KR101562615B1 - 1 Composition for the oxidative dyeing containing natural materials - Google Patents

Abstract

The present invention relates to a one-component oxidative type hair dye composition containing a natural component, and more particularly to a one-component oxidative hair dye composition containing one or more selected from a green tea polysaccharide, a white crystalline polysaccharide, a peony root, The hair dye composition according to the present invention contains a natural component and thus has a remarkable effect on irritation relief and scalp stability. The hair dye composition according to the present invention has excellent odor and color persistence as well as pleasant odor with a unique flavor, The hair is protected and the damage is minimized, so that natural hair dyeing is possible.

Natural ingredients, hair dye

Description

[0001] The present invention relates to a composition for oxidative dyeing containing natural ingredients,

The present invention relates to a one-component oxidative type hair dye composition containing a natural component, and more particularly to a one-component oxidative hair dye composition containing one or more selected from a green tea polysaccharide, a white crystalline polysaccharide, a peony root, .

The hair dye is classified into permanent hair dye, permanent hair dye, temporary hair dye and other hair dye depending on how long the stained color lasts.

The permanent hair dye is generally referred to as an " oxidative dye ", and is a principle that exhibits color by oxidation of a dye using an oxidative dye. Oxidative type hair dye is composed of 1 formulation, but generally consists of a hair dye 1 agent and an oxidizer 2. 1 Jane's hair dye contains a dye, a dye precursor and a coupler, which contains an alkaline agent such as ammonia and monoethanolamine, which causes oxidation of the hair by swelling the hair and accelerating decomposition of hydrogen peroxide. A chelating agent is also used for the purpose of controlling the oxidation reaction of dyes using a reducing agent or an antioxidant and blocking metal ions. In addition, hair conditioning agents and fragrances such as patty alcohols, surfactants or cationic polymers are included. 2 Hydrogen peroxide in the oxidizing agent oxidizes the melanin of the hair, brightens the background color of the hair, and promotes the oxidation reaction of the dye.

The semi-permanent hair dye is a principle of dyeing hair using non-oxidative dyes such as acid dyes or basic dyes. These dyes do not oxidize and polymerize, but are themselves colored dyes that attach to the hair by ionic bonding with the amino acid of the hair and dye the hair. It is relatively large in size compared to oxidative dyes and can not penetrate deeper into the hair (to the layer of the hair).

The hair dyeing agent temporarily attaches pigment or pearl to the surface of the hair using a film forming agent, thereby temporarily imparting a coloring effect to the hair.

Other hair dyeing agents include hair dyeing agents using vegetable natural dyes such as henna, indigo and chamomile, and metallic hair dyeing agents for dyeing hair by oxidation of silver nitrate and acetic acid.

The permanent hair dye agent is classified into a two-component type oxidative type hair dye agent and a one-part type oxidative type hair dye agent according to the formulation. 2 Formulation The oxidative type hair dye is divided into cream, lotion and liquid with a hair dyeing agent and divided into cream, lotion and liquid as the oxidizing agent in the second agent. The first agent and the second agent are mixed at a certain rate just before use and applied to the hair After leaving for a certain time, it is dyed by washing thoroughly with shampoo. In contrast, one type of oxidative type hair dye is generally in the form of powder or paste. It is mixed with water at a certain rate just before use and applied to the hair, and then dyed by washing with shampoo after leaving for a certain time.

2 Formulations Oxidation type dyeing agents generally exhibit color by causing an oxidation polymerization reaction between the dyes contained in one agent by mixing 1 agent and 2 agent. In addition, the hydrogen peroxide in the 2nd agent breaks down the melanin pigment in the hair to discolor the hair, so that the hue of the hair is brightened, and a brighter color can be expressed. On the other hand, the one-component oxidative type hair dye is colored by the oxidation reaction with the oxidation dye such as sodium perborate, sodium percarbonate, peracetic acid, peracetic acid, potassium permanganate, and sodium peroxide by mixing with water and oxidizing polymerization reaction with the oxidation dye. By the hydrogen peroxide generated by the melamine pigment in the hair breaks down the hair color by bleaching the hair color is bright.

