with steel sheets with a thickness of 3.2 mm and welding speeds of 100 cm / min, 112 cm / min, 120 cm / min, and 150 cm / min. did. The flank angle at that time was measured according to FIG. In FIG. In FIG.
- FIG. 5 is a conceptual diagram illustrating this relationship. This plots the flank angle on the horizontal axis and the fatigue strength on the vertical axis, and indicates that when the flank angle is A, the fatigue strength is A '. When the flank angle is changed from B to A, the fatigue strength changes from B 'to A'. Since the relationship between the flank angle and the fatigue strength is represented by a straight line (or curve) that goes down from the upper left to the lower right as shown in FIG. 5, reducing the flank angle may have an effect of improving the fatigue strength. Recognize.
- flank angle is a parameter that determines the stress concentration. As the flank angle increases, the stress concentration increases, so the fatigue strength decreases accordingly. Conversely, as the flank angle decreases, the stress concentration decreases and the fatigue strength increases. Conversely, when the design fatigue strength of the welded joint is determined, the upper limit of the flank angle is naturally determined.
- the flank angle of 55 ° is about 250 MPa in fatigue strength.
- a boundary line between a point having a flank angle of 55 ° or less and a point exceeding 55 ° can be drawn.
- the upper part of this boundary line has a flank angle of 55 ° or less and is a range in which fatigue strength can be secured.
- the flank angle tends to become smaller as the boundary line becomes higher.
- FIG. 3 it was observed that the flank angle tends to decrease under the four conditions of welding speeds of 100, 112, 120, and 150 cm / min.
- the flank angle gradually decreases. That is, the weld toe shape is improved.
- an object of the present invention is to reduce the flank angle, which has a large effect on fatigue strength while ensuring welding construction efficiency. Therefore, it was confirmed that sufficient fatigue strength can be secured even at a welding speed exceeding 110 cm / min at which welding efficiency can be expected to be sufficiently high, and even 120 cm / min or more.
- the thickness of the thin steel plate to which the present invention is applied is not particularly limited. However, since a technique limited to gas shielded arc welding using a solid wire for welding is handled, the range of plate thickness that can be practically applied, especially the lower limit is about 1.6 mm. The reason for this is that spot welding or laser welding is more frequently used for steel sheets thinner than 1.6 mm rather than arc welding. The upper limit of the plate thickness was set to 4 mm. The reason for this is that in the present invention, the steel sheet is limited to a steel plate of 700 MPa class or higher where improvement in fatigue characteristics is particularly important, and the steel sheet does not need to be thickened because of high strength.
- Mn is an element added to increase the strength of steel.
- the upper limit is made 2.5%.
- addition of 0.5% or more is necessary to ensure strength.
- S is an impurity in the present invention.
- An A-based inclusion (JIS G0555) is formed by bonding with Mn and deteriorates not only the hole expandability but also the ductility, so 0.02% is made the upper limit.
- making it lower than 0.0005% raises the cost in steelmaking significantly. Therefore, it is preferable to set 0.0005% as the lower limit.
- P is also an impurity in the present invention.
- the upper limit is set to 0.03%.
- the point of limiting the amount of Si in the steel sheet is the basis of the present invention.
- the present inventors consider that the action of Si in the steel sheet is due to the enlargement of the welding arc, but it is still difficult to say that it is sufficiently clear.
- the weld metal is the same Si, but the weld toe shape is not the same.
- the steel sheet Si content is 0.4%, the weld toe shape is improved.
- Such a phenomenon has not been known so far. However, such a phenomenon occurs when the welding speed exceeds 80 cm / min. Such a phenomenon cannot be confirmed at 80 cm / min or less.
- the upper limit of the amount of Si in the steel sheet is that the amount of Si diluted from the base metal, that is, the amount of Si in the weld metal increases, and the Si combines with oxygen to form SiO 2, thereby forming the weld metal after welding. Since the amount of slag generated on the surface increases, it was set to 1.8%. In general, in the automobile field or the like, a painting process is arranged after welding, but slag present on the surface of the weld metal is not preferable in the painting process. Therefore, this value was set.
- the function of Si in the steel sheet is different from the function of adjusting the Si amount of the weld metal.
- Si affects the viscosity and surface tension of molten iron and, through this function, affects the shape of the weld toe.
- the welding speed is a high welding speed exceeding 80 cm / min, and the tendency becomes more remarkable as the speed becomes higher. That is, when the welding speed is not so high (80 cm / min or less), the weld toe shape can be controlled by improving the viscosity and the surface tension.
- the welding speed increases, the control becomes possible.
- the welding wire Si amount changes, the minimum steel plate Si amount necessary for improving the weld toe shape also changes. Therefore, the relationship between the Si amount of the steel sheet and the Si amount of the welding wire is limited. That is, if it can be satisfied that the value of the following (formula 1) is 0.32 or more, the shape of the weld toe can be improved even in high-speed welding of 120 cm / min or more or over 110 cm / min.
- Equation 1 the value of (Equation 1) is further limited so that the weld toe shape can be improved more reliably.
- the amount of Si in the welding wire is limited by the amount of Si in the steel plate to ensure the value of (Equation 1).
- the flank angle is further reduced.
- FIG. 3 also shows a line when the value of (Equation 1) is 0.40, but it can be seen that the region is shifted upward as compared with the case where the value of (Equation 1) is 0.32. . In this case, the flank angle can be further reduced, and the effect of improving fatigue strength is further increased.
- the value of (Expression 1) is set to 0.40 or more, the flank angle reduction effect is large, so that the welding speed can be further increased.
- the welding speed can be 120 cm / min or more.
- the above is the reason for limiting the essential components of the steel sheet in the present invention.
- the following elements can be selectively added as necessary, but these are all for ensuring the strength and workability of the steel sheet, and improving the weld toe shape. Not for.
- the upper limit of the welding speed was set to 150 cm / min. This is because, as already described, the welding speed is one of the factors that determine the manufacturing efficiency of the welded structure, and the higher the speed, the higher the efficiency. On the other hand, an excessive increase in speed is not preferable from the viewpoint of the weld bead shape, for example, the movement of the molten pool becomes intense. In particular, the undercut 8 in FIG. 4 tends to appear.
- An object of the present invention is to improve the fatigue strength of a welded joint, and to improve the weld toe shape, such as reducing the flank angle, is the means. From the viewpoint of improving fatigue strength, if undercut occurs, the fatigue strength decreases. Therefore, the upper limit of the welding speed was set to 150 cm / min.
- the reason why Al is added to the steel sheet in the present invention is from the viewpoint of deoxidation, not from the viewpoint of improving the shape of the weld toe portion, which is the object of the present invention, and is also disclosed in Patent Document 5 and the like. Belongs to the technology.
- the lower limit of Al was set to 0.005% as the minimum value at which the effect of deoxidation can be exhibited.
- excessive addition of Al remains in the steel sheet as an oxide. In this case, the problem of the hole expandability of the steel plate arises.
- hole expansibility is one of the important characteristics required for steel sheets. Ensuring the hole expandability is not the object of the present invention, but ensuring the hole expandability was judged to be industrially significant.
- the upper limit of 0.1% of Al addition was set as a value that can ensure hole expandability.
- the purpose of adding Ti, Nb, V, Cr, and Mo to the steel sheet is to ensure the strength of the steel sheet.
- These elements combine with C to form carbides and increase the strength of the steel sheet.
- different component ranges are set for each element.
- the lower limit of 0.005% for Ti and Nb was set as the minimum value at which an increase in strength can be expected.
- the upper limit of 0.1% for Ti and Nb was set to this value because excessive addition deteriorates the ductility of the steel sheet.
- V is also an element having the same function as Ti and Nb.
- Ti and Nb do not have precipitation strengthening
- lower and upper limits are set to values different from Ti and Nb.
- the lower limit of 0.01% of V was set as the minimum value at which an increase in strength can be expected.
- the upper limit of 0.2% was set to this value because excessive addition deteriorates the ductility of the steel sheet.
- Cr is an element that forms carbides and increases the strength in the same way as Ti, but Cr has an effect of not only precipitation hardening but also solid solution hardening.
- the lower limit of 0.1% was set as the minimum value at which an increase in strength can be expected.
- the upper limit of 1.0% was set to this value because excessive addition deteriorates the ductility of the steel sheet.
- Mo is an element having the same effect as Cr.
