WO2010085028A1 - Copolymère à base de poly(oxyde de phényle), procédé de préparation du copolymère, membrane électrolyte polymère comprenant le copolymère et pile à combustible comprenant la membrane électrolyte polymère - Google Patents
Copolymère à base de poly(oxyde de phényle), procédé de préparation du copolymère, membrane électrolyte polymère comprenant le copolymère et pile à combustible comprenant la membrane électrolyte polymère Download PDFInfo
- Publication number
- WO2010085028A1 WO2010085028A1 PCT/KR2009/003846 KR2009003846W WO2010085028A1 WO 2010085028 A1 WO2010085028 A1 WO 2010085028A1 KR 2009003846 W KR2009003846 W KR 2009003846W WO 2010085028 A1 WO2010085028 A1 WO 2010085028A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- formula
- polyphenylether
- polymer electrolyte
- electrolyte membrane
- copolymer
- Prior art date
Links
- 229920013636 polyphenyl ether polymer Polymers 0.000 title claims abstract description 56
- 229920001577 copolymer Polymers 0.000 title claims abstract description 49
- 239000012528 membrane Substances 0.000 title claims description 81
- 239000005518 polymer electrolyte Substances 0.000 title claims description 60
- 239000000446 fuel Substances 0.000 title claims description 46
- 238000000034 method Methods 0.000 title claims description 27
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 93
- 150000001875 compounds Chemical class 0.000 claims description 21
- 230000035699 permeability Effects 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 14
- 150000002431 hydrogen Chemical class 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 6
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims description 6
- 125000006835 (C6-C20) arylene group Chemical group 0.000 claims description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052744 lithium Inorganic materials 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- 239000003054 catalyst Substances 0.000 description 16
- 239000003792 electrolyte Substances 0.000 description 16
- 125000003118 aryl group Chemical group 0.000 description 13
- 238000009792 diffusion process Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 125000000542 sulfonic acid group Chemical group 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 9
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 8
- 229910052794 bromium Inorganic materials 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- -1 sulfonate anions Chemical class 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 0 C*(*c1c2*)c1c(*)c(*)c2OC(C)(C)c(c(C)c1C)c(*)c(I*)c1OC Chemical compound C*(*c1c2*)c1c(*)c(*)c2OC(C)(C)c(c(C)c1C)c(*)c(I*)c1OC 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N DMSO Substances CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 108090000862 Ion Channels Proteins 0.000 description 3
- 102000004310 Ion Channels Human genes 0.000 description 3
- 229920000557 Nafion® Polymers 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- IPZJQDSFZGZEOY-UHFFFAOYSA-N dimethylmethylene Chemical compound C[C]C IPZJQDSFZGZEOY-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229920002313 fluoropolymer Polymers 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- NPDACUSDTOMAMK-UHFFFAOYSA-N 4-Chlorotoluene Chemical compound CC1=CC=C(Cl)C=C1 NPDACUSDTOMAMK-UHFFFAOYSA-N 0.000 description 2
- 125000006416 CBr Chemical group BrC* 0.000 description 2
- 229910000820 Os alloy Inorganic materials 0.000 description 2
- 229910001252 Pd alloy Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000006230 acetylene black Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 2
- 239000002828 fuel tank Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000001072 heteroaryl group Chemical group 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- IYZXTLXQZSXOOV-UHFFFAOYSA-N osmium platinum Chemical compound [Os].[Pt] IYZXTLXQZSXOOV-UHFFFAOYSA-N 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- ATGFTMUSEPZNJD-UHFFFAOYSA-N 2,6-diphenylphenol Chemical compound OC1=C(C=2C=CC=CC=2)C=CC=C1C1=CC=CC=C1 ATGFTMUSEPZNJD-UHFFFAOYSA-N 0.000 description 1
- 229920003934 Aciplex® Polymers 0.000 description 1
- OPDYDMMIJFNDPY-UHFFFAOYSA-N CC(CCC=C1C)=C1O Chemical compound CC(CCC=C1C)=C1O OPDYDMMIJFNDPY-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 229920003935 Flemion® Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910000929 Ru alloy Inorganic materials 0.000 description 1
- CLBRCZAHAHECKY-UHFFFAOYSA-N [Co].[Pt] Chemical compound [Co].[Pt] CLBRCZAHAHECKY-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 125000005549 heteroarylene group Chemical group 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- PCLURTMBFDTLSK-UHFFFAOYSA-N nickel platinum Chemical compound [Ni].[Pt] PCLURTMBFDTLSK-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- CFQCIHVMOFOCGH-UHFFFAOYSA-N platinum ruthenium Chemical compound [Ru].[Pt] CFQCIHVMOFOCGH-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/44—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols by oxidation of phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
- C08G65/485—Polyphenylene oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
- H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/05—Polymer mixtures characterised by other features containing polymer components which can react with one another
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a polyphenylether-based copolymer, a method of preparing the copolymer, a polymer electrolyte membrane including the copolymer, and a fuel cell including the polymer electrolyte membrane. More particularly, the present invention relates to a polyphenylether-based copolymer having a novel structure, a method of preparing the copolymer, a polymer electrolyte membrane including the copolymer, and a fuel cell including the polymer electrolyte membrane.