The above-mentioned 1-type oxidative dyeing agent has advantages that it is not necessary to separately mix an oxidizing agent and enables low-cost dyeing with a low production cost, but oxidative polymerization reaction occurs before an oxidative dye penetrates into hair, , The dyeability of the hair is lowered and the color persistence after dyeing is also lowered.

Accordingly, the inventor of the present invention has continued to study a method for improving the dyeability and color persistence of the one-component oxidative type hair dye in order to solve the above problems. As a result, the present inventors have found that natural ingredients such as green tea polysaccharide, One or two or more of the blends were found to have remarkable effects on improvement of dyeability and improvement of color persistence and on hair damage due to dyeing, thereby completing the present invention.

Accordingly, an object of the present invention is to provide a one-component oxidative dyeing composition containing natural ingredients capable of improving dyeability and color sustainability and alleviating damage to hair, and a mixed additive for an oxidative dyeing agent containing the natural component.

In order to achieve the above object, the present invention provides a one-component oxidative type hair dye composition containing a natural component, which is a mixture of one or more selected from green tea polysaccharide, monosial polysaccharide, peony root, licorice root, A blend additive for hair dyeing agent is provided.

Hereinafter, the present invention will be described in detail.

The present invention relates to an oxidative dyeing composition comprising one dosage form containing an oxidation dye precursor, a coupler and an oxidizing agent,

The above-mentioned one-type oxidative type hair dye may be powdered with one or more natural ingredients selected from green tea polysaccharide, monosial polysaccharide, peony root, lotus root, extract; concentrate; Or a mixture thereof, wherein the natural component is further contained as a mixed additive for an oxidative dye for hair dye.

More particularly, the present invention relates to a method for producing a green tea polysaccharide (hereinafter, referred to as " green tea polysaccharide ") in a one-component oxidative type hair dye containing an oxidative dye precursor, a coupler and an oxidizer, a thickener, a chelating agent, a flavoring agent, a surfactant, a pH adjusting agent, Selected from the group consisting of green tea polysaccharide, white tea polysaccharide, peony root, licorice root, and haniksucheko in combination with at least one natural ingredient selected from the group consisting of granular polysaccharide, The present invention provides an oxidized hair dye composition which improves dyeability to hair by using at least one natural component to improve color reproducibility and durability.

The present invention provides a one-component oxidative dyeing composition comprising an oxidation dye precursor, a coupler and an oxidizing agent, a thickener, a chelating agent, a flavoring agent, a surfactant, a pH adjusting agent, a stabilizer, a dispersing oil agent,

The above-mentioned one-type oxidative type hair dye may be powdered with one or more natural ingredients selected from green tea polysaccharide, monosial polysaccharide, peony root, lotus root, extract; concentrate; Or a mixture thereof. The present invention is characterized in that it is a one-pack type oxidative salt hair dye composition.

The green tea polysaccharide according to the present invention is prepared by removing the chlorophyll and the low molecular weight polyphenol from the ground green tea powder by a solvent extraction process, concentrating the green tea polysaccharide extract obtained by hot water extraction to remove the low molecular weight free protein by ultrafiltration, The final ultrafiltration concentrate is precipitated green tea polysaccharide precipitated through vacuum precipitation to obtain a powdery green tea polysaccharide. The purified polysaccharide is obtained by concentrating the extract with water added to the dried cottonseed leaves under reduced pressure, The free protein of the molecular weight is removed, and the resulting ultrafiltration concentrate is subjected to a precipitation reaction to precipitate the untranslated polysaccharide by vacuum drying to obtain a powdery, monolithic polysaccharide.

Peonies are peonies and Paeonia ( Paeoniaceae ) Lactiflora is a cultivar whose cultivation history is older than peonies. It is called peony or peony in particular, and it is called peony root in peony root and peeled peony root in peony root. It is called a peony. The peony root according to the present invention is obtained by pulverizing a dried peony in a pulverizer, but it can also be used in the form of an extract extracted with water or an organic solvent or a mixed solvent of an organic solvent and water.

