WO2007065843A2 - Utilisation de gibberelline comme agent de protection pour azoles afin de lutter contre des champignons parasites - Google Patents

Utilisation de gibberelline comme agent de protection pour azoles afin de lutter contre des champignons parasites Download PDF

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Publication number
WO2007065843A2
WO2007065843A2 PCT/EP2006/069112 EP2006069112W WO2007065843A2 WO 2007065843 A2 WO2007065843 A2 WO 2007065843A2 EP 2006069112 W EP2006069112 W EP 2006069112W WO 2007065843 A2 WO2007065843 A2 WO 2007065843A2
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WO
WIPO (PCT)
Prior art keywords
azole
gibberellin
compounds
use according
formula
Prior art date
Application number
PCT/EP2006/069112
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German (de)
English (en)
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WO2007065843A3 (fr
Inventor
Dirk Voeste
Siegfried Strathmann
Peter Dombo
Reinhard Stierl
Markus Gewehr
Original Assignee
Basf Se
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Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of WO2007065843A2 publication Critical patent/WO2007065843A2/fr
Publication of WO2007065843A3 publication Critical patent/WO2007065843A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring

Definitions

  • gibberellin as a safener for azoles to control harmful fungi
  • the present invention relates to
  • Cyproconazole difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafole, hexaconazole, imibenconazole, iponazolone, metconazole, myclobutanil, penconazazole, propiazonolol, propiconazolone, propiconazolone, propiconazolone, propiconazolone, propiconazolone, propiconazolone, propiconazolone Triticonazole, prochloraz, pefurazoate, imazalil, triflumizole, cyazofamid, benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam, etridiazole, hymexazole, or its salts or adducts to combat harmful
  • the invention relates to the use of the compounds I and the azole (2) in a process for combating harmful fungi with mixtures of the compounds I and (2) and the use of the compounds I and (2) for the production of such mixtures and agents which Mixtures included.
  • Gibberellin of the formula I and mordants which contain it in a mixture with azoles, such as triticonazole, are known from WO 02/069715.
  • the mixture of gibberellic acid and tebuconazole is described as the only biological example.
  • the azoles (2) are all known from the literature and are commercially available.
  • gibberellin as a safener for azoles was found to combat harmful fungi. It has also been found that gibberellin and azole can be used simultaneously, together or separately. It has also been found that gibberellin and azole can be used to prepare an agent.
  • Formula I comprises the Gibberellins of the formulas 1-1 to I-4.
  • Gibberellic acid of the formula (I-2) is particularly preferred.
  • the azoles mentioned above as component (2), their preparation and their action against harmful fungi are generally known (cf.
  • Penconazole 1- [2- (2,4-dichlorophenyl) pentyl] -1 H- [1,2,4] triazole (Pesticide Manual, 12th
  • Prothioconazole 2- [2- (1-chloro-cyclopropyl) -3- (2-chlorophenyl) -2-hydroxypropyl] -2,4-dihydro- [1,2,4] triazol-3-thione (WO 96/16048);
  • Triadimphone 1 - (4-chlorophenoxy) -3,3-dimethyl-1 - (1 H-1, 2,4-triazol-1-yl) -2-butanone; Triadimenol, ß- (4-chlorophenoxy) - ⁇ - (1, 1-dimethylethyl) -1 H-1, 2, 4-triazole-1-ethanol;
  • Cyazofamide 4-chloro-2-cyano-N, N-dimethyl-5- (4-methylphenyl) -1 H-imidazole-1 sulfonamide (CAS RN 1201 16-88-3],
  • Hymexazole 5-methyl-1, 2-oxazol-3-ol (JP 518249, JP 532202).
  • the azoles (2) are able to form salts or adducts with inorganic or organic acids or with metal ions.
  • inorganic acids examples include hydrohalic acids such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, sulfuric acid, phosphoric acid and nitric acid.
  • organic acids are formic acid, carbonic acid and alkanoic acids such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid as well as glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid, cinnamic acid, oxalic acid, alkylsulfonic acids (sulfonic acids with straight-chain alkyl radicals, or branched-chain alkyl radicals) or branched chain alkyl radicals, Arylsulfonic acids or - disulfonic acids (aromatic radicals such as phenyl and naphthyl which carry one or two sulfonic acid groups), alkylphosphonic acids (phosphonic acids with straight-chain or branched alkyl radicals having 1 to 20 carbon atoms), arylphosphonic acids or -diphosphonic acids (aromatic radicals such as phenyl and naphthyl which one or carry two
