WO2009074208A3 - Materiau d'electrode negative pour batteries li-ion - Google Patents

Materiau d'electrode negative pour batteries li-ion Download PDF

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Publication number
WO2009074208A3
WO2009074208A3 PCT/EP2008/009763 EP2008009763W WO2009074208A3 WO 2009074208 A3 WO2009074208 A3 WO 2009074208A3 EP 2008009763 W EP2008009763 W EP 2008009763W WO 2009074208 A3 WO2009074208 A3 WO 2009074208A3
Authority
WO
WIPO (PCT)
Prior art keywords
negative electrode
electrode material
ion batteries
batteries
lithium
Prior art date
Application number
PCT/EP2008/009763
Other languages
English (en)
Other versions
WO2009074208A2 (fr
Inventor
Stéphane LEVASSEUR
Cécile Tessier
Josette Olivier-Fourcade
Laure Monconduit
Costana Ionica-Bousquet
Claire Villevieille
Michèle VAN THOURNOUT
Original Assignee
Umicore
Centre National De La Recherche Scientifique
Saft Groupe S.A.
Universite Montpellier 2
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Umicore, Centre National De La Recherche Scientifique, Saft Groupe S.A., Universite Montpellier 2 filed Critical Umicore
Priority to CA2708708A priority Critical patent/CA2708708C/fr
Priority to US12/746,319 priority patent/US8486309B2/en
Priority to CN2008801200794A priority patent/CN101918317B/zh
Priority to KR1020107013399A priority patent/KR101439586B1/ko
Priority to JP2010537271A priority patent/JP5389046B2/ja
Priority to BRPI0821589A priority patent/BRPI0821589A2/pt
Priority to EP08859157A priority patent/EP2231524A2/fr
Publication of WO2009074208A2 publication Critical patent/WO2009074208A2/fr
Publication of WO2009074208A3 publication Critical patent/WO2009074208A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/003—Titanates
    • C01G23/005—Alkali titanates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/003—Titanates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Cobaltates
    • C01G51/42—Cobaltates containing alkali metals, e.g. LiCoO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La présente invention concerne les piles, accumulateurs ou batteries au lithium, et plus particulièrement un matériau actif pour l'électrode négative de batterie rechargeables. Il s'agit plus particulièrement d'un matériau comprenant une phase ayant comme formule générale Li2 +v-4cCcTi3-wFexMyM'zO7-α, dans laquelle M et M' sont des ions métalliques des groupes 2 à 15 ayant un rayon ionique entre 0.5 et 0.8 Å en environnement octaédrique d'oxygène, v, w, x, y, z et α étant liés par les relations: 2α = -v+4w-3x-ny-n'z, garantissant l'électroneutralité, avec n et n' les degrés d'oxydation formels respectifs de M et M'; -0,5 ≤ v ≤ +0,5; y+z > 0; x+y+z = w et 0 < w ≤ 0,3; caractérisé en ce que au moins une partie du lithium est substituée par du carbone selon la relation 0 < c ≤ (2+v)/4. Le matériau de présente des capacités massiques et volumiques améliorées, pouvant atteindre 190 Ah/kg, tout en conservant les avantages précédemment acquis, notamment: - une faible perte en capacité au premier cycle, de 2 à 10 Ah/kg; - une excellente cyclabilité; - une faible polarisation de 30 à 70 mV en régime C/15.
PCT/EP2008/009763 2007-12-10 2008-11-19 Materiau d'electrode negative pour batteries li-ion WO2009074208A2 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA2708708A CA2708708C (fr) 2007-12-10 2008-11-19 Materiau d'electrode negative pour batteries li-ion
US12/746,319 US8486309B2 (en) 2007-12-10 2008-11-19 Negative electrode material for Li-ion batteries
CN2008801200794A CN101918317B (zh) 2007-12-10 2008-11-19 用于锂离子电池的负极材料
KR1020107013399A KR101439586B1 (ko) 2007-12-10 2008-11-19 Ｌi-이온 배터리용 음극 물질
JP2010537271A JP5389046B2 (ja) 2007-12-10 2008-11-19 Ｌｉイオン電池のための負電極材料
BRPI0821589A BRPI0821589A2 (pt) 2007-12-10 2008-11-19 material ativo para um eletrodo de bateria de lítio, método para sintetizar o material sintético, uso, e, célula, acumulador ou bateria de lítio contendo um material ativo
EP08859157A EP2231524A2 (fr) 2007-12-10 2008-11-19 Materiau d'electrode negative pour batteries li-ion

