WO2010081646A2 - Associations de principes actifs fongicides - Google Patents

Associations de principes actifs fongicides Download PDF

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Publication number
WO2010081646A2
WO2010081646A2 PCT/EP2010/000028 EP2010000028W WO2010081646A2 WO 2010081646 A2 WO2010081646 A2 WO 2010081646A2 EP 2010000028 W EP2010000028 W EP 2010000028W WO 2010081646 A2 WO2010081646 A2 WO 2010081646A2
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plants
acid
plant
species
seed
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PCT/EP2010/000028
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German (de)
English (en)
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WO2010081646A3 (fr
Inventor
Stefan Herrmann
Peter Dahmen
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Bayer Cropscience Aktiengesellschaft
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Publication of WO2010081646A2 publication Critical patent/WO2010081646A2/fr
Publication of WO2010081646A3 publication Critical patent/WO2010081646A3/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Definitions

  • the present invention relates to novel drug combinations containing the known fungicidal active ingredient prothioconazole and at least one plant growth regulator, which are very well suited for controlling unwanted phytopathogenic fungi.
  • the invention also relates to a method for the curative or preventive treatment of phytopathogenic fungi on plants or crops, in particular the treatment of seeds, e.g. Cereal seed, and not least the treated seed itself.
  • prothioconazole has fungicidal properties [cf. The Pesticide Manual, 14th Edition (2006), page 895]. The effectiveness of this substance is good, but leaves in some cases to be desired.
  • Plant growth regulators hereinafter also abbreviated to PGRs, are generally understood to mean compounds or mixtures which influence the behavior of ornamental or crop plants or their agricultural products through physiological (eg hormonal) effects in terms of growth and differentiation , PGRs can e.g. accelerate or retard the growth of plants, prolong or shorten the resting state, or promote root growth. In particular, some PGRs are capable of reducing plant height, stimulating germination, inducing flowering, darkening leaf color, or affecting the timing or efficiency of fruiting.
  • plant growth regulators may e.g. inhibit the vegetative growth of plants, which is of interest on lawns, in ornamental plants, in orchards, on street embankments, on sports and industrial facilities, but also in the targeted inhibition of secondary drives such as tobacco.
  • the inhibition of vegetative growth in cereals leads to reduced storage by means of a stalk reinforcement. Similar effect is achieved e.g. in rapeseed, sunflower and corn.
  • the number of plants / shoots per area can be increased.
  • the yield can be influenced quantitatively (eg latex flow) or qualitatively (eg sugar content), the apikaidominance can be broken and side shoots can be promoted (eg ornamental plants), flowering and fruiting can be promoted (eg thinning of fruit trees for alternation breaking, Fruit abscission in olives for mechanical harvesting), the fruit ripeness can be harmonized with growth regulators, accelerated or retarded (eg capsule opening in cotton, ripening of tomatoes or bananas).
  • plants can be made more resistant to environmental stress such as drought, cold or soil salt content.
  • plant growth regulators the Defoliation of Kultu ⁇ flanzen be selectively induced in time, so that the mechanical harvest in crops such as cotton, potatoes or vines is facilitated or made possible.
  • growth regulators have no useful, direct fungicidal action, even though there are individual classes of growth regulators with minor fungicidal activity.
  • the present invention provides drug combinations or agents which solve the stated problem in at least some aspects.
  • the active compound combinations or compositions according to the invention have a synergistic effect.
  • the usual application rate of the individual substances can be reduced.
  • the active substance combinations according to the invention still offer a high degree of action against phytopathogens, even if the individual compounds are used in quantities in which they themselves show no (sufficient) effect. This basically allows a broadening of the spectrum of action on the one hand and a higher safety in handling and better environmental impact on the other.
  • it is possible, by using the combinations according to the invention to achieve a greatly improved fungicidal activity while at the same time protecting against bearing damage by the hemi-reinforcing action of the growth regulators with only one plant treatment.
  • the active compound combinations according to the invention can have further surprising properties which, in a broader sense, can also be described as synergistic, such as: the expansion of the activity spectrum, for example, to resistant pathogens of pancycine diseases; Greater application rates of the active ingredient; sufficient pest control with the aid of the active compound combinations according to the invention even at such application rates at which the individual active ingredients show no or almost no effect; advantageous behavior during formulation or during use, eg during milling, sieving, emulsifying, dissolving or spreading, improved storage or light stability; more advantageous formation of residues; improved toxicological or ecotoxicological behavior; improved properties for the plant, eg better growth, increased crop yields, better developed root system, larger leaf area, greener leaves, thicker shoots, less use of seeds, less phytotoxicity, mobilization of the plant's defense, good plant tolerance.
  • synergistic such as: the expansion of the activity spectrum, for example, to resistant pathogens of pancycine diseases; Greater application rates of the active ingredient; sufficient pest control with the aid of the
  • the active compound combinations or compositions according to the invention when applied, contribute significantly to the health of young cereal stocks, thereby increasing the wintering performance of the treated cereal seed and ensuring the quality and yield formation.
  • the active compound combinations according to the invention can contribute to an improved systemic action. Even if the individual active ingredients of the combination do not possess sufficient systemic properties, the active ingredient combinations according to the invention can certainly exhibit this property.
  • the active compound combinations according to the invention can lead to an increased persistence of the fungicidal action.
