WO2011016606A1 - Method and apparatus for separating seawater into caustic soda and fresh water by using green energy - Google Patents

Method and apparatus for separating seawater into caustic soda and fresh water by using green energy Download PDF

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Publication number
WO2011016606A1
WO2011016606A1 PCT/KR2009/007581 KR2009007581W WO2011016606A1 WO 2011016606 A1 WO2011016606 A1 WO 2011016606A1 KR 2009007581 W KR2009007581 W KR 2009007581W WO 2011016606 A1 WO2011016606 A1 WO 2011016606A1
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WO
WIPO (PCT)
Prior art keywords
caustic soda
water
seawater
fresh water
green energy
Prior art date
Application number
PCT/KR2009/007581
Other languages
French (fr)
Korean (ko)
Inventor
배오성
Original Assignee
Bae Oh Sung
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Filing date
Publication date
Priority claimed from PCT/KR2009/004417 external-priority patent/WO2011016593A1/en
Application filed by Bae Oh Sung filed Critical Bae Oh Sung
Priority to US12/998,391 priority Critical patent/US20110198234A1/en
Publication of WO2011016606A1 publication Critical patent/WO2011016606A1/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4604Treatment of water, waste water, or sewage by electrochemical methods for desalination of seawater or brackish water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/14Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/10Treatment of water, waste water, or sewage by heating by distillation or evaporation by direct contact with a particulate solid or with a fluid, as a heat transfer medium
    • C02F1/12Spray evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/009Apparatus with independent power supply, e.g. solar cells, windpower, fuel cells
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46155Heating or cooling
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/10Energy recovery
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies

Definitions

  • the present invention relates to a method and apparatus for separating seawater into caustic soda and fresh water using green energy, and more specifically, to generate power by itself through a power generation means and use 3.5% of salt ( By separating the seawater containing Nacl into caustic soda and fresh water, there is no external power supply, eliminating carbon dioxide emissions and fossil fuels that cause global warming, while reducing the enormous cost of caustic soda and fresh water.
  • the present invention relates to a method and apparatus for separating seawater into caustic soda and fresh water using green energy.
  • caustic soda sodium hydroxide
  • NaOH sodium hydroxide
  • pure caustic soda white crystals.
  • the caustic soda absorbs water vapor from the air and melts itself, so it should be kept in contact with air.
  • said caustic soda shows strong alkalinity in aqueous solution.
  • Caustic soda having such properties is widely used as a raw material in the manufacture of pulp, fiber, dye, rubber, soap, etc., and is widely used as a desiccant because it has a strong deliquescent property to absorb moisture in the air.
  • the caustic soda is prepared by adding a sulfuric acid to the raw material salt, followed by thermal decomposition to prepare caustic soda, and an ammonia soda method of producing caustic soda by reacting soda ash with Ca (OH) 2; And electrolysis methods for producing caustic soda by electrolysis of brine.
  • electrolysis methods including a diaphragm method and a mercury method ion exchange membrane method are most widely used.
  • the diaphragm method is a method of preparing caustic soda by installing a diaphragm made of asbestos from the graphite anode and the iron cathode so that combustion from the anode and caustic soda from the cathode do not react.
  • the mercury method is a method of preparing caustic soda using mercury as a negative electrode material, which is not currently used due to environmental pollution of mercury, which is a heavy metal.
  • the ion exchange membrane is installed inside the electrolytic cell, the anode and cathode terminals are installed in the anode and cathode tanks of the electrolytic cell partitioned on both sides, and the brine is used as an electrolyte to supply power to the two electrode terminals.
  • the brine is used as an electrolyte to supply power to the two electrode terminals.
  • a certain amount of water is injected into the cathode tank having the anode terminals connected to each other with an osmotic membrane interposed therebetween, and a certain amount of sodium chloride solution is injected into the anode tank having the anode terminals.
  • hydroxide ions (OH ⁇ ) and sodium ions (Na + ) remain, and the hydroxide ions (OH ⁇ ) and sodium ions (Na + ) react to form sodium hydroxide (NaOH).
  • the apparatus for producing caustic soda using the ion exchange membrane method as described above has a problem in that a large amount of power is required in performing the electrolysis as described above.
  • the present invention has been made to solve the above-described problems, the object of which is to produce power by itself through power generation means, such as solar power generation unit and hydroelectric power generation unit, using the produced power to produce seawater
  • power generation means such as solar power generation unit and hydroelectric power generation unit
  • seawater By separating it into caustic soda and fresh water, it uses green energy that can reduce the enormous cost of caustic soda and fresh water while eliminating carbon dioxide emissions and fossil fuels that cause global warming because there is no external power supply. It is to provide a method and apparatus for separating seawater into caustic soda and fresh water.
  • the apparatus for separating seawater into caustic soda and fresh water using the green energy for achieving the above object, the storage tank 110 for pumping and purifying the seawater after a certain amount, and the reservoir ( Connected to one side of the 110 and the channel 120 for flowing out the seawater discharged from the reservoir 110, the positive and negative electrodes are respectively installed on both sides of the reservoir 110 and the channel 120 to electrolyze seawater
  • the electrode 130 and the power supply unit 140 is installed on one side of the waterway 120 to supply electricity to the electrode 130, and to supply the power produced by itself to the power supply unit 140
  • the evaporation tower for separating the caustic soda and fresh water by injecting and heating the power generation means 150 and the caustic soda-containing water which is electrolyzed while passing through the waterway 120 and spraying and heating at the same time. ).
  • the method of separating the seawater into caustic soda and fresh water using the green energy for achieving the above object, (A) to produce power by itself through the solar power generation unit 1510 Supplying power to the power supply unit 140 and supplying electricity through the electrode 130 (S210); (B) temporarily storing the purified seawater in the storage tank 110 and first electrolyzing the electrode 130 through the electrode 130 (S220); (C) performing second electrolysis through the electrode 130 in the waterway 120 while flowing the first electrolyzed seawater from the reservoir 110 (S230); (D) injecting the caustic soda-containing water electrolyzed through the step (C) into the inlet through the jet port 1601 and simultaneously heating the same through the evaporation chamber 1610 to generate steam (S240); (E) receiving steam heated in the evaporation chamber 1610 through a moving duct 1615 to generate a steam turbine generator 1620 (S250); And (F) collecting the concentrated caustic soda heated through the evaporation chamber 1610
  • the power is produced by itself through power generation means such as solar power generation unit and hydroelectric power generation unit,
  • power generation means such as solar power generation unit and hydroelectric power generation unit
  • the seawater containing 3.5% of salt is separated into caustic soda and fresh water through electrolysis, so that there is no external power supply, so it is possible to exclude the emission of carbon dioxide from the manufacture of caustic soda and fresh water.
  • the elimination of fossil fuels can significantly reduce the cost of producing caustic soda and fresh water, while contributing to the prevention of pollution and global warming.
  • the evaporated steam is heated after evaporating water by heating the electrolyzed caustic soda-containing water through an evaporation tower.
  • the condensate discharged while generating the turbine generator can be used as fresh water.
  • FIG. 1 is a view schematically showing an apparatus for separating seawater into caustic soda and fresh water using green energy according to the present invention.
  • 2 to 4 is a view showing the power generation means of the apparatus for separating seawater into caustic soda and fresh water using the green energy according to the present invention.
  • Figure 5 is a cross-sectional view showing an evaporation tower of the device for separating seawater into caustic soda and fresh water using the green energy according to the present invention.
  • Figure 6 is a flow chart illustrating a method for separating seawater into caustic soda and fresh water using the green energy according to the present invention.
  • step S240 of FIG. 7 is a flowchart showing a subroutine of step S240 of FIG.
  • evaporation tower 1510 solar power generation unit 1520: hydroelectric power generation unit
  • ultrasonic generator 1616 magnetron 1615: mobile duct
  • FIG. 1 is a view schematically showing an apparatus for separating seawater into caustic soda and fresh water using green energy according to the present invention
  • FIGS. 2 to 4 are caustic soda and fresh water using green energy according to the present invention
  • 5 is a cross-sectional view showing an evaporation tower of a device for separating seawater into caustic soda and fresh water using green energy according to the present invention.
  • the device 100 for separating the seawater into caustic soda and fresh water using the green energy the storage tank 110 for temporarily storing the pumped seawater and then electrolyzed and discharged Is connected to one side of the reservoir, while flowing through the seawater discharged from the water reservoir 120 for the second electrolysis, and installed on both sides of the reservoir 110 and the water channel 120, respectively, electrolysis of sea water Electrode 130 of the positive and negative electrodes to be installed on one side of the waterway 120 to supply electricity to the electrode 130 and the self-produced in the power supply 140 Passing the power generation means 150 for supplying power and the caustic soda-containing water electrolyzed while passing through the water channel 120 and simultaneously evaporating the water contained therein to separate seawater into caustic soda and fresh water Evaporation Tower (160) It includes.
  • the reservoir 110 is a means for primarily electrolyzing by storing a predetermined amount of seawater pumped from the outside, so that the seawater can be discharged through the water channel 120. Openings are formed on one surface.
  • the channel 120 is a means for secondary electrolysis while one end is connected to the opening of the reservoir 110 to flow the sea water, and the connection pipe 121 is formed in a cross section of a “U” shape with both ends opened. And, it consists of a reservoir 122 to temporarily store the caustic soda-containing water electrolyzed through the reservoir 110 and the water channel 120 to be supplied to the evaporation tower 160 by pumping.
