WO2010062138A2 - Composition for the oxidative dyeing containing natural materials - Google Patents
Composition for the oxidative dyeing containing natural materials Download PDFInfo
- Publication number
- WO2010062138A2 WO2010062138A2 PCT/KR2009/007044 KR2009007044W WO2010062138A2 WO 2010062138 A2 WO2010062138 A2 WO 2010062138A2 KR 2009007044 W KR2009007044 W KR 2009007044W WO 2010062138 A2 WO2010062138 A2 WO 2010062138A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- agent
- hairdye
- composition
- hair
- polysaccharide
- Prior art date
Links
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- 229920001282 polysaccharide Polymers 0.000 claims abstract description 85
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- 229920000831 ionic polymer Polymers 0.000 description 1
- 239000009313 kushen Substances 0.000 description 1
- 201000002364 leukopenia Diseases 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- 230000027939 micturition Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000004165 myocardium Anatomy 0.000 description 1
- PETZRPLPRZXTAD-UHFFFAOYSA-N n-(4-aminophenyl)nitramide;hydrochloride Chemical compound Cl.NC1=CC=C(N[N+]([O-])=O)C=C1 PETZRPLPRZXTAD-UHFFFAOYSA-N 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 230000000144 pharmacologic effect Effects 0.000 description 1
- 229960003893 phenacetin Drugs 0.000 description 1
- QXYMVUZOGFVPGH-UHFFFAOYSA-N picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- RBWOKKSOBWYZQH-UHFFFAOYSA-N s-octyl benzenecarbothioate Chemical compound CCCCCCCCSC(=O)C1=CC=CC=C1 RBWOKKSOBWYZQH-UHFFFAOYSA-N 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 230000002936 tranquilizing effect Effects 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9755—Gymnosperms [Coniferophyta]
- A61K8/9761—Cupressaceae [Cypress family], e.g. juniper or cypress
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/75—Anti-irritant
Definitions
- the present invention relates to a composition for oxidative dyeing of keratin fibers, more particularly to a composition for oxidative dyeing of keratin fibers containing one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
- natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
- the hairdyes are categorized into permanent hairdye, semipermanent hairdye, temporary hairdyes and other hairdyes depending on how long the color persists.
- the permanent hairdye is generally an oxidative hairdye , which color is produced by an oxidation reaction of an oxidative dye.
- the semipermanent hairdye uses a non- oxidative, acidic or basic dye to dye hair.
- the temporary hairdye gives temporary coloring effect by adhering pigments, pearls, or the like to hair surface using a film- forming agent.
- Other hairdyes include those using natural plant dyes such as henna, indigo, chamomile, etc., metallic hairdyes which dye hair through oxidation with silver nitrate or lead acetate, or the like.
- an oxidative hairdye contains a first agent(dye phase) and a second agent(Developer).
- the dyes included in the first agent produce color as they are oxidatively polymerized.
- hydrogen peroxide in the second agent decomposes the melanin in hair and lightens the background hair color, so that a more distinct color may be produced.
- the oxidative dyes may enter the cortex layer of hair because they have a small size.
- the alkaline agent and hydrogen peroxide may irritate the scalp or skin and may damage the protein in hair. If the amount of the alkaline agent is increased to produce a brighter color, the irritation and hair damage also increase. And, increasing the amount of ammonia( alkaline agent) may result in offensive odor.
- an acidic dye or a temporary dye is used to avoid the problems associated with the oxidative dye. However, the dyeing performance is lower than the permanent hairdye. In addition, such dyes do not completely solve the irritation problem.
- the inventors of the present invention have searched for natural materials capable of alleviating irritation to the scalp and improving dyeing performance and color persistence by controlling reactivity with a dye to facilitate penetration into hair.
- natural materials capable of alleviating irritation to the scalp and improving dyeing performance and color persistence by controlling reactivity with a dye to facilitate penetration into hair.
- the use of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis reduces adverse effects of a hairdye, improves dyeing performance and color persistence, and alleviates damage of hair. Disclosure of Invention Technical Problem
- an object of the present invention is to provide a composition for oxidative dyeing containing natural materials capable of alleviating skin irritation and inflammation caused by hair dyeing, improving dyeing performance and color persistence and alleviating hair damage, and an additive mixture for oxidative dyeing containing the natural materials.
- Another object of the present invention is to provide a dyeing method capable of improving dyeing performance and color persistence by enhancing dyeing property of hair using a hairdye composition containing the natural materials and alleviating hair damage.
- the present invention provides a composition for oxidative dyeing of keratin fibers and an additive mixture for oxidative dyeing containing one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
- a hairdye for oxidative dyeing according to the present invention contains one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
- the one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis prevents or alleviates irritation or inflammation of the scalp caused by hair dyeing.
- Each of the herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens, Coptis chinensis may be in the form of powder, extract, concentrate or a combination thereof.
- the hairdye for oxidative dyeing according to the present invention may be a
- the hairdye for oxidative dyeing may further include an additive mixture selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata , Sophora flavescens, Coptis chinensis and a combination thereof as a third agent.
- composition for oxidative dyeing according to the present invention may contain
- the additive mixture according to the present invention may contain 0.01 to 100 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on the total weight of the additive mixture.
- one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on the total weight of the additive mixture.
- composition for oxidative dyeing according to the present invention has high affinity for hair, it improves dyeing property of hair, thereby providing superior dyeing performance, preventing discoloring of dyed hair, and providing superior color persistence.
- composition for oxidative dyeing reduces hair damage caused by hair dyeing.
- composition contains natural materials, various minerals, vitamins and proteins included therein alleviate allergic reactions or irritations on the scalp. Further, the characteristic odor may provide good feeling.
- composition for oxidative dyeing according to the present invention will provide a comfortable and safe hairdye for those who want to conceal their gray hairs or to express their individualities. Best Mode for Carrying out the Invention [24] Hereinafter, the embodiments of the present invention will be described in detail.
- the present invention provides a composition for oxidative dyeing of keratin fibers comprising an oxidative dye precursor, a coupler, an alkaline agent, an antioxidant, an oxidizing agent and a reducing agent, which comprises one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as an effective ingredient.
- natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as an effective ingredient.
- the present invention provides a composition for oxidative dyeing of keratin fibers, comprising an oxidative dye precursor, a coupler, an alkaline agent, an antioxidant, a reducing agent, etc. as a first agent and an oxidizing agent such as hydrogen peroxide as a second agent, or comprising only the first agent, wherein one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis is used.
- the present invention provides an additive mixture for oxidative dyeing comprising one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, which is mixed with the oxidative hairdye immediately before use to improve dyeing property of hair, thereby improving color development and persistence.
- composition and the additive mixture for oxidative dyeing according to the present invention prevent and alleviate irritations or inflammations of the scalp caused by hair dyeing.
- Each of the green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis is included in the hairdye in the form of powder, extract or concentrate, and is prepared as follows.
- Green tea polysaccharide is prepared by removing chlorophyll and low- molecular- weight polyphenols from pulverized green tea powder by solvent extraction, obtaining green tea polysaccharide extract by hot water extraction, concentrating the extract under reduced pressure, removing low-molecular-weight free proteins by ultrafiltration, precipitating green tea polysaccharide, and drying the precipitate in vacuum to obtain green tea polysaccharide in powder form.
- Cypress polysaccharide is prepared by extracting dried cypress leaves by adding water, concentrating the extract under reduced pressure, removing low-molecular- weight free proteins by ultrafiltration, precipitating cypress polysaccharide, and drying the precipitate in vacuum to obtain cypress polysaccharide in powder form.
