CN102227209B - Oxidising dyeing compositions containing natural materials - Google Patents
Oxidising dyeing compositions containing natural materials Download PDFInfo
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- CN102227209B CN102227209B CN200980147701.5A CN200980147701A CN102227209B CN 102227209 B CN102227209 B CN 102227209B CN 200980147701 A CN200980147701 A CN 200980147701A CN 102227209 B CN102227209 B CN 102227209B
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Abstract
The invention discloses a kind of composition for oxidation dyeing of keratin fibre.Described oxidising dyeing compositions contains one or more selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae (Eclipta prostrate), the Pseudobulbus Bletillae (Rhizoma Bletillae) (Bletilla striata), Radix Sophorae Flavescentis (Sophora flavescens) and the natural materials of Rhizoma Coptidis (Coptis chinensis).The described natural materials being included in this hair coloring preparation composition can effectively alleviate the stimulation to scalp, and provides good sensation by distinctive smell.Further, said composition has excellent Color and color durability and can reduce hair damage.Therefore, man and the Ms of institute's has age all can conveniently, safely have hair dyed, to cover white hair or to show individual character.
Description
Technical field
The present invention relates to composition for oxidation dyeing of keratin fibre, more particularly, to containing
The composition for oxidation dyeing of keratin fibre of one or more natural materials, described natural materials
Selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae (Eclipta prostrata),
The Pseudobulbus Bletillae (Rhizoma Bletillae) (Bletilla striata), Radix Sophorae Flavescentis (Sophora flavescens) and Rhizoma Coptidis (Coptis
chinensis)。
Background technology
In modern society, the man at various ages and Ms cover poliosis or displaying to have hair dyed
Individual character.But, oxidative hair dyes allergy is caused skin turgor or scalp to fester by some people.
Additionally, have the people of responsive type scalp to may also suffer scalp irritation, itch or inflammation.
Hair dye is divided into Permanent Hair Dyeing Agent, semipermanent to have hair dyed according to its color durability time
Agent, Temporary color and other hair dye.
Usually " oxidative hair dyes ", it is anti-by the oxidation of oxidation dye for Permanent Hair Dyeing Agent
Answer and produce color.Semi-permanent hairdye uses Non-oxidized, acidity or basic stain hair dyeing.
Temporary color then use film former that pigment, Margarita etc. are attached to hair surface and in
Existing temporary color effect.Other hair dye includes natural plant dye such as henna, indigo
Blue dyestuff, Flos Chrysanthemi dyestuff etc., metallic hairdye is anti-by carrying out oxidation with silver nitrate or lead acetate
Answer and have hair dyed.
Generally oxidative hair dyes contains the first reagent (dyeing phase) and (colour developing of the second reagent
Agent).When both preparations mix, the oxidized polymerization of dyestuff in the first reagent and produce face
Color.Further, the hydrogen peroxide in the second reagent decomposes the melanin in hair and makes the back of the body of hair
Scape color is thin out, so as to produce more strikingly color.
Oxidation dye can enter hair cortex because its granule is little.But, when they oxidations are poly-
It is difficult to after conjunction penetrate in hair.Therefore, if oxidation dye just there occurs before penetrating into hair
Polymerization, hair dyeing effect will bad or dyeing hair color can not be lasting.
And, alkaline agent and hydrogen peroxide can stimulate scalp or skin, and can damage in hair
Albumen.If increasing the consumption of alkaline agent and obtaining vivider color, then stimulate degree and head
Send out damage to be consequently increased.And the consumption increasing ammonia (alkaline agent) can produce niff.
Generally, for avoiding problem that oxidation dye brings to use acid stain or temporary dye
Material.But, its Color is then not as Permanent Hair Dyeing Agent.And, this kind of dyestuff does not has yet
It is fully solved stimulation problem.
Therefore, in order to, alleviate the stimulation of scalp and inflammation and reduce the side effect using hair dye,
People need exploitation one have antiinflammatory by use and alleviate skin irritant composition and alleviate
The compositions of the stimulation of hair dye.
For solving the problems referred to above, the present inventor always searches for alleviating scalp irritation
With improve the natural materials of hair dyeing effect and color durability, described natural materials by control with
The reaction of dyestuff and promote that dyestuff penetrates in hair.Result they find, use selected from green tea many
Sugar, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and the one of Rhizoma Coptidis or many
Plant natural materials, it is possible to alleviate the side effect of hair dye, improve hair dyeing effect and color durability,
And alleviate hair damage.
Summary of the invention
Technical problem
Therefore, it is an object of the present invention to provide a kind of oxidising dyeing containing natural materials to use
Compositions, its can alleviate the skin irritation caused by hair dyeing and inflammation, improve Color and
Color durability also alleviates hair damage, and a kind of oxidising dyeing containing described natural materials
Use additive agent mixture.
It is a further object to provide a kind of colouring method, it is by using containing described
The hair coloring preparation composition of natural materials and strengthen hair-dyeing performance, it is possible to improve Color and
Color durability, and alleviate hair damage.
Technical scheme
For realizing the object of the invention, the present invention provides a kind of keratin fibre oxidation dyeing combination
Thing and oxidising dyeing additive agent mixture, it contains selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Chinese herbaceous peony
One or more materials of medicine, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.
The oxidising dyeing hair dye of the present invention contain selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae,
One or more natural materials of Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.
Described selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), hardship
One or more natural goods mass-energy of ginseng and Rhizoma Coptidis prevent or alleviate the scalp caused due to hair dyeing
Stimulate or inflammation.
Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis, each of in Rhizoma Coptidis can be powder,
Extract, concentration form or a combination thereof.
