WO2009123244A1 - Solid-state image sensor with reduced blooming and colour mixing - Google Patents

Solid-state image sensor with reduced blooming and colour mixing Download PDF

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Publication number
WO2009123244A1
WO2009123244A1 PCT/JP2009/056763 JP2009056763W WO2009123244A1 WO 2009123244 A1 WO2009123244 A1 WO 2009123244A1 JP 2009056763 W JP2009056763 W JP 2009056763W WO 2009123244 A1 WO2009123244 A1 WO 2009123244A1
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WO
WIPO (PCT)
Prior art keywords
semiconductor region
solid
imaging apparatus
state imaging
region
Prior art date
Application number
PCT/JP2009/056763
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French (fr)
Inventor
Shouji Kouno
Toru Koizumi
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Canon Kabushiki Kaisha
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Filing date
Publication date
Application filed by Canon Kabushiki Kaisha filed Critical Canon Kabushiki Kaisha
Priority to KR1020107023614A priority Critical patent/KR101206589B1/en
Priority to AT09726927T priority patent/ATE543334T1/en
Priority to EP09726927A priority patent/EP2279614B1/en
Priority to CN2009801116483A priority patent/CN101981919B/en
Priority to US12/935,313 priority patent/US8670056B2/en
Publication of WO2009123244A1 publication Critical patent/WO2009123244A1/en

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144—Devices controlled by radiation
    • H01L27/146—Imager structures
    • H01L27/14601—Structural or functional details thereof
    • H01L27/1463—Pixel isolation structures
    • H—ELECTRICITY
    • H04—ELECTRIC COMMUNICATION TECHNIQUE
    • H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N25/00—Circuitry of solid-state image sensors [SSIS]; Control thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144—Devices controlled by radiation
    • H01L27/146—Imager structures
    • H01L27/14601—Structural or functional details thereof
    • H01L27/14609—Pixel-elements with integrated switching, control, storage or amplification elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0352—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their shape or by the shapes, relative sizes or disposition of the semiconductor regions
    • H01L31/035272—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their shape or by the shapes, relative sizes or disposition of the semiconductor regions characterised by at least one potential jump barrier or surface barrier
    • H01L31/03529—Shape of the potential jump barrier or surface barrier

Definitions

  • the present invention relates to a solid-state imaging apparatus converting an image into an electric signal.
  • the present invention relates an active pixel sensor (hereinafter referred to as ⁇ APS”) , including an amplifier in each pixel or in every plurality of pixels.
  • ⁇ APS active pixel sensor
  • a solid-state imaging apparatus of an APS structure is also called as a CMOS sensor, and is widely used for digital cameras and the like.
  • a conventional solid-state imaging apparatus has the problem of the following phenomena.
  • the phenomena are a blooming phenomenon, in which signal charges escape into an adjacent photoelectric converting portion, the color mixing, in which color reproducibility worsens by the blooming phenomenon, and the like.
  • the generating mechanisms of these phenomena are severally as follows: the signal charges accumulated in a semiconductor region constituting a photoelectric converting portion for accumulating signal charges (N type semiconductor region in the case where the signal charges are electrons) become a saturation state, and overflowing signal charges go over an element isolation region to arrive at an adjacent pixel.
  • Patent Document 1 discloses the configuration in which a deep isolation injection layer is formed under the element isolation region.
  • the Patent Document 1 describes the configuration of obstructing the effluences of signal charges from a photodiode.
  • Patent Document 2 Japanese Patent Application Laid-Open No. 2005-229105 discloses the following configuration. That is, an overflow path region is formed under an element isolation insulation film, and the overflow path region is made to have a piece of potential lower than that of a P type well region constituting a photodiode. Thus, the photodiode overflows with signal charges, which are discharged to an N type silicon substrate, to suppress the blooming.
  • Patent Document 3 Japanese Patent Application Laid-Open No. 2006-024907 (hereinafter referred to as Patent Document 3) describes an element isolation structure suppressing the escaping of signal charges.
  • Patent Document 3 Japanese Patent Application Laid-Open No. 2006-024907
  • the signal charges generated by a photoelectric conversion at a deep part of a well are sometimes discharged when the P well constituting the photodiode is deeply formed, and the sensitivity of the photodiode does not sometimes become high.
  • the signal charge collecting efficiency cannot be said yet to be sufficient, and there is room for further examination.
  • the present invention is based on the concept of providing the optimum element isolation structure according to the depth and concentration of a P type well constituting a photodiode.
  • the present invention is directed to provide a solid-state imaging apparatus capable of suppressing blooming and color mixing even if the sensitivity of the photoelectric converting portion of a photodiode or the like is improved.
  • An object of the present invention is to provide a solid-state imaging apparatus comprising a plurality of pixels, each pixel including a photoelectric converting portion for converting an incident light into signal charges and a transferring portion for transferring the signal charge from the photoelectric converting portion, wherein the photoelectric converting portion and the transferring portion are arranged at least on a semiconductor substrate, the photoelectric converting portion includes a first semiconductor region of a first conductivity type for accumulating the signal charge and a second semiconductor region of a second conductivity type forming PN junction with the first semiconductor region, a third semiconductor region of the first conductivity type is arranged between adjacent first semiconductor regions, a fourth semiconductor region of the second conductivity type and of an impurity concentration higher than that of the second semiconductor region is arranged between the first and third semiconductor regions, and a fifth semiconductor region of the second conductivity type, and of an impurity concentration higher than that of the second semiconductor region, to form an impurity concentration profile such that the impurity concentration gradually decreases toward a surface direction is arranged under the third
  • FIG. 1 is a planar layout view of pixels in a first embodiment.
  • FIG. 2 is a cross-sectional structure diagram of the first embodiment taken along a line 2-2 in FIG. 1.
  • FIG. 3 is a concentration profile of a P type well and a second P type element isolation diffusion layer of the first embodiment.
