WO2009095229A2 - Verfahren und vorrichtung zur herstellung von blockschaumstoff - Google Patents

Verfahren und vorrichtung zur herstellung von blockschaumstoff Download PDF

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Publication number
WO2009095229A2
WO2009095229A2 PCT/EP2009/000554 EP2009000554W WO2009095229A2 WO 2009095229 A2 WO2009095229 A2 WO 2009095229A2 EP 2009000554 W EP2009000554 W EP 2009000554W WO 2009095229 A2 WO2009095229 A2 WO 2009095229A2
Authority
WO
WIPO (PCT)
Prior art keywords
container
base body
bulge
vertices
corner points
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2009/000554
Other languages
German (de)
English (en)
French (fr)
Other versions
WO2009095229A3 (de
Inventor
Klaus-Werner Huland
Sascha Fahlenkamp
Joachim Tyfker
Erwin Otto
Roger Scholz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Priority to US12/865,019 priority Critical patent/US20140077407A1/en
Priority to EP09705426A priority patent/EP2247423A2/de
Priority to JP2010544631A priority patent/JP2011510841A/ja
Priority to CN2009801036879A priority patent/CN101932419A/zh
Publication of WO2009095229A2 publication Critical patent/WO2009095229A2/de
Publication of WO2009095229A3 publication Critical patent/WO2009095229A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/025Foaming in open moulds, followed by closing the moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/42Moulds or cores; Details thereof or accessories therefor characterised by the shape of the moulding surface, e.g. ribs or grooves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/36Feeding the material to be shaped
    • B29C44/38Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/58Moulds
    • B29C44/586Moulds with a cavity increasing in size during foaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/44Moulds or cores; Details thereof or accessories therefor with means for, or specially constructed to facilitate, the removal of articles, e.g. of undercut articles