  • the water channel 120 is preferably formed in a unit unit having a certain length of concrete, metal or synthetic resin, etc., it is preferably configured to be connected to each other to prevent leakage.
  • the channel 120 is made of a unit unit of about 1m in width, 1m in height, 2.5m in length, and connected to 300-500 sets or more in series, and increase or decrease according to the conditions. Can be.
  • the channel 120 may be configured in various ways, such as width, height depending on the surrounding situation.
  • the channel 120 configured as described above is configured so that the sea water flows naturally from the reservoir 110 to the reservoir 122, wherein the inclination angle of the channel can be set within 45 degrees according to the shape of the ground.
  • the electrode 130 has a plurality of cathodes (-) and anodes (+) are provided on one side and the other side of the reservoir 110 at regular intervals to electrolyze the seawater stored in the reservoir 110 primarily
  • a plurality of cathodes (-) and anodes (+) are installed on one side and the other side of the connection pipe 121 of the water channel 120 at regular intervals to secondary the seawater flowing continuously along the connection pipe 121.
  • the power supply unit 140 is installed on one wall surface of the water channel 120 to accumulate the electricity produced from the power generating means 150 and supply it to the electrode 130 and the evaporation tower 160.
  • the power generation unit 150 generates electricity through eco-friendly power generation such as hydroelectric power generation and solar power using seawater flowing along the waterway 120, and supplies the generated electricity to the power supply unit 140. .
  • the power generation means 150 is provided with a plurality of solar panels of which the angle is adjusted solar power generation as a primary power generation means for generating electricity by accumulating sunlight collected Hydroelectric power generation unit 1520, a second generation means for generating electricity by generating a rotational force by the seawater flowing along the waterway 120 and the generated rotational force in the generator 1510, BOS hydroelectric power generation unit It is composed of
  • the DC electricity produced by the solar power generation unit 1510 is used as it is. Supplied to the AC power produced by the hydroelectric power generation unit 1520 is converted into direct current through the converter 1525 and supplied to the power supply unit 140.
  • the solar power generation unit 1510 and the hydroelectric power generation unit 1520 are both installed and described as a configuration to secure the maximum amount of power generation, but as long as it can supply the necessary power, only one of the two Of course, you can install it.
  • the photovoltaic unit 1510 may be provided in plural along the upper end of the channel 120, and may be provided in plural on the outer surface of the channel in order to secure a sufficient amount of power generation.
  • the hydroelectric power generation unit 1520 is provided in a plurality at a predetermined interval inside the waterway 120, the propeller 1522 to rotate by the seawater flowing along the waterway 120, and the propeller 1522
  • An increase gear unit 1524 composed of a standby gear and a small gear rotated to be engaged with each other so as to transmit the rotational force, and a generator 1526 that receives the rotational movement of the increase gear unit 1524 and generates power.
  • the propeller 1522 is formed in a hemispherical cross-section concave in one direction so that each wing is rotated according to the flow of sea water is fixed to the lower end of the shaft through welding or bolts and nuts.
  • the propeller 1522 is formed in multiple stages at one end of the rotation shaft 1523 rotatably provided in the fixing frame 1521 with a height difference.
  • the speed increase gear unit 1524, the large rotational gear and the small gear geared to the rotational shaft 1523 and the small diameter to be meshed with the rotating shaft 1523 is alternately meshed to increase the rotational speed by a gear ratio of about 10: 1.
  • the amount of seawater flowing along the waterway 120 is small and the speed is slow so that the increased rotational force can be transmitted to the generator 1526 even if the propeller 1522 rotates slowly.
  • the gear ratio of the standby gear and the small gear is described as 10: 1, but is not limited thereto.
  • the evaporation tower 160 is heated by receiving the caustic soda-containing water stored in the reservoir 122 by electrolysis while flowing through the water channel (120).
  • the evaporation tower 160 injects and sprays caustic soda-containing water supplied from the reservoir 122 of the water channel 120 to the upper side through a pump (not shown).
  • a jet port 1601 for spraying caustic soda-containing water supplied from the reservoir 122, and at least three or more sequentially from the top in the evaporation tower 160 The evaporation chamber 1610 for generating steam by heating the caustic soda-containing water discharged through the jet port 1601 and the steam generated from the evaporation chamber 1610 is supplied through the moving duct 1615.
  • a steam turbine generator 1620 that is developed is included.
  • the inside of the evaporation tower 160 is partitioned so that at least three or more evaporation chambers 1610 can be sequentially stacked, and the evaporation chambers 1610 are respectively installed in the partitioned space and the bottom surface thereof.
  • the evaporation chamber (1610) is formed with a spray port (1602) for injecting the caustic soda-containing water evaporated through the respective evaporation chamber 1610, the front door is opened and closed for maintenance of the evaporation chamber (1610) ( 1604 is formed.
  • the caustic soda-containing water is configured to spray by the free fall to the lower end through the jet port 1601 and the injection port 1602, but is not limited to the rotary motor inside the jet port 1601 and the injection port 1602. Of course, it can be equipped with a spray.
  • the evaporation chamber 1610 is sequentially stacked inside the evaporation tower 160 and includes caustic soda that is introduced and injected through the ejection openings 1601 and the respective injection ports 1602. Heat the water.
  • the evaporation chamber 1610 is mounted on one side of the evaporation chamber 1610 and the heater 1612 to apply heat to the caustic soda-containing water is fixedly installed therein, the heat is applied by the heater
  • an ultrasonic generator 1614 for generating ultrasonic waves is mounted on the other side of the evaporation chamber 1610 and instantaneously heats the water particles sprayed through the heater and the ultrasonic generator. It is composed of a magnetron 1616 that explosively increases water vapor.
  • the water vapor separated by evaporation by the heater 1612 and the ultrasonic generator 1614 is decomposed into fine particles by a microwave emitted from the magnetron 1616 and amplified and discharged through the moving duct 1615.
  • the steam turbine generator 1620 is operated, and electricity generated by the steam turbine generator 1620 is supplied to the heater 1612, the ultrasonic generator 1614, and the magnetron 1620.
  • the steam turbine generator 1620 generates power and is stored in the fresh water storage tank 1625 used as agricultural water to store the remaining water vapor, and is heated through the three evaporation chamber (1610) It includes a caustic soda storage tank 1630 collecting the concentrated caustic soda through the drain 1160, and may be used as an organic natural fertilizer by mixing sawdust and the like in the concentrated caustic soda.
  • FIG. 6 is a flowchart illustrating a method of separating seawater into caustic soda and fresh water using green energy according to the present invention
  • FIG. 7 is a flowchart illustrating a subroutine of step S240 of FIG. 6.
  • the seawater purified by the foreign matter is temporarily stored in the reservoir 110 and then electrolyzed first through the electrode 130 (S220).
  • the seawater flows along the waterway 120 to produce AC power by itself through the hydroelectric power generation unit 1520, and then converts the DC power through the converter 1525 to the power supply unit 140 ( S235).
  • the caustic soda-containing water electrolyzed in the step S230 is introduced into the inlet through the jet port 1601 and sprayed through the evaporation chamber 1610 to generate steam (S240).
  • the step S240 the process of generating steam by heating the caustic soda-containing water through the evaporation chamber 1610
  • the step of heating the caustic soda-containing water is sprayed from the heater (1612) (S242)
  • the ultrasonic generator 1614 When the caustic soda-containing water heated through the step S242 is accumulated on the side of the evaporation chamber 1610, the ultrasonic generator 1614 generates ultrasonic waves (S244), and the heater 1612 and the ultrasonic generator 1614 are provided.
  • the magnetron 1616 instantaneously heats the water particles sprayed through the exponentially increasing water vapor (S246).
  • the steam heated in the evaporation chamber 1610 is supplied through a moving duct 1615 to generate a steam turbine generator 1620 (S250).
  • the electricity generated by the steam turbine generator 1620 itself is supplied to the heater 1612, the ultrasonic generator 1614 and the magnetron 1620 to operate.
  • step S240 the concentrated caustic soda heated and heated through the evaporation chamber 1610 in step S240 is collected through the drainage port 1603.
  • step S250 the steam turbine generator 1620 is developed and the remaining water vapor is liquefied and used as fresh water. (S260).
  • according to the present invention can be produced by separating the seawater into caustic soda and fresh water by producing electricity by itself through the photovoltaic unit, the hydropower unit and the steam turbine generator without receiving external power. Can be.

Abstract

The present invention relates to a method and an apparatus for separating seawater into caustic soda and fresh water by using green energy, which can reduce the huge costs resulting from the fabrication of the caustic soda and the fresh water since fossil fuels and carbon dioxide emissions, which are the causes of global warming, are eliminated, with no external power supply, by self-producing the power through a generating means and separating the seawater into the caustic soda and the fresh water with the produced power. To this end, the invention comprises: a water tank which pumps a certain amount of the seawater to refine the seawater, and discharges the refined seawater; a watercourse which is connected to the one side of the water tank, and in which the seawater discharged from the water tank flows out; positive and negative electrodes which are respectively installed on both sides of the watercourse and the water tank, and electrolyze the seawater; a power supplier which is installed on the one side of the watercourse, and supplies electricity to the electrodes; a generating means which supplies self-produced power to the power supplier; and an evaporation tower through which the water that includes the caustic soda and has been electrolyzed as it had passed through the watercourse flows inward, and in which the water is simultaneously sprayed and heated so as to evaporate the moisture contained therein, thereby separating the water into the caustic soda and fresh water.