  • FIG. 4 is a cross-sectional structure diagram of pixels in a second embodiment.
  • FIG. 5 is a planar layout view of pixels in a third embodiment.
  • FIG. 6 is a cross-sectional structure diagram of the third embodiment taken along a line 6-6 of FIG. 5.
  • FIG. 7 is a graph illustrating impurity concentration heights and electron suppressing ratios of the second P type element isolation diffusion layer to the impurity concentrations of a P type well.
  • FIG. 8 is an example of a block diagram in the case of applying a solid-state imaging apparatus according to the present invention to a camera.
  • FIG. 9 is an example of an equivalent circuit diagram of a pixel applicable to the present invention.
  • the accompanying drawings which are incorporated in and constitute a part of the specification, illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
  • the semiconductor substrate in the following description indicates a part to be a base on which each semiconductor region is formed, and a device is formed on the surface part of the semiconductor substrate.
  • the semiconductor substrate is denoted by a reference numeral 101 in FIG. 2.
  • the whole configuration including the semiconductor substrate 101 and a principal plane on which the device is formed is called as the semiconductor substrate.
  • the whole configuration including the portions denoted by reference numerals 101-108 in FIG. 2 is supposed to be called as the semiconductor substrate.
  • the principal plane on which the device of the semiconductor substrate 101 is formed is taken as the criterion of the depth of each semiconductor region in the semiconductor substrate when the depth is described, and it is supposed that the depth becomes deeper when a position becomes distant from the principal plane.
  • a position is defined by the upper and lower sides, a position closer to the principal plane on which the device of the semiconductor substrate 101 is formed is defined as the upper side.
  • FIG. 9 illustrates an example of an equivalent circuit diagram of pixels applicable to the present invention.
  • each pixel is denoted by a reference numeral 1410.
  • the pixel 1410 includes a photodiode 1400, which functions as a photoelectric converting portion, a transfer transistor 1401, a reset transistor 1402, an amplifying transistor 1403, and a selection transistor 1404.
  • the pixel further includes a power source line Vcc and an output line 1406.
  • the anode of the photodiode 1400 is connected to the grounding wire, and the cathode of the photodiode 1400 is connected to the source of the transfer transistor 1401. Moreover, the source of the transfer transistor 1401 may be configured in the semiconductor region shared by the cathode of the photodiode.
  • the drain of the transfer transistor 1401 is connected to the floating diffusion (hereinafter referred to as FD) region, and the gate of the transfer transistor 1401 is connected to a transfer control line, Furthermore, the drain of the reset transistor 1402 is connected to the power source line Vcc, and the source of the reset transistor 1402 is connected to the FD region. The gate of the reset transistor 1402 is connected to a reset control line.
  • the drain of the transfer transistor 1401 and the FD region, or the drain of the reset transistor 1402 and the FD region may be configured in a common semiconductor region.
  • the drain of the amplifying transistor 1403 is connected to the power source line Vcc, and the source of the amplifying transistor 1403 is connected to the drain of the selection transistor 1404.
  • the gate of the amplifying transistor 1403 is connected to the FD region.
  • the drain of the selection transistor 1404 is connected to the source of the amplifying transistor 1403, and the source of the selection transistor 1404 is connected to the output line 1406.
  • the gate of the selection transistor 1404 is connected to a vertical selection line driven by a vertical selection circuit (not illustrated) .
  • the photodiode 1400 pairs of electrons and holes are generated by an incident light. An electric charge, one of each of these pairs, is used to as a signal charge to be transferred by the transfer transistor 1401 to the FD region.
  • the gate potential of the amplifying transistor 1403 changes according to the transferred signal charge quantity.
  • the amplifying transistor 1403 outputs an amplified signal to output line 1406 by the source follower circuit, which the amplifying transistor 1403 constitutes with a not- illustrated constant current source, on the basis of the potential change of the gate of the amplifying transistor 1403.
  • the selection transistor 1404 controls the output from each pixel.
  • the circuit configuration illustrated here can be applied to all of the embodiments of the present invention. Furthermore, the following modifications can be considered.
  • the above circuit configuration can be applied to the configuration of lacking the transfer transistor 1401 with the photodiode 1400 connected to the gate of the amplifying transistor 1403 directly and the circuit configuration of sharing the amplifying transistor 1403 with a plurality of pixels.
  • the configuration of being not provided with the selection transistor 1404 but performing the selection of a pixel by controlling the gate potential of the amplifying transistor 1403 may be adopted.
  • FIG. 1 is a planar layout view of the pixels.
  • FIG. 2 is a cross-sectional structure diagram taken along a line 2-2 in FIG. 1.
  • FIG. 3 is an impurity concentration profile along a line 3-3 in FIG. 2.
  • a reference symbol 101 denotes a first conductivity type semiconductor substrate.
  • a reference symbol 103 denotes a first conductivity type first semiconductor region.
  • a reference symbol 102 denotes a second conductivity type second semiconductor region.
  • the first semiconductor region 103 and the second semiconductor region 102 constitute a PN junction, and constitute a photodiode functioning as a photoelectric converting portion.
  • a reference symbol 105 denotes a first conductivity type third semiconductor region.
  • the third semiconductor region 105 functions as the source region, the drain region, or the FD region of any of the MOS transistors constituting the above-mentioned pixel.
  • a reference symbol 104 denotes an element isolation region made of an insulator.
  • the element isolation region 104 isolates the first semiconductor region 103 and the third semiconductor region 105 from each other.
  • the active region in which a device is formed in the semiconductor substrate is defined.
  • a reference symbol 106 denotes a second conductivity type fourth semiconductor region.
  • the fourth semiconductor region 106 is arranged under the element isolation region 104 between the first semiconductor region 103 and the third semiconductor region 105, and functions as an element isolation structure together with the element isolation region 104. Moreover, the fourth semiconductor region 106 also has the function of suppressing the dark current generated in the neighborhood of the element isolation region 104. Moreover, the impurity concentration of the fourth semiconductor region 106 is higher than that of the second semiconductor region 102.
