WO2010059845A2 - Sailcloth - Google Patents
Sailcloth Download PDFInfo
- Publication number
- WO2010059845A2 WO2010059845A2 PCT/US2009/065174 US2009065174W WO2010059845A2 WO 2010059845 A2 WO2010059845 A2 WO 2010059845A2 US 2009065174 W US2009065174 W US 2009065174W WO 2010059845 A2 WO2010059845 A2 WO 2010059845A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- yarn
- fill
- warp
- sailcloth
- cloth
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63H—MARINE PROPULSION OR STEERING
- B63H9/00—Marine propulsion provided directly by wind power
- B63H9/04—Marine propulsion provided directly by wind power using sails or like wind-catching surfaces
- B63H9/06—Types of sail; Constructional features of sails; Arrangements thereof on vessels
- B63H9/067—Sails characterised by their construction or manufacturing process
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/44—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific cross-section or surface shape
- D03D15/46—Flat yarns, e.g. tapes or films
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/49—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads textured; curled; crimped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63H—MARINE PROPULSION OR STEERING
- B63H9/00—Marine propulsion provided directly by wind power
- B63H9/04—Marine propulsion provided directly by wind power using sails or like wind-catching surfaces
- B63H9/06—Types of sail; Constructional features of sails; Arrangements thereof on vessels
- B63H9/067—Sails characterised by their construction or manufacturing process
- B63H9/0678—Laminated sails
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/20—Metallic fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/04—Heat-responsive characteristics
- D10B2401/041—Heat-responsive characteristics thermoplastic; thermosetting
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/18—Outdoor fabrics, e.g. tents, tarpaulins
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2507/00—Sport; Military
- D10B2507/04—Sails
Definitions
- Sailcloth is typically made from a variety of materials, with one of the most common being a tightly woven cloth of polyester yarns. Sailcloth is one of the most tightly woven textiles in the world and requires extensively modified heavy looms to generate the necessary forces to attain such a dense construction.
- polyester sailcloth is only woven in what is known as a plain weave, in which every warp yarn passes over and under each fill yarn, with the yarns being crimped over each other. After weaving, the cloth is impregnated with a resin and heated, causing the resin to cure and also causing the polyester fabric to shrink.
- the above described weaving method tends to impart certain characteristics to the cloth due to the nature of the operation itself.
- the warp yarns, which run in the machine on long direction tend to crimp more than the weft or fill yarns, which run in the cross machine direction.
- Sails formed from such cloth are made up of a number of joined panels, and it is desirable to align the yarns with less crimp along directions of maximum stress or load in the sail. This, in turn, reduces stretch, which would otherwise cause the sail to lose its ideal or designed shape when subjected to increasing wind forces.
- the density of the warp of the as-woven cloth is from about 900-1500 and the density of the fill is greater than about 1000.
- the ratio of fill yarn weight to warp yarn weight is from about 1 : 1 to about 0.25 : 1.
- the warp yarns have a denier of from about 100-2000 and the fill yarns have a denier of from about 30-1000.
- the fabrics disclosed herein include warp yarns made of polyester, aramid, carbon, polyethylene, a thermoplastic yarn, and combinations thereof.
- the fabrics include textured fill yarns made of thermoplastic yarn, such as polyester, and may also include a flat filament yarn.
- a fabric may include a first fill yarn and a second fill yarn.
- the first fill yarn includes a first textured yarn
- the second fill yarn includes a second textured yarn.
- the first fill yarn and the second fill yarn are the same; in still other embodiments, the first fill yarn and the second fill yarn are made of different material; in still other embodiments, the first fill yarn is higher denier than the second fill yarn.
- a single shed comprises the first fill yarn and the second fill yarn.
- the present disclosure also describes method of manufacturing a woven cloth.
- Such methods include providing a warp yarn and a fill yarn, wherein the warp yarn includes a flat filament yarn and the fill yarn includes a yarn that has been modified so that the filaments do not lie substantially parallel to one another, for example a textured yarn.