- the lower limit of 0.05% of Mo was set as a minimum value at which an increase in strength can be expected.
- the upper limit of 0.5% was set to this value because excessive addition deteriorates the ductility of the steel sheet.
- welding wires In the present invention, two types of welding wires are considered: solid wires and flux-cored wires.
- the lower limit value must be set higher than the base material.
- the lower limit of 0.03% is set because it is difficult to ensure the strength when the lower limit is less than 0.03%.
- the upper limit of 0.15% is set to this value because if it exceeds this limit, there is a risk of hot cracking of the weld metal.
- Mn is also an element added to increase the strength of the weld metal.
- excessive addition causes excessive curing, so the upper limit is 2.5%.
- the steel material in the present invention is intended for a steel material of 700 MPa class or more which is usually required, a certain strength is also required for a welded joint. Since addition of 0.7% or more is necessary to secure the strength, this value was set as the lower limit.
- Si is an element having an effect of deoxidizing the weld metal.
- the lower limit of Si of 0.2% was set to this value because an amount less than this would result in insufficient deoxidation, and it would be easy to form blowholes in the weld metal.
- the effect can be obtained even if Si is added in excess of the value limited by the present invention.
- the present invention deals with the thickness range used in the automobile field and the like.
- the shielding gas may be Ar-based.
- the amount of Si which is a deoxidizing element, to be small. Therefore, in this invention, 0.7% was set as an upper limit which suppresses the amount of slag generation and reduces the amount of spatter generation.
- the upper limit is preferably set to 0.6%, more preferably 0.5%.
- S is generally an impurity. Excessive addition increases the danger of weld metal toughness deterioration and weld metal hot cracking, so the upper limit was made 0.08%.
- P is also an impurity in the present invention. If the P content increases, the weld metal toughness deteriorates and the risk of hot cracks in the weld metal increases, so 0.05% was made the upper limit.
- Cu has two effects: plating solid wire for welding, increasing conductivity, and preventing rusting of the wire. Therefore, it is not always necessary to add from the viewpoint of the effect of improving the shape of the weld toe which is the object of the present invention.
- the rust of the wire may cause a problem such as a blow hole, the value is limited in the present invention.
- the addition of Cu may be disliked, and the idea that it is better not to perform Cu plating even at the expense of conductivity is spreading. Therefore, in the present invention, including the case where Cu plating is not performed, the lower limit of Cu is not particularly provided, and 0% is included.
- the lower limit of Cu addition In order to develop the effect of Cu plating, it is desirable to set the lower limit of Cu addition to 0.05%.
- the upper limit of Cu addition 0.5%, is set because the effects such as conductivity are saturated even if it is added more than this, and the risk of Cu cracking increases.
- Ti, Nb, V, Cr, Mo, and Ni which are selective elements of the welding solid wire, are elements added to secure the strength of the weld metal as the first purpose. Since it is also an element that stabilizes the welding arc, it can be added for purposes other than securing the strength.
- the lower limit of Ti of 0.01% was set as a minimum value that can be expected to increase the strength and stabilize the welding arc.
- the upper limit of 0.5% was set at an amount exceeding this value because the weld metal was excessively hardened, causing problems in joint characteristics.
- the reason why the upper limit and the lower limit of Ti are higher than the upper limit and the lower limit of the Ti addition amount of the steel sheet stipulated by the present invention is because the phenomenon that Ti of the solid wire for welding is oxidized by the welding arc is considered. is there.
- the lower limit of 0.01% of Nb was set as the minimum value at which an increase in strength can be expected.
- the upper limit of 0.1% was set at an amount exceeding this value because the weld metal was excessively hardened, causing problems in joint characteristics.
- V is also an element having the function of securing the strength like Ti and Nb.
- Ti and Nb do not have precipitation strengthening, lower and upper limits are set to values different from Ti and Nb.
- the lower limit of 0.05% of V was set as the minimum value at which an increase in strength can be expected.
- the upper limit of 0.3% was set to this value because excessive addition deteriorates the ductility of the steel sheet.
- Cr is an element that forms carbides and increases the strength in the same way as Ti, but Cr has an effect of not only precipitation hardening but also solid solution hardening.
- the lower limit of 0.05% is set as the minimum value at which an increase in strength can be expected, but is preferably set to 0.1%.
- the upper limit of 1.0% was set because excessive addition causes hardening of the weld metal and causes problems such as toughness.
- Mo is an element having the same effect as Cr.
- the lower limit of 0.05% of Mo was set as a minimum value at which an increase in strength can be expected.
- the upper limit of 0.7% is set to 0.5% because excessive addition deteriorates the toughness of the weld metal.
- Ni there are two main purposes for adding Ni. That is, there are two points: ensuring the strength of the weld metal and ensuring the fatigue strength of the welded portion. Among these, since it is necessary to limit the Ni range to a narrower range from the viewpoint of securing the second fatigue strength, the Ni range regarding this point will be described later. From the viewpoint of ensuring the strength of the weld metal, the lower limit of Ni is set to 0.3%. This lower limit was set as the minimum value at which an increase in strength could be expected. The upper limit of 12.0% was set at a value higher than this, because the microstructure of the weld metal became austenite, and there was a risk that the strength would rather decrease, and there was a risk of hot cracking.
- a range that can be actively used is set to such an extent that the joint characteristics are not adversely affected.
- S can be expected to reduce the viscosity of the weld metal and improve the weld toe shape.
- the method of adding S to the steel plate causes a problem in the steel plate characteristics. Therefore, it is preferable to add to the solid wire.
- the method of adding to the solid wire also causes the problem of hot cracking as described above if added excessively, so the upper limit was made 0.08%.
- the amount of S should be 0.02% or more.
- the toughness of the weld metal may become a problem. However, this depends on the characteristics required for the welded joint and may be selected as appropriate by comparing the weld toe shape improvement with the required toughness.
- the transformation start temperature of the weld metal is lowered and the residual stress at the weld toe is actively reduced.
- This method actively incorporates the technique of a high fatigue strength welding material into the present invention, and the technique of the high fatigue strength welding material is a technique already disclosed in Patent Documents 1 and 2 and the like. This technique and the technique provided by the present invention do not cancel each other out, and can be used as necessary.
- the lower limit of 4.0% of Ni added to the solid wire for welding was set as a minimum value at which fatigue strength improvement due to the addition of Ni can be expected when the addition amount is less than this.
- the addition amount exceeds 12.0%, the austenite is increased as the microstructure of the weld metal, the transformation expansion amount of the weld metal is small, and in some cases, there is a possibility that the transformation does not occur.
- This value was set as the upper limit because the improvement effect could not be expected.
- the upper limit of S added to the solid wire for welding is preferably 0.01%, More preferably, it is desirable to set it to 0.006%.
- the wire used for thin plate welding in the automobile field is a solid wire.
- the solid wire is cheaper than the flux-cored wire, and the solid wire is preferable from the viewpoint of painting because it has a small amount of slag generated after welding.
- the advantage that the solid wire is cheaper is the case where the production amount of the wire is large to some extent.
- the flux-cored wire can be manufactured at a lower cost than the solid wire.
- the reason for this is that when it is necessary to change the wire composition, the wire material itself must be recreated for solid wires, whereas for flux-cored wires, only the flux components to be filled need to be adjusted. This is because the components of the entire wire can be changed. In such a situation, the present inventors considered it meaningful to provide a technique that can achieve better fatigue strength with a flux-cored wire.
- the problem with flux-cored wires is that the amount of hydrogen increases in addition to the slag generation problem described above. Therefore, when manufacturing a flux-cored wire, the flux filled in the wire is dried in advance to reduce the amount of hydrogen. However, even after the flux is dried and filled in the wire, if there is a slit-like seam in the steel outer sheath of the flux-cored wire that has a risk of entering the outside air, the flux absorbs moisture from the seam, resulting in hydrogen. Increase the amount.
- C other than SiC is contained mainly in the steel outer sheath in the flux-cored wire, and is contained for the purpose of preventing disconnection in the wire drawing process during wire production.
- C other than SiC also has the effect of reducing the transformation temperature of the weld metal, but in the present invention, the content of SiC in the flux filled in the steel outer shell is adjusted according to the component system, and the weld metal The transformation temperature can be sufficiently reduced.
- the lower limit of the C content other than SiC needs to be 0.01%.
- the upper limit of the C content other than SiC is set to 0.20%.