  • a reference symbol 107 denotes a second conductivity type fifth semiconductor region.
  • the fifth semiconductor region 107 is arranged under the third semiconductor region 105, and the impurity concentration of the fifth semiconductor region 107 is higher than that of the second semiconductor region 102 Furthermore, the fifth semiconductor region 107 is configured so that the impurity concentration thereof may decrease toward the surface direction of the pixel.
  • the fifth semiconductor region 107 includes a plurality of semiconductor regions, each arranged in a different depth from the others' here. As long as at least the impurity concentration of the semiconductor region arranged at the shallowest portion is lower than that of the semiconductor region arranged at the deepest portion, the effects of the present invention can be obtained.
  • a reference symbol 108 denotes a second conductivity type sixth semiconductor region arranged in the first semiconductor region 103.
  • the sixth semiconductor region 108 is the region for making the photoelectric converting portion a buried-type photodiode.
  • a reference symbol 109 denotes a wiring layer, and the wiring layer 109 functions as the gate electrodes of the MOS transistors constituting the above-mentioned pixel.
  • the fifth semiconductor region 107 has the following features.
  • the fifth semiconductor region 107 extends to the neighborhood of the first conductivity type semiconductor substrate 101 or contacts with the semiconductor substrate 101. (2) The fifth semiconductor region 107 is arranged under the third semiconductor region 105.
  • the impurity concentration of the fifth semiconductor region 107 is higher than that of the second semiconductor region 102.
  • the arrangement of a potential barrier between adjacent first semiconductor regions 103 enables the suppression of the effluences of the signal charges existing in the second semiconductor region 102 into an adjacent second semiconductor region 102. That is, as illustrated by a path 1 in FIG. 2, the fifth semiconductor region 107 functions as the potential barrier to the signal charges. In this way, the escaping of signal charges into adjacent pixels through paths 2, which escaping have much existed conventionally, is suppressed, and thereby blooming and color mixing can be suppressed. Thereby the sensitivity of the pixel can be improved.
  • the signal charges escaping into an adjacent pixel through the path 2 in FIG. 2 can be led to a path 3, and the escapes of the signal charges through the path 2 can be hereby suppressed as a result.
  • the letter L denotes the width of the fifth semiconductor region 107 here.
  • the width means the length of a straight line in the direction parallel to the straight line connecting two adjacent first semiconductor regions 103.
  • the width indicates the width of the potential barrier between the adjacent first semiconductor regions 103, and is the length of about 1 to 3 ⁇ m, although the length depends on a pixel pitch.
  • the letter x denotes the length in the width direction of the fifth semiconductor region 107, and the symbol N (x) indicates the difference between the impurity concentration at a point x in the fifth semiconductor region 107 and the impurity concentration of the second semiconductor region 102.
  • the point x is supposed here to be zero at the boundary of the fifth semiconductor region 107 with the pixel.
  • FIG. 7 illustrates a relation between the ratios of the impurity concentrations of the fifth semiconductor region 107 to the impurity concentrations of the second semiconductor region 102 and the cross talk ratios to adjacent pixels.
  • the cross talk ratios become smaller almost in proportion to the heights of the concentrations of the fifth semiconductor region 107. That is, the amounts of the escapes of the signal charges decrease.
  • the fifth semiconductor region 107 is wider in width than that of the fourth semiconductor region 106, and higher in impurity concentration than that of the fourth semiconductor region 106.
  • the effects mentioned above can be sufficiently obtained.
  • the escapes of the signal charges to the adjacent pixels are prevented, and thereby the amount of the signal charges that behave the passing of the path 1 can be more increased, and the color mixing suppression and the sensitivity improvement can be achieved.
  • the suppression ratio is tried to be improved by heightening the impurity concentration at a shallow portion in the fifth semiconductor region 107, the following side effect is sometimes produced.
  • the part of the fifth semiconductor region 107 closest to the principal plane of the semiconductor substrate 101 and the third semiconductor region 105 are close to each other.
  • the third semiconductor region 105 is used for the source regions and the drain regions of the MOS transistors constituting the pixel as mentioned above. Consequently, if the impurity concentration of the fifth semiconductor region 107 is made to be higher on the whole, then a shallow portion of the fifth semiconductor region 107 and the third semiconductor region 105 close to the shallow portion form a PN junction.
  • the PN junction sometimes exerts undesirable influences on the characteristics of the MOS transistors. Moreover, the phenomenon in which the PN junction suppresses the expansion of the depletion layer extending from the first semiconductor region 103 constituting the photodiode can happen.
  • the impurity concentration of the region of the fifth semiconductor region 107 close to the principal plane of the semiconductor substrate 101 is decreased.
  • the signal charges escaping through the path 2 in FIG. 2 are suppressed, and the signal charges behaving to pass through the path 3 can be increased. That is, it is desirable to form the fifth semiconductor region 107 as a multi-layer structure in which layers are stacked at different depths so that their impurity concentrations may become gradually higher from the principal plane side of the semiconductor substrate 101 toward the semiconductor substrate 101. For example, as illustrated in FIG.
  • the fifth semiconductor region 107 may be in the form of stacking a plurality of semiconductor regions 107-1, 107-2, 107-3, and 107-4 from the principal surface of the semiconductor substrate 101 so that the impurity concentration of each region may become gradually higher.
  • the fifth semiconductor region 107 is desirably arranged under the third semiconductor region 105 so as to discharge escaping signal charges to the adjacent pixels without making them escape.
  • the structure of the feature (2) is effective therefor.
  • the second semiconductor region 102 may be configured of a plurality of semiconductor regions the impurity concentrations of which are difference from one another (the impurity concentration peaks of which have different values from one another) .