Description

그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법 및 장치Method and apparatus for separating seawater into caustic soda and fresh water using green energy
본 발명은 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법 및 장치에 관한 것으로, 더욱 상세하게는 발전수단을 통해 자체적으로 전력을 생산하고 그 생산된 전력을 이용하여 3.5%의 소금(Nacl)이 포함된 해수를 가성소다와 담수로 분리하여 제조함으로써, 외부의 전력 공급이 없어서 지구 온난화의 원인인 이산화탄소의 배출과 화석연료를 배제하면서도 가성소다와 담수의 제조에 따른 막대한 비용을 절감할 수 있는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법 및 장치에 관한 것이다.The present invention relates to a method and apparatus for separating seawater into caustic soda and fresh water using green energy, and more specifically, to generate power by itself through a power generation means and use 3.5% of salt ( By separating the seawater containing Nacl into caustic soda and fresh water, there is no external power supply, eliminating carbon dioxide emissions and fossil fuels that cause global warming, while reducing the enormous cost of caustic soda and fresh water. The present invention relates to a method and apparatus for separating seawater into caustic soda and fresh water using green energy.
일반적으로, 가성소다(수산화 나트륨)는 화학식 NaOH이고 분자량은 39.997g/mol인 대표적인 강염기로서 순수한 가성소다는 흰색결정이다.Generally, caustic soda (sodium hydroxide) is a representative strong base having the formula NaOH and a molecular weight of 39.997 g / mol, pure caustic soda being white crystals.
이러한 가성소다는 공기 중에서 수증기를 흡수해 스스로 녹는 조해성이 있으므로 공기와의 접촉을 차단하여 보관해야 한다.The caustic soda absorbs water vapor from the air and melts itself, so it should be kept in contact with air.
또한, 상기한 가성소다는 수용액상에서는 강한 알카리성을 나타낸다.In addition, said caustic soda shows strong alkalinity in aqueous solution.
이러한 성질을 갖는 가성소다는 펄프, 섬유, 염료, 고무, 비누 등의 제조시 널리 사용되는 원료로서, 공기 중의 수분을 잘 흡수하는 조해성이 강하여 건조제로 널리 사용되고 있다.Caustic soda having such properties is widely used as a raw material in the manufacture of pulp, fiber, dye, rubber, soap, etc., and is widely used as a desiccant because it has a strong deliquescent property to absorb moisture in the air.
상기 가성소다의 제조방법으로는, 원료염에 황산을 첨가한 후 가열 분해하여 가성소다를 제조하는 르블랑법(Leblanc)과, 소다회를 Ca(OH)2와 반응시켜 가성소다를 제조하는 암모니아소다법과, 염수를 전기 분해하여 가성소다를 제조하는 전기 분해법 등이 있으며, 현재는 격막법, 수은법 이온교환막법을 포함하는 전기 분해법이 가장 널리 사용되고 있다.The caustic soda is prepared by adding a sulfuric acid to the raw material salt, followed by thermal decomposition to prepare caustic soda, and an ammonia soda method of producing caustic soda by reacting soda ash with Ca (OH) 2; And electrolysis methods for producing caustic soda by electrolysis of brine. Currently, electrolysis methods including a diaphragm method and a mercury method ion exchange membrane method are most widely used.
상기 격막법은 흑연 양극과 철 음극에서 나오는 석면으로 만든 격막을 설치하여 양극에서 나오는 연소와 음극에서 나오는 가성소다가 반응하지 않도록 하여 가성소다를 제조하는 방법이다.The diaphragm method is a method of preparing caustic soda by installing a diaphragm made of asbestos from the graphite anode and the iron cathode so that combustion from the anode and caustic soda from the cathode do not react.
그리고, 상기 수은법은 수은을 음극 재료로 사용하여 가성소다를 제조하는 벙법으로서, 중금속인 수은의 환경 오염문제로 인하여 현재는 사용되지 않는 방법이다.In addition, the mercury method is a method of preparing caustic soda using mercury as a negative electrode material, which is not currently used due to environmental pollution of mercury, which is a heavy metal.
한편, 상기 이온교환막법은 전해조 내부에 이온교환막을 설치하고, 양면으로 구획된 전해조의 양극수조와 음극수조에 양극단자와 음극단자를 설치한 후 전해질로 염수를 사용하여 상기 두 전극단자에 전력을 공급함으로써, 양극에서는 염소가스를 그리고 음극에서는 수소 및 가성소다를 얻는 방법이다.On the other hand, in the ion exchange membrane method, the ion exchange membrane is installed inside the electrolytic cell, the anode and cathode terminals are installed in the anode and cathode tanks of the electrolytic cell partitioned on both sides, and the brine is used as an electrolyte to supply power to the two electrode terminals. By supplying, chlorine gas is obtained at the positive electrode and hydrogen and caustic soda at the negative electrode.
즉, 삼투막을 사이에 두고 서로 연결된 음극단자가 있는 음극수조에는 일정량의 물을 주입하고 양극단자가 있는 양극수조에는 일정량의 염화나트륨용액을 주입한다. That is, a certain amount of water is injected into the cathode tank having the anode terminals connected to each other with an osmotic membrane interposed therebetween, and a certain amount of sodium chloride solution is injected into the anode tank having the anode terminals.
이와 같은 상태에서 음극단자와 양극단자에 각각 전력을 인가하게 되면, 음극으로는 양이온인 수소이온(H+)이 그리고 양극으로는 음이온인 염화이온(Cl-)이 모여 기체로 날아간다.In this state, when power is applied to the negative electrode terminal and the positive electrode terminal, hydrogen ions (H + ), which are positive ions, and chloride ions (Cl ), which are negative ions, fly to the gas as the negative electrode.
따라서, 수산화이온(OH-)과 나트륨이온(Na+)이 남게 되며, 상기 수산화이온(OH-)과 나트륨이온(Na+)이 반응하여 수산화나트륨(NaOH)이 되는 것이다.Accordingly, the hydroxide ions (OH ) and sodium ions (Na + ) remain, and the hydroxide ions (OH ) and sodium ions (Na + ) react to form sodium hydroxide (NaOH).
그러나, 상기와 같은 이온교환막법을 이용하여 가성소다를 제조하는 장치는, 상술한 바와 같은 전기분해를 수행함에 있어서 상당히 큰 전력이 소요되는 문제점이 있다.However, the apparatus for producing caustic soda using the ion exchange membrane method as described above has a problem in that a large amount of power is required in performing the electrolysis as described above.
즉, 이러한 전기는 통상적으로 화석연료를 통해 생산하게 되는데, 이와 같이 전기를 생산할 때 사용하는 화석연료는 이산화 탄소를 배출하여 지구 온난화를 가속화시키는 문제점이 있다.That is, such electricity is usually produced through fossil fuels, and thus fossil fuels used to produce electricity have a problem of accelerating global warming by emitting carbon dioxide.
또한, 상기한 바와 같이 화석연료로 생산된 전기를 이용할 경우에는 가성소다의 제조 비용이 상승되는 문제점이 있다.In addition, when using electricity produced as fossil fuel as described above there is a problem that the manufacturing cost of caustic soda rises.
따라서, 본 발명은 상술한 문제점을 해소하기 위해 안출된 것으로서, 그 목적은 태양광 발전부 및 유수력 발전부와 같은 발전수단을 통해 자체적으로 전력을 생산하고, 그 생산된 전력을 이용하여 해수를 가성소다와 담수로 분리하여 제조함으로써, 외부의 전력 공급이 없어서 지구 온난화의 원인인 이산화탄소의 배출과 화석연료를 배제하면서도, 가성소다와 담수의 제조에 따른 막대한 비용을 절감할 수 있는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법 및 장치를 제공하는 것이다.Accordingly, the present invention has been made to solve the above-described problems, the object of which is to produce power by itself through power generation means, such as solar power generation unit and hydroelectric power generation unit, using the produced power to produce seawater By separating it into caustic soda and fresh water, it uses green energy that can reduce the enormous cost of caustic soda and fresh water while eliminating carbon dioxide emissions and fossil fuels that cause global warming because there is no external power supply. It is to provide a method and apparatus for separating seawater into caustic soda and fresh water.
상기의 목적을 달성하기 위한 본 발명의 일측면에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치는, 해수를 일정량 펌핑하여 정제한 후 배출시키는 저수조(110)와, 상기 저수조(110)의 일측면에 연결되어 상기 저수조(110)로부터 배출되는 해수를 흘려보내는 수로(120)와, 상기 저수조(110)와 수로(120)의 양측에 각각 설치되어 해수를 전기분해하는 양극 및 음극의 전극(130)과, 상기 수로(120)의 일측면에 설치되어 상기 전극(130)에 전기를 공급하는 전원공급부(140)와, 상기 전원공급부(140)에 자체적으로 생산된 전력을 공급하는 발전수단(150)과, 상기 수로(120)를 통과하면서 전기분해된 가성소다 포함수를 내측으로 유입시켜 분사 및 가열함과 동시에 함유된 수분을 증발시켜 가성소다와 담수로 분리하는 증발타워(160)를 포함한다.The apparatus for separating seawater into caustic soda and fresh water using the green energy according to an aspect of the present invention for achieving the above object, the storage tank 110 for pumping and purifying the seawater after a certain amount, and the reservoir ( Connected to one side of the 110 and the channel 120 for flowing out the seawater discharged from the reservoir 110, the positive and negative electrodes are respectively installed on both sides of the reservoir 110 and the channel 120 to electrolyze seawater The electrode 130 and the power supply unit 140 is installed on one side of the waterway 120 to supply electricity to the electrode 130, and to supply the power produced by itself to the power supply unit 140 The evaporation tower for separating the caustic soda and fresh water by injecting and heating the power generation means 150 and the caustic soda-containing water which is electrolyzed while passing through the waterway 120 and spraying and heating at the same time. ).