- Herbaceous peony(Paeonia lactiflor ⁇ ) belongs to the family Paeoniaceae and has been grown longer than tree peony.
- Oriental medicine the root of herbaceous peony is used after washing and drying, or immersing in boiling water and drying. Especially, the root of herbaceous peony is called red peony and the root of herbaceous peony with the skin peeled off is called white peony.
- dried herbaceous peony is used after pulverization. But, it may also be extracted using water, organic solvent, or a mixture of water and organic solvent.
- Lotus root refers to the root of lotus, a perennial aquatic plant in the family
- lotus root powder prepared by pulverizing dried lotus root to an average particle size of 36 to 39 ⁇ m may be used.
- the particle size of 36 to 39 ⁇ m is selected considering the easiness of mixing with the hairdye, the scope of the present invention is not limited thereto. That is to say, the particle size may be larger or smaller.
- lotus root extract prepared by extracting the lotus root with water or organic solvent, or lotus root concentrate prepared by concentrating the lotus root extract may be used.
- the organic solvent may be one or more selected from a group consisting of ethanol, methanol, butanol, ether, ethyl acetate and chloroform. Also, mixtures of these organic solvent with water may be used.
- Eclipta prostrata is an annual herbaceous plant belonging to the family Asteraceae. It is 10 to 70 cm tall. The whole plant contains saponin, nicotine, tannin, vitamin A, ecliptine, varoius triphene compounds( -terthienyl methanol and acetate ester thereof), and the coumarin compound wedelolactone. Its leaf contains wedelolactone and demethylwedelolactone-7-glucoside.
- Eclipta prostrata is used after drying well and pulverizing. But, it may also be extracted using water, organic solvent, or a mixture of water and organic solvent.
- Oriental medicine its tuber, called bletillae tuber is used to treat wounds, gastric ulcer, or the like, as astringent, styptic or pus drainer. In China, it is used to treat heartburn, cough and dyspnea. Also, it is made into glue because it has slimy property.
- Bletilla striata may be used after being boiled, steamed, roasted, broiled or heated. More specifically, Bletilla striata may be boiled at 60 to 100 0 C for 30 minutes to 2 hours, steamed at 120 to 15O 0 C for 3 to 6 hours, roasted at 100 to 18O 0 C for 10 minutes to 1 hour, or broiled at 80 to 100 0 C for 10 minutes to 1 hour.
- the organic solvent may be selected from a group consisting of ethanol, methanol, butanol, ether, ethyl acetate, chloroform and mixtures of these organic solvents with water. Preferably, 80% ethanol may be used.
- Sophora flavescens is referred to in China as kushen(which literally means bitter root) because of its bitter taste. It has a characteristic persistent odor and very bitter and cold properties. It is used to treat dysentery, leucorrhea, pruritis vulvae, itching skin, or the like. It is also used when urination is difficult and painful due to cystitis. It is reported that it has such pharmacological effects as leucopenia treating, anti-radioactive, coronary blood flow increasing, heart muscle strengthening, blood glucose lowering, anti-tumor, antibacterial and immune suppressing effects.
- Sophora flavescens extract prepared in the same manner as the preparation of Bletilla striata extract is used.
- Coptis chinensis extract prepared in the same manner as the preparation of Bletilla striata extract is used.
- one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis is included in an amount of 0.01 to 30 wt%, preferably 0.1 to 10 wt%, based on the total weight of the hairdye composition.
- the natural material is included in an amount less than 0.01 wt%, the effect of improving dyeing performance and color persistence or alleviating hair damage and scalp irritation may not be attained. And, if it is included in an amount exceeding 30 wt%, coloring may be insufficient because oxidative polymerization of dye may be suppressed.
- a hairdye for oxidative dyeing according to the present invention may be a
- 1 -formulation type comprising a mixture of a hairdye as a first agent and a developer as a second agent, or a 2-formulation type including a hairdye as a first agent and a developer as a second agent, which are separately packaged.
- the hairdye may be one or more selected from a group consisting of: an acidic hairdye comprising an acidic dye and a direct dye; a semipermanent hairdye comprising a basic dye; a metallic hairdye comprising silver nitrate and lead acetate; a mordant hairdye comprising iron sulfate and aluminum compound along with py- rogallol, hematein or gallic acid; and a natural hairdye comprising a natural dye such as henna, indigo and chamomile.
- composition for oxidative dyeing according to the present invention may further comprise an additive mixture comprising one or natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as a third agent.
- the natural material may be included in an amount of 0.01 to 100 wt%, based on the total weight of the additive mixture.
- the additive mixture is used in an amount of 0.01 to 30 wt%, preferably 0.1 to 5 wt%, based on the total weight of the hairdye. If it is used in an amount less than 0.01 wt%, the effect of protecting scalp and skin may not be attained. And, if it is used in an amount exceeding 30 wt%, coloring may be insufficient because oxidative polymerization of dye may be suppressed.
- the additive mixture according to the present invention may be added when the first agent and the second agent are mixed.
- it may be mixed with any bleaching agent, including a cream-type bleach, a lotion-type bleach and a powder-type bleach comprising potassium persulfate and ammonium persulfate.
- the third agent according to the present invention i.e. the additive mixture, provides an excellent effect of protecting scalp and skin from itching, irritation, inflammation and erythema during hair dyeing.
- composition for oxidative dyeing according to the present invention may be used in a neutral to alkaline pH range of pH 6 to 12, preferably in an alkaline pH range of pH 8 to 11. If the pH is below 6, the oxidizing agent included in the second agent may not be decomposed well, so that it may not effectively penetrate into hair. And, a pH above 12 may result in damage of proteins in hair or skin irritation.
- the alkaline agent may be an alkaline agent commonly used in a hairdye, such as ammonia, monoethanolamine, aminomethylpropanol, ispropanolamine, sodium hydroxide, potassium hydroxide, etc.
- the composition for oxidative dyeing according to the present invention may comprise a oxidative dye precursor and a coupler, which are commonly used, in the first agent.
- a coupler which are commonly used, in the first agent.
- it may comprise two or more oxidative dye precursors and couplers.
- the oxidative dye precursor is not particularly limited, but o-aminophenol, /?-aminophenol, /?-phenylenediamine, toluene-2,5-diamine hydrochloride, /?-phenylenediamine hydrochloride, toluene-2,5-diamine, /?-phenylenediamine sulfate, /?-methylaminophenol sulfate, o-aminophenol sulfate, /?-aminophenol sulfate, toluene-2,5-diamine sulfate, p - phenylenediamine sulfate, etc.
- the coupler may be mixed with the oxidative dye precursor to provide various shades in hair.
- the composition for oxidative dyeing according to the present invention may comprise a commonly used direct dye within a range not interfering with the purpose of the present invention.
- the direct dye may be arianol dyes, p-nitm-o - phenylenediamine, nitro-/?-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro-/?-phenylenediamine hydrochloride, picramic acid, and other vegetable dyes, such as henna.
- composition for oxidative dyeing of the present invention may include the ingredients commonly used in a hairdye within a range not negatively affecting the effect of the present invention.
- antioxidant, sequestrant, solvent, surfactant, thickener, fragrance, conditioner, or the like may be used. They may be those commonly used in a hairdye and are not particularly limited.
- the antioxidant may be butylhydroxyanisole, dibutylhydroxytoluene, t - butylhydroquinone, tocopherols, etc.
