WO2011016758A1 - Способ производства листовой анизотропной электротехнической стали - Google Patents

Способ производства листовой анизотропной электротехнической стали Download PDF

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Publication number
WO2011016758A1
WO2011016758A1 PCT/RU2010/000414 RU2010000414W WO2011016758A1 WO 2011016758 A1 WO2011016758 A1 WO 2011016758A1 RU 2010000414 W RU2010000414 W RU 2010000414W WO 2011016758 A1 WO2011016758 A1 WO 2011016758A1
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WO
WIPO (PCT)
Prior art keywords
scanning
annealing
laser
width
steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/RU2010/000414
Other languages
English (en)
French (fr)
Russian (ru)
Inventor
Юрий Иванович ЛАРИН
Михаил Юрьевич ПОЛЯКОВ
Владимир Николаевич ПОЛЯКОВ
Алексей Юрьевич ШИШОВ
Сергей Андреевич КРЫСАНОВ
Борис Михайлович ЧЕРНЕНИЛОВ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Open Joint Stock Co <<novolipetsk Steel>>
Original Assignee
Open Joint Stock Co <<novolipetsk Steel>>
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Open Joint Stock Co <<novolipetsk Steel>> filed Critical Open Joint Stock Co <<novolipetsk Steel>>
Priority to BR112012001806-0A priority Critical patent/BR112012001806B1/pt
Publication of WO2011016758A1 publication Critical patent/WO2011016758A1/ru
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/06Surface hardening
    • C21D1/09Surface hardening by direct application of electrical or wave energy; by particle radiation
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties

Definitions

  • the present invention relates to the field of ferrous metallurgy, in particular to the production of cold rolled anisotropic electrical steel used for the manufacture of large magnetic circuits with low energy losses for magnetization reversal.
  • laser processing is proposed to be carried out in a magnetic field oriented along the rolling direction.
  • the absorption capacity of the insulating layer increasing with increasing wavelength, leads, in the case of using a CO 2 laser, to local overheating of the coating material and the formation of visible processing marks. With increasing ⁇ , the task of forming a sharply focused spot becomes more complicated. Finally, difficulties in the operation and tuning of the optical scheme, special cooling conditions make the practical use of CO 2 lasers ineffective.
  • the implementation of the proposed method is based on the use of radiation with a relatively low (from 10 W) output power.
  • the need for the formation of a sharply focused beam with a spot diameter at the focal point of up to 0.01 mm is due in this case to the choice of a single-mode radiation mode. at which a radiation power of more than 1 kW cannot be achieved.
  • Irradiation of a metal surface with a focused beam with a small cross-sectional area leads to the creation of high temperature gradients in the area affected by the spot. In this case, the depth of heating of the metal and the observed width of the line of action of the beam are no more than 20 ⁇ m.
  • the problem to which the technical solution is directed is to reduce the magnetic loss of cold-rolled strips of anisotropic electrical steel while maintaining a high level of magnetic induction and the resistance of the electrical insulation coating. This ensures a reduction in the cost of production and additional profit from its sale.
  • anisotropic electrical steel sheet including steel smelting, continuous casting, hot rolling.
  • decarburizing annealing degreasing
  • applying a protective coating high-temperature annealing
  • applying an electrical insulating coating rectifying annealing and electromagnetic exposure to the surface of a moving strip with a scanning non-circular laser beam elongated along the scanning direction.
  • electromagnetic exposure is carried out under an adjustable tension of the strip, creating an internal voltage in the metal in the range of 5-80 N / mm 2 .
  • continuous multimode laser radiation is used with a ratio of radiation power to scanning speed P / V in the range of 0.015-0.050 J / mm, while in the non-circular section of the beam its ratio length to width in the rolling direction is 0.005-0.075; and the magnitude of the strip tension during laser processing is determined by the following formula:
  • k is the proportionality coefficient equal to 0.002-0.010 depending on the chemical composition and mechanical properties of the treated steel.
  • a comparative analysis of the proposed technical solution with the prototype shows that the claimed method differs from the well-known topics.
  • the electromagnetic effect on the surface of the moving strip is carried out under controlled tension, which creates an internal voltage in the metal in the range of 5-80 N / mm 2 , and continuous electromagnetic multimode laser radiation of a non-circular cross section is used as the electromagnetic effect with the ratio of the radiation power to the scanning speed P / V in range 0.015-0.050 J / mm. while in the elongated along the scanning direction non-circular section of the beam, the ratio of its length to width in the rolling direction is 0.005-0.075.
  • the claimed method meets the criteria of the invention of "Novelty.”
  • a comparative analysis of the proposed solution not only with the prototype, but also with other technical solutions showed that methods for the production of anisotropic electrical steel sheet, including continuous casting, hot rolling, single or double cold rolling, decarburizing annealing, degreasing, applying a protective coating, high-temperature annealing, applying an insulating coating, rectifying annealing and electromagnetic effects on the surface of a moving strip with a scanning laser beam A cross section elongated along the scanning direction is widely known.
  • Figure 1 presents the implementation diagram of the proposed method. The method is as follows.
  • the strip -1 of steel in the treatment zone is transported by an iodine with adjustable tension - N -, which creates an internal voltage in the metal in the range of 5-80 N / mm 2 , and the ratio of the radiation power to the scanning speed P / V of the laser beam is 2 - support in the range of 0.015 - 0.050 J / mm, while in the elongated along the scanning direction -R- non-circular section - 3 - of the beam - 2 - the ratio of its length - s - to width - b - in the rolling direction -T- is 0.005 - 0.075.
  • a multimode fiber laser -4- with a generation wavelength of 1070 nm and an output power of 1.5 - 3.5 kW is used as a source of laser radiation.
  • the processing of strip -1- is carried out with a spot - 3 -, which have different sizes in the sweep direction and in the transverse direction to it.
  • This is achieved through the use of a special optical system, which is a set of cylindrical lenses located along the line of scanning the beam.
  • the time of laser exposure, the temperature of heating of the surface layer and the depth depend on the geometric shape and size of the spot -3- penetration of heat into the metal.
  • the width of the spot-b- laser radiation determines the time of laser exposure to the surface of the strip. Accordingly, when forming a spot elongated along the scanning line, it is possible to provide both sharp heating of the local zone of the surface with a maximum temperature gradient at its boundary, and smooth heating with a spot with a width of -b- 20-30 mm. providing deep warming up. Obviously, an increase in the extent of the spot is accompanied by a proportional decrease in the radiation density at each point of exposure.
  • the performed calculations for the sweep speed m / s and the total radiation power of 2.5 kW show that an increase in the width of the spot -b- from 3.5 mm to 25 mm with a length of -s- 100-300 ⁇ m corresponds to a change in the depth of heating of the metal from 30 up to 100 microns.
  • the depth of heating refers to the distance from the surface at which the temperature, expressed in degrees Celsius, is reduced by 2 times.
  • B and d are the width and thickness of the strip (mm), respectively.
  • Processing the strip with an internal voltage in the metal in the range of more than 80 N / mm 2 is accompanied by a sharp decrease in the magnitude of the magnetic induction below the permissible value.
  • the ratio of the radiation power to the scanning speed P / V is more than 0.050 J / mm, the insulating coating on the steel surface is destroyed, which is unacceptable, since it worsens the appearance of the product and can lead to a decrease in the resistance value of the electrical insulation coating.
  • a decrease in the ratio of length to width of the non-circular beam cross section less than 0.005 under the existing power limitations of modern fiber-optic lasers leads to a decrease in the density of laser radiation and, as a consequence, insufficiently deep heating of the metal in the laser irradiation zone, which excludes the possibility of using the applied tension to further reduce specific magnetic losses.
  • a laser beam with an output power of 2.5 kW having a non-circular cross section with a length of 150 ⁇ m along the scanning direction and a width of 20 mm in the direction of movement of the strip, and a tension in the processing section of 18 N / mm
  • the use of the proposed method for the production of anisotropic electrical steel sheet allows not only to reduce magnetic losses while maintaining a high level of magnetic induction, but also to reduce the cost of production and get additional profit from its sale.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electromagnetism (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacturing Of Steel Electrode Plates (AREA)
PCT/RU2010/000414 2009-08-03 2010-07-27 Способ производства листовой анизотропной электротехнической стали Ceased WO2011016758A1 (ru)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BR112012001806-0A BR112012001806B1 (pt) 2009-08-03 2010-07-27 Método de produção do aço elétrico anisotrópico em chapas

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2009129819/02A RU2405841C1 (ru) 2009-08-03 2009-08-03 Способ производства листовой анизотропной электротехнической стали
RU2009129819 2009-08-03

Publications (1)

Publication Number Publication Date
WO2011016758A1 true WO2011016758A1 (ru) 2011-02-10

Family

ID=43544525

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2010/000414 Ceased WO2011016758A1 (ru) 2009-08-03 2010-07-27 Способ производства листовой анизотропной электротехнической стали

Country Status (5)