The root of the lotus root according to the present invention can be used in the form of a lotus root powder obtained by pulverizing a dried lotus root with an average particle size of 36 to 39 탆 in a pulverizer. In the present invention, a powder having a size of 36 to 39 탆 is used in consideration of easiness of mixing with a hair dye and the like. However, the present invention is not limited to the particles of this size, and powders smaller or larger than this size may be used. The lotus root extract or the lotus root extract may be concentrated and used as a lotus root concentrate. The organic solvent may be at least one selected from the group consisting of ethanol, methanol, butanol, ether, ethyl acetate and chloroform, or a mixed solvent of these organic solvents and water may be used.

Eclipta prostrate ) is an annual plant of Asteraceae having a height of 10 to 70 cm. The stem grows straight and has a bristle in the whole, and the branch comes out from the fleshy leaf, and one branch grows from the end of the branch again. Leaves are larvae with no petiole, short petiole, vermiform shape, length of 3 ~ 10 cm, width of 5 ~ 25 mm, with hard hairs on both sides, 3 large veins near base and small sawtooth on edge. The flower is head-shaped, hanging from one to two in the leaf from August to September, about 1 cm in diameter, 2 to 4.5 cm in diameter, and bell-shaped in flower shape, 5 mm in length and 6 to 7 mm in width, It is about 11 mm in diameter, with 5 to 6 gun leaves, green, long oval, and sharp. The tongue is white, 2.5 to 3 mm long, and about 0.4 mm wide. The tip is flat or split into 2 pieces. It is light green and the corolla is divided into 4 pieces. The fruit is ripened in black and the length is 2.8 mm. The other one has four apicals, the white protuberance, and there are no tangles. Because the black juice flows down when you break this grass, it is called the chief mackerel by using the black fish fish mackerel. It grows in low mountains of the south central part, the fields. In the outpost, there is nicotine and coumarin compound weddelolactone. The outpost contains saponin, nicotine, tannin, vitamin A, ecliptine, various kinds of triphen compound (α-terthienyl methanol and acetic acid ester etc.), and leaves include wedelolactone, demethylwedelolactone -7-glucoside). The granules according to the present invention may be used in the form of extracts extracted with water or an organic solvent or a mixed solvent of an organic solvent and water although the granules are dried and crushed by a pulverizer after being dried well.

The one-component oxidative type hair dye composition of the present invention may comprise the natural component as a mixed additive for a one-component oxidized spirit hair dye or an oxidative type hair dye, wherein the natural ingredient according to the present invention is present in an amount of 0.01 to 50 By weight based on the total weight of the total weight of the blend additive, and 0.01 to 100% by weight based on the total weight of the blend additive.

The natural component is contained in an amount of 0.01 to 50% by weight, preferably 0.1 to 30% by weight, based on the total weight of the one-part hair dyeing composition. If the content of the natural product is less than 0.01% by weight, improvement in dyeability, color sustainability, lightening of hair damage and irritation-mitigating properties do not appear effectively. If the content of the natural product exceeds 50% by weight, oxidation polymerization reaction of the dye is inhibited, Range.

In addition, the natural component may be further contained as a mixed additive for oxidative hair dyeing agent, and the mixed additive for oxidative hair dyeing agent contains 0.01 to 50% by weight, preferably 0.1 By weight to 30% by weight. If the content of the natural product is less than 0.01% by weight, it is not effective in improving dyeability, color sustainability and hair damage, and if it exceeds 50% by weight, oxidation polymerization reaction of the dye is inhibited, It is possible to alleviate hair damage after dyeing, and it is also effective in relieving irritation caused by dyeing.

The one-component oxidative dyeing composition according to the present invention contains an oxidation dye precursor and a coupler, preferably two or more oxidation dye precursors and a coupler.

As the oxidation dye precursor and the coupler, most oxidation dye precursors and couplers known in the art can be used. Examples of such oxidation dye precursors include, but are not limited to, o-aminophenol, p-aminophenol, p-phenylenediamine, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, , 5-diamine, p-phenylenediamine sulfate, p-methylaminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate and p- . Examples of the coupler include 2-methyl-5-hydroxyethylaminophenol, p-amino-ocresol, m-aminophenol, 2,4-diaminophenoxyethanol hydrochloride, m-phenylenediamine hydrochloride, m -Phenylene diamine,? -Naphthol, resorcinol, 2-methylresorcinol and the like can be used. And can be used in combination with the oxidation dye precursor to exhibit various hues on the hair.

