WO2010052926A1

WO2010052926A1 - Method for manufacturing steel plate and steel pipe for ultrahigh-strength line pipe

Info

Publication number: WO2010052926A1
Application number: PCT/JP2009/005929
Authority: WO
Inventors: 原卓也; 藤城泰志; 寺田好男; 篠原康浩; 清水篤史; 内田悠
Original assignee: 新日本製鐵株式会社
Priority date: 2008-11-06
Filing date: 2009-11-06
Publication date: 2010-05-14
Also published as: BRPI0921686A2; JPWO2010052926A1; CN102203301A; CN102203301B; BRPI0921686B1; JP4819185B2; RU2461636C1

Abstract

Disclosed is a method for manufacturing a steel plate for an ultrahigh-strength line pipe, whereby: steel comprised of 0.03-0.08% C, 0.01-0.50% Si, 1.5-2.5% Mn, 0.01% or less P, 0.0030% or less S, 0.0001-0.20% Nb, 0.0005-0.03% Al, 0.003-0.030% Ti, less than 0.0003% B, 0.0010-0.0050% N, 0.0050% or less O, in terms of mass%, with the remainder being iron and unavoidable impurities, is shaped into ingots; this steel is cast into billets; these billets are hot-rolled to form a steel plate; water cooling to a prescribed temperature higher than the MS point is performed, after which a heat-recovery process is repeated at least one or more times to cool the surface of the aforementioned steel plate; and a final water-cooling is performed to cool the surface of the aforementioned steel plate to a temperature that is at or below the MS point.

Description

Steel sheet for ultra-high strength line pipe and method for manufacturing steel pipe

The present invention relates to a method for manufacturing a steel sheet for ultra-high strength line pipes having excellent deformability and low-temperature toughness, and a tensile strength (TS) in the circumferential direction of the steel pipe is 625 MPa or more, and for ultra-high strength line pipes manufactured using this steel sheet. The present invention relates to a method for manufacturing a steel pipe. In particular, the steel pipe obtained by the production method of the present invention can be widely used as a natural gas / crude oil transportation line pipe.
This application claims priority based on Japanese Patent Application No. 2008-285612 filed in Japan on November 6, 2008, the contents of which are incorporated herein by reference.

In recent years, pipelines have become increasingly important as long-distance transportation methods for crude oil and natural gas. Currently, the American Petroleum Institute (API) standard X65 is the basic design for trunk line pipes for long-distance transportation, and the actual usage of X65 line pipes is overwhelmingly large. However, a higher-strength line pipe is required for (1) improving transportation efficiency by increasing pressure and (2) improving local construction efficiency by reducing the outer diameter and weight of the line pipe. So far, line pipes up to X120 (tensile strength of 915 MPa or more) have been put into practical use.

On the other hand, in recent years, the concept of line pipe design has changed. Conventionally, it was a pipeline design (“stress based design”) with a constant stress. However, recently, a design ("strain based design") is adopted in which the circumferential welded portion of the steel pipe does not break even if the pipeline is strained, or the steel pipe itself does not buckle. Until now, for high-strength line pipes of X80 or higher, chemical components and production conditions that ensure the low temperature toughness of the base metal and the toughness of the weld heat affected zone have been studied. However, in the case of “strain based design”, the deformability of the base material or the deformability after painting of the steel pipe is also required. Unless these problems related to toughness and deformability are solved, it is impossible to manufacture steel pipes for line pipes of X80 or more for “strain based design”. To increase the strength of the pipeline, the balance between the strength of the base metal and the low temperature toughness, weld metal toughness and weld heat affected zone (HAZ) toughness, on-site weldability, joint softening resistance, and tube breakage by burst test Manufacturing conditions for manufacturing a steel pipe excellent in deformability of the base material while ensuring the properties and the like are required. Therefore, there is a demand for the development of an ultra-high strength thick line pipe of X80 or higher that satisfies these steel pipe characteristics.

So far, in order to improve the above steel pipe characteristics, for example, the following method has been proposed with respect to a method for manufacturing a steel pipe for a line pipe. In Patent Document 1 and Patent Document 2, in order to improve the deformability of the steel pipe, both the steel plate is slowly cooled in the former stage up to 500 to 600 ° C., and the latter latter is cooled at a higher cooling rate than the former stage. A method has been proposed. In this method, the microstructure of the steel sheet and the steel pipe can be controlled. Furthermore, in Patent Document 3 and Patent Document 4, in order to improve the buckling resistance of the steel pipe, both are cooled at a constant cooling rate of 15 ° C./s or more to manufacture a steel plate having a thickness of 16 mm. .

JP 2004-131799 A JP 2003-293089 A JP 11-279700 A Japanese Unexamined Patent Publication No. 2000-178689

However, the methods disclosed in Patent Literature 1 and Patent Literature 2 have a problem in that the variation in the material of the steel plate increases because the variation in the water cooling stop temperature of the steel plate is large. Also, in the methods disclosed in Patent Literature 3 and Patent Literature 4, since the variation in the water cooling stop temperature of the steel plate is large, in addition to the large variation in strength of the steel plate, it is large in terms of ensuring the deformability of the steel plate. It becomes a problem.
The present invention provides a method for producing a steel sheet and a steel pipe for an ultra-high strength line pipe having a tensile strength of 625 MPa or more (API standard X80 or more), which is excellent in the strength, low-temperature toughness and deformability of the base material and easy to be welded on site.