The oxidising dyeing hair dye of the present invention can be: dosage form-1, and it includes as the first reagent
Hair dye and the mixture of developer as the second reagent；Or dosage form-2, it includes respectively
The hair dye as the first reagent of packaging and as the developer of the second reagent.This oxidising dyeing
Can farther include the additive agent mixture as the 3rd reagent with hair dye, described additive mixes
Compound selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis,
Rhizoma Coptidis and their mixture.
With total restatement of this hair coloring preparation composition, the oxidising dyeing compositions of the present invention can comprise
One or more natural materials of 0.01-30wt%, this natural materials is selected from Polysaccharide from Green Tea, Cupressus funebris
Polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.
Further, with total restatement of this additive agent mixture, the additive agent mixture of the present invention can wrap
One or more natural materials containing 0.01-100wt%, this natural materials selected from Polysaccharide from Green Tea,
Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.
Beneficial effect
Owing to the oxidising dyeing compositions of the present invention has high-affinity to hair, which improve head
The dyeing property sent out, thus provide fabulous hair dyeing effect, it is therefore prevented that fading of colored hair,
Provide fabulous color durability.
The oxidising dyeing compositions of the present invention alleviates the hair damage caused by hair dyeing.This
Outward, owing to said composition contains natural materials, various mineral contained therein, vitamin and
Protein alleviates anaphylaxis or the stimulation of scalp.And its distinctive abnormal smells from the patient can bring good
Good sensation.
The oxidising dyeing compositions of the present invention can be to want cover poliosis or show the personage of individual character
Comfortable, safe hair dye is provided.
Detailed description of the invention
Embodiment of the present invention are described more fully below.
The present invention provide one include oxidation dye precursor, coupling agent, alkaline agent, antioxidant,
The composition for oxidation dyeing of keratin fibre of Oxidizing and Reducing Agents, it includes selected from green tea many
Sugar, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and the one of Rhizoma Coptidis or many
Plant natural materials as effective ingredient.
Specifically, the present invention provides a kind of composition for oxidation dyeing of keratin fibre, and it includes
As the oxidation dye precursor of the first reagent, coupling agent, alkaline agent, antioxidant, reducing agent etc.,
And the oxidant such as hydrogen peroxide as the second reagent, or only include this first reagent, its
In employ selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), hardship
Ginseng and one or more materials of Rhizoma Coptidis.
Further, the present invention provides and includes selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, lotus
The oxidising dyeing of one or more materials of Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis adds
Agent composition, it mixes the dye improving hair the most at once with described oxidative hair dyes
Color characteristic, thus improve color effects and the persistency of hair.
The oxidising dyeing compositions of the present invention and additive agent mixture be prevented from and alleviate by
The scalp irritation that causes of hair dyeing or inflammation.
Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis
In each of be contained in hair dye with powder, extract or concentration form, and according to such as
Prepared by lower section method.
The preparation of Polysaccharide from Green Tea: ground green tea powder is carried out solvent extraction therein to remove
Chlorophyll and low-molecular-weight polyphenol, obtain Polysaccharide from Green Tea extract through hot water extraction, under reduced pressure
Concentrate this extract, remove low-molecular-weight floating preteins therein through ultrafiltration, precipitate Polysaccharide from Green Tea,
It is vacuum dried this precipitate and obtains Polysaccharide from Green Tea powder.The preparation of Cupressus funebris polysaccharide: to dry flat
Cacumen Platycladi (Cacumen Biotae) adds water and extracts, this extract of concentrating under reduced pressure, remove low point therein through ultrafiltration
Son amount floating preteins, precipitates Cupressus funebris polysaccharide, is vacuum dried this precipitate and obtains Cupressus funebris polysaccharide powder.
Radix Paeoniae (Paeonia lactiflora) belongs to Paeoniaceae (Paeoniaceae), and its trophophase is longer than
Paeonia suffruticosa.In the Orient in medical science, Peony Root cleaned, be dried or through boiling water digestion, make after drying
With.Especially, Peony Root is referred to as red Chinese herbaceous peony, and the Peony Root after removing the peel is referred to as the Radix Paeoniae Alba.This
Invention uses the dry Radix Paeoniae ground.However, it is possible to use water, organic solvent, or water and having
The mixture of machine solvent extracts Radix Paeoniae.
Rhizoma Nelumbinis refers to the root of Flos Nelumbinis, Flos Nelumbinis be the one in Nymphaeceae (Nymphaeceae) for many years
Raw water plant.In the present invention, dry Rhizoma Nelumbinis can be ground as mean diameter 36-39 μm
And prepare Lotus root congee.Although it is contemplated that be prone to mix with hair dye and select particle diameter 36-39 μm,
But the scope of the invention is not limited to and this.That is, particle diameter can be more greater or lesser.Further,
Available water or organic solvent extraction Rhizoma Nelumbinis and prepare Nelumbo nucifera extract, or this Rhizoma Nelumbinis can be concentrated carry
Take thing and prepare Rhizoma Nelumbinis concentrate.Described organic solvent can be the one in lower group or many
Kind: ethanol, methanol, butanol, ether, ethyl acetate and chloroform.Equally, it is possible to use this
A little organic solvents and the mixture of water.
Herba Ecliptae belongs to the annual herb plant of Compositae, high 10-70cm.Plant whole body contains
Saponin, nicotine, tannin, vitamin A, ecliptine, multiple terphenyl compound (α-three thiophene
Methanol and acetate thereof), and coumarin compound 1,8,9-trihydroxy-3-methoxy-benzo[4,5 (wedelolactone).Its
Leaf contains 1,8,9-trihydroxy-3-methoxy-benzo[4,5 and demethylwedelolactone-7-glucoside.In the present invention,
By dried for Herba Ecliptae and use after grinding.However, it is possible to water, organic solvent or water with have
It is extracted by the mixture of machine solvent.