The one-component oxidative dyeing composition of the present invention may contain direct dyes or natural dyes to the extent that the object of the present invention is not impaired, and the direct dyes include Arianol dyes, p-nitro phenylenediamine, nitro-p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro-p-phenylenediamine hydrochloride, (Henna) can be used. Natural dyes can be various raw materials such as green tea, wool, logwood, gardenia, cochinil, cacao, red pepper, henna and safflower.

In addition, the single component type oxidative salt hair dye composition of the present invention can be used in a range that does not impair the effect of the present invention. For example, antioxidants, metal sequestrants, solvents, surfactants, thickeners, perfumes, and conditioning agents are used, but they are not particularly limited as they can be commonly used in hair dyeing agents.

Examples of the antioxidant include butylhydroxyanisole, dibutylhydroxytoluene, tertiary butylhydroquinone and tocopherols. Examples of the metal sequestering agent include EDTA, disodium iodide, tetrasodium- Ethanol, propyl alcohol, isopropyl alcohol, propylene glycol, hexylene glycol, diethylene glycol and the like can be used as the solvent, and as the surfactant, a cationic interface Anionic surfactant or nonionic surfactant can be used. As the above-mentioned thickener, a higher alcohol having 12 to 22 carbon atoms can be used singly or as a mixture, and a polymer thickener, a nonionic polymer and an anionic polymer, a paraffin And hard flowing isoparaffin. Examples of the conditioning agent include a cationic polymer, a quaternary ammonium salt, And the like can be used.

The oxidizing agent of the one-pack type oxidative dyeing composition according to the present invention is characterized by being selected from the group of peroxides, wherein the peroxide group is selected from the group consisting of sodium perborate, sodium percarbonate, peracetic acid, potassium permanganate, ammonium persulfate, potassium persulfate, At least one selected from sodium sulfate, calcium peroxide, barium peroxide and sodium peroxide can be selected and used.

The present invention relates to a pharmaceutical composition comprising at least one natural component selected from the group consisting of green tea polysaccharide, polyunsaturated polysaccharide, peony root, lotus root, extract; concentrate; Or a mixture thereof; and a mixed additive for a one-component oxidative type hair dye or an oxidative type hair dye.

The present invention relates to a method for the preparation of a medicament for the treatment of cancer, comprising: a) powdering one or more natural components selected from green tea polysaccharide, monoclonal polysaccharide, peony root, licorice root, extract; concentrate; Or a mixture thereof in an amount of 0.01 to 50% by weight based on the total weight;

b) applying the hair dye to the hair using the hair dye in an amount of 20 to 30 parts by weight based on 100 parts by weight of the hair to be dyed; And

c) After the dyeing, the hair is wrapped with a hair protecting film and left at room temperature for 10 to 30 minutes to wash the dyed hair with a rinsing agent and a shampooing agent, followed by a post-treatment step. And provides a dyeing method.

More specifically, the one-pack type oxidative dyeing agent according to the present invention was mixed with water at a ratio of 1:10, and then the hair was applied to the hair twice as much as the hair weight. The hair was allowed to stand for 30 minutes, Clean the hair with rinse and shampoo, dry and finish.

The present invention also relates to a method for preparing a dye-sensitized solar cell comprising the steps of: a) mixing a one-component oxidative dye containing an oxidative dye precursor, a coupler and an oxidizing agent with water;

b) powdering at least one natural ingredient selected from the group consisting of green tea polysaccharide, mannose polysaccharide, peony root, licorice root, and haniksiko; extract; concentrate; Or a mixture thereof in an amount of 0.01 to 100% by weight based on the total weight of the mixed additive for oxidative hair dyeing agent;

c) applying the hair dye containing the blending additive to hair in an amount of 20 to 30 parts by weight based on 100 parts by weight of the hair to be dyed; And

d) wrapping the hair after the dyeing with a hair protecting film, leaving the hair at room temperature for 10 to 30 minutes, washing the dyed hair with a rinsing agent and a shampoo, and drying the hair;

The present invention provides a dyeing method using a set of one-component oxidative dyeing agent set.