- C in the iron powder is included as C other than SiC. Therefore, from the point of reducing the hardening in wire drawing caused by C in the steel outer shell, the iron content in which the C content in the steel outer shell is 0.15% and the remaining C amount is added as a flux. It is desirable to supplement with the C content.
- the lower limit of the content of Si other than SiC and SiO 2 is set to 0.05%.
- the weld metal is hardened, which is not preferable from the viewpoint of joint characteristics, so the upper limit of its content was set to 1.2%.
- Mn is an element necessary for ensuring the strength of the weld metal. If the content is lower than 0.2%, it becomes difficult to ensure the strength of the weld metal. Therefore, the lower limit of the Mn content is set to 0.2%.
- the reason why the lower limit of Mn can be set lower than that of the welding solid wire in the present invention is that strength is ensured to some extent by addition of C.
- the upper limit of the Mn content is set to 2.5%.
- P is an unavoidable impurity element of the weld metal.
- the upper limit of the P content is set to 0.03%.
- S is an unavoidable impurity element of weld metal, but S is said to contribute to improving the bead shape by reducing the surface tension of the molten pool. Therefore, the present invention is also effectively used.
- the flux-cored wire in the present invention is limited to the component range that achieves the reduction of residual stress, the C content is high. Therefore, the content of S is, from the viewpoint of hot cracking, the solid wire in the present invention. It is necessary to set lower than the case. Therefore, the upper limit of S is set to 0.06%.
- the SiO 2 , Al 2 O 3 , Na 2 O, and K 2 O contained in the flux are usually called slag materials. These serve as a binder when granulating the flux component before production of the flux-cored wire, and after filling the flux component in the steel outer shell, drawing to a predetermined wire diameter, It acts as a lubricant that reduces the resistance between the inner surface of the skin and the flux.
- slag materials These serve as a binder when granulating the flux component before production of the flux-cored wire, and after filling the flux component in the steel outer shell, drawing to a predetermined wire diameter, It acts as a lubricant that reduces the resistance between the inner surface of the skin and the flux.
- the workability in the wire drawing step can be ensured even if the slag material that is these oxides is reduced as compared with the conventional case.
- the lower limit of the total amount is set to 0.05%.
- the upper limit of the total amount is set to 0.4%.
- the SiC in the present invention ensures an appropriate amount of Si in the flux-cored wire, further functions as a main element C source for reducing the transformation start temperature of the weld metal, and functions as SiC having lubricity and deacidification. In the present invention, it is an essential component.
- the lower limit of SiC was set to this value because the effect of improving the wire workability and reducing the slag amount due to the lubrication and deoxidation actions of SiC was not sufficient.
- SiC content in the flux increases, there is a possibility that the weld metal hardens and the austenite structure increases and the weld metal does not transform. In such a case, SiC is purposely added to the flux-cored wire. There is no merit. For this reason, the upper limit of the SiC content in the flux-cored wire is limited to 1.2%. In the case of a flux-cored wire, the amount of Si in the wire tends to be higher than the upper limit of the solid wire.
- the function of graphite in the present invention is an alternative to SiC.
- SiC As a C source, graphite is cheaper than SiC, but on the other hand, since graphite is light, it has a manufacturing problem that graphite is scattered during the manufacture of a flux-cored wire.
- graphite is more effective than SiC in terms of the function of the lubricant in wire drawing, and the present inventors decided to treat graphite as a selective element.
- SiC and graphite have the same function as a C source, in order to take this point into consideration, the total amount of C converted values of the following (Formula 2) was created to limit the total amount of C.
- Ni, Cr, Mo and Cu are added for the purpose of improving the mechanical strength of the weld metal such as Charpy characteristics, and lowering the transformation start temperature of the weld metal and improving the fatigue strength.
- As for Cu there is another purpose of improving conductivity by plating the wire with Cu.
- Ni is an element that lowers the transformation start temperature of the weld metal and is effective for improving joint fatigue strength, and also improves joint characteristics such as strength and toughness.
- the lower limit of the Ni content needs to be 0.1% as the minimum amount at which the improvement effect of joint fatigue strength can be sufficiently expected in a low SiC component system, but preferably 0.5% It is.
- the upper limit of the Ni content the effect of reducing the transformation start temperature of the weld metal is sufficiently obtained.
- the Ni content exceeds 5.0%, the interaction with C contained in the weld metal allows the cooling to end while the austenite remains austenite without transformation to bainite or martensite where the weld metal transforms at low temperatures. Therefore, the upper limit of the Ni content is set to 5.0%.
- Cr and Mo are elements that have the effect of reducing the transformation start temperature of the weld metal and increasing the strength and hardenability.
- Cr and Mo are more effective than Ni in improving the strength of the weld metal and ensuring hardenability. Therefore, using this effect, the weld metal is transformed into a structure having a low transformation temperature such as martensite, and the weld joint
- the Cr and Mo contents must be 0.1% or more, respectively.
- Cr and Mo are less effective in improving the toughness of the weld metal than Ni, if excessively contained, the toughness of the weld metal may be lowered. 2.0%.
- Cu like Cr and Mo, is an element that has the effect of reducing the transformation start temperature of weld metal, improving strength, and ensuring hardenability.
- Cu may also be plated on the surface of the wire to ensure normal electrical conductivity.
- the lower limit of the Cu content needs to be 0.1%.
- the upper limit of the Cu content is set to 0.5%.
- 6.0% was set as the upper limit of the total amount of one or more of Ni, Cr, Mo and Cu. This is because if the total content exceeds 6.0% and is excessively contained, the weld metal does not transform into bainite or martensite that transforms at a low temperature in the cooling process after welding, and remains in an austenitic structure. Therefore, it is difficult to improve the joint fatigue strength. For this reason, it is preferable to make the upper limit of content of the said total content 6.0%.
- there is no particular lower limit when adding one or more of Ni, Cr, Mo and Cu but since a lower limit is set for each additive element, Naturally, there is a lower limit of 0.1%.
- the lower limit of the total content when it is necessary to further increase the fatigue strength, it is desirable to set the lower limit of the total content to 1.5%.
- the addition of less than 1.5% is added for the purpose of improving mechanical characteristics such as Charpy characteristics, but whether to improve Charpy characteristics or fatigue characteristics depends on the purpose of those skilled in the art using the present invention. In addition, it is not particularly difficult for those skilled in the art to determine the addition amount.
- B is a hardenable element, which ensures the hardenability of the weld metal, makes the microstructure of the weld metal a stronger structure, and suppresses the formation of a structure that starts transformation at a high temperature and transforms at a lower temperature. Has the effect of making the microstructure. Since the weld metal has a higher oxygen content than steel sheets, B may bind to oxygen and lose its effect. Therefore, the hardenability by B in the weld metal and the tensile strength and fatigue strength by microstructure control. In order to improve the content, the lower limit of the B content is preferably 0.001%. On the other hand, the upper limit of the amount of B added is set to 0.015% because adding more than this causes the risk of cracking in the weld metal.
- Nb, V, and Ti are all elements that have the function of forming carbides in the weld metal to increase the strength, and by containing a small amount of one or more of Nb, V, and Ti in the weld metal.
- the joint strength can be improved. If the lower limit of the total content of one or more of Nb, V, and Ti is less than 0.005%, improvement in joint strength cannot be expected so much, so the lower limit of the total content is 0.005%. Is preferable. On the other hand, if the total content exceeds 0.3%, the strength of the weld metal becomes excessive and a problem occurs in joint characteristics. Therefore, the total content upper limit is preferably set to 0.3%.
- Ti in addition to the effect of improving the strength of the weld metal, it has a function of stabilizing the welding arc. Therefore, when Ti is contained, it is preferable to contain 0.003% or more of Ti.
- the range in which the flux-cored wire S can be actively used is set to such an extent that the joint characteristics are not adversely affected.
- S can be expected to reduce the viscosity of the weld metal and improve the weld toe shape.
- There are two methods for securing the amount of S in the weld metal a method of adding S to the steel plate and a method of adding S to the welding wire.
- the method of adding S to the steel plate causes a problem in the steel plate characteristics. Therefore, it is preferable to add to the flux-cored wire.
- the method of adding to the flux-cored wire too causes the problem of hot cracking as already described, so the upper limit was made 0.06%.
- the amount of S should be 0.02% or more.