  • the ions of the elements of the second main group, in particular calcium and magnesium, the third and fourth main group, in particular aluminum, tin and lead, and the first to eighth subgroups, in particular chromium, manganese, iron, cobalt, nickel, come as metal ions. Copper, zinc and others in dress.
  • the metal ions of the elements of the subgroups of the fourth period are particularly preferred.
  • the metals can be present in the various valences that they have. As described at the outset, in many crops, dressing the seeds with fungicides causes a delay or decrease in emergence and a poorer establishment of the crop at the start of the crop.
  • mixtures of the compounds I and (2) or the simultaneous joint or separate use of one of the compounds I and (2) are distinguished by the fact that these have negative effects on the plants which, depending on the dose, also Fluquinconazole or gibberellin may or may not occur or not occur as strongly.
  • the mixtures have excellent activity against a broad spectrum of phytopathogenic fungi, in particular from the class of the Ascomycetes, Basidiomycetes, Deuteromycetes and Peronosporomycetes (syn. Oomycetes). Some of them are systemically effective and can be used in plant protection as foliar, stain and soil fungicides.
  • Botrytis cinerea (gray mold) on strawberries, vegetables, flowers and grapevines
  • Cochliobolus species on corn, cereals, rice such as Cochliobolus sativus on cereals, Cochliobolus miyabeanus on rice
  • Peronospora species on cabbage and onion plants such as P. brassicae on cabbage or P. destructor on onion
  • Pseudoperonospora on various plants such as P. cubensis on cucumber or P. humili on hops
  • Puccinia species on different plants such as P. triticina, P. striformins, P. hordei or P. graminis on cereals, or P. asparagi on asparagus
  • compounds I and (2) for combating soybean rust has proven particularly useful, particularly in the treatment of soybean seeds.
  • the compounds I and (2) can be used to control harmful fungi such as Paecilomyces variotii in the protection of materials (e.g. wood, paper, dispersions for painting, fibers or fabrics) and in the protection of stored products.
  • the compounds I and (2) can be applied simultaneously, that is jointly or separately, or in succession, the sequence in the case of separate application generally not having any effect on the growth of the plants and the success in controlling them.
  • Pests such as insects, arachnids or nematodes or herbicidal or growth-regulating active ingredients or fertilizers can be added.
  • Mixtures of compounds I and (2) are usually used. Under certain circumstances, however, mixtures of the compounds I and (2) with possibly a plurality of active components may also be advantageous, such as, for example, mixtures of the compounds I and (2) with further fungicides.
  • the mixing ratio (weight ratio) of the compounds I and (2) is selected so that the described safener action occurs, for example compound I: compound (2) such as 100: 1 to 1: 100, in particular 10: 1 to 1:10 , for example 5: 1 to 1: 5, in particular 3: 1 to 1: 3, preferably 2: 1 to 1: 2.
  • the safener effect of the mixture is shown by the fact that the negative effect of azole on plant growth does not or does not occur as strongly.
  • the further active components are mixed in a ratio of 20: 1 to 1:20 to the compounds I and (2).
  • the application rates of the mixtures used are from 5 g / ha to 2000 g / ha, preferably from 20 to 900 g / ha, in particular from 50 to 750 g / ha .
  • the application rates for the compound I are generally from 1 to 1000 g / ha, preferably from 10 to 900 g / ha, in particular from 20 to 750 g / ha.
  • the application rates for the active ingredient (2) are generally from 1 to 1000 g / ha, preferably 10 to 900 g / ha, in particular 40 to 750 g / ha.
  • application rates of mixture of 1 to 1000 g / 100 kg of seed preferably 1 to 750 g / 100 kg, in particular 5 to 500 g / 100 kg, are generally used.
  • the use of the compounds I and (2) according to the invention in the process for combating harmful fungi is carried out by the separate or joint application of the compounds I and (2) or a mixture of the compounds I and (2) by spraying or dusting the seeds and the plants or the soil before or after sowing the plants or before or after emergence of the plants.
  • these can be converted into the customary formulations, e.g. Solutions, emulsions, suspensions, dusts, powders, pastes and granules.
