WO2009038125A1 - Polymère de nitroxyde de pyrroline et batterie l'utilisant - Google Patents

Polymère de nitroxyde de pyrroline et batterie l'utilisant Download PDF

Info

Publication number
WO2009038125A1
WO2009038125A1 PCT/JP2008/066855 JP2008066855W WO2009038125A1 WO 2009038125 A1 WO2009038125 A1 WO 2009038125A1 JP 2008066855 W JP2008066855 W JP 2008066855W WO 2009038125 A1 WO2009038125 A1 WO 2009038125A1
Authority
WO
WIPO (PCT)
Prior art keywords
battery
polymer
pyrroline nitroxide
same
pyrroline
Prior art date
Application number
PCT/JP2008/066855
Other languages
English (en)
Japanese (ja)
Inventor
Hiroyuki Nishide
Kenichi Oyaizu
Nobutaka Fujimoto
Yuji Kinpara
Shigeyuki Iwasa
Kentaro Nakahara
Original Assignee
Waseda University
Sumitomo Seika Chemicals Co., Ltd.
Nec Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Waseda University, Sumitomo Seika Chemicals Co., Ltd., Nec Corporation filed Critical Waseda University
Priority to JP2009533174A priority Critical patent/JP5424402B2/ja
Publication of WO2009038125A1 publication Critical patent/WO2009038125A1/fr

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F234/00—Copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F34/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/137—Electrodes based on electro-active polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/109—Primary casings; Jackets or wrappings characterised by their shape or physical structure of button or coin shape
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention porte sur un polymère de nitroxyde de pyrroline utilisé en tant que matériau d'électrode pour une batterie apte à émettre un courant de forte intensité, tout en présentant une faible diminution de capacité même lorsqu'elle est chargée/déchargée de façon répétée. L'invention porte également sur un matériau actif d'électrode contenant un tel polymère et sur une batterie utilisant un tel matériau actif d'électrode. De façon spécifique, l'invention porte sur un polymère de nitroxyde de pyrroline obtenu par polymérisation d'un composé nitroxyde de pyrroline représenté par la formule générale suivante (1). (Dans la formule, n est 0 ou 1).
PCT/JP2008/066855 2007-09-21 2008-09-18 Polymère de nitroxyde de pyrroline et batterie l'utilisant WO2009038125A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009533174A JP5424402B2 (ja) 2007-09-21 2008-09-18 ピロリン系ニトロキシド重合体およびそれを用いた電池

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007245589 2007-09-21
JP2007-245589 2007-09-21

Publications (1)

Publication Number Publication Date
WO2009038125A1 true WO2009038125A1 (fr) 2009-03-26

Family

ID=40467935

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/066855 WO2009038125A1 (fr) 2007-09-21 2008-09-18 Polymère de nitroxyde de pyrroline et batterie l'utilisant

Country Status (2)

Country Link
JP (1) JP5424402B2 (fr)
WO (1) WO2009038125A1 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010285408A (ja) * 2009-06-15 2010-12-24 Sumitomo Seika Chem Co Ltd ３−オキシラニル−２，２，５，５−テトラメチルピロリン−１−オキシルの製造方法
WO2012133204A1 (fr) * 2011-03-31 2012-10-04 学校法人早稲田大学 Batterie
WO2012133202A1 (fr) * 2011-03-31 2012-10-04 学校法人早稲田大学 Composition radicalaire et batterie l'utilisant
DE102014003300A1 (de) 2014-03-07 2015-09-10 Evonik Degussa Gmbh Neue Tetracyanoanthrachinondimethanpolymere und deren Verwendung
DE102014004760A1 (de) 2014-03-28 2015-10-01 Evonik Degussa Gmbh Neue 9,10-Bis(1,3-dithiol-2-yliden)-9,10-dihydroanthracenpolymere und deren Verwendung
EP3136410A1 (fr) 2015-08-26 2017-03-01 Evonik Degussa GmbH Utilisation de certains polymeres en tant qu'accumulateurs de charge
EP3135704A1 (fr) 2015-08-26 2017-03-01 Evonik Degussa GmbH Utilisation de certains polymeres en tant qu'accumulateurs de charge
EP3279223A1 (fr) 2016-08-05 2018-02-07 Evonik Degussa GmbH Utilisation de polymères contenant du thianthrène en tant qu'accumulateurs de charge
WO2018024901A1 (fr) 2016-08-05 2018-02-08 Evonik Degussa Gmbh Utilisation de polymères contenant du thianthrène comme accumulateurs de charges
WO2018046387A1 (fr) 2016-09-06 2018-03-15 Evonik Degussa Gmbh Procédé d'oxydation améliorée de groupes aminés secondaires
DE102017005924A1 (de) 2017-06-23 2018-12-27 Friedrich-Schiller-Universität Jena Verwendung benzotriazinyl-haltiger Polymere als Ladungsspeicher
US10756348B2 (en) 2015-08-26 2020-08-25 Evonik Operations Gmbh Use of certain polymers as a charge store
US10844145B2 (en) 2016-06-02 2020-11-24 Evonik Operations Gmbh Method for producing an electrode material
US10957907B2 (en) 2015-08-26 2021-03-23 Evonik Operations Gmbh Use of certain polymers as a charge store