  • the impurity concentration of the fifth semiconductor region 107 cannot be made to be higher so much, then the following configuration can be adopted. That is, a low impurity concentration portion is formed in the second semiconductor region 102 so that the difference of the impurity concentrations of both the adjacent second semiconductor region 102 and the fifth semiconductor region 107 may be larger.
  • the difference of the concentrations of both of them can be controlled to raise the suppression effect.
  • the extension of the deepest portion of the fifth semiconductor region 107 to the portion deeper than the deepest portion of the second semiconductor region 102 enables the effect mentioned above to be surer.
  • the conductivity type of the first conductivity type may be set to the N type, and the conductivity type of the second conductivity type may be set to the P type. If the signal charge is supposed to be the hole, then the first conductivity type may be set to the P type, and the second conductivity type may be set to the N type.
  • the structure can suppress color mixing and blooming effectively even in a pixel the pixel pitch of which is small.
  • the structure enables the suppression of the color mixing and the blooming without suppressing the extension of the depletion layer extending from the first semiconductor region 103 constituting a photodiode.
  • FIG. 6 is a cross-sectional structure diagram of pixels corresponding to FIG. 5 here.
  • the present embodiment is suitable to a pixel having a small pixel pitch similarly to the second embodiment.
  • a part of the fifth semiconductor region 107 is situated at a position distant from the first semiconductor region 103 constituting a photodiode and the third semiconductor region 105 functioning as the source and drain regions of MOS transistors.
  • the width of the fifth semiconductor region 107 of the present embodiment becomes narrower.
  • the fifth semiconductor region 107 is arranged so as not to overlap with the fourth semiconductor region 106 in the width direction.
  • the degree of the suppression of the escapes of the signal charges into the adjacent pixels is in proportion to the formula (1) , the impurity concentration is made to be higher in proportion to the width.
  • the structure enables the realization of the solid-state imaging apparatus having smaller pixels with keeping the same color mixing and blooming suppressing effect as that of the first embodiment. (Application to Camera Main Body)
  • FIG. 8 is an example of a circuit block diagram illustrating the case of applying the solid-state imaging apparatus of the present invention to a camera.
  • a shutter 1001 is situated in front of a taking lens 1002, which is an optical member, and the shutter 1001 controls an exposure.
  • a diaphragm 1003 controls a light quantity as the occasion demands, and an object image is focused on the light receiving surface of the solid-state imaging apparatus 1004.
  • the signal output from the solid-state imaging apparatus 1004 is processed by an imaging signal processing circuit 1005, and is converted from an A/D converter 1006 from an analog signal into a digital signal.
  • the output digital signal is further subjected to an arithmetic operation processing by a signal processing unit 1007.
  • the processed digital signal is accumulated in a memory unit 1010, and is transmitted to external equipment through an external I/F unit 1013.
  • the solid- state imaging apparatus 1004, the imaging signal processing circuit 1005, the A/D converter 1006, and the signal processing unit 1007 are severally controlled by a timing generator 1008, and the whole system is controlled by a whole control and arithmetic' operation unit 1009.
  • a timing generator 1008 In order to record an image in a recording medium 1012, an output digital signal is recorded through an I/F unit 1011 controlling a recording medium, which I/F unit 1011 is controlled by the whole control and arithmetic operation unit 1009.
  • the optimum P type element isolation diffusion layer structure is provided according to the depth and concentration of a P type well, and blooming and color mixing can be suppressed even if the sensitivity of a photodiode is improved.
  • any of the embodiments mentioned above is only an example of the concretization at the time of implementing the present invention, and the scope of the present invention must not be interpreted to be limited by these embodiments. That is, the present invention can be implemented in various forms without departing from the scope and the principal features thereof,

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Abstract

A solid-state imaging apparatus capable of suppressing blooming and color mixing includes a plurality of pixels, each including a photoelectric converting portion and a transferring portion for transferring signal electrons from the photoelectric converting portion, wherein a plurality of the photoelectric converting portions is formed in a first conductivity type well region formed on the semiconductor substrate; a second conductivity type first impurity region is arranged between the adjacent photoelectric converting portions; a first conductivity type second impurity region having an impurity concentration higher than that of the well region is arranged between the first impurity region and each of the photoelectric converting portions; and a first conductivity type third impurity region having an impurity concentration higher than that of the well region and decreasing from the semiconductor substrate toward the surface direction of the apparatus between the semiconductor substrate and the first impurity region.

Description

DESCRIPTION
SOLID-STATE IMAGE SENSOR WITH REDUCED BLOOMING AND COLOUR MIXING
TECHNICAL FIELD
The present invention relates to a solid-state imaging apparatus converting an image into an electric signal. In particular, the present invention relates an active pixel sensor (hereinafter referred to as λΛAPS") , including an amplifier in each pixel or in every plurality of pixels.
BACKGROUND ART
A solid-state imaging apparatus of an APS structure is also called as a CMOS sensor, and is widely used for digital cameras and the like.
A conventional solid-state imaging apparatus has the problem of the following phenomena. To put it concretely, the phenomena are a blooming phenomenon, in which signal charges escape into an adjacent photoelectric converting portion, the color mixing, in which color reproducibility worsens by the blooming phenomenon, and the like. The generating mechanisms of these phenomena are severally as follows: the signal charges accumulated in a semiconductor region constituting a photoelectric converting portion for accumulating signal charges (N type semiconductor region in the case where the signal charges are electrons) become a saturation state, and overflowing signal charges go over an element isolation region to arrive at an adjacent pixel. In order to settle the problem mentioned above, Japanese Patent Application Laid-Open No. 2004-266159 (hereinafter referred to as Patent Document 1) discloses the configuration in which a deep isolation injection layer is formed under the element isolation region. The Patent Document 1 describes the configuration of obstructing the effluences of signal charges from a photodiode.
