WO2010089877A1 - Procédé de production d'eau minérale potable, appareil pour la production d'eau minérale potable, et eau potable obtenue grâce à ce procédé - Google Patents

Procédé de production d'eau minérale potable, appareil pour la production d'eau minérale potable, et eau potable obtenue grâce à ce procédé Download PDF

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Publication number
WO2010089877A1
WO2010089877A1 PCT/JP2009/052049 JP2009052049W WO2010089877A1 WO 2010089877 A1 WO2010089877 A1 WO 2010089877A1 JP 2009052049 W JP2009052049 W JP 2009052049W WO 2010089877 A1 WO2010089877 A1 WO 2010089877A1
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Prior art keywords
mineral
water
drinking water
producing
boron
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PCT/JP2009/052049
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English (en)
Japanese (ja)
Inventor
三久馬 溝元
聡 松林
朝雄 中山
恵 鈴木
敏 松田
光司 中川
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赤穂化成株式会社
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Priority to PCT/JP2009/052049 priority Critical patent/WO2010089877A1/fr
Publication of WO2010089877A1 publication Critical patent/WO2010089877A1/fr

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025Reverse osmosis; Hyperfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/04Specific process operations in the feed stream; Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/06Specific process operations in the permeate stream
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

Definitions

  • the present invention relates to a method and apparatus for producing mineral drinking water that contributes to safety, security, and prevention of global warming, and the obtained mineral drinking water.
  • Bovine spongiform encephalopathy BSE
  • BSE Bovine spongiform encephalopathy
  • Mineral drinking water containing minerals and water which is the basis for human life, is one of the foods that require the most safe, secure, and health-improving effects, and to ensure food safety Mineral drinking water that has been managed in raw water and manufactured and packaged in various materials and forms is transported around the world.
  • the world's annual consumption of mineral water is 98.81 million kiloliters in 2000 when water scarcity was a concern. Since 2000, it has grown at an annual rate of 6% to 11%, and the annual consumption in 2005 has been 164 million kiloliters. Since 2003, it has exceeded the world consumption of beer and is the most used in various parts of the world. Has become one of the drinks that have been.
  • Non-patent Document 1 the annual consumption of mineral drinking water in 2008 is predicted to be 201 million kiloliters.
  • Non-patent Document 1 a large amount of packaging material is used in correlation with the annual consumption of mineral drinking water, and transport from the production area to the consumption area A large amount of energy is consumed, and there are concerns about adverse environmental impacts.
  • boron is rarely contained in natural water, but it may be contained in the form of metaboric acid in groundwater and hot spring water in volcanic areas, and metal surface treatment agents, Because it is used in glass and enamel industries, it may be mixed with natural water from factory wastewater. Boron has common toxicity in male reproductive organs as a result of exposure to boric acid or borax in laboratory animals, so there is a standard for tap water used for daily drinking. L and EU standards are 1 mg / L.
  • Patent Document 1 There has been proposed a groundwater purification method for easily removing contaminants from groundwater contaminated with boron at low cost (Patent Document 1).
  • a groundwater purification layer having a boron removal component is provided in the ground to purify the groundwater.
  • a large-scale construction is involved and the economy is poor. Costs also increase.
  • the groundwater after purification is pumped up, it may be contaminated after that, which causes a safety problem.
  • the water treatment means includes means for ion exchange of water, means for adding vitamins or minerals, means for adjusting the pH of water, and means for sealing the treated water in a cylindrical container.
  • a vending machine Patent Document 2
  • the device since the device includes a sealing means for sealing purified water in a container, the device must be a complicated device.
  • Patent Document 3 On the other hand, from the viewpoint of adjusting the mineral concentration, there is a drinking water production apparatus (Patent Document 3) for a mineral aqueous solution containing a calcium compound or a magnesium compound that is always immersed in water in an aqueous solution tank.
  • the mineral aqueous solution concentration is unstable. Therefore, complicated control for the adjustment is necessary, and even if a plurality of mineral aqueous solution tanks are provided and the concentration of the mineral aqueous solution is adjusted, the structure becomes complicated and the apparatus becomes expensive.
  • the hardness affects umami and ease of drinking, and preferably has an EDTA hardness of 100 to 3,000.
