WO2010059353A1 - Composition aqueuse de revêtement - Google Patents

Composition aqueuse de revêtement Download PDF

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Publication number
WO2010059353A1
WO2010059353A1 PCT/US2009/062462 US2009062462W WO2010059353A1 WO 2010059353 A1 WO2010059353 A1 WO 2010059353A1 US 2009062462 W US2009062462 W US 2009062462W WO 2010059353 A1 WO2010059353 A1 WO 2010059353A1
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WO
WIPO (PCT)
Prior art keywords
weight
copolymer
acid
hydroxy
monomers
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Application number
PCT/US2009/062462
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English (en)
Inventor
George Hendrickz
Jozef Theresia Huybrechts
Christiaan Engels
Jean-Luc Wietor
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E. I. Du Pont De Nemours And Company
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Application filed by E. I. Du Pont De Nemours And Company filed Critical E. I. Du Pont De Nemours And Company
Priority to US13/122,628 priority Critical patent/US8771797B2/en
Priority to EP09752948.1A priority patent/EP2342244B1/fr
Priority to BRPI0913708A priority patent/BRPI0913708A2/pt
Priority to CA2735977A priority patent/CA2735977A1/fr
Priority to CN200980143539.XA priority patent/CN102203150B/zh
Publication of WO2010059353A1 publication Critical patent/WO2010059353A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers

Definitions

  • the invention relates to a curable aqueous coating composition which coating composition may in particular be used in automotive and industrial coatings.
  • water-based coating compositions have become more and more important in recent years in various fields of application, including, automotive coatings.
  • a number of dear and pigmented aqueous coating compositions are utilized in various coatings, such as, for example aqueous basecoats, clear coats and topcoats. The aim of this is to keep the proportion of organic co-solvents in the water based coating compositions as small as possible.
  • water-based coating compositions produced do not in all respects achieve the high quality levels of conventional solvent-based coating compositions.
  • One feed stream comprises 5-60% by weight of the unsaturated acid functional monomer, 40-95% by weight of the reaction product of a monoepoxyester an ⁇ an unsaturated acid functional monomer, and 0-55% by weight of the other polymerisabie compounds.
  • surplus solvent is distilled off, But aqueous coating compositions based on those acrylate resins do not give a good shelf stability and good overall productivity in drying performance and have a unfavourable solids viscosity.
  • EP 1 285035 discloses water-based coating compositions comprising an aqueous dispersion of a pofyester-poiyacryiate hybrid resin which hybrid resin is obtainable by grafting a composition of radically polymerisabie monomers onto a partially unsaturated hydroxyl-functional polyester.
  • the partially unsaturated hydroxyl-functionaf polyester is obtained by reaction of a mixture of polycarboxyiic and, optionally monocarboxyiic acids, at least 50 mole-% of these acids are aliphatic acids with 6-12 carbon atoms, with (cyclo)aKphatric alcohols comprising an aliphatic or cycloaliphatic dioi, wherein 0.5 - 6 mole ⁇ % of the acids and/or alcohols are unsaturated.
  • the water-based coating compositions do not cause excessive foaming during spraying and show acceptable pot life.
  • WO 2007/090640 discloses an aqueous multi-component system comprising a water-dispersible (meth)acrylate copolymer and a low molecular oiigomeric, essentially unbranched hydrophobic polyester having at least two hydroxy! groups in the molecule.
  • the aqueous multi-component system is preferably cured with UV radiation.
  • the present invention relates to an aqueous coating composition
  • a cross-linkable binder resin comprises: at least one copolymer A) having cross-linkable reactive groups
  • said copolymer A) comprises: 5 to 64 % by weight, preferably 10 to 50 % by weight, most preferred 15 to 40 % by weight of a reaction product of at least one fatty acid having at least one ethylenic double bond and one hydroxy! group in the molecule with a polyaicohol having a hydroxy) functionality of 2 to 8, wherein the % by weight are relative to the binder solids of copolymer A).
  • ail molecular weights (both number and weight average molecular weight) referred to herein are determined by GPC (gel permeation chromatographie) using polystyrene as the standard and tetrahydrofuran ⁇ as the liquid phase.
  • Aqueous coating compositions are coating compositions, wherein water is used as solvent or thinner when preparing and/or applying the coating composition.
  • aqueous coating compositions contain 20 to 80% by weight of water, based on the total amount of the coating composition and optionally, up to 15% by weight, preferably, below 10% by weight of organic solvents, based on the total amount of the coating composition.
  • Liquid carrier means water or a mixture of water and at least one organic solvent, whereby the mixture contains maximal 40 % by weight of the organic solvent.
  • the liquid carrier contains 70 to 100 % by weight of water.
  • reaction product of the at least one fatty acid having at least one ethylenic double and one hydroxy! group in the molecule with a polyalcohol having a hydroxy! functionality of 2 to 8 shall be referred to as monomer a).
  • Copolymer A) is a copolymer prepared by radical polymerization of unsaturated monomers a) and further unsaturated monomers b) in a solvent
  • Unsaturated monomers b) contain hydrophilic ionic groups, preferably carboxyfic acid groups and/or amino groups.
  • Copolymer A) has an acid value of at least 10 mg KOH/g resin solids, preferably of 15 to 80 mg KOH/g resin solids, a hydroxy! value of 50 to 250 mg KOH/g resin solids and a number average molecular weight Mn of 800 to 8000.
  • copolymer A) comprises 5 to 64 % by weight of at least one monomer a) and 36 to 95 % by weight of at least one monomer b), wherein the % by weight are adding up to 100%.
  • copolymer A) comprises a) 5 to 64 % by weight of at least one reaction product of at least one fatty acid having at least one ethytenic double bond and one hydroxy) group in the molecule with a poJyalcohol having a hydroxy! functionality of 2 to 8 (monomer a) and b) 36 to 95 % by weight of unsaturated monomers comprising: b1 ) at least one hydroxyl-functional unsaturated monomer, b2) at least one acid-functional unsaturated monomer and
  • D3) optionally at least one other potymerizable unsaturated monomer different from monomers b1 ) and b2), wherein the % by weight are adding up to 100%.
  • Monomer a) is the reaction product of at least one fatty acid having at least one ethylenic double and one hydroxy) group in the molecule with a polyoJ having a hydroxy! functionality of 2 to 8.
  • Fatty acids having 8 to 24 carbon atoms, preferably 10 to 24 carbon atoms, in the molecule, may be used.
  • a preferred example of a useful fatty acid is ricinoteiceic acid (castor oil fatty acid).
  • Preferred polyalcohols are monomenc polyalcohols, in particular monomeric polyalcohols with a number average molecular weight of 62 to 362.
  • suitable polyalcohols having a hydroxy! functionality of 2 are alkytene glycols and alkane dtols, such as ethylene glycol, propylene glycol, dipropyten ⁇ glycol, diethylene glycol, Methylene glycol, neopentyJglycol, 1 ,3-pentanedioJ, 1 ,2- propandiol, 1 ,3-, 1,4- and 2,3-butanedtol, 1 ,5-pentanediol, 1 ,6-h ⁇ xanediol, dimethyiolpropane.
  • pofyols having a hydroxy! functionality of 3 and more are glycerine, trimethytolpropane. triethylolpropane, 1,2,4-butantriol, mon ⁇ -pentaerythritoi, di-pentaerythrito ) and bvpentaerythritol.
  • Preferred monomers a) are reaction products of fatty acids having 12-24 carbon atoms in the molecule with a poiyalcohol having a hydroxy! functionality of 2 to 8. These are, for example, the reaction products of ri ⁇ noteic acid and a poiyalcohol having a hydroxy) functionality of 2 to 8. Most preferred is the di- or triglyceride of ricinoleic acid.