- the sequestrant may be EDTA, disodium EDTA, tetrasodium EDTA, pentasodium EDTA, etc.
- the solvent may be ethanol, propyl alcohol, isopropyl alcohol, propylene glycol, hexylene glycol, diethylene glycol, etc.
- the surfactant may be a cationic, anionic or non-ionic surfactant
- the thickener may be a polymer thickener, a C12-C22 higher alcohol or a mixture thereof, a non-ionic polymer, an anionic polymer, paraffin , light liquid isoparaffin, etc.
- the conditioner may be a cationic polymer, a quaternary ammonium salt, silicone, etc.
- composition for oxidative dyeing according to the present invention may comprise one or more commonly used oxidizing agent(s) selected from hydrogen peroxide, urea peroxide, alkali metal bromate, ferricyanide, perborate and persulfate in the second agent. Particularly, hydrogen peroxide is preferred.
- the second agent may also comprise the ingredients commonly used in a hairdye within a range not negatively affecting the effect of the present invention.
- paraffin light liquid isoparaffin, higher fatty alcohol, higher fatty acid ester, cationic or non-ionic surfactant, stabilizer such as phenacetin, sequestrant such as disodium EDTA, pH adjuster such as phosphoric acid, etc.
- stabilizer such as phenacetin
- sequestrant such as disodium EDTA
- pH adjuster such as phosphoric acid, etc.
- the first agent and the second agent of the hairdye composition according to the present invention may generally further include water.
- water Preferably, purified water such as ion-exchanged water, distilled water, etc. is used.
- the amount of water is not particularly limited. An amount capable of sufficiently dissolving or dispersing the ingredients of the hairdye composition will be fine.
- the present invention further provides a hairdye set comprising a first agent, a second agent or a mixture thereof, comprising one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
- a hairdye set comprising a first agent, a second agent or a mixture thereof, comprising one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
- the hairdye set may further include an additive mixture comprising one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as a third agent.
- an additive mixture comprising one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as a third agent.
- the hairdye set may be: a hairdye set comprising a first agent comprising one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, an oxidative dye precursor, a coupler, an alkaline agent and an antioxidant, and a second agent comprising an oxidizing agent; a hairdye set comprising a first agent comprising an oxidative dye precursor, a coupler, an alkaline agent and an antioxidant, and a second agent comprising one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis and an oxidizing agent; a hairdye set comprising a first agent comprising
- the present invention also provides a dyeing method using a hairdye set for oxidative dyeing of keratin fibers, comprising:
- a hairdye comprising 0.01 to 30 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on a first agent, a second agent or a mixture thereof, with water;
- an additive mixture comprising 0.01 to 100 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on the total weight of the additive mixture, may be further added as a third agent.
- the first agent and the second agent of the hairdye composition according to the present invention are mixed immediately before application to hair.
- an oxidative hairdye for example in power form, in which the first agent and the second agent are mixed together may be used.
- 60 g of a commonly used first agent hairdye composition and 60 g of a commonly used second agent developer may be mixed together with 1 g of the additive mixture according to the present invention. Then, the mixture may be applied to hair such that the amount of the mixture may be 2 times the weight of the hair. Then, after waiting for 30 minutes, the dyed hair was cleaned with a shampoo, and then dried.
- the first agent (hairdye composition) of the present invention may be mixed with the second agent(developer) of the present invention at a ratio of 1 : 1. Then, the mixture may be applied to hair such that the amount of the mixture may be 2 times the weight of the hair. Then, after waiting for 30 minutes, the dyed hair was cleaned with a shampoo, and then dried.
- the first agent (hairdye composition) of the present invention may be mixed with the second agent(developer) of the present invention at a ratio of 1 : 1. Then, the mixture may be applied to hair such that the amount of the mixture may be 2 times the weight of the hair. Then, after waiting for 30 minutes, the dyed hair was cleaned with a shampoo, and then dried.
- the resultant green tea polysaccharide extract was filtered using a filter press and concentrated under reduced pressure at 62 C until 1/10 of the initial volume. Subsequently, the green tea polysaccharide concentrate was subjected to ultra- filtration(molecular weight cut-off: 30,000 daltons) to remove low-molecular- weight free proteins. Then, ethanol(5 times the volume of the resultant ultrafiltration concentrate) was slowly added at a rate of 100 mL/min to proceed ethanol precipitation. The precipitated green tea polysaccharide was dried at 45 C in vacuum. Green tea polysaccharide(250 g) was obtained in powder form.
- Cypress polysaccharide was prepared as follows. After washing dried cypress leaf(10 kg), water(20 L) was added and extraction was performed by stirring at room temperature for 24 hours. The resultant extract was filtered using a filter press and concentrated under reduced pressure at 50 C until 1/10 of the initial volume.
- Herbaceous peony(5 kg) was dried well and pulverized using a pulverizer to an average particle size of 36 to 39 ⁇ m to prepare herbaceous peony powder.
- a particle size of 36 to 39 ⁇ m was selected considering easiness of mixing with hairdye.
- Eclipta prostrata 5 kg was dried well and pulverized using a pulverizer to an average particle size of 36 to 39 ⁇ m to prepare Eclipta prostrata powder.
- a particle size of 36 to 39 ⁇ m was selected considering easiness of mixing with hairdye.
- Table 2 Second agent (developer) composition (unit: wt ⁇ i [96]
- Table 3 Third agent ( additive mixture ) composition ( unit : wt% ;
- Test Example 1 Confirmation of irritation alleviating effect through panel test [98] In order to confirm the scalp irritation alleviating effect, test was carried out on those who find difficulty in hair dyeing due to irritation.
- Group A Comparative Example 1 + second agent(developer) + Example 10 [104]
- Group B Comparative Example 1 + second agent(developer) + Example 11 [105]
- Group C Comparative Example 1 + second agent(developer) + Example 12 [106]
- Group D Comparative Example 1 + second agent(developer) + Example 13 [107]
- Group E Comparative Example 1 + second agent(developer) + Example 14 [108]
- Group F Comparative Example 1 + second agent(developer) + Example 15 [109]
- Group G Comparative Example 1 + second agent(developer) + Example 16 [HO]
- Group H Comparative Example 1 + second agent(developer) + Example 17 [111]
- Group I Comparative Example 1 + second agent(developer) + Example 18 [112]
- Group J Comparative Example 1 + second agent(developer), with no additive mixture
- the mixing ratio of the composition of Comparative Example 1, the second agent(developer), and the additive mixtures of Examples 10 to 18 was as follows.
- the additive mixtures of Examples 10 to 18 were added in an amount of 1 g when 60 g of the composition of Comparative Example 1 was mixed with 60 g of the second agent(developer) .
- Test Example 2 Evaluation of dyeing performance
- the first agent hairdye compositions of Examples 1 to 9 and Comparative Example 1 (Table 1) and the second agent(developer) composition (T able 2) were mixed at a ratio of 1 : 1 and evenly applied to 12 cm- long human hair such that the amount of the mixture was 2 times the weight of the hair.
- the hair included about 30% of gray hair.
- the dyed hair was cleaned for 1 minute with flowing water, using a shampoo, and then dried using a hair dryer.
- the color of the dried hair was measured using a colorimeter(Hunterlab Labscan XE).
- the result was compared with the brightness value L * measured with the colorimeter.
- a higher L * value means a thinner color, and a smaller value means a stronger color. Accordingly, a smaller L * value indicates a better dyeing performance.