- the toughness of the weld metal may become a problem. However, this depends on the characteristics required for the welded joint and may be selected as appropriate by comparing the weld toe shape improvement with the required toughness.
- the upper limit of S is preferably set to 0.03% from the viewpoint of crack sensitivity.
- An arc stabilizer is an element which has the effect
- the arc stabilizer can be used as long as it is a compound of Na, Al, F such as cryolite (Na 3 AlF 6 ) without using an oxide such as Na 2 O or K 2 O. Since a stabilizing effect is obtained, it is preferable to contain it as a compound other than an oxide from the viewpoint of reducing the amount of slag generated.
- the lower limit of the content of the arc stabilizer other than the oxide type is preferably 0.05%.
- the upper limit of the content is preferably 0.5%.
- the gas used for the shielding gas is CO 2 or Ar, but regarding Ar, it is still impossible to use 100% Ar for the shielding gas because of the stability of the arc.
- the method using 100% CO 2 is sufficiently possible within the range of the prior art if Si, which is a deoxidizing element, is used effectively, and also within the range of Si disclosed in the present invention.
- 100% CO 2 can be used as a shielding gas, and there is a merit that CO 2 gas is cheaper than Ar gas.
- the reason why the shielding gas mainly composed of Ar gas is used is that there is a merit that sputtering can be reduced.
- Ar gas is an inert gas, a minimum amount of CO 2 gas is required.
- the lower limit of 5% by mass of the CO 2 gas with respect to the shielding gas mainly composed of Ar gas is set to this value because the welding arc becomes unstable when the lower limit is less than 5%.
- the upper limit of 25% is exceeded, the amount of sputtering increases, and this value is set because it is not much different from the case where 100% CO 2 gas is used as the shielding gas.
- the reason for adding O 2 gas is to reduce the cost of the shielding gas, and is not directly related to the effect of improving the weld toe shape intended by the present invention.
- O 2 gas 100%
- Ar gas containing a certain amount of O 2 can be manufactured at a relatively low cost. Even if O 2 gas is contained to some extent, the effect of improving the weld toe shape is not lost.
- the lower limit of 2% of the component limitation range of the O 2 gas has a content rate lower than this, and this affects the cost of Ar gas.
- the upper limit of 4% is set to this value because an oxygen content of the weld metal increases and a problem on toughness occurs when the added amount exceeds the upper limit.
- Table 1 is a table of steel plate components used in Example 1. The purpose of Example 1 is to investigate the hole expandability of a steel plate.
- a steel slab having the components shown in Table 1 is heated to a heating temperature of 1150 to 1250 ° C., hot-rolled to a finishing temperature of 820 to 900 ° C., and then cooled at a cooling rate of 35 to 75 ° C./second.
- the steel sheet was wound at a winding temperature of 400 to 550 ° C. to obtain a hot-rolled steel sheet having a thickness of 2.6 mm. Since various tensile strengths can be obtained by controlling the cooling rate and the like, Table 1 also shows the tensile strength of the steel sheet.
- a square test piece of 250 mm ⁇ 250 mm was collected from these hot-rolled steel sheets, a circular hole with a diameter of 30 mm was punched in the center, and then a hole expansion test was performed with a conical punch with a vertex angle of 60 °.
- the hole expandability is determined by expanding the hole with a conical punch, observing a crack generated on the punched surface, measuring the diameter d when the crack has penetrated to the front and back surfaces of the plate, and increasing rate ⁇ (d-30) ⁇ 100/30 ⁇ . When the diameter is doubled to 60 mm, the hole expandability is 100%.
- Table 1 lists the components, tensile strength, and hole expandability of the steel sheet.
- the hole expansibility tends to decrease as the strength of the steel material increases. Therefore, the hole expandability is higher than that of a steel material of 700 MPa class or higher, which is handled by the present invention, and a lower strength material such as a 400 MPa class steel material. It is not appropriate to evaluate spreadability. Steel materials of 700 MPa or more should be compared and their superiority or inferiority should be evaluated. For this reason, the manufacturing conditions were selected so that the steel materials shown in Table 1 except for B13 and B14 had a strength of 700 MPa or more.
- the hole expansibility exceeds 70%, and it can be seen that good characteristics are exhibited.
- These steel sheets are comparative examples because Si is outside the scope of the present invention, but it can be seen that the hole expandability is good even if Si is below the lower limit of the present invention.
- Comparative Examples B13 and B14 although Si is within the range of the present invention example, Mn and C are outside the range of the present invention, and the strength is not 700 MPa class. Since the present invention is directed to a steel material of 700 MPa class or higher where fatigue problems become prominent, B13 and B14 are comparative examples in the present invention.
- Example 2 regarding the improvement of the weld toe shape and the fatigue test is shown below.
- Example 1 a lap fillet arc welded joint was prepared using a steel sheet having a hole expansibility exceeding 70%, and a weld toe shape and a fatigue test were performed.
- the lap fillet arc welded joint is one of the most commonly used welded joint shapes in the thickness range of the present invention, particularly in automobile underbody parts.
- Table 2 shows the components of the solid wire for welding used when producing the welded joint.
- a wire component outside the scope of the present invention is shown as a comparative example in the remarks column. What is described in the remarks column as an example of the present invention is within the scope of the present invention as a wire component, but since the present invention is defined as a combination with a steel plate, the remarks column in Table 2 Is for reference only.
- Tables 3 to 5 show the welding conditions and the composition of the shielding gas used. The results of Examples in Tables 3 to 5 are all for the case where the plate thickness of the steel plate is 2.6 mm.
- the influence of the welding speed can be investigated by changing the welding speed. At this time, the current is set so that a welded joint can be formed by one-pass welding. Specifically, 60 cm / min: 120 A, 85 cm / min: 170 A 100 cm / min: 200 A, 120 cm / min: 240 A 130 cm / min: 260 A, 140 cm / min: 280 A 170 cm / min: 320 A was set.
- a lap fillet arc welded joint was produced, and a cross-sectional macro was taken therefrom, and the flank angle and undercut depth defined in FIG. 2 were measured. When there was no undercut, the undercut depth was defined as 0. Moreover, the plane bending fatigue test piece shown in FIG. 6 was extract
- collected from the same welded joint, and the fatigue test was implemented. In the case of Example 2, the plate thickness 1 and the plate thickness 2 in FIG. 6 are 2.6 mm. When carrying out the fatigue test, a strain gauge was attached in the vicinity of the weld toe on the surface of the test piece to check the stress state on the surface. The repetitive stress was applied under the condition of stress ratio, R 0.1.
- the stress amplitude is 100 MPa
- the maximum stress is 111 MPa
- the minimum stress is 11 MPa
- the fatigue strength was defined as the maximum stress range in which the fatigue test was performed under these conditions and the fatigue fracture did not occur even when the stress was applied 2 million times.
- Tables 3 to 5 show the test results of flank angle, undercut depth, and fatigue strength. Tables 3 to 5 show a series of examples. As described above, since the fatigue strength required for the lap fillet welded joint of thin steel plates is about 250 MPa, the fatigue strength is 250 MPa or more as a guideline for evaluation.
- No. No. 1 is an example in which the fatigue strength was 270 MPa because the steel plate Si and the value of (Equation 1) were outside the scope of the present invention, but the welding speed was as slow as 70 cm / min and the weld toe shape was good. is there. That is, it can be seen that the weld toe shape can be improved by slowing the welding speed in accordance with the components of the steel sheet, but the welding efficiency must be sacrificed accordingly.
- the same combination of steel plate and welding wire has a fast welding speed.
- the shape of the weld toe was not good, and the fatigue strength was as low as 180 MPa and 170 MPa, respectively.
- No. 3, no. 4, no. 44 shows similar results. However, no. 3, no. 4, no. No.
- steel sheet Si is as low as 0.17%, but wire Si is as high as 1.55%, and the value of (Equation 1) is within the scope of the present invention.
- the fatigue strength is no. 3 is high, but no. In No. 44, since the welding speed is 120 cm / min, the fatigue strength is as low as 180 MPa. That is, the steel sheet Si amount alone has a single function, and shows that it has an effect that cannot be supplemented by the wire Si.
- no. Nos. 5 and 19 are examples in which blowholes are generated due to a lack of Si in the wire, but the weld toe shape and fatigue strength are not measured. No.
- the amount of wire Ni must be within the scope of the present invention.