  • prothioconazole ⁇ chemical name: 2 - [(2i? S) -2- (1-chlorocyclopropyl) -3- (2-chlorophenyl) -2-hydroxypropyl] -2H-l, 2,4-triazole-3 ( 4H) -thione ⁇ or its pure enantiomers and / or their
  • Plant growth regulators may be any compounds or mixtures capable of affecting the germination, growth, maturation or development of plants or their fruits. These plant growth regulators can be divided into different subclasses, which are given here by way of example:
  • Antiauxins such as clofibrin [2- (4-chlorophenoxy) -2-methylpropanoic acid] and 2,3,5-tri-iodobenzoic acid;
  • Cytokinins such as 2iP [N- (3-methylbut-2-enyl) -1-purin-6-amine], benzyladenines, kinetin, zeatin;
  • Defoliants such as calcium cyanamide, dimethipine, endothal, ethephon, merphos, metoxuron, pentachlorophenol, thidiazuron, tribufos; Ethylene inhibitors such as aviglyme, aviglycine hydrochloride, 1-methylcyclopropene;
  • Ethylene generators such as ACC (1-aminocyclopropanecarboxylic acid), et schedulingl, ethephon, glyoxime;
  • Growth inhibitors such as abscisic acid, Ancymidol, Butrahn, Carbaryl, chlorophonium or its chloride, Chlorpropham, Dikegulac, Dikegulac Nat ⁇ um, Flumetrahn, Fluo ⁇ damid, Fosamine, glyphosines, Isopynmol, jasmonic acid, malemic hydrazide or its potassium salt, Mepiquat or its chloride, piproctanyl or its bromide, Prohydrojasmon, Propham, 2,3,5-T ⁇ -iodobenzoic acid;
  • Growth inhibitors such as abscisic acid, Ancymidol, Butrahn, Carbaryl, chlorophonium or its chloride, Chlorpropham, Dikegulac, Dikegulac Nat ⁇ um, Flumetrahn, Fluo ⁇ damid, Fosamine, glyphosines, Isopynmol, jasmonic acid, malemic hydrazi
  • Mo ⁇ hactine such as Chlorfluren, Chlorflurenol, Chlorflurenol-methyl, Dichlorflurenol, Flurenol;
  • Growth retarders modifiers such as chlormequat, chlormequat-chlo ⁇ d, daminozides, flu ⁇ midol, mefluidides, mefluidide-diolamine, paclobutrazole, cyproconazole, tetcyclacis, uniconazole, uniconazole-P;
  • Growth stimulators such as brassinhde, forchlorfenuron, hymexazole, 2-amino-6-oxypurine-dimeric acid, indolinone derivatives, 3,4-disubstituted-maleimide-derivative and azepmon-derivative;
  • unclassified PGRs such as Benzofluor, Buminafos, Carvone, Ciobutide, Clofencet, Clofence Potassium, Cloxyfonac, Cloxyfonac Nat ⁇ um, Cyclanihde, Cycloheximide, Epocholeone, Ethychlozate, Ethylene, Fenridazon, Heptopargil, Holosulf, Inabenfide, Karetazan, Bleiarsenat, Methasulfocarb, Prohexadione Prohexadione-Calcium, Pydanone, Smtofen, T ⁇ apenthenol, T ⁇ nexapac and T ⁇ nexapac-ethyl;
  • PGRs such as 2,6-dinopropylnaphthalene, cloprop, 1-naphthylacetic acid ethyl ester, isoprothiolanes, ethyl MCPB ethyl [4- (4-chloro-o-tolyloxy) butyrate], N-acetylthiazolidine-4-carboxylic acid, decanol Pelargonic acid, N-phenylphthalimic acid, Tecnazene, T ⁇ acontanol, 2,3-
  • chlormequat chlormequat-chlo ⁇ d
  • cyclanihde dimethipin
  • e-thephon flumetrahn
  • fluoropmidol inabenfide
  • mepiquat mepiquat-chlo ⁇ d
  • 1-methylcyclopropene paclobutrazole
  • prohexadione-calcium Prohydrojasmon
  • T ⁇ bufos thidiazuron
  • T ⁇ nexapac T ⁇ nexapac -ethyl or uniconazole.
  • Trinexapac-ethyl, chlormequat chloride and paclobutrazole are particularly preferably used as PGR.
  • the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the synergistic effect is particularly pronounced.
  • the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range.
  • 1 part by weight of prothioconazoles accounts for 0.01-50, preferably 0.1-25, more preferably 1-15, most preferably 2-10 parts by weight of plant growth regulator.
  • the active ingredient prothioconazole may optionally be present in the form of its stereoisomers, its pure enantiomers and / or in the form of salts.
  • the expression "combination of active ingredients” means various possible combinations of the abovementioned active ingredients, such as ready mixes, tank mixes (which are understood to be application and spray mixtures which are prepared before use from the formulations of the individual active ingredients by combining and diluting) or combinations thereof (For example, a binary ready mix of two of the above-mentioned active ingredients is transferred with a formulation of the third individual substance in a tank mix).
  • the present invention further relates to an agent for controlling unwanted microorganisms comprising the active compound combinations according to the invention.
  • an agent for controlling unwanted microorganisms comprising the active compound combinations according to the invention.
  • Preference is given to fungicidal compositions which contain agriculturally useful auxiliaries, solvents, carriers, surface-active substances or extenders.
  • the invention relates to a method for controlling unwanted microorganisms, characterized in that the active ingredient combinations according to the invention are applied to the phytopathogenic fungi and / or their habitat.
  • the carrier means a natural or synthetic, organic or inorganic substance, with which the active ingredients are mixed or combined for better applicability, especially for application to plants or plant parts or seeds.
  • the carrier which may be solid or liquid, is generally inert and should be useful in agriculture. Suitable solid or liquid carriers are: for example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as finely divided silica, alumina and natural or synthetic silicates, resins, waxes, solids Fertilizers, water, alcohols, especially butanol, organic solvents, mineral and vegetable oils and derivatives thereof.
  • Suitable solid carriers for granules are suitable. eg broken and fractionated natural rocks such as calcite, marble, pumice, sepiohth, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stems.
  • Suitable liquefied gaseous diluents or carriers are those liquids which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
  • Aerosol propellants such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
  • Adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-like polymers can be used in the formulations, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as crayon and lecithin, and synthetic phosphohipes.
  • Other additives may be mineral and vegetable oils.
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or dichloromethane, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • alcohols such as butanol or glycol and their ethers and esters
  • ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • compositions according to the invention may additionally contain further constituents, for example surface-active substances Suitable surface-active substances are emulsifying and / or foam-forming agents, dispersants or wetting agents having ionic or nonionic properties or mixtures of these surface-active substances.
  • surface-active substances are emulsifying and / or foam-forming agents, dispersants or wetting agents having ionic or nonionic properties or mixtures of these surface-active substances.
  • Examples thereof are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, tau ⁇ nde ⁇ vate (preferably alkyl taurates), Phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, for example alkylarylpolyglycol ethers, alkylsulphonates, alkylsulphates, arylsulphonates, protein hydrolysates, ligands nin-sulphite liquors and methylcellulose.
  • the presence of a surface-active substance is necessary when one of the active ingredient and / or one of the inert carriers is not sufficiently soluble in water and when applied in water.
  • the proportion of surface-active substances is between 5 and 40 percent by weight of the agent according to the invention.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • additional components may also be included, e.g. protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, stabilizers, sequestering agents, complexing agents.
  • the active ingredients can be combined with any solid or liquid additive commonly used for formulation purposes.
  • the agents and formulations according to the invention contain between 0.05 and 99% by weight, 0.01 and 98% by weight, preferably between 0.1 and 95% by weight, particularly preferably between 0.5 and 90%. Active ingredient, most preferably between 10 and 70 weight percent.
  • the active compound combinations or compositions according to the invention can be used as such or as a function of their physical and / or chemical properties in the form of their formulations or the use forms prepared therefrom, such as aerosols, capsule suspensions, cold mist concentrates, hot mist concentrates, encapsulated granules, fine granules, flowable concentrates for the treatment of seed, ready-to-use solutions, dustable powders, emulsifiable concentrates, oil-in-water emulsions, water-in-oil emulsions, macrogranules, microgranules, oil-dispersible powders, oil-miscible flowable concentrates, oil-miscible liquids, foams, Pastes, pesticide-coated seeds, suspension concentrates, suspension-emulsion concentrates, soluble concentrates, suspensions, wettable powders, soluble powders, dusts and granules, water-soluble granules or tablets, water-soluble powders for seed treatment,
  • compositions mentioned can be prepared in a manner known per se, for example by mixing the active compounds or the active ingredient combinations with at least one customary extender, solvent or diluent, emulsifier, dispersing and / or binding or fixing agent, wetting agent, water repellent optionally Sikkative and UV stabilizers and optionally dyes and pigments, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and other processing aids.