- Fuel cells can be classified, according to the type of electrolyte used, as polymer electrolyte membrane fuel cells (PEMFC), phosphoric acid fuel cells (PAFC), molten carbonate fuel cells (MCFC), solid oxide fuel cells (SOFC), and the like.
- PEMFC polymer electrolyte membrane fuel cells
- PAFC phosphoric acid fuel cells
- MCFC molten carbonate fuel cells
- SOFC solid oxide fuel cells
- fuel cells have different operating temperatures and use different materials for their components according to the type of the electrolyte.
- PEMFCs have a higher output power, a lower operating temperature, and faster response characteristics than other types of fuel cells.
- Fuel cells can also be classified, according to a method of supplying fuel to an anode, as direct fuel feeding type or internal reforming type fuel cells.
- a representative example of the direct fuel feeding type is a direct methanol fuel cell (DMFC).
- DMFCs use a polymer electrolyte membrane as an electrolyte, and thus are classified as PEMFCs.
- DMFCs use methanol as a fuel and do not require a hydrogen reformer.
- DMFCs operate at a low temperature and have a simple, compact structure. Thus, DMFCs are suitable as a power source for small devices and portable devices.
- a fuel cell includes a power generator, a reformer, a fuel tank, a fuel pump, and the like.
- the power generator forms the body of the fuel cell, and the fuel pump supplies fuel contained in the fuel tank to the reformer. Hydrogen gas is generated by the reformer and supplied to the energy generator as a fuel by the fuel pump to generate electrical energy through electrochemical reactions.
- the power generator may include a membrane-electrode assembly (MEA), which includes an anode, a cathode, and a polymer electrolyte membrane.
- MEA membrane-electrode assembly
- a functional proton exchange membrane having a cation exchange capability is used as the electrolyte membrane for PEMFCs.
- proton exchange membranes including a sulfonic acid group are is used because the sulfonic acid group has a very high acidity and has C-S bonds that are stable in oxidation conditions.
- water molecules should be present.
- the sulfonic acid group in the electrolyte membrane dissociates into sulfonate anions and protons in the presence of water molecules.
- the protons migrate due to a proton concentration gradient or an electric field.
- the proton conductivity varies according to the number of sulfonic acid groups in the polymer electrolyte membrane, the structure of the polymer electrolyte membrane, the content of water in the polymer electrolyte membrane, and the like.
- electrolyte membranes for PEMFCs include fluorinated polymer electrolyte membranes, such as NAFION membranes, ACIPLEX membranes, FLEMION membranes, and DOW membranes. These fluorinated polymer electrolyte membranes have a lower proton conductivity at a temperature of 100 °C or higher and a high fuel permeability, and are expensive. In addition, the fluorinated polymer electrolyte membranes have a high proton conductivity but have a high permeability to fuel (for example, methanol). Thus, it is difficult to ensure both a high ionic conductivity and a low fuel permeability, which are the requirements for fuel cells.
- fuel for example, methanol
- the present invention provides a polyphenylether-based copolymer having a novel structure.
- the present invention also provides a method of preparing the polyphenylether-based copolymer.
- the present invention also provides a polymer electrolyte membrane including the polyphenylether-based copolymer.
- the present invention also provides a fuel cell including the polymer electrolyte membrane.