  • the monomers a) prepared by reacting at least one fatty acid having at least one ethylenic double and one hydroxy) group in the molecule with a polyalcohoi having a hydroxy! functionality of 2 to 8 can be mono- or diesters or compounds containing more than two ester groups in the molecule.
  • the polyalcohols may be completely or o ⁇ y partly esterified, Le. only one hydroxy! group, a part of the hydroxy! groups or ail hydroxy! groups of the poiyaicohot may be reacted with the fatty acid as defined above to form an ester bond, if the poiyaicohols are not completely esterified the monomer a) stif ⁇ contain one or more hydroxy! groups in addition to the one hydroxy! group incorporated by the fatty acid.
  • a preferably useful monomer a) is castor oil.
  • Castor oil is a natura! product and mainly comprises the irigfyceride of castor oil fatty acid (ricinoieic acid).
  • Natura! castor oil is, for example, a mixture of 80-88 % by weight of the trigiyceride of castor oil fatty acid (ricinoleic acid), 4-7 % by weight of the triglyceride of oleic acid, 3-5 % by weight of linofeic acid, 1 ,5-2 % by weight of palmitic acid and 1-1, ⁇ % by weight of stearic acid. Since castor oil is a cheap and renewable resource its use aliows to prepare the copolymers A) in a cost saving way. Castor oil is commercially available, for exampie from the company Mosseimann, Belgium,
  • Castor oii can be used in combination with other monomers a). Generaiiy a single monomer a) or a combination of different monomers a) can be used.
  • Monomers a) also include those reaction products, wherein at least one hydroxy! group, but not all hydroxy! groups of the po ⁇ ya ⁇ cohol are reacted with a fatty acid as defined above and wherein the remaining hydroxyl groups of the poiyaicoho! are reacted completely or part ⁇ y with fatty acids different from those as defined above.
  • saturated fatty acids and/or unsaturated fatty acids having no hydroxyl group in the molecule can be used in addition to the above defined fatty acids.
  • Examples for additionally usefu! fatty acids are saturated fatty acids with 10 to 24 carbon atoms, such as stearic acid, iauric acid, paimitic acid.
  • Further examples for additionally usefu! fatty acids are single or muttipte unsaturated fatty acids having no hydroxyl group in the molecule, such as oleic acid, linolenic add, iino ⁇ eic acid.
  • the copolymer A) further comprises unsaturated monomers b),
  • monomers b) comprising b1) 0 to 60 % by weight, preferably 10 to 40 % by weight, of at least one hydroxy functional unsaturated monomer, b2) 2 to 40 % by weight, preferably 4 to 20 % by weight, of at least one acid functional unsaturated monomer and b3) 0 to 50 % by weight, preferably 20-50% by weight, of at least one other polymerisabJe unsaturated monomer, wherein the % by weight of monomers b1) to b3) is relative to the binder solids of copolymer A).
  • copolymer A) comprises at least one monomer a) and monomers b1 ) to b3).
  • copolymer A) comprises 5 to 64 % by weight of monomer a) and 36 to 95 % by weight of monomers b1 ) to b3). wherein the % by weight are adding up to 100%.
  • copolymer A) consists of 5 to 64 % by weight of monomer a) and 36 to 95 % by weight of monomers b1 ) to b3), wherein the % by weight are adding up to 100%.
  • Monomer b1) relates to hydroxy-functionaJ unsaturated monomers.
  • Examples of monomer b1 ) are hydroxyalkyt esters with primary or secondary hydroxy! groups derived from alpha, beta-ethylenicaily unsaturated monocarboxylic adds. These can include, for example, hydroxyalkyl esters from acrylic acid, methacrytic acid, crotonic acid and/or iso-crotonic acid. Hydroxyalkyl esters derived from (meth)acryitc acid are preferred.
  • the hydroxyalkyl groups can contain, for example, 1 to 10 C atoms, preferably 2 to 6 G atoms.
  • Suitable hydroxyalkyl esters of alpha, b ⁇ ta- ethytenically unsaturated monocarboxylic acids with primary hydroxy! groups are hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, hydroxybutyl (m ⁇ th)acrylate, hydroxyamyl (meth)acrylat ⁇ , hydroxyhexyl (meth)acry!at ⁇ .
  • suitable hydroxyalkyl esters with secondary hydroxy! groups are 2-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, 3-hydroxybutyl (meth)acrylate.
  • monomers such as pdyalkyleneglycol (meth)acry(ates > e.g. polyethylenegrycol (meth)acrylate or polypropyieneglyco! (meth)acry!ate monomers can be used.
  • Reaction products from hydroxyalkyl (m ⁇ th)acylates with lactones can also be used as monomer b1).
  • the aforementioned are examples of hydroxyalkyl (meth)acrylates that can be used.
  • Suitable lactones are. for example, those that contain 3 to 15 C atoms in a ring, it is possible for the rings to have different substituents.
  • Preferred lactones are gamma-butyrolactone, delta-vaierolactone, epsilon-caprolactone, b ⁇ ta- hydroxy-beta-methyl-d ⁇ lta-valeroJactone, lambda-laurinlactone or mixtures thereof.
  • Epsilon-caprolactone is particularly preferred.
  • reaction products preferred are those of one mol of a hydroxyalkyi ester of an alpha, beta- ⁇ nsaturated monocarboxyiic add and 1 to 5 mol, preferably an average of 2 mols, of a lactone. Modification of the hydroxy! groups of the hydroxyalkyi esters with the lactone can take place before, during or after carrying out the copolymerization reaction.
  • Reaction products of a monoepoxyester and unsaturated acid functional compounds can also be used as monomer b1).
  • These monoepoxy esters are preferably glycidy) esters derived from aliphatic saturated monocarboxyiic acids with a tertiary or quaternary carbon atom in the alpha position. It is preferred to use giyoidyi esters of saturated alpha, alpha-dialkylaJkane-monocarboxylic acids with 5 to 13 C atoms in the acid molecule, in particular, preferably, 9 to 11 C atoms in the acid molecule. Examples for glycidyiesters are the glycidyl esters derived from versatic acid.
  • Suitable monoepoxyesters of this type are obtainable commercially, for example, under the name of Cardura®.
  • unsaturated acid functional compounds are aliphatic unsaturated monocarboxyiic acids such as (meth)acrytic acid, crotonic acid and isocrotonic acid.
  • Monomer b2) relates to unsaturated acid functional monomers.
  • suitable monomers b2) are poiymerizable ethylenically unsaturated carboxyl-functional monomers such as ethylenically unsaturated mono- and/or dicarboxyiic acids, e.g. (meth)acry1ic acid, maleic acid, fumaric acid, crotonic acid and isocrotonic acid as well as the corresponding semi-esters and anhydrides of ethylenically unsaturated dicarboxyiic acids.
  • the acid residue of these carboxylic acids has generally 1 to 8 C atoms.