  • the form of application depends on the respective purpose; in any case, it should ensure a fine and uniform distribution of the compounds I and (2).
  • the formulations are prepared in a known manner, e.g. by stretching the active ingredient with solvents and / or carriers, if desired using emulsifiers and dispersants.
  • solvents and auxiliaries The following are essentially considered as solvents / auxiliaries:
  • Aromade e.g. Solvesso products, XyIoI
  • paraffins e.g. petroleum fractions
  • alcohols e.g. methanol, butanol, pentanol, benzyl alcohol
  • ketones e.g. cyclohexanone, gamma-butryolactone
  • pyrrolidones NMP, NOP
  • acetates Glycol diacetate
  • glycols dimethyl fatty acid amides, fatty acids and fatty acid esters.
  • solvent mixtures can also be used
  • Carriers such as natural powdered rock (e.g. kaolins, clays, talc, chalk) and synthetic powdered rock (e.g. highly disperse silica, silicates); Emulsifiers such as nonionic and anionic emulsifiers (e.g. polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin sulfite liquors and methyl cellulose.
  • natural powdered rock e.g. kaolins, clays, talc, chalk
  • synthetic powdered rock e.g. highly disperse silica, silicates
  • Emulsifiers such as nonionic and anionic emulsifiers (e.g. polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin sulfite liquors and methyl cellulose
  • Suitable surfactants are alkali metal, alkaline earth metal salts, sulfonic acid ammonium salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde , Condensation products of Naphthalene or the naphthalene sulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ether, tribut
  • mineral oil fractions from medium to high boiling points such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons e.g. Toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, e.g. Dimethyl sulfoxide, N-methylpyrrolidone or water into consideration.
  • mineral oil fractions from medium to high boiling points such as kerosene or diesel oil
  • coal tar oils and oils of vegetable or animal origin aliphatic, cyclic and aromatic hydrocarbons e.g. Toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes
  • Powders, materials for broadcasting and dusts can be prepared by mixing or grinding the active substances together with a solid carrier.
  • Granules e.g. Coating, impregnation and homogeneous granules can be produced by binding the active ingredients to solid carriers.
  • Solid carriers are e.g. Mineral soils, such as silica gels, silicates, talc, kaolin, attack clay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics, fertilizers, e.g. Ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products, such as cereal flour, tree bark, wood and nutshell flour, cellulose powder and other solid carriers.
  • Mineral soils such as silica gels, silicates, talc, kaolin, attack clay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics
  • the formulations generally contain between 0.01 and 95% by weight, preferably between 0.1 and 90% by weight, of the active ingredients.
  • the active ingredients are used in a purity of 90% to 100%, preferably 95% to 100% (according to the NMR spectrum).
  • formulations are: 1. Products for dilution in water A) Water-soluble concentrates (SL)
  • active ingredients I and (2) 10 parts by weight of active ingredients I and (2) are dissolved with 90 parts by weight of water or a water-soluble solvent. Alternatively, wetting agents or other aids are added. The active ingredients dissolve when diluted in water. A formulation with an active substance content of 10% by weight is obtained in this way.
  • active ingredients I and (2) 15 parts by weight of active ingredients I and (2) are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (5 parts by weight each). Dilution in water results in an emulsion.
  • the formulation has an active substance content of 15% by weight.
  • 25 parts by weight of the active ingredients I and (2) are dissolved in 35 parts by weight of xylene with the addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (5 parts by weight in each case).
  • This mixture is added to 30 parts by weight of water using an emulsifying machine (e.g. Ultraturax) and brought to a homogeneous emulsion. Dilution in water results in an emulsion.
  • the formulation has an active ingredient content of 25% by weight.
  • the active substance content in the formulation is 20% by weight.
  • active ingredients I and (2) are finely ground with the addition of 50 parts by weight of dispersing and wetting agents and produced as technical equipment (e.g. extrusion, spray tower, fluidized bed) as water-dispersible or water-soluble granules. Dilution in water results in a stable dispersion or solution of the active ingredients.