  • the compositions according to the invention comprise not only formulations which are already ready for use and which can be applied to the plant or the seed with a suitable apparatus, but also commercial concentrates which have to be diluted with water before use.
  • the active compounds according to the invention can be used as such or in their (commercial) formulations as well as in the formulations prepared from these formulations in admixture with other (known) active substances, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators , Herbicides, fertilizers, safeners or semiochemicals.
  • active substances such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators , Herbicides, fertilizers, safeners or semiochemicals.
  • the erfmdungsconcee treatment of plants and parts of plants with the active ingredient combinations or agents is carried out directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, spraying, sprinkling, evaporating, atomizing, atomizing, sprinkling, foaming, brushing, spreading, drenching, drip irrigation and propagating material, in particular for seeds by dry pickling, wet pickling, slurry pickling, encrusting, single or multi-layer wrapping, etc. It is also possible to apply the active ingredients by the ultra-low-volume method or to inject the active ingredient preparation or the active ingredient itself into the soil.
  • the invention further comprises a method of treating seed.
  • the invention further relates to seed which has been treated according to one of the methods described in the previous paragraph.
  • the seeds according to the invention are used in methods for the protection of seed from undesirable microorganisms.
  • a seed treated with at least one active ingredient according to the invention is used.
  • the active compound combinations or compositions according to the invention are also suitable for the treatment of seed.
  • Much of the crop damage caused by harmful organisms is caused by infestation of the seed during storage or after sowing, and during and after germination of the plant. This phase is particularly critical because the roots and shoots of the growing plant are particularly sensitive and may cause even minor damage to the plant's death. There is therefore a great interest in protecting the seed and the germinating plant by using suitable means.
  • the present invention therefore also relates to a method of protecting seeds and germinating plants from the infestation of phytopathogenic fungi by treating the seed with an agent according to the invention.
  • the invention also relates to the use of the seed treatment agents of the invention for protecting the seed and the germinating plant from phytopathogenic fungi.
  • the invention relates to seed which has been treated with an agent according to the invention for protection against phytopathogenic fungi.
  • One of the advantages of the present invention is that due to the systemic properties of the active compound combinations or compositions according to the invention, the treatment of the seeds with these active ingredients or agents protects not only the seed itself, but also the resulting plants after emergence from phytopathogenic fungi. In this way, the immediate treatment of the culture at the time of sowing or shortly afterwards can be omitted.
  • the active compound combinations or compositions according to the invention can also be used in particular in transgenic seed, wherein the plant growing from this seed is capable of expressing a protein which acts against pests.
  • the active compounds or agents according to the invention By treating such seeds with the active compounds or agents according to the invention, it is possible to combat pests already determined by the expression of, for example, insecticidal protein. Surprisingly, a further synergistic effect can be observed, which additionally increases the effectiveness for protection against pest infestation.
  • compositions according to the invention are suitable for the protection of seed of any plant variety used in agriculture, in the greenhouse, in forests or in horticulture and viticulture.
  • these are seeds of cereals (such as wheat, barley, rye, T ⁇ ticale, millet and oats), corn, cotton, soy, rice, potatoes, sunflower, bean, coffee, turnip (eg sugar beet and fodder), peanut, rape, poppy, olive, coconut, cocoa, sugarcane, tobacco, vegetables (such as tomato, cucumber , Onions and lettuce), turf and ornamental plants (see also below).
  • cereals such as wheat, barley, rye, T ⁇ ticale, millet and oats
  • corn cotton, soy, rice, potatoes, sunflower, bean, coffee, turnip (eg sugar beet and fodder)
  • peanut, rape poppy, olive, coconut, cocoa, sugarcane, tobacco, vegetables (such as tomato, cucumber , Onions and lettuce), turf and ornamental plants
  • transgenic seed with the active compounds or agents according to the invention is of particular importance.
  • the heterologous gene in transgenic seed may e.g. from microorganisms of the species Bacillus, Rhizobium, Pseudomonas, Serratia, T ⁇ choderma, Cibibacter, Glomus or Ghocladium.
  • this heterologous gene is from Bacillus sp, wherein the gene product has an activity against the corn germmer (European com borer) and / or Western Com Rootworm.
  • the heterologous gene is from Bacillus thu ⁇ ngiensis.
  • the agent according to the invention is applied to the seed alone or in a suitable formulation.
  • the seed is treated in a state where it is so stable that no damage occurs during the treatment.
  • the treatment of the seed can be done at any time between harvesting and sowing.
  • seed is used which has been separated from the plant and freed from flasks, shells, stalks, hull, wool or pulp.
  • seed may be used which has been harvested, purified and dried to a moisture content of less than 15% by weight.
  • seed may also be used which, after drying, e.g. treated with water and then dried again.
  • the agents according to the invention can be applied directly, ie without containing further components and without being diluted. In general, it is preferable to apply the agents to the seed in the form of a suitable formulation. Suitable formulations and methods for seed treatment are known to those skilled in the art and are described, for example, in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003/0176428 A1, WO 2002/080675 A1, WO 2002 / 028186 A2.
  • the active compounds which can be used according to the invention can be converted into the customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other seed coating compositions, as well as ULV formulations.
  • formulations are prepared in a known manner by mixing the active ingredients with customary additives, such as conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also Water.
  • customary additives such as conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also Water.
  • Dyes which may be present in the seed dressing formulations which can be used according to the invention are all dyes customary for such purposes. Both water-insoluble pigments and water-soluble dyes are useful in this case. Examples which may be mentioned under the names rhodamine B, CI. Pigment Red 112 and CI. Solvent Red 1 known dyes.
  • Suitable wetting agents which may be present in the seed dressing formulations which can be used according to the invention are all wetting-promoting substances customary for the formulation of agrochemical active compounds. Preference is given to using alkylnaphthalene sulfonates, such as diisopropyl or diisobutyl naphthalene sulfonates.
  • Suitable dispersants and / or emulsifiers which may be present in the seed dressing formulations which can be used according to the invention are all nonionic, anionic and cationic dispersants customary for the formulation of agrochemical active compounds. Preference is given to using nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants.
  • Particularly suitable nonionic dispersants are, in particular, ethylene oxide-propylene oxide, block polymers, alkylphenol polyglycol ethers and also tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives.
  • Suitable anionic dispersants are in particular lignosulfonates, polyacrylic acid salts and arylsulfonate-formaldehyde condensates.
  • Defoamers which may be present in the seed-dressing formulations which can be used according to the invention are all foam-inhibiting substances customary for the formulation of agrochemical active compounds.
  • Preferably usable are silicone defoamers and magnesium stearate.
  • Preservatives which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Examples include dichlorophen and Benzylalkoholhemiformal. As secondary thickeners which may be present in the seed dressing formulations which can be used according to the invention, all substances which can be used for such purposes in agrochemical compositions are suitable. Preference is given to cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and highly dispersed silicic acid.