- a polyphenylether-based copolymer including a repeating unit represented by Formula 1a and a repeating unit represented by Formula 1b:
- M 1 , M 2 and M 3 are each independently hydrogen, lithium, sodium, or potassium;
- Ar 1 and Ar 2 are each independently a C6-C20 arylene group or a C2-C20 heteroarylene group;
- R 1 , R 2 , R 3 and R 4 are each independently hydrogen, a C1-C20 alkyl group, a C6-C20 aryl group, or a C2-C20 heteroaryl group;
- X is a halogen atom
- a method of preparing a polyphenylether-based copolymer represented by Formula 1 including: preparing a compound represented by Formula 6 by reacting a compound represented by Formula 4 and a compound represented by Formula 5; preparing a compound represented by Formula 7 by reacting the compound represented by Formula 6 with halogen; and preparing the compound represented by Formula 1 by sulfonating the compound represented by Formula 7:
- M 1 , M 2 and M 3 are each independently hydrogen, lithium, sodium, or potassium;
- Ar 1 and Ar 2 are each independently a C6-C20 arylene group or a C2-C20 heteroarylene group;
- R 1 , R 2 , R 3 and R 4 are each independently hydrogen, a C1-C20 alkyl group, a C6-C20 aryl group, or a C2-C20 heteroaryl group;
- X is a halogen atom
- a polymer electrolyte membrane including the polyphenylether-based copolymer.
- a fuel cell employing the polymer electrolyte membrane.
- a polymer electrolyte membrane having a high proton conductivity and a low fuel permeability can be manufactured relatively inexpensively.
- FIG. 1 is a schematic view of a direct methanol fuel cell (DMFC) according to an embodiment of invention.
- the present invention provides a polyphenylether-based copolymer including a repeating unit represented by Formula 1a and a repeating unit represented by Formula 1b:
- M 1 , M 2 and M 3 are each independently hydrogen, lithium, sodium, or potassium;
- Ar 1 and Ar 2 are each independently a C6-C20 arylene group or a C2-C20 heteroarylene group;
- R 1 , R 2 , R 3 and R 4 are each independently hydrogen, a C1-C20 alkyl group, a C6-C20 aryl group, or a C2-C20 heteroaryl group;
- the arylene group is a divalent cyclic aromatic system including at least two rings, which can be attached to each other or fused with each other.
- the heteroarylene group indicates an aryl group, wherein at least one carbon atom of the aryl group is substituted with at least one selected from the group consisting of N, O, S and P.
- the aryl group is a monovalent group corresponding to the arylene group
- the heteroaryl group is a monovalent group corresponding to the heteroaryl group.
- a sulfonic acid group of Formula 1b which is separated from a backbone and linked to a side chain moves relatively freely.
- a sulfonic acid group of Formula 1b may form micelles like a surfactant in the copolymer and may function as ionic channels.
- the size of ionic channels can also be controlled by adjusting the length of the side chain. Therefore, the polyphenylether-based copolymer can easily adjust the amount of water in the ionic channels, and can have high proton conductivity.
- the copolymer additionally includes a hydrophobic halogen atom in addition to benzene rings in its backbones, and permeation of methanol can be suppressed due to the hydrophobic backbones, and water uptake ratio is low. Also, thermal stability and oxidation/reduction reaction stability of the polyphenylether-based copolymer is high.
- a sulfonic acid group is directly connected to backbones only. Accordingly, if the amount of a sulfonic acid group is high in a polymer, the polymer itself dissolves in water and thus, an electrolyte membrane may lose its function. Thus, the amount of a sulfonic acid group is limited. Therefore, high proton conductivity cannot be obtained. Also, since a sulfonic acid group is connected directly to backbones, methanol may easily pass through backbones.
- the polyphenylether-based copolymer may include a repeating unit represented by Formula 2a and a repeating unit represented by Formula 2b:
- the polyphenylether-based copolymer may include a repeating unit represented by Formula 3a and a repeating unit represented by Formula 3b:
- the ratio of m:n in the polyphenylether-based copolymers described above may be in a range of 1:9 to 9:1.
- the polyphenylether-based copolymers may have a weight average molecular weight of 10,000 to 200,000, specifically 30,000 to 150,000.