  • the formulation has an active ingredient content of 50% by weight.
  • active ingredients I and (2) 75 parts by weight of active ingredients I and (2) are ground in a rotor-strator mill with the addition of 25 parts by weight of dispersing and wetting agents and silica gel. Dilution in water results in a stable dispersion or solution of the active ingredients.
  • the active substance content of the formulation is 75% by weight.
  • active ingredients I and (2) 10 parts by weight of active ingredients I and (2) are dissolved in 90 parts by weight of an organic solvent, e.g. XyIoI solved.
  • an organic solvent e.g. XyIoI solved.
  • the active ingredients as such, in the form of their formulations or the use forms prepared therefrom, e.g. in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dusts, sprinkling agents, granules by spraying, atomizing, dusting, scattering or pouring.
  • the forms of application depend entirely on the purposes of use; in any case, they should ensure the finest possible distribution of the active compounds according to the invention.
  • Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (wettable powders, oil dispersions) by adding water.
  • emulsions, pastes or oil dispersions the substances as such or dissolved in an oil or solvent can be homogenized in water by means of wetting agents, adhesives, dispersants or emulsifiers.
  • concentrates composed of an active substance, wetting agents, adhesives, dispersants or emulsifiers and possibly solvents or oil, which are suitable for dilution with water.
  • the active substance concentrations in the ready-to-use preparations can be varied over a wide range. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%.
  • the active ingredients can also be used with great success in the ultra-low-volume process (ULV), it being possible to apply formulations with more than 95% by weight of active ingredient or even the active ingredient without additives.
  • Various types of oils, wetting agents, adjuvants, and possibly only immediately before use (tank mix) can be added to the active ingredients.
  • These Agents are usually added to the agents according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1.
  • the compounds I and (2), the mixtures or the corresponding formulations are used by the harmful fungi, the plants, seeds, soils, surfaces, materials or spaces to be kept free of them with a fungicidally effective amount of the mixture, or the compounds I and (2) treated separately.
  • the application can take place before or after the infestation by the harmful fungi.
  • Soybean seeds were treated with an azole or azole with GA in the amounts indicated and sown.
  • the hypocotyl length was measured 9 days after sowing.
  • Soybean seeds were specified with an azole or azole with GA in the
  • the proportion of accumulated seeds was counted 8 days after sowing.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne (1) l'utilisation de gibberelline de formule (I) dans laquelle R est un atome d'hydrogène ou un groupe hydroxy, et la ligne pointillée signifie qu'à la place du cycle se trouve soit une simple liaison C-C, soit une double liaison C=C, en tant qu'agent de protection pour (2) au moins un azole choisi entre azaconazole, bitertanol, bromuconazole, cyproconazole, difénoconazole, diniconazole, énilconazole, époxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, triadiméfon, triadiménol, tébuconazole, tétraconazole, triticonazole, prochloraze, péfurazoate, imazalil, triflumizole, cyazofamide, bénomyl, carbendazime, thiabendazole, fubéridazole, éthaboxam, étridiazole, hymexazole, ou ses sels ou produits d'addition, pour lutter contre des champignons parasites. L'invention a également pour objet l'utilisation des composés de formule (I) et de (2) dans le cadre d'un procédé pour lutter contre des champignons parasites, avec des mélanges des composés de formule (I) et de (2), et l'utilisation des composés de formule (I) et de (2) pour préparer de tels mélanges, ainsi que des produits qui contiennent ces mélanges.
PCT/EP2006/069112 2005-12-09 2006-11-30 Utilisation de gibberelline comme agent de protection pour azoles afin de lutter contre des champignons parasites WO2007065843A2 (fr)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
DE102005059322 2005-12-09
DE102005059322.4 2005-12-09
EP06100789.4 2006-01-24
EP06100789 2006-01-24
EP06111313.0 2006-03-17
EP06111313 2006-03-17