  • Suitable adhesives which may be present in the seed dressing formulations which can be used according to the invention are all customary binders which can be used in pickling agents.
  • Preferably mentioned are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and Tylose.
  • the Gibberelhne are known (see R. Wegler “Chemistry of Crop Protection and Pest Control", Vol 2, Sp ⁇ nger Verlag, 1970, p 401-412).
  • the seed dressing formulations which can be used according to the invention can be used either directly or after prior dilution with water for the treatment of seed of various kinds, including seed of transgenic plants. In this case, additional synergistic effects may occur in interaction with the substances formed by expression.
  • the seed dressing formulations which can be used according to the invention or the preparations prepared therefrom by the addition of water
  • all mixing devices customarily usable for the dressing can be considered.
  • the seed is placed in a mixer which adds either desired amount of seed dressing formulations, either as such or after prior dilution with water, and mixes until evenly distributed the formulation on the seed.
  • a drying process follows.
  • the active compounds or compositions according to the invention have a strong microbicidal action and can be used for controlling unwanted microorganisms, such as fungi and bacteria, in crop protection and in material protection.
  • Fungicides can be used in crop protection to combat Plasmodiophoromycetes, Oomycetes, Chyt ⁇ diomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
  • Bactericides can be used in crop protection to combat Pseudomonadaceae, Rhizobiaceae, Enterobacte ⁇ aceae, Corynebacte ⁇ aceae and Streptomycetaceae.
  • the fungicidal compositions according to the invention can be used curatively or protectively for controlling phytopathogenic fungi.
  • the invention therefore also relates to curative and protective methods for controlling phytopathogenic fungi by the use of the invention Active ingredients or agents which are applied to the seed, the plant or parts of plants, the fruits or the soil in which the plants grow.
  • compositions of the invention for controlling phytopathogenic fungi in crop protection comprise an effective but non-phytotoxic amount of the active compounds according to the invention.
  • effective but non-phytotoxic amount is meant an amount of the agent of the invention sufficient to sufficiently control or completely kill the fungal disease of the plant and at the same time not cause any appreciable symptoms of phytotoxicity It depends on a number of factors, for example the fungus to be controlled, the plant, the climatic conditions and the contents of the agents according to the invention.
  • the good plant compatibility of the active compound combinations in the concentrations necessary for controlling plant diseases allows a treatment of aboveground plant parts, of plant and seed, and the soil.
  • plants and parts of plants can be treated.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including plant varieties which can or can not be protected by plant variety rights.
  • Plant parts are to be understood as meaning all the above-ground and underground parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes become.
  • the plant parts also include harvested material as well as vegetative and generative propagation material, for example pests, tubers, rhizomes, offshoots and seeds.
  • the active compound combinations according to the invention are suitable for good plant tolerance, favorable toxicity to warm-blooded animals and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the harvested crop. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • plants which can be treated according to the invention mention may be made of the following: cotton, flax, grapevine, fruits, vegetables, such as Rosaceae sp. (For example, core fruits such as apple and pear, but also drupes such as apricots, cherries, almonds and peaches and soft fruits such as strawberries), Ribesioidae sp., Juglandaceae sp, Betulaceae sp., Anacardiaceae sp, Fagaceae sp, Moraceae sp, Oleaceae sp, Actinidaceae sp, Lauraceae sp, Musaceae sp.
  • Rosaceae sp for example, core fruits such as apple and pear, but also drupes such as apricots, cherries, almonds and peaches and soft fruits such as strawberries
  • Ribesioidae sp. Juglandaceae sp
  • Asteraceae sp for example sunflower
  • Brassicaceae sp for example, white cabbage, red cabbage, broccoli, cauliflower, brussels sprouts, pak choi
  • plants and their parts can be treated.
  • wild-type or plant species obtained by conventional biological breeding methods such as crossing or protoplast fusion
  • plant cultivars and their parts are treated.
  • transgenic plants and plant cultivars obtained by genetic engineering if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
  • the term "parts” or “parts of plants” or “parts of plants” has been explained above.Propes of the respective commercially available or in use plant varieties are particularly preferably treated according to the invention.PV plants are understood as meaning plants with new properties ("traits") Both have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These may be varieties, breeds, biotypes and genotypes.
  • the treatment method of the invention may be used for the treatment of genetically modified organisms (GMOs), e.g. As plants or seeds are used.
  • GMOs genetically modified organisms
  • Genetically modified plants are plants in which a heterologous gene has been stably integrated into the genome.
  • heterologous gene essentially means a gene which is provided or assimilated outside the plant and which upon introduction into the nuclear genome, the chloroplast genome or the hypochondrial genome confers new or improved agronomic or other properties to the transformed plant expressing a protein or polypeptide of interest or that it downregulates or shuts down another gene present in the plant or other genes present in the plant (for example, by antisense technology, co-suppression technology or RNAi technology [RNA Interference ]).
  • a heterologous gene present in the genome is also referred to as transgene.
  • a transgene defined by its specific presence in the plant genome is referred to as a transformation or transgenic event.
  • the treatment according to the invention leads to superadditive (“synergistic") effects.
  • the following effects are possible which are beyond those actually expected Effects: reduced application rates and / or extended spectrum of activity and / or increased efficacy of the active ingredients and compositions that can be used according to the invention, improved plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or water or soil salt content increased Flowering, harvest relief, maturation acceleration, higher yields, larger fruits, greater plant height, intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruits, better shelf life and / or processability of the harvested products.
  • the active compound combinations according to the invention can also exert a tonic effect. They are also suitable for mobilizing the plant defense system against attack by undesirable phytopathogenic fungi and / or microorganisms and / or viruses. These may optionally be reasons for the increased effectiveness of the combinations according to the invention, for example against fungi.
  • Plant-strengthening (resistance-inducing) substances in the present context should also mean those substances or substance combinations which are able to stimulate the plant defense system in such a way that the treated plants, when subsequently inoculated with undesired phytopathogenic fungi, have a considerable degree of resistance against have these undesirable phytopathogenic fungi.
  • the substances according to the invention can therefore be employed for the protection of plants against attack by the mentioned pathogens within a certain period of time after the treatment.
  • the period of time over which a protective effect is achieved generally extends from 1 to 70 days, preferably 1 to 30 days, after the treatment of the plants with the active substances.
  • Plants and plant varieties which are preferably treated according to the invention include all plants which have genetic material conferring on these plants particularly advantageous, useful features (whether obtained by breeding and / or biotechnology).
  • Plants and plant varieties which are also preferably treated according to the invention are resistant to one or more biotic stress factors, ie these plants have an improved defense against animal and microbial pests such as nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and / or viroids .
  • Plants and plant varieties which can also be treated according to the invention are those plants which are resistant to one or more abiotic stress factors.
  • Abiotic stress conditions may include, for example, drought, cold and heat conditions, osmotic stress, waterlogging, increased soil salinity, increased exposure to minerals, ozone conditions, high light conditions, limited availability of nitrogen nutrients, limited availability of phosphorous nutrients, or avoidance of shade.