More specifically, when 1 g of the oxidizing type hair dye is mixed with water at a ratio of 10 g: 100 g, 1 g of the mixed additive for oxidative hair dye according to the present invention is mixed together, Is applied to the hair and allowed to stand for 30 minutes, which is the usual time for leaving the hair dye. Then, the hair is washed with a rinse agent and a shampoo, followed by drying and finishing.

The 1-type oxidative type hair dye agent according to the present invention contains natural ingredients which are one or a mixture of two or more selected from green tea polysaccharide, monosaccharide polysaccharide, peony root, licorice root, and haniksikcho, so that they can be used as various minerals, vitamins, It has a considerable effect on stability and can also be pleasurable with a unique flavor.

The one-component oxidative type hair dye according to the present invention has high affinity to hair due to the natural components contained in the hair dye, thereby enhancing the dyeability of the hair, thereby preventing color fading of dyed hair, This has an excellent effect. In addition, after hair dyeing, the hair is protected and the damage is minimized, so that the effect of reducing hair damage is excellent and natural dyeing is possible.

The present invention will be described in more detail with reference to the following examples and experimental examples. However, the following examples and experimental examples are provided to aid understanding of the present invention, and the scope of the present invention is not limited by these examples and experimental examples in any sense.

[ Manufacturing example  One] Green tea polysaccharide  Produce

The green tea polysaccharide according to the present invention was prepared by pulverizing dried green tea leaves in a solvent extraction process, dispersing 10 kg of green tea powder (d50 = 100 to 100 탆) prepared by sieving and classification into 150 L of 95% (v / v) The mixture was stirred at room temperature and centrifuged to recover chlorophyll and green tea leaves from which low molecular weight polyphenols were removed. The recovered residue was dried once after repeating the solvent extraction step once. In the solvent extraction process, 125 L of water was added to the green tea powder from which the chlorophyll and the low molecular weight polyphenol had been removed, and the mixture was stirred at 35? For 7 hours to conduct hot water extraction.

The obtained green tea polysaccharide extract was filtered and recovered using a filter press machine, and then concentrated under reduced pressure at 62 ° C to 1/10 of the initial volume. Subsequently, the green tea polysaccharide concentrate was subjected to ultrafiltration (molecular weight cut off: 30,000 daltons) to remove low molecular weight free proteins, ethanol was slowly added at a rate of 100 ml / min in a 5-fold volume of the final ultrafiltration concentrate, followed by ethanol precipitation . The precipitated green tea polysaccharide was vacuum dried at 45? To obtain 250 g of powdery green tea polysaccharide.

[ Manufacturing example  2] Untreated polysaccharide  Produce

The washed polysaccharide according to the present invention was prepared by washing 10 kg of dried soft cotton leaves and adding 20 L of water, followed by stirring at room temperature for 24 hours. The obtained extract was filtered and recovered using a filter press device, and then concentrated under reduced pressure at 50? To 1/10 of the initial volume.

Subsequently, the concentrate was subjected to ultrafiltration (molecular weight cut off: 30,000 daltons) to remove low molecular weight free proteins, and ethanol of 5 times the volume of the final ultrafiltration concentrate was slowly added at a rate of 100 ml / min to effect ethanol precipitation Respectively. The precipitated monolithic polysaccharide was vacuum-dried at 45 DEG C to obtain 430 g of a powdery polysaccharide-like polysaccharide.

[ Manufacturing example  3] Peony powder

5 kg of peanut were dried well and then pulverized in a pulverizer to an average particle size of 36 to 39 mu m to produce peanut powder. In the present invention, a powder having a size of 36 to 39 mu m was used in consideration of ease of mixing with a hair dye and the like.

[ Manufacturing example  4] Lotus root powder

5 kg of dried lotus root was crushed in a pulverizer with an average particle size of 36 to 39 탆 to prepare a lotus root powder. In the present invention, a powder having a size of 36 to 39 탆 was used in consideration of ease of mixing with a hair dye and the like.

[ Manufacturing example  5] Hanshik Cho powder

5 kg of granules were dried well and then pulverized in a pulverizer with an average particle size of 36 to 39 탆 to prepare a granular powder. In the present invention, a powder having a size of 36 to 39 탆 was used in consideration of ease of mixing with a hair dye and the like.