Definitions

  • the present invention relates to a method and an apparatus for producing slabstock foam, wherein on the bottom of a molding box, a container open on its underside is applied, the container is filled with foamable reaction mixture and is then removed.
  • reaction mixture is usually applied to the bottom of a container.
  • the reaction mixture foams, expands and occupies the space available through the container.
  • the container is often referred to as Schwarzumkiste and the process as "discontinuous box foaming".
  • reaction mixture is prepared in a mixing head immediately prior to the preparation of the block foam and applied to the bottom of the container, so passes a certain period of time between the beginning and the end of the application. During this time, however, the reaction mixture already flows over the bottom of the container and reacts with foaming. As a result, there are zones of different ages and different reaction progress in the finished product.
  • this variation of the properties for example the variation of the foam density, is disadvantageous for the further processing of the obtained block foam.
  • DE 29 01 177 A1 discloses a device for the discontinuous production of block foam, wherein a mixing device provided with component leads, a mixer having a stirrer is arranged in a bridge-like frame which, as a mixing container, is arranged on a top plate and can be positioned on the bottom thereof
  • Formbox has attachable, bottomless cylinder jacket.
  • serving as a mixing chamber bottomless cylinder jacket is lowered prior to introduction of the reaction components to the bottom of the mold box.
  • the mixing device is raised again with the bottomless cylinder jacket. The mixed reaction components then flow over the bottom of the mold box.
  • US 2,649,620 discloses a method of producing slabstock foam comprising placing a continuous, rigid and upright side boundary on the bottom of a mold box to define a relatively small area thereof and thus to form a disassemblable mixing vessel. Again, this mixing vessel thus formed is filled with reaction mixture and then removed upwards. Overall, the mixing container has a cylindrical shape.
  • the reaction mixture spreads after lifting the container radially on the bottom of the mold box.
  • the mixing box is placed in the middle of the molding box floor. If the molding box itself does not have a circular cross section, but rather the rectangular cross section customary in production, then the wavefront of the reaction mixture first reaches the longitudinal side of the molding box. This is the side with the shortest distance to the center of the ground. Subsequently, the wavefront reaches the transverse sides and finally the corners of the molding box. Upon impact of the wavefront on the sidewalls, the reaction mixture can spread only upwards. This leads to stratification phenomena and to the compression of the marginal material by further internal foaming reaction mixture. Because the wave front of the reaction mixture reaches the walls of the molding box at different times, inhomogeneities ultimately occur in the finished foam body. These are noticeable in particular by density fluctuations.
  • the object of the present invention is therefore to provide such an improved method and device.
  • the object is achieved by a method for the production of block foam, wherein a container open on its underside is applied to the bottom of a molding box, the container is filled with reaction components and then is removed and further wherein the container used whose horizontal cross-sectional contour can be described by providing starting from a basic body comprising at least three vertices in the region of at least one of the vertices -eine bulge.
  • the container used whose horizontal cross-sectional contour can be described by providing starting from a basic body comprising at least three vertices in the region of at least one of the vertices -eine bulge.
  • the shape of the container and in particular the contour of the open bottom can be conveniently described by considering the horizontal cross section of the container. Thus, a description of the container is reduced to a consideration of the contour of this cross section.
  • the contour then indicates the course of the wall of the container.
  • the contour itself may then be described as a combination or fusion of a base body with form elements which constitute a bulge from the interior of the container.
  • the bulge may take the form of a circular arc, the shape of an ellipse cutout or a parabolic shape, for example.
  • the bulge is provided at the vertices of the body. This is to be understood that the bulge is arranged in the region of the vertex and thus the vertex rises in the bulge.
  • the basic body comprises four corner points, neighboring corner points are connected to each other by concave lines and a bulge is provided at each of the four corner points.
  • the main body can be described as a quadrilateral whose sides are not straight but curved toward the inside of the quadrangle. The vertices of this deformed quadrilateral then go into the bulge, so are surrounded by this. The fusion of the outer contours of the deformed quadrangle and the bulge then gives the horizontal cross-sectional contour of the container.
  • the basic body comprises four corner points, adjacent corner points are respectively connected to one another by convex lines and a bulge is provided at each of the four corner points.
  • the main body may be described as a quadrilateral whose sides are not straight but curved from the inside of the quadrilateral. The vertices of this deformed quadrilateral then go into the bulge, so are surrounded by this. The fusion of the outer contours - A - the deformed quadrilateral and the bulge then gives the horizontal cross-sectional contour of the container.
  • the basic body comprises four corner points, neighboring corner points are respectively connected to one another by straight lines and a bulge is provided at each of the four corner points.
  • Body are described as a quadrilateral whose sides are straight. Opposing
  • Pages can be parallel and adjacent sides can be at right angles to each other. Overall, for example, a parallelogram, a rectangle or a square can result. The vertices of this quadrilateral then go into the bulge, so are surrounded by this. The fusion of the outer contours of the quadrangle and the bulge then gives the horizontal cross-sectional contour of the container.
  • the longitudinal side of the base body and the longitudinal side of the bottom of the molding box can furthermore have a length ratio of> 1: 2 to ⁇ 1: 5.
  • the aspect ratio can also be in a range from> 1: 2.5 to ⁇ 1: 4 or from> 1: 3 to ⁇ 1: 3.5.
  • the transverse side of the rectangular basic body and the transverse side of the bottom of the molding box can furthermore have a length ratio of> 1: 2 to ⁇ 1: 5.
  • the aspect ratio can also be in a range from> 1: 2.5 to ⁇ 1: 4 or from> 1: 3 to ⁇ 1: 3.5.
  • the bulges can be parts of a circular arc and, on the one hand, the distance of the center of the underlying circle to the corresponding corner point of the rectangle and, on the other hand, the radius underlying the circular arc have an aspect ratio of> 1: 10 to ⁇ 1: 1.
  • the distance of the arcuate bulge is finally described by the corner of the rectangle used as an intermediate construction element.
  • the aspect ratio is 1:10, it means that the center of the underlying circle is 10% of its radius away from the vertex.
  • the range of aspect ratios can also be ⁇ l: 50 to ⁇ 1: 1 or ⁇ l: 10 to ⁇ 1:40.
  • the block foam is polyurethane foam and the reaction components comprise a polyol component and an isocyanate component.
  • the reaction components can either be premixed premixed in the container or it can be presented separately in the container and then mixed, for example by means of a stirrer, the polyol component and the isocyanate component.
  • the present invention furthermore relates to a device for the discontinuous production of block foam, comprising a molding box and a lid which can be inserted into the molding box.