  • the content of the main minerals and essential trace minerals of calcium and calcium is extremely low, and if it exceeds 3,000, the taste becomes hard and difficult to drink.
  • enormous energy is required to deliver mineral drinking water that is safe, safe to drink, rich in taste, and contributes to health such as mineral supplementation to users.
  • Patent Document 5 After passing tap water, well water or spring water through a filter made of polypropylene or polyester fiber material, it is passed through an adsorption filter made of two activated carbon or carbon fiber materials having different water passage diameters, and a reverse osmosis membrane is further formed.
  • Patent Document 5 After passing through and removing suspended substances and dissolved chemical substances in the raw water for beverages, the purification system for beverages (Patent Document 5) that passes through the elution layer crushed and filled with various mineral-containing ores, tap water, A mineral water automatic vending device (Patent Document 6) is known that passes through a treatment filter, passes through a reverse osmosis membrane, and then stores and sells in a water storage tank filled with a mineral elution material.
  • This invention makes it a subject to provide the method and apparatus which manufactures the mineral drinking water which is safe and reliable, and improves the quality of life by energy saving.
  • Another object of the present invention is to provide a mineral drinking water that is safe and secure in terms of health, has a good taste, and can sufficiently supply minerals.
  • the inventors of the present invention have intensively studied to solve the above problems, and as a result, have completed the invention having the following configuration.
  • the invention of claim 1 is a primary treatment step using a filter capable of selecting raw water according to turbidity components, a secondary treatment step of removing residual chlorine or organic substances with an activated carbon filter, and adsorbing boron with an ion exchange resin. It consists of a next treatment step, a step of treating the water pressurized by the pressure pump with a reverse osmosis membrane, a step of adding a mineral concentrate via a water injection pump, and a step of treating the water added with the mineral concentrate with a microfiltration membrane.
  • a method for producing mineral drinking water characterized by the above.
  • the invention of claim 2 is a method for producing the mineral drinking water according to claim 1, characterized in that the boron concentration of the mineral concentrate is less than 10 mg / L.
  • the invention of claim 3 is a method for producing a mineral drinking water according to any one of claims 1 to 2, characterized in that the raw material of the mineral concentrate is deep sea water.
  • the invention of claim 4 is a method for producing a mineral drinking water according to any one of claims 1 to 3, wherein the ratio of magnesium (Mg) to calcium (Ca) (Mg / Ca) is 4/1. To 1/3.
  • a fifth aspect of the present invention is a method for producing a mineral drinking water according to any one of the first to fourth aspects, wherein the calcium carbonate hardness is 100 mg / L to 3,000 mg / L.
  • the invention of claim 6 is a mineral drinking water obtained by the method for producing a mineral drinking water according to any one of claims 1 to 5.
  • the invention according to claim 7 is characterized in that the mineral drinking water obtained from the method for producing mineral drinking water according to claim 6 has a boron concentration of less than 0.1 mg / L.
  • the mineral drinking water producing apparatus is a filter for selecting raw water based on turbidity components, an activated carbon filter for removing residual chlorine and organic substances, an ion exchange resin for adsorbing boron, and a pressure boosting pump.
  • the present invention can provide mineral drinking water that is safe and secure and improves not only the quality of life but also contributes to the prevention of global warming. Since it is a method of transporting and adding mineral concentrate to the raw water of the consumption area, compared to the conventional method of transporting mineral drinking water packed and packed in containers at the production area to the consumption area, the transport weight is much less, and the packaging material Less. In addition, containers filled with mineral drinking water prepared by mineral water production equipment installed in the consumption area are reused containers brought by consumers, reducing consumers' consumption and preventing consumers from global warming. It also increased awareness. Moreover, since the mineral concentrate with stable quality produced in the production area is added to the water obtained by treating the raw water in the consumption area in a form that is almost pure, it was possible to provide mineral drinking water with stable quality.
