KR101826006B1 - Hair cosmetic composition containing natural dyeing material - Google Patents
Hair cosmetic composition containing natural dyeing material Download PDFInfo
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- A—HUMAN NECESSITIES
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- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
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- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
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Abstract
본 발명은 천연 염료 성분을 함유하는 모발용 화장료 조성물에 관한 것으로서, 보다 상세하게는 발색제로서 무쿠나추출물과 저분자 페놀류를 함유하고 매염제로서 수용성 금속화합물을 함유하여 모발에 대한 염색효과가 우수하며, 샴푸 등의 제형으로 제공가능하여 사용상의 편의성이 높은 모발용 화장료 조성물에 관한 것이다.The present invention relates to a hair cosmetic composition containing a natural dye component. More particularly, the present invention relates to a hair cosmetic composition containing a mucuna extract and a low molecular phenol as a coloring agent and a water-soluble metal compound as a mordant for excellent dyeing effect on hair, To a cosmetic composition for hair which is easy to use.
Description
본 발명은 천연 염료 성분을 함유하는 모발용 화장료 조성물에 관한 것으로서, 보다 상세하게는 발색제로서 무쿠나추출물과 저분자 페놀류를 함유하고 매염제로서 수용성 금속화합물을 함유하여 모발에 대한 염색효과가 우수한 모발용 화장료 조성물에 관한 것이다.
The present invention relates to a cosmetic composition for hair containing natural dye components, and more particularly to a cosmetic composition for hair which has a mucuna extract and a low molecular phenol as a coloring agent and contains a water-soluble metal compound as a mordant agent and has excellent dyeing effect on hair .
산화염색용 염모제 조성물에 있어 자극취의 원인은 크게는 환원제와 알칼리제이며, 무엇보다 알칼리제인 암모니아가 가장 큰 원인이라 할 수 있다. The cause of irritation in the hair dye composition for oxidation dyeing is largely a reducing agent and an alkali agent, and ammonia which is an alkaline agent is the most important cause.
염모제의 1제식, 2제식 또는 3제식에 함유되는 알카리제로서는 암모니아, 에탄올아민, 탄산염 등을 들 수 있으나, 에탄올아민은 잔류성이 강하고, 모발 손상이나 피부 자극 등의 결점을 가지며, 또한, 탄산염은 과산화수소에 의한 탈색력이나 염모력을 강하게 하는 효과가 약하기 때문에, 모발의 색조를 그다지 밝게 할 수 없는 결점을 가진다. 이에 대해, 암모니아는 모발이나 두피 등에 잔류하지 않고, 모발 손상이나 피부 염증 등을 일으킬 우려도 없는 등 안전성이 우수하며, 더욱이 과산화수소의 탈색력이나 염모력을 충분히 강하게 하는 성질을 가지기 때문에, 가장 일반적으로 사용되고 있다. Examples of the alkaline agent to be contained in the formula 1, the formula 2 or the formula 3 of the hair dye include ammonia, ethanolamine, carbonate and the like. However, the ethanolamine is highly persistent and has defects such as hair damage and skin irritation. It has a drawback that it can not brighten the hue of the hair because the effect of strengthening the decolorizing power or salt strength by hydrogen peroxide is weak. On the other hand, since ammonia does not remain on hair or scalp, and does not cause hair damage or skin inflammation, it is excellent in safety. Further, since ammonia has a property of sufficiently strong decolorizing power and salt strength of hydrogen peroxide, .
그러나, 암모니아는 시술시에 특유의 자극성 냄새가 나고, 특히 모발의 명도를 높게 하는 경우, 다량 배합할 필요가 있기 때문에, 강렬한 자극성 냄새를 가지며, 불쾌감을 부여하는 큰 결점을 가지고 있다. 이러한 결점을 해소하기 위하여 단순히 암모니아 배합량을 낮추게 되면, 탈색이나 염색성능이 대폭 저하되어 버리는 문제점이 있다.However, since ammonia peculiarly irritating odor is produced at the time of the procedure, especially when the lightness of the hair is increased, it is necessary to mix a large amount of ammonia. Therefore, the ammonia has a strong irritating odor and has a great disadvantage of imparting discomfort. If the amount of ammonia is simply lowered in order to overcome such drawbacks, there is a problem that the decolorization or dyeing performance is significantly deteriorated.