  • the use of (meth)acrytic acid is particularly preferred.
  • Monomer b3) relates to unsaturated monomers, which differ from monomers a), b1) and b2). It can include ethylenically unsaturated monomers that, apart from having at least one ethylenically double bond, do not contain any other reactive functional groups.
  • suitable unsaturated monomers with no other functional groups are esters of unsaturated carboxylic acids with aliphatic monohydric branched or linear as well as cyclic alcohols with 1 to 20 C atoms.
  • unsaturated carboxylic acids are acrylic acid, methacryHc acid, crotonic acid and isocrotonic acid. Esters of (meth)acrylic acid are preferred.
  • Examples of (meth)acry!ic acid esters with aliphatic alcohols are methyiacrylate, ethylacrylate, isopropylacryiate, tert- butylacrylate, n-butytacryiate, isobutylacryiate, 2-ethylhexylacrylat ⁇ , laurylacrytate, stearytacrylate and appropriate methylacrylates
  • Examples of (meth)acryltc acid esters with cyclic alcohols are cyclohexylacrylate, trimethylcycJohexylacrylate, 4-tert. butylcyctohexyiacryiat ⁇ , isobomylacryiate and appropriate methacrylates.
  • Examples of (meth)acrylic acid esters with aromatic alcohols are b ⁇ nzyl(meth)acrylates.
  • vinyl esters such as, for example, vinyl acetate, vinyl propionate and vinyl esters derived from branched vinyl esters, such as, for example. vinyl acetate, vinyl propionate and vinyl esters derived from branched saturated monocarboxylic acids in alpha position, for example, vinyl esters derived from saturated alpha, alpha' dialkylalkane monocarboxylic acids and vinyl esters derived from saturated alpha-alkylalkan ⁇ monocarboxylic acids each with 5 to 13 carbon atoms, preferably, 9 to 11 carbon atoms in the molecule.
  • Examples of further suitable unsaturated monomers without other functional groups are vinylaromatic monomers, for example, styrene, vinyl toluene and/or tertiary butyl 8tyrene.
  • ethylenicaliy polyunsaturated monomers can also be used. These are monomers with at least 2 radically porymerizable double bonds. Examples of these are divinylb ⁇ nzene, 1 ,4-butanediol dtacrvtate, 1 ,6-hexanediol diacryJat ⁇ , neopentyl ⁇ jycoWimethacrylat ⁇ , glycerine dtmethacryiate.
  • Monomer b3) may also include ethylenicaliy unsaturated monomers with other functional groups, for example (meth)acrylamides and their derivatives, (meth)acryk>nitriles, siiane-functional unsaturated monomers, such as, for example, methacryloxypropyt trialkoxysilanes, vinyl trialkoxysilanes, each with, for example, 1 to 5 carbon atoms in the alkoxy group, acetoacetyl-functional unsaturated monomers, such as, for example, acetoacetoxy ethylm ⁇ thacryiate, unsaturated monomers containing urea groups, such as, for example, ethylene urea ethyl methacrylate and unsaturated monomers containing amino groups, such as, for example, dialkyiamino ethyl (meth)acrylates with, for example, 1 to 5 carbon atoms in the atkyt group and heterocyclic monomers, e.g. vinyl imi
  • copolymer A) comprises as monomer b3) esters of unsaturated carboxylic adds with aliphatic monohydric branched or linear as well as cyclic alcohols with 1 to
  • a preferred copolymer A) comprises:
  • b1) 0 to 60, preferably 10 to 40 % by weight of at least one hydroxyalkyl ester with primary or secondary hydroxy) groups derived from alpha, beta-ethyienicaily unsaturated monocarboxylic acids.
  • b2) 2 to 40, preferably 4 to 20 % by weight of at least one unsaturated acid functional monomer and b3.1) 0 to 50 % by weight of at least one ester of (meth)acryitc acid with aliphatic monohydric branched or linear as well as cyclic alcohols with 1 to 20 C atoms and b3.2) 0 to 50 % by weight of at least one vinyiaromatic unsaturated monomer, wherein the % by weight of monomers a) and b)1 to b3.2) are adding up to 100 % by weight.
  • copolymers A) comprise in particular 5 to 64 % by weight, preferably 15 to 40 % by weight, of the triglyceride of ricinoleic acid and 36 to 95 % by weight, preferably 60 to 85 % by weight of monomers b1) to b3), wherein monomers b1 ) to b3) are preferably monomers b1 ) to b3.2) as defined above and % by weight are adding up to 100 % by weight.
  • copolymers A) comprise preferably 15 to 40 % by weight of castor oil and 60 to 85 % by weight of monomers b1 ) to b3), wherein monomers b1 ) to b3) are preferably monomers b1 ) to b3.2) as defined above and % by weight are adding up to 100 % by weight.
  • the copolymers A contained in the coating compositions according to the invention are produced by radical copdymerization in a solvent. Radical polymerization is following the usual methods known by a person skilled in the art. Copolymer A) is prepared by polymerizing monomer a) and monomers b1 ) to b3).
  • monomer a) is used as polymerization medium and monomers b1 ) to b3) are polymerized in presence of monomer a), preferably in presence of at least 20 % by weight of the total amount of monomer a).
  • Copolymer A) can be prepared in a one-step process or by a skew feed polymerization process with at least two feed streams (at least two steps).
  • the copolymer A) can be made by first charging a reflux reactor with a first quantity of monomer a) and an organic solvent or solvent blend.
  • the temperature of the reactor contents is typically held between 60 0 C and 280 0 C during polymerization.
  • a first feed stream comprising a mixture of optionally a second quantity of monomer a), a first quantity of unsaturated hydroxyfunctional monomer, a further unsaturated monomer and an initiator is charged to the reactor over a period of time.
  • the reactor contents are rinsed with additional organic solvent.
  • a second feed stream comprising for example, a second quantity of the unsaturated hydroxyl-functional monomer, a quantity of an unsaturated acid-functional monomer, in an amount to provide the copolymer with the desired acid number, further unsaturated monomers, additional organic solvent, and additional initiator is charged to the reactor over a period of time.
  • the copolymer A) can also be made by a one- step polymerization process.
  • the copolymer A) is made by using at least 20 % by weight, more preferred 30 to 100 % by weight, most preferred 50 to 100 % by weight, of the total amount of monomer a) as polymerization medium in a one-step or multi-step polymerization process.
  • monomer a) can be present prior to charging the reactor with monomers b) or can be introduced directly in the monomer feed.
  • the rest of monomer a) can be added during a second polymerization step and/or can be added after polymerization of monomers b).