The Pseudobulbus Bletillae (Rhizoma Bletillae) is grown on sun-drenched place, and people are used as decoration.In the Orient in medical science,
The root of the Pseudobulbus Bletillae (Rhizoma Bletillae) is referred to as Bletilla striata (Thunb.ex A.Murray)Rchb.f., as astringent, hemorrhage or suppuration medicine be used for treating wound,
Gastric ulcer etc..In China, the Pseudobulbus Bletillae (Rhizoma Bletillae) is used for treating heartburn, coughing and pant.Viscous because having
Property, it is also made into glue.
In the present invention, the Pseudobulbus Bletillae (Rhizoma Bletillae) uses through boiling, steam, drying, after roasting or heating.More specifically,
The Pseudobulbus Bletillae (Rhizoma Bletillae) can be boiled 30 minutes to 2 hours in 60-100 DEG C, steam 3-6 hour in 120-150 DEG C,
Dry 10 minutes to 1 hour in 100-180 DEG C, or bake 10 minutes to 1 hour in 80-100 DEG C.
Extract under backflow after the Pseudobulbus Bletillae (Rhizoma Bletillae) so obtained is added water or organic solvent.First precipitate, filter
Rear centrifugal filtrate to be separated with residue, gained filtrate is under reduced pressure concentrated to give the Pseudobulbus Bletillae (Rhizoma Bletillae) and extracts
Thing.Described organic solvent is selected from lower group: ethanol, methanol, butanol, ether, ethyl acetate,
Chloroform and these organic solvents and the mixture of water.80% ethanol is preferably used.
(meaning of word is for " to have bitterness because its bitterness is referred to as " Radix Sophorae Flavescentis (kushen) " in China for Radix Sophorae Flavescentis
Root ").It has distinctive long-lasting odor, and taste is the most bitter and the property of medicine is cool.It is used for treating dysentery
Disease, leucorrhea, pruritus vulvae, skin pruritus etc..It is additionally operable to the row that treatment is caused by cystitis
Urine difficulty and pain.It is reported that its drug effect having has treatment leukopenia, radioprotective, increasing
Add coronary artery blood flow, strengthen cardiac muscle, reduction blood glucose, antitumor, antibacterial and immunosuppressant
Effect.
In the present invention, the preparation method phase of the preparation method of Radix Sophorae Flavescentis extract and bletilla striata extract
With.
In the Orient in medical science, gather in the crops the root of Rhizoma Coptidis November, dry, because it has strengthening stomach
Function, calm, antiinflammatory and antibacterial effect and be used for treating dyspepsia, gastritis, enteritis, stomach
Pain, feel sick, dysentery, cardiopalmus, fever, dysphoria, have sore throat, spit blood, nose goes out
Blood, hemorrhage, burn etc..
In the present invention, the preparation method phase of the preparation method of Rhizoma Coptidis extract and bletilla striata extract
With.
With total restatement of this hair coloring preparation composition, it comprises thus prepared one or more and is selected from
Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and the sky of Rhizoma Coptidis
So the consumption of material is 0.01-30wt%, preferably 0.1-10wt%.
If this contained natural materials consumption is less than 0.01wt%, just cannot realize it and improve
Hair dyeing effect and color durability or alleviate the effect of hair damage and scalp irritation.And, as
Fruit, can be pressed down due to the oxidative polymerization of dyestuff more than 30wt% containing this natural materials consumption
System and make to dye insufficient.
The oxidising dyeing hair dye of the present invention can be: dosage form-1, and it includes as the first reagent
Hair dye and the mixture of developer as the second reagent；Or dosage form-2, it includes respectively
The hair dye as the first reagent of packaging and as the developer of the second reagent.
Described hair dye can be one or more in lower group: includes that acid stain is with straight
Connect the acidic hair coloring preparation of dyestuff；Semi-permanent hairdye including basic stain；Including silver nitrate
Metallic hairdye with lead acetate；Including iron sulfate and aluminium compound and pyrogallic acid,
The mordant dyeing hair dye of hematein or gallic acid；And include natural dye such as henna,
Bipseudoindoxyl dye and the natural hair dye of Flos Chrysanthemi dyestuff.
The oxidising dyeing compositions of the present invention can farther include the interpolation as the 3rd reagent
Agent composition, it include one or more be selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis,
The natural materials of Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.Gross weight with described additive agent mixture
Meter, the consumption of this natural materials is 0.01-100wt%.
With total restatement of described hair dye, the consumption of described additive agent mixture is
0.01-30wt%, preferably 0.1-5wt%.If this contained additive agent mixture consumption is less than
0.01wt%, just cannot realize its protection scalp and effect of skin.And, if added containing this
Add agent composition consumption more than 30wt%, can be owing to the oxidative polymerization of dyestuff be suppressed
Make to dye insufficient.
Such as, when using commercially available oxidized form Permanent Hair Dyeing Agent, mixing described first reagent
During with the second reagent, the additive agent mixture of the present invention can be added.In addition.It can be with any drift
White agent mixing, including the cream shape bleach containing potassium peroxydisulfate and Ammonium persulfate., emulsion form drift
White agent and powdery bleach.
The 3rd i.e. additive agent mixture of reagent of the present invention provides and makes scalp and skin avoid dye
Send out that period causes itch, stimulate, inflammation and the excellent protective effect of erythema.
The oxidising dyeing compositions of the present invention can make to alkaline range in the neutrality of pH6-12
With, the alkaline range of preferably pH8-11.If pH is less than 6, the oxidation in this second reagent
Agent possibly cannot be decomposed well, thus cannot effectively penetrate into hair.And pH is higher than 12
The protein damage in hair or skin irritation can be caused.