한편, 무쿠나 프루리엔스(Mucuna pruriens)는 벨벳콩(velvet bean)으로도 불리는 열대 지방의 1년생 콩과식물이다. 무쿠나 프루리엔스는 사료로서 사용되며, 질소 고정 능력이 있어 토양을 비옥하게 할 수 있다. 또한 “네스카페(Nescafe)”로 불리는 커피 대용품으로서도 사용될 수 있으며, 강정제, 항우울제 등의 약리학적 목적으로도 사용되었다. 또한 이는 뇌에서 신경 전달 물질인 도파민(dopamine)으로 전환되는 도파(dopa)의 원천이며, 도파민의 감소는 파킨슨 병과 관련되어 있는데 파킨슨 병에 걸린 사람은 도파민을 생성하는 뇌세포가 파괴된다. 또한 무쿠나 프루리엔스는 콜린에스테라아제의 제해제인 부포테닌(bufotenine)과 학습, 수면, 기분의 조절과 관련된 뇌신경 전달 물질인 세로토닌(serotonine)을 함유하고 있다. Mucuna pruriens , on the other hand, is a tropical first-year soybean plant, also called velvet bean. Mukunapururiense is used as a feed and has a nitrogen fixation capability that can fertilize the soil. It can also be used as a coffee substitute called "Nescafe", and it has also been used for pharmacological purposes such as antidepressants and antidepressants. It is also a source of dopa that is converted to dopamine, a neurotransmitter in the brain. Dopaminergic depression is associated with Parkinson's disease. In people with Parkinson's disease, brain cells that produce dopamine are destroyed. Mucuna pruriente also contains bufotenine, a release of cholinesterase, and serotonine, a neurotransmitter involved in learning, sleeping, and controlling mood.
무쿠나 프루리엔스의 씨앗은 검정 또는 갈색이며, 이로부터 추출한 무쿠나 프루리엔스 추출물을 모발 염색에 이용하기 위해서는 알칼리제와 산화제를 사용하여야 하는데, 알칼리제와 산화제는 두피자극과 모발손상을 초래할 수 있고 무쿠나 추출물 자체의 발색력과 모발 부착력이 약해 일반 염모제에 비해 염색효과와 색상지속력이 떨어진다는 문제점이 있다.
The seeds of Mukunapururiense are black or brown. To use Mukunapururiensu extract extracted from them, an alkaline agent and oxidizing agent should be used for hair dyeing. Alkali agents and oxidants may cause scalp stimulation and hair damage There is a problem in that the coloring power of the mukuna extract and the hair adhesion are weak and the dyeing effect and the color sustainability are inferior to the general hair dye.
이에 본 발명자들은 특유의 자극성 냄새를 가지는 알칼리제인 암모니아를 사용하지 않으면서 염색력을 높이고, 빠르고 간편하게 염색이 가능하며, 천연 염료 성분을 사용하여 두피에 대한 자극은 줄이고 모발 손상을 최소화하고자 하였으며, 발색제로서 식물 추출물인 무쿠나 프루리엔스 추출물과 함께 저분자 페놀류를 사용하고 매염제로서 수용성 금속화합물을 사용하면 모발에 대한 염색효과와 색상지속성이 증가됨을 발견하고 본 발명을 완성하게 되었다.Therefore, the present inventors intend to increase the dyeing power without using an ammonia, which is a specific irritant odorant, and to quickly and easily dye the hair, to reduce the stimulation to the scalp and minimize hair damage by using a natural dye component, The present inventors have found that the use of a water-soluble metal compound as a mordanting agent increases the dyeing effect and color persistence of hair with the use of a low molecular weight phenol compound together with a plant extract, mucuna pruriente extract and a mordanting agent.
따라서, 본 발명의 목적은 식물 추출물인 무쿠나 프루리엔스 추출물을 발색제로서 사용하여 모발 및 두피에 대한 안전성을 높이고, 모발 염색효과와 색상지속성이 우수하며, 사용이 간편한 모발용 화장료 조성물을 제공하는 것이다.
Accordingly, it is an object of the present invention to provide a cosmetic composition for hair which uses Mucuna pruriente extract, which is a plant extract, as a coloring agent to enhance safety against hair and scalp, has excellent hair dyeing effect and color persistence, and is easy to use .