한편, 상기의 목적을 달성하기 위한 본 발명의 다른 측면에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법은, (A) 태양광 발전부(1510)를 통해 자체적으로 전력을 생산하여 전원공급부(140)에 공급한 후 전극(130)을 통해 전기를 공급하게 하는 단계(S210); (B) 이물질이 정제된 해수를 저수조(110)에 일시 저장한 후 상기 전극(130)을 통해 1차적으로 전기분해하는 단계(S220); (C) 상기 저수조(110)로부터 1차 전기분해된 해수를 흘려보내면서 수로(120)에서 전극(130)을 통해 2차 전기분해하는 단계(S230); (D) 상기 (C) 단계를 통해 전기분해된 가성소다 포함수를 분출구(1601)를 통해 내측으로 유입하여 분사함과 동시에 증발챔버(1610)를 통해 가열하여 증기를 발생시키는 단계(S240); (E) 상기 증발챔버(1610)에서 가열된 증기를 이동덕트(1615)를 통해 공급받아 증기 터빈 발전기(1620)를 발전시키는 단계(S250); 및 (F) 상기 (D) 단계에서 상기 증발챔버(1610)를 통해 가열되어 농축된 가성소다를 배수구(1603)를 통해 수집하고, 상기 (E) 단계에서 상기 증기 터빈 발전기(1620)를 발전시키고 남은 수증기를 액화시켜 담수로 사용하는 단계(S260)를 포함한다.On the other hand, the method of separating the seawater into caustic soda and fresh water using the green energy according to another aspect of the present invention for achieving the above object, (A) to produce power by itself through the solar power generation unit 1510 Supplying power to the power supply unit 140 and supplying electricity through the electrode 130 (S210); (B) temporarily storing the purified seawater in the storage tank 110 and first electrolyzing the electrode 130 through the electrode 130 (S220); (C) performing second electrolysis through the electrode 130 in the waterway 120 while flowing the first electrolyzed seawater from the reservoir 110 (S230); (D) injecting the caustic soda-containing water electrolyzed through the step (C) into the inlet through the jet port 1601 and simultaneously heating the same through the evaporation chamber 1610 to generate steam (S240); (E) receiving steam heated in the evaporation chamber 1610 through a moving duct 1615 to generate a steam turbine generator 1620 (S250); And (F) collecting the concentrated caustic soda heated through the evaporation chamber 1610 through the drain 1160 in step (D), and generating the steam turbine generator 1620 in step (E). Liquefy the remaining water vapor to use it as fresh water (S260).
상술한 바와 같이 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법 및 장치에 의하면, 태양광 발전부 및 유수력 발전부와 같은 발전수단을 통해 자체적으로 전력을 생산하고, 그 생산된 전력을 이용하여 전기분해를 통해 3.5%의 소금이 함유된 해수를 가성소다와 담수로 분리함으로써, 외부의 전력 공급이 없어서 가성소다와 담수의 제조에 따른 이산화탄소의 배출을 배제시킬 수 있을 뿐만 아니라 화석연료를 배제하여, 공해와 지구 온난화 방지에 기여하면서도 가성소다와 담수의 제조 비용을 현저히 절감시킬 수 있다.According to the method and apparatus for separating seawater into caustic soda and fresh water using the green energy according to the present invention as described above, the power is produced by itself through power generation means such as solar power generation unit and hydroelectric power generation unit, By using the electricity generated, the seawater containing 3.5% of salt is separated into caustic soda and fresh water through electrolysis, so that there is no external power supply, so it is possible to exclude the emission of carbon dioxide from the manufacture of caustic soda and fresh water. In addition, the elimination of fossil fuels can significantly reduce the cost of producing caustic soda and fresh water, while contributing to the prevention of pollution and global warming.
또한, 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법 및 장치에 의하면, 전기분해된 가성소다 포함수를 증발타워를 통해 가열하여 수분을 증발시킨 후, 증발된 증기를 터빈 발전기에 전달하여 전기를 생산할 수 있을 뿐만 아니라, 터빈 발전기를 발전시키면서 배출되는 응축수를 담수로 사용할 수 있다.In addition, according to the method and apparatus for separating seawater into caustic soda and fresh water using the green energy according to the present invention, the evaporated steam is heated after evaporating water by heating the electrolyzed caustic soda-containing water through an evaporation tower. In addition to producing electricity by passing it to the turbine generator, the condensate discharged while generating the turbine generator can be used as fresh water.
도 1은 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치를 개략적으로 나타내는 도면.1 is a view schematically showing an apparatus for separating seawater into caustic soda and fresh water using green energy according to the present invention.
도 2 내지 도 4는 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치의 발전수단을 나타내는 도면.2 to 4 is a view showing the power generation means of the apparatus for separating seawater into caustic soda and fresh water using the green energy according to the present invention.
도 5는 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치의 증발타워를 나타내는 단면도.Figure 5 is a cross-sectional view showing an evaporation tower of the device for separating seawater into caustic soda and fresh water using the green energy according to the present invention.
도 6은 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법을 나타내는 순서도.Figure 6 is a flow chart illustrating a method for separating seawater into caustic soda and fresh water using the green energy according to the present invention.
도 7은 상기 도 6의 S240 단계의 서브루틴을 나타내는 순서도.7 is a flowchart showing a subroutine of step S240 of FIG.
*도면의 주요부분에 대한 부호의 설명** Description of the symbols for the main parts of the drawings *
110 : 저수조 120 : 수로 122 : 저장조110: reservoir 120: channel 122: reservoir
130 : 전극 140 : 전원공급부 150 : 발전수단130 electrode 140 power supply unit 150 power generation means
160 : 증발타워 1510 : 태양광 발전부 1520 : 유수력 발전부160: evaporation tower 1510: solar power generation unit 1520: hydroelectric power generation unit
1521 : 고정틀 1522 : 프로펠러 1523 : 회전축1521: fixed frame 1522: propeller 1523: rotating shaft
1524 : 증속기어부 1525 : 컨버터 1526 : 발전기1524: Increase gear unit 1525: Converter 1526: Generator
1601 : 분출구 1602 : 분사구 1603 : 배수구1601: ejection opening 1602: injection opening 1603: drain
1604 : 도어 1610 : 증발챔버 1612 : 히터1604 door 1610 evaporation chamber 1612 heater
1614 : 초음파 발생부 1616 : 마그네트론 1615 : 이동덕트1614: ultrasonic generator 1616: magnetron 1615: mobile duct
1620 : 증기 터빈 발전기1620: Steam Turbine Generator
이하, 첨부한 도면을 참조하여 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법 및 장치를 상세하게 설명한다.Hereinafter, a method and apparatus for separating seawater into caustic soda and fresh water using green energy according to the present invention will be described in detail with reference to the accompanying drawings.
본 명세서의 도면들 중, 동일한 구성요소 또는 부품들은 가능한 한 동일한 참조부호를 나타내고 있음에 유의하여야 한다. 본 발명을 설명함에 있어, 관련된 공지기능 혹은 구성에 대한 구체적인 설명은 발명의 요지를 모호하지 않게 하기 위하여 생략한다. In the drawings of the present specification, it should be noted that like elements or parts represent the same reference numerals as much as possible. In describing the present invention, detailed descriptions of related well-known functions or configurations are omitted in order not to obscure the subject matter of the present invention.
먼저, 도 1 내지 도 5를 참조하여 본 발명의 일측면에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치를 설명한다.First, a device for separating seawater into caustic soda and fresh water using green energy according to an aspect of the present invention will be described with reference to FIGS. 1 to 5.
도 1은 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치를 개략적으로 나타내는 도면이고, 도 2 내지 도 4는 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치의 발전수단을 나타내는 도면이며, 도 5는 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치의 증발타워를 나타내는 단면도이다.1 is a view schematically showing an apparatus for separating seawater into caustic soda and fresh water using green energy according to the present invention, and FIGS. 2 to 4 are caustic soda and fresh water using green energy according to the present invention. 5 is a cross-sectional view showing an evaporation tower of a device for separating seawater into caustic soda and fresh water using green energy according to the present invention.
도시된 바와 같이, 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치(100)는, 펌핑한 해수를 일시 저장한 후 1차적으로 전기분해하여 배출시키는 저수조(110)와, 상기 저수조의 일측면에 연결되어 상기 저수조로부터 배출되는 해수를 흐르게 하면서 2차적으로 전기분해하는 수로(120)와, 상기 저수조(110)와 수로(120)의 양측에 각각 설치되어 해수를 전기분해하는 양극 및 음극의 전극(130)과, 상기 수로(120)의 일측면에 설치되어 상기 전극(130)에 전기를 공급하는 전원공급부(140)와, 상기 전원공급부(140)에 자체적으로 생산된 전력을 공급하는 발전수단(150)과, 상기 수로(120)를 통과하면서 전기분해된 가성소다 포함수를 내측으로 유입 및 가열함과 동시에 함유된 수분을 증발시켜 해수를 가성소다와 담수로 분리하는 증발타워(160)를 포함한다.As shown, the device 100 for separating the seawater into caustic soda and fresh water using the green energy according to the present invention, the storage tank 110 for temporarily storing the pumped seawater and then electrolyzed and discharged Is connected to one side of the reservoir, while flowing through the seawater discharged from the water reservoir 120 for the second electrolysis, and installed on both sides of the reservoir 110 and the water channel 120, respectively, electrolysis of sea water Electrode 130 of the positive and negative electrodes to be installed on one side of the waterway 120 to supply electricity to the electrode 130 and the self-produced in the power supply 140 Passing the power generation means 150 for supplying power and the caustic soda-containing water electrolyzed while passing through the water channel 120 and simultaneously evaporating the water contained therein to separate seawater into caustic soda and fresh water Evaporation Tower (160) It includes.
