WO2011016941A2 - Abrasive article with preconditioning and persistent indicators - Google Patents

Abrasive article with preconditioning and persistent indicators Download PDF

Info

Publication number
WO2011016941A2
WO2011016941A2 PCT/US2010/041275 US2010041275W WO2011016941A2 WO 2011016941 A2 WO2011016941 A2 WO 2011016941A2 US 2010041275 W US2010041275 W US 2010041275W WO 2011016941 A2 WO2011016941 A2 WO 2011016941A2
Authority
WO
WIPO (PCT)
Prior art keywords
abrasive
abrasive article
composites
preconditioning
article
Prior art date
Application number
PCT/US2010/041275
Other languages
English (en)
French (fr)
Other versions
WO2011016941A3 (en
Inventor
James L. Mcardle
Ann M. Hawkins
William C. Quade
Martin Kubik
Original Assignee
3M Innovative Properties Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Company filed Critical 3M Innovative Properties Company
Priority to EP10806804A priority Critical patent/EP2459345A2/en
Priority to CN2010800321360A priority patent/CN102470515A/zh
Priority to JP2012522849A priority patent/JP2013500173A/ja
Publication of WO2011016941A2 publication Critical patent/WO2011016941A2/en
Publication of WO2011016941A3 publication Critical patent/WO2011016941A3/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B37/00Lapping machines or devices; Accessories
    • B24B37/11Lapping tools
    • B24B37/20Lapping pads for working plane surfaces
    • B24B37/24Lapping pads for working plane surfaces characterised by the composition or properties of the pad materials
    • B24B37/245Pads with fixed abrasives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B37/00Lapping machines or devices; Accessories
    • B24B37/11Lapping tools
    • B24B37/20Lapping pads for working plane surfaces
    • B24B37/26Lapping pads for working plane surfaces characterised by the shape of the lapping pad surface, e.g. grooved

