WO2013127859A1 - Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans du soja - Google Patents

Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans du soja Download PDF

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Publication number
WO2013127859A1
WO2013127859A1 PCT/EP2013/053940 EP2013053940W WO2013127859A1 WO 2013127859 A1 WO2013127859 A1 WO 2013127859A1 EP 2013053940 W EP2013053940 W EP 2013053940W WO 2013127859 A1 WO2013127859 A1 WO 2013127859A1
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Prior art keywords
inhibitors
plant
herb
fung
composition
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PCT/EP2013/053940
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English (en)
Inventor
Markus Gewehr
Cyrill Zagar
Scott Peoples
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Basf Se
Basf Schweiz Ag
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Publication of WO2013127859A1 publication Critical patent/WO2013127859A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action

Definitions

  • the present invention relates to the use of an agrochemical composition comprising at least one specific herbicide and at least one specific fungicide for controlling undesired vegetation in soybean cultures, for the desiccation and/or defoliation of soybeans, for controlling phytopathogenic fungi in soybeans and for increasing the health of soybean plants.
  • the invention further relates to a method for controlling undesired vegetation in soybean cultures, to a method for the desiccation and/or defoliation of soybean plants, to a method for controlling phytopathogenic fungi in soybeans and to a method for increasing the health of soybeans by using said composition.
  • the invention also relates to an agrochemical composition comprising said at least one specific herbicide and said at least one specific fungicide.
  • the active compounds act as antidotes or antagonists and are also referred to as safeners, since they reduce or even prevent damage to the crop plants.
  • Soybeans are among the most important crop plants. Improving their growth conditions is thus an ongoing need.
  • the present invention relates to the use of an agrochemical composition
  • an agrochemical composition comprising A) at least one herbicide A selected from
  • acetylCoA carboxylase inhibitors selected from clethodim (A.1 ), cycloxydim (A.2), fenoxaprop (A.3), fluazifop (A.4), fluazifop-P (A.5), haloxyfop (A.6), haloxyfop-P (A.7), quizalofop (A.8), quizalofop-P (A.9), sethoxydim (A.10) and tepraloxydim (A.1 1 );
  • ACC inhibitors selected from clethodim (A.1 ), cycloxydim (A.2), fenoxaprop (A.3), fluazifop (A.4), fluazifop-P (A.5), haloxyfop (A.6), haloxyfop-P (A.7), quizalofop (A.8), quizalofop-P (A.9), se
  • acetolactate synthase inhibitors selected from chlorimuron
  • auxinic herbicides selected from 2,4-D (A.23) and dicamba (A.24);
  • protoporphyrinogen oxidase (PPO) inhibitors selected from acifluorfen
  • HPPD inhibitors 4-hydroxyphenylpyruvate-dioxygenase selected from bi- cyclopyrone (A.37), isoxaflutole (A.38), mesotrione (A.39), sulcotrione (A.40), tembotrione (A.41 ) and topramezone (A.42); and their agriculturally acceptable salts, esters and amides; and
  • B.a) sterol biosynthesis inhibitors selected from cyproconazole (B-1 ) > difenoconazole (B.2), epoxiconazole (B.3), fenarimol (B.4), fenbu- conazole (B.5), fenpropimorph (B.6), fluqinconazole (B.7), flusilazole (B.8), flutriafol (B.9), imazalil (B.10), ipconazole (B.1 1 ), metconazole (B.12), my- clobutanil (B.13), prochloraz (B.14), propiconazole (B.15), prothioconazole (B.16), tebuconazole (B.17), tetraconazole (B.18), triadimefon (B.19) and triadimenol (B.20);
  • SBI fungicides selected from cyprocon
  • B.b nucleic acid synthesis inhibitors selected from benalaxyl (B.21 ), benalaxyl- M (B.22), kiralaxyl (B.23), metalaxyl (B.24) and metalaxyl-M (mefenoxam) (B.25);
  • B.c inhibitors of cell division and cytoskeleton selected from benomyl (B.26), carbendazim (B.27), metrafenone (B.28), pyriofenone (B.29), thiabendazole
  • B.d signal transduction inhibitors selected from fludioxonil (B.33), iprodione
  • inhibitors with Multi Site Action selected from
  • thio- and dithiocarbamates selected from mancozeb (B.41 ), maneb (B.42), metam (B.43), metiram (B.44), thiram (B.45), zineb (B.46) and ziram (B.47); and
  • captan B.48
  • chlorothalonil B.49
  • tolylfluanid B.50
  • B.f fungicides with an unknown mode of action selected from cymoxanil (B.51 ), quintozene (B.52), tebufloquin (B.53), tricyclazol (B.54) and 4-cyclopropyl- [1 ,2,3]thiadiazole-5-carboxylic acid (2,4-dimethoxy-phenyl)-amide (B.55); for controlling undesired vegetation in soybean cultures.