Moreover, Japanese Patent Application Laid-Open No. 2005-229105 (hereinafter referred to as Patent Document 2) discloses the following configuration. That is, an overflow path region is formed under an element isolation insulation film, and the overflow path region is made to have a piece of potential lower than that of a P type well region constituting a photodiode. Thus, the photodiode overflows with signal charges, which are discharged to an N type silicon substrate, to suppress the blooming.
Moreover, in addition, also Japanese Patent Application Laid-Open No. 2006-024907 (hereinafter referred to as Patent Document 3) describes an element isolation structure suppressing the escaping of signal charges. However, in the case of forming the diffusion layer for element isolation as the one disclosed in the Patent Document 1 mentioned above, since the element isolation diffusion layer having a sufficient width cannot obtained as the miniaturization of a pixel progresses, sufficient color mixing and blooming suppressing effects cannot be obtained sometimes.
Moreover, if the overflow path region disclosed in the Patent Document 2 mentioned above is formed, the signal charges generated by a photoelectric conversion at a deep part of a well are sometimes discharged when the P well constituting the photodiode is deeply formed, and the sensitivity of the photodiode does not sometimes become high. Moreover, also by the element isolation structure disclosed in the Patent Document 3, the signal charge collecting efficiency cannot be said yet to be sufficient, and there is room for further examination.
DISCLOSURE OF THE INVENTION
The present invention is based on the concept of providing the optimum element isolation structure according to the depth and concentration of a P type well constituting a photodiode. The present invention is directed to provide a solid-state imaging apparatus capable of suppressing blooming and color mixing even if the sensitivity of the photoelectric converting portion of a photodiode or the like is improved.
An object of the present invention is to provide a solid-state imaging apparatus comprising a plurality of pixels, each pixel including a photoelectric converting portion for converting an incident light into signal charges and a transferring portion for transferring the signal charge from the photoelectric converting portion, wherein the photoelectric converting portion and the transferring portion are arranged at least on a semiconductor substrate, the photoelectric converting portion includes a first semiconductor region of a first conductivity type for accumulating the signal charge and a second semiconductor region of a second conductivity type forming PN junction with the first semiconductor region, a third semiconductor region of the first conductivity type is arranged between adjacent first semiconductor regions, a fourth semiconductor region of the second conductivity type and of an impurity concentration higher than that of the second semiconductor region is arranged between the first and third semiconductor regions, and a fifth semiconductor region of the second conductivity type, and of an impurity concentration higher than that of the second semiconductor region, to form an impurity concentration profile such that the impurity concentration gradually decreases toward a surface direction is arranged under the third semiconductor region.
The other features and advantages of the present invention will be apparent from the following description taken in conjunction with the accompanying drawings, in which like reference characters designate the same or similar parts throughout the figures thereof.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a planar layout view of pixels in a first embodiment.
FIG. 2 is a cross-sectional structure diagram of the first embodiment taken along a line 2-2 in FIG. 1.
FIG. 3 is a concentration profile of a P type well and a second P type element isolation diffusion layer of the first embodiment.
FIG. 4 is a cross-sectional structure diagram of pixels in a second embodiment.
FIG. 5 is a planar layout view of pixels in a third embodiment.
FIG. 6 is a cross-sectional structure diagram of the third embodiment taken along a line 6-6 of FIG. 5.
FIG. 7 is a graph illustrating impurity concentration heights and electron suppressing ratios of the second P type element isolation diffusion layer to the impurity concentrations of a P type well.
FIG. 8 is an example of a block diagram in the case of applying a solid-state imaging apparatus according to the present invention to a camera.
FIG. 9 is an example of an equivalent circuit diagram of a pixel applicable to the present invention. The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
BEST MODE FOR CARRYING OUT THE INVENTION
In the following, the exemplary embodiments of the solid-state imaging apparatus of the present invention will be described in detail with reference to the accompanying drawings.
A first embodiment of the present invention is described. The semiconductor substrate in the following description indicates a part to be a base on which each semiconductor region is formed, and a device is formed on the surface part of the semiconductor substrate. To put it concretely, the semiconductor substrate is denoted by a reference numeral 101 in FIG. 2. Moreover, it is supposed that the whole configuration including the semiconductor substrate 101 and a principal plane on which the device is formed is called as the semiconductor substrate. To put it concretely, the whole configuration including the portions denoted by reference numerals 101-108 in FIG. 2 is supposed to be called as the semiconductor substrate.
Furthermore, it is supposed that the principal plane on which the device of the semiconductor substrate 101 is formed is taken as the criterion of the depth of each semiconductor region in the semiconductor substrate when the depth is described, and it is supposed that the depth becomes deeper when a position becomes distant from the principal plane. Moreover, when a position is defined by the upper and lower sides, a position closer to the principal plane on which the device of the semiconductor substrate 101 is formed is defined as the upper side.
First, FIG. 9 illustrates an example of an equivalent circuit diagram of pixels applicable to the present invention. In FIG. 9, each pixel is denoted by a reference numeral 1410.
The pixel 1410 includes a photodiode 1400, which functions as a photoelectric converting portion, a transfer transistor 1401, a reset transistor 1402, an amplifying transistor 1403, and a selection transistor 1404. The pixel further includes a power source line Vcc and an output line 1406.
The anode of the photodiode 1400 is connected to the grounding wire, and the cathode of the photodiode 1400 is connected to the source of the transfer transistor 1401. Moreover, the source of the transfer transistor 1401 may be configured in the semiconductor region shared by the cathode of the photodiode.
The drain of the transfer transistor 1401 is connected to the floating diffusion (hereinafter referred to as FD) region, and the gate of the transfer transistor 1401 is connected to a transfer control line, Furthermore, the drain of the reset transistor 1402 is connected to the power source line Vcc, and the source of the reset transistor 1402 is connected to the FD region. The gate of the reset transistor 1402 is connected to a reset control line. The drain of the transfer transistor 1401 and the FD region, or the drain of the reset transistor 1402 and the FD region may be configured in a common semiconductor region. The drain of the amplifying transistor 1403 is connected to the power source line Vcc, and the source of the amplifying transistor 1403 is connected to the drain of the selection transistor 1404. The gate of the amplifying transistor 1403 is connected to the FD region. The drain of the selection transistor 1404 is connected to the source of the amplifying transistor 1403, and the source of the selection transistor 1404 is connected to the output line 1406. The gate of the selection transistor 1404 is connected to a vertical selection line driven by a vertical selection circuit (not illustrated) .