Country Link
BR (1) BR112012001806B1 (cs)
CZ (1) CZ306162B6 (cs)
PL (1) PL218343B1 (cs)
RU (1) RU2405841C1 (cs)
WO (1) WO2011016758A1 (cs)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2918689A4 (en) * 2012-11-08 2016-07-13 Nippon Steel & Sumitomo Metal Corp LASER PROCESSING DEVICE AND LASER BEAM PROCESS
CN111542622A (zh) * 2017-12-26 2020-08-14 Posco公司 取向电工钢板及其磁畴细化方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013099274A1 (ja) * 2011-12-28 2013-07-04 Jfeスチール株式会社 方向性電磁鋼板およびその鉄損改善方法
WO2016139818A1 (ja) * 2015-03-05 2016-09-09 Jfeスチール株式会社 方向性電磁鋼板およびその製造方法
PL3653759T3 (pl) * 2017-07-13 2025-01-27 Nippon Steel Corporation Blacha cienka ze stali elektrotechnicznej o ziarnach zorientowanych i sposób jej wytwarzania

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07220913A (ja) * 1994-02-04 1995-08-18 Nippon Steel Corp 磁気特性の優れた電磁鋼板
EP1607487A1 (en) * 2003-03-19 2005-12-21 Nippon Steel Corporation Grain-oriented magnetic steel sheet excellent in magnetic characteristic and its manufacturing method
RU2358346C1 (ru) * 2005-05-09 2009-06-10 Ниппон Стил Корпорейшн Лист из электротехнической стали с ориентированной зернистой структурой, имеющий низкие потери в сердечнике, и способ для его производства

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GB8324643D0 (en) * 1983-09-14 1983-10-19 British Steel Corp Production of grain orientated steel
US4772338A (en) * 1985-10-24 1988-09-20 Kawasaki Steel Corporation Process and apparatus for improvement of iron loss of electromagnetic steel sheet or amorphous material
US5192373A (en) * 1989-09-08 1993-03-09 Armco, Inc. Magnesium oxide coating for electrical steels and the method of coating
JP3160315B2 (ja) * 1991-06-28 2001-04-25 川崎製鉄株式会社 電子ビームの照射方法及び照射装置
IT1306157B1 (it) * 1999-05-26 2001-05-30 Acciai Speciali Terni Spa Procedimento per il miglioramento di caratteristiche magnetiche inlamierini di acciaio al silicio a grano orientato mediante trattamento
KR100442099B1 (ko) * 2000-05-12 2004-07-30 신닛뽄세이테쯔 카부시키카이샤 저철손 및 저소음 방향성 전기 강판 및 그의 제조 방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07220913A (ja) * 1994-02-04 1995-08-18 Nippon Steel Corp 磁気特性の優れた電磁鋼板
EP1607487A1 (en) * 2003-03-19 2005-12-21 Nippon Steel Corporation Grain-oriented magnetic steel sheet excellent in magnetic characteristic and its manufacturing method
RU2301839C2 (ru) * 2003-03-19 2007-06-27 Ниппон Стил Корпорейшн Текстурированный лист из электротехнической стали с высокими электрическими характеристиками и способ его изготовления
RU2358346C1 (ru) * 2005-05-09 2009-06-10 Ниппон Стил Корпорейшн Лист из электротехнической стали с ориентированной зернистой структурой, имеющий низкие потери в сердечнике, и способ для его производства

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2918689A4 (en) * 2012-11-08 2016-07-13 Nippon Steel & Sumitomo Metal Corp LASER PROCESSING DEVICE AND LASER BEAM PROCESS
CN104755637B (zh) * 2012-11-08 2017-03-15 新日铁住金株式会社 激光加工装置以及激光照射方法
US9607744B2 (en) 2012-11-08 2017-03-28 Nippon Steel & Sumitomo Metal Corporation Laser processing apparatus and laser irradiation method
CN111542622A (zh) * 2017-12-26 2020-08-14 Posco公司 取向电工钢板及其磁畴细化方法
CN111542622B (zh) * 2017-12-26 2022-05-31 Posco公司 取向电工钢板及其磁畴细化方法
US11772189B2 (en) 2017-12-26 2023-10-03 Posco Co., Ltd Grain-oriented electrical steel sheet and magnetic domain refining method therefor

Also Published As

Publication number Publication date
BR112012001806B1 (pt) 2018-01-16
PL218343B1 (pl) 2014-11-28
CZ201230A3 (cs) 2012-03-14
BR112012001806A2 (pt) 2017-06-27
CZ306162B6 (cs) 2016-08-31
PL398130A1 (pl) 2012-07-30
RU2405841C1 (ru) 2010-12-10

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