- the present invention also provides a method of preparing a polyphenylether-based copolymer represented by Formula 1 below, the method including: preparing a compound represented by Formula 6 by reacting a compound represented by Formula 4 and a compound represented by Formula 5; preparing a compound represented by Formula 7 by reacting the compound represented by Formula 6 with a halogen; and preparing the compound represented by Formula 1 by sulfonating the compound represented by Formula 7:
- M 1 , M 2 and M 3 are each independently hydrogen, lithium, sodium, or potassium;
- Ar 1 and Ar 2 are each independently a C6-C20 arylene group or a C2-C20 heteroarylene group;
- R 1 , R 2 , R 3 and R 4 are each independently hydrogen, a C1-C20 alkyl group, a C6-C20 aryl group, or a C2-C20 heteroaryl group;
- the present invention also provides a polymer electrolyte membrane including the polyphenylether-based copolymer. Since the polymer electrolyte membrane includes any one of the sulfone-based copolymers represented by Formulae 1 through 3, the methanol permeability is low, and the proton conductivity is high. In addition, the water uptake ratio is high.
- the polymer electrolyte membrane may have, at 100% relative humidity and a temperature of 25 °C , a proton conductivity of 1 ⁇ 10 -3 S/cm or higher, specifically, 8 ⁇ 10 -3 S/cm or higher, or more specifically in a range of 10 ⁇ 10 -3 S/cm to 200 ⁇ 10 -3 S/cm.
- the polymer electrolyte membrane may have, at 100% relative humidity and a temperature of 25 °C , a methanol permeability of 20 ⁇ 10 -7 cm 2 /s or less, specifically, 5.9 ⁇ 10 -7 cm 2 /s or less, or more specifically in a range of 4 ⁇ 10 -7 cm 2 /s to 0.01 ⁇ 10 -7 cm 2 /s.
- the polymer electrolyte membrane may have a proton conductivity of 1 ⁇ 10 -3 S/cm or higher and a methanol permeability of 5 ⁇ 10 -7 cm 2 /S or less, or specifically, a proton conductivity of 10 ⁇ 10 -3 S/cm to 200 ⁇ 10 -3 S/cm and a methanol permeability of 4 ⁇ 10 -7 cm 2 /s to 0.01 ⁇ 10 -7 cm 2 /s .
- the present invention also provides a fuel cell including the polymer electrolyte membrane.
- the fuel cell includes a cathode and an anode, wherein the polymer electrolyte membrane is interposed between the cathode and the anode.
- Each of the cathode and the anode includes a gas diffusion layer and a catalyst layer.
- the catalyst layer includes a metal catalyst that facilitates oxidation of hydrogen and reduction of oxygen.
- the catalyst layer may include at least one catalyst selected from the group consisting of platinum, ruthenium, osmium, a platinum-osmium alloy, a platinum-palladium alloy, and a platinum-M alloy where M is Ga, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, or Zn.
- the catalyst layer may include platinum, ruthenium, osmium, a platinum-ruthenium alloy, a platinum-osmium alloy, a platinum-palladium alloy, a platinum-cobalt alloy, a platinum-nickel alloy, or a mixture of these alloys.
- the metal catalyst is used while being supported on a support.
- the support can be a carbonaceous material, such as acetylene black or graphite, or inorganic micro-particles formed of alumina, silica, or the like.
- the gas diffusion layer carbon paper or carbon cloth may be used, but the present invention is not limited thereto.
- the gas diffusion layers function to support the cathode and anode, and also diffuse reactant gases into the catalyst layers, so that the reactant gases can easily reach the catalyst layers.
- the gas diffusion layers may be formed by treating a carbon paper or carbon cloth with a fluorine-based resin, such as polytetrafluoroethylene, to be water-repellent
- the carbon paper or carbon cloth treated to be water-repellent can prevent a reduction in gas diffusion efficiency due to water that is generated as the fuel cell operates.
- the cathode and anode may respectively further include a micro-porous layer between the gas diffusion layer and the catalyst layer, to further enhance the gas diffusion effect of the gas diffusion layer.
- the micro-porous layer may be formed by applying a composition containing a conductive material, such as carbon powder, carbon black, activated carbon, acetylene black, or the like, a binder such as polytetrafluoroethylene, and an ionomer if necessary, between the gas diffusion layer and the catalyst layer.
- the fuel cell may be a direct methanol fuel cell (DMFC).