- No. No. 41 is a wire Mn of 3.0%, which exceeds the range of the present invention.
- the weld metal hardness is higher than 400 in terms of Vickers hardness, which indicates that there is a problem in ductility. Therefore, the measurement of the weld toe shape and fatigue strength was not carried out.
- Example 2 the influence of the plate thickness was investigated using the steel plate B03 and the welding solid wire W05 used in Example 2.
- the plate thickness was subjected to the rolling conditions as shown in Example 1 so that the finished plate thickness was 2.0, 2.6, 4.0, 7.0 mm.
- the test method is the same as in Example 2.
- Table 6 shows the results. Both the steel plate and the wire have a component system within the scope of the present invention, and the value of (Equation 1) is also within the scope of the present invention. No. which is a plate thickness within the scope of the present invention. In 101101, 102, 106, and 108, the flank angle was 50 ° or less, and the fatigue strength was 280 MPa or more, which was a favorable value. No.
- 105 is an example in which the fatigue test result was good, but in order to produce a welded joint by one-pass welding, the welding speed had to be 40 cm / min. In this welding speed condition, it is not necessary to bring the steel plate and the welding wire within the scope of the present invention. It is clear from 1 and the like.
- a desirable board thickness range is 4 mm or less from a practical viewpoint.
- the lower limit is not particularly implemented, but it is considered that the welding method is about 1.6 mm from a practical point of view in view of the plate thickness range in which spot welding and laser welding are mainstream.
- No. 106 is an example in the case where the steel plates 6 and 7 in FIG. 4 have different thicknesses.
- the fatigue strength is higher than 250 MPa, the flank angle is lower than 50 °, and good results are obtained. ing.
- Example 4 The purpose of Example 4 is to investigate the components of the flux-cored wire and its characteristics. Tables 7 and 8 show the results of investigating the mass% of each component, the filling rate, the wire drawability, and the Charpy absorbed energy with respect to the total wire mass in the flux-cored wire. In addition, B06 of Table 1 was used as a steel material.
- Tables 7 and 8 there are more test items than Table 2 which is a table of examples of welding solid wires.
- This is a characteristic of the flux-cored wire, there is a flux component, and in the flux-cored wire according to the present invention, the amount of C addition is set higher than the solid wire for welding, so the Charpy characteristic of the weld metal is a problem. Therefore, Charpy characteristics are also listed in Table 7 and Table 8, and wire drawability, slag generation, scattering characteristics when using graphite, etc. compared to solid wire This is because there are many items to be evaluated.
- the wire symbols of 100 to 110 are flux-cored wires within the scope of the present invention, and 150 to 165 have wire components already outside the scope of the present invention.
- the flux scattering property is a comparison of the ratio of the amount of graphite prepared for producing the flux and the amount of graphite in the flux just before filling the wire. If the graphite does not scatter, these coincide with each other, and the scattering rate becomes 0%. However, when the graphite scatters, the graphite decreases just before the wire filling. Scatterability was evaluated by this reduction rate. The wire drawability was evaluated based on whether or not a breakage occurred during wire production.
- a steel plate with a thickness of 3.2 mm was butt welded with each wire, and a 1/4 size Charpy test piece with a 2 mm V notch machined into the center of the weld metal was sampled, and a Charpy test was conducted at 0 ° C. The value was evaluated.
- the amount of slag was evaluated by the weight of slag generated on the surface of the weld metal when bead-on-plate welding with a weld bead length of 250 mm was performed.
- Wires 150, 151, and 159 are slag materials that are outside the scope of the present invention, and the amount of slag produced exceeds 0.1 g, indicating that there is a problem in paintability.
- the amount of slag generated is less than 0.1 g.
- the wire 150 had a good weld bead.
- SiC is also less than the scope of the present invention.
- the slag material is excessively added to the wire 151, a disconnection problem occurs. There wasn't. Then, when the amount of slag was measured using the wire 151, slag generation exceeded 0.34g and 0.1g. That is, in order to prevent disconnection while suppressing slag generation, it is necessary to use SiC instead of slag material.
- the wire 152 is an example in which SiC exceeds the range of the present invention, and as a result, (Equation 2) also exceeds the range of the present invention, and a crack occurs in the weld. Even when SiC was within the range of the present invention, the same cracking occurred in the wire 165 in which (Equation 2) exceeded the range of the present invention.
- the wire 153 had Si exceeding the range of the present invention, and due to excessive Si, the Charpy test was less than 10 J.
- the wire 155 is a case where C exceeds the range of the present invention, and the Charpy value is also less than 10 J. In the wire 156, Si was less than the range of the present invention, and defects such as blow holes occurred in the welded portion.
- the wire 157 had C below the range of the present invention, and the strength of the steel outer shell was insufficient, a wire breakage problem occurred during wire production, and the wire could not be produced.
- the wire 158 had Mn below the range of the present invention, and the disconnection problem occurred for the same reason as the wire 157.
- Wires 160 to 162 and 164 have a total of Nb, V, and Ti exceeding the range of the present invention, and have Charpy values of less than 10 J.
- the wire 163 is one in which B exceeds the range of the present invention, and a crack is generated in the welded portion.
- the wires in Table 8 are 200 to 210 within the scope of the present invention. These wires contain a relatively large amount of Cu, Ni, Cr, and Mo as compared with the wires in Table 7. Wires 250 to 255 are comparative examples.
- the wire 250 had a slag material exceeding the range of the present invention, and the slag amount exceeded 0.3 g and 0.1 g. Although this tendency is also observed in the examples in Table 2, it was confirmed also in the component system to which Cu, Ni, Cr, and Mo were added.
- the wires 251 and 252 are those in which the total of these four elements exceeds the range of the present invention, but from Table 3, there is no particular problem. This point will be described in Example 5 described later.
- the wire 253 has a total of Nb, V, and Ti exceeding the range of the present invention. Therefore, Charpy values were less than 6J and 10J.
- the wire 254 is made of no added SiC, and the slag material is limited within the scope of the present invention, and uses graphite to prevent wire breakage. Therefore, the graphite scattering property is 40%. When the scattering property is so high, it becomes extremely difficult to manage the wire manufacturing process, and there is a risk that a slight change in the manufacturing process may greatly change the wire component. In such a case, it means that it is difficult to produce a high-quality wire.
- the wire 255 has a SiC addition amount that is below the range of the present invention, which causes a problem of wire breakage.
- the wires 200 to 210 had a slag generation amount of less than 0.1 g, had no problems with wire drawing and scattering, and had a Charpy value of 20 J or more.
- Example 5 there is no problem among the steel materials and wires used in Examples 1 and 4, that is, “Example of the present invention” is described as a reference in the remarks column of Tables 1 and 8-9.
- Example of the present invention a lap fillet weld was performed using a part of which is described as “Comparative Example”, and a fatigue test was performed.
- the table also shows the composition of the shielding gas used.
- the results of Examples in Tables 10 to 12 are all for the case where the plate thickness of the steel plate is 2.6 mm.
- the influence of the welding speed can be investigated by changing the welding speed.
- the current is set so that a welded joint can be formed by one-pass welding. Specifically, 60 cm / min: 120 A, 85 cm / min: 170 A 100 cm / min: 200 A, 120 cm / min: 240 A 130 cm / min: 260 A, 140 cm / min: 280 A 170 cm / min: 320 A was set.
- the stress amplitude is 100 MPa
- the maximum stress is 111 MPa
- the minimum stress is 11 MPa
- the fatigue strength was defined as the maximum stress range in which the fatigue test was performed under these conditions and the fatigue fracture did not occur even when the stress was applied 2 million times.
- Tables 9 to 11 show the test results of flank angle, undercut depth, and fatigue strength.
- Tables 10 to 12 show a series of examples. Except for Table 12 where the influence of the plate thickness was investigated, the plate thickness 10 and the plate thickness 11 of the steel plates 6 and 7 in FIG. 6 are 2.6 mm. .
- Table 9 is described in Table 1 as “Invention Example” in the remarks column of Table 1, B02 to B11, B25, B26, and “Comparative Example” in the remarks column of Table 1.
- B01 and B12 are used, and welding wires are prepared in lap fillet welded joints using the wires 100 to 110 described in Table 2 as “examples of the present invention” in the remarks column, and subjected to fatigue tests. It shows the test results when a piece was taken and a fatigue test was carried out.