The inventors of the present invention have intensively studied the production conditions of steel plates and steel pipes for obtaining ultra-high strength steel plates and steel pipes having a tensile strength of 625 MPa or more and excellent in low temperature toughness. As a result, the inventors have invented a new manufacturing method for steel sheets for ultra high strength line pipes and steel pipes for ultra high strength line pipes. The gist of the present invention is as follows.
(1) In the method for producing a steel sheet for ultra-high strength line pipes, C: 0.03 to 0.08%, Si: 0.01 to 0.50%, Mn: 1.5 to 2.5 in mass%. %, P: 0.01% or less, S: 0.0030% or less, Nb: 0.0001 to 0.20%, Al: 0.0001 to 0.03%, Ti: 0.003 to 0.030% , B: less than 0.0003%, N: 0.0010 to 0.0050%, O: 0.0050% or less, with the balance being made of iron and inevitable impurities; melting this steel; a slab Te; a steel sheet subjected to hot rolling the steel strip; after water cooling to a higher predetermined temperature M _S point, repeat at least once the process for recuperation, the steel sheet The surface of the steel plate is cooled; the final water cooling is performed to cool the surface of the steel sheet to a temperature below the _MS point.
here,
M _S = 545-330 [C] +2 [Al] -14 [Cr] -13 [Cu] -23 [Mn] -5 [Mo] -4 [Nb] -13 [Ni] -7 [Si] +3 [ Ti] +4 [V]
However, [C], [Al], [Cr], [Cu], [Mn], [Mo], [Nb], [Ni], [Si], [Ti], and [V] are C , Al, Cr, Cu, Mn, Mo, Nb, Ni, Si, Ti, V content (%).
(2) In the method for producing a steel sheet for ultra-high-strength line pipes described in (1) above, the steel further contains, in mass%, Mo: 0.01 to 1.0%, Cu: 0.01 to 1 0.5%, Ni: 0.01-5.0%, Cr: 0.01-1.5%, V: 0.01-0.10%, W: 0.01-1.0%, Zr: It may contain at least one of 0.0001 to 0.050% and Ta: 0.0001 to 0.050%.
(3) In the method for producing a steel sheet for ultra-high-strength line pipes described in (1) above, the steel further contains Mg: 0.0001 to 0.010%, Ca: 0.0001 to 0% by mass. 0.005%, REM: 0.0001 to 0.005%, Y: 0.0001 to 0.005%, Hf: 0.0001 to 0.005%, Re: 0.0001 to 0.005% You may contain 1 type.
(4) In the method for producing ultra-high strength line pipes for steel sheet according to the above (1), the average cooling rate from the first water-cooled until the surface of the steel sheet reached martensitic transformation start temperature (M _S point) (° C. / s ) _May be V _C90 or less.
here,
M _S = 545-330 [C] +2 [Al] -14 [Cr] -13 [Cu] -23 [Mn] -5 [Mo] -4 [Nb] -13 [Ni] -7 [Si] +3 [ Ti] +4 [V]
V _C90 = 10 ^{(3.69-0.75β)}
β = 2.7 [C] +0.4 [Si] + [Mn] +0.45 ([Ni] + [Cu]) + 0.8 [Cr] +2 [Mo]
However, [C], [Al], [Cr], [Cu], [Mn], [Mo], [Nb], [Ni], [Si], [Ti], and [V] are C , Al, Cr, Cu, Mn, Mo, Nb, Ni, Si, Ti, V content (%).
(5) In the method for manufacturing a steel sheet for ultra-high strength line pipe according to (1) above, the water cooling speed and the final water cooling speed may be _{VC 90} or more.
(6) In the manufacturing method of the steel sheet for ultra-high strength line pipes according to (1) above, the reheating temperature of the steel slab is 950 ° C. or more in the hot rolling, and in the non-recrystallization temperature range of the steel slab. The rolling ratio may be 3 or more.
(7) In the manufacturing method of the steel plate for ultra-high strength line pipes described in (1) above, cooling may be performed from a cooling start temperature of 800 ° C. or lower.
(8) In the manufacturing method of the steel pipe for ultra high strength line pipe, the steel plate manufactured by the manufacturing method of the steel sheet for ultra high strength line pipe according to (1) is formed into a tubular shape by UO pipe forming; The part is subjected to submerged arc welding from the inner and outer surfaces using a welding wire and a firing die or a melt-type flux;
(9) In the method for manufacturing a steel pipe for ultra-high strength line pipe according to (8) above, the welded portion may be heat treated after the submerged arc welding and before the pipe expansion.
(10) In the method for manufacturing a steel pipe for ultra-high-strength line pipes described in (8) above, the weld may be heat-treated at a temperature of 200 ° C. or higher and 500 ° C. or lower.

According to the present invention, after hot-rolling a steel plate with a limited chemical composition, it is cooled while repeating water cooling and recuperation, thereby reducing variations in the strength of the steel plate and steel pipe, and the steel plate and steel pipe before and after strain aging. It is possible to improve the deformability. As a result, the safety for the line pipe is greatly improved.