상기한 목적을 달성하기 위하여, 본 발명은 무쿠나 추출물, 저분자 페놀류 및 수용성 금속화합물을 함유하는 모발용 화장료 조성물을 제공한다.
In order to achieve the above object, the present invention provides a hair cosmetic composition containing mucuna extract, low-molecular phenols and a water-soluble metal compound.
본 발명은 천연 염료 성분을 사용함으로써 모발 및 두피에 대한 안전성을 높일 수 있고, 우수한 염색효과와 색상지속력을 제공할 수 있으며, 샴푸 등의 제형으로 제공가능하여 사용상의 편의성이 높다.
The present invention can increase the safety of hair and scalp by using natural dye components, can provide excellent dyeing effect and color sustainability, and can be provided as a form such as shampoo, which is convenient for use.
본 발명은 무쿠나 추출물, 저분자 페놀류 및 수용성 금속화합물을 함유하는 모발용 화장료 조성물에 관한 것으로서, 상기 무쿠나 추출물과 페놀류는 발색제로서 사용되고 상기 수용성 금속화합물은 매염제로서 사용된다. 또한 본 발명의 조성물은 2제형의 조성물로 제형화되며, 이는 상기 무쿠나 추출물과 저분자 페놀류를 포함하는 1제와 수용성 금속화합물을 포함하는 2제, 또는 상기 수용성 금속화합물을 포함하는 1제와 무쿠나 추출물과 저분자 페놀류를 포함하는 2제로 이루어진다.The present invention relates to a cosmetic composition for hair containing mucuna extract, low-molecular phenols and a water-soluble metal compound, wherein the mucuna extract and phenols are used as a coloring agent and the water-soluble metal compound is used as a mordant. In addition, the composition of the present invention is formulated into a two-part formulation, which is a two-component formulation containing a water-soluble metal compound and an agent containing a water-soluble metal compound, It consists of a two-component system containing a Kuna extract and a low-molecular-weight phenol.
이하, 본 발명에 대하여 보다 상세히 설명한다. 다만, 편의상 발색제는 1제에 포함되고, 매염제는 2제에 포함되는 것을 기준으로 본 발명의 조성을 설명한다.Hereinafter, the present invention will be described in more detail. However, for convenience, the composition of the present invention will be described based on that the coloring agent is included in the first agent and the mordant agent is included in the second agent.
본 발명에서 사용되는 무쿠나 추출물은 바람직하게는 무쿠나 프루리엔스(Mucuna pruriens)의 씨에서 추출한 것이다. The mucuna extract used in the present invention is preferably extracted from the seeds of Mucuna pruriens .
본 발명에서 사용하는 무쿠나 추출물의 추출방법은 당업계에서 사용하는 추출방법을 사용할 수 있으며, 예시적인 추출방법은 하기와 같다.The extraction method of Mukuna extract used in the present invention may be an extraction method used in the art, and an exemplary extraction method is as follows.
무쿠나 프루리엔스의 씨를 충분히 건조시킨 후 물 또는 유기용매를 넣고 환류 추출하여 침적시켰다. 그 후 여과포 여과와 원심분리를 통해 잔사와 여액을 분리하고, 분리된 여액을 감압 농축하여 용매를 제거하고 농축물을 동결건조하여 무쿠나 추출물을 얻었다. 본 발명에서 사용되는 유기용매는 에탄올, 메탄올, 부탄올, 에테르, 에틸아세테이트, 클로로포름 및 이들 유기용매와 물의 혼합용매로 이루어진 군에서 선택될 수 있으며, 바람직하게는 80% 에탄올이 사용된다.The seeds of Mukunapururians were thoroughly dried, and then water or an organic solvent was added thereto, followed by reflux extraction for deposition. Thereafter, the residue and the filtrate were separated by filtration and centrifugation through a filter cloth, and the separated filtrate was concentrated under reduced pressure to remove the solvent. The concentrate was lyophilized to obtain Mukuna extract. The organic solvent used in the present invention may be selected from the group consisting of ethanol, methanol, butanol, ether, ethyl acetate, chloroform, and a mixed solvent of these organic solvents and water, preferably 80% ethanol.