- the reason for using B01 and B12, which are comparative examples of steel materials, is that no particular problems have occurred at the stage of Table 1.
- the reason why the wires 150 to 165 in Table 8 were not used is that problems such as the Charpy value, wire drawability, and slag generation amount had already occurred before the fatigue test.
- the Si of the steel plate is lower than the present invention.
- the wire 101 contains Si twice or more than the wire 100, but the shape of the toe is still not improved.
- the influence of the steel plate Si is not only the influence of the base material dilution, but also the wire Si. It means that it cannot be supplemented with.
- No. No. 4 is within the scope of the present invention for both the steel plate Si and the wire Si, and is an example in which the flank angle is less than 55 ° and the fatigue strength is 300 MPa or more even at a welding speed of 140 cm / min.
- No. 1 with a welding speed of 170 cm / min.
- the flank angle exceeded 55 °, and undercutting occurred, so the fatigue strength was low. That is, if the welding speed exceeds the range of the present invention, the effect of improving fatigue strength cannot be realized.
- No. Nos. 7 to 13 are examples of the present invention, and the effects of selected elements in the steel sheet were observed. As already shown in Table 1 of Example 1, these elements can be secured to the extent that mechanical characteristics can be secured. It was shown that the fatigue improvement effect can be obtained even with the addition of. Of these, No. 9 and 10 are examples in which 3% of oxygen was added to the shielding gas, and the fatigue improvement effect was sufficiently obtained.
- No. Nos. 16 to 20 use B02 which is a component system within the scope of the present invention for the steel sheet, and change the wire to 100 and 102 to 105 within the scope of the present invention.
- Table 2 of Example 2 all of these wire components are within the scope of the present invention, and even if a selective element is added within this component range, a sufficient fatigue doctrine effect is obtained, and all fatigue components are fatigued.
- the strength is 300 MPa or more.
- No. 21 is an example using 100% CO 2 as the shielding gas, and the fatigue improvement effect was confirmed as in the other examples of the present invention.
- No. Nos. 24-28 are examples using 106-110 wires in which a large amount of S was added to the wires. Compared to 8, the flank angle was slightly smaller, and as a result, the fatigue strength was slightly increased. This is considered to be due to the addition of a large amount of S.
- the wires 106 to 110 are examples in which S is higher than the wire 100 in Table 2.
- the Charpy value tends to decrease, whether to give priority to improving fatigue or securing Charpy is: What is necessary is just to determine according to the required characteristic with respect to the coupling of an applied structure, and it can be easily judged by those skilled in the art.
- No. Nos. 29 to 31 are examples in which a steel material having a relatively high Si content is used, which is characterized in that the value of the formula (1) is large and the fatigue strength is improved.
- Table 10 was carried out mainly for the purpose of investigating the influence of wire selection elements, Cu, Ni, Cr and Mo.
- the data shown in Table 5 is obtained by combining the steel plates B01, B04, and B06 in Table 1 of Example 1, using the wires 200 to 210, 251, and 252 in Table 3 of Example 2, and overlapping them. It is a fatigue test result when producing a fillet joint. No. 51 is the case where the Si content of the steel sheet is below the range of the present invention, but the flank angle exceeds 55 °, which is not preferable from the viewpoint of fatigue strength. However, the fatigue strength was 300 MPa or more.
- No. No. 52 is that the Si amount of the steel sheet is within the scope of the present invention and (Equation 1) is also within the scope of the present invention.
- Equation 1 is also within the scope of the present invention.
- the fatigue strength is further improved and exceeds 400 MPa when the wire 200 having a large amount of addition of elements such as Cu, Ni, Cr, and Mo is used.
- This tendency is 53, 54, 55 and 57 were also confirmed.
- This is considered that the effect of reducing the residual stress due to the addition amount of elements such as Cu, Ni, Cr, and Mo is added, and the fatigue improvement effect is increased.
- No. Nos. 56 and 58 have a fatigue strength of 360 MPa, which is sufficiently improved. It was not until it reached 400 MPa like 52.
- No. 59 and 60 are within the scope of the present invention, but the amount of element addition of Cu, Ni, Cr, Mo, etc. in the wire exceeds the scope of claim 11 of the present invention. Both fatigue strengths exceed 400 MPa, and the improvement effect is great. Therefore, it is shown that there is a sufficient effect as a measure for improving fatigue.
- the wires 251 and 252 contain many alloying elements, the fatigue strength is No. 1. 52. This indicates that even if these element addition amounts exceed 6% in total, no further improvement in fatigue can be obtained. In that sense, it can be determined that the wires 251 and 252 have a high wire manufacturing cost and little industrial merit. Therefore, it is desirable that the wire component range be within the scope of claim 11 of the present invention.
- No. 61 to 65 are examples using wires 207 to 210 having a relatively high S.
- No. No. 61 has a high fatigue strength of 430 MPa because the alloying element of the wire is relatively high, and the effect of reducing the residual stress in addition to the effect of improving the shape of the toe is considered.
- No. Nos. 62 to 65 have a fatigue strength of 360 MPa or more but do not reach 400 MPa. This is thought to be due to the fact that fatigue improvement was manifested in the toe shape improvement effect and no effect on the residual stress reduction effect was added.
- no. 61 to 65 were all good with a flank angle of less than 40 °. This is considered that the effect of S was filled in addition to satisfying the range of Si in the present invention.
- adding a large amount of S may cause problems such as Charpy value and cracking, so it is necessary to determine the usage considering the required characteristics of the joint. It can be judged.
- Table 11 shows the effect of plate thickness.
- the steel plate is B02, the steel plate component is within the scope of the present invention, the wire is 100, and the wire component is also within the scope of the present invention.
- the joint is No. 101, 102, and 108.
- the plate thickness was 7.0 mm, welding was not possible unless the welding speed was 40 cm / min. If it tried to exceed 110 cm / Min, the fillet leg length was insufficient, resulting in two passes. No.
- the fatigue strength of 101, 102, 108 is 290 MPa or more.
- the plate thickness is 4.0 mm, the result is slightly less than 300 MPa.
- No. 106 and 109 are examples in which the plate thickness 1 and the plate thickness 2 are different from each other. However, it has been found that if both plate thicknesses are within the preferable application range of the present invention, the fatigue strength is improved.
- the weld toe shape can be improved and the fatigue strength is all better than 250 MPa.