Described alkaline agent can be usually used in the alkaline agent such as ammonia, monoethanolamine of hair dye, aminomethyl propanol,
Isopropanolamine, sodium hydroxide, potassium hydroxide etc..
The oxidising dyeing compositions of the present invention can include the oxidation dye being usually used in the first reagent
Color precursor and coupling agent.Preferably include two kinds or above oxidation dye precursor and coupling agent.
The most of oxidation dye precursor and coupling agent being currently known can be used.Described oxidising dyeing
Precursor includes but not limited to: o-aminophenol, para-aminophenol, p-phenylenediamine, Toluene-2,4-diisocyanate, 5-
Diamino hydrochlorate, para-phenylene diamine dihydrochloride, Toluene-2,4-diisocyanate, 5-diamidogen, p-phenylenediamine sulfate, right
Methylaminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene
-2,5-diamidogen sulfate, p-phenylenediamine sulfate.For coupling agent, 2-methyl-5-can be used
Hydroxyethylaminophenol, to amino orthoresol, m-aminophenol, 2,4-diamino phenoxy second
Alcohol hydrochloride, metaphenylene diamine hydrochloride, m-diaminobenzene., alpha-Naphthol, resorcinol, 2-methyl
Resorcinol etc..Described coupling agent can mix to provide shades of colour with described oxidation dye precursor
The hair of the depth.
Not hindering in the range of the object of the invention, the oxidising dyeing compositions of the present invention can be wrapped
Include conventional direct dyes.Described direct dyes can be: Arianol dyestuff, to nitro-neighbour
Phenylenediamine, nitro-pphenylenediamine, 2-Amino-4-nitrophenol, 2-Amino-5-nitrophenol,
Nitro-pphenylenediamine's hydrochlorate, 4,6-dinitro-2-aminophenol. and other vegetable colour such as henna.
Further, in the range of effect of the present invention not being had side effects, the oxygen of the present invention
Change the composition that staining composition can include being usually used in hair dye.Can use such as, antioxidation
Agent, chelating agen, solvent, surfactant, thickening agent, aromatic, hair conditioner etc..They
The composition in hair dye can be commonly used for but be not limited to these.
Described antioxidant can be Butylated hydroxyanisole, dibenzylatiooluene, tert-butyl group hydrogen
Quinone, tocopherol etc., described chelating agen can be EDTA, EDETATE SODIUM, EDTA tetra-sodium,
EDTA five sodium etc., and described solvent can be ethanol, propanol, isopropanol, propylene glycol, second
Glycol, diethylene glycol etc..
Described surfactant can be cation, anion or nonionic surfactant, described
Thickening agent can be polymer viscosifier, C12-C22Above alcohol or its mixture, non-ionic polymeric
Thing, anionic polymer, paraffin, light liquid isoparaffin etc., and described hair conditioner can
For cationic polymer, quaternary ammonium salt, silicone etc..
The oxidising dyeing compositions of the present invention can include that one or more are selected from lower group conventional
Oxidant in the second reagent: hydrogen peroxide, urea peroxide, alkali metal bromate, ferrum cyanogen
Compound, perborate and high-sulfate.In particular it is preferred to hydrogen peroxide.
And, bring in the range of side effect to the effect of the present invention, described second reagent
May also include the composition being usually used in hair dye.Such as, it may include the different chain of paraffin, light liquids
Alkane, high fatty alcohol, high-grade aliphatic ester, cation or anion surfactant, steady
Determine agent such as Phenacetin, chelating agen such as EDETATE SODIUM, pH adjusting agent such as phosphoric acid etc..
In addition to mentioned component, described first reagent of the hair coloring preparation composition of the present invention and
Two reagent generally still further comprise water.Pure water such as ion exchange water, distilled water are preferably used
Deng.The consumption of water is not particularly limited.It is preferably able to fully dissolve or disperse described hair dye to combine
The composition of thing.
The present invention also provides for a kind of one-tenth resisdye including the first reagent, the second reagent or its mixture
Sending out agent, it includes that one or more are selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, drought
Lotus grass, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and the natural materials of Rhizoma Coptidis.
Described complete hair dye can farther include the additive agent mixture as the 3rd reagent, institute
State additive agent mixture and include that one or more are selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, lotus
The natural materials of Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.
More specifically, described complete hair dye can be: a kind of complete hair dye, it includes, bag
Containing one or more selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae),
Radix Sophorae Flavescentis and the first of the material of Rhizoma Coptidis, oxidation dye precursor, coupling agent, alkaline agent and antioxidant
Reagent, and comprise the second reagent of oxidant；A kind of complete hair dye, it includes, comprises
First reagent of oxidation dye precursor, coupling agent, alkaline agent and antioxidant, and comprise one
Or it is multiple selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis
Material and the second reagent of oxidant with Rhizoma Coptidis；A kind of complete hair dye, it includes first
Reagent and the mixture of the second reagent, wherein said first reagent comprise oxidation dye precursor,
Coupling agent, alkaline agent and antioxidant, and described second reagent comprises oxidant and a kind of or many
Plant selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Huang
Material even；In addition to above-mentioned three kinds of complete hair dyes, and a kind of complete hair dye, its
Farther including the additive agent mixture as the 3rd reagent, it comprises one or more selected from green
Tea polysaccharide, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and the material of Rhizoma Coptidis.