구체적으로, 도 1 및 도 2에 도시된 바와 같이, 상기 저수조(110)는 외부로부터 펌핑된 해수를 일정량 저장하여 1차적으로 전기분해하는 수단으로서, 수로(120)를 통해 해수를 배출시킬 수 있도록 일면에 개구부가 형성되어 있다.Specifically, as shown in FIGS. 1 and 2, the reservoir 110 is a means for primarily electrolyzing by storing a predetermined amount of seawater pumped from the outside, so that the seawater can be discharged through the water channel 120. Openings are formed on one surface.
상기 수로(120)는 상기 저수조(110)의 개구부와 일단이 연결되어 해수를 흘려보내면서 2차적으로 전기분해하는 수단으로서, 양단이 개구된 "U"자 형상의 단면으로 형성된 연결관(121)과, 상기 저수조(110)와 수로(120)를 통해 전기분해된 가성소다 포함수를 일시적으로 저장하여 증발타워(160) 측으로 펌핑을 통해 공급하게 하는 저장조(122)로 구성된다.The channel 120 is a means for secondary electrolysis while one end is connected to the opening of the reservoir 110 to flow the sea water, and the connection pipe 121 is formed in a cross section of a “U” shape with both ends opened. And, it consists of a reservoir 122 to temporarily store the caustic soda-containing water electrolyzed through the reservoir 110 and the water channel 120 to be supplied to the evaporation tower 160 by pumping.
이때, 상기 수로(120)는 콘크리트나 금속 또는 합성수지 등으로 일정한 길이를 갖는 단위 유니트로 성형한 후, 서로 연결되어 누수를 방지할 수 있게 구성하는 것이 바람직하다.In this case, the water channel 120 is preferably formed in a unit unit having a certain length of concrete, metal or synthetic resin, etc., it is preferably configured to be connected to each other to prevent leakage.
예를 들면, 상기 수로(120)는 가로 1m, 높이 1m, 길이 2.5m정도의 단위 유니트를 만들고, 만들어진 단위 유니트를 300~500세트 혹은 그 이상을 일렬로 연결하여, 조건에 따라 증감하여 구성할 수 있다. 또한, 상기 수로(120)는 주변 상황에 따라 폭, 높이 등을 다양하게 구성할 수 있음은 물론이다.For example, the channel 120 is made of a unit unit of about 1m in width, 1m in height, 2.5m in length, and connected to 300-500 sets or more in series, and increase or decrease according to the conditions. Can be. In addition, the channel 120 may be configured in various ways, such as width, height depending on the surrounding situation.
또한, 상기와 같이 구성된 수로(120)는 해수가 저수조(110)로부터 저장조(122)에 자연스럽게 흐를 수 있도록 구성되며, 이때 수로의 경사 각도는 지면의 형태에 따라 45도 이내에서 설정될 수 있다.In addition, the channel 120 configured as described above is configured so that the sea water flows naturally from the reservoir 110 to the reservoir 122, wherein the inclination angle of the channel can be set within 45 degrees according to the shape of the ground.
한편, 상기 전극(130)은 저수조(110)의 일측면 및 타측면에 음극(-) 및 양극(+)이 일정 간격으로 복수개 설치되어 상기 저수조(110) 내에 저장된 해수를 1차적으로 전기분해하고, 상기 수로(120)의 연결관(121)의 일측면 및 타측면에 음극(-) 및 양극(+)이 일정 간격으로 복수개 설치되어 상기 연결관(121)을 따라 연속적으로 흐르는 해수를 2차적으로 전기분해한다.On the other hand, the electrode 130 has a plurality of cathodes (-) and anodes (+) are provided on one side and the other side of the reservoir 110 at regular intervals to electrolyze the seawater stored in the reservoir 110 primarily In addition, a plurality of cathodes (-) and anodes (+) are installed on one side and the other side of the connection pipe 121 of the water channel 120 at regular intervals to secondary the seawater flowing continuously along the connection pipe 121. Electrolyze with
상기 전원공급부(140)는 상기 수로(120)의 일측 벽면에 설치되어 상기 발전수단(150)으로부터 생산된 전기를 축적하여 상기 전극(130) 및 증발타워(160)에 공급한다.The power supply unit 140 is installed on one wall surface of the water channel 120 to accumulate the electricity produced from the power generating means 150 and supply it to the electrode 130 and the evaporation tower 160.
상기 발전수단(150)은 상기 수로(120)를 따라 흐르는 해수를 이용한 유수력발전 및 태양광과 같은 친환경적인 발전을 통해 전기를 생산하여, 그 생산된 전기를 상기 전원공급부(140)에 공급한다.The power generation unit 150 generates electricity through eco-friendly power generation such as hydroelectric power generation and solar power using seawater flowing along the waterway 120, and supplies the generated electricity to the power supply unit 140. .
즉, 도 1 내지 도 4에 도시된 바와 같이, 상기 발전수단(150)은 각도가 조절되는 복수개의 태양전지판을 구비하여 집광되는 태양광을 축적하여 전기를 생산하는 1차 발전수단인 태양광 발전부(1510)와, 상기 수로(120)를 따라 흐르는 해수에 의해 회전력을 발생시키고, 발생된 회전력을 발전기에서 발전시켜 전기를 생산하는 2차 발전수단인 유수력 발전부(1520, BOS 수력발전부)로 구성된다.That is, as shown in Figures 1 to 4, the power generation means 150 is provided with a plurality of solar panels of which the angle is adjusted solar power generation as a primary power generation means for generating electricity by accumulating sunlight collected Hydroelectric power generation unit 1520, a second generation means for generating electricity by generating a rotational force by the seawater flowing along the waterway 120 and the generated rotational force in the generator 1510, BOS hydroelectric power generation unit It is composed of
이때, 상기 저수조(110) 및 수로(120)에 설치된 전극(130)을 통해 전기분해를 할 때에는 직류를 이용함에 따라, 태양광 발전부(1510)에서 생산된 직류 전기는 그대로 전원공급부(140)에 공급되고, 유수력 발전부(1520)에서 생산된 교류 전기는 컨버터(1525)를 통해 직류로 변환되어 전원공급부(140)에 공급된다.In this case, when electrolysis is performed through the electrode 130 installed in the water tank 110 and the water channel 120, the DC electricity produced by the solar power generation unit 1510 is used as it is. Supplied to the AC power produced by the hydroelectric power generation unit 1520 is converted into direct current through the converter 1525 and supplied to the power supply unit 140.
한편, 본 명세서에서는 상기 태양광 발전부(1510)와 유수력 발전부(1520)를 모두 설치하여 발전량을 최대한으로 확보하는 구성으로 설명하고 있지만, 필요한 전원을 공급할 수 있기만 하면, 둘 중 어느 하나만을 설치하여도 상관없음은 물론이다.In the present specification, the solar power generation unit 1510 and the hydroelectric power generation unit 1520 are both installed and described as a configuration to secure the maximum amount of power generation, but as long as it can supply the necessary power, only one of the two Of course, you can install it.
여기서, 상기 태양광 발전부(1510)는 수로(120)의 상단을 따라 복수개 설치되며, 충분한 발전량을 확보하기 위해 수로 바깥쪽 지면에 복수개 설치되어도 상관없다.Here, the photovoltaic unit 1510 may be provided in plural along the upper end of the channel 120, and may be provided in plural on the outer surface of the channel in order to secure a sufficient amount of power generation.
한편, 상기 유수력 발전부(1520)는 상기 수로(120)의 내부에 일정 간격으로 복수개 설치되어, 상기 수로(120)를 따라 흐르는 해수에 의해 회전하는 프로펠러(1522)와, 상기 프로펠러(1522)의 회전력을 전달할 수 있도록 서로 맞물림되어 회전되는 대기어 및 소기어로 구성된 증속기어부(1524)와, 상기 증속기어부(1524)의 회전운동을 전달받아 발전하는 발전기(1526)로 구성된다.On the other hand, the hydroelectric power generation unit 1520 is provided in a plurality at a predetermined interval inside the waterway 120, the propeller 1522 to rotate by the seawater flowing along the waterway 120, and the propeller 1522 An increase gear unit 1524 composed of a standby gear and a small gear rotated to be engaged with each other so as to transmit the rotational force, and a generator 1526 that receives the rotational movement of the increase gear unit 1524 and generates power.
이때, 상기 프로펠러(1522)는 각각의 날개가 해수의 흐름에 따라 회전이 잘 이루어질 수 있도록 일방향으로 오목한 반구형상의 단면으로 형성되어 축의 하단에 용접 또는 볼트 및 너트를 통해 고정된다.At this time, the propeller 1522 is formed in a hemispherical cross-section concave in one direction so that each wing is rotated according to the flow of sea water is fixed to the lower end of the shaft through welding or bolts and nuts.