- Test Example 3 Evaluation of color persistence [128] (3) Evaluation of color persistence of hairdve compositions of Examples 1 to 18 and Comparative Example 1
- Test Example 2 The hair dyed in Test Example 2 was immersed in a shampoo solution, shaken at 200 rpm for 30 minutes using a shaker, rinsed with flowing water for 1 minute, and dried using a hair dryer. Then, L * value was measured using a colorimeter. Color persistence was evaluated from the difference ⁇ L * of brightness with the values given in Tables 6 and 7. A smaller ⁇ L * value means a better color persistence. The result is given in Table 8.
- Test Example 4 Evaluation of hair damage [133] In order to evaluate hair damage, a panel of five experts was asked to evaluate damage of the hair dyed in Test Example 2 according to the following standard. The result is given in Table 9.
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Abstract
Disclosed is a composition for oxidative dyeing of keratin fibers. The composition for oxidative dyeing contains one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis. The natural materials included in the hairdye composition are effective in alleviating irritations of the scalp and provide good feeling with characteristic odor. Further, the composition has superior dyeing performance and color persistence and minimizes hair damage. Accordingly, men and women of all ages may safely and conveniently dye their hair to conceal gray hairs or to express their individualities.
Description
The present invention relates to a composition for oxidative dyeing of keratin fibers, more particularly to a composition for oxidative dyeing of keratin fibers containing one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
In the modern society, men and women of all ages dye their hair to conceal gray hairs or to express their individualities. However, some people are allergic to the oxidative hairdyes and suffer from swollen skin or festering scalp. In addition, those who have sensitive scalps may suffer from scalp irritation, itching or inflammation.
The hairdyes are categorized into permanent hairdye, semipermanent hairdye, temporary hairdyes and other hairdyes depending on how long the color persists.
The permanent hairdye is generally an oxidative hairdye , which color is produced by an oxidation reaction of an oxidative dye. The semipermanent hairdye uses a non-oxidative, acidic or basic dye to dye hair.
And, the temporary hairdye gives temporary coloring effect by adhering pigments, pearls, or the like to hair surface using a film-forming agent. Other hairdyes include those using natural plant dyes such as henna, indigo, chamomile, etc., metallic hairdyes which dye hair through oxidation with silver nitrate or lead acetate, or the like.
In general, an oxidative hairdye contains a first agent(dye phase) and a second agent(Developer). When the two agents are mixed, the dyes included in the first agent produce color as they are oxidatively polymerized. And, hydrogen peroxide in the second agent decomposes the melanin in hair and lightens the background hair color, so that a more distinct color may be produced.
The oxidative dyes may enter the cortex layer of hair because they have a small size. However, when they are polymerized by oxidation, it is difficult for them to penetrate into the hair. As such, if the oxidative dye is polymerized before penetrating into hair, the hair is not dyed well or the dyed hair does not sustain the color for a long time.
Further, the alkaline agent and hydrogen peroxide may irritate the scalp or skin and may damage the protein in hair. If the amount of the alkaline agent is increased to produce a brighter color, the irritation and hair damage also increase. And, increasing the amount of ammonia(alkaline agent) may result in offensive odor.
Often, an acidic dye or a temporary dye is used to avoid the problems associated with the oxidative dye. However, the dyeing performance is lower than the permanent hairdye. In addition, such dyes do not completely solve the irritation problem.
Accordingly, there is a need for developing a composition capable of reducing irritations of a hairdye by using ingredients having antiinflammatory and skin irritation alleviating effects, in order to reduce irritations and inflammations on the scalp and reduce adverse effects of the use of the hairdye.
In order to solve the aforementioned problems, the inventors of the present invention have searched for natural materials capable of alleviating irritation to the scalp and improving dyeing performance and color persistence by controlling reactivity with a dye to facilitate penetration into hair. As a result, they have found out that the use of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis reduces adverse effects of a hairdye, improves dyeing performance and color persistence, and alleviates damage of hair.
Accordingly, an object of the present invention is to provide a composition for oxidative dyeing containing natural materials capable of alleviating skin irritation and inflammation caused by hair dyeing, improving dyeing performance and color persistence and alleviating hair damage, and an additive mixture for oxidative dyeing containing the natural materials.
Another object of the present invention is to provide a dyeing method capable of improving dyeing performance and color persistence by enhancing dyeing property of hair using a hairdye composition containing the natural materials and alleviating hair damage.
To achieve the object of the present invention, the present invention provides a composition for oxidative dyeing of keratin fibers and an additive mixture for oxidative dyeing containing one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
A hairdye for oxidative dyeing according to the present invention contains one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
The one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis prevents or alleviates irritation or inflammation of the scalp caused by hair dyeing.
Each of the herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens, Coptis chinensis may be in the form of powder, extract, concentrate or a combination thereof.
The hairdye for oxidative dyeing according to the present invention may be a 1-formulation type including a mixture of a hairdye as a first agent and a developer as a second agent, or a 2-formulation type including a hairdye as a first agent and a developer as a second agent, which are separately packaged. The hairdye for oxidative dyeing may further include an additive mixture selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens, Coptis chinensis and a combination thereof as a third agent.
The composition for oxidative dyeing according to the present invention may contain 0.01 to 30 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on the total weight of the hairdye composition.
And, the additive mixture according to the present invention may contain 0.01 to 100 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on the total weight of the additive mixture.
Since the composition for oxidative dyeing according to the present invention has high affinity for hair, it improves dyeing property of hair, thereby providing superior dyeing performance, preventing discoloring of dyed hair, and providing superior color persistence.
The composition for oxidative dyeing according to the present invention reduces hair damage caused by hair dyeing. In addition, because the composition contains natural materials, various minerals, vitamins and proteins included therein alleviate allergic reactions or irritations on the scalp. Further, the characteristic odor may provide good feeling.
The composition for oxidative dyeing according to the present invention will provide a comfortable and safe hairdye for those who want to conceal their gray hairs or to express their individualities.
Hereinafter, the embodiments of the present invention will be described in detail.
The present invention provides a composition for oxidative dyeing of keratin fibers comprising an oxidative dye precursor, a coupler, an alkaline agent, an antioxidant, an oxidizing agent and a reducing agent, which comprises one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as an effective ingredient.
More specifically, the present invention provides a composition for oxidative dyeing of keratin fibers, comprising an oxidative dye precursor, a coupler, an alkaline agent, an antioxidant, a reducing agent, etc. as a first agent and an oxidizing agent such as hydrogen peroxide as a second agent, or comprising only the first agent, wherein one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis is used.
Further, the present invention provides an additive mixture for oxidative dyeing comprising one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, which is mixed with the oxidative hairdye immediately before use to improve dyeing property of hair, thereby improving color development and persistence.
The composition and the additive mixture for oxidative dyeing according to the present invention prevent and alleviate irritations or inflammations of the scalp caused by hair dyeing.
Each of the green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis is included in the hairdye in the form of powder, extract or concentrate, and is prepared as follows.
Green tea polysaccharide is prepared by removing chlorophyll and low-molecular-weight polyphenols from pulverized green tea powder by solvent extraction, obtaining green tea polysaccharide extract by hot water extraction, concentrating the extract under reduced pressure, removing low-molecular-weight free proteins by ultrafiltration, precipitating green tea polysaccharide, and drying the precipitate in vacuum to obtain green tea polysaccharide in powder form. Cypress polysaccharide is prepared by extracting dried cypress leaves by adding water, concentrating the extract under reduced pressure, removing low-molecular-weight free proteins by ultrafiltration, precipitating cypress polysaccharide, and drying the precipitate in vacuum to obtain cypress polysaccharide in powder form.