  • monomer a) is not used as polymerization medium, e.g. the total amount of monomer a) is added only in a second polymerization step and/or after polymerization of monomers b), the final polymer dispersion might not be stable.
  • copolymer A) can be prepared by using a macromonomer. Therefore, copolymer A) can be a graft copolymer comprising:
  • those m ⁇ cromonomers can be used as described in US 5,936,026 and used in preparing the graft copolymers. After at least partial neutralization of the ionic groups these macromonomers form stable solutions or dispersions in water.
  • the macromonomer preferably contains carboxyl groups.
  • the macromonomer c) is preferably prepared using a free radical initiator in a solvent with a Co (II) or Co (ill) chelate chain transfer agent and contains 10 to 100 percent, preferably 20 to 40 percent, by weight of an acid- or amine-functional unsaturated monomer.
  • acid-functional monomers are acrylic acid, rnethacrylic acid, maleic acid, and itaconic acid or their anhydrides (which can be hydrolyzed to the acid after polymerization).
  • amine-functional monomers are t-butylamino ethyl methacryiate, diethyl (or dimethyl) amino ethyl acrylate, diethyl amino ethyl methacrylate, and the like.
  • the macromonomer is based on acid-functional monomers, most preferred on (methjacrylic acid.
  • acid- or amin ⁇ - functional monomer up to 90 % by weight, based on the weight of the macromonomer, of other polymerized ethylenically unsaturated monomers can be present.
  • Other ethylenically unsaturated monomers can be, for example, the same unsaturated monomers as described for monomers b).
  • the copolymer A) may be prepared by polymerizing ethylenically unsaturated monomers in the presence of macromonomers c) each having a terminal ethylene unsaturation for grafting. To ensure that the resulting macromonomer only has one terminal ethylenically unsaturated group which will polymerize with the other monomers to form copolymer A, the macromonomer is polymerized by using a catalytic chain transfer agent. Typically, in the first step of the process for preparing the macromonomer, the monomers are blended with an inert organic solvent which is water misdble or water dispersibie and a cobalt chain transfer agent and heated usually to the reflux temperature of the reaction mixture. In subsequent steps additional monomers and cobalt catalyst and conventional polymerization catalyst are added and polymerization is continued until a macromonomer is formed of the desired molecular weight
  • Suitable cobalt chain transfer agents or catalysts are described in U.S. Pat. No. 4,680,352, U.S. Pat. No. 4,722,984 and WO 87/03605.
  • Preferred are pentacyanocobaltate (Il or Ml), diaquabis(borondifluorodirnethyl-glyoxirnato) cobaltate
  • Ethyienically unsaturated sulfonic, sutfinic, phosphoric or phosphonic add and esters thereof also can be used such as styrene sulfonic acid, acrylarredo methyl propane sulfonic acid, vinyl phosphonic acid can also be used.
  • these chain transfer agents are used at concentrations of about 5-1000 ppm based on the monomers used.
  • the relatively hydrophobic monomer a e.g. the ⁇ - or triglyceride of ri ⁇ noteic ack. or the castor oil, i.e. the part of the copolymer formed by monomer a
  • this can be done, for example, with ionic groups, in particular acid groups of monomers b) and/or of macromonomer c).
  • copolymer A) can be prepared by polymerizing monomers b) in presence of a mixture of monomer a) and at least one macromonomer c) as defined above.
  • monomers b) are polymerized in presence of a mixture containing 20 to 80 % by weight of monomer a) and 80 to 20 % by weight of macromonomer c), wherein the % by weight of monomer a) and macromonomer c) is adding up to 100 % by weight.
  • the absolute amount of monomer a) in the above mixture shall be at least 20 % by weight of the total amount of monomer a) used in preparing the copolymer A).
  • All usual polymerization initiators for radical copolymerization can be considered, such as, aliphatic azo compounds, for example, azobis-isobutyronitrile or azobis- methylbutyronitrile, diazylperoxides, for example, dibenzoylperoxide, dialkylperoxides, for example, di-tertiary-butylperoxide or di-tertiary-amylp ⁇ roxide, alkyfhydroperoxides, for example, tertiary-butylhydroperoxide or peresters, for example, tertiary-butylperoxybenzoate.
  • Chain transfer agents for example alkylhalides, such as, alkyl bromides, or mercaptanes, such as, dodecylmercaptane, can be used to regulate the molar mass.
  • Suitable organic co-solvents are inter alia water-dilutabfe monovalent or bivalent alcohols or glycols, for example, ⁇ thanol, n-propanol, isopropanol, n-butanol, isobutanol, ethylene glycol, diethyiene glycol, triethylene glycol, propylene glycol and glycerine, water-dilutabie monoethers derived from polyhydric alcohols, for example methoxypropanol or m ⁇ thoxybutanol, as well as water-dilutabie glycol ethers, such as, for example, butylglycd or butyldiglycol.
  • water-dilutabfe monovalent or bivalent alcohols or glycols for example, ⁇ thanol, n-propanol, isopropanol, n-butanol, isobutanol, ethylene glycol, diethyiene glycol, triethylene glycol, propylene
  • copolymers A selects the nature and proportion of components a), b) and c) for the production of copolymers A in such a manner that copolymers A with the desired acid number of at least 10 mg KOH/g resin solids, the desired hydroxy) number and molecular weight are obtained.
  • Acid groups can be introduced via the acid-functional macromonomer c) and/or via acid-functional monomers b).
  • the minimum acid value is required to stabilize the part of copolymer A) containing the hydrophobic monomer a) in the aqueous medium.
  • no ⁇ ionic stabilization e.g. with monomers, such as, poiyalkylenegiycol (m ⁇ th)acry1ates ( is possible.
  • the copolymer A is neutralized and dispersed or dissolved in an aqueous carrier.
  • Neutralization can be performed before or during dispersing or dissolving the copolymer A in the aqueous carrier.
  • the aqueous carrier preferably contains 80 - 100 % by weight of water.
  • neutralizing agents for the preferred acid groups of copolymer A inorganic bases or amines can be used. Examples of those neutralizing agents are ammonium hydroxide, sodium hydroxide, potassium hydroxide, amino methyl propanol, amino ethyl propanol, dimethyl ethanol amine, triethytamine and the like.
  • the coating composition according to the invention may comprise other components in addition to copolymer A).
  • the coating composition can comprise, for example, additional water-dilutaWe binders.
  • the additional water-dilutabie binders which can be used are not subject to any particular restrictions. All water-dilutaWe binders usually used to prepare aqueous coating compositions, e.g., in the field of automotive and industrial coating can be used as additional binder component.
