WO2014033240A1 - Utilisation d'une composition agrochimique à effet fongicide, herbicide et améliorant la phytoprotection dans le riz - Google Patents

Utilisation d'une composition agrochimique à effet fongicide, herbicide et améliorant la phytoprotection dans le riz Download PDF

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Publication number
WO2014033240A1
WO2014033240A1 PCT/EP2013/067957 EP2013067957W WO2014033240A1 WO 2014033240 A1 WO2014033240 A1 WO 2014033240A1 EP 2013067957 W EP2013067957 W EP 2013067957W WO 2014033240 A1 WO2014033240 A1 WO 2014033240A1
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Prior art keywords
fung
herb
inhibitors
rice
herbicide
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PCT/EP2013/067957
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English (en)
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Markus Gewehr
Cyrill Zagar
Scott Peoples
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Basf Se
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Publication of WO2014033240A1 publication Critical patent/WO2014033240A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14—Di-thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A01N59/20—Copper

Definitions

  • the present invention relates to the use of an agrochemical composition comprising at least one specific herbicide and at least one specific fungicide for controlling undesired vegetation in rice cultures, for the desiccation and/or defoliation of rice, for controlling phytopathogenic fungi in rice and for increasing the health of rice plants.
  • the invention further relates to a method for controlling undesired vegetation in rice cultures, to a method for the desiccation and/or defoliation of rice plants, to a method for controlling phytopathogenic fungi in rice and to a method for increasing the health of rice by using said composition.
  • the invention also relates to an agrochemical composition comprising said at least one specific herbicide and said at least one specific fungicide.
  • this composition has better herbicidal activity, i.e. a better activity against harmful plants, than would have been expected based on the herbicidal activity observed for the individual compounds, or a broader activity spectrum.
  • the time frame, within which the desired herbicidal action can be achieved may be expanded by said composition. This allows a more flexibly timed application of the compositions according to the present invention in comparison with the single compounds.
  • composition also has a better compatibility with useful plants. Accordingly, the present invention relates to the use of an agrochemical composition comprising
  • acetylCoA carboxylase inhibitors selected from alloxydim (A.1 ), butroxydim (A.2), clethodim (A.3), clodinafop (A.4), cycloxydim (A.5), cyhalofop (A.6), diclofop (A.7), fenoxaprop (A.8), fenoxaprop-P (A.9), fluazi- fop (A.10), fluazifop-P (A.1 1 ), haloxyfop (A.12), haloxyfop-P (A.13), met- amifop (A.14), pinoxaden (A.15), profoxydim (A.16), propaquizafop (A.17), quizalofop (A.18), quizalofop-P (A.19), sethoxydim (A.20), tepraloxydim
  • ACC inhibitors selected from alloxy
  • acetolactate synthase inhibitors selected from azimsulfuron (A.23), bensulfuron-methyl (A.24), bispyribac (A.25), clorimuron-ethyl
  • A.26 cinosulfuron (A.27), cyclosulfamuron (A.28), ethoxysulfuron (A.29), flucetosulfuron (A.30), halosulfuron-methyl (A.31 ), imazamox (A.32), ima- zapic (A.33), imazethapyr (A.34), imazapyr (A.35), imazosulfuron (A.36), metazosulfuron (A.37), metsulfuron-methyl (A.38), orthosulfamuron (A.39), penoxsulam (A.40), propyrisulfuron (A.41 ), pyrazosulfuron-ethyl (A.42), py- ribenzoxim (A.43), pyriftalid (A.44), pyriminobac-methyl (A.45), pyrimisulfan (A.46) and triafamone (A.47);
  • photosynthetic electron transport inhibitors at the photosystem II receptor site selected from bentazone (A.55), dimethametryn (A.56), prometryn
  • VLCFA inhibitors selected from acetochlor (A.60), anilofos (A.61 ), butachlor (A.62), cafen- strole (A.63), fenoxasulfone (A.64), fentrazamide (A.65), ipfencarbazone (A.66), mefenacet (A.67), pretilachlor (A.68), metolachlor (A.69), S- metolachlor (A.70), naproanilide (A.71 ) and piperophos (A.72); A.f) bleacher herbicides selected from benzobicyclon (A.73), benzofenap
  • PPO protoporphyrinogen-IX-oxidase
  • sterol biosynthesis inhibitors selected from