Herbaceous peony(Paeonia lactiflora) belongs to the family Paeoniaceae and has been grown longer than tree peony. In Oriental medicine, the root of herbaceous peony is used after washing and drying, or immersing in boiling water and drying. Especially, the root of herbaceous peony is called red peony and the root of herbaceous peony with the skin peeled off is called white peony. In the present invention, dried herbaceous peony is used after pulverization. But, it may also be extracted using water, organic solvent, or a mixture of water and organic solvent.
Lotus root refers to the root of lotus, a perennial aquatic plant in the family Nymphaeceae. In the present invention, lotus root powder prepared by pulverizing dried lotus root to an average particle size of 36 to 39 ㎛ may be used. Although the particle size of 36 to 39 ㎛ is selected considering the easiness of mixing with the hairdye, the scope of the present invention is not limited thereto. That is to say, the particle size may be larger or smaller. Further, lotus root extract prepared by extracting the lotus root with water or organic solvent, or lotus root concentrate prepared by concentrating the lotus root extract may be used. The organic solvent may be one or more selected from a group consisting of ethanol, methanol, butanol, ether, ethyl acetate and chloroform. Also, mixtures of these organic solvent with water may be used.
Eclipta prostrata is an annual herbaceous plant belonging to the family Asteraceae. It is 10 to 70 cm tall. The whole plant contains saponin, nicotine, tannin, vitamin A, ecliptine, varoius triphene compounds( -terthienyl methanol and acetate ester thereof), and the coumarin compound wedelolactone. Its leaf contains wedelolactone and demethylwedelolactone-7-glucoside. In the present invention, Eclipta prostrata is used after drying well and pulverizing. But, it may also be extracted using water, organic solvent, or a mixture of water and organic solvent.
Bletilla striata grows on sunny place and is planted for ornamental purposes. In Oriental medicine, its tuber, called bletillae tuber is used to treat wounds, gastric ulcer, or the like, as astringent, styptic or pus drainer. In China, it is used to treat heartburn, cough and dyspnea. Also, it is made into glue because it has slimy property.
In the present invention, Bletilla striata may be used after being boiled, steamed, roasted, broiled or heated. More specifically, Bletilla striata may be boiled at 60 to 100℃ for 30 minutes to 2 hours, steamed at 120 to 150℃ for 3 to 6 hours, roasted at 100 to 180℃ for 10 minutes to 1 hour, or broiled at 80 to 100℃ for 10 minutes to 1 hour. Thus obtained Bletilla striata is extracted under reflux after adding water or organic solvent. After sedimentation, followed by filtration and centrifuge to separate the residual from the filtrate, the resultant filtrate is concentrated under reduced pressure to obtain Bletilla striata extract. The organic solvent may be selected from a group consisting of ethanol, methanol, butanol, ether, ethyl acetate, chloroform and mixtures of these organic solvents with water. Preferably, 80% ethanol may be used.
Sophora flavescens is referred to in China as kushen(which literally means bitter root) because of its bitter taste. It has a characteristic persistent odor and very bitter and cold properties. It is used to treat dysentery, leucorrhea, pruritis vulvae, itching skin, or the like. It is also used when urination is difficult and painful due to cystitis. It is reported that it has such pharmacological effects as leucopenia treating, anti-radioactive, coronary blood flow increasing, heart muscle strengthening, blood glucose lowering, anti-tumor, antibacterial and immune suppressing effects.
In the present invention, Sophora flavescens extract prepared in the same manner as the preparation of Bletilla striata extract is used.
In Oriental medicine, the root of Coptis chinensis is harvested in November and dried under sunlight to be used to treat indigestion, gastritis, enteritis, stomachache, nausea, dysentery, palpitation, fever, dysphoria, sore throat, hematemesis, nosebleed, bloody discharge, burn, etc. because it has stomach strengthening, tranquilizing, anti-inflammation and antibacterial effects.
In the present invention, Coptis chinensis extract prepared in the same manner as the preparation of Bletilla striata extract is used.
Thus prepared one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis is included in an amount of 0.01 to 30 wt%, preferably 0.1 to 10 wt%, based on the total weight of the hairdye composition.
If the natural material is included in an amount less than 0.01 wt%, the effect of improving dyeing performance and color persistence or alleviating hair damage and scalp irritation may not be attained. And, if it is included in an amount exceeding 30 wt%, coloring may be insufficient because oxidative polymerization of dye may be suppressed.
A hairdye for oxidative dyeing according to the present invention may be a 1-formulation type comprising a mixture of a hairdye as a first agent and a developer as a second agent, or a 2-formulation type including a hairdye as a first agent and a developer as a second agent, which are separately packaged.
The hairdye may be one or more selected from a group consisting of: an acidic hairdye comprising an acidic dye and a direct dye; a semipermanent hairdye comprising a basic dye; a metallic hairdye comprising silver nitrate and lead acetate; a mordant hairdye comprising iron sulfate and aluminum compound along with pyrogallol, hematein or gallic acid; and a natural hairdye comprising a natural dye such as henna, indigo and chamomile.
The composition for oxidative dyeing according to the present invention may further comprise an additive mixture comprising one or natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as a third agent. The natural material may be included in an amount of 0.01 to 100 wt%, based on the total weight of the additive mixture.
The additive mixture is used in an amount of 0.01 to 30 wt%, preferably 0.1 to 5 wt%, based on the total weight of the hairdye. If it is used in an amount less than 0.01 wt%, the effect of protecting scalp and skin may not be attained. And, if it is used in an amount exceeding 30 wt%, coloring may be insufficient because oxidative polymerization of dye may be suppressed.
For example, when a commercially available oxidative permanent hairdye is used, the additive mixture according to the present invention may be added when the first agent and the second agent are mixed. In addition, it may be mixed with any bleaching agent, including a cream-type bleach, a lotion-type bleach and a powder-type bleach comprising potassium persulfate and ammonium persulfate.
The third agent according to the present invention, i.e. the additive mixture, provides an excellent effect of protecting scalp and skin from itching, irritation, inflammation and erythema during hair dyeing.
The composition for oxidative dyeing according to the present invention may be used in a neutral to alkaline pH range of pH 6 to 12, preferably in an alkaline pH range of pH 8 to 11. If the pH is below 6, the oxidizing agent included in the second agent may not be decomposed well, so that it may not effectively penetrate into hair. And, a pH above 12 may result in damage of proteins in hair or skin irritation.
The alkaline agent may be an alkaline agent commonly used in a hairdye, such as ammonia, monoethanolamine, aminomethylpropanol, ispropanolamine, sodium hydroxide, potassium hydroxide, etc.
The composition for oxidative dyeing according to the present invention may comprise a oxidative dye precursor and a coupler, which are commonly used, in the first agent. Preferably, it may comprise two or more oxidative dye precursors and couplers.
Most of currently known oxidative dye precursors and couplers may be used. The oxidative dye precursor is not particularly limited, but o-aminophenol, p-aminophenol, p-phenylenediamine, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, toluene-2,5-diamine, p-phenylenediamine sulfate, p-methylaminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate, p-phenylenediamine sulfate, etc. may be used. And, for the coupler, 2-methyl-5-hydroxyethylaminophenol, p-amino-o-cresol, m-aminophenol, 2,4-diaminophenoxyethanol hydrochloride, m-phenylenediamine hydrochloride, m-phenylenediamine, α-naphtol, resorcinol, 2-methylresorcinol, etc. may be used. The coupler may be mixed with the oxidative dye precursor to provide various shades in hair.
