WO2009031614A1 - 炭化水素油の脱硫方法及びそれを用いた燃料電池システム - Google Patents

炭化水素油の脱硫方法及びそれを用いた燃料電池システム Download PDF

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Publication number
WO2009031614A1
WO2009031614A1 PCT/JP2008/065971 JP2008065971W WO2009031614A1 WO 2009031614 A1 WO2009031614 A1 WO 2009031614A1 JP 2008065971 W JP2008065971 W JP 2008065971W WO 2009031614 A1 WO2009031614 A1 WO 2009031614A1
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WIPO (PCT)
Prior art keywords
hydrocarbon oil
desulfurizing
fuel cell
cell system
disclosed
Prior art date
Application number
PCT/JP2008/065971
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English (en)
French (fr)
Inventor
Yasuhiro Toida
Masataka Herai
Original Assignee
Japan Energy Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Energy Corporation filed Critical Japan Energy Corporation
Priority to JP2009531274A priority Critical patent/JP5337036B2/ja
Publication of WO2009031614A1 publication Critical patent/WO2009031614A1/ja

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0675—Removal of sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

　本発明は、特に燃料電池で使用する灯油や軽油などの炭化水素油の脱硫方法について、還元処理や水素を必要とせず、また、常温から１００°C程度までの温度で、効率的に脱硫できる脱硫剤による炭化水素油の脱硫方法、さらに該脱硫方法を使用する燃料電池システムを提供することを課題とする。本発明の炭化水素油の脱硫方法は、アルミニウムを含有する金属酸化物及び／又は含水金属酸化物を、２００～９８０°Cの温度で焼成して得られる固体酸を含み、酸化アルミニウムを２０～１００質量％含有する脱硫剤と、炭化水素油とを接触させて脱硫することを特徴とする。脱硫剤は、硫酸根を含む酸化アルミニウム、特にγ-アルミナが好ましい。また、本発明は、係る炭化水素油の脱硫方法を使用する燃料電池システムである。
PCT/JP2008/065971 2007-09-07 2008-09-04 炭化水素油の脱硫方法及びそれを用いた燃料電池システム WO2009031614A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009531274A JP5337036B2 (ja) 2007-09-07 2008-09-04 炭化水素油の脱硫方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007232367 2007-09-07
JP2007-232367 2007-09-07

Publications (1)

Publication Number Publication Date
WO2009031614A1 true WO2009031614A1 (ja) 2009-03-12

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ID=40428927

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/065971 WO2009031614A1 (ja) 2007-09-07 2008-09-04 炭化水素油の脱硫方法及びそれを用いた燃料電池システム

Country Status (2)

Country Link
JP (1) JP5337036B2 (ja)
WO (1) WO2009031614A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010209125A (ja) * 2009-03-06 2010-09-24 Japan Energy Corp 炭化水素油の脱硫方法及び燃料電池システム
JP2010209154A (ja) * 2009-03-06 2010-09-24 Japan Energy Corp 炭化水素油の脱硫方法及び燃料電池システム
JP2011190369A (ja) * 2010-03-15 2011-09-29 Jx Nippon Oil & Energy Corp 吸着脱硫剤の製造方法、炭化水素油の脱硫方法及び燃料電池システム
JP2011207723A (ja) * 2010-03-30 2011-10-20 Jx Nippon Oil & Energy Corp 硫酸根アルミナの製造方法、炭化水素油の過酸化物価低減方法、炭化水素油の脱硫方法及び燃料電池システム
JP5328655B2 (ja) * 2007-09-07 2013-10-30 Ｊｘ日鉱日石エネルギー株式会社 固体酸、その製造方法及び固体酸を脱硫剤として用いる炭化水素油の脱硫方法
JP2021162362A (ja) * 2020-03-30 2021-10-11 一般財団法人石油エネルギー技術センター 脱硫率の推算方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106268620B (zh) * 2016-09-21 2019-01-25 曲阜师范大学 一种负载型固体酸甲醛消除剂的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2060091A (en) * 1932-08-13 1936-11-10 Standard Oil Co California Process of converting and removing sulphur from petroleum
US4835338A (en) * 1987-08-31 1989-05-30 Aluminum Company Of America Process for removal of carbonyl sulfide from organic liquid by adsorption using alumina adsorbent capable of regeneration
JP3251313B2 (ja) * 1991-10-03 2002-01-28 株式会社ジャパンエナジー アルミナ系固体酸触媒の製造法
WO2005073348A1 (ja) * 2004-02-02 2005-08-11 Japan Energy Corporation 炭化水素油の脱硫方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62246993A (ja) * 1986-04-21 1987-10-28 Mitsubishi Heavy Ind Ltd 低級パラフイン系炭化水素の製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2060091A (en) * 1932-08-13 1936-11-10 Standard Oil Co California Process of converting and removing sulphur from petroleum
US4835338A (en) * 1987-08-31 1989-05-30 Aluminum Company Of America Process for removal of carbonyl sulfide from organic liquid by adsorption using alumina adsorbent capable of regeneration
JP3251313B2 (ja) * 1991-10-03 2002-01-28 株式会社ジャパンエナジー アルミナ系固体酸触媒の製造法
WO2005073348A1 (ja) * 2004-02-02 2005-08-11 Japan Energy Corporation 炭化水素油の脱硫方法

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5328655B2 (ja) * 2007-09-07 2013-10-30 Ｊｘ日鉱日石エネルギー株式会社 固体酸、その製造方法及び固体酸を脱硫剤として用いる炭化水素油の脱硫方法
JP2010209125A (ja) * 2009-03-06 2010-09-24 Japan Energy Corp 炭化水素油の脱硫方法及び燃料電池システム
JP2010209154A (ja) * 2009-03-06 2010-09-24 Japan Energy Corp 炭化水素油の脱硫方法及び燃料電池システム
JP2011190369A (ja) * 2010-03-15 2011-09-29 Jx Nippon Oil & Energy Corp 吸着脱硫剤の製造方法、炭化水素油の脱硫方法及び燃料電池システム
JP2011207723A (ja) * 2010-03-30 2011-10-20 Jx Nippon Oil & Energy Corp 硫酸根アルミナの製造方法、炭化水素油の過酸化物価低減方法、炭化水素油の脱硫方法及び燃料電池システム
JP2021162362A (ja) * 2020-03-30 2021-10-11 一般財団法人石油エネルギー技術センター 脱硫率の推算方法
JP7454782B2 (ja) 2020-03-30 2024-03-25 一般財団法人石油エネルギー技術センター 脱硫率の推算方法

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Publication number Publication date
JPWO2009031614A1 (ja) 2010-12-16
JP5337036B2 (ja) 2013-11-06

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