Definitions

  • Abrasive articles are useful for a variety of grinding and finishing applications.
  • One such application is precision lapping and polishing machines.
  • Single-side lapping and polishing machines have a platen that is rotated relative to the workpiece.
  • Double-side machines utilize a pair of opposing platens which rotate relative to the workpiece.
  • Both types of machines can be used with fixed abrasives or liquid abrasive slurries.
  • fixed abrasives such as a coated abrasive product
  • the inventors have discovered that both of the above needs, preconditioning and identification, can be provided by indicators on the working surface of the abrasive article.
  • the preconditioning indicator is worn away. Once the preconditioning indicator is uniformly worn away, the preconditioning step is complete and the abrasive article can be placed into production to remove stock from the workpiece.
  • the persistent indicator on the working surface of the abrasive article allows the operator to identify the type of abrasive article mounted to the platen without needing to remove the abrasive article to see the backing where grade information is often printed on coated abrasives.
  • the persistent indicator serves as an end point indicator signaling that the coated abrasive article has a limited life remaining after the persistent indicator is completely worn away.
  • the invention resides in an abrasive article comprising: A backing having a first major surface and a second major surface opposed to the first major surface.
  • a three-dimensional abrasive layer attached to the first major surface, the three- dimensional abrasive layer comprising a plurality of shaped abrasive composites spaced apart by a plurality of land areas between the shaped abrasive composites, each of the shaped abrasive composites comprising a top surface and a sidewall, and the plurality of shaped abrasive composites and the plurality of land areas both formed from abrasive particles dispersed within an organic binder.
  • a preconditioning indicator located on the top surface of at least some of the plurality of shaped abrasive composites and a persistent indicator located on at least some of the plurality of land areas.
  • FIG. 1 illustrates a top view of a coated abrasive article having a preconditioning indicator.
  • FIG. IA illustrates a partial cross section through the coated abrasive article taken at IA - IA of FIG. 1.
  • FIG. 2 illustrates a top view of a coated abrasive article having a persistent
  • FIG. 2 A illustrates a partial cross section through the coated abrasive article taken at 2A - 2A ofFIG. 2.
  • FIG. 3 illustrates a top view of a coated abrasive article signaling that the coated abrasive article has limited life remaining after the persistent indicator is completely worn away
  • FIG. 3 A illustrates a partial cross section through the coated abrasive article taken at 3A - 3A ofFIG. 3.
  • FIG. 4A illustrates printed indicia on the three-dimensional abrasive layer of the coated abrasive article prior to preconditioning.
  • FIG. 4B illustrates printed indicia on the three-dimensional abrasive layer of the coated abrasive article during use.
  • the present invention pertains to coated abrasive articles 10 that have a backing 12 and a three-dimensional abrasive layer 18 typically comprising diamond, diamond agglomerates, ceria, or other abrasive particles.
  • the abrasive particles are dispersed within a binder and bonded to a surface of the backing 12.
  • the abrasive layer typically comprises a plurality of shaped abrasive composites 20 separated by a plurality of land areas 22 both of which are formed from a binder precursor and a plurality of abrasive particles that is cured or hardened into the three-dimensional abrasive layer 18.
  • the abrasive article is useful for polishing or grinding a variety of hard to abrade substrates such as ceramics, glass, single-crystal substrates, and hard metals.
  • the abrasive article can be mounted to a platen of a lapping or a polishing machine that rotates the platen relative to the workpiece to produce the desired stock removal and finish on the workpiece.
  • a coated abrasive product when used in a lapping or polishing machine is required to be preconditioned prior to its general production use.
  • the preconditioning serves to precisely machine the three-dimensional abrasive layer 18 of the coated abrasive article 10 such that all areas of the three-dimensional abrasive layer are in uniform contact with the workpiece and to prepare the three-dimensional abrasive layer such that the cut rate of the three-dimensional abrasive layer is substantially uniform at all locations within the working surface of the three-dimensional abrasive layer.
  • the preconditioning sequence is complete; preferably, by viewing the three-dimensional abrasive layer 18 of the coated abrasive article 10 to determine when it is substantially uniform.
  • coated abrasive articles 10 in various grades having faster or slower cut rates and producing rougher or smoother finishes to obtain the desired final finish on the workpiece. Since the coated abrasive article 10 is mounted to the platen by the backing 12, the grade identification typically printed on the backing 12 is often obscured during use of the coated abrasive article 10. Removing the coated abrasive article 10 from the platen to check the grade or identification information typically requires another preconditioning sequence to uniformly prepare the abrasive layer again for use. Thus, there is a need to identify what type of abrasive article is mounted to the platen while viewing the three-dimensional abrasive layer 18 of the coated abrasive article 10.
  • the coated abrasive article 10 includes a backing 12 having a first major surface 14 and a second major surface 16, which oppose each other.
  • a three-dimensional abrasive layer 18 is attached to the first major surface 14.
  • the three-dimensional abrasive layer 18 comprises a plurality of shaped abrasive composites 20 separated from each other by a plurality of land areas 22 between the shaped abrasive composites 20.
  • the shaped abrasive composites 20 comprise a top surface 24 and at least one sidewall 26.