 [ Example  1 to 17 and Comparative Example  One]

Using the natural ingredients prepared in Preparation Examples 1 to 5, the hair dyeing agents of Examples 1 to 8 and Comparative Example 1 were prepared with the compositions shown in Table 1 below.

The mixing additives for the oxidative salt hair dye were prepared using the natural ingredients prepared in Preparation Examples 1 to 5 and the compositions shown in Table 2 below.

[ Test Example  1] Evaluation of dyeability

(1) Evaluation of the salt bonding strength of the hair dye composition of Examples 1 to 8 and Comparative Example 1

In order to evaluate the salt-forming power of the hair dye composition of Examples 1 to 8 and Comparative Example 1, the hair dye composition of each formulation of Examples 1 to 8 and Comparative Example 1 in Table 1 was mixed with water at a ratio of 1:10 , Twice the weight of the hair, and applied evenly to the human hair of 12 cm in length. The hair used was one containing about 30% of gray hair.

After applying the hair dye to the hair, the hair was allowed to stand for 30 minutes, which was the usual time for leaving the hair dye. Then, the hair was washed with running water for 1 minute and dried using a hair drier. The dried hair was measured for color using a color difference meter (model: Hunterlab Labscan XE). The results were compared using the L ^* value, which is the brightness value measured by the colorimeter. The larger the L ^* value, the more bright the color, and the smaller the color, the darker the color. Therefore, the smaller the L ^* value after dyeing, the better the dyeability.

As shown in Table 3, the natural ingredients, which are one or two or more selected from the group consisting of green tea polysaccharide, monocotyl polysaccharide, peony root, licorice root, and haniksikcho in the hair dye composition according to the present invention have high affinity for hair, I could confirm.

(2) Evaluation of Salt Bonding Ability of Compositions of Examples 9 to 17

In the evaluation of the salt strength of the compositions of Examples 9 to 17, 1 g of each of the compositions of Examples 9 to 17 was mixed together when 10 g: 100 g of the one-form hair dye of Comparative Example 1 and water were mixed , Twice the weight of the hair, and applied evenly to the human hair of 12 cm in length. The hair used was one containing about 30% of gray hair.

After applying the hair dye to the hair, the hair was allowed to stand for 30 minutes, which was the usual time for leaving the hair dye. Then, the hair was washed with running water for 1 minute and dried using a hair drier. The dried hair was measured for color using a color difference meter (model: Hunterlab Labscan XE). The results were compared using the L ^* value, which is the brightness value measured by the colorimeter. The larger the L ^* value, the more bright the color, and the smaller the color, the darker the color. Therefore, the smaller the L ^* value after dyeing, the better the dyeability.

As shown in Table 4, the combination of the green hair polysaccharide, the monosaccharide polysaccharide, the peony root, the lotus root, and the one or two or more selected from the group consisting of green tea polysaccharide, peony root, It was confirmed that when the additives were mixed, the natural component had high affinity to the hair and excellent dyeability.

 [ Test Example  2] Color persistence evaluation

The hair dyed in Test Example 1 was put in a shampoo solution and shaken at a speed of 200 rpm for 30 minutes using a shaker, rinsed for 1 minute in flowing water, and dried with a hair dryer. After drying, the L ^* value was measured using a colorimeter and the color persistence was evaluated by using the value of? L ^* which is a difference from the lightness values of Tables 3 and 4. The smaller the value of ΔL ^* , the better the color persistence. The results are shown in Table 5 below.

As shown in Table 5, when a natural component, which is a mixture of one or more selected from the green tea polysaccharides, the unilamellar polysaccharides, the peony root, the licorice root, and the herbicide of the present invention, is added to the oxidizing type hair dyeing agent or the hair dye mixing additive, And the excellent durability of the clear color was confirmed.

[ Test Example  3] Hair Damage  evaluation

In order to evaluate the degree of damage to the hair of the hair dye containing the compositions of Examples 1 to 17 and Comparative Example 1, the hair dyed in Test Example 1 was evaluated according to the following criteria. The results are shown in Table 6 below.