  • C14 demethylase inhibitors selected from bromuconazole (B-1 ) > cyproconazole (B.2), difenoconazole (B.3), diniconazole (B.4), dini- conazole-M (B.5), epoxiconazole (B.6), fenbuconazole (B.7), flusilazole (B.8), flutriafol (B.9), hexaconazole (B.10), ipconazole (B.1 1 ), metconazole (B.12), myclobutanil (B.13), propiconazole (B.14), prothioconazole (B.15), simeconazole (B.16), tebuconazole (B.17), tetraconazole (B.18), triadime- fon (B.19), triticonazole (B.20), pefurazoate (B.21 )
  • B.24 the delta14-reductase inhibitor tridemorph (B.24); B.b) nucleic acid synthesis inhibitors selected from benalaxyl (B.25), benalaxyl- M (B.26), kiralaxyl (B.27), metalaxyl (B.28), metalaxyl-M (mefenoxam) (B.29), ofurace (B.30), oxadixyl (B.31 ) and hymexazole (B.32);
  • B.c inhibitors of cell division and cytoskeleton selected from benomyl (B.33), carbendazim (B.34), thiabendazole (B.35), thiophanate-methyl (B.36) and pencycuron (B.37);
  • inhibitors of amino acid and protein synthesis selected from the protein synthesis inhibitors kasugamycin (B.38), kasugamycin hydrochloride-hydrate (B.39), polyoxine (B.40) and validamycin A (B.41 );
  • B.e signal transduction inhibitors selected from the MAP / histidine kinase inhibitors iprodione (B.42), fenpiclonil (B.43) and fludioxonil (B44.);
  • phospholipid biosynthesis inhibitors selected from edifenphos (B.45), ipro- benfos (B.46) and isoprothiolane (B.47);
  • inhibitors with Multi Site Action selected from
  • inorganic active substances selected from Bordeaux mixture (B.52), copper acetate (B.53), copper hydroxide (B.54), copper oxychloride (B.55), copper sulfate (B.56), copper sulfate pentahydrate (B.57), basic copper sulfate (B.58), oxine-copper (B.59), copper-7-oxyquinolate (B.60), copper- ammonium-complex (B.61 ), copper carbonate (B.62), copper chloride (B.63) and sulfur (B.64);
  • thio- and dithiocarbamates selected from ferbam (B.65), mancozeb (B.66), maneb (B.67), metam (B.68), metiram (B.69), propineb (B.70), thiram (B.71 ), zineb (B.72) and ziram (B.73);
  • organochlorine compounds selected from chlorothalonil (B.74), captan (B.75), folpet (B.76), and phthalide (B.77); and
  • B.h cell wall synthesis inhibitors selected from validamycin (B.83), polyoxin B (B.84), pyroquilon (B.85), tricyclazole (B.86), carpropamid (B.87), fenoxanil
  • B.i) plant defence inducers selected from acibenzolar-S-methyl (B.90), pro- benazole (B.91 ), isotianil (B.92), tiadinil (B.93), fosetyl (B.94) and fosetyl- aluminum (B.95); and B.j) fungicides with an unknown mode of action selected from cymoxanil (B.96), tebufloquin (B.97) and 4,4-difluoro-3,3-dimethyl-1 -(3-quinolyl)isoquinoline (B.98); for controlling undesired vegetation in rice cultures.
  • the term "rice” denotes both the plant itself as well as its harvested product, such rice grains or seeds.
  • the invention moreover relates to a composition as defined above or below, comprising at least one herbicide A and at least one fungicide B.
  • composition according to the invention or to be used according to the invention may be a physical mixture of the at least one compound A and the at least one com- pound B. Accordingly, the invention also provides a mixture comprising at least one compound A and at least one compound B. However, the composition may also be any combination of at least one compound A with at least one compound B, it not being required for compounds A and B to be present together in the same formulation.
  • An example of a composition according to the invention or to be used according to the invention in which the at least one compound A and the at least one compound B are not present together in the same formulation is a combipack. In a combipack, two or more components of a combipack are packaged separately, i.e., not jointly pre- formulated.
  • combipacks include one or more separate containers such as vials, cans, bottles, pouches, bags or canisters, each container containing a separate component for an agrochemical composition.
  • a two-component combipack comprising a first component which in turn comprises at least one compound A, a liquid or solid carrier and, if appropriate, at least one surfactant and/or at least one customary auxiliary, and a second component which in turn comprises at least one compound B, a liquid or solid carrier and, if appropriate, at least one surfactant and/or at least one customary auxiliary. More details, e.g.