Publications (2)

Publication Number Publication Date
WO2007065843A2 true WO2007065843A2 (fr) 2007-06-14
WO2007065843A3 WO2007065843A3 (fr) 2007-11-15

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AR (1) AR057229A1 (fr)
UY (1) UY29996A1 (fr)
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008095924A2 (fr) * 2007-02-06 2008-08-14 Basf Se Insecticides servant de phytoprotecteurs pour des fongicides à effet phytotoxique
WO2008155416A2 (fr) * 2007-06-20 2008-12-24 Basf Se Gibbérellines comme phytoprotecteurs de sécurité pour des fongicides présentant une activité phytotoxique
CN101755781A (zh) * 2010-01-05 2010-06-30 陕西美邦农资贸易有限公司 一种含戊菌唑与多菌灵的杀菌组合物
WO2010081646A3 (fr) * 2009-01-15 2010-11-25 Bayer Cropscience Aktiengesellschaft Associations de principes actifs fongicides
WO2014118129A1 (fr) * 2013-02-04 2014-08-07 Syngenta Participations Ag Procédé de phytoprotection
WO2014118127A1 (fr) * 2013-02-04 2014-08-07 Syngenta Participations Ag Composition de stéréoisomère du difénoconazole présentant une phytotoxicité réduite
WO2014118125A1 (fr) * 2013-02-04 2014-08-07 Syngenta Participations Ag Procédé de phytoprotection
WO2014118128A1 (fr) * 2013-02-04 2014-08-07 Syngenta Participations Ag Procédé de phytoprotection
CN104186484A (zh) * 2014-09-08 2014-12-10 赵伟 增效苯醚甲环唑可分散片剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2535332A1 (de) * 1975-08-07 1977-02-17 Bayer Ag Fungizide mittel
DE2734426A1 (de) * 1976-07-29 1978-02-16 Ici Ltd Zusammensetzung und verfahren zur bekaempfung von pilzen
US5665680A (en) * 1994-08-24 1997-09-09 Sumitomo Chemical Company, Limited Method for increasing yield of soybean by inhibition of gibberellin biosynthesis
WO2002069715A2 (fr) * 2001-03-06 2002-09-12 Bayer Cropscience Ag Agent desinfectant

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2535332A1 (de) * 1975-08-07 1977-02-17 Bayer Ag Fungizide mittel
DE2734426A1 (de) * 1976-07-29 1978-02-16 Ici Ltd Zusammensetzung und verfahren zur bekaempfung von pilzen
US5665680A (en) * 1994-08-24 1997-09-09 Sumitomo Chemical Company, Limited Method for increasing yield of soybean by inhibition of gibberellin biosynthesis
WO2002069715A2 (fr) * 2001-03-06 2002-09-12 Bayer Cropscience Ag Agent desinfectant

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008095924A3 (fr) * 2007-02-06 2009-05-07 Basf Se Insecticides servant de phytoprotecteurs pour des fongicides à effet phytotoxique
WO2008095924A2 (fr) * 2007-02-06 2008-08-14 Basf Se Insecticides servant de phytoprotecteurs pour des fongicides à effet phytotoxique
WO2008155416A2 (fr) * 2007-06-20 2008-12-24 Basf Se Gibbérellines comme phytoprotecteurs de sécurité pour des fongicides présentant une activité phytotoxique
WO2008155416A3 (fr) * 2007-06-20 2009-06-18 Basf Se Gibbérellines comme phytoprotecteurs de sécurité pour des fongicides présentant une activité phytotoxique
WO2010081646A3 (fr) * 2009-01-15 2010-11-25 Bayer Cropscience Aktiengesellschaft Associations de principes actifs fongicides
CN101755781B (zh) * 2010-01-05 2013-04-10 陕西美邦农资贸易有限公司 一种含戊菌唑与多菌灵的杀菌组合物
CN101755781A (zh) * 2010-01-05 2010-06-30 陕西美邦农资贸易有限公司 一种含戊菌唑与多菌灵的杀菌组合物
WO2014118129A1 (fr) * 2013-02-04 2014-08-07 Syngenta Participations Ag Procédé de phytoprotection
WO2014118127A1 (fr) * 2013-02-04 2014-08-07 Syngenta Participations Ag Composition de stéréoisomère du difénoconazole présentant une phytotoxicité réduite
WO2014118125A1 (fr) * 2013-02-04 2014-08-07 Syngenta Participations Ag Procédé de phytoprotection
WO2014118128A1 (fr) * 2013-02-04 2014-08-07 Syngenta Participations Ag Procédé de phytoprotection
US9462807B2 (en) 2013-02-04 2016-10-11 Syngenta Participations Ag Difenoconazole sterepospmeric composition with reduced phytotoxicity
CN104186484A (zh) * 2014-09-08 2014-12-10 赵伟 增效苯醚甲环唑可分散片剂及其制备方法

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WO2007065843A3 (fr) 2007-11-15
AR057229A1 (es) 2007-11-21

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