- FIG. 1 is a schematic view of a DMFC.
- the DMFC includes an anode 34 to which fuel is supplied, a cathode 30 to which an oxidant is supplied, and an electrolyte membrane 41 which is disposed between the anode 34 and the cathode 30.
- the anode 34 includes an anode diffusion layer 22 and an anode catalyst layer 33.
- the cathode 30 includes a cathode diffusion layer 32 and a cathode catalyst layer 31.
- An aqueous solution of methanol is transferred to the anode catalyst layer 33, through the anode diffusion layer 22, and then is decomposed into electrons, protons, carbon dioxide, and the like.
- the protons are transferred to the cathode catalyst layer 31 through the electrolyte membrane 41, the electrons are transferred to an external circuit, and carbon dioxide is discharged to the outside.
- a condenser was mounted on a 500 mL, 3-necked flask, and 12.25 g of 2,6-dimethylphenol, 2.745 g of 2,6-diphenylphenol, 0.15 g of CuCl(I) and 50 mL of pyridine were dissolved in 400 mL of 4-chlorotoluene in the flask.
- the mixture solution was reacted at room temperature for 18 hours in an oxygen bubbling condition to obtain a polymer.
- the color of the reaction solution changed from bright yellow to dark brown during the reaction.
- the polymer solution was precipitated in 2L of methanol to obtain a solid.
- a condenser was mounted on a 100 mL, 3-necked flask, and 5g of polyphenylether prepared in Step 1 was dissolved in 5 g of chloroform in the flask.
- a mixed solution of 1 mL of chloroform and 1 mL of bromine was placed into a dropping funnel and slowly dropwise added into the solution. Then, the mixed solution was reacted at room temperature for 1 hour. After the reaction was complete, the reaction solution was precipitated in 800 mL of methanol to obtain a solid.
- a condenser was mounted on a 500mL, 3-necked flask, and 5g of polyphenylether bromated in Step 2 was dissolved in 250 g of chloroform in the flask.
- a mixed solution of 60 mL of chloroform and 9 mL of chlorosulfonic acid was placed into a dropping funnel and slowly dropwise added into the solution. Then, the mixed solution was reacted at room temperature for 1 hour while stirring. After the reaction was complete, the reaction solution was precipitated in 2 L of a methanol solution diluted with water in a ratio of 5:5 to obtain a solid. Next, the solid was washed several times with methanol and distilled water until the pH reached 7, thereby resulting in a product represented by Formula 8 below.
- a polyphenylether copolymer was prepared in the same method as in Example 1, except that the amount of bromine added in Step 2 of Example 1 was varied to 0.4 mol based on 1 mol of polyphenylether.
- a polyphenylether copolymer was prepared in the same method as in Example 1, except that the amount of bromine added in Step 2 of Example 1 was varied to 0.6mol based on 1 mol of polyphenylether.
- a polyphenylether copolymer was prepared in the same method as in Example 1, except that the amount of bromine added in Step 2 of Example 1 was varied to 0.8 mol based on 1 mol of polyphenylether.
- a polyphenylether copolymer was prepared in the same method as in Example 1, except that the amount of bromine added in Step 2 of Example 1 was varied to 1.0 mol based on 1 mol of polyphenylether.
- a polyphenylether copolymer was prepared in the same method as in Example 1, except that the amount of bromine added in Step 2 of Example 1 was varied to 1.2 mol based on 1 mol of polyphenylether.
- a polyphenylether copolymer was prepared in the same method as in Example 1, except that the amount of bromine added in Step 2 of Example 1 was varied to 1.4 mol based on 1 mol of polyphenylether.
- a polyphenylether copolymer was prepared in the same method as in Example 1, except that the amount of bromine added in Step 2 of Example 1 was varied to 1.6 mol based on 1 mol of polyphenylether.
- the polyphenylether copolymer prepared in Example 1 was precipitated in a 1M sulfuric acid solution at 100 °C for 24 hours to exchange sodium cations of the sulfonate group with protons. Next, the protonated copolymer was washed with deionized water. Then the protonated copolymer was dissolved in dimethyl sulfoxide (DMSO), cast on a glass plate using a round glass rod, and dried in a vacuum oven at 150 °C to form a polymer electrolyte membrane having a thickness of 0.01-0.1 ⁇ m .