As shown in Table 6, when the natural ingredients, which are one or two or more selected from the green tea polysaccharide, the polyunsaturated polysaccharide, the peony root, the licorice root, and the herbicide of the present invention, are added to the oxidizing type hair dyeing agent or the hair dyeing additive After hair dyeing, hair was protected and damage was minimized.

Claims (18)

1. An oxidation type hair dye composition comprising one formulation containing an oxidation dye precursor, a coupler and an oxidizing agent, The above-mentioned one-shot type oxidative type hair dye agent is a natural component; extract; concentrate; Or a mixture thereof. ≪ RTI ID = 0.0 > 1. < / RTI > The method according to claim 1, Wherein the natural component further comprises a green tea polysaccharide from which chlorophyll, low molecular weight polyphenol and low molecular weight free protein are removed from the green tea. The method according to claim 1, Wherein said natural polysaccharide further comprises a monosaccharide polysaccharide from which a low molecular weight free protein is removed from a monocotyledonous leaf. The method according to claim 1, Wherein the natural component further comprises a lotus root. 5. The method according to any one of claims 1 to 4, Wherein the natural component is contained in an amount of 0.01 to 50% by weight based on the total weight of the hair dye composition. 5. The method according to any one of claims 1 to 4, Wherein the oxidizing agent of the hair dye composition is selected from the group of peroxides. The method according to claim 6, Wherein the peroxide group is at least one selected from sodium perborate, sodium percarbonate, peracetic acid, potassium permanganate, ammonium persulfate, potassium persulfate, sodium persulfate, calcium peroxide, barium peroxide and sodium peroxide. ≪ / RTI > A hair dye preparation set comprising the oxidized type hair dye composition of claim 1, Powder as a natural ingredient; extract; concentrate; Or a mixture thereof. The mixed additive for a one-component oxidative type hair dyeing agent. 10. The method of claim 9, A green tea polysaccharide in which chlorophyll, low molecular weight polyphenol and low molecular weight free protein are removed from the green tea as the natural ingredient. 10. The method of claim 9, Wherein said natural polysaccharide further comprises a monosaccharide polysaccharide from which a low molecular weight free protein is removed from a cotton bud. 10. The method of claim 9, A mixed additive for a one-component oxidative type hair dye containing a lotus root as the natural component. A set of oxidative hair dye formulations comprising the mixed additive for the oxidized type hair dye formulation of any one of claims 9 to 12. a) Powder as a natural ingredient; extract; concentrate; Or a mixture thereof in an amount of 0.01 to 50% by weight based on the total weight; b) applying the hair dye to the hair using the hair dye in an amount of 20 to 30 parts by weight based on 100 parts by weight of the hair to be dyed; And c) wrapping the hair after the dyeing with a hair protecting film, leaving the hair at room temperature for 10 to 30 minutes, washing the dyed hair with a rinsing agent and a shampoo, and drying the hair; Wherein the method comprises the steps of: a) mixing a one-component oxidative type hair dye containing an oxidation dye precursor, a coupler and an oxidizing agent with water; b) Powdered peony as a natural ingredient in the hair dye formulation; extract; concentrate; Or a mixture thereof in an amount of 0.01 to 100% by weight based on the total weight of the mixed additive for oxidative hair dyeing agent; c) applying the hair dye containing the blending additive to hair in an amount of 20 to 30 parts by weight based on 100 parts by weight of the hair to be dyed; And d) wrapping the hair after the dyeing with a hair protecting film, leaving the hair at room temperature for 10 to 30 minutes, washing the dyed hair with a rinsing agent and a shampoo, and drying the hair; Wherein the method comprises the steps of: 16. The method according to claim 14 or 15, Wherein the green tea polysaccharide further comprises a green tea polysaccharide from which the chlorophyll, the low molecular weight polyphenol and the low molecular weight glass protein are removed from the green tea as the natural ingredient. 16. The method according to claim 14 or 15, Wherein said natural polysaccharide further comprises a monosaccharide polysaccharide from which a low molecular weight free protein is removed from said monocotyledonous leaves. 16. The method according to claim 14 or 15, A dyeing method using a one-pack type oxidative dye set containing a lotus root as the natural component.