The composition for oxidative dyeing according to the present invention may comprise a commonly used direct dye within a range not interfering with the purpose of the present invention. The direct dye may be arianol dyes, p-nitro-o-phenylenediamine, nitro-p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro-p-phenylenediamine hydrochloride, picramic acid, and other vegetable dyes, such as henna.
Further, the composition for oxidative dyeing of the present invention may include the ingredients commonly used in a hairdye within a range not negatively affecting the effect of the present invention. For example, antioxidant, sequestrant, solvent, surfactant, thickener, fragrance, conditioner, or the like may be used. They may be those commonly used in a hairdye and are not particularly limited.
The antioxidant may be butylhydroxyanisole, dibutylhydroxytoluene, t-butylhydroquinone, tocopherols, etc., the sequestrant may be EDTA, disodium EDTA, tetrasodium EDTA, pentasodium EDTA, etc., and the solvent may be ethanol, propyl alcohol, isopropyl alcohol, propylene glycol, hexylene glycol, diethylene glycol, etc.
The surfactant may be a cationic, anionic or non-ionic surfactant, the thickener may be a polymer thickener, a C12-C22 higher alcohol or a mixture thereof, a non-ionic polymer, an anionic polymer, paraffin , light liquid isoparaffin, etc., and the conditioner may be a cationic polymer, a quaternary ammonium salt, silicone, etc.
The composition for oxidative dyeing according to the present invention may comprise one or more commonly used oxidizing agent(s) selected from hydrogen peroxide, urea peroxide, alkali metal bromate, ferricyanide, perborate and persulfate in the second agent. Particularly, hydrogen peroxide is preferred.
And, the second agent may also comprise the ingredients commonly used in a hairdye within a range not negatively affecting the effect of the present invention. For example, paraffin, light liquid isoparaffin, higher fatty alcohol, higher fatty acid ester, cationic or non-ionic surfactant, stabilizer such as phenacetin, sequestrant such as disodium EDTA, pH adjuster such as phosphoric acid, etc. may be included.
In addition to the aforesaid ingredients, the first agent and the second agent of the hairdye composition according to the present invention may generally further include water. Preferably, purified water such as ion-exchanged water, distilled water, etc. is used. The amount of water is not particularly limited. An amount capable of sufficiently dissolving or dispersing the ingredients of the hairdye composition will be fine.
The present invention further provides a hairdye set comprising a first agent, a second agent or a mixture thereof, comprising one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
The hairdye set may further include an additive mixture comprising one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as a third agent.
More specifically, the hairdye set may be: a hairdye set comprising a first agent comprising one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, an oxidative dye precursor, a coupler, an alkaline agent and an antioxidant, and a second agent comprising an oxidizing agent; a hairdye set comprising a first agent comprising an oxidative dye precursor, a coupler, an alkaline agent and an antioxidant, and a second agent comprising one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis and an oxidizing agent; a hairdye set comprising a mixture of a first agent comprising an oxidative dye precursor, a coupler, an alkaline agent and an antioxidant and a second agent comprising an oxidizing agent along with one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis; and a hairdye set further comprising an additive mixture comprising one or more selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as a third agent in addition to the aforesaid three hairdye sets.
The present invention also provides a dyeing method using a hairdye set for oxidative dyeing of keratin fibers, comprising:
a) mixing a hairdye comprising 0.01 to 30 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on a first agent, a second agent or a mixture thereof, with water;
b) applying 20 to 30 parts by weight of the hairdye to 100 parts by weight of hair; and
c) leaving the hairdye-applied hair at room temperature for 5 to 30 minutes, without any treatment, after heat treatment or after covering with hair protecting film, cleaning thus dyed hair with a conditioner or shampoo, and then drying it.
In a), an additive mixture comprising 0.01 to 100 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on the total weight of the additive mixture, may be further added as a third agent.
The first agent and the second agent of the hairdye composition according to the present invention are mixed immediately before application to hair. The mixing ratio of the first agent and the second agent is, in general, first agent : second agent = 1 : 1 to 1 : 3, based on weight, but not particularly limited thereto.
Further, an oxidative hairdye, for example in power form, in which the first agent and the second agent are mixed together may be used.
More specifically, 60 g of a commonly used first agent hairdye composition and 60 g of a commonly used second agent developer may be mixed together with 1 g of the additive mixture according to the present invention. Then, the mixture may be applied to hair such that the amount of the mixture may be 2 times the weight of the hair. Then, after waiting for 30 minutes, the dyed hair was cleaned with a shampoo, and then dried.
Alternatively, the first agent (hairdye composition) of the present invention may be mixed with the second agent(developer) of the present invention at a ratio of 1 : 1. Then, the mixture may be applied to hair such that the amount of the mixture may be 2 times the weight of the hair. Then, after waiting for 30 minutes, the dyed hair was cleaned with a shampoo, and then dried.
The examples and experiments will now be described. The following examples and experiments are for illustrative purposes only and not intended to limit the scope of the present invention.
Preparation Example
(1) Preparation of green tea polysaccharide
Green tea polysaccharide was prepared by solvent extraction as follows. Dried green tea leaf was pulverized and sieved. Thus prepared green powder(d50 = 100 to 100 ㎛, 10 kg) was dispersed in 95%(v/v) ethanol(150 L) and stirred at room temperature. Thus prepared solution was centrifuged and residual green tea from which chlorophyll and low-molecular-weight polyphenols were removed was recovered. The recovered residue was subjected to the aforedescribed solvent extraction once again, and then dried. Water(125 L) was added to thus obtained green tea powder from which chlorophyll and low-molecular-weight polyphenols were removed. Then, hot water extraction was performed by stirring at 35 C for 7 hours.
The resultant green tea polysaccharide extract was filtered using a filter press and concentrated under reduced pressure at 62 C until 1/10 of the initial volume. Subsequently, the green tea polysaccharide concentrate was subjected to ultrafiltration(molecular weight cut-off: 30,000 daltons) to remove low-molecular-weight free proteins. Then, ethanol(5 times the volume of the resultant ultrafiltration concentrate) was slowly added at a rate of 100 mL/min to proceed ethanol precipitation. The precipitated green tea polysaccharide was dried at 45 C in vacuum. Green tea polysaccharide(250 g) was obtained in powder form.
(2) Preparation of cypress polysaccharide
Cypress polysaccharide was prepared as follows. After washing dried cypress leaf(10 kg), water(20 L) was added and extraction was performed by stirring at room temperature for 24 hours. The resultant extract was filtered using a filter press and concentrated under reduced pressure at 50 C until 1/10 of the initial volume.
Subsequently, the concentrate was subjected to ultrafiltration(molecular weight cut-off: 30,000 daltons) to remove low-molecular-weight free proteins. Then, ethanol(5 times the volume of the resultant ultrafiltration concentrate) was slowly added at a rate of 100 mL/min to proceed ethanol precipitation. The precipitated cypress polysaccharide was dried at 45℃ in vacuum. Cypress polysaccharide(430 g) was obtained in powder form.
(3) Preparation of herbaceous peony powder
Herbaceous peony(5 kg) was dried well and pulverized using a pulverizer to an average particle size of 36 to 39 ㎛ to prepare herbaceous peony powder. A particle size of 36 to 39 ㎛ was selected considering easiness of mixing with hairdye.
(4) Preparation of lotus root powder
Dried lotus root(5 kg) was pulverized using a pulverizer to an average particle size of 36 to 39 ㎛ to prepare lotus root powder. A particle size of 36 to 39 ㎛ was selected considering easiness of mixing with hairdye.