  • the invention furthermore relates to a method for controlling undesired vegetation in rice cultures, which method comprises allowing an effective amount of an agrochemical composition as defined above or below to act on rice plants or parts thereof and/or the environment where the rice cultures grow or are to grow.
  • the rice might be resistant to one or more herbicides or to attack by insects owing to genetic engineering or breeding.
  • the invention relates moreover to the use of a composition as defined above or below, for the desiccation and/or defoliation of rice plants, and to a method for the desiccation and/or defoliation of rice plants, which method comprises treating rice plants or parts thereof with an effective amount of an agrochemical composition as defined above or below.
  • compositions which, at a reduced total amount of active compounds applied, show improved activity against important harmful fungi, in particular for certain indications. It was a further object to provide for compositions that are useful for the control of specific pathogens in specific important crops that are often susceptible to the attack of pathogens.
  • the invention thus also refers to the use of a composition as defined above or below, for controlling phytopathogenic fungi in rice, and to a method for controlling phytopath- ogenic fungi in rice, which method comprises treating the fungi, rice plants or parts thereof, the locus where the rice plants grow or are to grow or rice seeds to be protect- ed from fungal attack or rice seeds from which the rice plants are to grow with an effective amount of an agrochemical composition as defined above or below.
  • Healthier plants are desirable since they result among others in better yields and/or a better quality of the plants or crops. Healthier plants also better resist to biotic and/or abiotic stress. A high resistance against biotic stresses in turn allows the person skilled in the art to reduce the quantity of pesticides applied and consequently to slow down the development of resistances against the respective pesticides. It was therefore also an object of the present invention to provide an agrochemical composition which solves the problems outlined above, and which should, in particular, improve the health of rice plants, in particular the yield and/or quality of rice plants.
  • the present invention also relates to the use of a composition as defined above or below, for synergistically increasing the health of rice, in particular the yield of rice plants, and to a method for synergistically increasing the health of rice, in particular the yield of rice plants, which method comprises treating rice plants or parts thereof, the locus where the rice plants grow or are to grow or rice seeds from which the rice plants are to grow with a synergistically effective amount of an agrochemical composition as defined above and below.
  • the methods of the invention comprise allowing an effective amount of the composition as defined above or below to act on rice plants or parts thereof and/or the environment (e.g. the locus) where the rice cultures grow or are to grow.
  • the methods of the invention include treatment of the seeds from which the rice plants are to grow. If the rice plants are not resistant against the herbicide(s) used and/or the herbicide(s) is/are not selective enough and/or no safener is used, it is convenient to avoid their direct contact with the herbicide(s) used as far as possible in order to avoid injury of the rice plants (except, of course, for the desiccation and/or defoliation method).
  • any known method for broadcasting agricultural compositions can be used. For further details, see below.
  • the herbicides A and the fungicides B as well as their agrochemical action and methods for producing them are generally known.
  • the commercially available compounds can be found in "The Pesticide Manual, 15th Edition, British Crop Protection Council (2009)" among other publications.
  • the at least one herbicide A is selected from clethodim, cycloxydim, cyhalo- fop, fenoxaprop, fenoxaprop-P, fluazifop, fluazifop-P, haloxyfop, haloxyfop-P, met- amifop, pinoxaden, profoxydim, propaquizafop, quizalofop, quizalofop-P, sethoxydim, tepraloxydim, bensulfuron-methyl, bispyribac, cyclosulfamuron, flucetosulfuron, ima- zamox, Imazapic, imazethapyr, imazapyr, imazosulfuron, metazosulfuron, metsulfuron- methyl, penoxsulam, propyrisulfuron, pyrazosulfuron-ethyl, pyribenzoxim, pyrimisulfan
  • cyhalofop cyhalofop-butyl (A.93); fenoxaprop-P: fenoxaprop-P-ethyl (A.94); fluazifop-P: fluazifop-P-butyl (A.95), fluazifop-P-methyl (A.96); haloxyfop-P: haloxyfop-P-etotyl (A.97), haloxyfop-P-methyl (A.98), haloxyfop-P-sodium (A.99); quizalofop: quizalofop-methyl (A.100), quizalofop-tefuryl (A.101 ); quizalafop-P: quizalafop-P-methyl (A.102), quizalafop-P-ethyl (A.93); fenoxaprop-P: fenoxaprop-P-ethyl (A.94);
  • 2,4-D 2,4-D-ammonium (A.1 17), 2,4-D-butotyl (A.1 18), 2,4-D-2-butoxypropyl (A.1 19), 2,4-D-3-butoxypropyl (A.120), 2,4-D-butyl (A.121 ), 2,4-D-diethylammonium (A.122), 2,4-D-dimethylammonium (A.123), 2,4-D-diolamine (A.124), 2,4-D-dodecylammonium (A.125), 2,4-D-ethyl (A.126), 2,4-D-2-ethylhexyl (A.127), 2,4-D-heptylammonium (A.128), 2,4-D-isobutyl (A.129), 2,4-D-isooctyl (A.130), 2,4-D-isopropyl (A.131 ), 2,4-D- isopropy
  • esters and amides of 2,4-D more preference is given to following salts and esters:
  • 2,4-D 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D- ethyl, 2,4-D-2-ethylhexyl, 2,4-D-isobutyl, 2,4-D-isooctyl, 2,4-D-isopropyl, 2,4-D- isopropylammonium, 2,4-D-sodium, 2,4-D-tris(isopropyl)ammonium, 2,4-D-trolamine, 2,4-D-(2-hydroxyethyl)trimethylammonium;
  • the at least one herbicide A is more preferably selected from clethodim, cycloxydim, cyhalofop, cyhalofop-butyl, fenoxaprop, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-P, fluazifop-P-butyl, fluazifop-P-methyl, haloxyfop, haloxyfop-P, haloxyfop-P- etotyl, haloxyfop-P-methyl, haloxyfop-P-sodium, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop, quizalofop-methyl, quizalofop-tefuryl, quizalofop-P, quizalafop-P-methyl, quizalafop-ethyl,
  • the at least one herbicide A is selected from cycloxydim, cyhalo- fop, fenoxaprop-P, fluazifop-P, haloxyfop-P, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop-P, sethoxydim, tepraloxydim, bensulfuron-methyl, bispyri- bac, cyclosulfamuron, imazamox, imazapic, imazethapyr, imazosulfuron, penoxsulam, quinclorac, bentazone, propanil, tefuryltrione, 1 ,5-dimethyl-6-thioxo-3-(2,2,7-trifluoro-3- oxo-4-(prop-2-ynyl)-3,4-dihydro-2H-benzo[b][1 ,4]oxazin-6-yl)
  • the at least one herbicide A is selected from cycloxydim, cyhalo- fop, cyhalofop-butyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop-P, fluazifop-P-butyl, fluazifop-P-methyl, haloxyfop-P, haloxyfop-P-etotyl, haloxyfop-P-methyl, haloxyfop-P- sodium, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop-P, quizalafop-P- methyl, quizalafop-P-ethyl, quizalafop-P-tefuryl, sethoxydim, tepraloxydim, bensulfuron- methyl, bispyribac, bispyribac-sodium
  • the at least one herbicide A is cyhalofop and the at least one fungicide B has one of the above general or, in particular, one of the below pre- ferred meanings.
  • the at least one herbicide A is cyhalofop-butyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is fenoxaprop-P and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is fenoxaprop-P-ethyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is fluazifop-P and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is fluazifop-P-butyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is fluazifop-P-methyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is haloxyfop-P and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is haloxyfop-P-etotyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is haloxyfop-P-methyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is haloxyfop-P-sodium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is metamifop and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is pinoxaden and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is profoxydim and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is propaquizafop and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is quizalofop-P and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is quizalafop-P-methyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is quizalafop-P-ethyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is quizalafop-P-tefuryl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is sethoxydim and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is tepraloxydim and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is bensulfuron-methyl and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is bispyribac and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is bispyribac-sodium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is cyclosulfamuron and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazamox and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazamox-ammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazapic and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazapic-ammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazapic- isopropylammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazethapyr and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazethapyr- ammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazethapyr- isopropylammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is imazosulfuron and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is penoxsulam and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is quinclorac and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is quinclorac- dimethylammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is quinclorac-sodium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is quinclorac- triethylammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is bentazone and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is bentazone- diethanolammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is bentazone- dimethylammonium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is bentazone-sodium and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is propanil and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is tefuryltrione and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is 1 ,5-dimethyl-6-thioxo- 3-(2,2,7-trifluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H-benzo[b][1 ,4]oxazin-6-yl)-1 ,3,5- triazinane-2,4-dione (CAS 1258836-72-4) and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is pentoxazone and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is pyraclonild and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one herbicide A is saflufenacil and the at least one fungicide B has one of the above general or, in particular, one of the below preferred meanings.