  • Plants and plant varieties which can also be treated according to the invention are those plants which are characterized by increased yield properties.
  • An increased yield can in these plants z.
  • it may be based on improved plant physiology, improved plant growth and improved plant development, such as water utilization efficiency, water retention efficiency, improved nitrogen utilization, increased carbon assimilation, improved photosynthesis, increased germination power and accelerated maturation.
  • Yield can be further influenced by improved plant architecture (under stress and non-stress conditions), including early flowering, control of flowering for hybrid seed production, seedling growth, plant size, internode count and distance, root growth, seed size, Fruit size, pod size, pod or ear number, number of seeds per pod or ear, seed mass, increased seed filling, reduced seed drop, reduced pod popping and stability.
  • Other yield-related traits include seed composition such as carbohydrate content, protein content, oil content and composition, nutritional value, reduction of nontoxic compounds, improved processability, and improved shelf life.
  • Plants which can be treated according to the invention are hybrid plants which already express the properties of the heterosis or the hybrid effect, which generally leads to higher yield, higher vigor, better health and better resistance to biotic and abiotic stress factors.
  • Such plants are typically produced by crossing an inbred polypreparent parent line (the female crossbrunner) with another inbred male fertile parent line (the male crossbred partner).
  • the hybrid seed is typically harvested from the male sterile plants and sold to propagators.
  • Pollen sterile plants can sometimes be produced (eg in maize) by delaving (ie mechanical removal of the male reproductive organs or the male flowers); however, it is more common for male sterility to be due to genetic determinants in the plant genome.
  • Pollen sterile plants can also be obtained using plant biotechnology methods such as genetic engineering.
  • a particularly convenient means of producing male sterile plants is described in WO 89/10396, wherein, for example, a ribonuclease such as a barnase is selectively expressed in the tapetum cells in the stamens. The fertility can then be restorated by expression of a ribonuclease inhibitor such as barstar in the tapetum cells.
  • herbicide-tolerant plants i. H. Plants tolerant to one or more given herbicides. Such plants can be obtained either by genetic transformation or by selection of plants containing a mutation conferring such herbicide tolerance.
  • Herbicide-tolerant plants are, for example, glyphosate-tolerant plants, i. H. Plants tolerant to the herbicide glyphosate or its salts.
  • glyphosate-tolerant plants can be obtained by transforming the plant with a gene encoding the enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS).
  • EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
  • EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
  • EPSPS genes are the AroA gene (mutant CT7) of the bacterium Salmonella typhimurium, the CP4 gene of the bacterium Agrobacterium sp., The genes for a EPSPS from the petunia, for a EPSPS from the tomato or for a Encoding EPSPS from Eleusine.
  • Glyphosate-tolerant plants can also be obtained by expressing a gene encoding a glyphosate oxidoreductase enzyme. Glyphosate-tolerant plants can also be obtained by expressing a gene encoding a glyphosate acetyltransferase enzyme. Glyphosate-tolerant plants can also be obtained by selecting plants that select naturally occurring mutations of the above mentioned genes.
  • herbicide-resistant plants are, for example, plants which have been tolerated to herbicides which inhibit the enzyme glutamine synthase, such as bialaphos, phosphinotricin or glufosinate.
  • Such plants can be obtained by expressing an enzyme which detoxifies the herbicide or expresses a mutant of the enzyme glutamine synthase, which is resistant to inhibition.
  • an effective detoxifying enzyme is, for example, an enzyme encoding a phosphinotricin acetyltransferase (such as the bar or pat protein from Streptomyces species). Plants expressing an exogenous phosphinotricin acetyltransferase have been described.
  • hydroxyphenylpyruvate dioxygenase HPPD
  • the hydroxyphenylpyruvate dioxygenases are enzymes that catalyze the reaction in which para-hydroxyphenylpyruvate (HPP) is converted to homogentisate.
  • Plants tolerant to HPPD inhibitors may be transformed with a gene encoding a naturally occurring resistant HPPD enzyme or a gene encoding an imitated HPPD enzyme.
  • Tolerance to HPPD inhibitors can also be achieved by transforming plants with genes encoding certain enzymes that allow the formation of homogentisate despite inhibition of the native HPPD enzyme by the HPPD inhibitor.
  • the tolerance of plants to HPPD inhibitors can also be improved by transforming plants with a gene coding for a prephenate dehydrogenase enzyme in addition to a gene which codes for an HPPD-tolerant enzyme.
  • ALS inhibitors include sulfonylurea, imidazolinone, triazolopyrimidines, pyrimidinyloxy (thio) benzoates and / or sulfonylaminocarbonyltriazolinone herbicides.
  • ALS also known as acetohydroxy acid synthase, AHAS
  • AHAS acetohydroxy acid synthase
  • plants tolerant to imidazolinone and / or sulfonylurea can be obtained by induced mutagenesis, selection in cell cultures in the presence of the herbicide or by mutation breeding.
  • Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering which can also be treated according to the invention are insect-resistant transgenic plants, i. Plants that have been made resistant to attack by certain target insects. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such insect resistance.
  • insect-resistant transgenic plant includes any plant containing at least one transgene comprising a coding sequence encoding:
  • an insecticidal crystal protein from Bacillus thuringiensis or an insecticidal part thereof such as the insecticidal crystal proteins, available online at: http: //www.hfesci.sussex ac.uk/Home/Neil_Cnckmore/Bt/, or insecticidal parts thereof, eg proteins of the cry protein classes CrylAb, CrylAc, CrylF, Cry2Ab, Cry3Ae or Cry3Bb or insecticidal parts from that; or
  • a Bacillus thunngiensis k ⁇ stall protein or a part thereof which acts as an insecticide in the presence of a second K ⁇ stallprotems other than Bacülus thunngiensis or a part thereof, such as the binary toxin, which consists of the K ⁇ stallpreinen Cy34 and Cy35; or
  • an insecticidal hybrid protein comprising parts of two different insecticides of Bacillus thunngiensis K ⁇ stallpro- teins, such as a Hyb ⁇ d from the proteins of 1) above or a Hyb ⁇ d from the proteins of 2) above, z.
  • the protein CrylA.105 produced by the corn event MON98034 (WO 2007/027777); or
  • a secreted protein from Baculus thunngiensis or Baculus cereus which acts in the presence of a second secreted protein from Baculus thunngiensis or B cereus insecticide, such as the binary toxin consisting of the proteins VIPlA and VIP2A.
  • an insecticidal hybrid protein comprising parts of various secreted proteins of Baculus thunngiensis or Baculus cereus, such as Hyb ⁇ d of the proteins of 1) or a hybrid of the proteins of 2) above; or
  • Species and / or due to changes in the coding DNA during were induced during cloning or transformation (preserving the coding for a msecidal protein), such as the protein VTP3Aa in cotton event COT 102.
  • insect-resistant transgenic plants in the present context also include any plant comprising a combination of genes encoding the proteins of any of the above classes 1 to 8.