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Abstract
Description
また、特許文献5~9には疲労強度に優れた鋼板に関する技術が開示されている。
前記薄鋼板が、質量%で、
C :0.02~0.15%、
Si:0.2~1.8%、
Mn:0.5~2.5%、
P :0.03%以下、
S :0.02%以下
を含有する薄鋼板であり、前記薄鋼板と該溶接用ワイヤが含有するSiが、下記(式1)の値が0.32以上になるように組み合わせることを特徴とする、高強度薄鋼板の隅肉アーク溶接方法。
但し、Si(鋼板)は前記薄鋼板のSi量を、また、Si(ワイヤ)は前記溶接用ワイヤの全Si量を示す。
Al:0.005~0.1%
を含有することを特徴とする、上記(1)または(2)項に記載の高強度薄鋼板の隅肉アーク溶接方法。
Ti:0.005~0.1%、
Nb:0.005~0.1%、
V :0.01~0.2%、
Cr:0.1~1.0%、
Mo:0.05~0.5%
のいずれか1種または2種以上を含有することを特徴とする、上記(1)ないし(3)項のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
C :0.03~0.15%、
Si:0.2~2.0%、
Mn:0.7~2.5%、
P :0.05%以下、
S :0.08%以下、
Cu:0.5%以下(0%を含む。)
を含有し、残部鉄及び不可避不純物からなる溶接用ソリッドワイヤを用いることを特徴とする上記(1)ないし(4)項のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
Ti:0.01~0.5%、
Nb:0.01~0.1%、
V :0.05~0.3%、
Cr:0.05~1.0%、
Mo:0.05~0.7%、
Ni:0.3~12.0%
のいずれか1種または2種以上を含有することを特徴とする、上記(5)項のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
Ni:4.0~12.0%
に制限することを特徴とする、上記(6)項に記載の高強度薄鋼板の隅肉アーク溶接方法。
鋼製外皮およびフラックスの一方または双方に、ワイヤ全体での合計の質量%で、
C(SiC中のCを除く。):0.01~0.20%、
Si(SiCおよびSiO2中のSiを除く。):0.05~1.2%、
Mn:0.2~2.5%、
P:0.03%以下、
S:0.06%以下、
さらに、鋼製外皮内に充填されるフラックスとして、ワイヤ全体の質量%で、
SiC:0.05~1.2%
を含有するとともに、
SiO2、Al2O3、Na2OおよびK2Oの1種または2種以上を合計で0.05~0.4%含有し、残部が鉄および不可避不純物からなる溶接用フラックス入りワイヤとすることを特徴とする上記(1)ないし(4)項のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
グラファイト:0.02%以上
含有し、かつ下記(式2)で定義されるC換算値の合計量が0.15~0.45%である溶接用フラックス入りワイヤであることを特徴とする、上記(9)項に記載の高強度薄鋼板の隅肉アーク溶接方法。
但し、上記[グラファイト]、[SiC]は、それぞれワイヤ全体に対するグラファイト、SiCの質量%を示す。
Ni:0.1~5.0%、
Cr:0.1~2.0%、
Mo:0.1~2.0%、
Cu:0.1~0.5%
の1種または2種以上を合計で0.1~6.0%含有することを特徴とする、上記(9)または(10)項のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
B:0.001~0.015%
を含有することを特徴とする、上記(9)ないし(11)項のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
S:0.02~0.06%
を含有することを特徴とする、上記(9)ないし(14)項のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
CO2:5%以上25%以下、
O2 :4%以下(0%を含む。)
を含有し、残部Arおよび不可避不純物からなるシールドガスを用いることを特徴とする、上記(1)ないし(15)項のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
(17) 引張強さが700MPa以上の高強度薄鋼板の隅肉アーク溶接継手において、溶接速度が80cm/min超、特に110cm/min超150cm/min以下で行ったガスシールドアーク溶接継手であって、
前記薄鋼板が、質量%で、
C :0.02~0.15%、
Si:0.2~1.8%、
Mn:0.5~2.5%、
P :0.03%以下、
S :0.02%以下
を含有し、残部鉄及び不可避不純物からなる薄鋼板であり、前記薄鋼板と前記溶接用ワイヤが含有するSiが、前記(式1)の値が0.32以上になるように組み合わせたことを特徴とする、高強度薄鋼板の隅肉アーク溶接継手。
(18) 前記(式1)の値が0.40以上になるように、前記薄鋼板と前記溶接用ワイヤとを組み合わせることを特徴とする、上記(17)項に記載の高強度薄鋼板の隅肉アーク溶接継手。
一方、本発明では、後述するように、このような鋼板の成分を溶接材料で補うということができない現象を利用するものである。このような現象が生じるためには、溶接ビード形状決定因子として、溶融プールの表面張力以外の材料因子があるためと考えられるが、それがどのようなメカニズムで影響しているかは必ずしも明確ではない。
しかし、本発明のように、溶接止端形状を決定する材料因子が溶融プールの成分以外にも存在することは、これまで注目されてこなかった因子の発見でもあるために、従来期待されていた以上の形状改善が期待できる。
一方、本発明の目的は、溶接施工効率を確保しつつ、かつ、疲労強度に与える影響が大きいフランク角を小さくすることが目的である。そのため、溶接施工効率が十分高くなることが期待できる溶接速度110cm/min超、さらには120cm/min以上であっても、十分疲労強度が確保できることが確認された。
鋼板Si量の下限、0.2%は、溶接ビード止端形状改善であるSiの働きとして決定した。
鋼板Si量の上限は、母材から希釈されてくるSi量、すなわち溶接金属中のSi量が増加し、そのSiが酸素と結合しSiO2を形成することにより、溶接施工後の、溶接金属表面に生成するスラグ量が多くなってくるため1.8%と設定した。一般に、自動車分野などでは、溶接施工後に塗装工程を配置しているが、溶接金属表面に存在するスラグは塗装工程では好ましくない。そのため、この値を設定した。
(式1)の値が0.32以上であることは、母材希釈に関係なく、満足しなければならない。それは、本発明は、単なる溶接金属の成分調整を利用した技術ではないからである。この点が、従来技術と大きく相違するところである。
図3には、(式1)=0.32の直線が描かれている。図3よりわかるように、(式1)の値が0.32以上となる条件のとき、フランク角が55°以下となる。すなわち、鋼板のSi量と溶接ワイヤのSi量で決まる、(式1)の下限0.32は、これを下回る値では、高溶接速度では、溶接止端部の形状改善効果が得られないためこの値を設定した。上限は特に定めていないが、鋼板および溶接ワイヤのSi量の上限値からおのずと範囲が限定される。
なお、(式1)の値は、鋼板及び溶接用ワイヤの両方のSi量で決定され、それぞれのSi量を独立に決定することができないが、当業者であればそれは容易に決定することができ、特に問題が生じるようなことではない。
さらに、(式1)の値を0.40以上にすれば、フランク角はさらに低減する。図3には、(式1)の値が0.40の場合の線も描かれているが、(式1)の値が0.32の場合より領域が上方にシフトしていることがわかる。この場合、フランク角はさらに低減させることが可能であり、疲労強度の向上効果はより大きくなる。(式1)の値を0.40以上にする場合は、フランク角低減効果が大きいため、溶接速度をさらに上げることが可能となる。例えば、溶接速度を120cm/min以上とすることもできる。
その一方で、過剰な高速化は、溶融プールの動きを激しくするなど、溶接ビード形状の観点からは、好ましくない。特に、図4におけるアンダーカット8が出やすくなる傾向にある。本発明の目的は、溶接継手の疲労強度向上であり、フランク角低減などの溶接止端形状改善は、その手段である。疲労強度向上の観点からは、アンダーカットが発生してしまうと、疲労強度は低くなる。そこで、溶接速度の上限を150cm/minと設定した。もちろん150cm/minの溶接速度を超えると、すぐに継手の疲労強度が低下するものではない。溶接条件によっては、これより速い溶接速度でやっても問題ない。しかし、図3に示すように、本発明に従えば、150cm/minの高速溶接においても、十分な疲労強度を確保できることを確認している。
グラファイトの下限、0.02%は、これより少ないグラファイトでは、グラファイト添加の効果が発現できなくなるのでこの値を設定した。グラファイトの上限は、本発明では特に設けていないが、(式2)の範囲を限定しているため、グラファイトの上限はおのずと制限される。また、(式2)の下限、0.15%は、これを下回る下限を設定すると、グラファイトの含有量を0.02%未満にしなければならないためこの値を設定した。一方、上限の0.45%は、これを上回る添加量では、溶接金属のCレベルが高くなりすぎ、溶接金属の硬化性、靭性、割れ感受性の問題が生じてくるのでこの値を設定した。
次に、本発明におけるシールドガスの限定理由について述べる。
60cm/min:120A、 85cm/min:170A
100cm/min:200A、120cm/min:240A
130cm/min:260A、140cm/min:280A
170cm/min:320A
と設定した。
一方、No.5、19は、本発明の範囲内であるがワイヤのSi不足によるブローホールが発生した例で、溶接止端形状および疲労強度は測定していない例である。
No.13は、成分的には本発明の範囲内にあるが、溶接速度が170cm/minと速く、フランク角は55°と比較的小さかったが、アンダーカットが発生し、溶接止端形状の改善ができなかった例である。なお、No.13は、No.12のように、溶接速度を本発明の範囲内に設定すれば、疲労向上効果が期待できる。また、No.13以外にも、表3のNo.11、表4のNo.21、23はいずれも溶接速度が150cm/minを上回っており、すべてアンダーカットが発生し、かつフランク角も大きくなった例で、疲労強度は、250MPaに達していない。