It is the schematic of the hardness distribution of the board thickness direction of the manufactured steel plate. It is the schematic of the temperature distribution of the plate | board thickness direction of the steel plate during cooling. It is the schematic which shows an example of the relationship between the cooling pattern of the steel plate surface, and the transformation diagram of steel.

Hereinafter, the contents of the present invention will be described in detail.
The present invention relates to an ultra-high strength line pipe excellent in low temperature toughness having a tensile strength (TS) of 625 MPa or more. The ultra high strength line pipe of this strength level can withstand about 1.2 to 2.0 times the pressure compared to the conventional mainstream X65, so it can transport more gas with the same size as before. become. When using X65 at a higher pressure, it is necessary to increase the thickness of the line pipe. As a result, material costs, transportation costs, and local welding costs increase, and pipeline laying costs increase significantly. Therefore, in order to reduce the pipeline laying cost, an ultra-high strength line pipe excellent in low temperature toughness having a tensile strength (TS) of 625 MPa or more is required. On the other hand, as the required strength of the steel pipe increases, it becomes difficult to manufacture the steel pipe rapidly. In particular, when "strain based design" is required, it is necessary to obtain not only the balance between the strength and low temperature toughness of the base metal and the toughness of the seam weld, but also the target characteristics including the deformability after strain aging. It is. However, it is very difficult to satisfy all these characteristics.

In line pipes that require “strain based design”, the strength of the weld metal that connects the line pipes (the strength of the circumferential weld) is the longitudinal direction of the base material (the part that was the steel plate or steel plate) It must be higher than the strength in the pipe axis direction). In an environment where line pipes are used, frozen soil may thaw in the summer or freeze again in the winter. In such a case, the line pipe is distorted and breaks from the circumferential weld. In particular, when the strength of the circumferential weld is under-matching than the strength of the base metal, the fracture occurs with a smaller strain. Therefore, it is necessary to lower the strength of the base material in the longitudinal direction than the strength of the circumferential weld, and the upper limit of the strength of the base material in the longitudinal direction is set by the strength of the circumferential weld. In particular, since each grade of line pipe has a strength range, the upper limit restricts the strength of the base material for manufacturing the line pipe to a narrow range. Therefore, it is required to stably manufacture a line pipe and its base material with suppressed variation in strength.

In order to limit the tensile strength of the base material of the line pipe to 625 MPa or more and a narrow range, the inventors conducted intensive research. As a result, it has become clear that it is extremely important to use low carbon steel for the steel sheet and to make the cooling conditions appropriate during hot rolling of the steel sheet. For example, if the amount of C exceeds 0.08%, the hardenability is too high, and the strength greatly changes between the center portion and the surface of the steel plate. Therefore, low carbon steel is used for the steel plate. Also, for example, even if the C amount is 0.08% or less, if the cooling condition is not limited at all on the steel sheet surface, martensite may or may not be generated depending on the method for cooling the steel sheet surface. . In that case, there is a difference in hardness between the steel plate surface and the central portion of the steel plate in the thickness direction (inside the steel plate), or there is a variation in strength within a single steel plate or between manufactured steel plates. A line pipe having a range strength cannot be manufactured.

The intensity variation will be described with reference to FIGS. 1A and 1B. FIG. 1A is a schematic diagram of the hardness distribution in the plate thickness direction of the manufactured steel plate, and FIG. 1B is a schematic diagram of the temperature distribution in the plate thickness direction of the steel plate being cooled. 1A and 1B, the dotted line indicates the center of the plate thickness, the alternate long and short dash line (a) indicates the result of simple cooling by water cooling (for example, the cooling condition indicated by the broken line (i) in FIG. 2), and the solid line (b ) Shows the results under the cooling conditions of the present invention. As shown by the alternate long and short dash line (a) in FIG. 1A, when cooling (simple cooling) is performed without restricting the cooling conditions of the steel sheet surface, the steel sheet surface and the center part in the thickness direction of the steel sheet (inside the steel sheet) There is a difference in hardness. This difference in hardness is caused by the temperature distribution in the plate thickness direction of the steel plate being cooled as shown in FIG. 1B. Since the steel sheet surface is in direct contact with water during water cooling, it is easily cooled. However, since the cooling rate is governed by heat transfer inside the steel plate, the inside of the steel plate is less likely to be cooled than the steel plate surface. Therefore, structures having different hardnesses are obtained on the steel sheet surface and the steel sheet interior. Therefore, in simple cooling, a hardness distribution is produced in the manufactured steel sheet due to the temperature distribution in the steel sheet being cooled. Such a hardness distribution is not limited to the thickness direction of the plate, and can occur at any location in the steel plate due to non-uniformity such as uneven cooling water amount. Such a variation in strength within the steel sheet is a problem in that it causes surface defects such as wrinkles and cracks during the manufacture of a steel pipe in which stress concentration occurs on the surface of the steel sheet. Moreover, in simple cooling, since the temperature which stops the water cooling of a steel plate may change for every manufacturing lot, the dispersion | variation in intensity | strength is easy to produce between the manufactured steel plates.