  • an insect resistant plant contains more than one transgene encoding a protein of any one of the above 1 to 8 in order to extend the spectrum of the corresponding target insect species or to delay the development of resistance of the insects to the plants by use different proteins which are insecticides for the same target insect species, but have a different mode of action, such as binding to different receptor binding sites in the insect.
  • Plants or plant varieties obtained by methods of plant biotechnology, such as genetic engineering), which can also be treated according to the invention, are tolerant to abiotic stress factors. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such stress resistance. Particularly useful plants with stress tolerance include the following:
  • Plants which contain a transgene which is able to reduce the expression and / or activity of the gene for the poly (ADP- ⁇ bose) polymerase (PARP) in the plant cells or plants.
  • PARP poly (ADP- ⁇ bose) polymerase
  • Plants containing a stress tolerance-enhancing transgene encoding a plant-functional enzyme of the nicotmamide adenine nucleotide salvage biosynthetic pathway including nicotinamide, nicotinate phosphobiphenyltransferase, nicotinic acid mononucleotide adenyltransferase, nicotinamide adenine dinucleotide synthetase or nicotinamide phosphobiphenyltransferase.
  • Plants or plant varieties obtained by plant biotechnology methods, such as genetic engineering which can also be treated according to the invention have a modified amount, quality and / or shelf life of the harvested product and / or altered properties of certain components of the harvested product on, such as:
  • Distribution of side chains, viscosity behavior, gel strength, starch grain size and / or starch comorphology in comparison with the synthesized starch in wild-type plant cells or plants is modified, so that this modified starch is better suited for certain applications.
  • Transgenic plants that synthesize non-starch carbohydrate polymers or non-starch carbohydrate polymers whose properties are altered compared to wild-type plants without genetic modification. Examples are plants that produce polyfructose, particularly of the inulin and levan type, plants that produce alpha-1,4-glucans, plants that produce alpha-1,6-branched alpha-1,4-glucans, and plants that produce Produce alternan.
  • Plants or plant varieties obtained by methods of plant biotechnology, such as genetic engineering), which can also be treated according to the invention, are plants such as cotton plants with altered fiber properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered fiber properties; these include:
  • plants such as cotton plants containing an altered form of cellulose synthase genes
  • plants such as cotton plants, containing an altered form of rsw2 or rsw3 homologous nucleic acids
  • plants such as cotton plants with increased expression of the sucrose phosphate synthase
  • plants such as cotton plants with increased expression of sucrose synthase
  • plants such as cotton plants with modified reactivity fibers, e.g. By expression of the N-acetylglucosamine transferase gene, including nodC, and chitin synthase genes.
  • Plants or plant varieties which can also be treated according to the invention are plants such as oilseed rape or related Brassica plants with altered oil composition properties.
  • Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered oil properties; these include: a) plants, such as oilseed rape plants, which produce oil of high oleic acid content;
  • plants such as oilseed rape plants, which produce oil with a low linolenic acid content.
  • plants such as oilseed rape plants, which produce oil with a low saturated fatty acid content.
  • transgenic plants which can be treated according to the invention are plants with one or more genes which code for one or more toxins, the transgenic plants which are offered under the following commercial names: YIELD GARD® (for example maize, Cotton, soybeans), KnockOut® (for example corn), BiteGard® (for example maize), BT-Xtra® (for example corn), StarLink® (for example maize), Bollgard® (cotton), Nucotn® (cotton) , Nucotn 33B® (cotton), NatureGard® (for example corn), Protecta® and NewLeaf® (potato).
  • YIELD GARD® for example maize, Cotton, soybeans
  • KnockOut® for example corn
  • BiteGard® for example maize
  • BT-Xtra® for example corn
  • StarLink® for example maize
  • Bollgard® cotton
  • Nucotn® cotton
  • Nucotn 33B® cotton
  • NatureGard® for example corn
  • Protecta® and NewLeaf® pot
  • Herbicide-tolerant crops to be mentioned include, for example, corn, cotton and soybean varieties sold under the following tradenames: Roundup Ready® (glyphosate tolerance, for example, corn, cotton, soybean), Liberty Link® (phosphinotcincolerant, for example, rapeseed) , 1MI® (imidazone tolerance) and SCS® (sylphonylurea tolerance), for example corn.
  • Roundup Ready® glyphosate tolerance
  • Liberty Link® phosphinotcincolerant, for example, rapeseed
  • 1MI® imidazone tolerance
  • SCS® serine-seseed
  • transgenic plants that can be treated according to the invention are plants that contain transformation events, or a combination of transformation events, and that are listed, for example, in the files of various national or regional authorities (see, for example, http: // /grnomfo.jrc.it/gmp_browse.aspx and http://www.agbios.com/dbase.php).
  • the active compounds or compositions according to the invention can be used in the protection of materials for the protection of technical materials against attack and destruction by undesired microorganisms, such as e.g. Mushrooms, are used.
  • Technical materials as used herein mean non-living materials prepared for use in the art.
  • technical materials to be protected from microbial alteration or destruction by the active compounds of the present invention may be adhesives, glues, paper, wallboard and board, textiles, carpets, leather, wood, paints and plastics, coolants, and other microorganism infested materials or can be decomposed.
  • the materials to be protected also include parts of production plants and buildings, eg cooling water circuits, cooling and heating systems and ventilation and air conditioning systems, which may be affected by the proliferation of microorganisms.
  • technical materials preferably called adhesives, glues, papers and cartons, leather, wood, paints, cooling lubricants and heat transfer fluids, more preferably wood.
  • the active compounds or compositions according to the invention can prevent adverse effects such as decay, deterioration, decomposition, discoloration or mold.
  • the compounds according to the invention can be used to protect against the growth of objects, in particular hulls, sieves, nets, structures, wharfage systems and signal systems, which come into contact with seawater or brackish water.
  • Storage Goods are understood natural substances of plant or animal origin or their processing products, which were taken from nature and for long-term protection is desired
  • Storage goods of plant origin such as plants or plant parts, such as stems, leaves, tubers, seeds , Fruits, grains, can be protected in freshly harvested condition or after processing by (pre-) drying, wetting, crushing, grinding, pressing or roasting
  • Storage Goods also includes timber, whether unprocessed, such as timber, power poles and barriers, or in the form of finished products, such as furniture, storage goods of animal origin are, for example, skins, leather, furs and hair.
  • the active compounds according to the invention can prevent disadvantageous effects such as decay, deterioration, disintegration, discoloration or mold.