- DMSO dimethyl sulfoxide
- a polymer electrolyte membrane having a thickness of 0.01-0.1 ⁇ m was manufactured using the same method as in Example 9, except that the polyphenylether copolymer prepared in Example 2 was used.
- a polymer electrolyte membrane having a thickness of 0.01-0.1 ⁇ m was manufactured using the same method as in Example 9, except that the polyphenylether copolymer prepared in Example 3 was used.
- a polymer electrolyte membrane having a thickness of 0.01-0.1 ⁇ m was manufactured using the same method as in Example 9, except that the polyphenylether copolymer prepared in Example 4 was used.
- a polymer electrolyte membrane having a thickness of 0.01-0.1 ⁇ m was manufactured using the same method as in Example 9, except that the polyphenylether copolymer prepared in Example 5 was used.
- a polymer electrolyte membrane having a thickness of 0.01-0.1 ⁇ m was manufactured using the same method as in Example 9, except that the polyphenylether copolymer prepared in Example 6 was used.
- a polymer electrolyte membrane having a thickness of 0.01-0.1 ⁇ m was manufactured using the same method as in Example 9, except that the polyphenylether copolymer prepared in Example 7 was used.
- a polymer electrolyte membrane having a thickness of 0.01-0.1 ⁇ m was manufactured using the same method as in Example 9, except that the polyphenylether copolymer prepared in Example 8 was used.
- a polysulfone-based polymer represented by Formula 9 below (BASF Co. Ltd, ULTRASON S3010) was treated with sulfuric acid using the same method as in Example 9 and used as a polymer electrolyte membrane.)
- NAFION 112 (DuPont) was used as a polymer electrolyte membrane.
- the NAFION 112 was precipitated in a 1M sulfuric acid solution at 100 °C for 24 hours in order to exchange sodium cations of the sulfonate group with protons. Next, the hydrogenated copolymer was washed with deionized water.
- Proton conductivity [S/cm] (membrane thickness[cm]/membrane area[cm 2 ]) ⁇ initial conductivity[S]
- Each of the polymer electrolyte membranes manufactured in Examples 9 through 16 and Comparative Examples 1 and 2 was interposed between two cells. Then, 15 mL of 1M methanol aqueous solution was supplied to one cell and 15 mL of distilled water was supplied to the other cell. For the cell to which distilled water was supplied, 10 ⁇ l of distilled water was extracted from the cell in every ten minutes, and then the cell was filled with 10 ⁇ l of distilled water. The concentration of methanol contained in the extracted sample was measured by gas chromatography. Also, a graph showing methanol concentration according to time was prepared, and methanol permeability was calculated by using Equation 2 below from a slope of the graph. The results are shown in Table 1 below.
- Methanol permeability [cm 2 /S] (concentration gradient[ppm/s] ⁇ volume ⁇ thickness of electrolyte membrane thickness)/(area of electrolyte membrane ⁇ methanol concentration)
- the thickness of the electrolyte membrane was 0.05 ⁇ m , the diameter of the electrolyte membrane was 3 cm; methanol concentration was 1 mol(32000 ppm); a volume of solution was 15 ml; and the area of the electrolyte membrane was 7.06 cm 2
- the polymer electrolyte membranes manufactured in Examples 9 through 16 and Comparative Example 1 and 2 were immersed in distilled water at 30 °C for 24 hours.
- the polymer electrolyte membranes immersed in distilled water were removed from the distilled water and weighed (M wet ) and dried in a vacuum oven at 100 °C for 24 hours.
- the dried polymer electrolyte membranes were then weighed (M dry ), and the water uptake ratio was calculated according to Equation 3 below. The results are shown in Table 1 below.
- the polymer electrolyte membranes manufactured in Examples 9 through16 including the polyphenylether-based copolymer according to an embodiment of the present invention have low methanol permeability and low water uptake ratios compared with the polymer electrolyte membrane of Comparative Example 1.
- the polymer electrolyte membranes manufactured in Examples 13 through 16 have high proton conductivity while having low methanol permeability and low water uptake ratio, compared with the polymer electrolyte membrane of Comparative Example 1.
- the polymer electrolyte membranes manufactured in Examples 13 through 16 have remarkably low methanol permeability compared with the polymer electrolyte membrane of Comparative Example 2.