  • the term "soybean” denotes both the plant itself as well as its harvested product, such as soybean grains or seeds.
  • the invention moreover relates to a composition as defined above or below, comprising at least one herbicide A and at least one fungicide B.
  • composition according to the invention or to be used according to the invention may be a physical mixture of the at least one compound A and the at least one com- pound B. Accordingly, the invention also provides a mixture comprising at least one compound A and at least one compound B. However, the composition may also be any combination of at least one compound A with at least one compound B, it not being required for compounds A and B to be present together in the same formulation.
  • An example of a composition according to the invention or to be used according to the invention in which the at least one compound A and the at least one compound B are not present together in the same formulation is a combipack. In a combipack, two or more components of a combipack are packaged separately, i.e., not jointly pre- formulated.
  • combipacks include one or more separate containers such as vials, cans, bottles, pouches, bags or canisters, each container containing a separate component for an agrochemical composition.
  • a two-component combipack comprising a first component which in turn comprises at least one compound A, a liquid or solid carrier and, if appropriate, at least one surfactant and/or at least one customary auxiliary, and a second component which in turn comprises at least one compound B, a liquid or solid carrier and, if appropriate, at least one surfactant and/or at least one customary auxiliary. More details, e.g.
  • the invention furthermore relates to a method for controlling undesired vegetation in soybean cultures, which method comprises allowing an effective amount of an agrochemical composition as defined above or below to act on soybean plants or parts thereof and/or the environment where the soybean cultures grow or are to grow.
  • the soybeans might be resistant to one or more herbicides or to attack by insects owing to genetic engineering or breeding.
  • the invention relates moreover to the use of a composition as defined above or below, for the desiccation and/or defoliation of soybean plants, and to a method for the desiccation and/or defoliation of soybean plants, which method comprises treating soybean plants or parts thereof with an effective amount of an agrochemical composition as defined above or below.
  • compositions which, at a reduced total amount of active compounds applied, show improved activity against important harmful fungi, in particular for certain indications. It was a further object to provide for compositions that are useful for the control of specific pathogens in specific important crops that are often susceptible to the attack of pathogens.
  • the invention thus also refers to the use of a composition as defined above or below, for controlling phytopathogenic fungi in soybeans, and to a method for controlling phy- topathogenic fungi in soybeans, which method comprises treating the fungi, soybean plants or parts thereof, the locus where the soybean plants grow or are to grow or soy- bean seeds to be protected from fungal attack or soybean seeds from which the soybean plants are to grow with an effective amount of an agrochemical composition as defined above or below.
  • Healthier plants are desirable since they result among others in better yields and/or a better quality of the plants or crops. Healthier plants also better resist to biotic and/or abiotic stress. A high resistance against biotic stresses in turn allows the person skilled in the art to reduce the quantity of pesticides applied and consequently to slow down the development of resistances against the respective pesticides.
  • the present invention also relates to the use of a composition as defined above or below, for synergistically increasing the health of soybeans, in particular the yield of soybean plants, and to a method for synergistically increasing the health of soybeans, in particular the yield of soybean plants, which method comprises treating soybean plants or parts thereof, the locus where the soybean plants grow or are to grow or soybean seeds from which the soybean plants are to grow with a synergistical- ly effective amount of an agrochemical composition as defined above and below.