(5) Preparation of
Eclipta prostrata
powder
Eclipta prostrata 5 kg was dried well and pulverized using a pulverizer to an average particle size of 36 to 39 ㎛ to prepare Eclipta prostrata powder. A particle size of 36 to 39 ㎛ was selected considering easiness of mixing with hairdye.
(6) Preparation of
Bletilla striata
extract
Well dried Bletilla striata(5 kg) was roasted at 150℃ for 30 minutes. After adding 80% ethanol, followed by extraction under reflux, the residue and filtrate were separated by filtration and centrifuge. The resultant filtrate was concentrated under reduced pressure to obtain Bletilla striata extract.
(7) Preparation of
Sophora flavescens
extract
Washed Sophora flavescens(5 kg) was boiled at 100℃ for 2 hours. After extraction under reflux, the residue and filtrate were separated by filtration and centrifuge. The resultant filtrate was concentrated under reduced pressure to obtain Sophora flavescens extract.
(8) Preparation of
Coptis chinensis
extract
Well dried Coptis chinensis(5 kg) was roasted at 150℃ for 30 minutes. After adding 80% ethanol, followed by extraction under reflux, the residue and filtrate were separated by filtration and centrifuge. The resultant filtrate was concentrated under reduced pressure to obtain Bletilla striata extract.
Examples and Comparative Example
Hairdyes of Examples 1 to 9 and Comparative Example 1 were prepared by mixing 60 g of a first agent composition shown in Table 1 with 60 g of a second agent composition shown in Table 2. Additive mixtures(third agent) of Examples 10 to 18 were added in an amount of 1 g when 60 g of the first agent composition of Comparative Example 1 was mixed with 60 g of the second agent composition shown in Table 2, as shown in Table 3.
Test Example 1: Confirmation of irritation alleviating effect through panel test
In order to confirm the scalp irritation alleviating effect, test was carried out on those who find difficulty in hair dyeing due to irritation.
36 people were grouped into 9 groups. Each group(4 people) was subjected to hair dyeing using each of the hairdye compositions of Examples 1 to 9. Then, they were asked to evaluate the degree of irritation improvement. The control group was given the composition of Comparative Example 1 and the second agent(developer).
Each of the compositions of Examples 1 to 9 and the developer of Table 2 were mixed at a ratio of 60 g : 60 g. Hair dyeing was performed for 30 minutes.
And, 40 were grouped into groups A, B, C, D, E, F, G, H, I and J, 4 people per each. They were subjected to hair dyeing using the following hairdye compositions and were asked to evaluate the degree of irritation improvement.
Group A: Comparative Example 1 + second agent(developer) + Example 10
Group B: Comparative Example 1 + second agent(developer) + Example 11
Group C: Comparative Example 1 + second agent(developer) + Example 12
Group D: Comparative Example 1 + second agent(developer) + Example 13
Group E: Comparative Example 1 + second agent(developer) + Example 14
Group F: Comparative Example 1 + second agent(developer) + Example 15
Group G: Comparative Example 1 + second agent(developer) + Example 16
Group H: Comparative Example 1 + second agent(developer) + Example 17
Group I: Comparative Example 1 + second agent(developer) + Example 18
Group J: Comparative Example 1 + second agent(developer), with no additive mixture
The mixing ratio of the composition of Comparative Example 1, the second agent(developer), and the additive mixtures of Examples 10 to 18 was as follows. The additive mixtures of Examples 10 to 18 were added in an amount of 1 g when 60 g of the composition of Comparative Example 1 was mixed with 60 g of the second agent(developer).
After hair dyeing, the panels were asked to evaluate the improvement of irritation from 1 to 5 points, with 0.5 point intervals. They were asked to give 1 point when they felt little improvement in irritation(the same irritation as existing hairdye) and to give 5 points when they experienced distinct improvement in irritation of the scalp. The result is given in Table 5.
As seen in Table 4 and Table 5, the control group and Group J, who were subjected to hair dyeing only with the composition of Comparative Example 1 and the second agent(developer), without using green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens or Coptis chinensis, felt irritations the same as existing hairdyes. Of the panels who had been suffering from irritations during hair dyeing, those who used the compositions of Examples 1 to 9 and those in the Groups A, B, C, D, E, F, G, H and I experienced improved irritations over existing hairdyes. Therefore, it was confirmed that the compositions comprising the natural materials according to the present invention are effective in relieving scalp irritations caused by hair dyeing.
Test Example 2: Evaluation of dyeing performance
(1) Evaluation of uptake of hairdye compositions of Examples 1 to 9 and Comparative Example 1
In order to evaluate the uptake of the hairdye compositions of Examples 1 to 9 and Comparative Example 1, the first agent hairdye compositions of Examples 1 to 9 and Comparative Example 1(Table 1) and the second agent(developer) composition(Table 2) were mixed at a ratio of 1 : 1 and evenly applied to 12 cm-long human hair such that the amount of the mixture was 2 times the weight of the hair. The hair included about 30% of gray hair. Then, after waiting for 30 minutes, the dyed hair was cleaned for 1 minute with flowing water, using a shampoo, and then dried using a hair dryer. The color of the dried hair was measured using a colorimeter(Hunterlab Labscan XE). The result was compared with the brightness value L* measured with the colorimeter. A higher L* value means a thinner color, and a smaller value means a stronger color. Accordingly, a smaller L* value indicates a better dyeing performance.
As seen in Table 6, all of Examples 1 to 9, in which one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis were included, showed better dyeing performance than Comparative Example 1 because of higher affinity for hair.
(2) Evaluation of uptake of hairdye compositions of Examples 10 to 18 and Comparative Example 1
In order to evaluate the uptake of the hairdye compositions of Examples 10 to 18, 1 g of the composition of Examples 10 to 18 was added when 60 g of the first agent hairdye composition of Comparative Example 1 was mixed with 60 g of the second agent (developer) composition(Table 2). The mixture was evenly applied to 12 cm-long human hair such that the amount of the mixture was 2 times the weight of the hair. The hair included about 30% of gray hair.
Then, after waiting for 30 minutes, the dyed hair was cleaned for 1 minute with flowing water, using a shampoo, and then dried using a hair dryer. The color of the dried hair was measured using a colorimeter(Hunterlab Labscan XE). The result was compared with the brightness value L* measured with the colorimeter. A higher L* value means a thinner color, and a smaller value means a stronger color. Accordingly, a smaller L* value indicates a better dyeing performance.
As seen in Table 7, all of Examples 10 to 18, in which one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis were added to the first agent hairdye composition of Comparative Example 1 and the second agent (developer) composition of Table 2, showed better dyeing performance than Comparative Example 1 because of higher affinity for hair.
Test Example 3: Evaluation of color persistence
(3) Evaluation of color persistence of hairdye compositions of Examples 1 to 18 and Comparative Example 1
The hair dyed in Test Example 2 was immersed in a shampoo solution, shaken at 200 rpm for 30 minutes using a shaker, rinsed with flowing water for 1 minute, and dried using a hair dryer. Then, L* value was measured using a colorimeter. Color persistence was evaluated from the difference ㅿL* of brightness with the values given in Tables 6 and 7. A smaller ㅿL* value means a better color persistence. The result is given in Table 8.
As seen in Table 8, when one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis was added to the oxidative hairdye or the additive mixture, discoloring of dyed hair was prevented and superior color persistence was attained.