  • the lid has a recess which simulates the contour of a container.
  • the horizontal cross-sectional contour of the container can be described by providing a bulge in the region of at least one of the corner points starting from a basic body comprising at least three corner points.
  • the lid is supported by its side walls on the bottom of the mold box, so that under the lid creates a cavity.
  • This cavity can be filled by means of the inventively designed container with reaction mixture.
  • the reaction mixture spreads uniformly over the bottom of the mold box, foams up and pushes the lid up in the course of the foam development.
  • the recess in the lid, so in the horizontal cover surface, is suitable for receiving a container, which may have the geometries described above.
  • the device is particularly suitable for the production of polyurethane foam.
  • FIG. 1 is the horizontal cross-sectional contour of a container for the invention
  • FIG. 2 shows the horizontal cross-sectional contour of a further container for the method according to the invention
  • FIG. 3 shows the horizontal cross-sectional contour of a further container for the method according to the invention
  • FIG. 3a shows the geometric construction of the cross-sectional contour of the container of FIG. 3
  • FIG. 4 shows a further variant of a cross-sectional contour from FIG. 3
  • FIG. 5 shows a further variant of a cross-sectional contour from FIG. 3
  • FIG. 6 shows a further variant of a cross-sectional contour from FIG. 3
  • FIG. 7 a molding box for the production of block foam
  • FIG. 8a-8c the time course of filling a molding box
  • FIG. 1 shows the horizontal cross-sectional contour of a container which is used in the method according to the invention.
  • the container has an oblong shape in cross-section with a long side 1 and a short side 2.
  • curved bulges 3 At the corners of the contour are curved bulges 3, which can be regarded as parts of a circular arc.
  • the contours of the long side 1 and the short side 2 are each concave, that is, curved toward the interior of the container.
  • FIG. 2 shows the horizontal cross-sectional contour of a further container which is used in the method according to the invention.
  • the container has an oblong shape in cross-section with a long side 1 and a short side 2.
  • curved bulges 3 At the corners of the contour are curved bulges 3, which can be regarded as parts of a circular arc.
  • the contours of the long side 1 and the short side 2 are each convex, ie curved away from the interior of the container.
  • FIG. 3 shows the horizontal cross-sectional contour of a further container which is used in the method according to the invention.
  • the container has an oblong shape in cross-section with a long side 1 and a short side 2.
  • curved bulges 3 which can be regarded as parts of a circular arc.
  • the contours of the long side 1 and the short side 2 are each straight.
  • These straight sections 1 and 2 of the contour and thus the container wall can be regarded as remnants of a rectangular basic body. If sections 1 and 2 are extended until they intersect, the geometrical shape of the rectangular base is obtained.
  • the curved bulges 3 can be considered as parts of a circular arc.
  • FIG. 3a shows the geometric construction of the structure shown in FIG. 3 shown contour, so the container wall.
  • the rectangular base body is constructed by the wall sections 1, 2, 4 and 5.
  • the corners are designated by dots 6.
  • the corners 6 are centers for circles, which are formed by arcs 3 and 7. If the circles and the rectangular basic body are combined with each other, then the dashed segments and a cross-sectional contour according to FIG. 3 remains.
  • FIG. 4 shows a further variant of a horizontal cross section of a container for the method according to the invention.
  • the center points of the circles, which form the circular arc-shaped bulges 3 are positioned outside the rectangular basic body with the wall sections 1 and 2.
  • FIG. 5 shows a further variant of a horizontal cross-sectional contour of a container for the method according to the invention.
  • the centers of the circles, which form the circular arc-shaped bulges 3 positioned on the corners of the rectangular base body.
  • the diameter of the circles is the same size as the shorter side length of the rectangle, so that the wall portion 2 of FIG. 3 is no longer recognizable.
  • FIG. 6 shows a further variant of a horizontal cross-sectional contour of a container for the method according to the invention.
  • the centers of the circles, which form the circular arc-shaped bulges 3 positioned within the rectangular base body with the wall sections 1 and 2.
  • FIG. 7 shows a molding box for the production of block foam.
  • This molding box has the walls 8 and 9.
  • the fourth side wall 8 ' which is indicated in the drawing, has been folded over hinges 10 to the side.
  • cover 11 has been inserted.
  • the lid 11 is supported by its side walls on the bottom of the mold box, so that under the lid 11, a cavity is formed. This cavity can be filled with capable of foaming reaction mixture.
  • Cover 11 has a recess 12 which is suitable for receiving a container.
  • the horizontal cross-sectional contour of this recess and thus of the corresponding container is represented by a rectangular base body, which further has curved bulges at the corners. It is expedient that the recess 12 of the lid 11 corresponds to the shape of the container, since a sealing of the lid relative to the reaction mixture can be better achieved.
  • FIG. 8a-8c show schematically how in the method according to the invention the bottom of a molding box is filled with reaction mixture.
  • the view is directly from above on the molding box.
  • FIG. 8a shows the starting position.
  • the molding box is formed by longitudinal sides 8 and transverse sides 9 as well as by the bottom 13.
  • a container is positioned, which has a rectangular base body, formed by wall sections 1 and 2, and curved bulges 3.
  • the container is filled with capable of foaming reaction mixture 14.
  • reaction mixture 14 flows over the bottom 13 of the molding box. Due to the Design of the container, the reaction mixture 14 does not spread radially uniform, but starts from the original container shape. In the course of propagation, the shape of the spreading reaction mixture 14 continues to approach the geometry of the molding box.
  • the propagating wavefront 15 is shown by a dashed line.
  • FIG. Fig. 8c shows a later time state after removal of the container.
  • the reaction mixture 14 now covers almost the entire bottom 13 of the molding box. It can be seen that the distance of the wavefront 15 to the longitudinal sides 8 and transverse sides 9 and to the corners of the molding box has only slight differences. The wavefront 15 will reach the walls 8, 9 of the container as well as its corners at substantially the same time.
  • the present invention has been described above as belonging to a process for producing slabstock foam. However, it is also within the scope of the invention and its equivalents that the method with the container according to the invention can be used wherever it is important to distribute a fluid, in particular a viscous and / or reacting fluid, on a surface, that the fluid reaches the respective vertical area boundary with the smallest possible time difference.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyurethanes Or Polyureas (AREA)
PCT/EP2009/000554 2008-01-31 2009-01-29 Verfahren und vorrichtung zur herstellung von blockschaumstoff Ceased WO2009095229A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/865,019 US20140077407A1 (en) 2008-01-31 2009-01-29 Method and device for producing slabstock foam
EP09705426A EP2247423A2 (de) 2008-01-31 2009-01-29 Verfahren und vorrichtung zur herstellung von blockschaumstoff
JP2010544631A JP2011510841A (ja) 2008-01-31 2009-01-29 スラブストック発泡体の製造方法及び製造装置
CN2009801036879A CN101932419A (zh) 2008-01-31 2009-01-29 用于生产泡沫材料板的方法和装置