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002151084A (ja) * 2000-02-25 2002-05-24 Nec Corp 二次電池
JP2002304996A (ja) * 2001-04-03 2002-10-18 Nec Corp 蓄電デバイス
JP2005097409A (ja) * 2003-09-24 2005-04-14 Mitsubishi Gas Chem Co Inc 安定ラジカルを持つ高分子化合物の製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002151084A (ja) * 2000-02-25 2002-05-24 Nec Corp 二次電池
JP2002304996A (ja) * 2001-04-03 2002-10-18 Nec Corp 蓄電デバイス
JP2005097409A (ja) * 2003-09-24 2005-04-14 Mitsubishi Gas Chem Co Inc 安定ラジカルを持つ高分子化合物の製造方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KENICHI OYAIZU ET AL.: "Synthesis and Characterization of Radical-Bearing Polyethers as an Electrode-Active Material for Organic Secondary Batteries", MACROMOLECULES, vol. 41, no. 18, 19 August 2008 (2008-08-19), pages 6646 - 6652 *
OZHOGINA OLGA A.: "Synthesis of bifunctionalized nitroxyls via intramolecular epoxide ring opening", TETRAHEDRON LETTERS, vol. 43, no. 4, 21 January 2002 (2002-01-21), pages 553 - 555 *

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010285408A (ja) * 2009-06-15 2010-12-24 Sumitomo Seika Chem Co Ltd ３−オキシラニル−２，２，５，５−テトラメチルピロリン−１−オキシルの製造方法
US9356292B2 (en) 2011-03-31 2016-05-31 Sumitomo Seika Chemicals Co., Ltd. Radical composition and battery using same
WO2012133204A1 (fr) * 2011-03-31 2012-10-04 学校法人早稲田大学 Batterie
WO2012133202A1 (fr) * 2011-03-31 2012-10-04 学校法人早稲田大学 Composition radicalaire et batterie l'utilisant
JP5969981B2 (ja) * 2011-03-31 2016-08-17 住友精化株式会社 ラジカル組成物およびそれを用いた電池
DE102014003300A1 (de) 2014-03-07 2015-09-10 Evonik Degussa Gmbh Neue Tetracyanoanthrachinondimethanpolymere und deren Verwendung
US9890230B2 (en) 2014-03-07 2018-02-13 Evonik Degussa Gmbh Tetracyanoanthraquinodimethane polymers and use thereof
DE102014004760A1 (de) 2014-03-28 2015-10-01 Evonik Degussa Gmbh Neue 9,10-Bis(1,3-dithiol-2-yliden)-9,10-dihydroanthracenpolymere und deren Verwendung
US10263280B2 (en) 2014-03-28 2019-04-16 Evonik Degussa Gmbh 9,10-Bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene polymers and use thereof
EP3136410A1 (fr) 2015-08-26 2017-03-01 Evonik Degussa GmbH Utilisation de certains polymeres en tant qu'accumulateurs de charge
EP3135704A1 (fr) 2015-08-26 2017-03-01 Evonik Degussa GmbH Utilisation de certains polymeres en tant qu'accumulateurs de charge
US10957907B2 (en) 2015-08-26 2021-03-23 Evonik Operations Gmbh Use of certain polymers as a charge store
US10756348B2 (en) 2015-08-26 2020-08-25 Evonik Operations Gmbh Use of certain polymers as a charge store
US10844145B2 (en) 2016-06-02 2020-11-24 Evonik Operations Gmbh Method for producing an electrode material
WO2018024901A1 (fr) 2016-08-05 2018-02-08 Evonik Degussa Gmbh Utilisation de polymères contenant du thianthrène comme accumulateurs de charges
US10608255B2 (en) 2016-08-05 2020-03-31 Evonik Operations Gmbh Use of thianthrene-containing polymers as a charge store
EP3279223A1 (fr) 2016-08-05 2018-02-07 Evonik Degussa GmbH Utilisation de polymères contenant du thianthrène en tant qu'accumulateurs de charge
WO2018046387A1 (fr) 2016-09-06 2018-03-15 Evonik Degussa Gmbh Procédé d'oxydation améliorée de groupes aminés secondaires
US11001659B1 (en) 2016-09-06 2021-05-11 Evonik Operations Gmbh Method for the improved oxidation of secondary amine groups
DE102017005924A1 (de) 2017-06-23 2018-12-27 Friedrich-Schiller-Universität Jena Verwendung benzotriazinyl-haltiger Polymere als Ladungsspeicher