- the fuel cell employing the polymer electrolyte membrane including the polyphenylether-based copolymer has improved properties in terms of proton conductivity, methanol permeability, and water uptake ratio.
- the fuel cell employing the polymer electrolyte membrane including the polyphenylether-based copolymer has improved properties in terms of proton conductivity, methanol permeability, and water uptake ratio.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- Medicinal Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Fuel Cell (AREA)
- Conductive Materials (AREA)
Abstract
L'invention porte sur un copolymère à base de poly(oxyde de phényle) comprenant une unité récurrente représentée par la formule 1a et une unité récurrente représentée par la formule 1b : dans lesquelles : M1, M2, M3, Ar1, A42, R1, R2, R3, R4, X, m et n sont tels que définis dans la description détaillée de l'invention.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2009-0004643 | 2009-01-20 | ||
KR1020090004643A KR101573191B1 (ko) | 2009-01-20 | 2009-01-20 | 폴리페닐에테르계 공중합체, 이의 제조방법, 이를 포함하는고분자 전해질막 및 이를 채용한 연료전지 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010085028A1 true WO2010085028A1 (fr) | 2010-07-29 |
Family
ID=42356065
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2009/003846 WO2010085028A1 (fr) | 2009-01-20 | 2009-07-14 | Copolymère à base de poly(oxyde de phényle), procédé de préparation du copolymère, membrane électrolyte polymère comprenant le copolymère et pile à combustible comprenant la membrane électrolyte polymère |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR101573191B1 (fr) |
WO (1) | WO2010085028A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113140769A (zh) * | 2021-02-24 | 2021-07-20 | 吴丹 | 一种无机复合聚苯醚质子交换膜及其制备方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102664565B1 (ko) | 2022-02-15 | 2024-05-13 | 인비즈넷 주식회사 | 안심번호 제공방법 및 시스템 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0369598A2 (fr) * | 1988-10-12 | 1990-05-23 | Mitsubishi Chemical Corporation | Composition à base de matière synthétique |
US6045883A (en) * | 1995-06-29 | 2000-04-04 | Asahi Kasei Kogyo Kabushiki Kaisha | Resin composition and resin composition for secondary battery jar |
US20070196712A1 (en) * | 2006-02-20 | 2007-08-23 | Samsung Sdi Co., Ltd. | Multiblock copolymer, method of preparing the same, polymer electrolyte membrane prepared from the multiblock copolymer, method of preparing the polymer electrolyte membrane, and fuel cell employing the polymer electrolyte membrane |
US20080157422A1 (en) * | 2006-12-29 | 2008-07-03 | Samsung Sdi Co., Ltd. | Composition containing proton-conductive copolymer, polymer electrolyte membrane, method of producing the membrane , and fuel cell using the membrane |
-
2009
- 2009-01-20 KR KR1020090004643A patent/KR101573191B1/ko active IP Right Grant
- 2009-07-14 WO PCT/KR2009/003846 patent/WO2010085028A1/fr active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0369598A2 (fr) * | 1988-10-12 | 1990-05-23 | Mitsubishi Chemical Corporation | Composition à base de matière synthétique |
US6045883A (en) * | 1995-06-29 | 2000-04-04 | Asahi Kasei Kogyo Kabushiki Kaisha | Resin composition and resin composition for secondary battery jar |
US20070196712A1 (en) * | 2006-02-20 | 2007-08-23 | Samsung Sdi Co., Ltd. | Multiblock copolymer, method of preparing the same, polymer electrolyte membrane prepared from the multiblock copolymer, method of preparing the polymer electrolyte membrane, and fuel cell employing the polymer electrolyte membrane |
US20080157422A1 (en) * | 2006-12-29 | 2008-07-03 | Samsung Sdi Co., Ltd. | Composition containing proton-conductive copolymer, polymer electrolyte membrane, method of producing the membrane , and fuel cell using the membrane |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113140769A (zh) * | 2021-02-24 | 2021-07-20 | 吴丹 | 一种无机复合聚苯醚质子交换膜及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