즉, 상기 프로펠러(1522)는 높이차를 두고 고정틀(1521)에 회전가능하게 구비된 회전축(1523)의 일단에 다단으로 형성된다.That is, the propeller 1522 is formed in multiple stages at one end of the rotation shaft 1523 rotatably provided in the fixing frame 1521 with a height difference.
한편, 상기 증속기어부(1524)는, 상기 회전축(1523)에 직경이 큰 대기어와, 상기 대기어와 기어 물림되는 직경이 작은 소기어가 번갈아 맞물려 10:1 정도의 기어비에 의해 회전 속도가 증가하게 구성되어, 상기 수로(120)를 따라 흐르는 해수의 양이 적고 속도가 느려 상기 프로펠러(1522)가 느리게 회전하더라도 증속된 회전력이 발전기(1526)에 전달될 수 있게 구성된다.On the other hand, the speed increase gear unit 1524, the large rotational gear and the small gear geared to the rotational shaft 1523 and the small diameter to be meshed with the rotating shaft 1523 is alternately meshed to increase the rotational speed by a gear ratio of about 10: 1. In this case, the amount of seawater flowing along the waterway 120 is small and the speed is slow so that the increased rotational force can be transmitted to the generator 1526 even if the propeller 1522 rotates slowly.
이때, 상기 대기어와 소기어의 기어비는 10:1로 설명하고 있으나, 이에 한정되지 않음은 물론이다.In this case, the gear ratio of the standby gear and the small gear is described as 10: 1, but is not limited thereto.
한편, 상기 증발타워(160)는 수로(120)를 통하여 흐르는 중에 전기분해되어 저장조(122)에 저장된 가성소다 포함수를 공급받아 가열한다.On the other hand, the evaporation tower 160 is heated by receiving the caustic soda-containing water stored in the reservoir 122 by electrolysis while flowing through the water channel (120).
즉, 도 1 및 도 5에 도시된 바와 같이, 상기 증발타워(160)는 상기 수로(120)의 저장조(122)로부터 공급되는 가성소다 포함수를 펌프(도시 생략)를 통해 상부측으로 유입 및 분사한 후 가열함으로써 발생된 증기를 배출하는 수단으로서, 상기 저장조(122)로부터 공급되는 가성소다 포함수를 분사하는 분출구(1601)와, 상기 증발타워(160)의 내부에 상부로부터 적어도 3개 이상 순차적으로 적층되어 상기 분출구(1601)를 통해 배출되는 가성소다 포함수를 가열하여 증기를 발생시키는 증발챔버(1610)와, 상기 증발챔버(1610)로부터 발생된 증기를 이동덕트(1615)를 통해 공급받아 발전되는 증기 터빈 발전기(1620)를 포함한다.That is, as shown in FIGS. 1 and 5, the evaporation tower 160 injects and sprays caustic soda-containing water supplied from the reservoir 122 of the water channel 120 to the upper side through a pump (not shown). As a means for discharging the steam generated by heating after the heating, a jet port 1601 for spraying caustic soda-containing water supplied from the reservoir 122, and at least three or more sequentially from the top in the evaporation tower 160 The evaporation chamber 1610 for generating steam by heating the caustic soda-containing water discharged through the jet port 1601 and the steam generated from the evaporation chamber 1610 is supplied through the moving duct 1615. A steam turbine generator 1620 that is developed is included.
이때, 상기 증발타워(160)의 내부는 적어도 3개 이상의 증발챔버(1610)를 순차적으로 적층시킬 수 있도록 구획되어 있고, 구획된 공간부에는 상기 증발챔버(1610)를 각각 설치함과 동시에 바닥면에는 각각의 증발챔버(1610)를 통해 수분이 증발된 가성소다 포함수를 하단으로 분사시키는 분사구(1602)가 각각 형성되어 있으며, 전면에는 상기 증발챔버(1610)의 유지관리를 위해 개폐되는 도어(1604)가 형성되어 있다.At this time, the inside of the evaporation tower 160 is partitioned so that at least three or more evaporation chambers 1610 can be sequentially stacked, and the evaporation chambers 1610 are respectively installed in the partitioned space and the bottom surface thereof. In each of the evaporation chamber (1610) is formed with a spray port (1602) for injecting the caustic soda-containing water evaporated through the respective evaporation chamber 1610, the front door is opened and closed for maintenance of the evaporation chamber (1610) ( 1604 is formed.
여기서, 가성소다 포함수는 상기 분출구(1601) 및 분사구(1602)를 통해 하단으로 자유낙하에 의해 분사하도록 구성되어 있으나, 이에 한정되지 않고 상기 분출구(1601) 및 분사구(1602) 내부에 회전모터를 구비하여 분사될 수 있음은 물론이다.Here, the caustic soda-containing water is configured to spray by the free fall to the lower end through the jet port 1601 and the injection port 1602, but is not limited to the rotary motor inside the jet port 1601 and the injection port 1602. Of course, it can be equipped with a spray.
또한, 도 5에 도시된 바와 같이, 상기 증발챔버(1610)는 증발타워(160)의 내부에 순차적으로 적층되어 상기 분출구(1601) 및 각각의 분사구(1602)를 통해 유입 및 분사된 가성소다 포함수를 가열한다.In addition, as shown in FIG. 5, the evaporation chamber 1610 is sequentially stacked inside the evaporation tower 160 and includes caustic soda that is introduced and injected through the ejection openings 1601 and the respective injection ports 1602. Heat the water.
구체적으로, 상기 증발챔버(1610)는 내부에 고정 설치되어 분사되는 가성소다 포함수에 열을 가하는 히터(1612)와, 상기 증발챔버(1610)의 일측면에 장착되어 상기 히터에 의해 열이 인가된 가성소다 포함수가 증발챔버의 측면부에 고이면 초음파를 발생시키는 초음파 발생부(1614)와, 상기 증발챔버(1610)의 타측면에 장착되어 상기 히터와 초음파 발생부를 통해 분사되는 수분입자를 순간적으로 가열하여 수증기를 폭발적으로 증대시키는 마그네트론(1616)으로 구성된다.Specifically, the evaporation chamber 1610 is mounted on one side of the evaporation chamber 1610 and the heater 1612 to apply heat to the caustic soda-containing water is fixedly installed therein, the heat is applied by the heater When the caustic soda-containing water is accumulated in the side of the evaporation chamber, an ultrasonic generator 1614 for generating ultrasonic waves is mounted on the other side of the evaporation chamber 1610 and instantaneously heats the water particles sprayed through the heater and the ultrasonic generator. It is composed of a magnetron 1616 that explosively increases water vapor.
이때, 상기 히터(1612)와 초음파 발생부(1614)에 의해 증발로 분리된 수증기가 마그네트론(1616)에서 발사된 마이크로 웨이브에 의해 미세 입자로 분해되어 증폭되며 상기 이동덕트(1615)를 통해 배출되면서 증기 터빈 발전기(1620)를 가동시키며, 상기 증기 터빈 발전기(1620)를 통해 자체적으로 발전된 전기를 상기 히터(1612), 초음파 발생부(1614) 및 마그네트론(1620)에 공급하여 가동시킨다.At this time, the water vapor separated by evaporation by the heater 1612 and the ultrasonic generator 1614 is decomposed into fine particles by a microwave emitted from the magnetron 1616 and amplified and discharged through the moving duct 1615. The steam turbine generator 1620 is operated, and electricity generated by the steam turbine generator 1620 is supplied to the heater 1612, the ultrasonic generator 1614, and the magnetron 1620.
한편, 상기 증발타워(160)의 외부에는 상기 증기 터빈 발전기(1620)를 발전시키고 남은 수증기를 저장하여 농산업 용수로 사용하는 담수 저장탱크(1625)와, 상기 3개의 증발챔버(1610)를 통해 가열되어 농축된 가성소다를 배수구(1603)를 통해 수집하는 가성소다 저장탱크(1630)를 포함하며, 이때 상기 농축된 가성소다에 톱밥 등을 혼합하면 유기질 천연비료로 사용할 수도 있다.On the other hand, outside the evaporation tower 160, the steam turbine generator 1620 generates power and is stored in the fresh water storage tank 1625 used as agricultural water to store the remaining water vapor, and is heated through the three evaporation chamber (1610) It includes a caustic soda storage tank 1630 collecting the concentrated caustic soda through the drain 1160, and may be used as an organic natural fertilizer by mixing sawdust and the like in the concentrated caustic soda.
이하, 상술한 도 1 내지 도 5와, 도 6 및 도 7을 참조하여 본 발명의 다른 측면에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법을 설명한다.Hereinafter, a method of separating seawater into caustic soda and fresh water using green energy according to another aspect of the present invention will be described with reference to FIGS. 1 to 5 and FIGS. 6 and 7.
도 6은 본 발명에 따른 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법을 나타내는 순서도이고, 도 7은 상기 도 6의 S240 단계의 서브루틴을 나타내는 순서도이다.6 is a flowchart illustrating a method of separating seawater into caustic soda and fresh water using green energy according to the present invention, and FIG. 7 is a flowchart illustrating a subroutine of step S240 of FIG. 6.
먼저, 태양광 발전부(1510)를 통해 자체적으로 전력을 생산하여 전원공급부(140)에 공급한 후 전극(130)을 통해 전기를 공급하게 한다(S210).First, power is produced by itself through the solar power generation unit 1510 and then supplied to the power supply unit 140 to supply electricity through the electrode 130 (S210).