  • the shaped abrasive composites 20 and the land areas 22 are integrally formed from the same abrasive slurry comprising a binder and a plurality of abrasive particles that is hardened or cured in a mold to form the three- dimensional abrasive layer 18.
  • the three-dimensional abrasive layer 18 comprises an organic resin binder and abrasive particles, and any optional additives such as fillers, pigments, or coupling agents, etc.
  • the preconditioning indicator 28 can comprise a first coating 32 on at least some of the top surfaces 24 of the shaped abrasive composites 20 (FIG. IA).
  • the persistent indicator 30 can comprise a second coating 34 on at least some of the land areas 22 between the shaped abrasive composites 20.
  • the persistent indicator 28 comprises a second coating 34 on at least some of the land areas 22 and on at least some of the sidewalls 26 of the shaped abrasive composites 20 (FIG. 2A).
  • the top surfaces 24 are often slightly rounded or uneven and not perfectly parallel to the second major surface 16 that is attached to the platen of the polishing or lapping machine.
  • the first coating 32 is completely removed from the top surfaces 24, and the top surfaces 24 are uniformly planar (same height from the second major surface 16) and parallel to the second major surface 16.
  • the transition from the first coating 32 appearing on at least some or a portion of the top surfaces 24 to the absence of the first coating 32 anywhere on the top surfaces 24 of the shaped abrasive composites 20 signals when the preconditioning step is complete as best seen by comparing FIG. 1 and FIG. 2. Once the first coating 32 is entirely worn away, the coated abrasive article 10 is ready for use.
  • the angle ⁇ between the sidewall 26 and the top surface 24 after preconditioning is less than about 110 degrees facilitates detection of the exact moment when the first coating 32 is completely removed.
  • a steeper sidewall 26 angle can prevent excessive preconditioning of the coated abrasive article 10, which would reduce its useful life without providing any additional benefit during the coated abrasive article's initial use.
  • the angle ⁇ can be between about 90 degrees to about 110 degrees, or between about 90 degrees to about 100 degrees.
  • the coated abrasive article 10 comprised a circular abrasive disc 35.
  • the preconditioning indicator 28 and persistent indicator 30 comprised at least one stripe 37 extending from a first side 39 of the circular abrasive disc 35 to a second side 41 of the circular abrasive disc.
  • the stripes 37 can intersect with each other while passing substantially through the disc's center while being uniformly or non-uniformly radially spaced about the circumference of the disc.
  • the stripes 37 can be substantially parallel to each other and spaced uniformly or non-uniformly across the three-dimensional abrasive layer 18.
  • the stripes can form a grid of horizontal and vertical lines.
  • the number of stripes 37 can be between 1 to about 20, or between 1 to about 10.
  • the stripes 37 can comprise printed indicia 36 as opposed to a solid continuous line.
  • the preconditioning indicator 28 and the persistent indicator 30 While it is possible for the preconditioning indicator 28 and the persistent indicator 30 to completely cover the entire three-dimensional abrasive layer 18, doing so would make it difficult to use printed indicia 36 to serve as both a preconditioning indicator 28 and as a persistent indicator 30.
  • Utilizing stripes extending across the face of the circular abrasive disc 35, can provide for a first coating 32 at the opposing sides and near the center of the three-dimensional abrasive layer 18 in order to effectively determine that planarization of the top surfaces 24 of the shaped abrasive composites 20 has occurred completely across the entire face of the circular abrasive disc 35 while still retaining legibility of the printed indicia 36.
  • the persistent indicator 30 remains on the land areas 22 and, optionally, on the sidewalls 26 of the shaped abrasive composites 20.
  • the persistent indicator 30 can use a code, such as different colors, different symbols, or different patterns, which correspond to a particular product identification such as the abrasive grade or abrasive product identification.
  • the persistent indicator 30 comprises printed indicia that allow the user to identify at least one of the following: manufacturer name, product identification number, lot number, trademark, abrasive grit designation, additives and treatments, safety information, or combinations of the foregoing.
  • the preconditioning indicator 28 and the persistent indicator 30 each comprise printed indicia 36.
  • the printed indicia 36 allows for the abrasive product to be identified prior to preconditioning as shown in FIG 4A, and also after preconditioning as shown in FIG. 4B. To better effect identification of the product, it has been determined that the relative sizes of the land areas 22, the shaped abrasive composites 20, and the printing letters should be controlled.
  • the spacing of the shaped abrasive composites 20 from sidewall 26 to sidewall 26 should be between about 0.5 mm to about 5.0 mm, the maximum dimension of the top surface 24 should be between about 1.0 mm to about 5.0 mm, and the height, h, of the font should be between about 20 mm to about 40 mm. Selections within these ranges help to ensure that the printed indicia are readily visible and readable after preconditioning is complete.
  • the printed indicia 36 are also present on at least some of the sidewalls 26. It is believed that by printing the land areas 22 and the sidewalls 26, the printed indicia is readable over a much larger viewing angle. In that regard, to facilitate reading the printed indicia 36 at angles significantly greater than 0 degrees to the first major surface 14, the shape of the shaped abrasive composites 20 can comprise a hexagonal shape in cross section in one embodiment.
  • a shaped abrasive composite having a hexagonal cross section has a sidewall 26 with six flats that provide reasonably sized printing surfaces and the flats are oriented at different positions around the abrasive composite enabling the printed indicia 36 to be readily viewed regardless of the rotational position of the circular abrasive article attached to the platen of the lapping and polishing machine.