Also Published As

Publication number Publication date
JP5424402B2 (ja) 2014-02-26
JPWO2009038125A1 (ja) 2011-01-06

Similar Documents

Publication Publication Date Title
WO2009038125A1 (fr) Polymère de nitroxyde de pyrroline et batterie l'utilisant
WO2008061174A3 (fr) Cellule électrochimique secondaire avec une capacité de vitesse élevée
WO2008103666A3 (fr) Électrodes comprenant des particules actives mixtes
TW200605424A (en) Composition for electrolyte, polymer electrolyte, and battery using the same
TW200737565A (en) Non-aqueous electrolyte and electrochemical device with an improved safety
EP2131470A3 (fr) Bloc-batteries et procédé de chargement
TW200703754A (en) Electrode for lithium secondary battery comprising electrode additive and lithium secondary battery using the same
WO2008099557A1 (fr) Bouillie destinée à la formation d'une électrode de batterie
EP1819002A3 (fr) Composition électrolyte pour batteries nickel-zinc
WO2009060828A1 (fr) Oxyde métallique complexe et batterie secondaire au sodium
WO2007102997A3 (fr) Chargeur de piles
WO2009089018A3 (fr) Electrodes poreuses et procédés associés
WO2008139157A8 (fr) Anode de silicium pour une batterie rechargeable
MY151488A (en) Improved energy storage device
FR2932175B1 (fr) Materiau d'electrode positive forme d'un oxyde de type lamellaire pour accumulateur au lithium.
WO2007116363A3 (fr) Pile electrochimique au lithium rechargeable
MX345475B (es) Anodo para celda de bateria de iones de litio, su proceso de fabricacion y esta bateria que los incorpora.
WO2006105253A3 (fr) Accumulateur electrochimique
TW200740001A (en) Non-aqueous electrolyte and electrochemical device with an improved safety
WO2009082492A3 (fr) Compositions de matériaux pour électrodes en petites particules et procédés pour leur formation
WO2012021029A3 (fr) Électrolyte non aqueux pour une pile rechargeable au lithium, et pile rechargeable au lithium contenant celui-ci
PL1749320T3 (pl) Akumulator litowy z polimerowym separatorem
TW200701536A (en) Lithium secondary battery having improved stability to overcharge
WO2009125967A3 (fr) Électrolyte non aqueux pour batteries secondaires au lithium et batteries secondaires au lithium le contenant
WO2012037426A3 (fr) Séparateur d'électrodes

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08832282

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2009533174

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 08832282

Country of ref document: EP

Kind code of ref document: A1