The present invention also provides for a kind of using complete hair dye to carry out keratin fibre oxidation dyeing
Colouring method, comprising:
A) based on the first reagent, the second reagent or its mixture, water is mixed with hair dye,
Described hair dye include 0.01-30wt% one or more selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide,
The natural materials of Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis；
B) hair dye of 20-30 weight portion is applied to the hair of 100 weight portions；And
C) keep the most untreated for the hair after application stain 5-30 minute, warp
Heat treatment or through covering after hair protecting film, cleans the hair of dyeing with hair conditioner or shampoo,
Then hair is dried.
In step a), also can add the additive agent mixture as the 3rd reagent further, with
Total restatement of described additive agent mixture, its one or more comprising 0.01-100wt% are selected from
Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and the sky of Rhizoma Coptidis
So material.
First reagent and second reagent of hair coloring preparation composition of the present invention mix before hair dyeing at once.
The weight ratio of usual first reagent and the second reagent is, the first reagent: the second reagent=1: 1-
: 1-3, but it is not particularly limited to this.
Further, the oxidative hair dyes of such as powdery, wherein the first reagent and can be used
Two reagent mix.
More particularly, the first conventional for 60g reagent hair coloring preparation composition and 60g can be commonly used
Second reagent colour development agent additive agent mixture of the present invention with 1g mixes.Then, will be mixed
Compound is had hair dyed by the consumption doubling hair weight.Then after waiting 30 minutes, with hair washing
Essence is dried after being cleaned up by colored hair.
Or, can be by the second examination of first reagent (hair coloring preparation composition) of the present invention with the present invention
Agent (developer) mixes according to the ratio of 1: 1.Then, by mixture by doubling hair weight
The consumption hair dyeing of amount.Then after waiting 30 minutes, after colored hair being cleaned up with shampoo
It is dried.
Embodiment
Embodiment and experiment be will now be described.The mesh that the following example and experiment are merely to illustrate
, and it is not intended to be limiting the scope of the present invention.
Preparation embodiment
(1) preparation of Polysaccharide from Green Tea
Polysaccharide from Green Tea is prepared as follows with solvent extraction.By dry green tea mill
Broken, sieve.The green powder (d50=100-100 μm, 10kg) of preparation is dissolved in 95% (v/v)
In ethanol (150L), and stir at room temperature.By the solution centrifugal of preparation, reclaim and go disleaf green
Green tea residue after element and low-molecular-weight polyphenol.The above-mentioned solvent of green tea residue that will reclaim
Extraction operates once again, is then dried.Water (125L) is joined gained remove chlorophyll and
Green tea powder after low-molecular-weight polyphenol, then carries out hot water extraction in 7 hours in 35 DEG C of stirrings.
By the Polysaccharide from Green Tea extract Filter Press of gained, under reduced pressure concentrate in 62 DEG C
To initial volume 1/10.Then, this Polysaccharide from Green Tea concentrate is carried out ultrafiltration and (retain molecule
Amount: 30,000 dalton) to remove low-molecular-weight floating preteins.Then, with 100mL/min
Speed slowly add in ultrafiltration concentrate by ethanol (5 times of gained ultrafiltration concentrate volumes)
Row ethanol precipitates.Under vacuo the Polysaccharide from Green Tea of precipitation is dried in 45 DEG C.Obtain green tea many
Icing Sugar end (250g).
(2) preparation of Cupressus funebris polysaccharide
It is prepared as follows Cupressus funebris polysaccharide.(20L) is added water after dry Cupressus funebris leaf is cleaned (10kg),
Stirring is extracted for 24 hours at room temperature.By the extract Filter Press of gained, and
The 1/10 of initial volume under reduced pressure it is concentrated in 50 DEG C.
Then, this concentrate is carried out ultrafiltration (molecular cut off: 30,000 dalton) to remove
Low-molecular-weight floating preteins.Then, with the speed of 100mL/min slowly by ethanol (5 times
Gained ultrafiltration concentrate volume) add in ultrafiltration concentrate and carry out ethanol precipitation.In 45 DEG C very
Under sky, the Cupressus funebris polysaccharide of precipitation is dried.Obtain Cupressus funebris polysaccharide (430g) powder.
(3) preparation of Radix Paeoniae powder
By dried for Radix Paeoniae (5kg), and grind as mean diameter 36-39 μm with grinder, with system
Standby Radix Paeoniae powder.In view of easily mixing with hair dye and select particle diameter 36-39 μm.
(4) preparation of Lotus root congee
Dry Rhizoma Nelumbinis (5kg) ground into mean diameter 36-39 μm with grinder, to prepare Rhizoma Nelumbinis
Powder.In view of easily mixing with hair dye and select particle diameter 36-39 μm.
(5) preparation of Fructus seu radix camptothecae acuminatae (Fructus Camptothecae Acuminatae) grass meal
By dried for 5kg Herba Ecliptae, and grind as mean diameter 36-39 μm with grinder, with
Prepare Fructus seu radix camptothecae acuminatae (Fructus Camptothecae Acuminatae) grass meal.In view of easily mixing with hair dye and select particle diameter 36-39 μm.
(6) preparation of bletilla striata extract
The dried Pseudobulbus Bletillae (Rhizoma Bletillae) (5kg) is dried 30 minutes in 150 DEG C.In returning after adding 80% ethanol
Flow down extraction, with centrifugal, residue is separated with filtrate through filtering.Under reduced pressure concentrate gained
Filtrate obtain bletilla striata extract.
(7) preparation of Radix Sophorae Flavescentis extract
Clean Radix Sophorae Flavescentis (5kg) is boiled 2 hours in 100 DEG C.Extract in backflow is lower, through filtering and
It is centrifuged and residue is separated with filtrate.Under reduced pressure concentrate the filtrate of gained to obtain Radix Sophorae Flavescentis and carry
Take thing.