  • the methods of the invention comprise allowing an effective amount of the composition as defined above or below to act on soybean plants or parts thereof and/or the environment (e.g. the locus) where the soybean cultures grow or are to grow.
  • the methods of the invention include treatment of the seeds from which the soybean plants are to grow. If the soybean plants are not resistant against the herbicide(s) used and/or the herbicide(s) is/are not selective enough and/or no safener is used, it is convenient to avoid their direct contact with the herbicide(s) used as far as possible in order to avoid injury of the soybean plants (except, of course, for the desiccation and/or defoliation method).
  • any known method for broadcasting agricultural compositions can be used. For further details, see below.
  • the herbicides A and the fungicides B as well as their agrochemical action and methods for producing them are generally known.
  • the commercially available compounds can be found in "The Pesticide Manual, 15th Edition, British Crop Protection Council (2009)" among other publications.
  • the at least one herbicide A is selected from clethodim, cycloxydim, sethox- ydim, tepraloxydim, chlorimuron, cloransulam, imazamox, imazapic, imazapyr, ima- zethapyr, thifensulfuron, tribenuron, 2,4-D, dicamba, flumiclorac, flumioxazin, fluthiacet- methyl, fomesafen, lactofen, 1 ,5-dimethyl-6-thioxo-3-(2,2,7-trifluoro-3-oxo-4-(prop-2- ynyl)-3,4-dihydro-2H-benzo[b][1 ,4]oxazin-6-yl)-1 ,3,5-triazinane-2,4-d
  • chlorimuron chlorimuron-ethyl (A.43); cloransulam: cloransulam-methyl (A.44); imazamox: imazamox-ammonium (A.45); imazapic: imazapic-ammonium (A.46); imazapyr: imazapyr-isopropylammonium (A.47); imazethapyr: imazethapyr-ammonium (A.48); thifensulfuron: thifensulfuron-methyl (A.49); tribenuron: tribenuron-methyl (A.50);
  • 2,4-D 2,4-D-ammonium (A.51 ), 2,4-D-butotyl (A.52), 2,4-D-2-butoxypropyl (A.53), 2,4- D-3-butoxypropyl (A.54), 2,4-D-butyl (A.55), 2,4-D-diethylammonium (A.56), 2,4-D- dimethylammonium (A.57), 2,4-D-diolamine (A.58), 2,4-D-dodecylammonium (A.59), 2,4-D-ethyl (A.60), 2,4-D-2-ethylhexyl (A.61 ), 2,4-D-heptylammonium (A.62), 2,4-D- isobutyl (A.63), 2,4-D-isooctyl (A.64), 2,4-D-isopropyl (A.65), 2,4-D- isopropylammonium (
  • 2,4-D 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D- ethyl, 2,4-D-2-ethylhexyl, 2,4-D-isobutyl, 2,4-D-isooctyl, 2,4-D-isopropyl, 2,4-D- isopropylammonium, 2,4-D-sodium, 2,4-D-tris(isopropyl)ammonium, 2,4-D-trolamine, 2,4-D-(2-hydroxyethyl)trimethylammonium; dicamba: dicamba-butotyl, dicamba-diglycolamine, dicamba-dimethylammonium, dicamba-diolamine, dicamba-isopropylammonium, dicamba-potassium, dicamba- sodium, dicamba-trolamine, dic
  • the at least one herbicide A is more preferably selected from clethodim, cycloxydim, sethoxydim, tepraloxydim, chlorimuron, chlorimuron-ethyl, cloransulam, cloransulam- methyl, imazamox, imazamox-ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyr-isopropylammonium, imazethapyr, imazethapyr-ammonium, thifensulfuron, thifensulfuron-methyl, tribenuron, tribenuron-methyl, 2,4-D, 2,4-D-ammonium, 2,4-D- butotyl, 2,4-D-2-butoxypropyl, 2,4-D-3-butoxypropyl, 2,4-D-butyl, 2,4-D-diethylammonium, 2,4-D-dimethylammonium, 2,4-
  • the at least one herbicide A is selected from clethodim, cy- cloxydim, sethoxydim, tepraloxydim, imazamox, imazapic, imazapyr, imazethapyr, 2,4- D, dicamba, flumioxazin, 1 ,5-dimethyl-6-thioxo-3-(2,2,7-trifluoro-3-oxo-4-(prop-2-ynyl)- 3,4-dihydro-2H-benzo[b][1 ,4]oxazin-6-yl)-1 ,3,5-triazinane-2,4-dione (CAS 1258836-72- 4), bentazone, mesotrione, topramezone; and their agriculturally acceptable salts, esters and amides.