In order to suppress such variation in strength, the steel sheet surface is not cooled at a time, but is cooled while repeating water cooling and recuperation described later, so that the strength within a single steel sheet and between manufactured steel sheets. Succeeded in reducing the variation of Recuperation is the temperature of the steel sheet surface (low temperature part) than immediately after water cooling by stopping water cooling for a predetermined time and transferring heat from the inside of the steel sheet to the steel sheet surface (heat transfer from the high temperature part to the low temperature part). Is a process to increase By this recuperation, the temperature difference between the inside of the steel sheet and the steel sheet surface is reduced, and the temperature distribution in the steel sheet becomes uniform. Moreover, even in different production lots, the temperature history can be controlled uniformly. However, in the present invention, in order to obtain a bainite / ferrite mixed structure, after water cooling to higher predetermined temperature of the surface of the steel sheet martensitic transformation start temperature (M _S point), at least once a process for recuperation It is most important to repeat the above cooling. Furthermore, the steel sheet surface from the water cooling initiation (initial water cooling) is below the average critical cooling rate cooling rate of 90% martensite structure is obtained in the steel sheet surface to reach the martensite transformation start temperature (M _S point), The intensity variation is further suppressed. Note that recuperation may be performed by adjusting the amount of cooling water (for example, by reducing the amount of water). Moreover, you may reheat after performing final water cooling. In this case, the water cooling stop temperature may exceed the _MS point.

Hereinafter, the reason for limiting the steel plate (base material) component of the present invention will be described. In the chemical component of the present invention,% means mass%.
C is indispensable as a basic element for improving the strength of the base material. Therefore, it is necessary to add 0.03% or more of C. When C is added excessively exceeding 0.08%, the weldability and toughness of the steel material are lowered. Therefore, the upper limit of the addition amount of C is set to 0.08%.

Si is required as a deoxidizing element during steelmaking. For deoxidation, it is necessary to add 0.01% or more of Si to the steel. However, when Si is added exceeding 0.50%, the HAZ toughness of the steel material decreases. Therefore, the upper limit of the amount of Si is 0.50%.

Mn is an element necessary for ensuring the strength and toughness of the base material. However, if the amount of Mn exceeds 2.5%, the HAZ toughness of the base material is significantly lowered. If the amount of Mn is less than 1.5%, it becomes difficult to ensure the strength of the base material. Therefore, the range of the amount of Mn is set to 1.5 to 2.5%.

P is an element that affects the toughness of steel. If the amount of P exceeds 0.01%, not only the base material but also the toughness of the HAZ is significantly reduced. Therefore, the upper limit of the amount of P is set to 0.01%.

When S is added in excess of 0.0030%, coarse sulfides are generated. Since this coarse sulfide reduces toughness, the upper limit of the amount of S is made 0.0030%.

Nb is an element having the effect of improving the strength by forming carbides and nitrides. However, the addition of Nb of 0.0001% or less has no effect. Further, when Nb exceeds 0.20%, toughness is reduced. Therefore, the range of the amount of Nb is set to 0.0001 to 0.20%.

Al is usually added as a deoxidizer. In the present invention, if Al is added in an amount exceeding 0.03%, a Ti-based oxide is not generated. Therefore, the upper limit of the amount of Al is set to 0.03%. Moreover, in order to reduce the amount of oxygen in molten steel, it is necessary to add Al 0.0001% or more. Therefore, the lower limit of the amount of Al is set to 0.0001%.

Ti is an element that exerts an effect on the refinement of crystal grains as a deoxidizing material and further as a nitride-forming element. However, the addition of a large amount of Ti causes a significant decrease in toughness due to the formation of carbides, so the upper limit of the amount of Ti needs to be 0.030%. However, in order to obtain a predetermined effect, it is necessary to add 0.003% or more of Ti. Therefore, the range of the amount of Ti is set to 0.003 to 0.030%.

B is an element that generally dissolves in steel to increase hardenability and remarkably suppress the formation of ferrite. Therefore, the amount of B is less than 0.0003%.

N is necessary for finely depositing TiN and reducing the austenite grain size. If the amount of N is 0.0010%, refinement is not sufficient, so the lower limit of the amount of N is set to 0.0010%. Further, if the amount of N exceeds 0.0050%, the amount of solute N increases and the low temperature toughness of the base material deteriorates. Therefore, the upper limit of the amount of N is set to 0.0050%.

When O is added excessively over 0.0050%, a coarse oxide is generated and the toughness of the base material is lowered. Therefore, the upper limit of the amount of O is set to 0.0050%.

Steel containing the above elements and the balance being iron (Fe) and inevitable impurities is a preferable basic composition used for the steel plate and steel pipe of the present invention.

In the present invention, at least one element selected from Mo, Cu, Ni, Cr, V, Zr, and Ta can be added as needed to improve the strength and toughness.

Mo is an element that improves hardenability and at the same time forms carbides and nitrides to improve strength. In order to obtain the effect, it is necessary to add 0.01% or more of Mo. However, the addition of a large amount of Mo exceeding 1.0% increases the strength of the base material more than necessary and significantly reduces the toughness. Therefore, the range of the amount of Mo is set to 0.01 to 1.0%.