KR101573191B1 (ko) | 2015-12-01 |
KR20100085388A (ko) | 2010-07-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2013081437A1 (fr) | Composé à base de sulfonate, membrane électrolyte polymère le comprenant et pile à combustible le comprenant | |
CN101024692B (zh) | 含磺酸基的聚硅氧烷化合物及其制法以及包含它的燃料电池 | |
KR100813242B1 (ko) | 고분자 전해질막, 이의 제조 방법 및 이를 구비한 연료전지 | |
KR100634551B1 (ko) | 이온전도성 가교 공중합체 및 이를 포함하는 연료전지 | |
KR100707163B1 (ko) | 고체산, 이를 포함하는 고분자 전해질막 및 이를 채용한연료전지 | |
WO2014178619A1 (fr) | Membrane électrolytique polymère, ensemble électrodes à membrane comprenant une membrane électrolytique polymère, et pile à combustible comprenant un ensemble électrodes à membrane | |
WO2010053297A2 (fr) | Membrane électrolytique polymère | |
WO2017142344A1 (fr) | Particules à noyau-enveloppe, membrane électrolytique polymère comprenant lesdites particules, pile à combustible ou cellule électrochimique comprenant la membrane électrolytique polymère, et procédé pour fabriquer des particules à noyau-enveloppe | |
US7759453B2 (en) | Multiblock copolymer, method of preparing the same, polymer electrolyte membrane prepared from the multiblock copolymer, method of preparing the polymer electrolyte membrane, and fuel cell employing the polymer electrolyte membrane | |
KR100790854B1 (ko) | 고분자 전해질막 및 이를 구비한 연료전지 | |
WO2012134095A2 (fr) | Copolymère conducteur d'ion hydrogène comprenant un groupe diphénylfluorène dans lequel un groupe acide sulfonique est introduit, procédé pour le préparer, membrane électrolytique polymère produite à partir de celui-ci, ensemble membrane/électrolyte l'employant et pile à combustible à membrane électrolytique polymère l'adoptant | |
Zhu et al. | Synthesis and characterization of polysulfone-containing sulfonated side chains for direct methanol fuel cells | |
WO2016122200A1 (fr) | Composé comprenant un cycle aromatique et membrane polyélectrolyte utilisant ce composé | |
WO2016163773A1 (fr) | Membrane à électrolyte polymère, pile électrochimique et cellule d'écoulement la comprenant, procédé de fabrication d'une membrane à électrolyte polymère, et électrolyte de cellule d'écoulement | |
WO2010085028A1 (fr) | Copolymère à base de poly(oxyde de phényle), procédé de préparation du copolymère, membrane électrolyte polymère comprenant le copolymère et pile à combustible comprenant la membrane électrolyte polymère | |
KR100907476B1 (ko) | 부분적으로 불소가 도입된 이온 전도성 공중합체를 함유한고분자 전해질 막, 그의 제조방법 및 고분자 전해질 막을채용한 고분자 전해질형 연료전지 | |
KR100659130B1 (ko) | 고분자 전해질막 및 이를 구비한 연료전지 | |
WO2016122195A1 (fr) | Composé comprenant un anneau aromatique, polymère comprenant ce composé et membrane polyélectrolytique l'utilisant | |
WO2023085592A1 (fr) | Membrane électrolytique polymère-copolymère ramifié à base de fluorène et de biphényle et système d'électrolyse de l'eau l'utilisant | |
KR20160081117A (ko) | 술폰화된 폴리(이사틴-에테르술폰), 이의 제조방법 및 이를 포함하는 연료전지용 고분자 막 | |
WO2010076911A1 (fr) | Copolymères post-sulfonés contenant des groupes perfluorocyclobutane et leur procédé de préparation et leur utilisation | |
WO2023106657A1 (fr) | Conducteur ionique à échange cationique à base de polycarbazole et son procédé de fabrication | |
WO2010082716A1 (fr) | Copolymère à base de polysulfone, procédé de préparation du copolymère à base de polysulfone, membrane électrolyte polymère comprenant le copolymère à base de polysulfone, et pile à combustible comprenant la membrane électrolyte polymère | |
KR100773322B1 (ko) | 크로스링크된 pbi를 포함하는 연료전지용 고분자전해질막 및 그 제조방법 | |
WO2016089156A2 (fr) | Polymère et membrane électrolytique polymère le comprenant |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09838915 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 09838915 Country of ref document: EP Kind code of ref document: A1 |