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP07291475.7 2007-12-10
EP07291475 2007-12-10
US633008P 2008-01-07 2008-01-07
US61/006.330 2008-01-07

Publications (2)

Publication Number Publication Date
WO2009074208A2 WO2009074208A2 (fr) 2009-06-18
WO2009074208A3 true WO2009074208A3 (fr) 2009-09-17

Family

ID=39885000

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/009763 WO2009074208A2 (fr) 2007-12-10 2008-11-19 Materiau d'electrode negative pour batteries li-ion

Country Status (9)

Country Link
US (1) US8486309B2 (fr)
EP (1) EP2231524A2 (fr)
JP (1) JP5389046B2 (fr)
KR (1) KR101439586B1 (fr)
CN (1) CN101918317B (fr)
BR (1) BRPI0821589A2 (fr)
CA (1) CA2708708C (fr)
TW (1) TWI462378B (fr)
WO (1) WO2009074208A2 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101340821B1 (ko) 2009-03-30 2013-12-11 유미코르 리튬 이차 전지용 고전압 음극 활성 물질
JP2011165372A (ja) * 2010-02-05 2011-08-25 Nippon Telegr & Teleph Corp <Ntt> リチウム二次電池用負極材料とその製造方法およびリチウム二次電池
US7909576B1 (en) * 2010-06-24 2011-03-22 General Electric Company Fastening device for rotor blade component
JP5662261B2 (ja) * 2011-06-20 2015-01-28 日本電信電話株式会社 リチウム二次電池用負極材料製造方法及びリチウム二次電池
DE102012203139A1 (de) * 2012-02-29 2013-08-29 Robert Bosch Gmbh Feststoffzelle
FR2992955A1 (fr) 2012-07-06 2014-01-10 Saint Gobain Ct Recherches Produit fondu a base de lithium
FR2992956A1 (fr) 2012-07-06 2014-01-10 Saint Gobain Ct Recherches Produit fondu a base de lithium

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003030283A1 (fr) * 2001-10-02 2003-04-10 Valence Technology, Inc. Pile au lithium a base de titanates de metal de transition lithie
WO2004100292A1 (fr) * 2003-05-09 2004-11-18 Umicore Electrode negative pour batteries au lithium

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11283624A (ja) * 1998-03-31 1999-10-15 Matsushita Electric Ind Co Ltd リチウム二次電池およびその製造方法
JP2001185141A (ja) 1999-12-22 2001-07-06 Kyocera Corp リチウム電池
JP2002008658A (ja) 2000-06-27 2002-01-11 Toyota Central Res & Dev Lab Inc リチウム二次電池電極活物質用リチウムチタン複合酸化物およびその製造方法
CA2327370A1 (fr) * 2000-12-05 2002-06-05 Hydro-Quebec Nouvelle methode de fabrication de li4ti5o12 pur a partir du compose ternaire tix-liy-carbone: effet du carbone sur la synthese et la conductivite de l'electrode
EP1261050A1 (fr) * 2001-05-23 2002-11-27 n.v. Umicore s.a. Poudre de phosphate de lithium et d'un métal de transition pour piles rechargeables
CN100448071C (zh) * 2003-03-18 2008-12-31 黄穗阳 锂电池正极材料及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003030283A1 (fr) * 2001-10-02 2003-04-10 Valence Technology, Inc. Pile au lithium a base de titanates de metal de transition lithie
WO2004100292A1 (fr) * 2003-05-09 2004-11-18 Umicore Electrode negative pour batteries au lithium
EP1623473B1 (fr) * 2003-05-09 2006-06-21 Umicore Electrode negative pour batteries au lithium

Also Published As

Publication number Publication date
BRPI0821589A2 (pt) 2015-09-29
US20110042628A1 (en) 2011-02-24
WO2009074208A2 (fr) 2009-06-18
TWI462378B (zh) 2014-11-21
EP2231524A2 (fr) 2010-09-29
JP5389046B2 (ja) 2014-01-15
CA2708708A1 (fr) 2009-06-18
TW200941801A (en) 2009-10-01
KR101439586B1 (ko) 2014-09-11
CN101918317B (zh) 2013-03-27
CA2708708C (fr) 2013-11-05
CN101918317A (zh) 2010-12-15
KR20100113488A (ko) 2010-10-21
US8486309B2 (en) 2013-07-16
JP2011507166A (ja) 2011-03-03

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