Cu is an effective element for increasing strength without reducing toughness. However, if the amount of Cu is less than 0.01%, the effect is not obtained. If the amount of Cu exceeds 1.5%, cracks are likely to occur during heating of the steel slab or during welding. Therefore, the content of Cu is set to 0.01 to 1.5%.

Ni is an element effective for improving toughness and strength. In order to obtain the effect, it is necessary to add 0.01% or more of Ni. However, when Ni is added over 5.0%, the weldability is lowered. Therefore, the upper limit of the amount of Ni is set to 5.0%.

Cr is an element that improves the strength of steel by precipitation strengthening. Therefore, it is necessary to add 0.01% or more of Cr. However, when Cr is added in a large amount, the hardenability is increased, so that a martensite structure is formed and the toughness is lowered. Therefore, the upper limit of the Cr content is 1.5%.

V is an element that has the effect of improving the strength by forming carbides and nitrides. However, the addition of 0.01% or less V has no effect. Further, when V exceeds 0.10%, toughness is reduced. Therefore, the range of the amount of V is set to 0.01 to 0.10%.

W is an element that improves hardenability and at the same time forms carbides and nitrides to improve strength. In order to acquire the effect, it is necessary to add 0.01% or more of W. However, the addition of a large amount of W exceeding 1.0% increases the strength of the base material more than necessary and significantly reduces the toughness. Therefore, the range of the amount of W is set to 0.01 to 1.0%.

Zr and Ta are elements that have the effect of improving the strength by forming carbides and nitrides similarly to Nb. However, the addition of 0.0001% or less has no effect. In addition, addition of Zr or Ta exceeding 0.050% causes a decrease in toughness. Therefore, the range of the amount of Zr or Ta is set to 0.0001 to 0.050%.

In the present invention, if necessary, at least one element selected from Mg, Ca, REM, Y, Hf, and Re is added in order to improve the pinning effect due to the oxide or the lamellar resistance. Can do.

Mg is mainly added as a deoxidizer. However, if Mg is added over 0.010%, a coarse oxide is likely to be formed, and the base material and the HAZ toughness are lowered. Further, when Mg is added in an amount of less than 0.0001%, it is not possible to sufficiently expect intragranular transformation and generation of oxides necessary as pinning particles. Therefore, the addition range of Mg is set to 0.0001 to 0.010%.

Ca, REM, Y, Hf, and Re suppress the generation of MnS that tends to extend in the rolling direction by generating sulfides, and improve the properties in the plate thickness direction of the steel material, particularly the lamellar resistance. If Ca and REM, Y, Hf, and Re are all less than 0.0001%, this effect cannot be obtained. Therefore, the lower limit of the amount of Ca and REM, Y, Hf, Re is set to 0.0001%. Conversely, when Ca and REM, Y, Hf, and Re all exceed 0.0050%, the number of Ca and REM, Y, Hf, and Re oxides increases, and the ultrafine Mg-containing oxides. The number decreases. Therefore, the upper limit of the amount of Ca and REM, Y, Hf, Re is set to 0.0050%.

Steel containing the above components is melted in the steel making process, and then cast by continuous casting or the like to obtain a steel piece (slab). The steel slab is subjected to hot rolling (rolling after heating the steel slab) to obtain a steel plate. In this case, the steel slab is heated to a temperature equal to or higher than the _AC3 point (reheating temperature) and rolled so that the reduction ratio in the recrystallization temperature range is 2 or more and the reduction ratio in the non-recrystallization temperature range is 3 or more. To do. As a result, the average prior austenite grain size of the obtained steel sheet is 20 μm or less.

The reheating temperature of the steel slab (slab) is preferably 950 ° C. or higher. In addition, if the reheating temperature becomes too high, the γ grains become coarse during heating, so the reheating temperature is preferably 1250 ° C. or lower.

Regarding the reduction ratio in the recrystallization temperature range, if the reduction ratio is less than 2, recrystallization does not occur sufficiently, so the reduction ratio is preferably 2 or more.

If the reduction ratio in the non-recrystallization temperature range is 3 or more, the average prior austenite grain size of the steel sheet will be 20 μm or less. Therefore, it is preferable that the rolling ratio in the non-recrystallization temperature region is 3 or more. More preferably, the rolling ratio in the non-recrystallization temperature region is 4 or more. In this case, the average prior austenite grain size of the steel sheet can be made 10 μm or less.

About the temperature (water cooling start temperature) which starts water cooling, it is preferable to cool a steel plate from the water cooling start temperature of 800 degrees C or less. That is, cooling of the steel sheet is started from _Ae3 or less. In this case, ferrite transformation occurs and the yield ratio of the steel sheet decreases, so that the deformability of the steel sheet becomes good.