본 발명의 조성물에서 무쿠나 추출물은 1제의 조성물 총 중량에 대하여 0.1~5.0중량%의 양으로 함유된다. In the composition of the present invention, mucuna extract is contained in an amount of 0.1 to 5.0% by weight based on the total weight of the composition of one agent.
이는 0.1중량% 미만으로 사용하면 염색성, 색상지속성 향상에 효과가 없으며, 5.0중량%를 초과하면 추출물이 과포화 용해되면서 제형 내에서 침전되거나 석출될 수 있기 때문에, 상기 범위로 사용하는 것이 바람직하다.If it is used in an amount of less than 0.1% by weight, it is not effective in improving dyeability and color persistence. If it exceeds 5.0% by weight, the extract may be precipitated or precipitated in supernatant while being supersaturated.
본 발명의 조성물에서는 발색제로서 무쿠나 추출물과 함께 저분자 페놀류를 사용한다. 저분자 페놀류는 이에 한정되는 것은 아니지만, 몰식자산, 살리실산, 카테킨, 카테콜, 바닐린, 바닐릭산, 페룰산, 시링산 등으로 이루어진 군으로부터 선택된 1종 이상의 것이다. 상기 저분자 페놀류는 1제의 조성물 총 중량에 대하여 0.1~10중량%의 양으로 함유된다. 이는 0.1중량% 미만으로 사용하면 염색성, 색상지속성 향상에 효과가 없으며, 10.0중량%를 초과하면 저분자 페놀류가 과포화 용해되면서 제형내 에서 침전되거나 석출될 수 있기 때문에, 상기 범위로 사용하는 것이 바람직하다.In the composition of the present invention, low molecular weight phenols are used together with mucuna extract as a coloring agent. The low-molecular phenols include, but are not limited to, at least one selected from the group consisting of gallic acid, salicylic acid, catechin, catechol, vanillin, vanillic acid, ferulic acid, The low molecular weight phenols are contained in an amount of 0.1 to 10% by weight based on the total weight of the composition of one agent. If it is used in an amount of less than 0.1% by weight, it is not effective in improvement in dyeability and color persistence. If it is more than 10.0% by weight, the low molecular weight phenols may be precipitated or precipitated in the form of a supersaturated solution.
또한, 본 발명에서 사용하는 저분자 페놀류는 분자량이 90~500g/mol 것으로 분자량이 500g/mol를 초과하는 것은 염료가 모발 큐티클 층 내부로 침투하지 못하므로 모발 염색성이 현저히 떨어지며, 또한 90g/mol 미만이 되면 발색이 되지 않는다. 따라서 저분자 페놀류의 분자량은 상기 범위로 사용하는 것이 바람직하다.The molecular weight of the low molecular weight phenols used in the present invention is in the range of 90 to 500 g / mol. When the molecular weight exceeds 500 g / mol, the dye can not penetrate into the hair cuticle layer, It does not develop color. Therefore, the molecular weight of the low molecular weight phenol is preferably within the above range.
본 발명의 조성물에서는 매염제로서 수용성 금속화합물을 사용한다. 수용성 금속화합물은 이에 한정되는 것은 아니지만, 염화제일철, 염화제이철, 황산제일철 및 황산제이철 등으로 이루어진 군으로부터 선택된 1종 이상의 것이다. 상기 수용성 금속화합물은 2제의 조성물 총 중량에 대하여 0.1~10중량%의 양으로 함유된다. 이는 0.1중량% 미만으로 사용하면 염색성, 색상지속성 향상에 효과가 없으며, 10.0중량%를 초과하면 수용성 금속화합물이 과포화 용해되면서 제형 내에서 침전되거나 석출될 수 있기 때문에, 상기 범위로 사용하는 것이 바람직하다.In the composition of the present invention, a water-soluble metal compound is used as a mordant. The water-soluble metal compound is not limited thereto, but is at least one selected from the group consisting of ferrous chloride, ferric chloride, ferrous sulfate and ferric sulfate. The water-soluble metal compound is contained in an amount of 0.1 to 10% by weight based on the total weight of the composition of the two agents. If it is used in an amount of less than 0.1% by weight, it is not effective in improving dyeability and color persistence. If it is more than 10.0% by weight, the water-soluble metal compound may be precipitated or precipitated in supernatant while supersaturated and dissolved. .