  • (1) is a filter for primary treatment of raw water, which is selected according to the turbidity component of the raw water, and a ceramic membrane, a hollow fiber membrane or the like is preferably used. In order to surely remove the turbidity component of the raw water, it is preferable to use a material that can be separated by ultrafiltration or ultrafiltration that can separate substances of about 0.1 ⁇ m or more.
  • (2) is a filter for secondary treatment of primary treated water, and is an activated carbon filter made of coconut shell, phenol resin, charcoal or the like that adsorbs residual chlorine and organic matter as raw materials.
  • (3) is an ion exchange resin that adsorbs boron, and thirdarily treats water that has been secondarily treated.
  • (4) is a booster pump, and treated water is passed through a filter (5) made of a reverse osmosis membrane.
  • (6) is a water injection pump. After the treated water has passed through the filter (5) tank made of a reverse osmosis membrane, the mineral concentrate produced in the production area is appropriately supplied.
  • (7) is a filter immediately before being filled into a container, and is a final check filter for reliably preventing contamination of microorganisms and the like, and is constituted by a microfiltration membrane.
  • the raw water is first filtered with a filter (1) to remove turbidity components and then passed to the filter (2) to remove residual chlorine and organic matter.
  • the filter (3) when the raw water contains boron, it is adsorbed by the filter (3).
  • the treated water is boosted by the booster pump (4), the ions in the raw water are removed by the reverse osmosis membrane of the filter (5), and the separated impurities are discharged as concentrated water.
  • the mineral concentrate is added and mixed with the treated water via the infusion pump (6), and the hardness of the mineral drinking water to be produced is arbitrarily adjusted by changing the amount of the mineral concentrate added. Can do.
  • the mineral drinking water prepared in this way is supplied as a mineral drinking water product after passing through a final check filter (7) for preventing contamination of microorganisms and the like.
  • the raw water contains boron
  • the boron contained in the final mineral drinking water is less than 0.1 mg / L, which makes consumers feel safe and secure.
  • the raw material of the mineral concentrate is not particularly limited, but seawater that contains many kinds of minerals, has a high concentration, is widely distributed throughout the world, and is relatively easily available is preferable. Furthermore, from the viewpoint of food safety, deep sea water with very few radioactive substances, dioxins and viable bacteria is more preferable.
  • Minerals are the basis for human beings to live, and it is desirable to appropriately take a variety of minerals. Furthermore, the three functions expected for food (nutrition, taste, and physical condition adjustment) were confirmed, and the ratio of magnesium (Mg) to Mg (Ca) (Mg / Ca) was changed from 4/1 to 1 / 3. It is desirable that the calcium carbonate hardness is 100 mg / L to 3,000 mg / L. Next, embodiments of the present invention will be specifically described based on examples, but the present invention is not limited to these.
  • the mineral concentrate of Example 1 was filled into a 10 L BIB container (bag in box). The weight of the container was 586 g. Further, 10 L of the mineral concentrate of Example 1 was diluted with ion-exchanged water, 600 L of mineral water having a hardness of 1000 was produced, filled in a 2 L PET container, and then packaged six by 6 in a cardboard container. The weight of the container was 37,300 g. Comparing the liquid capacity and container weight of mineral concentrate and mineral water with a hardness of 1000, the mineral concentrate is 590L in liquid capacity and about 36,000g in container weight, and is transported from the production area to the consumption area. In this case, it becomes energy saving.
  • Deep sea water was treated with a reverse osmosis membrane treatment device and a heating and concentration device to obtain a mineral concentrate 1 excluding sodium chloride and potassium chloride.
  • a mineral concentrate 1 excluding sodium chloride and potassium chloride.
  • the mineral concentrate 1 was analyzed by a conventional method, it was 30 g / L magnesium and 91 mg / L boron.
  • the mineral concentrate 1 was treated with a boron selective anti-exchange resin to obtain a mineral concentrate 2 containing 30 g / L magnesium and 9 mg / L boron.
  • the mineral concentrate 2 was retreated with a boron selective ion exchange resin to obtain a mineral concentrate 3 containing 30 g / L magnesium and 0.1 mg / L boron.
  • the mineral concentrate 3 obtained in Example 3 was diluted 10-fold with raw water 1 of magnesium 5 mg / L, calcium 65 mg / L, and boron 0.1 mg / L, and magnesium 3,004 mg / L, calcium 58 mg / L, boron A mineral concentrate 4 of less than 0.1 mg / L was obtained.
  • the mineral concentrate 3 obtained in Example 3 was diluted 10-fold with raw water 2 of magnesium 3 mg / L, calcium 15 mg / L, boron 0.1 mg / L, magnesium 3,003 mg / L, calcium 14 mg / L, boron A mineral concentrate 5 of less than 0.1 mg / L was obtained.