Next the operation of the equivalent circuit is described. In the photodiode 1400, pairs of electrons and holes are generated by an incident light. An electric charge, one of each of these pairs, is used to as a signal charge to be transferred by the transfer transistor 1401 to the FD region. The gate potential of the amplifying transistor 1403 changes according to the transferred signal charge quantity. The amplifying transistor 1403 outputs an amplified signal to output line 1406 by the source follower circuit, which the amplifying transistor 1403 constitutes with a not- illustrated constant current source, on the basis of the potential change of the gate of the amplifying transistor 1403. The selection transistor 1404 controls the output from each pixel. The circuit configuration illustrated here can be applied to all of the embodiments of the present invention. Furthermore, the following modifications can be considered. For example, the above circuit configuration can be applied to the configuration of lacking the transfer transistor 1401 with the photodiode 1400 connected to the gate of the amplifying transistor 1403 directly and the circuit configuration of sharing the amplifying transistor 1403 with a plurality of pixels. Moreover, also the configuration of being not provided with the selection transistor 1404 but performing the selection of a pixel by controlling the gate potential of the amplifying transistor 1403 may be adopted.
Next, the planar structures and the cross- sectional structures of pixels will be described with reference to FIGS. 1-3. FIG. 1 is a planar layout view of the pixels. FIG. 2 is a cross-sectional structure diagram taken along a line 2-2 in FIG. 1. FIG. 3 is an impurity concentration profile along a line 3-3 in FIG. 2.
A reference symbol 101 denotes a first conductivity type semiconductor substrate. A reference symbol 103 denotes a first conductivity type first semiconductor region. A reference symbol 102 denotes a second conductivity type second semiconductor region. The first semiconductor region 103 and the second semiconductor region 102 constitute a PN junction, and constitute a photodiode functioning as a photoelectric converting portion.
A reference symbol 105 denotes a first conductivity type third semiconductor region. The third semiconductor region 105 functions as the source region, the drain region, or the FD region of any of the MOS transistors constituting the above-mentioned pixel.
A reference symbol 104 denotes an element isolation region made of an insulator. The element isolation region 104 isolates the first semiconductor region 103 and the third semiconductor region 105 from each other. By the element isolation region 104, the active region in which a device is formed in the semiconductor substrate is defined.
A reference symbol 106 denotes a second conductivity type fourth semiconductor region. The fourth semiconductor region 106 is arranged under the element isolation region 104 between the first semiconductor region 103 and the third semiconductor region 105, and functions as an element isolation structure together with the element isolation region 104. Moreover, the fourth semiconductor region 106 also has the function of suppressing the dark current generated in the neighborhood of the element isolation region 104. Moreover, the impurity concentration of the fourth semiconductor region 106 is higher than that of the second semiconductor region 102.
A reference symbol 107 denotes a second conductivity type fifth semiconductor region. The fifth semiconductor region 107 is arranged under the third semiconductor region 105, and the impurity concentration of the fifth semiconductor region 107 is higher than that of the second semiconductor region 102 Furthermore, the fifth semiconductor region 107 is configured so that the impurity concentration thereof may decrease toward the surface direction of the pixel. The fifth semiconductor region 107 includes a plurality of semiconductor regions, each arranged in a different depth from the others' here. As long as at least the impurity concentration of the semiconductor region arranged at the shallowest portion is lower than that of the semiconductor region arranged at the deepest portion, the effects of the present invention can be obtained.
A reference symbol 108 denotes a second conductivity type sixth semiconductor region arranged in the first semiconductor region 103. The sixth semiconductor region 108 is the region for making the photoelectric converting portion a buried-type photodiode.
A reference symbol 109 denotes a wiring layer, and the wiring layer 109 functions as the gate electrodes of the MOS transistors constituting the above-mentioned pixel.
In the following, the structure and the function of the fifth semiconductor region 107, which is the feature of the present embodiment, will be minutely described. The fifth semiconductor region 107 has the following features.
(1) The fifth semiconductor region 107 extends to the neighborhood of the first conductivity type semiconductor substrate 101 or contacts with the semiconductor substrate 101. (2) The fifth semiconductor region 107 is arranged under the third semiconductor region 105.
(3) The impurity concentration of the fifth semiconductor region 107 is higher than that of the second semiconductor region 102.
(4) The closer to a principal plane of the semiconductor substrate 101 a position is, the lower the impurity concentration of the fifth semiconductor region 107 becomes. That is, the impurity concentration of the fifth semiconductor region 107 becomes the highest at the deepest portion.
According to the features (1) and (3) , the arrangement of a potential barrier between adjacent first semiconductor regions 103 enables the suppression of the effluences of the signal charges existing in the second semiconductor region 102 into an adjacent second semiconductor region 102. That is, as illustrated by a path 1 in FIG. 2, the fifth semiconductor region 107 functions as the potential barrier to the signal charges. In this way, the escaping of signal charges into adjacent pixels through paths 2, which escaping have much existed conventionally, is suppressed, and thereby blooming and color mixing can be suppressed. Thereby the sensitivity of the pixel can be improved.
According to the features (2) and (4), the signal charges escaping into an adjacent pixel through the path 2 in FIG. 2 can be led to a path 3, and the escapes of the signal charges through the path 2 can be hereby suppressed as a result.
In the following, the features mentioned above will be further minutely described.
As the result of the examination of the inventors of the present invention, it was found that the suppression ratio of the signal charges flowing into adjacent pixels were in proportion to the following formula (1) .