- the method includes weaving the warp and fill yarns to form a cloth.
- the cloth is woven such that the density of the warp is from about 900-1500 and the density of the fill is greater than about 1000.
- the present disclosure also describes methods for manufacturing sails.
- the method includes providing a woven cloth or a woven sailcloth including a flat filament warp yarn and a fill yarn that includes a yarn that has been modified so that the filaments do not lie substantially parallel to one another, for example a textured yarn.
- the density of the as-woven warp is from about 900-1500 and the density of the fill is greater than about 1000.
- the warp yarn and the fill yarn comprises polyester.
- the method includes providing one or more panels formed from the woven cloth or the woven sailcloth, and positioning the one or more panels to form a sail. In some embodiments, the method includes positioning the panels such that the warp yarns are positioned generally parallel to, or approximately along a predicted load line of the sail.
- Figure 1 includes a table and a graph showing the results of stress tests on a fill oriented sailcloth.
- the warp was 150 denier, with an as-woven density of about 1715; the fill was about 350 denier with an as- woven density of about 1122.
- Strips of cloth 16 inches long and 2 inch wide were cut in the fill orientation or the bias (45%) orientation. strips were subject to a stretch test, or fluttered (whirled in a circle with one end free at 30 mph for 30 minutes; this is done on a specially constructed testing machine), and then stretched.
- Figure 2 includes a table and a graph showing the results of stress tests on a warp-oriented sailcloth.
- the warp oriented sailcloth was made of 100% polyester, flat-filament yarns in the warp orientation and 100% polyester textured yarn in the fill orientation.
- the warp yarns were 350 denier, with an as-woven density of about 973; the fill yarns were about 150 denier with density of about 1617.
- the graph and the table indicate that the bias-cut samples (Nr 1 and Nr 2) show 1% stretch at approximately at 18.3 pounds for the unfluttered sample, and 16.0 pounds for the flutter-treated sample. Note that these values similar to the bias cut-samples of the fill-oriented sailcloth of Figure 1.
- the warp-cut samples show 1% stretch at 78.2 and 75.4 pounds. These values are comparable, if not better, than those for the fill-cut samples of the fill-oriented sailcloth shown in Figure 1.
- Figure 4 is a diagram illustrating load lines or lines of force emanating from the corners of a triangular sail.
- Figure 5 is a scanning electron micrograph (SEM) of a sample of the woven fabric described herein.
- the fabric comprises yarns in which weave-crimp (crimp) is imparted to the fill yarns, leaving the warp yarns relatively uncrimped. This is accomplished by using textured yarn in the fill direction.
- the resulting cloth has more resistance to stretch in the warp orientation than in the fill orientation, and therefore provides a longer, continuous piece of fabric that can be aligned with anticipated loads or stresses.
- Such fabrics are useful, for example, in the manufacture of sails or architectural fabrics (e.g., awnings, tents, tension structures and the like).
- cloth and fabric are used interchangeably and refer to a pliable material made usually by weaving natural or synthetic fibers and/or filaments.
- the cloth or fabric is sailcloth.
- the term "yarn” or “yarns” means an assemblage of filaments or fibers, joined together to form a continuous strand.
- Non-limiting examples include materials having good tensile strength and stretch resistance.
- yarns include those composed of polyester, aramid, polyolefin, carbon, polyamids, and the like, as well as blends and composites, such as, for example, aramid blended or wrapped with polyester.
- yarns used in the present compositions and methods range in size from about 30 to about 2000 denier.
- the warp yarns may range in size from about 100 to about 2000 denier, from about 200 to about
- the term "density" of a fabric is determined by multiplying the square root of the yarn in denier which is a number proportional to the effective diameter of the yarn, by the yarns count per inch.
- the fabrics described herein have warp densities from about 900 to about 1500 and fill densities greater than about 1000. Or, more generally, the warp density will be less than the fill density.