(8) preparation of Rhizoma Coptidis extract
Dried Rhizoma Coptidis (5kg) is dried 30 minutes in 150 DEG C.In returning after adding 80% ethanol
Flow down extraction, with centrifugal, residue is separated with filtrate through filtering.Under reduced pressure concentrate gained
Filtrate obtain Rhizoma Coptidis extract.
Embodiment and comparative example
By the first reagent composition shown in 60g table 1 and the second reagent set shown in 60g table 2
Compound mixes, to prepare embodiment 1-9 and the hair dye of comparative example 1.As shown in table 3, when
First reagent composition of 60g comparative example 1 mixes with the second reagent composition shown in 60g table 2
During conjunction, the addition of the additive agent mixture (the 3rd reagent) of embodiment 10-18 is 1g.
Table 1: the first reagent (hair dye) compositions (unit: wt%)
Table 2: the second reagent (developer) compositions (unit: wt%)
| Composition | Content |
| Palmityl alcohol | 3.5 |
| Mineral oil | 1.0 |
| Polyoxyethylene laurel ether | 0.5 |
| Polyoxyethylene stearyl alcohol ether | 1.5 |
| Phenacetin | 0.03 |
| EDETATE SODIUM | 0.2 |
| Phosphoric acid | 0.16 |
| Hydrogenperoxide steam generator (35%) | 17 |
| Pure water | To 100 |
Table 3: the three reagent (additive agent mixture) compositions (unit: wt%)
Experimental example 1: confirm abirritant effect by group experiment
For confirming to alleviate the effect of scalp irritation, the people being difficult to have hair dyed because producing stimulation is carried out
Test.
36 people are divided into 9 groups.With each of hair coloring preparation composition of embodiment 1-9 to often
Group (4 people) have hair dyed.Then, they are inquired and stimulate, with assessment, the degree improved.
Matched group uses compositions and second reagent (developer) of comparative example 1.
By the developer of each of compositions of embodiment 1-9 and table 2 with 60g: 60g
Ratio mixes.Have hair dyed 30 minutes.
Table 4
Further, 40 people are divided into A, B, C, D, E, F, G, H, I and J group, often
Organize 4 people.Use following hair coloring preparation composition that they are had hair dyed, then inquire that they are to comment
Estimate and stimulate the degree improved.
A group: comparative example 1+ the second reagent (developer)+embodiment 10
B group: comparative example 1+ the second reagent (developer)+embodiment 11
C group: comparative example 1+ the second reagent (developer)+embodiment 12
D group: comparative example 1+ the second reagent (developer)+embodiment 13
E group: comparative example 1+ the second reagent (developer)+embodiment 14
F group: comparative example 1+ the second reagent (developer)+embodiment 15
G group: comparative example 1+ the second reagent (developer)+embodiment 16
H group: comparative example 1+ the second reagent (developer)+embodiment 17
I group: comparative example 1+ the second reagent (developer)+embodiment 18
J group: comparative example 1+ the second reagent (developer), additive-free mixture
The compositions of comparative example 1, the second reagent (developer) and the additive of embodiment 10-18
The mixed proportion of mixture is as follows.When the compositions of 60g comparative example 1 is (aobvious with 60g the second reagent
Toner) mixing time, the addition of the additive agent mixture of embodiment 10-18 is 1g.
Inquire after hair dyeing each group divide with 1-5 and 0.5 be divided into interval assessment stimulate improvement situation.When
1 point is given during their sensory stimuli improvement degree the least (stimulation with existing hair dye is identical), when
To 5 points when sensation scalp irritation has clear improvement.Its result such as table 5.
Table 5
As shown in table 4 and table 5, in matched group and J group, only use the compositions of comparative example 1
With the second reagent (developer) have hair dyed, and unused Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis,
The people of Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis or Rhizoma Coptidis, the stimulation felt is identical with existing hair dye.
Past suffers that hair dyeing stimulate the group perplexed always, uses the people of the compositions of embodiment 1-9
Feel with the people of A, B, C, D, E, F, G, H and I group and improve than existing hair dye
Stimulation degree.Therefore, this just confirm the present invention include the compositions of natural materials alleviate because of
The scalp irritation aspect that hair dyeing causes is effective.
Experimental example 2: the assessment of hair dyeing effect
(1) the absorbing state assessment of the hair coloring preparation composition of embodiment 1-9 and comparative example 1
In order to assess the absorbing state of the hair coloring preparation composition of embodiment 1-9 and comparative example 1, will
Embodiment 1-9 and the first reagent hair coloring preparation composition of comparative example 1 (table 1) and the second reagent (show
Toner) compositions (table 2) with 1: 1 ratio mix, by this mixture by doubling hair weight
The Crinis Carbonisatus level dyeing to 12cm length of the consumption of amount.This hair contains the poliosis of about 30%.Deng
After 30 minutes, with shampoo, hair dyeing is carried out flowing water and clean 1 minute, then electricity consumption dries up.
The dry color sent out is measured with tintometer (Hunterlab Labscan XE).Measured by tintometer is bright
Angle value L*Result compares.Higher L*Value refers to light color, and relatively low L*Value then refers to dark color.
Therefore, less L*Value shows preferable hair dyeing effect.
Table 6
As shown in table 6, all implement 1-9 include one or more selected from Polysaccharide from Green Tea,
The natural materials of Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis, by
The hair dyeing effect being better than comparative example 1 is shown in itself and the high affinity of hair.
(2) the absorbing state assessment of the hair coloring preparation composition of embodiment 10-18 and comparative example 1
In order to assess the absorbing state of the hair coloring preparation composition of embodiment 10-18, when 60g compares
First reagent hair coloring preparation composition of example 1 and 60g the second reagent (developer) compositions (table 2)
During mixing, add the compositions of 1g embodiment 10-18.By this mixture by doubling head
Send out the consumption Crinis Carbonisatus level dyeing to 12cm length of weight.This hair contains the poliosis of about 30%.