J^ x x N (x)ώc (1)
The letter L denotes the width of the fifth semiconductor region 107 here. The width means the length of a straight line in the direction parallel to the straight line connecting two adjacent first semiconductor regions 103. The width indicates the width of the potential barrier between the adjacent first semiconductor regions 103, and is the length of about 1 to 3 μm, although the length depends on a pixel pitch. Moreover, the letter x denotes the length in the width direction of the fifth semiconductor region 107, and the symbol N (x) indicates the difference between the impurity concentration at a point x in the fifth semiconductor region 107 and the impurity concentration of the second semiconductor region 102. The point x is supposed here to be zero at the boundary of the fifth semiconductor region 107 with the pixel.
As the feature (3) mentioned above, it is known from the formula (1) that the more the impurity concentration of the fifth semiconductor region 107 becomes larger than that of the second semiconductor region 102, the more the possibility of the suppression of the escapes of the signal charges into the adjacent pixels becomes larger. A concrete example pertaining to the above is illustrated in FIG. 7. FIG. 7 illustrates a relation between the ratios of the impurity concentrations of the fifth semiconductor region 107 to the impurity concentrations of the second semiconductor region 102 and the cross talk ratios to adjacent pixels. As known from FIG. 7, the cross talk ratios become smaller almost in proportion to the heights of the concentrations of the fifth semiconductor region 107. That is, the amounts of the escapes of the signal charges decrease. Then it is desirable that the fifth semiconductor region 107 is wider in width than that of the fourth semiconductor region 106, and higher in impurity concentration than that of the fourth semiconductor region 106. Hereby, the effects mentioned above can be sufficiently obtained. As described above, according to the features (1) and (3) , the escapes of the signal charges to the adjacent pixels are prevented, and thereby the amount of the signal charges that behave the passing of the path 1 can be more increased, and the color mixing suppression and the sensitivity improvement can be achieved.
If the suppression ratio is tried to be improved by heightening the impurity concentration at a shallow portion in the fifth semiconductor region 107, the following side effect is sometimes produced. In FIG. 2, the part of the fifth semiconductor region 107 closest to the principal plane of the semiconductor substrate 101 and the third semiconductor region 105 are close to each other. The third semiconductor region 105 is used for the source regions and the drain regions of the MOS transistors constituting the pixel as mentioned above. Consequently, if the impurity concentration of the fifth semiconductor region 107 is made to be higher on the whole, then a shallow portion of the fifth semiconductor region 107 and the third semiconductor region 105 close to the shallow portion form a PN junction. Hereby a high concentration PN junction is formed, and the PN junction sometimes exerts undesirable influences on the characteristics of the MOS transistors. Moreover, the phenomenon in which the PN junction suppresses the expansion of the depletion layer extending from the first semiconductor region 103 constituting the photodiode can happen.
On the other hand, as illustrated in FIG. 3, the impurity concentration of the region of the fifth semiconductor region 107 close to the principal plane of the semiconductor substrate 101 is decreased. Hereby, the signal charges escaping through the path 2 in FIG. 2 are suppressed, and the signal charges behaving to pass through the path 3 can be increased. That is, it is desirable to form the fifth semiconductor region 107 as a multi-layer structure in which layers are stacked at different depths so that their impurity concentrations may become gradually higher from the principal plane side of the semiconductor substrate 101 toward the semiconductor substrate 101. For example, as illustrated in FIG. 2, the fifth semiconductor region 107 may be in the form of stacking a plurality of semiconductor regions 107-1, 107-2, 107-3, and 107-4 from the principal surface of the semiconductor substrate 101 so that the impurity concentration of each region may become gradually higher. Hereby, furthermore, blooming and color mixing can be suppressed. In order to maximize the effect of the feature (4), the fifth semiconductor region 107 is desirably arranged under the third semiconductor region 105 so as to discharge escaping signal charges to the adjacent pixels without making them escape. The structure of the feature (2) is effective therefor.
Moreover, as illustrated in FIG. 3, the second semiconductor region 102 may be configured of a plurality of semiconductor regions the impurity concentrations of which are difference from one another (the impurity concentration peaks of which have different values from one another) . For example, if the impurity concentration of the fifth semiconductor region 107 cannot be made to be higher so much, then the following configuration can be adopted. That is, a low impurity concentration portion is formed in the second semiconductor region 102 so that the difference of the impurity concentrations of both the adjacent second semiconductor region 102 and the fifth semiconductor region 107 may be larger. By such a configuration, the difference of the concentrations of both of them can be controlled to raise the suppression effect.
Moreover, the extension of the deepest portion of the fifth semiconductor region 107 to the portion deeper than the deepest portion of the second semiconductor region 102 enables the effect mentioned above to be surer.
Incidentally, if the signal charge is supposed to be the electron, then the conductivity type of the first conductivity type may be set to the N type, and the conductivity type of the second conductivity type may be set to the P type. If the signal charge is supposed to be the hole, then the first conductivity type may be set to the P type, and the second conductivity type may be set to the N type.
Next, as a second embodiment of the solid-state imaging apparatus of the present invention, the apparatus having the structure illustrated in FIG. 4 will be described. The structure can suppress color mixing and blooming effectively even in a pixel the pixel pitch of which is small. In the structure of FIG. 4, the deeper a position of the fifth semiconductor region 107 from the principal plane of the semiconductor substrate 101 becomes, the wider the width of the layer becomes. The structure enables the suppression of the color mixing and the blooming without suppressing the extension of the depletion layer extending from the first semiconductor region 103 constituting a photodiode.
Next, the apparatus including a structure illustrated in FIGS. 5 and 6 will be described as a third embodiment of the solid-state imaging apparatus of the present invention. FIG. 6 is a cross-sectional structure diagram of pixels corresponding to FIG. 5 here.