- the fabric would comprise 52 yarns per inch of 350 denier polyester in the warp and 132 yarns per inch of 150 denier in the fill. Using the above density calculation, this would result in a cloth having a warp density of 973 and a fill density of 1617.
- the warp yarns (41) are relatively uncrimped as compared to the textured fill yarns (43), as illustrated by the scanning electron microscope photo shown in Figure 5, and the densities are sufficient to provide a fabric having good stretch resistance along the bias and the warp (see e.g., Figures 1 and 2).
- flat-filament warp yarns include, but are not limited to polyester, aramid, carbon, polyethylene, nylon, polypropylene, and combinations thereof.
- thermoplastic or textured yarns are incorporated into the warp along with the flat-filament yarns.
- flat filament yarns are incorporated into the fill along with the textured yarns.
- the majority of the yarns in the warp orientation are flat-filament, and the majority of yarns in the fill orientation are textured.
- materials such as fiberglass may be incorporated into the fabric to provide strength and rigidity for use.
- materials such as fiberglass may be incorporated into the fabric to provide strength and rigidity for use.
- architectural fabrics may include fiberglass to provide strength and rigidity.
- the fabrics disclosed herein can be formed by standard weaving methods known in the art, incorporating textured yarn in the fill orientation, and non-textured or flat-filament yarns in the warp orientation.
- the fabrics include multiple types of warp yarns, multiple types of fill yarns, or multiple yarns per shed.
- the warp and/or the fill may be formed using yarns of different denier and/or different material.
- the sailcloth is subjected to additional finishing operations.
- the fabric is first cleaned to remove any seizing.
- the fabric is dipped into an aqueous bath of heat curable resin, such as melamine, which serves to lock the woven geometry and decrease stretch.
- the fabric is then dried and heat-set by passing through an oven, causing the yarns to shrink, thereby increasing density.
- the fabric is then calendared by passing the fabric between a pair of rolls under high pressure, with one of the rolls being heated.
- the cloth may be used as such to construct a sail.
- the sail may be made of a single panel or it may be made of many panels. The panels are cut and arranged such that the uncrimped warp yarns follow the predicted major lines of stress in the sail when the sail is used (e.g., are generally parallel to the predicted load lines).
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Woven Fabrics (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011537622A JP5622742B2 (ja) | 2008-11-24 | 2009-11-19 | 帆布 |
EP09764130A EP2370313A2 (en) | 2008-11-24 | 2009-11-19 | Sailcloth |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/277,183 | 2008-11-24 | ||
US12/277,183 US7886777B2 (en) | 2008-11-24 | 2008-11-24 | Sailcloth |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010059845A2 true WO2010059845A2 (en) | 2010-05-27 |
WO2010059845A3 WO2010059845A3 (en) | 2011-05-19 |
Family
ID=42195137
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2009/065174 WO2010059845A2 (en) | 2008-11-24 | 2009-11-19 | Sailcloth |
Country Status (5)
Country | Link |
---|---|
US (1) | US7886777B2 (ja) |
EP (1) | EP2370313A2 (ja) |
JP (1) | JP5622742B2 (ja) |
KR (1) | KR20110094074A (ja) |
WO (1) | WO2010059845A2 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102660825A (zh) * | 2012-05-29 | 2012-09-12 | 吴江市博涵纺织有限公司 | 一种多功能芳纶面料 |