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  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

La présente invention a pour objet un procédé de production d'une eau minérale potable qui ne présente pas de danger pour la santé et qui peut être bue sans anxiété. Le procédé comprend une étape de traitement primaire consistant à traiter une eau brute avec un filtre qui peut être choisi en fonction des composants de turbidité de l'eau brute, une étape de traitement secondaire consistant à éliminer le chlore résiduel ou la matière organique à travers un filtre au charbon actif, une étape de traitement tertiaire consistant à adsorber le bore sur une résine échangeuse d'ions, une étape de traitement de l'eau, dont la pression a été élevée par une pompe d'élévation de la pression, au moyen d'une membrane d'osmose inverse, une étape consistant à ajouter un liquide minéral concentré par une pompe d'injection d'eau, et une étape consistant à traiter l'eau, à laquelle le liquide minéral concentré a été ajouté, au moyen d'une membrane de microfiltration.
PCT/JP2009/052049 2009-02-06 2009-02-06 Procédé de production d'eau minérale potable, appareil pour la production d'eau minérale potable, et eau potable obtenue grâce à ce procédé WO2010089877A1 (fr)

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PCT/JP2009/052049 WO2010089877A1 (fr) 2009-02-06 2009-02-06 Procédé de production d'eau minérale potable, appareil pour la production d'eau minérale potable, et eau potable obtenue grâce à ce procédé

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PCT/JP2009/052049 WO2010089877A1 (fr) 2009-02-06 2009-02-06 Procédé de production d'eau minérale potable, appareil pour la production d'eau minérale potable, et eau potable obtenue grâce à ce procédé

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464421A (zh) * 2010-11-18 2012-05-23 李复兴 一种安全健康饮用水设备
CN103539288A (zh) * 2013-10-31 2014-01-29 神华集团有限责任公司 工业废水的回收方法及废水回收系统
CN105217874A (zh) * 2015-10-21 2016-01-06 李喜文 一种纳米活性矿透高机能水的制备方法
CN110482735A (zh) * 2019-07-18 2019-11-22 四川陆和兴硅素科技有限公司 硅素水混合生产装置
CN111225881A (zh) * 2017-08-28 2020-06-02 Mva参与咨询有限公司 用于对水进行净化和理化调节的系统
RU2778684C2 (ru) * 2017-08-28 2022-08-23 Мва Партисипасоеш Энд Консультория Лтда. Система очистки и регулирования физико-химического состава воды и применение полученной воды

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JP2006192422A (ja) * 2004-12-17 2006-07-27 Miura Dsw Kk 水中のホウ素含有量を低減させて飲用に適した水を製造する方法
JP2007117979A (ja) * 2005-10-26 2007-05-17 Yoshiomi Morita 製水機
JP2008086989A (ja) * 2006-06-28 2008-04-17 Sanyo Electric Co Ltd 水供給装置

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Publication number Priority date Publication date Assignee Title
JPH0889956A (ja) * 1994-09-20 1996-04-09 Daikin Ind Ltd 超純水製造装置
JPH1015356A (ja) * 1996-07-09 1998-01-20 Kubota Corp 水処理方法
JP2002509802A (ja) * 1998-03-31 2002-04-02 ユナイテッド・ステイツ・フィルター・コーポレイション 水処理システム及びpH調節を含む水処理法
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464421A (zh) * 2010-11-18 2012-05-23 李复兴 一种安全健康饮用水设备
CN103539288A (zh) * 2013-10-31 2014-01-29 神华集团有限责任公司 工业废水的回收方法及废水回收系统
CN105217874A (zh) * 2015-10-21 2016-01-06 李喜文 一种纳米活性矿透高机能水的制备方法
CN105217874B (zh) * 2015-10-21 2017-11-21 李喜文 一种纳米活性矿透高机能水的制备方法
CN111225881A (zh) * 2017-08-28 2020-06-02 Mva参与咨询有限公司 用于对水进行净化和理化调节的系统
EP3677553A4 (fr) * 2017-08-28 2021-05-05 MVA Participações & Consultoria Ltda. Système de purification et d'ajustement physico-chimique de l'eau
RU2778684C2 (ru) * 2017-08-28 2022-08-23 Мва Партисипасоеш Энд Консультория Лтда. Система очистки и регулирования физико-химического состава воды и применение полученной воды
CN110482735A (zh) * 2019-07-18 2019-11-22 四川陆和兴硅素科技有限公司 硅素水混合生产装置

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