  • shaped abrasive composites with a sidewall having 5 to 8 flats (pentagonal to octagonal) can be used.
  • the coated abrasive article 10 is shown after the shaped abrasive composites 20 have been used up and the second coating 34 is worn completely away.
  • the persistent indicator 30 can function as an end point indicator foreshadowing the need to replace the coated abrasive article 10 with a new one. Once the persistent indicator 30 is no longer visible, the coated abrasive product has a limited remaining life.
  • the land areas 22 should be sufficiently thick to enable operating the machine for a reasonable period of time prior to completely using up the abrasive layer. In various embodiments of the invention, the thickness, t, of the land areas 22 can be between about 25 microns to about 125 microns, or between about 10 microns to about 200 microns.
  • the coated abrasive article 10 is used with various lubricants and grinding aids.
  • Suitable lubricants include water-based solutions of one or more of the following: amines, mineral oil, kerosene, mineral spirits, pine oil, water-soluble emulsions of oils, polyethylenimine, ethylene glycol, propylene glycol, monoethanolamine, diethanolamine, triethanolamine, amine borate, boric acid, amine carboxylate, indoles, thioamine salt, amides, hexahydro-l,3,5-triethyltriazine, carboxylic acids, sodium 2- mercaptobenzothiazole, isopropanolamine, triethylenediamine tetraacetic acid, propylene glycol methyl ether, benzotriazole, sodium 2-pyridinethiol-l -oxide, and hexylene glycol.
  • Lubricants may also include corrosion inhibitors, fungi inhibitors, stabilizers,
  • first and second coatings should be selected such that they are not readily dissolved or removed during use by the lubricant or grinding aid.
  • Suitable first and/or second coatings can include pigmented or dye-based colorants in oil-based, solvent-based, water-based, or UV-curable liquid carrier systems.
  • solvent-based or UV-curable coatings are preferred.
  • suitable solvent-based coatings include: n-butyl lactate based printing inks, ketone based printing inks, ester based printing inks, or acetone/toluene based paints.
  • the preconditioning indicator 28 and/or the persistent indicator 30 can be molded into at least a portion of the three-dimensional abrasive layer 18 by using appropriately colored resins.
  • a first colored abrasive slurry can be used to slightly fill the mold cavities to a first height.
  • a second colored abrasive slurry can be used to fill the majority of the height of the mold cavities to a second height corresponding to approximately the bases of the shaped abrasive composites
  • a third colored abrasive slurry could be used to fill the mold cavities to the final height corresponding to approximately the thickness, t, of the land areas.
  • first and the third colors could be the same. Additionally, it is possible to use selected mold cells as a pseudo "dot-matrix printer" to mold printed indicia 36 directly into the three-dimensional abrasive layer 18 by selectively differentially coloring specific shaped abrasive composites 20 in the abrasive layer to form letters, numbers, or symbols.
  • Suitable materials and methods to produce the coated abrasive article 10 are generally known to those of skill in the art.
  • Suitable organic binders to mold the three- dimensional abrasive layer 18 are disclosed in U.S. patent number 7,044,835 starting at column 9, line 20 and proceeding until column 11, line 65.
  • Suitable backing 12 materials to support the three-dimensional abrasive layer 18 are disclosed in U.S. patent number 7,044,835 starting at column 11, line 65 and proceeding until column 12, line 40.
  • Suitable abrasive particles to mold within the three-dimensional abrasive layer 18 are disclosed in U.S. patent number 7,044,835 starting at column 12, line 41 and proceeding until column 15, line 44.
  • High-resolution indicia markings were applied to 673LA or 673FA coated abrasive discs (available from 3M Corporation) using a PZ Pilot Plus piezoelectric impulse inkjet print head and ImageMaster software, both from Squid Ink Manufacturing, Spring Lake Park, MN.
  • the abrasive discs were approximately 30 cm in diameter.
  • the shaped abrasive composites 20 had a hexagonal cross section with a top surface 24 measuring 3.30 mm across the flats, having a height of 0.76 mm, and the spacing between adjacent composites was 1.40 mm.
  • the shaped abrasive composites 20 and the land areas 22 comprised diamond abrasive particles in radiation-curable resin binders.
  • 3M coated abrasive products were used for test examples, commercially available under the following trade names: 3M Trizact 673LA grade AlO, Trizact 673FA grade A80, and Trizact 673FA grade Al 60.
  • Suitable indicia to print including text characters and solid stripe markings were selected through the ImageMaster computer interface.
  • Disc samples were translated by hand past the piezoelectric print head using a sliding table device mounted under the print head. After printing, the disc markings were held briefly under a Squid Ink infrared lamp to speed drying of the ink.
  • PZ 4845 black ink available from Squid Ink was fed to the print head.
  • the printed indicia comprised one or more stripes that extended from one edge of the disc to an opposing edge and/or printed letters and numbers having various heights of 1/2 inch (1.27 cm), 5/8 inch (1.59 cm), 3/4 inch (1.91 cm), 1 inch (2.54 cm), 1.125 inch (2.86 cm), or 1.25 inch (3.18 cm).
  • Printed discs were then tested using a Strasbaugh 6DC single-side lapping machine and an aqueous coolant solution (10% Sabrelube 9016 / water). Coolant flow was 30 ml/min. The machine table rotation was set at 100 rpm and the sample plate rotation was 100 rpm. Simulated preconditioning and use cycles were performed for 5 -minute intervals using A35 268XA Trizact PSA or A45 963FA Trizact PSA discs (available from 3M Corporation) mounted on the sample plate and with a 25 or 35 Ib load applied to the sample head. In some cases, disc wear was accelerated by introducing Pl 80 AlOx abrasive grain (Treibacher Alodur BFRPL) onto the disc surface during the test cycles.
  • Pl 80 AlOx abrasive grain Tereibacher Alodur BFRPL