  • the at least one fungicide is selected from
  • sterol biosynthesis inhibitors selected from
  • C14 demethylase inhibitors selected from difenoconazole, epox- iconazole, flusilazole, hexaconazole, metconazole, propiconazole, prothio- conazole, tebuconazole, triadimefon, triticonazole, prochloraz and triflumizol; and the delta14-reductase inhibitor tridemorph;
  • nucleic acid synthesis inhibitors selected from metalaxyl, metalaxyl-M (mefenox- am) and hymexazole;
  • B.c inhibitors of cell division and cytoskeleton selected from benomyl, carbendazim, thiabendazole, thiophanate-methyl and pencycuron;
  • B.d) inhibitors of amino acid and protein synthesis selected from the protein synthesis inhibitors kasugamycin, kasugamycin hydrochloride-hydrate and validamycin A;
  • lipid and membrane synthesis inhibitors selected from phospholipid biosynthesis inhibitors selected from edifenphos, iprobenfos and isoprothiolane;
  • inhibitors with Multi Site Action selected from
  • inorganic active substances selected from copper sulfate, copper sulfate pen- tahydrate, basic copper sulfate and sulfur;
  • thio- and dithiocarbamates selected from mancozeb and metiram; and organochlorine compounds selected from chlorothalonil and phthalide;
  • B.h cell wall synthesis inhibitors selected from validamycin, pyroquilon, tricyclazole, carpropamid, fenoxanil and diclocymet;
  • the at least one fungicide is selected from difenoconazole, epoxicona- zole, hexaconazole, metconazole, propiconazole, prothioconazole, tebuconazole, pro- chloraz, tridemorph, hymexazole, benomyl, carbendazim, thiabendazole, thiophanate- methyl, pencycuron, kasugamycin, kasugamycin hydrochloride-hydrate, iprodione, iso- prothiolane, copper sulfate, copper sulfate pentahydrate, basic copper sulfate, sulfur, mancozeb, metiram, chlorothalonil, validamycin, pyroquilon, tricyclazole, probenazole, isotianil, tebufloquin and 4,4-difluoro-3,3-dimethyl-1 -(3-quinolyl)is
  • the at least one fungicide is selected from epoxiconazole, metconazole, propiconazole, prothioconazole, tebuconazole, prochloraz, tridemorph, carbendazim, thiabendazole, thiophanate-methyl, iprodione, isoprothiolane, copper sulfate, copper sulfate pentahydrate, basic copper sulfate, sulfur, mancozeb, metiram, tricyclazole, probenazole and isotianil.
  • the at least one fungicide B is epoxiconazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is metconazole and the at least one herbicide A has one of the above general or, in particular, one of the pre- ferred meanings.
  • the at least one fungicide B is propiconazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings. In another particular embodiment, the at least one fungicide B is prothioconazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is tebuconazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is prochloraz and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is tridemorph and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is carbendazim and the at least one herbicide A has one of the above general or, in particular, one of the pre- ferred meanings.
  • the at least one fungicide B is thiabendazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is thiophanate-methyl and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is iprodione and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is isoprothiolane and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is copper sulfate and the at least one herbicide A has one of the above general or, in particular, one of the pre- ferred meanings.
  • the at least one fungicide B is copper sulfate pen- tahydrate and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is basic copper sulfate and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is sulfur and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings. In another particular embodiment, the at least one fungicide B is mancozeb and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is metiram and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is tricyclazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is probenazole and the at least one herbicide A has one of the above general or, in particular, one of the preferred meanings.
  • the at least one fungicide B is isotianil and the at least one herbicide A has one of the above general or, in particular, one of the pre- ferred meanings.
  • composition to be used in the uses and the methods according to the invention comprises
  • the composition comprises as component A at least one, preferably exactly one, herbicide A.
  • the composition comprises as component A at least two, preferably exactly two, herbicides A different from each other.
  • the composition comprises as component A at least three, preferably exactly three, herbicides A different from each other.
  • the composition comprises as component B at least one, preferably exactly one, fungicide B.
  • the composition comprises as component B at least two, preferably exactly two, fungicides B different from each other.
  • the composition comprises as component A at least one, preferably exactly one, herbicide A, and at least one, preferably exactly one, fungicide B.
  • the composition compris- es as component A at least two, preferably exactly two, herbicides A different from each other, and at least one, preferably exactly one, fungicide B.
  • the composition comprises as component A at least three, preferably exactly three, herbicides A different from each other, and at least one, preferably exactly one, fungicide B.
  • the composition comprises as only active components at least one, preferably exactly one, herbicide A, and at least one, preferably exactly one, fungicide B.