다음에, 이물질이 정제된 해수를 저수조(110)에 일시 저장한 후 전극(130)을 통해 1차적으로 전기분해한다(S220).Next, the seawater purified by the foreign matter is temporarily stored in the reservoir 110 and then electrolyzed first through the electrode 130 (S220).
그 다음, 상기 저수조(110)로부터 1차 전기분해된 해수를 흘려보내면서 수로(120)에서 전극(130)을 통해 2차 전기분해한다(S230).Then, the second electrolysis through the electrode 130 in the channel 120 while flowing the first electrolyzed seawater from the reservoir 110 (S230).
이때, 상기 수로(120)를 따라 해수가 흐르는 중에 유수력 발전부(1520)를 통해 자체적으로 교류 전력을 생산한 후, 컨버터(1525)를 통해 직류로 변환하여 전원공급부(140)로 공급한다(S235).At this time, the seawater flows along the waterway 120 to produce AC power by itself through the hydroelectric power generation unit 1520, and then converts the DC power through the converter 1525 to the power supply unit 140 ( S235).
이후, 상기 S230 단계를 통해 전기분해된 가성소다 포함수를 분출구(1601)를 통해 내측으로 유입하여 분사함과 동시에 증발챔버(1610)를 통해 가열하여 증기를 발생시킨다(S240).Thereafter, the caustic soda-containing water electrolyzed in the step S230 is introduced into the inlet through the jet port 1601 and sprayed through the evaporation chamber 1610 to generate steam (S240).
이때, 상기 S240 단계에서, 증발챔버(1610)를 통해 가성소다 포함수를 가열하여 증기를 발생시키는 과정은, 히터(1612)가 상부로부터 분사되는 가성소다 포함수를 가열하는 단계(S242)와, 상기 S242 단계를 통해 가열된 가성소다 포함수가 증발챔버(1610)의 측면에 고이면 초음파 발생부(1614)가 초음파를 발생시키는 단계(S244)와, 상기 히터(1612)와 초음파 발생부(1614)를 통해 분사되는 수분입자를 마그네트론(1616)이 순간적으로 가열하여 수증기를 폭발적으로 증대시키는 단계(S246)를 포함한다.At this time, in the step S240, the process of generating steam by heating the caustic soda-containing water through the evaporation chamber 1610, the step of heating the caustic soda-containing water is sprayed from the heater (1612) (S242), When the caustic soda-containing water heated through the step S242 is accumulated on the side of the evaporation chamber 1610, the ultrasonic generator 1614 generates ultrasonic waves (S244), and the heater 1612 and the ultrasonic generator 1614 are provided. The magnetron 1616 instantaneously heats the water particles sprayed through the exponentially increasing water vapor (S246).
상기 S240 단계 이후, 상기 증발챔버(1610)에서 가열된 증기를 이동덕트(1615)를 통해 공급받아 증기 터빈 발전기(1620)를 발전시킨다(S250).After the step S240, the steam heated in the evaporation chamber 1610 is supplied through a moving duct 1615 to generate a steam turbine generator 1620 (S250).
이때, 상기 증기 터빈 발전기(1620)를 통해 자체적으로 발전된 전기를 상기 히터(1612), 초음파 발생부(1614) 및 마그네트론(1620)에 공급하여 가동시킨다.At this time, the electricity generated by the steam turbine generator 1620 itself is supplied to the heater 1612, the ultrasonic generator 1614 and the magnetron 1620 to operate.
이후, 상기 S240 단계에서 증발챔버(1610)를 통해 가열되어 농축된 가성소다 를 배수구(1603)를 통해 수집하고, 상기 S250 단계에서 증기 터빈 발전기(1620)를 발전시키고 남은 수증기를 액화시켜 담수로 사용한다(S260).Thereafter, the concentrated caustic soda heated and heated through the evaporation chamber 1610 in step S240 is collected through the drainage port 1603. In step S250, the steam turbine generator 1620 is developed and the remaining water vapor is liquefied and used as fresh water. (S260).
따라서, 상술한 바와 같이, 본 발명에 의하면 외부의 전원을 공급받지 않고 태양광 발전부, 유수력 발전부 및 증기 터빈 발전기를 통해 자체적으로 전기를 생산하여 해수를 가성소다와 담수로 분리하여 제조할 수 있다.Therefore, as described above, according to the present invention can be produced by separating the seawater into caustic soda and fresh water by producing electricity by itself through the photovoltaic unit, the hydropower unit and the steam turbine generator without receiving external power. Can be.
이상에서는 본 발명의 일실시예에 따라 본 발명을 설명하였지만, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 변경 및 변형한 것도 본 발명에 속함은 당연하다.Although the present invention has been described above according to an embodiment of the present invention, a person skilled in the art to which the present invention belongs has changed and modified within the scope without departing from the technical spirit of the present invention. Of course.

Claims (13)

  1. 태양광 또는 유수력과 같은 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치로서,It is a device that separates seawater into caustic soda and fresh water by using green energy such as sunlight or running water.
    해수를 일정량 펌핑하여 정제한 후 배출시키는 저수조(110)와,Reservoir tank 110 for pumping and purifying seawater after purification,
    상기 저수조(110)의 일측면에 연결되어 상기 저수조(110)로부터 배출되는 해수를 흘려보내는 수로(120)와,A water channel 120 connected to one side of the water tank 110 to flow seawater discharged from the water tank 110;
    상기 저수조(110)와 수로(120)의 양측에 각각 설치되어 해수를 전기분해하는 양극 및 음극의 전극(130)과,Electrodes 130 of the positive and negative electrodes that are respectively installed on both sides of the reservoir 110 and the water channel 120 to electrolyze seawater,
    상기 수로(120)의 일측면에 설치되어 상기 전극(130)에 전기를 공급하는 전원공급부(140)와,A power supply unit 140 installed at one side of the channel 120 to supply electricity to the electrode 130;
    상기 전원공급부(140)에 자체적으로 생산된 전력을 공급하는 발전수단(150)과,Power generation means 150 for supplying the power produced itself to the power supply unit 140,
    상기 수로(120)를 통과하면서 전기분해된 가성소다 포함수를 내측으로 유입시켜 분사 및 가열함과 동시에 함유된 수분을 증발시켜 가성소다와 담수로 분리하는 증발타워(160)를 포함하는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.The evaporation tower 160 which separates the caustic soda and fresh water by injecting and heating the electrolyzed caustic soda-containing water into the inside while passing through the waterway 120 and simultaneously evaporating moisture contained therein. A device that separates seawater into caustic soda and fresh water using green energy.
  2. 제 1항에 있어서,The method of claim 1,
    상기 수로(120)는, 양단이 개구된 "U"자 형상의 단면으로 형성된 연결관(121)과, 상기 저수조(110)와 수로(120)를 통해 전기분해된 가성소다 포함수를 일시적으로 저장하여 상기 증발타워(160) 측으로 공급하게 하는 저장조(122)로 구성된 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.The water channel 120 temporarily stores a connecting pipe 121 formed in a “U” shaped cross-section with both ends opened, and caustic soda containing water electrolyzed through the water tank 110 and the water channel 120. The device for separating seawater into caustic soda and fresh water using the green energy, characterized in that consisting of a reservoir 122 for supplying to the evaporation tower (160).
  3. 제 1항에 있어서,       The method of claim 1,
    상기 발전수단(150)은 각도가 조절되는 복수개의 태양전지판을 구비하여 집광되는 태양광을 축적함으로써 전기를 생산하는 태양광 발전부(1510)를 포함하는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.The power generation means 150 includes a photovoltaic power generation unit 1510 that generates electricity by accumulating solar light collected by having a plurality of solar panels whose angles are adjusted. Separation device with caustic soda and fresh water.
  4. 제 1항에 있어서,The method of claim 1,
    상기 발전수단(150)은 상기 수로(120)를 따라 흐르는 해수에 의해 회전력을 발생시키고, 발생된 회전력을 발전기에서 발전시켜 전기를 생산하는 유수력 발전부(1520)를 포함하는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.The power generation unit 150 generates a rotational force by the seawater flowing along the waterway 120, and the hydroelectric power generation unit 1520 for generating electricity by generating the generated rotational force in the generator, characterized in that the green A device that separates seawater into caustic soda and fresh water using energy.
  5. 제 4항에 있어서,The method of claim 4, wherein
    상기 유수력 발전부(1520)는 상기 수로(120)의 내부에 일정 간격으로 복수개 설치되어, 상기 수로(120)를 따라 흐르는 해수에 의해 회전하는 프로펠러(1522)와, 상기 프로펠러(1522)의 회전력을 전달할 수 있도록 서로 맞물림되어 회전되는 대기어 및 소기어로 구성된 증속기어부(1524)와, 상기 증속기어부(1524)의 회전운동을 전달받아 발전하는 발전기(1526)로 구성된 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.The hydroelectric power generating unit 1520 is provided in plural in the water channel 120 at regular intervals, the propeller 1522 to rotate by the seawater flowing along the waterway 120, and the rotational force of the propeller 1522 Green gear, characterized in that consisting of a generator geared to receive the rotational movement of the gearbox (1524) and the gearbox (1524) is rotated and meshed with each other so as to transmit the transmission gear 1515 A device that separates seawater into caustic soda and fresh water using energy.