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
PCT/US2010/041275 2009-07-27 2010-07-08 Abrasive article with preconditioning and persistent indicators WO2011016941A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP10806804A EP2459345A2 (en) 2009-07-27 2010-07-08 Abrasive article with preconditioning and persistent indicators
CN2010800321360A CN102470515A (zh) 2009-07-27 2010-07-08 具有预处理标记和永久标记的磨料制品
JP2012522849A JP2013500173A (ja) 2009-07-27 2010-07-08 予備処理指標及び持続的指標を有する研磨物品

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/509,707 2009-07-27
US12/509,707 US20110021114A1 (en) 2009-07-27 2009-07-27 Abrasive article with preconditioning and persistent indicators

Publications (2)

Publication Number Publication Date
WO2011016941A2 true WO2011016941A2 (en) 2011-02-10
WO2011016941A3 WO2011016941A3 (en) 2011-04-28

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PCT/US2010/041275 WO2011016941A2 (en) 2009-07-27 2010-07-08 Abrasive article with preconditioning and persistent indicators

Country Status (5)

Country Link
US (1) US20110021114A1 (enrdf_load_stackoverflow)
EP (1) EP2459345A2 (enrdf_load_stackoverflow)
JP (1) JP2013500173A (enrdf_load_stackoverflow)
CN (1) CN102470515A (enrdf_load_stackoverflow)
WO (1) WO2011016941A2 (enrdf_load_stackoverflow)

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US8118644B2 (en) * 2008-10-16 2012-02-21 Rohm And Haas Electronic Materials Cmp Holdings, Inc. Chemical mechanical polishing pad having integral identification feature
CN103962974B (zh) * 2013-01-31 2017-08-04 盖茨优霓塔传动系统(苏州)有限公司 磨轮
CA2929139A1 (en) 2013-11-12 2015-05-21 3M Innovative Properties Company Structured abrasive articles and methods of using the same
US9491997B2 (en) * 2013-12-02 2016-11-15 Soft Lines International, Ltd. Drum assembly, cosmetic device with drum assembly, and battery compartment for cosmetic device
KR20160147917A (ko) 2014-05-02 2016-12-23 쓰리엠 이노베이티브 프로퍼티즈 컴파니 불연속된 구조화된 연마 용품 및 작업편의 연마 방법
KR102420782B1 (ko) * 2014-10-21 2022-07-14 쓰리엠 이노베이티브 프로퍼티즈 컴파니 연마 예비성형품, 연마 용품, 및 접합된 연마 용품을 제조하는 방법
EP3215316B1 (en) * 2014-11-07 2018-07-11 3M Innovative Properties Company Printed abrasive article
CN106853610B (zh) * 2015-12-08 2019-11-01 中芯国际集成电路制造(北京)有限公司 抛光垫及其监测方法和监测系统
US11103117B2 (en) * 2016-04-29 2021-08-31 3M Innovative Properties Company Cleaning articles including scouring bodies that form printed instructions
JP7379331B2 (ja) * 2017-10-26 2023-11-14 スリーエム イノベイティブ プロパティズ カンパニー 画像層を有する可撓性研磨物品
EP3898087A1 (en) * 2018-12-18 2021-10-27 3M Innovative Properties Company Patterned abrasive substrate and method

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US5709598A (en) * 1993-06-02 1998-01-20 Dai Nippon Printing Co., Ltd. Abrasive tape and method of producing the same
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US20020077037A1 (en) * 1999-05-03 2002-06-20 Tietz James V. Fixed abrasive articles
US6287184B1 (en) * 1999-10-01 2001-09-11 3M Innovative Properties Company Marked abrasive article
JP2002264025A (ja) * 2001-03-14 2002-09-18 Dainippon Printing Co Ltd 研磨フィルム
JP4184656B2 (ja) * 2001-12-19 2008-11-19 大日本印刷株式会社 識別表示を有する研磨シート
JP3892807B2 (ja) * 2002-12-27 2007-03-14 憲司 中村 美容用研磨・艶出しシート
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JP2009241196A (ja) * 2008-03-31 2009-10-22 Asahi Diamond Industrial Co Ltd 工具及び砥粒層チップ

Also Published As

Publication number Publication date
EP2459345A2 (en) 2012-06-06
US20110021114A1 (en) 2011-01-27
WO2011016941A3 (en) 2011-04-28
CN102470515A (zh) 2012-05-23
JP2013500173A (ja) 2013-01-07

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