  • the at least one herbicide A is selected from clethodim, cy- cloxydim, sethoxydim, tepraloxydim, imazamox, imazamox-ammonium, imazapic, ima- zapic-ammonium, imazapyr, imazapyr-isopropylammonium, imazethapyr, imazethapyr- ammonium, 2,4-D, 2,4-D-ammonium, 2,4-D-butotyl, 2,4-D-2-butoxypropyl, 2,4-D-3- butoxypropyl, 2,4-D-butyl, 2,4-D-diethylammonium, 2,4-D-dimethylammonium, 2,4-D- diolamine, 2,4-D-dodecylammonium, 2,4-D-ethyl, 2,4-D-2-ethylhexyl, 2,4-D- hept
  • the at least one herbicide A is selected from clethodim, cycloxydim, sethoxydim, tepraloxydim, imazamox, imazamox-ammonium, imazapic, imazapic- ammonium, imazapyr, imazapyr-isopropylammonium, imazethapyr, imazethapyr- ammonium, 2,4-D, 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-dimethylammonium, 2,4-D- diolamine, 2,4-D-ethyl, 2,4-D-2-ethylhexyl, 2,4-D-isobutyl, 2,4-D-isooctyl, 2,4-D- isopropyl, 2,4-D-isopropylammonium, 2,4-D-sodium, 2,4-D-triisopropanolammonium,
  • the at least one herbicide A is clethodim and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is cycloxydim and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is sethoxydim and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is tepraloxydim and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazamox and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazapic and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazapyr and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazethapyr and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is 2,4-D and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is dicamba and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is flumioxazin and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is 1 ,5-dimethyl-6-thioxo- 3-(2,2,7-trifluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H-benzo[b][1 ,4]oxazin-6-yl)-1 ,3,5- triazinane-2,4-dione (CAS 1258836-72-4) and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is bentazone and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is mesotrione and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is topramezone and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one fungicide is selected from cyproconazole, epoxiconazole, fenpropimorph, flutriafol, metconazole, myclobutanil, propiconazole, tebuconazole, tetraconazole, carbendazim, metrafenone, thiophanate-methyl, fludioxonil, mancozeb, thiram, captan, chlorothalonil and 4-cyclopropyl-[1 ,2,3]thiadiazole-5-carboxylic acid (2,4-dimethoxy-phenyl)-amide.
  • the at least one fungicide is selected from cyproconazole, epoxiconazole, fenpropimorph, metconazole, carbendazim, metrafenone, thiophanate-methyl and thiram.
  • the at least one fungicide B is cyproconazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is epoxiconazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is fenpropimorph and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is metconazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is carbendazim and the at least one herbicide A has one of the above general or, in particular, one of the pre- ferred meanings.
  • the at least one fungicide B is metrafenone and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings. In another particular embodiment, the at least one fungicide B is thiophanate-methyl and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is thiram and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • composition to be used in the uses and the methods according to the invention comprises
  • herbicide A selected from clethodim, cycloxydim, sethoxydim, tepra- loxydim, imazamox, imazamox-ammonium, imazapic, imazapic-ammonium, ima- zapyr, imazapyr-isopropylammonium, imazethapyr, imazethapyr-ammonium, 2,4- D, 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D- ethyl, 2,4-D-2-ethylhexyl, 2,4-D-isobutyl, 2,4-D-isooctyl, 2,4-D-isopropyl, 2,4-D- isopropylammonium, 2,4-D-sodium, 2,4-D-triisopropanolammonium, 2,4-
  • At least one fungicide B selected from cyproconazole, epoxiconazole, fenpropi- morph, metconazole, carbendazim, metrafenone, thiophanate-methyl and thiram.