  6. 제 1항에 있어서,The method of claim 1,
    상기 증발타워(160)는 상기 수로(120)의 저장조(122)로부터 공급되는 가성소다 포함수를 분사하는 분출구(1601)와, 상기 증발타워(160)의 내부에 상부로부터 적어도 3개 이상 순차적으로 적층되어 상기 분출구(1601)를 통해 배출되는 가성소다 포함수를 가열하여 증기를 발생시키는 증발챔버(1610)와, 상기 증발챔버(1610)로부터 발생된 증기를 이동덕트(1615)를 통해 공급받아 발전되는 증기 터빈 발전기(1620)로 구성된 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.The evaporation tower 160 is a spout 1601 for injecting caustic soda-containing water supplied from the reservoir 122 of the waterway 120 and at least three or more sequentially from the top in the evaporation tower 160 The evaporation chamber 1610 for generating steam by heating the caustic soda-containing water which is stacked and discharged through the spout 1601 and the steam generated from the evaporation chamber 1610 are supplied through a moving duct 1615. Apparatus for separating seawater into caustic soda and fresh water using green energy, characterized in that consisting of a steam turbine generator (1620).
  7. 제 6항에 있어서,The method of claim 6,
    상기 증발타워(160)의 내부는 적어도 3개 이상의 증발챔버(1610)를 순차적으로 적층시킬 수 있도록 구획되어 있고, 구획된 공간부에는 상기 증발챔버(1610)를 각각 설치함과 동시에 바닥면에는 각각의 증발챔버(1610)를 통해 수분이 증발된 가성소다 포함수를 하단으로 분사시키는 분사구(1602)가 각각 형성되어 있으며, 전면에는 상기 증발챔버(1610)의 유지관리를 위해 개폐되는 도어(1604)가 형성되어 있는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.The inside of the evaporation tower 160 is partitioned so that at least three or more evaporation chambers 1610 can be sequentially stacked, and the evaporation chambers 1610 are respectively installed in the partitioned spaces, Each of the injection holes 1602 for spraying the caustic soda-containing water evaporated through the evaporation chamber 1610 to the bottom, the front door 1604 is opened and closed for maintenance of the evaporation chamber 1610 A device for separating seawater into caustic soda and fresh water using green energy, characterized in that is formed.
  8. 제 6항에 있어서,The method of claim 6,
    상기 증발챔버(1610)는 내부에 고정 설치되어 상기 분출구(1601) 및 각각의 분사구(1602)를 통해 유입 및 분사된 가성소다 포함수를 가열하는 히터(1612)와, 상기 증발챔버(1610)의 일측면에 장착되어 상기 히터(1612)에 의해 열이 인가된 가성소다 포함수가 증발챔버의 측면부에 고이면 초음파를 발생시키는 초음파 발생부(1614)와, 상기 증발챔버(1610)의 타측면에 장착되어 상기 히터(1612)와 초음파 발생부(1614)를 통해 분사되는 수분입자를 순간적으로 가열하여 수증기를 폭발적으로 증대시키는 마그네트론(1616)으로 구성된 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.The evaporation chamber 1610 is fixedly installed therein, the heater 1612 for heating the caustic soda-containing water introduced and injected through the jet port 1601 and each injection port 1602, and the evaporation chamber 1610 An ultrasonic generator 1614 for generating ultrasonic waves when the caustic soda-containing water, which is mounted on one side and applied with heat by the heater 1612, accumulates in the side portion of the evaporation chamber, and is mounted on the other side of the evaporation chamber 1610 Seawater is caustic soda and fresh water using green energy, which is composed of a magnetron 1616 that explosively increases water vapor by heating the water particles sprayed through the heater 1612 and the ultrasonic generator 1614. Device to separate.
  9. 제 6항에 있어서,The method of claim 6,
    상기 증발타워(160)의 외부에는 상기 증기 터빈 발전기(1620)를 발전시키고 남은 수증기를 저장하여 농산업 용수로 사용하는 담수 저장탱크(1625)와, 상기 증발챔버(1610)를 통해 가열되어 농축된 가성소다 알칼리수를 배수구(1603)를 통해 수집하는 가성소다 저장탱크(1630)를 포함하는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 장치.Outside of the evaporation tower 160, the steam turbine generator 1620 generates the remaining water vapor and stored in the fresh water storage tank (1625) for use as agricultural water and the caustic soda heated through the evaporation chamber (1610). Apparatus for separating seawater into caustic soda and fresh water using green energy, characterized in that it comprises a caustic soda storage tank (1630) for collecting alkaline water through the drain (1603).
  10. 태양광 또는 유수력과 같은 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법으로서,As a method of separating seawater into caustic soda and fresh water by using green energy such as sunlight or hydropower,
    (A) 태양광 발전부(1510)를 통해 전력을 생산하여 전원공급부(140)에 공급한 후 전극(130)을 통해 전기를 공급하게 하는 단계(S210);(A) producing power through the solar power generation unit 1510 and supplying power to the power supply unit 140 to supply electricity through the electrode 130 (S210);
    (B) 이물질이 정제된 해수를 저수조(110)에 일시 저장한 후 상기 전극(130)을 통해 1차적으로 전기분해하는 단계(S220);(B) temporarily storing the purified seawater in the storage tank 110 and first electrolyzing the electrode 130 through the electrode 130 (S220);
    (C) 상기 저수조(110)로부터 1차 전기분해된 해수를 흘려보내면서 수로(120)에서 전극(130)을 통해 2차 전기분해하는 단계(S230);(C) performing second electrolysis through the electrode 130 in the waterway 120 while flowing the first electrolyzed seawater from the reservoir 110 (S230);
    (D) 상기 (C) 단계를 통해 전기분해된 가성소다 포함수를 분출구(1601)를 통해 내측으로 유입하여 분사함과 동시에 증발챔버(1610)를 통해 가열하여 증기를 발생시키는 단계(S240);(D) injecting the caustic soda-containing water electrolyzed through the step (C) into the inlet through the jet port 1601 and simultaneously heating the same through the evaporation chamber 1610 to generate steam (S240);
    (E) 상기 증발챔버(1610)에서 가열된 증기를 이동덕트(1615)를 통해 공급받아 증기 터빈 발전기(1620)를 발전시키는 단계(S250); 및(E) receiving steam heated in the evaporation chamber 1610 through a moving duct 1615 to generate a steam turbine generator 1620 (S250); And
    (F) 상기 (D) 단계에서 상기 증발챔버(1610)를 통해 가열되어 농축된 가성소다를 배수구(1603)를 통해 수집하고, 상기 (E) 단계에서 상기 증기 터빈 발전기(1620)를 발전시키고 남은 수증기를 액화시켜 담수로 사용하는 단계(S260)를 포함하는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법.(F) collecting the concentrated caustic soda heated through the evaporation chamber 1610 through the drainage port 1603 in step (D), and generating and remaining the steam turbine generator 1620 in step (E). Method of separating seawater into caustic soda and fresh water using the green energy, characterized in that it comprises the step of liquefying water vapor to use as fresh water (S260).
  11. 제 10항에 있어서,The method of claim 10,
    (C1) 상기 (C) 단계에서는 상기 수로(120)를 따라 해수가 흐르는 중에 유수력 발전부(1520)를 통해 자체적으로 교류 전력을 생산한 후 컨버터(1525)를 통해 직류로 변환하여 전원공급부(140)에 공급하는 단계(S235)를 더 포함하는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법.In the step (C), while the seawater flows along the waterway 120, AC power is produced through the hydroelectric power generation unit 1520, and then converted into direct current through the converter 1525, thereby supplying power. 140) using the green energy characterized in that it further comprises the step of supplying (S235) method for separating seawater into caustic soda and fresh water.
  12. 제 10항에 있어서,The method of claim 10,
    상기 (D) 단계에서 상기 증발챔버(1610)를 통해 가성소다 포함수를 가열하여 증기를 발생시키는 과정은,In the step (D), the process of generating steam by heating caustic soda-containing water through the evaporation chamber 1610,
    (D1) 히터(1612)가 상부로부터 분사되는 가성소다 포함수를 가열하는 단계(S242);(D1) heating the caustic soda-containing water injected from the top by the heater 1612 (S242);
    (D2) 상기 (D1) 단계를 통해 가열된 가성소다 포함수가 증발챔버(1610)의 측면에 고이면 초음파 발생부(1614)가 초음파를 발생시키는 단계(S244); 및(D2) when the caustic soda-containing water heated through the step (D1) is accumulated on the side of the evaporation chamber 1610, the ultrasonic generator 1614 generates ultrasonic waves (S244); And
    (D3) 상기 히터(1612)와 초음파 발생부(1614)를 통해 분사되는 수분입자를 마그네트론(1616)이 순간적으로 가열하여 수증기를 폭발적으로 증대시키는 단계(S246)를 포함하는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법.(D3) Green energy, characterized in that the magnetron 1616 instantaneously heating the water particles sprayed through the heater 1612 and the ultrasonic generator 1614 to explosively increase the water vapor (S246). How to separate seawater into caustic soda and fresh water.
  13. 제 12항에 있어서,The method of claim 12,
    상기 히터(1612), 초음파 발생부(1614) 및 마그네트론(1620)은 증기 터빈 발전기(1620)를 통해 자체적으로 발전된 전기로 가동되는 것을 특징으로 하는 그린에너지를 이용하여 해수를 가성소다와 담수로 분리하는 방법.The heater 1612, the ultrasonic generator 1614, and the magnetron 1620 are separated from caustic soda and fresh water using green energy, which is operated by electricity generated by itself through a steam turbine generator 1620. How to.
PCT/KR2009/007581 2009-08-07 2009-12-18 Method and apparatus for separating seawater into caustic soda and fresh water by using green energy WO2011016606A1 (en)

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