Test Example 4: Evaluation of hair damage
In order to evaluate hair damage, a panel of five experts was asked to evaluate damage of the hair dyed in Test Example 2 according to the following standard. The result is given in Table 9.
As seen in Table 9, all of Examples 1 to 18, in which one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis was added to the hairdye or additive mixture, showed better hair protecting effect than Comparative Example 1.
The present application contains subject matter related to Korean Patent Application No. 10-2008-0119841, 10-2008-0137707, 10-2009-0015583 and 10-2009-0024743 filed in the Korean Intellectual Property Office on November 28, 2008, December 31, 2008, February 25, 2009, and March 24, 2009, the entire contents of which is incorporated herein by reference.
While the present invention has been described with respect to the specific embodiments, it will be apparent to those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined in the following claims.
Claims (12)
- A composition for oxidative dyeing of keratin fibers comprising an oxidative dye precursor, a coupler, an alkaline agent, a water-soluble antioxidant, an oxidizing agent and a reducing agent, which comprises one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as an effective ingredient.
- The composition for oxidative dyeing of keratin fibers according to claim 1, wherein each of the green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis is powder, extract, concentrate or a combination thereof.
- The composition for oxidative dyeing of keratin fibers according to claim 1, wherein the natural material(s) is comprised in an amount of 0.01 to 30 wt%, based on the total weight of the hairdye composition.
- The composition for oxidative dyeing of keratin fibers according to claim 1, which is a 1-formulation type comprising a mixture of a hairdye as a first agent and a developer as a second agent, or a 2-formulation type comprising a hairdye as a first agent and developer as a second agent, which are separately packaged.
- The composition for oxidative dyeing of keratin fibers according to claim 4, which further comprises an additive mixture as a third agent.
- The composition for oxidative dyeing of keratin fibers according to claim 4, which is one or more selected from a group consisting of: an acidic hairdye comprising an acidic dye and a direct dye; a semipermanent hairdye comprising a basic dye; a metallic hairdye comprising silver nitrate and lead acetate; a mordant hairdye comprising iron sulfate and aluminum compound along with pyrogallol, hematein or gallic acid; and a natural hairdye comprising a natural dye such as henna, indigo and chamomile.
- The composition for oxidative dyeing of keratin fibers according to claim 5, wherein the additive mixture comprises 0.01 to 100 wt% of natural materials, based on the total weight of the additive mixture.
- The composition for oxidative dyeing of keratin fibers according to any of claims 1 to 7, which prevents or alleviates irritations or inflammations of the scalp caused by hair dyeing.
- A hairdye set comprising a first agent, a second agent or a mixture thereof, comprising one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis.
- The hairdye set according to claim 9, which further comprises an additive mixture comprising one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis as a third agent.
- A dyeing method using a hairdye set for oxidative dyeing of keratin fibers, comprising:mixing a hairdye comprising 0.01 to 30 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on a first agent, a second agent or a mixture thereof, with water;applying 20 to 30 parts by weight of the hairdye to 100 parts by weight of hair; andleaving the hairdye-applied hair at room temperature for 5 to 30 minutes, without any treatment, after heat treatment or after covering with hair protecting film, cleaning thus dyed hair with a conditioner or shampoo, and then drying it.
- The dyeing method according to claim 11, wherein, in said mixing, an additive mixture comprising 0.01 to 100 wt% of one or more natural material(s) selected from green tea polysaccharide, cypress polysaccharide, herbaceous peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens and Coptis chinensis, based on the total weight of the additive mixture, is further added as a third agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200980147701.5A CN102227209B (en) | 2008-11-28 | 2009-11-27 | Oxidising dyeing compositions containing natural materials |
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20080119841 | 2008-11-28 | ||
| KR10-2008-0119841 | 2008-11-28 | ||
| KR1020080137707A KR101636807B1 (en) | 2008-12-31 | 2008-12-31 | Composition for the anti-irritation effect on the scalp containing natural ingredients for hair colorants |
| KR10-2008-0137707 | 2008-12-31 | ||
| KR10-2009-0015583 | 2009-02-25 | ||
| KR1020090015583A KR101625470B1 (en) | 2008-11-28 | 2009-02-25 | Composition for the oxidative dyeing containing natural materials |
| KR10-2009-0024743 | 2009-03-24 | ||
| KR1020090024743A KR101653642B1 (en) | 2009-03-24 | 2009-03-24 | Compositions for the oxidative dyeing containing natural materials |
Publications (2)
| Publication Number | Publication Date |
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| WO2010062138A2 true WO2010062138A2 (en) | 2010-06-03 |
| WO2010062138A3 WO2010062138A3 (en) | 2010-10-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/KR2009/007044 WO2010062138A2 (en) | 2008-11-28 | 2009-11-27 | Composition for the oxidative dyeing containing natural materials |
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| WO (1) | WO2010062138A2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103040669A (en) * | 2011-10-14 | 2013-04-17 | 株式会社爱茉莉太平洋 | Hair dye composition |
| FR3000676A1 (en) * | 2013-01-10 | 2014-07-11 | Oreal | Composition, useful for dyeing human keratin fibers, preferably hair, comprises oxidation dye precursor e.g. phenylenediamines, and oil extract of lotus flower obtained form e.g. Nelumbium speciosum |
| US20140310888A1 (en) * | 2011-11-28 | 2014-10-23 | Gw Cosmetics Gmbh | Agent and method for coloring keratin fibers |
| WO2013113645A3 (en) * | 2012-01-31 | 2014-12-18 | Henkel Ag & Co. Kgaa | Oxidant preparation having optimized viscosity for treating keratin fibers |
| CN110201210A (en) * | 2018-07-27 | 2019-09-06 | 武汉纺织大学 | A kind of preparation method of bletilla striata dressing easy to operate |
| CN110724717A (en) * | 2019-11-07 | 2020-01-24 | 皖西学院 | Preparation method and application of bletilla striata glucomannan ester |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103040669A (en) * | 2011-10-14 | 2013-04-17 | 株式会社爱茉莉太平洋 | Hair dye composition |
| US20140310888A1 (en) * | 2011-11-28 | 2014-10-23 | Gw Cosmetics Gmbh | Agent and method for coloring keratin fibers |
| US9125842B2 (en) * | 2011-11-28 | 2015-09-08 | Gw Cosmetics Gmbh | Agent and method for coloring keratin fibers |
| WO2013113645A3 (en) * | 2012-01-31 | 2014-12-18 | Henkel Ag & Co. Kgaa | Oxidant preparation having optimized viscosity for treating keratin fibers |
| US9283158B2 (en) | 2012-01-31 | 2016-03-15 | Henkel Ag & Co. Kgaa | Oxidant preparation having optimized viscosity for treating keratin fibers |
| FR3000676A1 (en) * | 2013-01-10 | 2014-07-11 | Oreal | Composition, useful for dyeing human keratin fibers, preferably hair, comprises oxidation dye precursor e.g. phenylenediamines, and oil extract of lotus flower obtained form e.g. Nelumbium speciosum |
| CN110201210A (en) * | 2018-07-27 | 2019-09-06 | 武汉纺织大学 | A kind of preparation method of bletilla striata dressing easy to operate |
| CN110201210B (en) * | 2018-07-27 | 2021-09-14 | 武汉纺织大学 | Preparation method of easy-to-operate bletilla striata dressing |
| CN110724717A (en) * | 2019-11-07 | 2020-01-24 | 皖西学院 | Preparation method and application of bletilla striata glucomannan ester |
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|---|---|
| WO2010062138A3 (en) | 2010-10-21 |
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