WO2018051211A1 (en) | 2016-09-13 | 2018-03-22 | Kiu On Hong Limited | Improved woven sailcloth |
US20190186055A1 (en) * | 2017-12-14 | 2019-06-20 | The Gap, Inc. | Yarn formed from recycled cotton and recycled para-aramid, and fabrics made therefrom |
KR20210040822A (ko) * | 2018-09-02 | 2021-04-14 | 친 왕 | 의복용 날염 직물 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6257160B1 (en) | 2000-03-07 | 2001-07-10 | Fred Aivars Keire | Sail of woven material and method of manufacture |
JP2005290575A (ja) | 2004-03-31 | 2005-10-20 | Toyobo Co Ltd | 手術着等に好適に使用できる織物 |
EP1705273A2 (en) | 2005-03-25 | 2006-09-27 | Roberto Bernasconi | Textile fabrics for clothing |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56159164A (en) * | 1980-05-13 | 1981-12-08 | Hiraoka Shokusen | Composite cloth silk having excellent tear strength |
US4444822A (en) * | 1983-03-21 | 1984-04-24 | Howe & Bainbridge | Sailcloth |
US4499842A (en) * | 1983-04-11 | 1985-02-19 | North Sails, Inc. | Sail cloth and sail made therefrom |
US4590121A (en) * | 1985-03-07 | 1986-05-20 | Peter Mahr | Sail cloth |
US4892780A (en) * | 1987-07-16 | 1990-01-09 | Cochran William H | Fiber reinforcement for resin composites |
JPH0823097B2 (ja) * | 1987-09-09 | 1996-03-06 | 東レ株式会社 | セールクロス |
US4864953A (en) * | 1988-03-09 | 1989-09-12 | North Sails, Inc. | Batten for sail |
US5001003A (en) * | 1988-08-17 | 1991-03-19 | North Sails Group, Inc. | Laminated sailcloth with scrim |
US5079055A (en) * | 1989-09-21 | 1992-01-07 | Doyle Brian P | Reinforcement for laminate synthetic materials |
US5097784A (en) * | 1990-08-21 | 1992-03-24 | North Sails Group, Inc. | Sail of one piece three dimensional laminated fabric having uninterrupted load bearing yarns |
US5394563A (en) * | 1990-10-01 | 1995-03-07 | Doyle; Brian P. | Anti-G garment fabric |
US5161479A (en) * | 1992-04-07 | 1992-11-10 | North Sails Group, Inc. | Laminated sail fabric |
DE19720107C2 (de) * | 1996-05-29 | 1999-09-30 | North Sails Group Inc | Segel und Segeltuch, das ein gewebtes Tuch aus natürlichen Fasern simuliert |
JP2000110072A (ja) * | 1998-09-30 | 2000-04-18 | Kanebo Ltd | コーティング布帛 |
US6106649A (en) * | 1998-10-02 | 2000-08-22 | North Sails Group, Inc. | Continuous method of making a three dimensional sail |
US6725885B2 (en) * | 2001-05-22 | 2004-04-27 | North Sails Group, Llc | Sailcloth |
JP2005097786A (ja) * | 2003-09-25 | 2005-04-14 | Teijin Techno Products Ltd | セールクロス |
-
2008
- 2008-11-24 US US12/277,183 patent/US7886777B2/en active Active
-
2009
- 2009-11-19 JP JP2011537622A patent/JP5622742B2/ja not_active Expired - Fee Related
- 2009-11-19 EP EP09764130A patent/EP2370313A2/en not_active Withdrawn
- 2009-11-19 WO PCT/US2009/065174 patent/WO2010059845A2/en active Application Filing
- 2009-11-19 KR KR1020117014078A patent/KR20110094074A/ko not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6257160B1 (en) | 2000-03-07 | 2001-07-10 | Fred Aivars Keire | Sail of woven material and method of manufacture |
JP2005290575A (ja) | 2004-03-31 | 2005-10-20 | Toyobo Co Ltd | 手術着等に好適に使用できる織物 |
EP1705273A2 (en) | 2005-03-25 | 2006-09-27 | Roberto Bernasconi | Textile fabrics for clothing |
Also Published As
Publication number | Publication date |
---|---|
EP2370313A2 (en) | 2011-10-05 |
US20100126619A1 (en) | 2010-05-27 |
US7886777B2 (en) | 2011-02-15 |
JP2012510002A (ja) | 2012-04-26 |
KR20110094074A (ko) | 2011-08-19 |
WO2010059845A3 (en) | 2011-05-19 |
JP5622742B2 (ja) | 2014-11-12 |
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