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008007078A DE102008007078B3 (de) 2008-01-31 2008-01-31 Verfahren und Vorrichtung zur Herstellung von Blockschaumstoff
DE102008007078.5 2008-01-31

Publications (2)

Publication Number Publication Date
WO2009095229A2 true WO2009095229A2 (de) 2009-08-06
WO2009095229A3 WO2009095229A3 (de) 2010-04-15

Family

ID=40577361

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/000554 Ceased WO2009095229A2 (de) 2008-01-31 2009-01-29 Verfahren und vorrichtung zur herstellung von blockschaumstoff

Country Status (6)

Country Link
US (1) US20140077407A1 (https=)
EP (1) EP2247423A2 (https=)
JP (1) JP2011510841A (https=)
CN (1) CN101932419A (https=)
DE (1) DE102008007078B3 (https=)
WO (1) WO2009095229A2 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4233898A2 (en) 2016-05-04 2023-08-30 CureVac SE Influenza mrna vaccines

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4160074A (en) 1975-09-12 1979-07-03 Nihon Soflan Chemical & Engineering Co., Ltd. Polyisocyanate foam having isotropic cells and method and apparatus for preparing same

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Publication number Priority date Publication date Assignee Title
GB1022559A (en) * 1964-01-14 1966-03-16 Nat Gypsum Co Foamed synthetic resins and method and apparatus for producing the same
JPS5848338B2 (ja) * 1975-09-12 1983-10-27 東洋ゴム工業株式会社 トウホウセイキホウオユウスルポリイソシアネ−トケイハツポウタイノセイゾウホウホウ ナラビニ ソノソウチ
JPS5250060A (en) * 1975-10-20 1977-04-21 Kyowa Shinku Gijutsu Kk Vacuum defreezing process for freezed substance and its apparatus
NO773175L (no) * 1977-09-15 1979-03-16 Laader Berg Anordning ved anlegg for fremstilling av skumplast
DE2901176A1 (de) * 1979-01-13 1980-07-24 Hennecke Gmbh Maschf Einrichtung zum diskontinuierlichen herstellen von blockschaumstoff
DE2901177A1 (de) * 1979-01-13 1980-07-24 Bayer Ag Einrichtung zum diskontinuierlichen herstellen von blockschaumstoff
IE52288B1 (en) * 1981-02-18 1987-09-02 Hyman Int Ltd Production of foams
JPS6177214U (https=) * 1984-10-25 1986-05-23
JPH0784015B2 (ja) * 1987-03-12 1995-09-13 東洋護謨化学工業株式会社 ポリウレタンフオ−ムの製造方法
JPS63222819A (ja) * 1987-03-12 1988-09-16 Human Ind Corp ポリウレタンフオ−ムの製造方法
DE19834100C2 (de) * 1998-07-29 2000-05-11 Hennecke Gmbh Verfahren und Vorrichtung zum Herstellen von Schaumstoffblöcken mit eckigem Querschnitt im Flocken-Verbund

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
US4160074A (en) 1975-09-12 1979-07-03 Nihon Soflan Chemical & Engineering Co., Ltd. Polyisocyanate foam having isotropic cells and method and apparatus for preparing same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4233898A2 (en) 2016-05-04 2023-08-30 CureVac SE Influenza mrna vaccines

Also Published As

Publication number Publication date
EP2247423A2 (de) 2010-11-10
CN101932419A (zh) 2010-12-29
US20140077407A1 (en) 2014-03-20
JP2011510841A (ja) 2011-04-07
DE102008007078B3 (de) 2009-05-28
WO2009095229A3 (de) 2010-04-15

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