본 발명의 모발용 조성물은 1제 및 2제로 구성될 수 있으며, 헤어토닉, 모발 영양화장수, 헤어에센스, 헤어세럼 스칼프트리트먼트, 헤어트리트먼트, 헤어컨디셔너, 헤어샴푸, 헤어로션, 헤어염모제 등으로 제형화될 수 있다. 또한, 제형에 따라 적절한 성분을 함유할 수 있다.The composition for hair of the present invention may be composed of one or two agents and may be formulated into hair tonic, hair nutrition lotion, hair essence, hair serum scarf treatment, hair treatment, hair conditioner, hair shampoo, hair lotion, . It may also contain suitable ingredients depending on the formulation.
본 발명에 따른 모발용 화장료 조성물은 모발에 도포하기 직전에, 1제와 2제를 혼합하여 사용한다. 이때 1제:2제의 혼합비율은 일반적으로 1:1이나, 특별히 이 비율에 한정되는 것은 아니다. 혼합물의 도포시간은 일반적으로 1분 이상으로 하는 것이 바람직하지만, 특별히 이 시간에 한정되는 것은 아니다.
The cosmetic composition for hair according to the present invention is used by mixing a first agent and a second agent immediately before applying the composition to hair. In this case, the mixing ratio of 1: 2 is generally 1: 1, but it is not particularly limited to this ratio. The application time of the mixture is generally preferably not less than 1 minute, but is not particularly limited to this time.
이하, 실시예 및 실험예를 들어 본 발명을 상세히 설명하지만, 본 발명이 이들 예로만 한정되는 것은 아니다.
Hereinafter, the present invention will be described in detail with reference to Examples and Experimental Examples, but the present invention is not limited thereto.
[참고예 1] 무쿠나 추출물의 제조[Referential Example 1] Preparation of mucuna extract
무쿠나 프루리엔스(Mucuna pruriens)의 씨 1kg을 깨끗이 씻은 후 열풍 건조기를 사용하여 70℃에서 약 5시간 동안 건조시킨 후 분쇄시켰다. 상기 분쇄물을 5L의 에탄올/물(80/20 v/v)을 넣고 50℃에서 약 6시간 추출하였다. 추출액을 여과한 후 감압농축하여 용매를 제거하고 농축물은 동결건조하여 고형 분말을 제조하였다.
1 kg of the seeds of Mucuna pruriens was thoroughly washed and dried at 70 ° C for about 5 hours using a hot air drier and then pulverized. The pulverized product was extracted with 5 L of ethanol / water (80/20 v / v) at 50 ° C for about 6 hours. The extract was filtered and concentrated under reduced pressure to remove the solvent. The concentrate was lyophilized to prepare a solid powder.
[참고예 2] 실시예 및 비교예의 제조[Referential Example 2] Preparation of Examples and Comparative Examples
하기 표 1의 조성으로 통상적인 방법을 이용하여 1제와 2제로 구성된 샴푸 조성물을 제조하였다.A shampoo composition consisting of one-part and two-part was prepared by a conventional method with the composition shown in Table 1 below.
[시험예 1] 염색력 평가[Test Example 1] Dyeing force evaluation
상기 실시예 1~2 및 비교예 1~3의 염색력을 평가하기 위하여 흰머리가 30% 포함된 길이 12cm, 무게 1g의 모발트레스를 물에 충분히 적신 후 시료의 1제와 2제의 양을 동일하게 5g씩 취해 혼합한 후 샴푸하였다. 3분 경과 후 흐르는 물에 1분간 세척한 후 헤어드라이어를 이용해 건조시켰다. 위 과정을 10회 반복 후 건조된 모발을 색차계(기종: Hunterlab Labscan XE)를 이용하여 색을 측정하였다. 결과는 색차계로 측정한 샴푸전후의 L*값의 변화를 이용하여 비교하였으며, L*값은 명도를 나타내는 수치로써 L*값이 클수록 색이 밝음을 의미한다. 따라서 샴푸전후의 밝기차이인 ΔL*값이 클수록 보다 색이 진하게 표현되는 것을 의미하며 염색력이 우수함을 뜻한다. 결과는 하기 표2에 나타내었다.To evaluate the dyeing powers of Examples 1 to 2 and Comparative Examples 1 to 3, hair tresses having a length of 12 cm and a weight of 1 g containing 30% of gray hair were thoroughly soaked in water, and then the amounts of the first and second samples were the same 5 g each was taken, mixed and shampooed. After 3 minutes, it was washed with running water for 1 minute and then dried using a hair dryer. After repeating the above procedure 10 times, the dried hair was measured for color using a color difference meter (model: Hunterlab Labscan XE). The results were compared using the change of L * value before and after the shampoo measured by the colorimeter. L * value is a value indicating the lightness, and the larger the L * value, the brighter the color. Therefore, the larger the ΔL * value, the difference in brightness before and after shampooing, means the darker the color is expressed and the better the dyeing power. The results are shown in Table 2 below.