Then, after waiting 30 minutes, with shampoo, hair dyeing is carried out flowing water and clean 1 minute, then
Electricity consumption dries up.The dry color sent out is measured with tintometer (Hunterlab Labscan XE).Will
The brightness value L that tintometer measures*Result compares.Higher L*Value refers to light color, and relatively low
L*Value then refers to dark color.Therefore, less L*Value shows preferable hair dyeing effect.
Table 7
As shown in table 7, in all of embodiment 10-18, one or more selected from Polysaccharide from Green Tea,
The natural materials of Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis is added
Enter the second reagent (developer) group of the first reagent hair coloring preparation composition to comparative example 1 and table 2
In compound, show the hair dyeing effect being better than comparative example 1 due to itself and the high affinity of hair
Really.
Experimental example 3: the assessment of color durability
(3) assessment of the hair coloring preparation composition color durability of embodiment 1-18 and comparative example 1
By in experimental example 2 dyeing hair be immersed in shampoo solution, with agitator with
200rpm speed oscillation 30 minutes, flowing water rinses 1 minute, then electricity consumption dries up.Then,
L is measured with tintometer*Value.Discrepancy delta L according to brightness value*Comment with the numerical value in table 6 and 7
Estimate color durability.Less Δ L*Value i.e. refers to preferable color durability.Result such as table 8 institute
Show.
Table 8
As shown in table 8, when one or more are selected from Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, lotus
The natural materials of Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis is injected towards this oxidative hair dyes
Or time in this additive agent mixture, it is therefore prevented that fading and reaching fabulous color of colored hair is held
Property for a long time.
Experimental example 4: the assessment of hair damage
In order to assess hair damage, the expert group of 5 people is asked to be tested according to following criterion evaluation
The degree of impairment of colored hair in example 2.Result is as shown in table 9.
Table 9
◎: the most smooth, zero: smooth, △: moderate, ×: coarse
As shown in table 9, in all of embodiment 1-18, one or more selected from Polysaccharide from Green Tea,
The natural materials of Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis is added
Entering to described hair dye or additive agent mixture, it shows the protection head being better than comparative example 1
Send out effect.
The application contain with Application No. No.10-2008-0119841,
No.10-2008-0137707, No.10-2009-0015583 and No.10-2009-0024743's
The theme that korean patent application is relevant, they are submitted to the date of application of Korean Intellectual Property Office and divide
Be not: on November 28th, 2008,2008 on December 31, on February 25th, 2009
With on March 24th, 2009, it is incorporated by herein with the form referred to.
Although having been directed towards particular implementation to describe the present invention, those skilled in the art are come
Say, in the case of the spirit and scope of the invention determined without departing substantially from claims, it is clear that
Various changes and modifications can also be made.
Claims (12)
1. one kind include oxidation dye precursor, coupling agent, alkaline agent, water soluble antioxidant,
The composition for oxidation dyeing of keratin fibre of Oxidizing and Reducing Agents, it include Polysaccharide from Green Tea,
The mixture of Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis natural
Material is as effective ingredient.
Composition for oxidation dyeing of keratin fibre the most according to claim 1, wherein
Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis are powder
End, extract or a combination thereof.
Composition for oxidation dyeing of keratin fibre the most according to claim 1, wherein,
In terms of the gross weight of hair coloring preparation composition, the content of described natural materials is 0.01-30wt%.
Composition for oxidation dyeing of keratin fibre the most according to claim 1, wherein,
Dosage form-1 includes the hair dye as the first reagent and the mixing of the developer as the second reagent
Thing, or dosage form-2 includes the hair dye as the first reagent packed respectively and as the second reagent
Developer.
Composition for oxidation dyeing of keratin fibre the most according to claim 4, it enters
One step includes that additive agent mixture is as the 3rd reagent；Described additive agent mixture includes that green tea is many
The mixture of sugar, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis
Natural materials.
Composition for oxidation dyeing of keratin fibre the most according to claim 4, described
Compositions is one or more in lower group: include the acidity of acid stain and direct dyes
Hair dye；Semi-permanent hairdye including basic stain；Including silver nitrate and the gold of lead acetate
Belong to hair dye；Including iron sulfate and aluminium compound and pyrogallic acid, hematein or do not eat
The mordant dyeing hair dye of son acid；And include natural dye henna, bipseudoindoxyl dye and Flos Chrysanthemi
The natural hair dye of dyestuff.
Composition for oxidation dyeing of keratin fibre the most according to claim 5, wherein,
With total restatement of described additive agent mixture, described additive agent mixture includes 0.01-100wt%
Natural materials.
8. according to the keratin fibre oxidation dyeing group described in claim 1-7 any one
Compound, it prevents or alleviates the scalp irritation or inflammation caused by hair dyeing.
9. include the hair dye as the first reagent, as the developer of the second reagent or its mix
The complete hair dye of compound, it includes Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Fructus seu radix camptothecae acuminatae (Fructus Camptothecae Acuminatae)
The natural materials of the mixture of grass, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.
Complete hair dye the most according to claim 9, it farther includes additive and mixes
Compound is as the 3rd reagent, and described additive agent mixture includes Polysaccharide from Green Tea, Cupressus funebris polysaccharide, Chinese herbaceous peony
The natural materials of the mixture of medicine, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.