  • Blumeria species such as Blumeria graminis
  • Podosphaera species such as Podosphaera leucotricha
  • Sphaerotheca species such as Sphaerotheca fuliginea
  • Uncinula species such as Uncinula necator
  • Gymnosporangium species such as Gymnosporangium sabinae
  • Hemileia species such as Hemileia vastatrix
  • Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae
  • Puccinia species such as Puccinia graminis, Puccinia recondita or Puccinia triticina
  • U-romyces species such as Uromyces appendiculatus
  • Bremia species such as Bremia lactucae
  • Peronospora species such as Peronospora pisi or P. brassicae
  • Phytophthora species such as Phytophthora infestans
  • Plasmopara species like for example Plasmopara viticola
  • Pseudoperonospora species such as, for example, Pseudoperonospora humuh or Pseudoperonospora cubensis
  • Pythium species such as Pythium ultimum;
  • Phaeosphae ⁇ a species such as Phaeosphae ⁇ a nodorum
  • Pyrenophora species such as, for example, Pyrenophora teres
  • Ramula ⁇ a species such as Ramula ⁇ a collo-cygni, Rhynchospo ⁇ um species, such as Rhynchospo ⁇ um secahs
  • Septo ⁇ a species such as Septo ⁇ a apn
  • Typhula species such as Typhula incarnata
  • Ventu ⁇ a species such as Ventu ⁇ a inaequalis
  • Root and stem diseases caused by e.g. Corticium species such as, for example, Cor- ticium graminearum; Fusa ⁇ um species, such as Fusa ⁇ um oxysporum; Gaeumannomyces species such as Gaeumannomyces graminis; Rhizoctonia species, such as Rhizoctonia solani; Tapesia species, such as Tapesia acuformis; Thielaviopsis species, such as Thielaviopsis basicola;
  • Corticium species such as, for example, Cor- ticium graminearum
  • Fusa ⁇ um species such as Fusa ⁇ um oxysporum
  • Gaeumannomyces species such as Gaeumannomyces graminis
  • Rhizoctonia species such as Rhizoctonia solani
  • Tapesia species such as Tapesia acuformis
  • Thielaviopsis species such as Thielaviopsis basicola
  • Ear and panicle diseases caused by e.g. Alternana species such as Alternaria spp .; Aspergillus species, such as Aspergillus flavus; Cadastrum species such as, for example, Cladospo ⁇ um cladospo ⁇ oides; Claviceps species, such as Claviceps pu ⁇ urea; Fusa ⁇ um species, such as Fusa ⁇ um culmorum; Gibberella species, such as Gibberella zeae; Monographella species, such as Monographella nivalis; Septo ⁇ a species, such as Septo ⁇ a nodorum;
  • sphacelotheca species such as, for example, sphacelotheca reihana
  • Tilletia species such as Tületia ca ⁇ es, T. controversa
  • Urocystis species such as Urocystis occulta
  • Ustilago species such as Ustilago nuda, U. nuda t ⁇ tici
  • Botrytis species such as Botrytis cinerea
  • Penicillium species such as, for example, Penicillium expansum and P. purpurogenum
  • Sclerotinia species such as Sclerotinia sclerotiorum
  • Sclerotinia species such as Sclerotinia sclerotiorum
  • Verticilium species such as Verticilium alboatrum
  • Nectria species such as Nectria galligena
  • Degenerative diseases of woody plants caused by e.g. Esca species such as, for example, Phaemoniella clamydospora and Phaeoacremonium aleophilum and Fomitiporia mediterranea;
  • Botrytis species such as Botrytis cinerea
  • Rhizoctonia species such as Rhizoctonia solani
  • Helminthosporium species such as Helminthosporium solani
  • Xanthomonas species such as Xanthomonas campestris pv. Oryzae
  • Pseudomonas species such as Pseudomonas syringae pv. Lachrymans
  • Erwinia species such as Erwinia amylovora
  • the following diseases of soybean beans can be controlled:
  • Choanephora leaf blight Choanephora infundibulifera trispora (Syn.)), Dactuliophora leaf spot (Daculliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot (Leptosphaerulina trifolii), Phyllostica Leaf Spot (Phyllosticta sojaecola), Pod and Star Blight (Phomopsis sojae), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Ae ⁇ - al, Fohage, and Web Bhght (Rhizoctonia solani), Rust (Phakopsora pachyrhizi, Phakopsor
  • Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregular, Pythium debaryanum, Pythium my ⁇ otylum, Pythium ultimum), Rhizoctonia Root Red, Stem Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotmia Southern Bhght (Sclerotmia rolfsn) , Thielaviopsis Root Red (Thielaviopsis basicola).
  • the active compounds according to the invention preferably act against fungi, in particular molds, wood-discolouring and wood-destroying fungi (Basidiomycetes) and against slime organisms and algae.
  • Alterna ⁇ a such as Alterna ⁇ a tenuis
  • Aspergillus such as Aspergillus niger
  • Chaetomium like Chaetomium globosum
  • Coniophora such as Conophora puetana
  • Lentinus like Lentinus tig ⁇ nus
  • Penicilhum like Penicilhum glaucum
  • Polyporus such as Polyporus versicolor
  • Aureobasidium such as Aureobasidium pullulans
  • Sclerophoma such as Sclerophoma pityophila
  • T ⁇ choderma as T ⁇ choderma vi ⁇ de
  • Esche ⁇ chia such as Esche ⁇ chia coli
  • Pseudomonas such as Pseudomonas aeruginosa
  • Staphylococcus such as Staphylococcus aureus.
  • the active compound combinations according to the invention also have very good antifungal effects. They have a very broad antimycotic spectrum of action, in particular against dermatophytes and yeasts, mold and diphasic fungi (eg against Candida species such as Candida albicans, Candida glabrata) and Epidermophyton floccosum, Aspergillus species such as Aspergillus niger and Aspergillus fumigatus, T ⁇ chophyton species such as Trichophyton menta- grophytes, Microsporon species such as Microsporon canis and audouinn.
  • Candida species such as Candida albicans, Candida glabrata
  • Epidermophyton floccosum Aspergillus species such as Aspergillus niger and Aspergillus fumigatus
  • T ⁇ chophyton species such as Trichophyton menta- grophytes
  • Microsporon species such as Microsporon canis and audouinn.
  • the list of these fungi is
  • the active compound combinations according to the invention can therefore be used both in medical and non-medical applications.
  • the amounts of auric wall can be varied within a relatively wide range, depending on the mode of administration.
  • the application rate of the active compounds according to the invention is
  • Leaves from 0.1 to 10,000 g / ha, preferably from 10 to 1,000 g / ha, more preferably from 50 to 300 g / ha (when used by pouring or drop, the application rate can even be reduced, especially if inert Substrates such as rockwool or Perht are used); more preferably from 1 to 75 g / ha, more preferably from 5 to 60 g / ha, from 10 to 50 g / ha and from 15 to 40 g / ha of prothioconazole used;
  • seed treatment from 2 to 200 g per 100 kg of seed, preferably from 3 to 150 g per 100 kg of seed, more preferably from 2.5 to 25 g per 100 kg of seed, most preferably from 2.5 to 12, 5 g per 100 kg of seed; more preferably from 1 to 5 g per 100 kg of seed, more preferably from 0.5 to 2 g / ha and from 0.75 to 1.5 g / ha of prothioconazole used;
  • the active compounds or compositions according to the invention can therefore be used to protect plants within a certain period of time after the treatment against attack by the mentioned pathogens.