As for the cooling method, it is most important to cool the steel plate surface by repeating water cooling and recuperation until the steel plate surface reaches the martensitic transformation start temperature. By this cooling method, the above-described variation in strength of the steel sheet can be suppressed. Furthermore, cooling of the critical water cooling start average cooling rate of the steel sheet surface from (the first water cooling) until the surface of the steel sheet reached martensitic transformation start temperature (M _S point) (° C. / s) 90% martensite is obtained When the speed is V _C90 (° _C./s ) or less, the variation in strength is further suppressed. Incidentally, in the following (1) and (2) and (3) shows a calculation formula for the _{M S} point and _{V C90,} respectively.
M _S = 545-330 [C] +2 [Al] -14 [Cr] -13 [Cu] -23 [Mn] -5 [Mo] -4 [Nb] -13 [Ni] -7 [Si] +3 [ Ti] +4 [V] (1)
V _C90 = 10 ^{(3.69-0.75β)} (2)
β = 2.7 [C] +0.4 [Si] + [Mn] +0.45 ([Ni] + [Cu]) + 0.8 [Cr] +2 [Mo] (3)
However, in the above formulas (1) to (3), [C], [Al], [Cr], [Cu], [Mn], [Mo], [Nb], [Ni], [Si], [Ti] ] And [V] are the contents (%) of C, Al, Cr, Cu, Mn, Mo, Nb, Ni, Si, Ti, and V, respectively.
In addition, the temperature of the steel plate surface is measuring the center part of the width direction of a steel plate.

The recuperation in the present invention will be described. Recuperation of the present invention, when cooling the steel sheet after cooling once by water cooling the surface of the steel sheet to a predetermined temperature higher than M _S point, stops for a predetermined time water cooling, water cooling temperature of the steel sheet surface than immediately This is an operation to raise the height. That is, after performing water cooling until reaching a predetermined temperature higher than the _MS point, the process of performing recuperation is repeated at least once to cool the surface of the steel sheet. Then, the last water cooling (final water cooling) is performed and the surface of a steel plate is cooled to the temperature below _MS point. You may reheat again after this final water cooling. When this recuperation is performed, the final cooling temperature is the temperature after the last recuperation. In addition, in order to prevent the dispersion | variation in the intensity | strength in a steel plate, it is preferable that the frequency | count of reheating of the steel plate before final water cooling is 2 times or more. Moreover, in order to ensure productivity, it is preferable that the speed of water cooling and final water cooling is _VC90 or more. The cooling device used in the present invention has several places (called zones) where nozzles that can be controlled to have the same water density are gathered. In the present invention, for example, these zones are assigned to a water cooling zone that performs water cooling and a recuperation zone that does not perform water cooling. That is, when water cooling is performed in the first zone (water cooling zone) and water cooling is not performed in the second zone (recuperation zone), the surface temperature of the steel sheet is the temperature at the outlet of the second zone. Higher than the temperature at the outlet. Furthermore, when water cooling is performed in the third zone (water cooling zone), the surface temperature of the steel sheet decreases. In this way, the surface temperature of the steel sheet is lowered by repeating the water cooling zone and the recuperation zone. The zone where no water cooling is performed (recuperation zone) can be arbitrarily determined in consideration of the cooling state of the steel sheet. Finally, the steel sheet surface is cooled to a temperature below the _MS point in the last water cooling zone.

The reason why cooling is performed under the above cooling conditions will be specifically described below with reference to FIG. FIG. 2 is an example of the relationship between the cooling pattern of the steel sheet surface and the steel transformation diagram. A broken line (i) in FIG. 2 shows a cooling pattern when the steel plate is cooled at the cooling rate _VC90 . In this cooling pattern, about 90% of the steel sheet has a martensite structure. As shown by the dotted line (ii) in FIG. 2, when the average cooling rate on the steel sheet surface is higher than the cooling rate _VC90 , the steel sheet surface has a substantially martensitic structure. Therefore, even when the steel sheet surface is reheated, the toughness of the steel sheet surface is significantly reduced, and surface defects such as surface cracks may occur in the steel sheet during the production of the steel pipe. On the other hand, as shown by the solid lines (iii) and (iv) in FIG. 2, when the average cooling rate on the surface of the steel sheet is smaller than the cooling rate _VC90 , the steel sheet has the bainite / ferrite mixed structure of the present invention. . In addition, by reheating the steel sheet surface, a steel sheet with a uniform structure and less variation in strength can be produced.

冷却 About the cooling stop temperature, when the last water cooling (final water cooling) is stopped at 200 ° C. or less, a defect considered to be caused by hydrogen is generated at the center of the plate thickness of the steel sheet. For this reason, the lower limit of the cooling stop temperature is preferably 200 ° C.

Next, a method for producing a line pipe by the UO process (UO pipe making) using the steel sheet for ultra-high strength line pipe produced by the production method described above will be described. After manufacturing a steel plate having a thickness of 12 to 25 mm, it is formed into a tubular shape by UO pipe making (C press, U press, O press). Thereafter, the end portions of the steel plates formed into a tubular shape are brought together to perform tack welding. MAG welding or MIG welding is used for this tack welding. After tack welding, submerged arc welding is performed from the inner and outer surfaces of the butted portion of the steel sheet formed into a tubular shape. In this submerged arc welding, a welding wire and a fired mold or a molten flux are used. Finally, pipe expansion is performed to produce a steel pipe.