11. carry out the colouring method of keratin fibre oxidation dyeing with complete hair dye, comprising:
Based on the hair dye as the first reagent, the developer as the second reagent or its mixing
Thing, mixes water with hair dye, described hair dye include 0.01-30wt% Polysaccharide from Green Tea,
The mixture of Cupressus funebris polysaccharide, Radix Paeoniae, Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis natural
Material；
The hair dye of 20-30 weight portion is applied to the hair of 100 weight portions；And
Hair after application stain is put the most untreated holding 5-30 minute, warp
Heat treatment or through covering after hair protecting film, cleans the hair of dyeing with hair conditioner or shampoo,
Then hair is dried.
12. colouring method according to claim 11, wherein, enter in described mixing
One step addition additive agent mixture is as the 3rd reagent, with total restatement of described additive agent mixture,
Described additive agent mixture include the Polysaccharide from Green Tea of 0.01-100wt%, Cupressus funebris polysaccharide, Radix Paeoniae,
The natural materials of the mixture of Rhizoma Nelumbinis, Herba Ecliptae, the Pseudobulbus Bletillae (Rhizoma Bletillae), Radix Sophorae Flavescentis and Rhizoma Coptidis.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410403462.8A CN104146911B (en) | 2008-11-28 | 2009-11-27 | Oxidising dyeing composition containing natural materials |
| CN201410403390.7A CN104127332B (en) | 2008-11-28 | 2009-11-27 | Composition for oxidative dyeing containing natural materials |
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2008-0119841 | 2008-11-28 | ||
| KR20080119841 | 2008-11-28 | ||
| KR10-2008-0137707 | 2008-12-31 | ||
| KR1020080137707A KR101636807B1 (en) | 2008-12-31 | 2008-12-31 | Composition for the anti-irritation effect on the scalp containing natural ingredients for hair colorants |
| KR10-2009-0015583 | 2009-02-25 | ||
| KR1020090015583A KR101625470B1 (en) | 2008-11-28 | 2009-02-25 | Composition for the oxidative dyeing containing natural materials |
| KR10-2009-0024743 | 2009-03-24 | ||
| KR1020090024743A KR101653642B1 (en) | 2009-03-24 | 2009-03-24 | Compositions for the oxidative dyeing containing natural materials |
| PCT/KR2009/007044 WO2010062138A2 (en) | 2008-11-28 | 2009-11-27 | Composition for the oxidative dyeing containing natural materials |
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| CN201410403462.8A Division CN104146911B (en) | 2008-11-28 | 2009-11-27 | Oxidising dyeing composition containing natural materials |
| CN201410403390.7A Division CN104127332B (en) | 2008-11-28 | 2009-11-27 | Composition for oxidative dyeing containing natural materials |
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| CN102227209B true CN102227209B (en) | 2016-08-17 |
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| CN201410403462.8A Expired - Fee Related CN104146911B (en) | 2008-11-28 | 2009-11-27 | Oxidising dyeing composition containing natural materials |
| CN200980147701.5A Active CN102227209B (en) | 2008-11-28 | 2009-11-27 | Oxidising dyeing compositions containing natural materials |
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| CN102406582A (en) * | 2011-12-06 | 2012-04-11 | 曾庆桂 | Natural hair dye composition and preparation method thereof |
| FR3000676B1 (en) * | 2013-01-10 | 2014-12-26 | Oreal | OXIDATION COLORING COMPOSITION COMPRISING OIL EXTRACT OF LOTUS FLOWERS, COLORING PROCESS AND APPROPRIATE DEVICE |
| CN104490687A (en) * | 2014-12-13 | 2015-04-08 | 汤泓 | Natural liquid for brightening hair and moistening hair |
| CN105061615B (en) * | 2015-07-28 | 2018-04-13 | 华南理工大学 | One kind has antiviral and immunocompetent arbor-vitae leaf polyose of enhancing and its preparation method and application |
| CN106811995A (en) * | 2015-11-27 | 2017-06-09 | 苑少纯 | A kind of dyeing of indigo pigment dyeing silk fabric |
| CN107385959A (en) * | 2017-08-25 | 2017-11-24 | 贵州盛茂白芨开发有限公司 | A kind of colouring method of bletilla striata dyestuff |
| CN114983888B (en) * | 2022-06-01 | 2024-02-13 | 森气生物科技(上海)有限公司 | Permanent gel hair dye and application method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6139853A (en) * | 1996-01-05 | 2000-10-31 | Hans Schwarzkopf Gmbh & Co. Kg | Hair colorants and an application mixture for coloring human hair |
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| CN1105683A (en) * | 1994-01-18 | 1995-07-26 | 龚枫砰 | Yellow health-care (coloring agent) dye |
| CN1207031A (en) * | 1996-01-05 | 1999-02-03 | 汉斯·史瓦兹考普两合公司 | Hair colorant and application mixture for coloring human hair |
| JP3309221B1 (en) * | 2001-04-27 | 2002-07-29 | 株式会社コスモビューティー | Hair dyeing hair styling composition |
| KR100625180B1 (en) * | 2006-03-16 | 2006-09-20 | 박정금 | Composition for hair color and preparation method thereof |
| KR100812118B1 (en) * | 2006-11-30 | 2008-03-12 | (주)아모레퍼시픽 | Natural hairdye composition using simultaneous color-fixing art |
| KR100872898B1 (en) * | 2007-04-27 | 2008-12-10 | 김경숙 | Composition for hair color having an extract of green tea |
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| US6139853A (en) * | 1996-01-05 | 2000-10-31 | Hans Schwarzkopf Gmbh & Co. Kg | Hair colorants and an application mixture for coloring human hair |
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| CN104127332A (en) | 2014-11-05 |
| CN104146911B (en) | 2018-01-23 |
| CN102227209A (en) | 2011-10-26 |
| CN104146911A (en) | 2014-11-19 |
| CN104127332B (en) | 2017-04-12 |
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