No.16、は、鋼板Si、ワイヤSiともに本発明の範囲内であるが、(式1)の値が本発明の範囲外になっているものである。すなわち、鋼板、ワイヤのSi量だけでなく、(式1)の値も本発明の範囲内にしなければならないことを示す例である。No.25は、鋼板Si量が低く、(式1)の値も低くなった例である。これら比較例では、溶接速度が70cm/minの場合を除き、フランク角は全て55°を上回っており、疲労強度は250MPaに達していない。
No.42は、ワイヤNiが高く、そのため、高温割れが発生し、試験ができなくなった例である。Ni添加で疲労強度をさらに改善させるためには、No.35のように、ワイヤNi量を本発明の範囲内にする必要がある。No.41は、ワイヤMnが3.0%と本発明の範囲を超えているものである。この溶接継手の場合、溶接金属硬さがビッカース硬さで400を上回っており、延性上問題があることがわかったものである。そのため、溶接止端形状と疲労強度の測定は実施しなかったものである。
60cm/min:120A、 85cm/min:170A
100cm/min:200A、120cm/min:240A
130cm/min:260A、140cm/min:280A
170cm/min:320A
と設定した。
No.29~31は、鋼材のSi量が比較的高い鋼材を用いた例であり、(1)式の値が大きいのが特徴で、疲労強度が向上した例である。
2 Si添加後Fe原子
3 Si
4 ワイヤ
5 フランク角
6 鋼板
7 鋼板
8 アンダーカット深さ
9 試験片
10 板厚
11 板厚
Claims (18)
- 引張強さが700MPa以上の高強度薄鋼板の隅肉アーク溶接方法において、溶接速度が80cm/min超、特に110cm/min超150cm/min以下であって、
前記薄鋼板が、質量%で、
C :0.02~0.15%、
Si:0.2~1.8%、
Mn:0.5~2.5%、
P :0.03%以下、
S :0.02%以下
を含有する薄鋼板であり、前記薄鋼板と該溶接用ワイヤが含有するSiが、下記(式1)の値が0.32以上になるように組み合わせることを特徴とする、高強度薄鋼板の隅肉アーク溶接方法。
Si(鋼板)+0.1×Si(ワイヤ) ・・・(式1)
但し、Si(鋼板)は前記薄鋼板のSi量を、また、Si(ワイヤ)は前記溶接用ワイヤの全Si量を示す。 - 前記(式1)の値が0.40以上になるように、前記薄鋼板と前記溶接用ワイヤとを組み合わせることを特徴とする、請求項1に記載の高強度薄鋼板の隅肉アーク溶接方法。
- 前記薄鋼板が、さらに、質量%で、
Al:0.005~0.1%
を含有することを特徴とする、請求項1または2に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記薄鋼板が、さらに、質量%で、
Ti:0.005~0.1%、
Nb:0.005~0.1%、
V :0.01~0.2%、
Cr:0.1~1.0%、
Mo:0.05~0.5%
のいずれか1種または2種以上を含有することを特徴とする、請求項1~3のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記溶接用ワイヤとして、質量%で、
C :0.03~0.15%、
Si:0.2~2.0%、
Mn:0.7~2.5%、
P :0.05%以下、
S :0.08%以下、
Cu:0.5%以下(0%を含む。)
を含有し、残部鉄及び不可避不純物からなる溶接用ソリッドワイヤを用いることを特徴とする請求項1~4のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記溶接用ソリッドワイヤが、さらに、質量%で、
Ti:0.01~0.5%、
Nb:0.01~0.1%、
V :0.05~0.3%、
Cr:0.05~1.0%、
Mo:0.05~0.7%、
Ni:0.3~12.0%
のいずれか1種または2種以上を含有することを特徴とする、請求項5に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記溶接用ソリッドワイヤが含有するNiを、質量%で、
Ni:4.0~12.0%
に制限することを特徴とする、請求項6に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記溶接用ソリッドワイヤが含有するSを、質量%で、0.02~0.08%に制限することを特徴とする、請求項5~7のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
- 前記溶接用ワイヤが、スリット状の継ぎ目がない鋼製外皮内にフラックスを充填してなるガスシールドアーク溶接用フラックス入りワイヤであって、
鋼製外皮およびフラックスの一方または双方に、ワイヤ全体での合計の質量%で、
C(SiC中のCを除く。):0.01~0.20%、
Si(SiCおよびSiO2中のSiを除く。):0.05~1.2%、
Mn:0.2~2.5%、
P:0.03%以下、
S:0.06%以下、
さらに、鋼製外皮内に充填されるフラックスとして、ワイヤ全体の質量%で、
SiC:0.05~1.2%
を含有するとともに、SiO2、Al2O3、Na2OおよびK2Oの1種または2種以上を合計で0.05~0.4%含有し、残部が鉄および不可避不純物からなる溶接用フラックス入りワイヤとすることを特徴とする請求項1~4のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記溶接用フラックス入りワイヤが、ワイヤ全体の質量%で、さらに、鋼製外皮内に充填されるフラックスとして、
グラファイト:0.02%以上
含有し、かつ下記(式2)で定義されるC換算値の合計量が0.15~0.45%である溶接用フラックス入りワイヤであることを特徴とする、請求項9に記載の高強度薄鋼板の隅肉アーク溶接方法。
C換算値の合計量=[グラファイト]+0.3×[SiC] ・・・ (式2)
但し、上記[グラファイト]、[SiC]は、それぞれワイヤ全体に対するグラファイト、SiCの質量%を示す。 - 前記溶接用フラックス入りワイヤが、鋼製外皮およびフラックスの一方または双方に、ワイヤ全体の質量%で、さらに、
Ni:0.1~5.0%、
Cr:0.1~2.0%、
Mo:0.1~2.0%、
Cu:0.1~0.5%
の1種または2種以上を合計で0.1~6.0%含有することを特徴とする、請求項9ないし10のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記溶接用フラックス入りワイヤが、鋼製外皮およびフラックスの一方または双方に、ワイヤ全体の質量%で、さらに、
B:0.001~0.015%
を含有することを特徴とする、請求項9ないし11のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記溶接用フラックス入りワイヤが、鋼製外皮およびフラックスの一方または双方に、ワイヤ全体の質量%で、さらに、Nb、VおよびTiの1種または2種以上を合計で0.005~0.3%含有することを特徴とする、請求項9ないし12のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
- 前記溶接用フラックス入りワイヤが、鋼製外皮内に充填されるフラックスとして、ワイヤ全体の質量%で、さらに、酸化物系以外のアーク安定剤を0.05~0.5%含有することを特徴とする、請求項9ないし13のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。
- 前記溶接用フラックス入りワイヤが、鋼製外皮およびフラックスの一方または双方に、ワイヤ全体の質量%で、
S:0.02~0.06%
を含有することを特徴とする、請求項9ないし14のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 前記高強度薄鋼板の隅肉アーク溶接方法がガスシールドアーク溶接であり、シールドガスとして、質量%で、
CO2:5%以上25%以下、
O2 :4%以下(0%を含む。)
を含有し、残部Arおよび不可避不純物からなるシールドガスを用いることを特徴とする、請求項1~15のいずれか1項に記載の高強度薄鋼板の隅肉アーク溶接方法。 - 引張強さが700MPa以上の高強度薄鋼板の隅肉アーク溶接継手において、溶接速度が80cm/min超、特に110cm/min超150cm/min以下で行ったガスシールドアーク溶接継手であって、
前記薄鋼板が、質量%で、
C :0.02~0.15%、
Si:0.2~1.8%、
Mn:0.5~2.5%、
P :0.03%以下、
S :0.02%以下
を含有し、残部鉄及び不可避不純物からなる薄鋼板であり、前記薄鋼板と前記溶接用ワイヤが含有するSiが、前記(式1)の値が0.32以上になるように組み合わせたことを特徴とする、高強度薄鋼板の隅肉アーク溶接継手。 - 前記(式1)の値が0.40以上になるように、前記薄鋼板と前記溶接用ワイヤとを組み合わせることを特徴とする、請求項17に記載の高強度薄鋼板の隅肉アーク溶接継手。
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JPWO2021085544A1 (ja) * | 2019-10-31 | 2021-11-25 | Jfeスチール株式会社 | Mig溶接方法 |
JP7060159B2 (ja) | 2019-10-31 | 2022-04-26 | Jfeスチール株式会社 | Mig溶接方法 |
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Also Published As
Publication number | Publication date |
---|---|
KR20140114878A (ko) | 2014-09-29 |
CN102548703B (zh) | 2015-05-13 |
MY161851A (en) | 2017-05-15 |
WO2011037272A4 (ja) | 2011-06-03 |
MX2012003512A (es) | 2012-05-08 |
IN2012DN02544A (ja) | 2015-08-28 |
CN102548703A (zh) | 2012-07-04 |
JPWO2011037272A1 (ja) | 2013-02-21 |
TW201125675A (en) | 2011-08-01 |
TWI412422B (zh) | 2013-10-21 |
KR20120062784A (ko) | 2012-06-14 |
JP5623413B2 (ja) | 2014-11-12 |
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