In the method for manufacturing a steel pipe for an ultra-high strength line pipe according to the present invention, after the submerged arc welding of the inner and outer surfaces described above, and before the pipe expansion, a heat treatment is performed on the welded portion (seam welded portion). preferable. Moreover, it is preferable to heat-process a welding part at the temperature of 200 degreeC or more and 500 degrees C or less as heat treatment conditions of this steel pipe. By this heat treatment, MA (mixed structure of austenite and martensite) harmful to toughness generated in the welded portion (welded metal) can be reduced. When the weld is heated to a temperature of 200 ° C. or higher and 500 ° C. or lower, the coarse MA generated along the prior austenite grain boundaries decomposes into fine cementite. However, when the weld is heat treated at less than 200 ° C., coarse MA does not decompose into cementite. Therefore, the lower limit of the heat treatment temperature of the weld zone is 200 ° C. Moreover, if the welded part is heat-treated at a temperature exceeding 500 ° C., the toughness of the welded part deteriorates. Therefore, the upper limit of the heat treatment temperature of the weld is 500 ° C.

Next, examples of the present invention will be described.
After heating a steel piece having a thickness of 240 mm having the chemical composition shown in Table 1 to 1000 to 1210 ° C., it is hot in a recrystallization temperature range of 950 ° C. or more until the thickness of the steel piece (transport thickness) reaches 70 to 100 mm. Rolled. Further, hot rolling was performed in a non-recrystallization temperature range of 880 to 750 ° C. until the thickness of the steel slab (plate thickness) became 12 to 25 mm. Thereafter, cooling of the steel sheet (initial water cooling) is started from a temperature of 650 to 795 ° C., water cooling is performed to a predetermined temperature higher than the _MS point, and then a reheating process is repeated at least once or more to cool the steel sheet. went. Thereafter, cooling (final water cooling) was stopped at a temperature of 300 to 470 ° C. In Table 1, the carbon equivalent C _eq and the weld crack sensitivity index P _cm are also shown for reference.
In order to evaluate the yield strength and tensile strength of each manufactured steel sheet, a full-thickness test piece based on the API5L standard was sampled from each steel sheet and subjected to a tensile test at room temperature. Regarding the sampling direction, these full-thickness test pieces were collected so that the longitudinal direction of the full-thickness test pieces coincided with the width direction of the steel sheet. Further, the sampling position of the full thickness test piece is a position 1 m away from the steel plate front end and the steel plate end in the longitudinal direction of the steel plate. Two full-thickness test pieces were collected on both sides from the center of the plate width of the steel plate at these positions.

Next, after forming this steel plate by UO pipe making, the butt portion of the steel plate was tack welded by carbon dioxide arc welding. Thereafter, seam welding by submerged arc welding was performed from the inner and outer surfaces of the butted portion of the steel plate using a welding wire and a melt flux to obtain a steel pipe. The average heat input of seam welding was 2.0 to 5.0 kJ / mm. Some steel pipes were subjected to heat treatment at 250 to 450 ° C. in the seam welds. Table 2 shows the production conditions of the steel plate and the steel pipe.

In order to evaluate the yield strength and tensile strength of each manufactured steel pipe, an API test piece was collected from each steel pipe and subjected to a tensile test. Regarding the sampling direction, these API specimens were collected such that the longitudinal direction of the API specimen coincided with the pipe axis direction of the steel pipe. As for the sampling position, two API test pieces were sampled on both sides of the cut surface perpendicular to the pipe axis, centered on a position one quarter turn away from the seam welded portion of each steel pipe. Also, as a reference, in order to evaluate the deformability after strain aging, these steel pipes were heat-treated at 210 ° C. (held for 5 minutes and then air-cooled), and two API test pieces were collected from the same position as above and pulled. A test was conducted. The tensile test is based on API standard 2000. In order to evaluate the toughness of the steel pipe, a Charpy test and a DWT test at −30 ° C. were performed. The Charpy test and the DWT test are also compliant with the API standard 2000. Charpy specimen and DWT specimen are sampled from a position 1/2 turn away from the seam weld of the steel pipe at the cutting plane perpendicular to the pipe axis so that the longitudinal direction of the specimen coincides with the circumferential direction of the steel pipe It was done. Two DWT specimens were taken from each steel pipe, and three Charpy specimens were taken from the thickness center of each steel pipe.
Furthermore, the HAZ toughness of each manufactured steel pipe was evaluated. A specimen for evaluating HAZ toughness is taken from the weld heat affected zone (HAZ) in the vicinity of the seam welded portion of the steel pipe, and is FL + 1 mm (1 mm from the boundary between the HAZ portion and the seam welded portion to the HAZ portion side). A notch was made. Three of these specimens were taken from each steel pipe. Each of these test pieces was evaluated by a Charpy test at −30 ° C.
These test results are shown in Table 3. In Table 3, not only the tensile strength but also the yield strength and the yield ratio are shown for reference.

Steels 1 to 22 represent examples of the present invention. As apparent from Table 3, these steel plates and steel pipes had a tensile strength of X80 or more, and the variation in strength within the steel plates and steel pipes was also suppressed to 60 MPa or less. Moreover, the Charpy energy of the steel pipe was 200 J or more, the DWTT ductile fracture surface ratio was 85% or more, and the Charpy absorbed energy (HAZ toughness) of the weld heat affected zone exceeded 50 J. Thus, the steel pipe in the Example of this invention had high toughness. Steels 23 to 35 represent comparative examples that do not satisfy the production conditions of the present invention. That is, in Steel 23, since the amount of C in the steel is smaller than the range of the present invention, the tensile strength was not sufficient. In Steels 24 to 29, at least one element out of the basic components and selected elements is added to the steel beyond the scope of the present invention, so that the toughness (Charpy energy) or HAZ toughness of the base material of the steel pipe is increased. It was not enough. On the other hand, in the steels 30 to 35, the steel plate surface was cooled without reheating, so the strength variation of the steel plate and the steel pipe was as large as 100 MPa or more. Moreover, the yield strength of the steel pipe after heat treatment at 210 ° C. increased by 200 MPa or more compared to the yield strength of the steel plate. That is, since the steel plate surface was cooled without reheating, the deformability after strain aging was greatly reduced.