  • Those water-dilutabie binders as well as preparation methods for the binders are known to the person skilled in the art and are disclosed in detail in various patents and other documents.
  • water- dilutabie binders are polyurethane(urea) resins, polyester resins, (meth)acryitc copolymer resins different from copolymer A), epoxy resins, polysiioxane resins, alkyd resins, cellulose esters, meiamine resins and any hybrid binders derived therefrom.
  • Copolymers A contain cross-linkable functional groups suitable for crosslinking reactions with appropriate crosslinkers.
  • the additional water-dilutaW ⁇ binders may contain cross-linkable functional groups as well. Suitable functional groups are, for example, hydroxyl groups, blocked hydroxy! groups, acetoacetyl groups, unsaturated groups, for example, (meth)acryk>yl groups and aliyt groups, epoxide groups, carboxyl groups, carbamate groups, amine groups and blocked amine groups.
  • these copolymers and binders are modified in a suitable manner to render them hydrophilic.
  • the coating composition according to the invention may optionally comprise at least one cross-linking agent B) which cross-linking agent is capable of entering into a cross-linking reaction with the reactive functional groups of copolymer A) and additional binder components.
  • the cross-linking agents which can be used are not subject to any particular restrictions. All cross-linking agents usually used to prepare aqueous coating compositions, e.g., in the field of automotive and industrial coating can be used. Those cross-linking agents as well as preparation methods for the cross-linking agents are known to the person skilled in the art and are disclosed in detail in various patents and other documents.
  • cross-linking agents may, for example, be used: polyisocyanates with free isocyanate groups or with at least partially blocked isocyanate groups, amine/fonmaidehyde condensation resins, for example, meiamine resins.
  • copolymer A) and the optionally present additional binders contain hydroxyl groups and cross-linking agents with free or blocked poJyisocyanate groups are used.
  • the binder components and the cross-linking agent are used in such proportion that the equivalent ratio of reactive functional groups of copolymer A) and additional binders to the corresponding reactive groups of the cross-linking agent B) can be 5:1 to 1:5, for example, preferably, 3:1 to 1:3, and in particular, preferably, 1.5:1 to 1.1.5.
  • the coating compositions can also contain pigments and/or fillers. All colour and/or special effect-giving pigments of organic or inorganic type used in paints are suitable for pigments.
  • inorganic or organic colour pigments are titanium dioxide, micronised titanium dioxide, iron oxide pigments, carbon black, azo pigments, phthalocyanine pigments, quinacridone or pyrrolopyrrole pigments.
  • special effect pigments are metal pigments for example, from aluminum or copper, interference pigments, such as, for example, aluminum coated with titanium dioxide, coated mica, graphite effect pigments.
  • fillers are silicon dioxide, barium sulphate, talcum, aluminium silicate and magnesium silicate.
  • the coating compositions can also contain usual additives. These additives are additives usually used in the paint industry. Examples of such additives are light stabilizers, for example, based on benztriazoles and HALS compounds, rheology additives different from the SCAs prepared according to the present invention, thickeners, such as, cross-linked polycarboxylic acid or polyurethanes, anti-foaming agents, wetting agents and catalysts for the crosslinking reaction. The additives are added in the usual amounts familiar to the person skilled in the art.
  • the coating compositions contain furthermore water, for example, 30-60% by weight, and possibly small amounts of organic solvents, e.g., up to 15% by weight, preferably, below 10% by weight based on the entire coating composition.
  • organic solvents are solvents conventionally used in coating techniques. These may originate from the preparation of the binders or are added separately.
  • suitable solvents are monohydric or polyhydric alcohols, e.g., propanol, butanol, hexanol; glycol ethers or esters, for example, diethvfene glycol dialkyl ether, dipropylene glycol dialkyl ether, each with C1- to C6-alkyl, ethoxypropanol, butyl glycol; glycols, for example, ethylene glycol, propylene glycol, N-methyl pyrroiidone and ketones, e.g., methyl ethyl ketone, acetone, cydohexanone; aromatic or aliphatic hydrocarbons, for example, toluene, xylene, or straight-chain or branched aliphatic C6-C12-hydrocarbons. If organic solvents are present, water-miscible organic solvents are preferred.
  • the aqueous coating composition according to the invention can be produced in a known manner.
  • the coating compositions according to the invention are suited for use as clear coats but can be pigmented with conventional pigments and used as solid-color or effect topcoats, color- and/or special effect-imparting basecoats or undercoats such as sealer, primer, surfacer or primer surfacer. They can be used to coat a substrate with a single coat or can be used within a multilayer coating of substrates.
  • the aqueous coating compositions may comprise single-component aqueous coating compositions or aqueous coating compositions producible by mixing two or more separately stored components.
  • the coating compositions, according to the invention can be applied using known methods, in particular, by spray application.
  • the coating compositions obtained can be cured at room temperature or forced at higher temperatures, for example, up to 80°C, preferably at 20 to 60°C. They can, however, even be cured at higher temperatures of, for example, 80 to 180°C. Curing temperatures are depending on the curing chemistry as welt as the field of use of the aqueous coating compositions
  • the coating compositions are suitable for automotive and industrial coatings.
  • the coatings can be used for both vehicle production line painting and vehicle and vehicle part refinishing as well as for coating large vehicles and transportation vehicles, such as, trucks, busses and railroad cars.
  • vehicle production line painting baking temperatures of 80 to 180°C, for example, are used, preferably 110 to 140°C.
  • refinishing curing temperatures of for example, 20°C to 80°C, in particular, 20 to 60°C are used.
  • stable aqueous binder dispersions are provided, which can be easily incorporated into aqueous coating compositions.