  • the period within which protection is brought about generally lasts from 1 to 28 days, preferably from 1 to 14 days, particularly preferably from 1 to 10 days, very particularly preferably from 1 to 7 days after the treatment of the plants the active substances or up to 200 days after seed treatment.
  • DON Deoxynivalenol
  • Nivalenol Nivalenol
  • 15-Ac-DON 3-Ac-DON
  • T2- and HT2-Toxin Fumonisins
  • Zearalenone Monihformin
  • Fusa ⁇ n Diaceoto-
  • DON Deoxynivalenol
  • Nivalenol Nivalenol
  • 15-Ac-DON 15-Ac-DON
  • 3-Ac-DON 3-Ac-DON
  • T2- and HT2-Toxin Fumonisins
  • Zearalenone Zearalenone
  • Monihformin Fusa ⁇ n
  • Diaceoto- are particularly, but not exclusively, mentioned here.
  • Fusa ⁇ um spec such as Fusa ⁇ um acuminatum, F. avenaceum, F. crookwellense, F. culmorum, F. graminearum (Gibberella zeae), F. equiseti, F. fujikoroi, F. musarum, F. oxysporum, F. prohferatum, F. poae, F. pseudograminearum, F.
  • the ratio of the components is preferably selected such that a synergistic effect is obtained.
  • synergistic effect as understood by Colby in the article “Calculation of the synergistic and antagonistic responses of bicycloid combinations” (in Weeds, 1967, 15, 20-22).
  • X means the efficiency when using the active substance A in an application rate of m g / ha
  • Y means the efficiency when using the active ingredient B in an application rate of n g / ha
  • Eg means the efficiency of the use of the active compounds A and B in application rates of m and n g / ha means and
  • the efficiency is determined in%. It means 0% an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infestation is observed.
  • prothioconazole 250EC formulation
  • the PGRs are used in the form of their commercial products at their recommended dosage. It is diluted with the appropriate amount of water to the desired concentration.
  • winter wheat plants are sprayed in a defined stage on 7.5 m 2 cells with the preparation of active compound in the stated application rate.

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Abstract

La présente invention concerne de nouvelles associations de principes actifs contenant le principe actif fongicide connu prothioconazole et au moins un régulateur de croissance des plantes, ces associations étant particulièrement adaptées pour lutter contre des champignons phytopathogènes indésirables. L'invention concerne en outre un procédé pour le traitement curatif ou préventif de champignons phytopathogènes sur des plantes ou des plantes utiles, en particulier pour le traitement de semences, p. ex. de semences de céréales, ainsi que la semence traitée elle-même.
PCT/EP2010/000028 2009-01-15 2010-01-07 Associations de principes actifs fongicides WO2010081646A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09150587 2009-01-15
EP09150587.5 2009-01-15

Publications (2)

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WO2012038935A3 (fr) * 2010-09-23 2012-06-21 Globachem Utilisation d'une composition pour augmenter le rendement des cultures
WO2013120729A1 (fr) * 2012-02-13 2013-08-22 Syngenta Participations Ag Régulation de la croissance des plantes
WO2013127859A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans du soja
WO2013127846A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le maïs
WO2014053398A1 (fr) 2012-10-01 2014-04-10 Basf Se Mélanges pesticides comprenant de l'acide jasmonique ou un dérivé de celui-ci
CN103719089A (zh) * 2013-11-18 2014-04-16 安徽淮化股份有限公司 一种用于瓜菜类的植物生长调节剂组合物
CN103918656A (zh) * 2014-04-22 2014-07-16 四川国光农化股份有限公司 一种植物生长调节剂组合物及其制剂
CN104336019A (zh) * 2014-10-10 2015-02-11 四川利尔作物科学有限公司 农药组合物及其应用
CN104542648A (zh) * 2015-01-27 2015-04-29 四川利尔作物科学有限公司 杀菌组合物及其应用
CN105766934A (zh) * 2014-10-10 2016-07-20 四川利尔作物科学有限公司 农药组合物及其应用
WO2018229055A1 (fr) * 2017-06-12 2018-12-20 Fine Agrochemicals Limited Régulateur de croissance végétale et fongicide
CN109105386A (zh) * 2018-09-06 2019-01-01 南京农业大学 一种玉米抗倒增产调节剂及其应用
CN109566616A (zh) * 2017-09-29 2019-04-05 陕西美邦农药有限公司 一种含甲苯酞氨酸的组合物
RU2786999C2 (ru) * 2017-06-12 2022-12-27 Файн Агрокемикалс Лимитед Регулятор роста растений и фунгицид

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BE1019682A5 (nl) * 2010-09-23 2012-09-04 Globachem Gebruik van een samenstelling voor het verhogen van de opbrengst van gewassen.
WO2012038935A3 (fr) * 2010-09-23 2012-06-21 Globachem Utilisation d'une composition pour augmenter le rendement des cultures
US9314031B2 (en) 2012-02-13 2016-04-19 Syngenta Participations Ag Plant growth regulation
WO2013120729A1 (fr) * 2012-02-13 2013-08-22 Syngenta Participations Ag Régulation de la croissance des plantes
EA025900B1 (ru) * 2012-02-13 2017-02-28 Зингента Партисипейшнс Аг Регуляция роста растений
WO2013127859A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans du soja
WO2013127846A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le maïs
WO2014053398A1 (fr) 2012-10-01 2014-04-10 Basf Se Mélanges pesticides comprenant de l'acide jasmonique ou un dérivé de celui-ci
CN103719089A (zh) * 2013-11-18 2014-04-16 安徽淮化股份有限公司 一种用于瓜菜类的植物生长调节剂组合物
CN103918656A (zh) * 2014-04-22 2014-07-16 四川国光农化股份有限公司 一种植物生长调节剂组合物及其制剂
CN104336019A (zh) * 2014-10-10 2015-02-11 四川利尔作物科学有限公司 农药组合物及其应用
CN105685055A (zh) * 2014-10-10 2016-06-22 四川利尔作物科学有限公司 农药组合物及其应用
CN105766934A (zh) * 2014-10-10 2016-07-20 四川利尔作物科学有限公司 农药组合物及其应用
CN104542648A (zh) * 2015-01-27 2015-04-29 四川利尔作物科学有限公司 杀菌组合物及其应用
CN104542648B (zh) * 2015-01-27 2016-06-08 四川利尔作物科学有限公司 杀菌组合物及其应用
WO2018229055A1 (fr) * 2017-06-12 2018-12-20 Fine Agrochemicals Limited Régulateur de croissance végétale et fongicide
EP3424323A1 (fr) * 2017-06-12 2019-01-09 Fine Agrochemicals Limited Régulateur de croissance et fongicide
RU2786999C2 (ru) * 2017-06-12 2022-12-27 Файн Агрокемикалс Лимитед Регулятор роста растений и фунгицид
CN109566616A (zh) * 2017-09-29 2019-04-05 陕西美邦农药有限公司 一种含甲苯酞氨酸的组合物
CN109105386A (zh) * 2018-09-06 2019-01-01 南京农业大学 一种玉米抗倒增产调节剂及其应用

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