It is possible to provide a method for producing a steel sheet and a steel pipe for an ultra-high-strength line pipe having a tensile strength of 625 MPa or more (API standard X80 or more), which is excellent in strength, low-temperature toughness and deformability of the base material and easy to be welded on site.

Claims

% By mass
C: 0.03-0.08%
Si: 0.01 to 0.50%
Mn: 1.5 to 2.5%
P: 0.01% or less S: 0.0030% or less Nb: 0.0001 to 0.20%
Al: 0.0001 to 0.03%
Ti: 0.003-0.030%
B: Less than 0.0003% N: 0.0010 to 0.0050%
O: steel containing 0.0050% or less, the balance being iron and inevitable impurities;
Cast this steel into billets;
This steel slab is hot-rolled into a steel plate;
After performing water cooling until a predetermined temperature higher than the MS point is reached, the process of reheating is repeated at least once to cool the surface of the steel sheet;
Final water cooling is performed to cool the surface of the steel sheet to a temperature below the MS point;
The manufacturing method of the steel plate for ultra high strength line pipes characterized by the above-mentioned.
M S = 545-330 [C] +2 [Al] -14 [Cr] -13 [Cu] -23 [Mn] -5 [Mo] -4 [Nb] -13 [Ni] -7 [Si] +3 [ Ti] +4 [V]
However, [C], [Al], [Cr], [Cu], [Mn], [Mo], [Nb], [Ni], [Si], [Ti], and [V] are C , Al, Cr, Cu, Mn, Mo, Nb, Ni, Si, Ti, V content (%)
The steel is further in mass%,
Mo: 0.01 to 1.0%
Cu: 0.01 to 1.5%
Ni: 0.01 to 5.0%
Cr: 0.01 to 1.5%
V: 0.01 to 0.10%
W: 0.01 to 1.0%
Zr: 0.0001 to 0.050%
Ta: 0.0001 to 0.050%
The manufacturing method of the steel plate for ultra-high-strength line pipes of Claim 1 containing at least 1 sort (s) among these.
The steel is further in mass%,
Mg: 0.0001 to 0.010%
Ca: 0.0001 to 0.005%
REM: 0.0001 to 0.005%
Y: 0.0001 to 0.005%
Hf: 0.0001 to 0.005%
Re: 0.0001 to 0.005%
The manufacturing method of the steel plate for ultra-high-strength line pipes of Claim 1 containing at least 1 sort (s) among these.
Ultra-high-strength line according to claim 1, wherein the average cooling rate from the first water-cooled until the surface of the steel sheet reached martensitic transformation start temperature (M S point) (℃ / s) is equal to or is V C90 less Manufacturing method of steel plate for pipes.
M S = 545-330 [C] +2 [Al] -14 [Cr] -13 [Cu] -23 [Mn] -5 [Mo] -4 [Nb] -13 [Ni] -7 [Si] +3 [ Ti] +4 [V]
V C90 = 10 (3.69-0.75β)
β = 2.7 [C] +0.4 [Si] + [Mn] +0.45 ([Ni] + [Cu]) + 0.8 [Cr] +2 [Mo]
However, [C], [Al], [Cr], [Cu], [Mn], [Mo], [Nb], [Ni], [Si], [Ti], and [V] are C , Al, Cr, Cu, Mn, Mo, Nb, Ni, Si, Ti, V content (%)
The method for producing a steel sheet for ultra-high-strength line pipe according to claim 1, wherein the water cooling speed and the final water cooling speed are VC90 or more.
2. The ultrahigh strength according to claim 1, wherein in the hot rolling, the reheating temperature of the steel slab is 950 ° C. or more, and the reduction ratio in the non-recrystallization temperature range of the steel slab is 3 or more. Manufacturing method of steel plate for line pipe.
The method for producing a steel sheet for ultra-high strength line pipe according to claim 1, wherein cooling is performed from a cooling start temperature of 800 ° C or lower.
A steel sheet manufactured by the method for manufacturing a steel sheet for ultra-high strength line pipe according to claim 1 is formed into a tubular shape by UO pipe forming;
Submerged arc welding is performed on the abutting portion of the steel sheet from the inner and outer surfaces using a welding wire and a firing die or a molten flux;
Then expand the tube;
A method for producing a steel pipe for an ultra-high-strength line pipe.
The method for manufacturing a steel pipe for an ultra-high-strength line pipe according to claim 8, wherein the welded portion is heat-treated after the submerged arc welding and before the pipe expansion.
The method for manufacturing a steel pipe for an ultra-high-strength line pipe according to claim 9, wherein the weld is heat-treated at a temperature of 200 ° C or higher and 500 ° C or lower.