상기 표2에서 보는 것과 같이 무쿠나추출물과 저분자 페놀류인 몰식자산과 살리실산, 그리고 수용성 금속화합물인 황산제일철7수화물을 함께 사용한 실시예1∼2이 조분자 페놀류 및 수용성 금속화합물 중 1가지만을 함유하거나 2가지 모두 함유하지 않은 비교예1∼3보다 염색력이 훨씬 우수함을 알 수 있다.
As shown in Table 2, in Examples 1 and 2, in which mucuna extract, low molecular weight phenol, gallic acid and salicylic acid, and ferrous sulfate heptahydrate, which is a water-soluble metal compound, were used together, they contained only one of the crude molecular phenol and water- It can be seen that the dyeing power is much better than those of Comparative Examples 1 to 3 which do not contain branches.
[시험예 2] 색상지속력 평가[Test Example 2] Evaluation of color sustainability
실시예 1~2와 비교예3의 색상지속력을 평가하기 위해 시험예1의 모발트레스를 소듐폴리옥시에칠렌라우릴에텔설페이트 28% 용액에 넣은 후 쉐이커를 이용하여 30분간 200rpm의 속도록 흔들어 준 후 흐르는 물에 1분간 헹구어 헤어드라이어로 건조하였다. 건조 후 색차계를 이용하여 L*값을 측정하여 시험예1의 최종명도값과의 차이인 ΔL*값을 이용해 색상 지속성을 평가하였다. ΔL*값이 작을수록 색상지속력이 우수함을 의미한다. 결과는 하기 표 3에 나타내었다.To evaluate the color sustainability of Examples 1 to 2 and Comparative Example 3, the hair tress of Test Example 1 was put into a 28% solution of sodium polyoxyethylene lauryl ether sulfate and shaken at 200 rpm for 30 minutes using a shaker Rinsed in running water for 1 minute and dried with a hair dryer. After drying, the L * value was measured using a colorimeter, and the color persistence was evaluated by using the value of? L *, which is a difference from the final brightness value of Test Example 1. The smaller the value of ΔL *, the better the color sustainability. The results are shown in Table 3 below.
상기 표 3에서 보는 바와 같이, 비교예 3의 경우는 명도값 차이가 크게 나타나 색상지속력이 떨어지지만, 실시예 1~2는 명도값의 차이가 적어 비교예 3보다 색상지속력이 훨씬 우수함을 알 수 있다.As shown in Table 3, in the case of Comparative Example 3, the difference in brightness value was large and the color sustainability was poor. However, in Examples 1 and 2, the color persistence was much better than that in Comparative Example 3 have.
Claims (11)
수용성 금속화합물을 포함하는 제2제
로 이루어지는 2제형의 모발용 화장료 조성물로서,
상기 저분자 페놀류는 살리실산; 및 몰식자산, 카테킨, 카테콜, 바닐린, 바닐릭산, 페룰산 및 시링산으로 이루어진 군에서 선택된 1종 이상의 혼합물이고,
상기 수용성 금속화합물은 황산제일철 및 황산제이철로 이루어진 군에서 선택된 1종 이상인, 모발용 화장료 조성물.A first agent comprising a mucuna extract and a low molecular weight phenol as a coloring agent; And
A second agent comprising a water-soluble metal compound
(2) a cosmetic composition for hair,
The low molecular weight phenols include salicylic acid; And mixtures of at least one member selected from the group consisting of gallic acid, catechin, catechol, vanillin, vanillic acid, ferulic acid and sialic acid,
Wherein the water-soluble metal compound is at least one selected from the group consisting of ferrous sulfate and ferric sulfate.
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