Also the present embodiment is suitable to a pixel having a small pixel pitch similarly to the second embodiment. As illustrated in FIG. 5, a part of the fifth semiconductor region 107 is situated at a position distant from the first semiconductor region 103 constituting a photodiode and the third semiconductor region 105 functioning as the source and drain regions of MOS transistors. In comparison with the width of the fifth semiconductor region 107 of first embodiment, the width of the fifth semiconductor region 107 of the present embodiment becomes narrower. In the present embodiment, the fifth semiconductor region 107 is arranged so as not to overlap with the fourth semiconductor region 106 in the width direction. The degree of the suppression of the escapes of the signal charges into the adjacent pixels is in proportion to the formula (1) , the impurity concentration is made to be higher in proportion to the width. The structure enables the realization of the solid-state imaging apparatus having smaller pixels with keeping the same color mixing and blooming suppressing effect as that of the first embodiment. (Application to Camera Main Body)
FIG. 8 is an example of a circuit block diagram illustrating the case of applying the solid-state imaging apparatus of the present invention to a camera.
A shutter 1001 is situated in front of a taking lens 1002, which is an optical member, and the shutter 1001 controls an exposure. Next, a diaphragm 1003 controls a light quantity as the occasion demands, and an object image is focused on the light receiving surface of the solid-state imaging apparatus 1004. The signal output from the solid-state imaging apparatus 1004 is processed by an imaging signal processing circuit 1005, and is converted from an A/D converter 1006 from an analog signal into a digital signal. The output digital signal is further subjected to an arithmetic operation processing by a signal processing unit 1007. The processed digital signal is accumulated in a memory unit 1010, and is transmitted to external equipment through an external I/F unit 1013. The solid- state imaging apparatus 1004, the imaging signal processing circuit 1005, the A/D converter 1006, and the signal processing unit 1007 are severally controlled by a timing generator 1008, and the whole system is controlled by a whole control and arithmetic' operation unit 1009. In order to record an image in a recording medium 1012, an output digital signal is recorded through an I/F unit 1011 controlling a recording medium, which I/F unit 1011 is controlled by the whole control and arithmetic operation unit 1009. According to the present invention, in a solid- state imaging apparatus having an APS structure, the optimum P type element isolation diffusion layer structure is provided according to the depth and concentration of a P type well, and blooming and color mixing can be suppressed even if the sensitivity of a photodiode is improved.
Incidentally, any of the embodiments mentioned above is only an example of the concretization at the time of implementing the present invention, and the scope of the present invention must not be interpreted to be limited by these embodiments. That is, the present invention can be implemented in various forms without departing from the scope and the principal features thereof,
This application claims the benefit of Japanese Patent Application No. 2008-094999, filed April 1, 2008, which is hereby incorporated by reference herein in its entirety.

Claims

1. A solid-state imaging apparatus comprising: a plurality of pixels, each including a photoelectric converting portion for converting an incident light into signal charges and a transferring portion for transferring the signal charges from the photoelectric converting portion, wherein the photoelectric converting portion and the transferring portion are arranged at least on a semiconductor substrate, the photoelectric converting portion includes a first semiconductor region of a first conductivity type for accumulating the signal charges and a second semiconductor region of a second conductivity type forming PN junction with the first semiconductor region, a third semiconductor region of the first conductivity type is arranged between adjacent first semiconductor regions, a fourth semiconductor region of the second conductivity type and of an impurity concentration higher than that of the second semiconductor region is arranged between the first and third semiconductor regions, and a fifth semiconductor region of the second conductivity type, and of an impurity concentration higher than that of the second semiconductor region, to form an impurity concentration profile such that the impurity concentration gradually decreases toward a surface direction is arranged under the third semiconductor region.
2. The solid-state imaging apparatus according to claim 1, wherein the fifth semiconductor region comprises a plurality of impurity regions stacked in a direction vertical to a surface of the semiconductor substrate.
3. The solid-state imaging apparatus according to claim 1, wherein the third semiconductor region has a width in a direction of a depth larger than that of the fourth semiconductor region, and has an impurity concentration higher than that of the fourth semiconductor region.
4. The solid-state imaging apparatus according to claim 2, wherein the photoelectric converting portion comprises a plurality of impurity regions stacked in a direction vertical to a surface of the semiconductor substrate so as to form a plurality of impurity concentration peaks, and so as to make larger an impurity concentration difference between the third semiconductor region and the second semiconductor region.
5. The solid-state imaging apparatus according to claim 1, wherein the fifth semiconductor region has a width gradually increasing as a depth increases.
6. The solid-state imaging apparatus according to claim 1, wherein the fifth semiconductor region is arranged so as not to overlapped with the fourth semiconductor region in a width direction.
7. The solid-state imaging apparatus according to claim 1, each pixel comprising further comprising an amplification transistor for amplifying the signal according to said signal charges generated in the photoelectric converting portion, wherein the third semiconductor region forms a drain region of the amplification transistor.
8. The solid-state imaging apparatus according to claim 7, wherein the amplification transistor has an input terminal to which a floating diffusion region is connected, and the fourth and fifth semiconductor regions are arranged so as to surround the photoelectric converting portion and the floating diffusion region.
9. The solid-state imaging apparatus according to claim 1, wherein the fifth semiconductor region is arranged deeper than the deepest portion of the second semiconductor region.
10. A camera comprising: a solid-state imaging apparatus according to claim 1; a signal processing circuit for processing a signal output from the solid-state imaging apparatus; and an optical member for focusing an image of an object onto a light receiving surface of the solid- state imaging apparatus .
PCT/JP2009/056763 2008-04-01 2009-03-25 Solid-state image sensor with reduced blooming and colour mixing WO2009123244A1 (en)

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KR20100126543A (en) 2010-12-01
US8670056B2 (en) 2014-03-11
US20110169989A1 (en) 2011-07-14
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KR101206589B1 (en) 2012-11-29
RU2444150C1 (en) 2012-02-27

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