  • Particularly preferred are the compositions 1 .1 to 1 .14308, comprising at least one herbicide A and at least one fungicide B, preferably comprising the herbicide A and the fungicide B, as defined in the respective row of table 1 .
  • the compound numbers (A.x for herbicide A; B.x for fungicide B) correspond to the compound numbers given above in the list of herbicides A and fungicides B to be used according to the present inven- tion.
  • Table 1 compositions 1 .1. to 1 .14308 herb. fung. No herb. fung. No herb. fung.
  • A.2 B.54 1.190 A.2 B.92 1.228 A.3 B.32 herb. fung. No herb. fung. No herb. fung.
  • A.4 B.58 1.390 A.4 B.96 1.428 A.5 B.36
  • A.6 B.2 1.530 A.6 B.40 1.568 A.6 B.78
  • A.10 B.42 1.962 A.10 B.80 1.1000 A.11 B.20

Abstract

La présente invention concerne l'utilisation d'une composition agrochimique comprenant au moins un herbicide spécifique et au moins un fongicide spécifique pour lutter contre la végétation indésirable dans les rizières, pour la dessiccation et/ou la défoliation du riz, pour lutter contre les champignons phytopathogènes dans le riz et pour améliorer la santé des plants de riz. L'invention concerne en outre un procédé de lutte contre la végétation indésirable dans les rizières, un procédé de dessiccation et/ou de défoliation de plants de riz, un procédé de lutte contre les champignons phytopathogènes dans le riz et un procédé d'amélioration de la santé du riz à l'aide de ladite composition. L'invention concerne également une composition agrochimique comprenant ledit au moins un herbicide spécifique et ledit au moins un fongicide spécifique.
PCT/EP2013/067957 2012-08-31 2013-08-30 Utilisation d'une composition agrochimique à effet fongicide, herbicide et améliorant la phytoprotection dans le riz WO2014033240A1 (fr)

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CN104255728A (zh) * 2014-03-29 2015-01-07 潍坊先达化工有限公司 2,4-二氯苯氧丁酸及其衍生物的应用
CN104542642A (zh) * 2014-12-24 2015-04-29 广东中迅农科股份有限公司 含有灭草松和唑草酮以及五氟磺草胺的除草组合物
CN105532676A (zh) * 2016-02-06 2016-05-04 江苏省农用激素工程技术研究中心有限公司 用于防治油菜田杂草的除草组合物
CN106070249A (zh) * 2016-06-01 2016-11-09 浙江天丰生物科学有限公司 一种水稻田用除草组合物
CN106386825A (zh) * 2016-08-26 2017-02-15 安徽美兰农业发展股份有限公司 一种五氟磺草胺和丙炔噁草酮复配可分散油悬浮剂及其制备方法
CN107232193A (zh) * 2017-07-28 2017-10-10 安徽省圣丹生物化工有限公司 一种稻田除草剂及其制备方法
CN108496971A (zh) * 2018-06-08 2018-09-07 佛山市普尔玛农化有限公司 一种含有苯嘧磺草胺和氟酮磺草胺的除草剂
CN110402923A (zh) * 2019-08-16 2019-11-05 山西农业大学 唑啉草酯水乳剂及其制备方法和应用

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CN104255728A (zh) * 2014-03-29 2015-01-07 潍坊先达化工有限公司 2,4-二氯苯氧丁酸及其衍生物的应用
CN104542642A (zh) * 2014-12-24 2015-04-29 广东中迅农科股份有限公司 含有灭草松和唑草酮以及五氟磺草胺的除草组合物
CN105532676A (zh) * 2016-02-06 2016-05-04 江苏省农用激素工程技术研究中心有限公司 用于防治油菜田杂草的除草组合物
CN106070249A (zh) * 2016-06-01 2016-11-09 浙江天丰生物科学有限公司 一种水稻田用除草组合物
CN106386825A (zh) * 2016-08-26 2017-02-15 安徽美兰农业发展股份有限公司 一种五氟磺草胺和丙炔噁草酮复配可分散油悬浮剂及其制备方法
CN107232193A (zh) * 2017-07-28 2017-10-10 安徽省圣丹生物化工有限公司 一种稻田除草剂及其制备方法
CN108496971A (zh) * 2018-06-08 2018-09-07 佛山市普尔玛农化有限公司 一种含有苯嘧磺草胺和氟酮磺草胺的除草剂
CN110402923A (zh) * 2019-08-16 2019-11-05 山西农业大学 唑啉草酯水乳剂及其制备方法和应用

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