  • the binder dispersions can be prepared in a cost saving way from cheap renewable resources as main component, ⁇ y using monomer a) as polymerization medium less amounts of organic solvents are required for the radical polymerization process and expensive destination process can be avoided. Usually organic solvents need to be distilled off prior to or after conversion of the copolymer into the aqueous phase.
  • aqueous coating compositions of the present invention show very good drying results compared with known aqueous coating compositions of prior art.
  • final coatings show improved hardness and scratch resistance as well as improved gloss and recoat adhesion. Even in higher film thicknesses of, for example 40-60 ⁇ m, pop-free coatings are obtained.
  • the reactor contents were held for 30 minutes. After the 30 minutes hold period, 180 grams of HEMA, 90 grams of AA, 360 grams of lsobutyl Methacrylate (IBMA), 6 grams of DTBP and 14 grams of EPR were added over 2 hours and 30 minutes at about 150*C followed by a rinsing step for the feed system of 20 grams of EPR. After the rinsing step, the contents of the reactor were held for 2 hours at 150°C followed by cooling to 100 C. In a next step, the 105.6 grams of dimethylamino ⁇ thanoj (DMEA) were added for a theoretical acid value of 39, the amount corrected for the measured acid value. The polymer blend was diluted with 1914.4 grams of water preheated at about 70°C.
  • DMEA dimethylamino ⁇ thanoj
  • the polymer blend was diluted with 1914.4 grams of water preheated at about 70°C.
  • the contents of the reactor were held for 2 hours at 150°C followed by cooling to 100 C.
  • the 105.6 grams of dimethyiamino ethanol (DMEA) were added for a theoretical acid value of 39, the amount corrected for the measured acid value.
  • the polymer blend was diluted with 3914.4 grams of water preheated at about 70°C. Test results:
  • a mixture of 384 grams of styrene (S) ,368 grams of 2-Hydroxypropyl methacrylate (HPMA), 368 grams of Butyl Acrylate (BA), 20 grams of Tertiary butyl peroxy 2-ethyihexanoate (TBPO) and 112 grams of dipropyieneglycol mono methylether (DPM) were added over 3 hours to the reactor while keeping the contents at about 90 4 C followed by a rinsing step for the feed system of 20 grams of DPM.
  • the polymer biend was diluted with 1914.4 grams of water preheated at about 70 ⁇ C. Test results:
  • the batch was not stable and phase separated.
  • Comparative example 2 Preparation of Acrylic Copolymer Dispersion with 35 % bv weight of dehydrated castor oil as polymerization medium
  • a reactor with a propeller type of stirrer, a thermometer, condenser and monomer/initiator feeding system
  • 630 grams of Dehydrated castor oil and 100 grams of ethoxypropanol (EPR) were loaded and heated to about 150*C
  • EPR ethoxypropanol
  • a mixture of 180 grams of 2-Hydroxyethyl methacrylate (HEMA), 360 grams of Styrene (S), 12 grams of Di-tertiary butyl peroxide (OTBP) and 28 grams of EPR were added over 2 hours 30 minutes to the reactor while keeping the contents at 150°C.
  • HEMA 2-Hydroxyethyl methacrylate
  • S Styrene
  • OTBP Di-tertiary butyl peroxide
  • HEMA Hydroxyethyl methacryiate
  • S Styrene
  • AA acrylic acid
  • DCP Dicumylperoxide
  • BMA n-Butyl Methacryiate
  • the polymer blend was diluted with 865 grams of water preheated at about 70°C. Test results.
  • the solids content has been determined by drying the sample at 135 g C for 1 hour in an aluminium dish of 5 cm diameter.
  • a white paint was prepared from a binder component and a white tint, the binder component containing the acrylic copolymer dispersion of Example 5.
  • the binder component was prepared by mixing the following ingredients:
  • the tint was prepared by dispersing under high shear the following ingredients: 43.80 % by weight of TiQ. (TiPure ⁇ R-706), 7.8 % by weight of a dispersing agent (graft copolymer according to example 2 of US 5,231 ,131), 5.53 % by weight of demineralized water, 0.12 % by weight of AMP 95 (2-ar ⁇ «no-2HTiethyl-propan-1-ol, Dow Chemicals), 0.45 % by weight of Surfynoi 104 (wetting agent, Air Products) and 0.45 % by weight of ethylene glycol monobutyi ether. After dispersing 40.23 % by weight of the acrylic copolymer dispersion of comparative example 3 was stirred in.
  • a paint according to paint example 1 was prepared, with the difference that the acrylic copolymer dispersion of Example 5 in the binder component was replaced by the acrylic copolymer dispersion of comparative example 3.
  • the paint was sprayed and baked according to paint example 1.
  • the baked coating of paint example 1 exhibited a gloss of 86 units (at 20°) compared to a gloss of only 82 units for the baked coating of comparative paint example 1.
  • a black paint was prepared from the binder composition of paint example 1 and a black tint
  • the black tint was prepared by grinding 6.79 % by weight of carbon black (Raven 5000 Ultra Il Powder; Columbian Chemicals) with 25.54 % by weight of demineralized water, 10.91 % by weight of a dispersing agent (graft copolymer according to example 2 of US 5,231 ,131 ), 0.12 % by weight of AMP 95 (2-amino-2- methyl-propan-1-ol), 0.1% by weight of Surfynol 104 (wetting agent, Air Products), 0.1 % by weight of ethylene glycol monobutyl ether.
  • the paint was sprayed in a resulting dry film thickness of 40-50 ⁇ m to a panel and baked (30 min. at 80 0 C). After three days, a second coat of the same black paint was sprayed in a resulting dry film thickness of 40-50 ⁇ m onto the first coat and baked on top of the first coat under the same conditions.
  • the coated panel was left for ten days in a humidity cabinet (Bac Ford, 40 0 C) and left to recover for one hour.
  • Comparative paint example 2 A paint according to paint example 2 was prepared, with the difference that the acrylic copolymer dispersion of Example 5 in the binder component was replaced by acrylic copolymer dispersion of comparative example 3.
  • the paint was sprayed and baked according to paint example 2.
  • the panels coated with paint 2 and comparative paint 2 were subjected to a High- Pressure Cleaning test (according to HPC Volvo, 423-0015; 120 bar, water temperature: 50°C, distance nozzle to substrate 10 cm, 2 sweeps/s, 30 s).
  • a High- Pressure Cleaning test according to HPC Volvo, 423-0015; 120 bar, water temperature: 50°C, distance nozzle to substrate 10 cm, 2 sweeps/s, 30 s.
  • the coating with paint 2 delamination of the top coat (second coat) from the bottom coat (first coat) did not exceed 5% of the total area exposed.
  • the coating with comparative paint 2 delamination did exceed 95% of the total area exposed.