  • the composition comprises as component A at least one, preferably exactly one, herbicide A.
  • the composition compris- es as component A at least two, preferably exactly two, herbicides A different from each other.
  • the composition comprises as component A at least three, preferably exactly three, herbicides A different from each other.
  • the composition comprises as component B at least one, preferably exactly one, fungicide B.
  • the composition comprises as component B at least two, preferably exactly two, fungicides B different from each other.
  • the composition comprises as component A at least one, preferably exactly one, herbicide A, and at least one, preferably exactly one, fungicide B.
  • the composition comprises as component A at least two, preferably exactly two, herbicides A different from each other, and at least one, preferably exactly one, fungicide B.
  • the composition comprises as component A at least three, preferably exactly three, herbicides A different from each other, and at least one, preferably exactly one, fungicide B.
  • the composition comprises as only active components at least one, preferably exactly one, herbicide A, and at least one, preferably exactly one, fungicide B.
  • compositions 1 .1 to 1 .5170 comprising at least one herbicide A and at least one fungicide B, preferably comprising the herbicide A and the fungicide B, as defined in the respective row of table 1 .
  • the compound numbers (A.x for herbicide A; B.x for fungicide B) correspond to the compound numbers given above in the list of herbicides A and fungicides B to be used according to the present invention.
  • Table 1 compositions 1 .1. to 1 .5170
  • A.6 B.6 1.319 A.6 B.44 1.357 A.7 B.27
  • A.6 B.9 1.322 A.6 B.47 1.360 A.7 B.30
  • A.6 B.12 1.325 A.6 B.50 1.363 A.7 B.33
  • A.6 B.24 1.337 A.7 B.7 1.375 A.7 B.45
  • A.29 B.1 1.1579 A.29 B.39 1.1617 A.30 B.22
  • A.29 B.3 1.1581 A.29 B.41 1.1619 A.30 B.24
  • A.34 B.50 1.1903 A.35 B.33 1.1941 A.36 B.16
  • A.35 B.1 1.1909 A.35 B.39 1.1947 A.36 B.22

Abstract

La présente invention concerne l'utilisation d'une composition agrochimique comprenant au moins un herbicide spécifique et au moins un fongicide spécifique permettant de lutter contre les végétaux non souhaités dans les cultures de soja, contre le dessèchement et/ou la défoliation du soja, permettant de lutter contre les champignons phytopathogènes dans le soja et d'améliorer la santé des plants de soja. L'invention concerne en outre un procédé permettant de lutter contre les plantes non souhaitées dans les cultures de soja, un procédé contre le dessèchement et/ou la défoliation des plants de soja, un procédé permettant de lutter contre les champignons phythopathogènes dans le soja et un procédé permettant d'améliorer la santé du soja par l'utilisation de ladite composition. L'invention concerne également une composition agrochimique comprenant au moins ledit herbicide spécifique et au moins ledit fongicide spécifique.
PCT/EP2013/053940 2012-03-01 2013-02-27 Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans du soja WO2013127859A1 (fr)

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CN104709982A (zh) * 2013-12-11 2015-06-17 中国石油化工股份有限公司 一种低磷水处理剂组合物及其应用
CN110604135A (zh) * 2019-09-23 2019-12-24 中国农业科学院草原研究所 一种适用于东北苜蓿地的复配型除草剂
US11197479B2 (en) 2018-08-23 2021-12-14 Globachem Nv Use of silthiofam for the treatment of soybean rust

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US11197479B2 (en) 2018-08-23 2021-12-14 Globachem Nv Use of silthiofam for the treatment of soybean rust
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