Abstract

L'invention porte sur des compositions aqueuses de revêtement comprenant une résine liante réticulable et un support liquide, dans lequel ladite résine liante réticulable comprend un copolymère A) comprenant : 5 à 64 % en poids d'un produit de réaction d'au moins un acide gras ayant au moins une double liaison éthylénique et un groupe hydroxyle dans la molécule avec un polyalcool ayant une fonctionnalité hydroxyle de 2 à 8, les % en poids se rapportant aux matières solides du liant du copolymère A).
PCT/US2009/062462 2008-10-30 2009-10-29 Composition aqueuse de revêtement WO2010059353A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US13/122,628 US8771797B2 (en) 2008-10-30 2009-10-29 Aqueous coating composition
EP09752948.1A EP2342244B1 (fr) 2008-10-30 2009-10-29 Composition aqueuse de revêtement
BRPI0913708A BRPI0913708A2 (pt) 2008-10-30 2009-10-29 composição de revestimento aquosa e processo para a preparação de uma camada de revestimento
CA2735977A CA2735977A1 (fr) 2008-10-30 2009-10-29 Composition aqueuse de revetement
CN200980143539.XA CN102203150B (zh) 2008-10-30 2009-10-29 含水涂料组合物

Applications Claiming Priority (2)

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US19781608P 2008-10-30 2008-10-30
US61/197,816 2008-10-30

Publications (1)

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WO2010059353A1 true WO2010059353A1 (fr) 2010-05-27

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US (1) US8771797B2 (fr)
EP (1) EP2342244B1 (fr)
CN (1) CN102203150B (fr)
BR (1) BRPI0913708A2 (fr)
CA (1) CA2735977A1 (fr)
WO (1) WO2010059353A1 (fr)

Citations (8)

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GB1146694A (en) * 1965-03-13 1969-03-26 Reichhold Chemie Ag Water-dilutable coating compositions and lacquer binders
US3954688A (en) * 1974-07-30 1976-05-04 E. I. Du Pont De Nemours And Company Aqueous electrocoating composition of the reaction product of an epoxy ester resin and a maleinized drying oil blended with a cross-linking agent
JPS5986617A (ja) * 1982-11-09 1984-05-18 Mitsui Toatsu Chem Inc 不飽和ポリエステル樹脂組成物
US6174948B1 (en) * 1996-12-24 2001-01-16 The University Of Southern Mississippi Latex compositions containing ethylenically unsaturated esters of fatty compounds and applications thereof
US6281272B1 (en) * 1998-02-18 2001-08-28 Ppg Industries Ohio, Inc. Low temperature cure waterborne coating compositions having improved appearance and humidity resistance and methods for coating substrates
US6683132B1 (en) * 2002-12-19 2004-01-27 Eastman Chemical Company Self-crosslinking aqueous acetoacetate-functionalized sulfonated alkyd systems
EP1486545A1 (fr) * 2003-06-09 2004-12-15 Rohm And Haas Company composition aqueuse d'un copolymere et procede de preparation de revetement
EP1285035B1 (fr) * 2000-05-19 2007-07-11 Akzo Nobel Coatings International B.V. Composition liante aqueuse et reticulable et composition de revetement, de laquage ou d'etancheification comprenant ladite composition liante

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2677671A (en) * 1952-08-05 1954-05-04 Interchem Corp Interpolymer from lower alkyl ester of methacrylic acid, fatty acid ester of epoxy resin and ester of alpha, beta unsaturated dicarboxylic acid with diels-alder adduct of cyclopentadiene and allyl alcohol
JPS565863A (en) * 1979-06-28 1981-01-21 Kansai Paint Co Ltd Aqueous coating composition
DE19930961A1 (de) * 1999-07-05 2001-01-11 Bayer Ag Polyurethan-Dispersionen

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1146694A (en) * 1965-03-13 1969-03-26 Reichhold Chemie Ag Water-dilutable coating compositions and lacquer binders
US3954688A (en) * 1974-07-30 1976-05-04 E. I. Du Pont De Nemours And Company Aqueous electrocoating composition of the reaction product of an epoxy ester resin and a maleinized drying oil blended with a cross-linking agent
JPS5986617A (ja) * 1982-11-09 1984-05-18 Mitsui Toatsu Chem Inc 不飽和ポリエステル樹脂組成物
US6174948B1 (en) * 1996-12-24 2001-01-16 The University Of Southern Mississippi Latex compositions containing ethylenically unsaturated esters of fatty compounds and applications thereof
US6281272B1 (en) * 1998-02-18 2001-08-28 Ppg Industries Ohio, Inc. Low temperature cure waterborne coating compositions having improved appearance and humidity resistance and methods for coating substrates
EP1285035B1 (fr) * 2000-05-19 2007-07-11 Akzo Nobel Coatings International B.V. Composition liante aqueuse et reticulable et composition de revetement, de laquage ou d'etancheification comprenant ladite composition liante
US6683132B1 (en) * 2002-12-19 2004-01-27 Eastman Chemical Company Self-crosslinking aqueous acetoacetate-functionalized sulfonated alkyd systems
EP1486545A1 (fr) * 2003-06-09 2004-12-15 Rohm And Haas Company composition aqueuse d'un copolymere et procede de preparation de revetement

Also Published As

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BRPI0913708A2 (pt) 2015-10-13
US20110183075A1 (en) 2011-07-28
CN102203150A (zh) 2011-09-28
EP2342244A1 (fr) 2011-07-13
CA2735977A1 (fr) 2010-05-27
EP2342244B1 (fr) 2014-04-30
US8771797B2 (en) 2014-07-08
CN102203150B (zh) 2014-03-12

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